This Table Gives the Standard State Chemical Thermodynamic Properties of About 2500 Individual Substances in the Crystalline, Liquid, and Gaseous States

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STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES

This table gives the standard state chemical thermodynamic properties of about 2500 individual substances in the crystalline, liquid, and gaseous states. Substances are listed by molecular formula in a modiﬁed Hill order; all substances not containing carbon appear ﬁrst, followed by those that contain carbon. The properties tabulated are:

DfH° Standard molar enthalpy (heat) of formation at 298.15 K in kJ/mol DfG° Standard molar Gibbs energy of formation at 298.15 K in kJ/mol S° Standard molar entropy at 298.15 K in J/mol K

Cp Molar heat capacity at constant pressure at 298.15 K in J/mol K

The standard state pressure is 100 kPa (1 bar). The standard states are deﬁned for different phases by:

• The standard state of a pure gaseous substance is that of the substance as a (hypothetical) ideal gas at the standard state pressure. • The standard state of a pure liquid substance is that of the liquid under the standard state pressure. • The standard state of a pure crystalline substance is that of the crystalline substance under the standard state pressure.

An entry of 0.0 for DfH° for an element indicates the reference state of that element. See References 1 and 2 for further information on reference states. A blank means no value is available. The data are derived from the sources listed in the references, from other papers appearing in the Journal of Physical and Chemical Reference Data, and from the primary research literature. We are indebted to M. V. Korobov for providing data on fullerene compounds.

References

1. Cox, J. D., Wagman, D. D., and Medvedev, V. A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1989. 2. Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., Bailey, S. M., Churney, K. L., and Nuttall, R. L., The NBS Tables of Chemical Thermodynamic Properties, J. Phys. Chem. Ref. Data, Vol. 11, Suppl. 2, 1982. 3. Chase, M. W., Davies, C. A., Downey, J. R., Frurip, D. J., McDonald, R. A., and Syverud, A. N., JANAF Thermochemical Tables, Third Edi- tion, J. Phys. Chem. Ref. Data, Vol. 14, Suppl.1, 1985. 4. Chase, M. W., NIST-JANAF Thermochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998. 5. Daubert, T. E., Danner, R. P., Sibul, H. M., and Stebbins, C. C., Physical and Thermodynamic Properties of Pure Compounds: Data Compi- lation, extant 1994 (core with 4 supplements), Taylor & Francis, Bristol, PA. 6. Pedley, J. B., Naylor, R. D., and Kirby, S. P., Thermochemical Data of Organic Compounds, Second Edition, Chapman & Hall, London, 1986. 7. Pedley, J. B., Thermochemical Data and Structures of Organic Compounds, Thermodynamic Research Center, Texas A & M University, Col- lege Station, TX, 1994. 8. Domalski, E. S., and Hearing, E. D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase, Volume III, J. Phys. Chem. Ref. Data, 25, 1-525, 1996. 9. Zabransky, M., Ruzicka , V., Majer, V., and Domalski, E. S., Heat Capacity of Liquids, J. Phys. Chem. Ref. Data, Monograph No. 6, 1996. 10. Gurvich, L. V., Veyts, I.V., and Alcock, C. B., Thermodynamic Properties of Individual Substances, Fourth Edition, Vol. 1, Hemisphere Pub- lishing Corp., New York, 1989. 11. Gurvich, L. V., Veyts, I.V., and Alcock, C. B., Thermodynamic Properties of Individual Substances, Fourth Edition, Vol. 3, CRC Press, Boca Raton, FL, 1994. 12. NIST Chemistry Webbook, .

5-4

STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° -4.0 -42.0 239.5 35.6 65.5 36.0 91.2 65.3 218.4 30.9 -47.7 -74.1 228.1 35.0 410.0 358.8 257.1 37.0 259.2 231.2 187.9 29.4 H f -331.0 -258.2 -283.7 215.0 31.9 -1869.0 -1827.5 345.7 105.9 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -16.3 145.0 289.1 194.6 13.0 147.0 379.2 H f kJ/mol p C J/mol K ° S J/mol K Crystal ° ubstances not containing carbon: not containing ubstances G f S kJ/mol ° H f kJ/mol Potassium aluminum hydrideAluminum phosphate -183.7 -1733.8 -1617.9 90.8 93.2 Silver(I) bromateSilver(I) chlorateSilver(I) perchlorateSilver(II) fluorideSilver(I) iodateSilver(I) nitrateDisilver Silver(I) chromate -10.5Silver(II) oxide -30.3Silver(III) oxide -31.1 71.3 64.5 151.9 -360.0 Aluminum borohydride 142.0 -171.1Aluminum bromide -124.4 -93.7 -731.7Aluminum dichloride -33.4Aluminum chloride -641.8 149.4 140.9 -24.3Aluminum fluoride 217.6 33.9 102.9 93.1 27.6 142.3 121.4Aluminum hydride 117.0 100.0 -527.2 88.0 Aluminum iodide -704.2 -1510.4 -628.8 180.2 -1431.1 109.3 100.6 -46.0 66.5 91.1 75.1 -313.8 30.0 -300.8 40.2 159.0 98.7 -425.1 -583.2 -1204.6 -1188.2 277.1 62.6 -207.5 Silver(I) oxideSilver(I) sulfide (argentite) -31.1 -32.6 -11.2 -40.7 121.3 144.0 65.9 76.5 Silver(I) sulfate -715.9 -618.4 200.4 131.4 4 3 3 4 3 12 S 2 3 4 3 K LiNaP Lithium aluminum hydride Sodium aluminum hydride -116.3 -15.5 -44.7 78.7 83.2 3 2 3 H Na Sodium tetrafluoroaluminate 2 3 4 4 4 4 3 CrO O O O O S 3 4 2 2 2 2 2 2 2 3 Ag AlI AlH AlH AlIAlP Aluminum monoiodide Aluminum phosphide -166.5 AlH AlH Aluminum monohydride AcAgAgBrAgBrO Actinium Silver Silver(I) bromide -100.4 0.0 -96.9 0.0 107.1 52.4 56.5 42.6 27.2 25.4 406.0 284.9 366.0 246.0 188.1 173.0 20.8 20.8 AlBrAlCl AlCl AlF Aluminum monobromide AgClAgClO AgClO AgFAgF AgIAgIO Silver(I) chlorideAgNO Ag Silver(I) fluorideAg Silver(I) iodideAg Ag -127.0 -109.8AlCl -204.6 96.3AlF -61.8 50.8 AlF -66.2 Aluminum monochloride AlH 115.5 Aluminum monofluoride 56.8 AlNAlO Aluminum nitride Aluminum monoxide -318.0 -287.0 20.2 30.1 AlBr AlO Molecular Formula Name Ag AlAlB Aluminum 0.0 28.3 24.4 330.0 289.4 164.6 21.4 Ag

5-5

STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 388.3 80.6 S J/mol K Gas ° G f kJ/mol 0.0 154.8 20.8 ° 66.4 68.970.0 222.8 38.1 485.9 433.3 233.2 36.4 222.2 171.9 239.4 35.0 515.1 36.9 238.1 195.4 225.0 32.9 200.9 150.1 230.6 33.4 295.0 265.7 211.2149.5 29.2 120.9 213.2 31.7 H f -970.7 -516.7 -130.0 -159.0 363.9 79.2 -314.0 -122.2 -149.8 200.5 29.6 -130.0 -159.0 259.4 45.7 -1290.8-2628.0 -1220.4 490.0 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -305.0-821.3 -259.4 -774.2 216.3 181.2 126.6 -785.8 -261.5 -770.8 -248.9 289.1 327.2 65.6 75.7 -239.7 -238.5-427.2 229.7 -387.4 206.3 106.7 -205.6 -403.8 -232.5 -388.7 324.2 290.1 67.8 62.7 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol O) 2 -rhombohedral) 0.0 5.9 11.1 565.0 521.0 153.4 20.8 b Boron ( Dialuminum Aluminum hexabromide Aluminum hexachloride Aluminum hexafluoride Aluminum hexaiodide Aluminum oxide (corundum)Aluminum sulfideArsenic(III) bromideArsenic(III) chloride -1675.7Arsenic(III) fluoride -1582.3Arsine Arsenic acid 50.9 -724.0Arsenic(III) iodide 79.0 Diarsenic -197.5 Arsenic(V) oxideArsenic(III) sulfide 116.9 105.1 Gold(III) bromide -58.2 -906.3 Gold(III) chlorideGold(III) fluoride -59.4 -924.9 213.1Digold -169.0 -782.3 105.8 -168.6Boron tribromide 105.4 163.6 -53.3 116.5 Boron trichloride 116.3 -117.6 Cesium metaborate -363.6 -972.0 -915.0 104.4 80.6 Aluminum oxide (Al 4 2 6 6 3 3 O 5 3 3 3 3 3 3 3 6 3 3 3 3 6 O S 3 Br Cl F I O O S 2 2 2 2 2 2 2 2 2 2 2 2 Al As B BBr BBr Bromoborane(1) Al AlS Aluminum monosulfide Al Al Al Al AsAsAsBr AsCl Arsenic (gray) Arsenic (yellow)AsInAsO Indium arsenide Arsenic monoxide 0.0 14.6 35.1 -58.6 24.6 -53.6BCl 75.7 47.8 302.5 261.0 174.2 20.8 Al AmAr Americium Argon AsI As AtAuAuBrAuBr 0.0 AuClAuCl AuF AuH Astatine Gold Gold(I) bromide Gold(I) chloride Gold hydride BF -14.0 0.0 -34.7 0.0 Fluoroborane(1) 47.4 25.4 366.1 326.3 180.5 20.8 AsF AsGaAsH AsH As Gallium arsenideAuI -71.0Au -67.8 64.2BClBClO Gold(I) iodide 46.2 BCsO Chloroborane(1) Chloroxyborane 0.0 Molecular Formula Name Al

