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Carboline Pyroclad X1 Part A Carboline Pyroclad X1 Part A ALTEX COATINGS LTD Chemwatch Hazard Alert Code: 3 Version No: 1.2 Issue Date: 12/04/2020 Safety Data Sheet according to HSNO Regulations Print Date: 12/04/2020 S.GHS.NZL.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Carboline Pyroclad X1 Part A Synonyms Not Available Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains bisphenol A/ diglycidyl ether resin, liquid) Other means of identification Not Available Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Part A of a multi-component industrial coating Details of the supplier of the safety data sheet Registered company name ALTEX COATINGS LTD Address 91-111 Oropi Road, Tauranga, New Zealand Other New Zealand Telephone +64 7 5411221 Fax +64 7 5411310 Website Not Available Email [email protected] Emergency telephone number Association / Organisation NZ POISONS CENTRE CHEMWATCH EMERGENCY RESPONSE Emergency telephone 0800 764 766 +64 800 700 112 numbers Other emergency telephone Not Available +61 2 9186 1132 numbers Once connected and if the message is not in your prefered language then please dial 01 SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. Classified as Dangerous Goods for transport purposes. Chronic Aquatic Hazard Category 2, Specific target organ toxicity - single exposure Category 2, Specific target organ toxicity - repeated exposure Classification [1] Category 2, Eye Irritation Category 2, Reproductive Toxicity Category 2, Skin Sensitizer Category 1, Skin Corrosion/Irritation Category 3, Acute Aquatic Hazard Category 2 Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI Determined by Chemwatch 6.3B, 6.4A, 6.5B (contact), 6.8B, 6.9B, 9.1B, 9.1D using GHS/HSNO criteria Label elements Hazard pictogram(s) SIGNAL WORD WARNING Hazard statement(s) H411 Toxic to aquatic life with long lasting effects. H371 May cause damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H317 May cause an allergic skin reaction. H316 Causes mild skin irritation. Page 1 continued... Version No: 1.2 Page 2 of 14 Issue Date: 12/04/2020 Carboline Pyroclad X1 Part A Print Date: 12/04/2020 Precautionary statement(s) Prevention P201 Obtain special instructions before use. P260 Do not breathe mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P321 Specific treatment (see advice on this label). P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor/physician/first aider. P314 Get medical advice/attention if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. Precautionary statement(s) Storage P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 25068-38-6 25-55 bisphenol A/ diglycidyl ether resin, liquid 10043-35-3 25-50 boric acid 13463-67-7 2.5-10 titanium dioxide (rutile) Not Available 2.5-10 blended carbon SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper Eye Contact and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. For thermal burns: Decontaminate area around burn. Consider the use of cold packs and topical antibiotics. For first-degree burns (affecting top layer of skin) Hold burned skin under cool (not cold) running water or immerse in cool water until pain subsides. Use compresses if running water is not available. Cover with sterile non-adhesive bandage or clean cloth. Skin Contact Do NOT apply butter or ointments; this may cause infection. Give over-the counter pain relievers if pain increases or swelling, redness, fever occur. For second-degree burns (affecting top two layers of skin) Cool the burn by immerse in cold running water for 10-15 minutes. Use compresses if running water is not available. Do NOT apply ice as this may lower body temperature and cause further damage. Do NOT break blisters or apply butter or ointments; this may cause infection. Protect burn by cover loosely with sterile, nonstick bandage and secure in place with gauze or tape. To prevent shock: (unless the person has a head, neck, or leg injury, or it would cause discomfort): Lay the person flat. Elevate feet about 12 inches. Elevate burn area above heart level, if possible. Continued... Version No: 1.2 Page 3 of 14 Issue Date: 12/04/2020 Carboline Pyroclad X1 Part A Print Date: 12/04/2020 Cover the person with coat or blanket. Seek medical assistance. For third-degree burns Seek immediate medical or emergency assistance. In the mean time: Protect burn area cover loosely with sterile, nonstick bandage or, for large areas, a sheet or other material that will not leave lint in wound. Separate burned toes and fingers with dry, sterile dressings. Do not soak burn in water or apply ointments or butter; this may cause infection. To prevent shock see above. For an airway burn, do not place pillow under the person's head when the person is lying down. This can close the airway. Have a person with a facial burn sit up. Check pulse and breathing to monitor for shock until emergency help arrives. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Indication of any immediate medical attention and special treatment needed Treat symptomatically. The material may induce methaemoglobinaemia following exposure. Initial attention should be directed at oxygen delivery and assisted ventilation if necessary. Hyperbaric oxygen has not demonstrated substantial benefits. Hypotension should respond to Trendelenburg's position and intravenous fluids; otherwise dopamine may be needed. Symptomatic patients with methaemoglobin levels over 30% should receive methylene blue. (Cyanosis, alone, is not an indication for treatment). The usual dose is 1-2 mg/kg of a 1% solution (10 mg/ml) IV over 50 minutes; repeat, using the same dose, if symptoms of hypoxia fail to subside within 1 hour. Thorough cleansing of the entire contaminated area of the body, including the scalp and nails, is of utmost importance. BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV): Determinant Index Sampling Time Comment 1. Methaemoglobin in blood 1.5% of haemoglobin During or end of shift B, NS, SQ B: Background levels occur in specimens collected from subjects NOT exposed NS: Non-specific determinant; also observed after exposure to other materials SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a screening test or confirmatory test. For acute or repeated short term exposures to boron and its compounds: Nausea, vomiting, diarrhoea and epigastric pain, haematemesis and blue-green discolouration of both faeces and vomitus characterise adult boron intoxication. Access and correct any abnormalities found in airway and circulation. A tidal volume of 10-15 mg/kg should be maintained. Emesis should be induced unless the patient is in coma, is experiencing seizures or has lost the gag reflex. If any of these are present, gastric lavage should be performed with a large-bore tube after endotracheal intubation or in the presence of continuous respiratory action. Activated charcoal is probably not of value though its use might be indicated following gastric evacuation. Catharsis might be useful to eliminate any borates remaining in the gastro-intestinal tract (magnesium sulfate: adults, 30 gms: children 250 mg/kg). Peritoneal dialysis and haemodialysis remove some borates. [Ellenhorn and Barceloux: Medical Toxicology] SECTION 5 FIREFIGHTING MEASURES Extinguishing media Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course.
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