Standard Thermodynamic Properties of Chemical
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Appendix a List of International Authors, Contributors, and Reviewers
APPENDIX A LIST OF INTERNATIONAL AUTHORS, CONTRIBUTORS, AND REVIEWERS COCHAIRS Ayité-Lô Nohende Ajavon Université de Lomé Togo Daniel L. Albritton National Oceanic and Atmospheric Administration US Gérard Mégie Centre National de la Recherche Scientifique France Robert T. Watson World Bank US AUTHORS AND CONTRIBUTORS CHAPTER 1 CONTROLLED SUBSTANCES AND OTHER SOURCE GASES Chapter Lead Authors Stephen A. Montzka NOAA Climate Monitoring and Diagnostics Laboratory US Paul J. Fraser CSIRO Division of Atmospheric Research Australia Coauthors James H. Butler NOAA Climate Monitoring and Diagnostics Laboratory US Peter S. Connell Lawrence Livermore National Laboratory US Derek M. Cunnold Georgia Institute of Technology US John S. Daniel NOAAAeronomy Laboratory US Richard G. Derwent UK Meteorological Office UK Shyam Lal Physical Research Laboratory India Archie McCulloch Marbury Technical Consulting UK David E. Oram University of East Anglia UK Claire E. Reeves University of East Anglia UK Eugenio Sanhueza Instituto Venezolano de Investigaciones Cientificas Venezuela L. Paul Steele CSIRO Division of Atmospheric Research Australia Guus J.M. Velders National Institute of Public Health and the Environment (RIVM) The Netherlands Ray F. Weiss University of California at San Diego/Scripps Institution US of Oceanography Rodolphe J. Zander Université de Liège Belgium Contributors Stephen O. Andersen Environmental Protection Agency US James Anderson Harvard University US Donald R. Blake University of California at Irvine US A.1 AUTHORS, CONTRIBUTORS, AND REVIEWERS Martyn P. Chipperfield University of Leeds UK Ed Dlugokencky NOAA Climate Monitoring and Diagnostics Laboratory US James W. Elkins NOAA Climate Monitoring and Diagnostics Laboratory US Andreas Engel Universität Frankfurt Germany David B. Harper The Queen's University of Belfast UK Emmanuel Mahieu Université de Liège Belgium Klaus Pfeilsticker Universität Heidelberg Germany Jean-Pierre Pommereau Service d'Aéronomie du CNRS France James M. -
Aldrich FT-IR Collection Edition I Library
Aldrich FT-IR Collection Edition I Library Library Listing – 10,505 spectra This library is the original FT-IR spectral collection from Aldrich. It includes a wide variety of pure chemical compounds found in the Aldrich Handbook of Fine Chemicals. The Aldrich Collection of FT-IR Spectra Edition I library contains spectra of 10,505 pure compounds and is a subset of the Aldrich Collection of FT-IR Spectra Edition II library. All spectra were acquired by Sigma-Aldrich Co. and were processed by Thermo Fisher Scientific. Eight smaller Aldrich Material Specific Sub-Libraries are also available. Aldrich FT-IR Collection Edition I Index Compound Name Index Compound Name 3515 ((1R)-(ENDO,ANTI))-(+)-3- 928 (+)-LIMONENE OXIDE, 97%, BROMOCAMPHOR-8- SULFONIC MIXTURE OF CIS AND TRANS ACID, AMMONIUM SALT 209 (+)-LONGIFOLENE, 98+% 1708 ((1R)-ENDO)-(+)-3- 2283 (+)-MURAMIC ACID HYDRATE, BROMOCAMPHOR, 98% 98% 3516 ((1S)-(ENDO,ANTI))-(-)-3- 2966 (+)-N,N'- BROMOCAMPHOR-8- SULFONIC DIALLYLTARTARDIAMIDE, 99+% ACID, AMMONIUM SALT 2976 (+)-N-ACETYLMURAMIC ACID, 644 ((1S)-ENDO)-(-)-BORNEOL, 99% 97% 9587 (+)-11ALPHA-HYDROXY-17ALPHA- 965 (+)-NOE-LACTOL DIMER, 99+% METHYLTESTOSTERONE 5127 (+)-P-BROMOTETRAMISOLE 9590 (+)-11ALPHA- OXALATE, 99% HYDROXYPROGESTERONE, 95% 661 (+)-P-MENTH-1-EN-9-OL, 97%, 9588 (+)-17-METHYLTESTOSTERONE, MIXTURE OF ISOMERS 99% 730 (+)-PERSEITOL 8681 (+)-2'-DEOXYURIDINE, 99+% 7913 (+)-PILOCARPINE 7591 (+)-2,3-O-ISOPROPYLIDENE-2,3- HYDROCHLORIDE, 99% DIHYDROXY- 1,4- 5844 (+)-RUTIN HYDRATE, 95% BIS(DIPHENYLPHOSPHINO)BUT 9571 (+)-STIGMASTANOL -
Abstract Measurement and Analysis of Bromate Ion