5-6

STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 89.2 93.3 188.271.1 36.0 20.7 349.225.0 70.8 -4.0 203.536.4 29.2 87.6 232.166.1 56.7 184.3 280.347.3 93.2 232.8 350.7 186.1 830.5 774.0 201.9 30.5 158.4 357.5 364.9 187.0 342.0 288.8 216.2 30.0 442.7 412.7 171.8 29.2 -854.0 -607.0 -300.4 -305.9 229.6 43.0 -454.8 -462.3 242.5 57.3 -1136.0 -1119.4 254.4 -1440.1 -1410.4 317.3 79.1 42.773.256.3 171.8 184.2 151.1 73.2 173.6 280.6 103.3 94.6 99.6 230.6 211.3 321.0 296.8 130.3 125.7 -523.0 -464.8 262.3 137.7 -490.4 -460.6 357.4 95.4 -541.0 -392.7 199.6 , monoclinic) -794.3 -723.4 38.0 -561.9 -551.0 240.1 42.2 b etrachlorodiborane etrafluorodiborane etraborane(10) rihydro(phosphorus trifluoride)boron Potassium borohydride -227.4 -160.3 106.3 96.1 Boron trifluoride Metaboric acid ( Borane(3) Boric acidBoron triiodide Potassium metaborateLithium metaborateSodium metaborateBoron dioxide -1094.3Diboron -968.9T -981.6T -1032.2Diborane -923.4 90.0Diboron dioxide -976.1 -977.0Boron oxide 80.0 86.1Boron sulfide -920.7Borazine 51.5T 66.7 Sodium tetraborate 73.5 59.8 Pentaborane(9) Pentaborane(11) 65.9 Hexaborane(10) Nonaborane(15) Decaborane(14) Barium bromide -1273.5Barium chloride -240.6Barium chloride dihydrate -1194.3 -3291.1Barium fluorideBarium hydride -3096.0 54.0Barium hydroxide -994.1 Barium iodide 189.5 62.8Barium nitrite 100.0Barium nitrate 186.8 111.7 -1456.9 -757.3 -1293.2 -855.0 -736.8 -1207.1 -806.7 203.0 146.0 -177.0 -1156.8 -944.7 123.7 -138.2 -602.1 96.4 75.1 -768.2 -988.0 63.0 71.2 -792.6 46.0 -843.8 214.0 -832.0 151.4 67.0 279.8 66.9 Aminetrifluoroboron -1353.9 2 O 7 4 2 4 6 3 N PT 2 O H 3 3 3 2 2 O O O 2 2 2 2 N 14 2 4 2 2 2 2 2 O K LiNa Lithium borohydride Sodium borohydrideRb6 Rubidium metaborate2 -190.83 -188.6 -125.06 -123.910 75.9 101.39 11 82.6 10 86.8 15 -971.0 -913.0 94.3 74.1 3 H H Na Sodium tetrafluoroborate -1844.7 -1750.1 145.34 120.3 2 3 3 4 4 4 2 2 H 3 3 3 4 Cl F H O O S H H Na H H H H 3 2 2 2 2 2 2 2 3 4 4 5 5 6 9 10 B B B B B B BF BH BFO Fluorooxyborane BF BH BH BI BS Boron monosulfide B BF BO B BH BLiO BNBNaO BO Boron nitride Boron monoxide B B B -254.4 -228.4 14.8BaCl BaCl BaF 19.7BaH BaH BaI BaN BaN 647.5 614.5 212.3 29.5 BH BKO BO B B B BaBaBr Barium 0.0 62.5 28.1 180.0 146.0 170.2 20.8 B BHO BH Borane(1) BF

5-7

STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 350.1 90.9 262.4 52.8 274.8 56.4 S J/mol K Gas ° G f kJ/mol ° 40.8 3.7 258.8 36.4 14.6 -1.0 240.1 35.0 82.2 82.4 273.7 45.5 -93.8 -109.2 229.0 33.0 -36.3 -53.4 198.7 29.1 219.7 36.9 111.9 82.4 175.0 20.8 235.6 37.1 H f -464.4 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -300.8-458.6 -240.5 -351.8 178.2 225.1 124.6 -255.6 -229.4 -428.9 292.5 -350.6 320.2 66.6 99.6 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol Ammonium bromide -270.8 -175.2 113.0 96.0 Beryllium bromideBeryllium chlorideBeryllium fluorideBeryllium hydroxideBeryllium iodideBismuth trichloride -353.5Bismuth hydroxide -490.4Bismuth triiodide -1026.8 -902.5Dibismuth -445.6 -979.4Bismuth oxide -192.5 -815.0Bismuth sulfate 75.8 108.0Bismuth sulfide 53.4 45.5 62.4 69.4 51.8 62.1 -379.1 121.0 -711.3 -315.0 71.1 Bromine trifluoride 177.0Bromine pentafluoride -573.9 -2544.3 -175.3 105.0 -143.1Bromogermane -493.7 -140.6 151.5 200.4 113.5 122.2 Potassium bromatePotassium perbromate -265.7 -256.0 -360.2 -287.9 358.9 -271.2 -174.4 79.7 149.2 170.1 105.2 120.2 Barium sulfateBeryllium sulfate -1473.2 -1362.2 132.2 101.8 -1205.2 -1093.8 77.9 85.7 3 3 2 3 S 3 4 Si Bromotrichlorosilane S O S 2 2 SiN Bromosilane 3 O 3 12 3 3 4 2 4 3 4 2 3 3 5 2 O O S 3 2 2 2 2 Bi BrCsBrCuBrFBrF Cesium bromide Copper(I) bromide Bromine fluoride -405.8 -104.6 -391.4 -100.8 113.1 96.1 52.9 54.7 BaOBaO Barium oxide -548.0 -520.3 72.1 47.3 -112.0 BrInBrKBrKO Indium(I) bromide Potassium bromide -175.3 -393.8 -169.0 -380.7 113.0 95.9 52.3 -56.9 -94.3 259.5 36.7 BrI Iodine bromide BrH BrHBrHSiBrH Hydrogen bromide Bromosilylene BeCl BeF BeH BeI BeOBeO BiH Beryllium oxideBiI Bi Bi Bi BkBr -609.4 Berkelium -580.1 Bromine (atomic) 13.8 25.6 BrKO BrLi 0.0 BrNO Lithium bromide Nitrosyl bromide -351.2 -342.0 74.3 BrClBrCl BrF Bromine chloride BrGeBrGeH Germanium monobromide Molecular Formula Name BaSBeBeBr Barium sulfide BerylliumBeSBiBiClOBiCl Beryllium sulfide Bismuth Bismuth oxychloride -460.0 -456.0 0.0 78.2 49.4 -234.3 -366.9 9.5 -322.1 16.4 0.0 120.5 34.0 34.0 56.7 25.5 324.0 286.6 136.3 20.8 207.1 168.2 187.0 20.8

5-8 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 377.1 95.3 359.8 89.9 309.7 65.5 -21.0 152.0209.0 155.0 271.1 45.4 38.6 125.8 109.6 233.0 34.2 -282.0 0.0 152.2 75.7 30.9 3.1 245.5 36.0 -13.0 -355.6 -336.4 248.1 -317.6-347.7 -328.5 -331.4 348.6 280.7 80.8 -300.0 -318.0 396.2 101.8 -184.5 -175.7 240.2 -139.3 -162.8 348.1 76.0 itanium(II) bromide -402.0 itanium(III) bromide -548.5 -523.8 176.6 101.7 T Phosphorus(III) bromide T Sodium bromateBromine dioxide Bromine -334.1 -242.6 128.9 Mercury(I) bromideSulfur bromide -206.9 -181.1 218.0 3 2 Si Dibromosilane 2 2 2 CaCdCoCrCuFeH Calcium bromideHg Cadmium bromideHg Cobalt(II) bromideMg Chromium(II) bromideMn Copper(II) bromideNi Iron(II) bromidePbPt Mercury(II) bromideS Se Magnesium bromideSn Manganese(II) bromide -682.8Sr Nickel(II) bromide -316.2Ti Lead(II) bromide -220.9 -302.1 -663.6Zn -296.3 Platinum(II) bromideCe -141.8 130.0 ClSi Selenium dibromide 137.2Dy -249.8 bromide Tin(II) Fe -170.7 Strontium bromide 76.7 Ga -238.1 -524.3 -153.1HSi -384.9 Zinc bromideIn 140.6 Cerium(III) bromide -503.8 Tribromochlorosilane OP 172.0 -212.1 79.5 P Dysprosium(III) bromide 117.2 -278.7Pt Iron(III) bromide -82.0 Re Gallium(III) bromide -261.9Ru Tribromosilane Sb Indium(III) bromide 161.5Sc Phosphoric tribromide -243.5 -717.6Ti Ge 80.1 -697.1 Platinum(III) bromidePa -891.4 Rhenium(III) bromide -328.7Pt -836.2 Ruthenium(III) bromide 135.1 Antimony(III) bromide -312.1 Scandium bromide 75.3 -386.6 -268.2 138.5 Germanium(IV) bromide -359.8 Protactinium(IV) bromide -458.6 -428.9 Platinum(IV) bromide 180.0 -120.9 -167.0 -138.0 -259.4 -743.1 -239.3 -824.0 207.1 -787.8 -156.5 234.0 -194.6 -223.9 372.9 80.2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 BrRbBrSiBrTlBr Rubidium bromide Bromosilyldyne Thallium(I) bromide -394.6 -173.2 -381.8 -167.4 110.0 120.5 52.8 -37.7 Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br Br BrNaBrNaO Sodium bromide -361.1 -349.0 86.8 51.4 -143.1 -177.1 241.2 36.3 Br Br BrO Bromine monoxide Br BrO Br

