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Carboline Plasite 7159 Part A Carboline Plasite 7159 Part A ALTEX COATINGS LTD Chemwatch Hazard Alert Code: 3 Version No: 1.2 Issue Date: 14/04/2020 Safety Data Sheet according to HSNO Regulations Print Date: 14/04/2020 S.GHS.NZL.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Carboline Plasite 7159 Part A Synonyms Not Available PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL Proper shipping name (including paint thinning or reducing compound) Other means of identification Not Available Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Part A of a multi-component industrial coating Details of the supplier of the safety data sheet Registered company name ALTEX COATINGS LTD Address 91-111 Oropi Road, Tauranga, New Zealand Other New Zealand Telephone +64 7 5411221 Fax +64 7 5411310 Website Not Available Email [email protected] Emergency telephone number Association / Organisation NZ POISONS CENTRE CHEMWATCH EMERGENCY RESPONSE Emergency telephone 0800 764 766 +64 800 700 112 numbers Other emergency telephone Not Available +61 2 9186 1132 numbers Once connected and if the message is not in your prefered language then please dial 01 SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. Classified as Dangerous Goods for transport purposes. Chronic Aquatic Hazard Category 2, Flammable Liquid Category 2, Skin Corrosion/Irritation Category 2, Eye Irritation Category 2, Reproductive Classification [1] Toxicity Category 2, Acute Toxicity (Oral) Category 5, Skin Sensitizer Category 1, Acute Aquatic Hazard Category 2, Acute Vertebrate Hazard Category 3 Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI Determined by Chemwatch 3.1B, 6.1E (oral), 6.3A, 6.4A, 6.5B (contact), 6.8B, 9.1B, 9.1D, 9.3C using GHS/HSNO criteria Label elements Hazard pictogram(s) SIGNAL WORD DANGER Hazard statement(s) H411 Toxic to aquatic life with long lasting effects. H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H303 May be harmful if swallowed. Page 1 continued... Version No: 1.2 Page 2 of 17 Issue Date: 14/04/2020 Carboline Plasite 7159 Part A Print Date: 14/04/2020 H317 May cause an allergic skin reaction. H433 Harmful to terrestrial vertebrates. Precautionary statement(s) Prevention P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P308+P313 IF exposed or concerned: Get medical advice/ attention. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P321 Specific treatment (see advice on this label). P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Precautionary statement(s) Storage P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 14808-60-7 25-50 silica crystalline - quartz 7779-90-0 10-25 zinc phosphate 9003-36-5 10-25 phenol/ formaldehyde glycidyl ether copolymer 107-98-2 10-25 propylene glycol monomethyl ether - alpha isomer 13463-67-7 2.5-10 titanium dioxide (rutile) 108-10-1 2.5-10 methyl isobutyl ketone 108-88-3 0.1-1 toluene SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Skin Contact Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Continued... Version No: 1.2 Page 3 of 17 Issue Date: 14/04/2020 Carboline Plasite 7159 Part A Print Date: 14/04/2020 Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Ingestion Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Indication of any immediate medical attention and special treatment needed for phosphate salts intoxication: All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Ingestion of large quantities of phosphate salts (over 1.0 grams for an adult) may cause an osmotic catharsis resulting in diarrhoea and probable abdominal cramps. Larger doses such as 4-8 grams will almost certainly cause these effects in everyone. In healthy individuals most of the ingested salt will be excreted in the faeces with the diarrhoea and, thus, not cause any systemic toxicity. Doses greater than 10 grams hypothetically may cause systemic toxicity. Treatment should take into consideration both anionic and cation portion of the molecule. All phosphate salts, except calcium salts, have a hypothetical risk of hypocalcaemia, so calcium levels should be monitored. Treat symptomatically. SECTION 5 FIREFIGHTING MEASURES Extinguishing media Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Advice for firefighters When silica dust is dispersed in air, firefighters should wear inhalation protection as hazardous substances from the fire may be adsorbed on the silica particles. When heated to extreme temperatures, (>1700 deg.C) amorphous silica can fuse. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water course. Fire Fighting Consider evacuation (or protect in place). Fight fire from a safe distance, with adequate cover. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control the fire and cool adjacent area. Avoid spraying water onto liquid pools. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). Fire/Explosion Hazard Combustion products include: carbon dioxide (CO2) aldehydes phosphorus oxides (POx) silicon dioxide (SiO2) other pyrolysis products typical of burning organic material. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Remove all ignition sources. Clean up all
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