ABSTRACT MEASUREMENT AND ANALYSIS OF BROMATE ION REDUCTION IN SYNTHETIC GASTRIC JUICE by Jason Dimitrius Keith Bromate ion is a possible carcinogen that is regulated by the US EPA at a Maximum Contamination Level (MCL) of 10 µg/L in drinking water. In order to propose an improved scientifically appropriate bromate ion MCL, a more rigorous scientific methodology is needed for determining low level dose health risks. The objectives of this research project were to measure bromate ion with oxidizing and/or reducing agents typically ingested in foods and drinking water. The loss of bromate ion in HCl is too slow for significant reduction in the stomach. -5 Addition of 10 M H2S, a gastric juice component, decreases the half-life from 153 to 14 minutes. The ingested reducing agents iodide ion, nitrite ion, and iron(II) decrease the lifetime of bromate ion in the stomach. Chlorine, monochloramine, and iron(III) have little actual effect on the lifetime of bromate ion. The measured rates and chemical details of the reactions are discussed. MEASUREMENT AND ANALYSIS OF BROMATE ION REDUCTION IN SYNTHETIC GASTRIC JUICE A Thesis Submitted to the faculty of Miami University in partial fulfillment of the requirements for the degree of Master of Science Department of Chemistry by Jason Dimitrius Keith Miami University Oxford, Ohio 2005 Co-Advisor________________ (Dr. Gilbert Gordon) Co-Advisor________________ (Dr. Gilbert E. Pacey) Reader_________________ (Dr. Michael W. Crowder) Reader_________________ (Dr. Hongcai Zhou) TABLE OF CONTENTS TABLE OF CONTENTS ii LIST OF TABLES iii LIST OF FIGURES iv ACKNOWLEDGEMENTS v INTRODUCTION 1 Bromate Ion Chemistry and Human Toxicology 1 Prior Analytical Methodology 6 Objectives 7 METHOD DEVELOPMENT AND ESTABLISHMENT OF PROTOCOLS 7 Solution Preparation 7 Preparation and Measurement of Stock HOCl/ Cl2 and ClNH2 Solutions 11 Measurement of Iron(II) and Iron(III) in Solution 12 Instrumentation. -
China and Weapons of Mass Destruction: Implications for the United States
China and Weapons of Mass Destruction: Implications for the United States China and Weapons of Mass Destruction: Implications for the United States 5 November 1999 This conference was sponsored by the National Intelligence Council and Federal Research Division. The views expressed in this report are those of individuals and do not represent official US intelligence or policy positions. The NIC routinely sponsors such unclassified conferences with outside experts to gain knowledge and insight to sharpen the level of debate on critical issues. Introduction | Schedule | Papers | Appendix I | Appendix II | Appendix III | Appendix IV Introduction This conference document includes papers produced by distinguished experts on China's weapons-of-mass-destruction (WMD) programs. The seven papers were complemented by commentaries and general discussions among the 40 specialists at the proceedings. The main topics of discussion included: ● The development of China's nuclear forces. ● China's development of chemical and biological weapons. ● China's involvement in the proliferation of WMD. ● China's development of missile delivery systems. ● The implications of these developments for the United States. Interest in China's WMD stems in part from its international agreements and obligations. China is a party to the International Atomic Energy Agency (IAEA), the Treaty on the Non-Proliferation of Nuclear Weapons (NPT), the Zangger Committee, and the Chemical Weapons Convention (CWC) and has signed but not ratified the Comprehensive Nuclear Test Ban Treaty (CTBT). China is not a member of the Australia Group, the Wassenaar Arrangement, the Nuclear Suppliers Group, or the Missile Technology Control Regime (MTCR), although it has agreed to abide by the latter (which is not an international agreement and lacks legal authority). -
1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5- -
Investigation of Evaporation Characteristics of Polonium and Its Lighter Homologues Selenium and Tellurium from Liquid Pb-Bi-Eutecticum
EUROPEAN ORGANIZATION FOR NUCLEAR RESEARCH CERN-PH-EP/2004-061 18 November 2004 Investigation of evaporation characteristics of polonium and its lighter homologues selenium and tellurium from liquid Pb-Bi-eutecticum J. Neuhausen*1, U. Köster2 and B. Eichler1 1Laboratory for Radio- and Environmental Chemistry; Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland 2CERN, ISOLDE, CH-1211 Genève 23, Switzerland Abstract The evaporation behaviour of polonium and its lighter homologues selenium and tellurium dissolved in liquid Pb-Bi-eutecticum (LBE) has been studied at various temperatures in the range from 482 K up to 1330 K under Ar/H2 and Ar/H2O-atmospheres using γ-ray spectroscopy. Polonium release in the temperature range of interest for technical applications is slow. Within short term (1h) experiments measurable amounts of polonium are evaporated only at temperatures above 973 K. Long term experiments reveal that a slow evaporation of polonium occurs at temperatures around 873 K resulting in a fractional polonium loss of the melt around 1% per day. Evaporation rates of selenium and tellurium are smaller than those of polonium. The presence of H2O does not enhance the evaporation within the error limits of our experiments. The thermodynamics and possible reaction pathways involved in polonium release from LBE are discussed. (Submitted to Radiochimica Acta) * Author for correspondence (E-mail: [email protected]). 