5-9 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° -50.3-23.8 -51.8 48.2 217.9 279.0 32.1 64.9 121.3 105.3 165.2 21.8 H f -336.8 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -457.3 -443.9 277.8 -415.5 -431.8 377.9 97.1 -189.5 -163.2 -123.0 281.6 63.9 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol , fcc) 0.0 72.0 26.9 423.0 385.0 191.8 23.1 g anadium(IV) bromide itanium(IV) bromide -616.7 -589.5 243.5 131.5 -549.4 -568.2 398.4 100.8 ellurium tetrabromideantalum(V) bromide -190.4 -598.3 ungsten(VI) bromide -348.5 Cadmium sulfate -933.3 -822.7 123.0 99.6 T T Phosphorus(V) bromideT -269.9 Calcium chlorideCalcium fluorideCalcium hydrideCalcium hydroxideCalcium iodideCalcium nitrateCalcium phosphate -795.4Cadmium chloride -1228.0Cadmium fluoride -748.8 -181.5 -1175.6Cadmium hydroxide -985.2Cadmium iodide 108.4 -142.5 -533.5 -897.5 68.5 -938.2 -528.9 72.9 41.4 83.4 67.0 -742.8 -4120.8 142.0 41.0 87.5 Cerium(III) chloride 193.2 -3884.7Cerium(III) iodide -391.5Cerium(IV) oxide 149.4 -700.4 236.0 -560.7 -343.9Cerium(III) oxide -647.7 227.8 -203.3 -473.6 115.3 -201.4 77.4 96.0 74.7 Cesium perchlorate 161.1 -1060.5Perchloryl fluoride 80.0 -669.3 -984.8Chlorine trifluoride -1088.7 151.0 -1024.6 -1796.2 -1706.2 87.4 62.3 -443.1 150.6 61.6 -314.3 114.6 175.1 108.3 Calcium sulfate -1434.5 -1322.0 106.5 99.7 2 2 2 6 4 P O S 2 3 O O S 8 3 2 3 2 4 2 2 2 4 2 2 2 2 3 O O 2 3 SiSnTe Ti VV ZrP Tetrabromosilane Ta bromide Tin(IV) WT Zirconium(IV) bromide -377.4 -350.2 -760.7 264.4 -314.6 -331.4 411.9 103.4 3 2 4 4 4 4 4 4 5 5 6 Br Br CdSCdTeCeCeCl Cadmium sulfide Cadmium telluride Cerium ( -161.9 -92.5 -156.5 -92.0 64.9 100.0 Br Br CaCaCl Calcium 0.0 41.6 25.9 177.8 144.0 154.9 20.8 Br Br Br Br Br ClFO ClF CaF CaH CaH CaI CaN CaOCaO CdCdCl CdF Calcium oxideCdH CdI CdOCdO CadmiumCeI Cadmium oxideCeO CeS -634.9Ce Cf -603.3Cl 38.1ClCu Cerium(II) sulfideClF 0.0 42.0 Californium -258.4 Chlorine (atomic) -228.7 Copper(I) chloride 51.8 54.8 Chlorine fluoride 26.0 43.4 -459.4 -451.5 78.2 0.0 -137.2 50.0 -119.9 86.2 48.5 111.8 167.7 20.8 ClCsClCsO Cesium chloride -443.0 -414.5 101.2 52.5 Molecular Formula Name CaSCa Calcium sulfide -482.4 -477.4 56.5 47.4

5-10 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 250.7 51.0 285.7 60.5 263.7 54.7 0.0 223.1 33.9 80.3 97.9 266.2 45.4 51.712.6 66.1 54.4 261.7 272.2 44.7 53.2 89.1 105.0 263.7 46.0 -75.0 -92.3-78.7 -95.3 -66.1 186.9 236.7 29.1 37.2 102.5 120.5 256.8 42.0 189.9 36.9 101.8 98.1 226.6 31.5 155.2 124.2 247.0 36.9 -23.9 -13.6 135.1 17.8 -5.5 247.6 35.6 -40.6 -245.6 121.0 -212.5 -198.3 309.8 66.5 -394.1 134.0 -364.0 -320.0 311.9 77.0 -579.5 -510.8 221.8 -538.1 -501.6 329.8 84.5 Chlorine monoxide Ammonium chloridePhosphonium chloride -314.4 -145.2 -202.9 94.6 84.1 Sulfuryl chloride Chlorogermane Perchloric acid Ammonium perchloratePotassium chloratePotassium perchlorateLithium perchlorate -295.3Nitryl chloride -88.8Sodium chloriteSodium chlorate 186.2 Sodium perchlorate -397.7 -432.8 -296.3Chlorine dioxide -303.1 -381.0 Chlorine superoxide (ClOO) 143.1 151.0 100.3 112.4 -307.0 Chlorine -365.8 -383.3 -262.3 -254.9Chromyl chloride 123.4 142.3 Mercury(I) chloride -265.4 -210.7 191.6 Sulfur chloride pentaﬂuoride -1065.7 4 2 3 2 3 4 2 4 4 2 Si Dichlorosilane S 3 4 SiN NO P Chlorosilane Rb Rubidium perchlorate2 -437.2 -306.92 161.1 S 3 4 4 4 2 2 4 5 CoCrCrO CuFeH Hg Cobalt(II) chlorideHg Chromium(II) chlorideMgMn Copper(II) chlorideNi Iron(II) chlorideO OS Mercury(II) chlorideO Magnesium chloride Manganese(II) chloride Nickel(II) chloride -312.5 -395.4 Thionyl chloride -269.8 -356.0 -220.1 109.2 115.3 -175.7 -341.8 -224.3 78.5 71.2 -302.3 108.1 -641.3 -178.6 -481.3 118.0 -591.8 71.9 -440.5 146.0 -305.3 76.7 89.6 118.2 -259.0 71.4 72.9 97.7 71.7 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 ClO Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl ClF ClTlCl Thallium(I) chloride -204.1 -184.9 111.3 50.9 -67.8 ClH ClI Iodine chloride ClRbClSi Rubidium chloride Chlorosilylidyne -435.4 -407.8 95.9 52.4 ClH ClInClKClKO Indium(I) chloride Potassium chloride -186.2 -436.5 -408.5 82.6 51.3 -214.6 -233.3 239.1 36.5 Cl ClHClHOClHO ClH Hydrogen chloride Hypochlorous acid Cl ClH ClKO ClLiClLiO ClNOClNaO Lithium chlorideClNaO ClO Nitrosyl chloride Chlorine oxide -408.6 -384.4 59.3 48.0 Cl ClNO ClNaClNaO ClOVClO Sodium chlorideClO chloride Vanadyl Cl -411.2 -384.1 72.1 -607.0 50.5 -556.0 75.0 ClGe Germanium monochloride ClGeH

5-11 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° H f -374.0 -649.0 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -50.0 -59.4 230.0 H f -539.3 -482.5 227.6-597.1-734.7 -513.0 -520.8 -668.5 -482.0 222.5 244.3 313.9 138.8 75.8 -558.5 -512.9 -695.6 325.5 -659.3 344.3 84.9 89.9 -319.7 -272.3 217.1 -287.0 -267.8 311.8 71.8 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol anadium(III) chloride -580.7 -511.2 131.0 93.2 itanium(II) chloride -513.8 -464.4 87.4 69.8 itanium(III) chloride -720.9 -653.5 139.7 97.2 Sulfur dichloride T Nitrogen trichloride Phosphorus(III) chloride T Uranium(III) chloride -866.5 -799.1 159.0 102.5 Uranyl chloride -1243.9 -1146.4 150.5 107.9 Sulfur chloride U 2 2 O PbPtS S SnSrTi Lead(II) chlorideZn Platinum(II) chlorideZrCrDy chloride Tin(II) Er Strontium chlorideEuFe Zinc chlorideGa Zirconium(II) chlorideGd Chromium(III) chlorideHSi Dysprosium(III) chloride -359.4Ho -123.4 Erbium chlorideIn Europium(III) chloride -314.1Ir Iron(III) chlorideLa Gallium(III) chloride 136.0 Lu Gadolinium(III) chloride -325.1 -828.9N Trichlorosilane Nd Holmium chloride -781.1 -502.0 OP Indium(III) chloride -556.5 -1000.0 -415.1OV 114.9 Iridium(III) chlorideOs Lanthanum chloride -486.1 -369.4P Lutetium chloride -936.0 75.6 Pr -998.7 123.0 111.5Pt Neodymium chloride -1008.0Re -524.7 -399.5 Phosphoric trichloride 91.8 Rh trichloride Vanadyl 71.3 -454.8 -334.0Ru Osmium(III) chlorideSb -1005.4Sc 142.0 142.3 Praseodymium chloride -537.2 Sm Platinum(III) chloride -245.6 -1072.2Tb Rhenium(III) chloride 96.7 Ti Rhodium(III) chloride 100.0 -945.6 Tl Ruthenium(III) chloride -1041.0Tm 88.0 Antimony(III) chlorideU Scandium chlorideVV Samarium(III) chloride -190.4 chloride Terbium 88.0 -1056.9 Thallium(III) chloride -182.0 108.8 Thulium chloride -264.0 -299.2 -266.1 -205.0 113.0 -188.0 -382.2 123.8 -1025.9 -925.1 -323.7 100.0 92.4 184.1 -997.0 -315.1 107.9 -986.6 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Molecular Formula Name

5-12 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -750.2 75.0 -374.9 -305.0-513.8 364.6 112.8 -292.9 266.2 56.0 -531.8 -462.7-329.3 245.6-687.0-511.3 -619.8 -440.1 239.7 -495.8 258.6-569.4 145.3 -457.3 165.3 -503.7 -657.0 347.7 -471.5 -617.0 255.0 96.1 -432.2 330.7 365.8 90.3 -525.5 98.3 -492.0 362.4 96.2 -804.2 -737.2 252.3 145.2 -763.2 -726.3 353.2 95.4 anadium(IV) chloride itanium(IV) chloride ellurium tetrachlorideantalum(V) chloride -326.4 138.5 -859.0 ungsten(VI) chloride -602.5 Cobalt(II) sulfate -888.3 -782.3 118.0 Cesium hydrogen fluoride -923.8 -858.9 135.2 87.3 Yttrium chlorideT -1000.0 T Uranium(IV) chloridePhosphorus(V) chlorideT Uranium(VI) chloride -1019.2 -930.0 -443.5 197.1 122.0 -1092.0 -962.0 285.8 175.7 -809.6 -786.6 419.0 -1013.0 -928.0 431.0 Cobalt(II) fluorideCobalt(II) hydroxideCobalt(II) iodideCobalt(II) nitrateCobalt(III) sulfideCobalt(II,III) oxideChromium(II) fluoride -692.0 -539.7Chromium(III) fluorideChromium(II) iodide -647.2 -454.3Chromium(III) iodide -88.7 -420.5 Chromium(IV) oxide 82.0Chromium(VI) oxide 79.0 Chromium iron oxide 68.8 -147.3 Chromium(III) oxide -891.0Chromium(II,III) oxide -778.0 -1159.0 -774.0 -1088.0 -156.9 102.5 -205.0 -598.0 93.9 123.4 -1444.7 78.7 -1139.7 -1343.8 -1531.0 -1058.1 146.0 81.2 133.6 118.7 4 2 6 O O S 4 3 Pb3 4 Lead(II) chromate -930.9 H 2 2 4 2 2 3 4 2 2 3 S O 2 FeO O O 2 3 Y YbGeHfPaPbPtSi Ytterbium(III) chlorideSn Germanium(IV) chloride Te Hafnium(IV) chlorideTh Protactinium(IV) chlorideTi Lead(IV) chloride U Platinum(IV) chlorideVV Tetrachlorosilane Zr chloride Tin(IV) NbP Thorium(IV) chloride -959.8 PaTa -1043.0U -990.4WT Zirconium(IV) chloride -953.0 -901.3 Niobium(V) chloride -231.8 192.0 190.8 Protactinium(V) chloride 120.5 -1186.2 -1094.1 190.4 -980.5 -797.5 120.3 -889.9 -1145.0 -683.2 -1034.0 181.6 210.5 238.0 119.8 148.1 -884.5 -964.4 -932.0 390.7 -703.7 107.5 -646.0 400.6 120.8 2 3 2 2 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 6 6 Cl Cl CoSCo Cobalt(II) sulfide -82.8 Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl Cl CmCoCoF Curium Cobalt 0.0 0.0 30.0 24.8 424.7 380.3 179.5 23.0 Cl Cl CrO CoH CoI CoN CoOCoO Co CrCrF Cobalt(II) oxideCrF CrI CrI CrO CrO ChromiumCr Cr CsCsF -237.9CsF -214.2 53.0 Cesium Cesium fluoride 55.2 0.0 23.8 23.4 -553.5 -525.5 0.0 92.8 51.1 85.2 32.2 396.6 351.8 174.5 20.8 76.5 49.6 175.6 20.8 Cr

5-13 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 238.4 47.4 252.8 51.6 S J/mol K Gas ° G f kJ/mol ° 79.4 62.3 158.8 22.7 -33.4 34.7 -95.7 -118.5 236.2 33.4 484.2 431.9 241.6 36.6 H f -251.9 33.3 -203.4 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -299.8 -273.3 -275.4 173.8 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol Cesium hydrogen sulfate -1158.1 Copper(II) sulfateCopper(II) tungstate -771.4 -1105.0 -662.2 109.2 Cesium oxideCesium sulfide -345.8 -308.1 -359.8 146.9 76.0 Cesium nitrateCesium superoxideCopper(II) fluorideCopper(II) hydroxideCopper(II) nitrate -286.2 -506.0 -406.5 155.2 Dicopper -542.7 -449.8 Dysprosium(III) iodide -302.9 Dysprosium(III) oxideErbium fluorideErbium oxideEuropium(III) oxideEuropium(II,III) oxideFluorine (atomic) -620.5 -1863.1 -1771.5Fluorogermane -1711.0 149.8 -1897.9 116.3 -1651.4 -1808.7 -2272.0 -1556.8 -2142.0 155.6 146.0 205.0 108.5 122.2 Cesium amide -118.4 Cesium sulfiteCesium sulfate -1134.7 -1443.0 -1323.6 211.9 134.9 Copper(I) oxideCopper(I) sulfide -168.6 -79.5 -146.0 -86.2 93.1 120.9 63.6 Ammonium fluoride 76.3 -464.0 -348.7 72.0 65.3 2 6 S 4 3 S S 3 O O S W N 3 4 3 3 4 2 2 4 4 3 2 2 2 O S SiN Fluorosilane O O O S O 3 3 O O 2 2 2 3 4 O 2 2 2 2 2 2 3 2 Cu FH CsH CuO CuSCuSeCu Copper(II) sulfide Copper(II) selenide -53.1 -39.5 -53.6 66.5 47.8 Cs CuCuF Copper 0.0 33.2 24.4 337.4 297.7 166.4 20.8 CsHCsHOCsHO Cesium hydride Cesium hydroxide -416.2 -54.2 -371.8 104.2 69.9 -256.0 -256.5 254.8 49.7 FGeFGeH FHFH Germanium monofluoride Hydrogen fluoride CsO Cs CuH CuICuN CuOCuO Copper(I) iodide Copper(II) oxideDy ErErF Er EsEu -67.8Eu Eu -157.3F -69.5 Erbium -129.7 96.7 Einsteinium 42.6 Europium 54.1 42.3 0.0 0.0 0.0 73.2 28.1 77.8 27.7 317.1 280.7 175.3 195.6 142.2 20.8 188.8 20.8 FGa Gallium monofluoride Molecular Formula Name CsICsNO Cesium iodide -346.6 -340.6 123.1 52.8 Cs Cs Cu DyDyI DysprosiumFI 0.0 Iodine fluoride 75.6 27.7 290.4 254.4 196.6 20.8 FIn Indium(I) fluoride

5-14 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 252.8 43.4 278.7 56.8 271.9 60.5 284.0 66.0 260.4259.8 49.8 44.1 0.0 202.8 31.3 7.1 -24.3 225.8 32.6 25.4 39.4 259.5 44.5 69.5 82.0 19.2 58.2 277.2 62.1 43.1 57.824.5 249.9 41.8 41.0 247.5 43.3 -66.5 -51.0 248.1 41.3 109.0 105.3 216.4 32.0 -619.0 -628.0 252.7 43.9 -182.4 -132.1 -90.6-958.4 260.8 -936.9 53.4 273.1 58.7 -1297.0 -1254.3 -1205.8 285.4-1166.1 68.8 -1160.6-1190.2 339.2 -1150.0 73.3 301.9 -Difluorodiazine -Difluorodiazine Sulfuryl fluoride Uranyl fluoride -1653.5 -1557.4 135.6 103.2 Nitryl fluoride Fluorine superoxide (FOO) Fluorine cis trans Fluorine dioxide Difluoroamidogen Fluorine monoxide Nitrogen trifluoride Phosphorus(III) fluoride Uranium(III) fluorideYttrium fluoride -1502.1 -1433.4 -1718.8 123.4 -1644.7 100.0 95.1 -1058.5 -1051.9 -1288.7 331.9 -1277.8 74.3 311.8 70.3 2 S U 2 2 2 2 2 2 FeHKHNHNaHRbMgN Iron(II) fluorideN Potassium hydrogen fluorideN Difluoramine Ni Sodium hydrogen fluorideO Rubidium hydrogen fluorideOS Magnesium fluorideO O O Pb -927.7 Nickel(II) fluorideSi -859.7Sr Thionyl fluoride -920.3 -711.3 -922.6ZnGa 104.3 -852.2 -668.6 -855.6Gd -1124.2HSi Lead(II) fluoride 76.9 90.9 87.0 120.1Ho -1071.1 Difluorosilylene N Strontium fluorideNd 75.0 68.1 79.4 Zinc fluoride 57.2OP Gallium(III) fluorideP -651.4 Gadolinium(III) fluoride Sb Trifluorosilane 61.6 -604.1Sc Holmium fluorideSmTh 73.6 Neodymium fluorideU Phosphoric trifluoride Y -664.0 64.1 Ge Antimony(III) fluoride -1216.3 -617.1 Scandium fluoride -1163.0 -1164.8 Samarium(III) fluoride -764.4 110.5 Thorium(III) fluoride -1085.3 82.1 -713.3 -1707.0 84.0 Germanium(IV) fluoride -1657.0 70.0 73.7 65.7 -915.5 -1778.0 -1629.2 -1555.6 92.0 -1247.0 -1234.0 300.5 67.8 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 F F F F F F F F F F F F F F F F F F F F F FKFLiFNO Potassium fluoride Lithium fluoride Nitrosyl fluoride -567.3 -616.0 -537.8 -587.7 66.6 35.7 49.0 41.6 FNO FO FNSFNaFO Thionitrosyl fluoride (NSF) Sodium fluorideF Fluorine oxide -576.6 -546.3 51.1 46.9 FRbFSi Rubidium fluoride Fluorosilylidyne F F F -557.7 FTlF Thallium(I) fluoride -324.7 F F F F F F F F F