2 1. Introduction Liquid Lead-Bismuth eutecticum (LBE) is proposed to be used as target material in spallation neutron sources [1] as well as in Accelerator Driven Systems (ADS) for the transmutation of long-lived nuclear waste [2]. In these systems polonium is formed as a product of (p,xn) and (n,γ)-reactions according to the following processes: 209Bi ⎯⎯(p,xn)⎯→208,209Po (1) γ β − 209Bi ⎯⎯(n,⎯)→210Bi ⎯⎯→⎯ 210Po (2) Within 1 year of operation employing a proton beam current of 1 mA around 2 g of polonium are produced in this manner [3]. -
Operation Permit Application
Un; iy^\ tea 0 9 o Operation Permit Application Located at: 2002 North Orient Road Tampa, Florida 33619 (813) 623-5302 o Training Program TRAINING PROGRAM for Universal Waste & Transit Orient Road Tampa, Florida m ^^^^ HAZARDOUS WAb 1 P.ER^AlTTlNG TRAINING PROGRAM MASTER INDEX CHAPTER 1: Introduction Tab A CHAPTER 2: General Safety Manual Tab B CHAPTER 3: Protective Clothing Guide Tab C CHAPTER 4: Respiratory Training Program Tab D APPENDIX 1: Respiratory Training Program II Tab E CHAPTER 5: Basic Emergency Training Guide Tab F CHAPTER 6: Facility Operations Manual Tab G CHAPTER 7: Land Ban Certificates Tab H CHAPTER 8: Employee Certification Statement Tab. I CHAPTER ONE INTRODUCTION prepared by Universal Waste & Transit Orient Road Tampa Florida Introducti on STORAGE/TREATMENT PERSONNEL TRAINING PROGRAM All personnel involved in any handling, transportation, storage or treatment of hazardous wastes are required to start the enclosed training program within one-week after the initiation of employment at Universal Waste & Transit. This training program includes the following: Safety Equipment Personnel Protective Equipment First Aid & CPR Waste Handling Procedures Release Prevention & Response Decontamination Procedures Facility Operations Facility Maintenance Transportation Requirements Recordkeeping We highly recommend that all personnel involved in the handling, transportation, storage or treatment of hazardous wastes actively pursue additional technical courses at either the University of South Florida, or Tampa Junior College. Recommended courses would include general chemistry; analytical chemistry; environmental chemistry; toxicology; and additional safety and health related topics. Universal Waste & Transit will pay all registration, tuition and book fees for any courses which are job related. The only requirement is the successful completion of that course. -
Inorganic Chemistry for Dummies® Published by John Wiley & Sons, Inc
Inorganic Chemistry Inorganic Chemistry by Michael L. Matson and Alvin W. Orbaek Inorganic Chemistry For Dummies® Published by John Wiley & Sons, Inc. 111 River St. Hoboken, NJ 07030-5774 www.wiley.com Copyright © 2013 by John Wiley & Sons, Inc., Hoboken, New Jersey Published by John Wiley & Sons, Inc., Hoboken, New Jersey Published simultaneously in Canada No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except as permitted under Sections 107 or 108 of the 1976 United States Copyright Act, without either the prior written permis- sion of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 646-8600. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley. com/go/permissions. Trademarks: Wiley, the Wiley logo, For Dummies, the Dummies Man logo, A Reference for the Rest of Us!, The Dummies Way, Dummies Daily, The Fun and Easy Way, Dummies.com, Making Everything Easier, and related trade dress are trademarks or registered trademarks of John Wiley & Sons, Inc. and/or its affiliates in the United States and other countries, and may not be used without written permission. All other trade- marks are the property of their respective owners. John Wiley & Sons, Inc., is not associated with any product or vendor mentioned in this book. -