5-15 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 358.1348.3 120.8 122.8 S J/mol K Gas ° G f kJ/mol ° -8.4 79.9 301.2 79.2 71.0 H f -763.2 -722.0 299.6 77.6 -1594.4 -1520.7 300.8 84.8 -1220.5 -1116.5 291.5 97.0 -1615.0 -1572.8 282.8 73.6 -1117.0 -1017.0-1318.0 313.9 110.5 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -864.8 -822.5 -751.7 327.7 99.2 -1585.5 -1473.0 259.7 169.8 -1557.7 -1472.2-1747.7 -1631.4 350.5 251.5 120.6 -1721.7 -1632.1 341.1 119.0 -1480.3 -1373.1 175.7 -1433.9 -1369.8 320.9 98.6 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol anadium(IV) fluorideanadium(V) fluoride -1403.3 etrafluorohydrazine antalum(V) fluoride -1903.6 ellurium hexafluoride ungsten(VI) fluoride Iron(II) sulfateIron(II) tungstate -928.4 -1155.0 -1054.0 -820.8 131.8 107.5 114.6 100.6 T HexafluorodisilaneIron(II) iodideIron(III) iodide Iron(II) molybdate -2427.0 -2299.7Iron disulfideIron(III) oxide 219.1Iron(II,III) oxide 129.5 -113.0 -1075.0 -975.0 129.3 118.5 -178.2 -824.2 -166.9 -1118.4 -742.2 -1015.4 52.9 87.4 146.4 62.2 103.9 -2383.3 143.4 -2307.3 391.0 129.9 Sulfur tetrafluoride Uranium(IV) fluorideIodine pentafluoride Phosphorus(V) fluoride T -1914.2 -1823.3 151.7 116.0Sulfur hexafluoride T Uranium(VI) fluoride -2197.0 -1598.7 -2068.5 -1572.7 227.6 368.0 166.8 91.2 -2147.4 -2063.7 377.9 129.6 4 Si Ammonium hexafluorosilicate -2681.7 -2365.3 280.2 228.1 2 Si Sodium hexafluorosilicate -2909.6 -2754.2 207.1Si 187.1 Iron(II) orthosilicate -1479.9 -1379.0 145.2 132.9 2 S W 3 4 4 N Si Potassium hexafluorosilicate -2956.0 -2798.6 226.0 2 4 4 2 2 8 2 O O O 2 3 2 2 3 HfN PbS SiThU Hafnium fluorideVV Xe Lead(IV) fluorideZrI Tetrafluorosilane Nb Thorium(IV) fluorideP Ta VV Xenon tetrafluorideH Zirconium(IV) fluorideIr -1930.5K Niobium(V) fluorideMo -1830.4Na -941.8 Os 113.0 -2097.8PtS -2003.4 Iridium(VI) fluorideSeSi Molybdenum(VI) fluoride -261.5 -1911.3 142.0Te U -1809.9 Osmium(VI) fluoride 110.7WT -1813.8 Platinum(VI) fluoride 104.6 -1699.0 Selenium hexafluoride 103.7 160.2 134.7 -579.7 -461.6 247.7 -1669.8 -1759.0 246.0 -1724.0 235.6 341.7 -1739.7 93.0 -1673.6 321.9 97.1 -544.0 -460.0 357.8 121.1 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 F F F F F F F F F F F F FeFeI Iron 0.0 27.3 25.1 416.3 370.7 180.5 25.7 FeO FeSFeS Iron(II) sulfide -100.0 -100.4 60.3 50.5 F F F FeI FeOFeO Fe Fe Iron(II) oxideFmFrGa Fermium Francium Gallium -272.0 0.0 0.0 0.0 0.0 95.4 40.8 26.1 5.6 272.0 233.7 169.0 25.3 FeMoO Molecular Formula Name F F Fe F F F F F F F F F F F

5-16 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 283.2 57.5 26.5 1.7 206.6 29.2 39.0 34.2 183.7 29.9 90.8 113.4 217.1 45.0 10.5 22.6 229.0 34.9 -79.5 -46.0 254.1 45.6 438.5 473.1 416.3218.0 252.8 203.3 35.6 114.7 20.8 279.5 253.5 231.1 32.1 351.5 345.6 181.2 29.2 193.7 226.8 137.3 162.3 264.0 327.3 140.6 294.1 328.1 239.0 43.7 -174.1 -80.7 155.6 109.9 -133.9 -73.5 266.9 54.1 rigermane Sodium hydrogen sulfate -1125.5 -992.8 113.0 Sodium hydrogen phosphate -1748.1 -1608.2 150.5 135.3 Gallium suboxide -356.0 Hydrogen (atomic) Gallium(III) hydroxideGallium(III) iodideDigallium Gallium(III) oxide -964.4Gadolinium(III) oxide -238.9 -831.3Germane 100.0 Germanium(IV) iodideGermanium(IV) oxide 205.0 -1089.1 100.0 -1819.6Digermanium -998.3Digermane T 85.0 -141.8 92.1 Iodic acid -144.3 -580.0 271.1 -521.4 106.7 39.7Nitrous acid 52.1 Nitric acid Hydrazoic acid -230.1 Hydroperoxy -56.9 -106.3 428.9 104.1 Potassium hydrogen sulfate -1160.6 -1031.3 138.1 Metaphosphoric acid -948.5 Iodogermane P 3 S 4 4 S 3 O 3 I 6 8 O 2 3 4 3 3 4 2 2 P RbSRe Rubidium hydrogen sulfate Perrhenic acid -1159.0 -762.3 -656.4 158.2 3 O O O H H 3 4 3 2 3 4 4 2 2 2 2 2 2 3 Ga Ge HIHIO Hydrogen iodide HNa HORbHOTlHO Rubidium hydroxide Thallium(I) hydroxide -418.8 -238.9 -373.9 -195.8 94.0 88.0 69.0 -238.0 -239.1 248.5 49.5 HO Hydroxyl Ga GaH H HNO GaI GaNGaO Gallium nitrideGd Gallium monoxide Gd GeGeH GeO GadoliniumGeO GeP GermaniumGeSGeTe -110.5 Ge Germanium(II) oxide Germanium phosphide Germanium(II) sulﬁde Germanium(II) tellurideHKHKOHKO 0.0 0.0 -261.9 Potassium hydride -21.0 -237.2 Potassium hydroxide -69.0 68.1 20.0 -17.0 50.0 -71.5 31.1 37.0 63.0 71.0 23.3 -424.6 -57.7 -379.4 81.2 68.9 397.5 372.0 359.8 -46.2 331.2 194.3 -73.2 92.0 167.9 224.3 27.5 42.0 30.7 30.9 234.0 -232.0 33.7 -229.7 238.3 49.2 GaPGaSbGa Gallium phosphide Gallium antimonideGeI -88.0 -41.8Ge -38.9 76.1 48.5 HN HNaHNaOHNaO Sodium hydride Sodium hydroxideHO -425.8 -56.3 -379.7 -33.5 64.4 40.0 59.5 36.4 -191.0 -193.9 229.0 48.0 HLiHLiOHN Lithium hydride Lithium hydroxide Imidogen -487.5 -90.5 -441.5 -68.3 42.8 20.0 49.6 27.9 -229.0 -234.2 214.4 46.0 HNO HO HO GeH

5-17 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 270.9 54.4 S J/mol K Gas ° G f kJ/mol 0.0 130.7 28.8 5.4 13.5 210.2 37.1 ° 29.799.6 15.9 219.0 34.7 -20.6 -33.4 205.8 34.2 -45.9 -16.4 192.8 35.1 184.9 194.6 195.0 33.9 145.1 147.8 232.8 41.1 142.7361.0 113.3 195.7 32.3 H f kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 50.6 149.3 121.2 98.9 95.4 159.4 238.5 48.4 -18.1 84.1 15.5 51.5 H f -187.8 -120.4 109.6 89.1 -136.3 -105.6 232.7 43.1 -285.8 -237.1 70.0 75.3 -241.8 -228.6 188.8 33.6 -814.0 -690.0 156.9 138.9 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol ater antalum hydride -32.6 -69.0 79.1 90.8 T Hydrogen Magnesium hydroxideNitramideNickel(II) hydroxideHydrogen peroxide -924.5 -833.5 63.2 -529.7Hydrogen disulﬁde 77.0 -89.5 -447.2 88.0 Hydrazine Ammonium nitriteAmmonium nitrate -256.5 -365.6 -183.9 151.1 139.3 Amidogen Hydrogen sulﬁde Hydrogen telluride Ammonia Phosphine Uranium(III) hydride -127.2 -72.8 63.7 49.3 Potassium dihydrogen phosphate -1568.3 -1415.9 134.9 116.6 Sulfuric acid Phosphinic acidPhosphonic acidPhosphoric acid -604.6 -964.4 -1284.4 -1124.3 110.5 106.1 -1271.7 -1123.6 -595.4 150.8 145.0 2 2 2 3 2 P 4 O SnSrZnSiS Se hydroxide Tin(II) Strontium hydroxide Zinc hydroxide Metasilicic acid Selenic acidP -561.1 -959.0 P P -491.6 -641.9 -1188.7 155.0 -553.5 -1092.4 -530.1 134.0 81.2 O O 2 2 2 2 2 3 4 4 2 3 4 2 2 2 2 2 KNKO LiNMgMgO N NNa Potassium amideNRbN Lithium amideNiO Magnesium hydrideOW O O Sodium amideO Rubidium amideO O O -128.9 O S S -179.5 -75.3SeSr -35.9Te Th -123.8 -113.0 Zr 31.1ISi -64.0N Hydrogen selenide 35.4 NO Strontium hydride 76.9O O Thorium hydrideO 66.2 Zirconium(II) hydrideP Iodosilane SbU HydroxylamineINN N N -180.3 Stibine -169.0 -139.7 Ammonium iodide -128.8 -100.0 -114.2 35.0 50.7 31.0 36.7 -201.4 -112.5 117.0 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 4 4 4 4 H H H H HSiHTa Silylidyne HRbHS Rubidium hydride Mercapto -52.3 H H H H H H H Molecular Formula Name H H H H H H H H H H H H H H H H H H H H H H H H H H H H

5-18 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 0.0 126.2 20.8 80.3 127.3 272.7 80.8 34.3 56.9 204.6 42.8 108.8 68.2 288.1106.8 37.4 70.2 180.8 20.8 162.8 188.3 227.7 49.0 126.0 102.5 239.6 32.9 0.0 75.9 28.0 61.4 31.8 175.0 20.8 -5.0 20.9 92.5 120.9 -361.2 -254.0 165.6 154.9 risilane Mercury(II) sulfate -707.5 Ammonium phosphate -1671.9 Mercury(I) sulfate -743.1 -625.8 200.7 132.0 Ammonium azideDiphosphoric acidDiphosphine Disilane 115.5T -2241.0 274.2 112.5 Hafnium oxideMercury(II) iodideDimercury Mercury(I) iodide -2231.7 -1144.7Holmium oxideIodine (atomic) -105.4 -1088.2 -101.7 59.3Potassium iodatePotassium periodate 180.0 60.3 -121.3Sodium iodateSodium periodate -111.0 -1880.7 233.5 -1791.1Iodine (rhombic) 158.2 -501.4 -467.2 -418.4 115.0 -361.4 151.5 175.7 -481.8 -429.3 106.5 -323.0 163.0 0.0 92.0 116.1 54.4 62.4 19.3 260.7 36.9 Ammonium hydrogen sulﬁteAmmonium hydrogen sulfate -768.6 -1027.0 Ammonium sulfateAmmonium hydrogen phosphate -1566.9 -1180.9 -901.7 220.1 187.5 188.0 P S P 4 S S 4 4 2 S 3 4 O S 4 3 3 4 SiP Orthosilicic acidO O 3 -1481.1 -1332.9 192.0 4 2 3 2 4 4 7 2 2 2 2 3 4 I O O 2 N 2 2 2 2 N O O P SiSnNONO NO Si N Silane Si Stannane N Ammonium hydroxide 4 4 4 4 4 4 5 5 5 6 8 8 9 12 MgNiPbSnSr Magnesium iodide Nickel(II) iodide Lead(II) iodide iodide Tin(II) Strontium iodide -364.0 -358.2 -78.2 -175.5 129.7 -143.5 -558.1 -173.6 174.9 77.4 81.6 2 2 2 2 2 2 Hg IInIKIKO Indium(I) iodide Potassium iodide -116.3 -327.9 -120.5 -324.9 130.0 106.3 52.9 7.5 -37.7 267.3 36.8 H H I I I I HgSHgTeHg Mercury(II) sulﬁde (red) Mercury(II) telluride -58.2 -42.0 -50.6 82.4 48.4 He Helium HfHfO Hafnium 0.0 43.6 25.7 619.2 576.5 186.9 20.8 HoHo Holmium 0.0 75.3 27.2 300.8 264.8 195.6 20.8 H HgI H H HgHgOHgO Mercury Hg Mercury(II) oxideI IKO ILiINaINaO INaO -90.8IO -58.5 Lithium iodide Sodium iodideI 70.3 44.1 Iodine monoxide -270.4 -287.8 -270.3 -286.1 86.8 98.5 51.0 52.1 H H IRbITlI Rubidium iodide Thallium(I) iodide -333.8 -123.8 -328.9 -125.4 118.4 127.6 53.2 7.1 H H H H H H H

5-19 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 374.4 78.4 446.1 105.4 S J/mol K Gas ° G f kJ/mol 0.0 164.1 20.8 ° 380.9 123.7 87.5 249.7 37.9 387.0 364.4 236.5 32.6 H f -120.5 -122.6 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol 6.3 ° H f kJ/mol 84.9 p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol anadium(IV) iodide itanium(IV) iodide -375.7 -371.5 249.4 125.7 -277.8 Phosphorus(III) iodideT -45.6 Potassium oxidePotassium sulfide -361.5 -380.7 -364.0 105.0 Diindium Indium(III) oxideIndium(III) sulfideIndium(IV) tellurideIridium(IV) oxideIridium(IV) sulfideIridium(III) sulfidePotassiumPotassium permanganatePotassium nitritePotassium nitrate -925.8 -427.0 -175.3 Potassium superoxide -830.7Dipotassium -412.5 -274.1 104.2Potassium peroxide -138.0 163.6 -234.0 -837.2 92.0 118.0 -737.6 -369.8 0.0 -494.6 171.7 -284.9 -306.6Lanthanum oxide -394.9 117.6 -239.4 152.1 57.3 133.1 -494.1 116.7 107.4 64.7 -425.1 96.4 77.5 29.6 102.1 -1793.7 -1705.8 127.3 108.8 89.0 60.5 160.3 20.8 Potassium sulfatePotassium phosphate -1437.8 -1950.2 -1321.4 175.6 131.5 4 5 3 2 3 S P 3 3 2 4 4 3 O 2 2 2 O S Te 2 O O O S O S 2 2 2 2 2 2 2 2 2 3 2 ZnInLaLuP RuSb Zinc iodidePt Indium(III) iodideSi Lanthanum iodideSn Lutetium iodideTi VV Ruthenium(III) iodideZr Antimony(III) iodide Platinum(IV) iodide Tetraiodosilane iodide Tin(IV) -238.0 -208.0 Zirconium(IV) iodide -668.9 -209.0 -548.0 -65.7 -100.4 161.1 -72.8 -189.5 -481.6 2 3 3 3 3 3 3 4 4 4 4 4 4 In K I I I I I I I I I InInOInPInSInSbIn Indium Indium monoxide Indium phosphide Indium(II) sulfide Indium antimonide -88.7 -138.1 -30.5 0.0 -77.0 -131.8 -25.5 59.8 67.0 86.2 45.4 57.8 49.5 26.7 344.3 238.0 243.3 208.7 173.8 20.8 I I I K K I KO In In IrIrO IrS Ir K KMnO KNO KNO IridiumKNaK K Potassium sodium Li 0.0 35.5 Lithium 25.1 0.0 665.3 29.1 617.9 24.8 193.6 20.8 159.3 126.6 138.8 20.8 Molecular Formula Name K Kr Krypton LaLaSLa Lanthanum Lanthanum monosulfide -456.0 -451.5 0.0 73.2 59.0 56.9 27.1 431.0 393.6 182.4 22.8

5-20 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 91.333.2 87.6 51.3 210.8 240.1 29.9 37.2 472.7 455.5 153.3 20.8 215.9 174.4 197.0 36.1 287.7 form) -214.2 -218.4 78.2 50.0

a Nitrogen (atomic) Lithium nitriteLithium nitrateDilithium Lithium peroxideLutetium oxide -372.4 -483.1 -302.0Magnesium nitrate -381.1 -634.3 96.0 90.0 Dimagnesium -1878.2Manganese(II) nitrateSodium permanganate -1789.0 -790.7Manganese(IV) oxide 110.0 -589.4 101.8 164.0Manganese(III) oxide 141.9 Manganese(II,III) oxide -576.3 -1156.0 Sodium molybdateMolybdenum(IV) oxide -520.0Molybdenum(VI) oxide -465.1Molybdenum(IV) sulfide -959.0 53.1 -1387.8Sodium nitrite -881.1Sodium nitrate 54.1 -1283.2 110.5 -1468.1Nitrogen dioxide -588.9 155.6 -745.1 -1354.3 107.7 -533.0 139.7 -235.1 -668.0 159.7 46.3 -225.9 77.7 141.7 56.0 62.6 75.0 -358.7 -467.9 63.6 -284.6 -367.0 103.8 116.5 92.9 Magnesium sulfate -1284.9 -1170.6 91.6 96.5 Lithium oxideLithium sulfide -597.9 -561.2 -441.4 37.6 54.1 Lithium sulfateLithium phosphate -1436.5 -2095.8 -1321.7 115.1 117.6 4 4 6 6 O Si Magnesium orthosilicateSi -2174.0 -2055.1 Manganese(II) orthosilicate 95.1 118.5 -1730.5 -1632.1 163.2 129.9 2 2 3 O S Se4 O Magnesium selenateSi3 4 4 Manganese(II) metasilicate -968.5 Pb -1320.9 -1240.5 Lead(II) molybdate 89.1 86.4 -1051.9 -951.4 166.1 119.7 2 3 SiS P Lithium metasilicate -1648.1 -1557.2 79.8 99.1 2 4 4 2 2 3 2 3 4 3 2 2 3 4 4 O O O O Si Molybdenum silicide -125.2 -125.7 106.3 93.1 RbRb Rubidium nitrite Rubidium nitrate -367.4 -495.1 -306.2 -395.8 172.0 147.3 102.1 2 2 2 2 3 3 O 2 2 3 O O O O S O 2 2 2 2 2 2 2 3 NNaO Li Mg N LiNO LiNO Li Li MdMgMgN MgOMgO Mendelevium Magnesium Magnesium oxideMnNaO MnOMnO MnO Mn Manganese(II) oxide 0.0 -601.6Mo 0.0MoNa -569.3MoO MoO MoO 27.0Mo 32.7 37.2 Molybdenum -385.2 24.9NNaO NO -362.9 59.7 45.4 Nitric oxide 0.0 147.1 28.7 112.5 24.1 148.6 20.8 658.1 612.5 182.0 20.8 NO NO MgO MgSMg Magnesium sulfideMnS Manganese(II) sulfide ( -346.0 -341.8MoS 50.3 45.6 MnSeMn Manganese(II) selenide -106.7 -111.7 90.8 51.0 Li Li MnMnN ManganeseMn 0.0 32.0 26.3 280.7 238.5 173.7 20.8 NO Li Li LrLuLu Lawrencium Lutetium 0.0 0.0 51.0 26.9 427.6 387.8 184.8 20.9