Boiling Rubidium A8 a Reactor : Coolant
UNITED STATES ATOMlC ENERGY CUMMISSiON -F - - 71013 BOILING RUBIDIUM A8 A REACTOR : COOLANT. PREPARkTION OF RUBDIUM adETAL, PHYBICAL AND 33PBER.MO~AMIcC PROFERTLES, AND COMPATIBILITY WITH INCONEL , technical Infor~ionEx?snsion, Oak Ridgs, Timnessee DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. This mprt em~~$utrraf 2 gtwks, Pcljrt I asd Pea*t 11. *. .I. I *** .* ** . ... .. : :: . :*:. *::: /f- 8. .* .*** . e.. 0.. .* 0.. * *. 0... 0.. *I *to.. 0 *a ** . ..a . .a* .* - -8 OPSE RIDCE SCHOOL OF REACTOR TECHNOUXY ''BOI~RUBIDIUM AS A BEACTOR.COOLANT : , PREPAMTION OF RUBIDIUM METALg PHYSICAL AND THERMJDYNAMIC PROPERTIESg AND COMPATIBILI!PY WII"H INCONEX" This report cont~insinformaticg. geiierated by E. group of @$SORT students under .the leadershim df S; Reed Nixon aa part of an assigned summer project. -
76 Chapt-24-Organic2
The Chemistry of Alkanes Physical Properties of Alkanes as molecular size increases so does the boiling point of the alkane increased size increased dispersion forces Alkanes Boiling Point ˚C H Methane CH 4 H C H -161.6 H H H Ethane C2H6 H C C H -88.6 H H Propane C3H8 CH3 (CH2)1 CH3 -42.1 Butane C4H10 CH3 (CH2)2 CH3 -0.5 Pentane C5H12 CH3 (CH2)3 CH3 36.1 hexane C6H14 CH3 (CH2)4 CH3 68.7 Chemical Reactions and Alkanes because the C-C and C-H bonds are relatively strong , the alkanes are fairly unreactive their inertness makes them valuable as lubricating materials and as backbone material in the construction of other hydrocarbons Combustion of Alkanes At high temperatures alkanes combust ΔH˚ CH4 + O2 CO2 + 2H2O -890.4 kJ C4H10 + 13/2O2 4CO2 + 5H2O -3119 kJ these reactions are all highly exothermic Halogenation of Alkanes at temperatures above 100 ˚C CH4 + Cl2 CH3Cl + HCl chloromethane CH3Cl + Cl2 CH2Cl2 + HCl dichloromethane CH2Cl2 + Cl2 CHCl3 + HCl trichloromethane chloroform CHCl3 + Cl2 CCl4 + HCl tetrachloromethane Carbon tetrachloride Mechanism for Halogenation of Methane CH4 + Cl2 CH3Cl + HCl hν Cl2 • Cl + • Cl hν: energy required to break the Cl-Cl bond • Cl H H C H H • Cl is very reactive and able to attack the C-H bond Mechanism for Halogenation of Methane CH4 + Cl2 CH3Cl + HCl CH4 + • Cl • CH3 + HCl H Cl H • C H H Mechanism for Halogenation of Methane CH4 + Cl2 CH3Cl + HCl • CH3 + Cl2 CH3 Cl + • Cl Cl Cl H • Cl • C H H H Cl C H H Mechanism for Halogenation of Methane Cl2 • Cl + • Cl chlorine free radical CH4 + • Cl • CH3 + HCl -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
Investigation on the Polonium Problem in Lead-Bismuth Coolant for Nuclear Reactors
Proceedings of the Korean Nuclear Society Spring Meeting Gyeongju, Korea, May 2003 Investigation on the Polonium Problem in Lead-Bismuth Coolant for Nuclear Reactors Sung Il Kim, Kun Jai Lee Korea Advanced Institute of Science and Technology 373-1, Kusong-dong, Yusong-gu, Daejon, 305-701, Korea Abstract By using lead-bismuth eutectic as a coolant for nuclear reactors and liquid metal targets of accelerator driven system attention is paid to high hazard of alpha-active polonium generated in lead-bismuth eutectic under operation of these installation. Therefore rather high technology culture and special means of radiation safety ensuring are required in handling with radioactive lead-bismuth eutectic. The results of investigation are briefly described on lead-bismuth eutectic purification from polonium using alkaline extraction. 1. Introduction Very long-lived core, lead-bismuth cooled, fast reactors have continued to be investigated in Japan, and in the United States at the University of California at Berkeley. A lead-bismuth cooled, accelerator-driven, sub-critical actinide-burner (labeled ATW) has been proposed by the Los Alamos National Laboratory (LANL) for burning the actinides and long-life fission products from spent light water reactor fuel. In Korea, KAERI is setting up a long-term research program called HYPER (Hybrid Power Extraction Reactor) and also SNU (Seoul National University) proposed a new transmutation concept designated as PEACER (Proliferation-resistant Environmental- friendly Accident-tolerant Continuable and Economical Reactor). Both of them include the concept of pyroprocess-based partitioning system and lead-bismuth cooled transmutation reactor. So we needed a study on the problem of coolant activation in lead-bismuth coolant reactor.