5-21 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol 0.0 191.6 29.1 0.0 146.3 20.8 ° 81.6 103.7 220.0 38.6 -28.5 -51.9 222.8 31.8 142.1 103.9 230.2 37.6 249.2 231.7 161.1 21.9 385.0 171.5 149.4 211.1 29.7 H f kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 50.3 86.6 142.4 314.7 72.7 -19.5 97.5 209.2 142.7 11.1 99.8 304.4 79.2 H f kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol Sodium oxideSodium sulfide -414.2 -375.5 75.1 -364.8 -349.8 69.1 83.7 Nickel(II) sulfate -872.9 -759.7 92.0 138.0 Nitrogen Nitrogen trioxide Nitrogen tetroxide Nitrogen pentoxideSilicon nitrideSodium superoxideDisodium -43.1Sodium peroxide 113.9 178.2 143.1 -743.5 -260.2Niobium(IV) oxideNiobium(V) oxide -642.6 -218.4Neodymium oxide 101.3 -510.9 115.9 -447.7 72.1 95.0Nickel(III) oxideOxygen (atomic) -796.2 89.2 -1899.5 -740.5 -1766.0 -1807.9 -1720.8 54.5 137.2 13.3Rubidium oxide 158.6 132.1 57.5 117.1 111.3 -489.5 355.7 95.3 -339.0 Nitrous oxide Sodium sulfiteSodium sulfate -1100.8 -1012.5 -1387.1 -1270.2 145.9 149.6 120.3 128.2 S SiS Sodium metasilicate -1554.9 -1462.8 113.9 5 3 2 3 3 4 SrPbRaSrZn Strontium nitrite Lead(II) nitrate Radium nitrate Strontium nitrate Zinc nitrate -762.3 -451.9 -992.0 -978.2 -796.1 -780.0 -483.7 222.0 194.6 149.9 S 3 2 3 2 2 Tl3 4 4 Thallium(I) nitrate5 6 6 6 6 -243.9 -152.4 160.7 99.5 4 O O O O O O O S 3 O 2 2 2 2 2 2 2 2 2 O O O O O O O O O NaSi Sodium azide 21.7 93.8 96.9 76.6 2 2 2 2 2 2 2 2 2 2 2 3 4 N Na OP Phosphorus monoxide OPbOPbOPdORaORb Lead(II) oxide (massicot) Lead(II) oxide (litharge) Palladium(II) oxide Radium oxide -217.3 -219.0 -187.9 -188.9 -85.4 68.7 66.5 -523.0 45.8 45.8 31.4 348.9 325.9 218.0 Na Na NbNbONbO Niobium Niobium(II) oxide -405.8 -378.6 0.0 48.1 41.3 36.4 24.6 725.9 681.1 186.3 30.2 NO NiSNi Nickel(II) sulfide -82.0 -79.5 53.0 47.1 N N NiNiO Nickel 0.0 29.9 26.1 429.7 384.5 182.2 23.4 N NaNaO Na Na SodiumNb NdNd Ne NeodymiumNo 0.0O Neon 51.3 NobeliumORh 28.2 0.0 Rhodium monoxide 71.5 0.0 27.5 107.5 77.0 153.7 20.8 327.6 292.4 189.4 22.1 Molecular Formula Name N N NP Phosphorus nitride -63.0 N N N N N N Na Na

5-22 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 6.3 -19.9 222.0 30.2 0.0 205.2 29.4 53.4 26.8 234.0 31.3 21.0 -99.6 -126.4 211.6 29.9 142.7 163.2 238.9 39.2 -279.9 -281.6 252.1 39.5 -320.5 -296.8 -300.1 248.2 39.9 -quartz) -910.7 -856.3 41.5 44.4 -322.0 a anadium(III) oxide -1218.8 -1139.3 98.3 103.2 itanium(III) oxide -1520.9 -1434.2 78.8 97.4 itanium(IV) oxide -944.0 -888.8 50.6 55.0 erbium oxide -1865.2 115.9 ellurium dioxideungsten(IV) oxide -322.6 -270.3 -589.7 79.5 -533.9 50.5ungsten(VI) oxide 56.1 -842.9 -764.0 75.9 73.8 Thallium(I) oxideOxygen Rubidium peroxide -178.7 -147.3 126.0 -472.0 Ozone Praseodymium oxideRhodium(III) oxideScandium oxideSamarium(III) oxideT T Thulium oxide -1809.6V -343.0Yttrium oxideYtterbium(III) oxide -1908.8 -1823.0 -1819.4 -1734.6 77.0 151.0 117.4 -1888.7 94.2 103.8 114.5 -1794.5 139.7 -1814.6 -1905.3 -1726.7 -1816.6 116.7 133.1 99.1 115.4 102.5 Phosphorus dioxide Sulfur dioxide T T Uranium(IV) oxideSulfur trioxide -1085.0 -1031.8 77.0Uranium(VI) oxide 63.6 -454.5 -374.2 70.7 -1223.8 -1145.7 96.1 -441.0 -373.8 81.7 -465.7 113.8 -471.5 274.6 -395.7 51.4 -371.1 256.8 50.7 2 2 2 2 2 2 2 2 2 2 2 2 P PbRbRb RuS SeSi Lead(IV) oxideSn Rubidium superoxideTe Th Ruthenium(IV) oxideTi U Selenium dioxideWT Silicon dioxide ( Zr oxide Tin(IV) PbS Thorium(IV) oxidePbSi -278.7 Pr -277.4Rh S -305.0 -217.3 Zirconium(IV) oxideSc SiSr Lead(II) sulﬁte 68.6 Lead(II) metasilicate -225.4 Sm Tb Ti 64.6 -577.6Tm -1226.4U -515.8V -1169.2 Strontium metasilicateWT Y -1100.6 49.0 65.2Yb -1042.8Os -1145.7 52.6 61.8 PbS -669.9 PbSe -1062.1 50.4 109.6 56.2 -1633.9 Osmium(VIII) oxide 90.0 -1549.7 Lead(II) sulfate Lead(II) selenate 96.7 88.5 -394.1 -920.0 -304.9 -609.2 -813.0 -504.9 143.9 148.5 167.8 103.2 -337.2 -292.8 293.8 74.1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 O O O O O OSi Silicon monoxide OS Sulfur monoxide OSeOSnOSrOTiOTl Selenium monoxide oxide Tin(II) Strontium oxide oxide Titanium(II) -280.7 -592.0 -519.7 -251.9 -561.9 -495.0 57.2 54.4 50.0 44.3 45.0 40.0 15.1 1.5 -8.4 232.1 31.6 O OU Uranium(II) oxide O O O O O O O O O O OVOZnO oxide Vanadium(II) Zinc oxide -431.8 -404.2 -350.5 38.9 -320.5 45.4 43.7 40.3 O O O O O O O O O O O O O O O O O O O

5-23 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 187.1 24.3 S J/mol K Gas ° G f kJ/mol ° 58.9 24.4 280.0 67.2 144.0 103.5 218.1 32.1 H f kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol anadium(V) oxideanadium(III,IV) oxide -1550.6 -1933.0 -1419.5 -1803.0 131.0 163.0 127.7 itanium(III,IV) oxide -2459.4 -2317.4 129.3 154.8 antalum(V) oxide -2046.0 -1911.2 143.1etraphosphorus 135.1 Lead(II,II,IV) oxideThallium(I) sulfateStrontium orthosilicateZinc orthosilicate -718.4Antimony(V) oxideT -601.2T V 211.3V -931.8 -2304.5Rhenium(VII) oxide 146.9 oxideUranium(IV,VI) -830.4 -2191.1 -1636.7 oxideUranium(V,VI) 230.5 153.1 -1523.2 oxideUranium(IV,V) -971.9 134.3 131.4Phosphorus (white)Phosphorus (red) -829.2Phosphorus (black) 123.3 Diphosphorus 125.1 -1240.1T -3427.1 -1066.0 -3242.9 -3574.8 207.1 -4510.4 250.5 -3369.5 -4275.1 166.1 215.5 282.6 0.0 334.1 -17.6 -39.3 238.4 293.3 41.1Platinum(IV) sulfide 22.8 23.8 21.2 -1100.0 -108.8 -994.0 -99.6 452.0 74.7 65.9 316.5 280.1 163.2 20.8 Rubidium sulfate -1435.6 -1316.9 197.4 134.1 2 2 SiS Lead(II) orthosilicate -1363.1 -1252.6 186.6 137.2 2 2 3 2 2 2 Zr Zirconium(IV) sulfate -2217.1 172.0 2 3 3 3 4 2 3 2 iZr Zirconium titanate -2024.1 -1915.8 116.7 114.0 2 Pb Pb RaSRb RuSSrSTl SZnSiSr Radium sulfateSiZn SiZr Ruthenium(VIII) oxideT Strontium sulfateSb Ta Zinc sulfateTi V V Zirconium(IV) orthosilicateRe U -1471.1S -239.3U -1365.6U -1453.1 -152.2 138.0 -1340.9 146.4 -2033.4 -982.8 117.0 -1919.1 -871.5 84.1 110.5 98.7 99.2 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 7 7 8 8 9 2 4 P O O O O O O O O O O O O O OsP P P P OsmiumPuRa 0.0 Plutonium 32.6 Radium 24.7 0.0 0.0 791.0 71.0 745.0 192.6 20.8 159.0 130.0 176.5 20.8 PaPbPbSPbSePbTePdPdSPm Protactinium Lead Lead(II) sulfide Lead(II) selenide Lead(II) telluride Palladium Palladium(II) sulfide Promethium 0.0 -100.4 -102.9 -70.7 -98.7 -101.7 0.0 -75.0 -69.5 102.5 91.2 -67.0 0.0 51.9 110.0 0.0 50.2 49.5 46.0 50.5 64.8 26.4 37.6 26.0 607.0 195.2 563.0 162.2 198.1 378.2 175.4 339.7 22.9 20.8 167.1 20.8 PoPrPtPtSPtS Polonium Praseodymium Platinum Platinum(II) sulfide 0.0 -81.6 0.0 -76.1 0.0 55.1 73.2 43.4 27.2 41.6 25.9 355.6 320.9 565.3 189.8 520.5 21.4 192.4 25.5 Molecular Formula Name O O O O O O O O O

5-24 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 0.0 169.7 20.8 0.0 176.2 20.8 678.0 181.1 20.8 128.6235.6 79.7 187.0 228.2227.1 227.1 254.9 32.5 36.4 146.0594.0 96.2 536.0 252.0 229.9 35.4 34.4 168.2 118.0 268.1 36.7 112.5 60.9 223.7 32.3 form) 6.7

a anadium 0.0 28.9 24.9 514.2 754.4 182.3 26.0 itanium 0.0 30.7 25.0 473.0 428.4 180.3 24.4 ellurium 0.0 49.7 25.7 196.7 157.1 182.7 20.8 echnetium 0.0 antalum 0.0 41.5 25.4 782.0 739.3 185.2 20.9 ungsten 0.0 32.6 24.3 849.4 807.1 174.0 21.3 T T Yttrium 0.0 44.4 26.5 421.3 381.1 179.5 25.9 T T Uranium 0.0 50.2 27.7 533.0 488.4 199.8 23.7 Sulfur (rhombic)Sulfur (monoclinic) 0.0 0.3 32.1 22.6 277.2 236.7 167.8 23.7 Thallium(I) sulfideDisulfur Diantimony -97.1Thallium(I) selenide -93.7Diselenium 151.0 Disilicon -59.0 -59.0Ditellurium 172.0 2 2 2 2 2 2 2 Te Te TbTc Terbium 0.0 73.2 28.9 388.7 349.7 203.6 24.6 YbZnZr Ytterbium Zinc Zirconium 0.0 0.0 0.0 59.9 39.0 41.6 26.7 25.4 25.4 152.3 608.8 118.4 130.4 566.5 173.1 94.8 181.4 20.8 161.0 26.7 20.8 Y Xe Xenon TlTmU VV WT Thallium Thulium 0.0 0.0 64.2 74.0 26.3 27.0 182.2 232.2 147.4 197.5 181.0 190.1 20.8 20.8 SbSb ScSeSeSeSeSrSeTl Antimony ScandiumSi Selenium (gray)Si Selenium ( Sm Selenium (vitreous) Strontium selenideSnSnSrTa Silicon Samarium (white) Tin 0.0 (gray)Th Tin 0.0Ti Strontium 0.0 -385.8 5.0 45.7 42.4 Thorium 34.6 25.2 25.4 25.5 0.0 0.0 0.0 -2.1 0.0 0.1 18.8 69.6 51.2 44.1 20.0 29.5 55.0 27.0 25.8 0.0 26.8 262.3 227.1 377.8 222.1 51.8 187.0 336.0 180.3 27.3 176.7 174.8 20.8 20.8 22.1 450.0 206.7 301.2 405.5 172.8 266.2 168.0 164.4 183.0 168.5 130.9 22.3 30.4 164.6 21.3 602.0 20.8 560.7 190.2 20.8 SSnSSrSTl sulfide Tin(II) Strontium sulfide -100.0 -472.4 -467.8 -98.3 68.2 77.0 48.7 49.3 RbReRhRn Rubidium Rhenium Rhodium Radon 0.0 0.0 0.0 76.8 36.9 31.5 31.1 25.5 25.0 80.9 769.9 556.9 53.1 724.6 510.8 170.1 188.9 185.8 20.8 20.8 21.0 S SSi Silicon monosulfide RuS Ruthenium 0.0 28.5 24.1 642.7 595.8 186.5 21.5 SZnSZnS Zinc sulfide (wurtzite) Zinc sulfide (sphalerite)SeZnSe -192.6 -206.0 Zinc selenide -201.3 57.7 46.0 -163.0 -163.0 84.0

5-25 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 345.9 84.4 330.6 80.0 342.8 82.4 357.8 89.4 318.5 74.6 347.8325.3 87.1 77.0 276.7 52.4 224.7 41.8 S J/mol K Gas ° G f kJ/mol ° 59.0 -41.1 85.3 186.2 165.3 248.3 46.9 H f -477.0 -464.0-933.6 264.5 49.6 261.6 61.1 -587.8 307.4 70.9 -219.1 -204.9 283.5 57.7 -648.3 69.3 -706.3-477.4 -439.4 300.8 66.9 72.3 -639.8 46.8 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 32.5 80.3 -27.1 18.4 112.1 138.0 131.0 236.2 45.0 H f -301.3 -236.8 225.4 121.6 -268.3 78.1 -128.2 130.7 -95.7 83.3 -127.2 -96.2 -110.9 309.1 61.8 kJ/mol p C J/mol K ° S J/mol K ubstances containing carbon: containing ubstances Crystal ° S G f kJ/mol ° H f kJ/mol ribromofluoromethane richlorofluoromethane etrabromomethanerichloromethyl 29.4etrachloromethane 47.7 212.5 144.3rifluoromethyl etrafluoromethane 83.9 67.0 358.1 91.2 rifluoroiodomethane Bromodichlorofluoromethane Carbon (graphite)Carbon (diamond) 0.0 1.9 2.9 5.7 2.4 8.5 6.1 716.7 671.3 158.1 20.8 Carbonyl bromide Carbonyl chloride Silver(I) carbonateBarium carbonateBeryllium carbonateBromochlorodifluoromethane Bromotrichloromethane Bromotrifluoromethane Bromotrinitromethane Dibromodichloromethane -505.8Dibromodifluoromethane -1213.0 -1025.0 -436.8 -1134.4 167.4 112.1T Calcium carbonate (calcite) 112.3 Calcium carbonate (aragonite) 86.0 52.0Cadmium carbonate 65.0 Chlorotrifluoromethane Chlorotrinitromethane Dichlorodifluoromethane -1207.6 -1207.8T -1129.1 -1128.2T 91.7 -750.6Cobalt(II) carbonate 88.0Cesium carbonate -669.4 83.5 82.3 92.5 T T Iron(II) carbonate -713.0 -1139.7 -1054.3 204.5 123.9 -740.6 -666.7 92.9 82.1 Carbonyl fluoride 6 6 2 F 2 3 3 O O 2 3 3 3 3 3 2 2 3 3 3 3 3 3 3 O O ClFCl F O ClFT Dibromochlorofluoromethane Tribromochloromethane F O FT 2 2 2 2 2 2 3 3 4 2 2 3 3 4 O IT 2 3 3 4 CBr CCl CF CFeO CBr CCaO CCoO CF CBrCl C C CAgNCAg Silver(I) cyanide 146.0 156.9 107.2 66.7 CCl CBr CBr CBr CBrN CBrCl CBrF CBrNCBr CBr Cyanogen bromideCClF CClNCClN CCl 140.5 CCl Cyanogen chloride CF CBaO CBeO CBrClF CCaO CCdO CClFO Carbonyl chloride fluoride CCs CCuNCFN Copper(I) cyanide Cyanogen fluoride 96.2 111.3 84.5 CCl Molecular Formula Name CF

5-26 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 316.4 67.4 246.6 39.9 238.0 44.9 293.2 54.7 242.9 52.5 304.3 63.2 327.7316.8 69.2 65.1 293.1 60.9 287.6276.3 52.7 264.4 49.2 47.0 222.9 37.5 43.1 28.0 224.7 34.6 -81.9 234.6 40.8 390.4 372.9 194.9 33.8 145.7 147.9 194.2 38.7 251.0 356.2 75.0 127.6 113.0 247.8 46.9 595.8 -695.4 259.7 51.0 -424.9-482.6 295.1 58.7 280.9 55.9 -452.3 246.7 42.9 -108.6 -102.5 218.8 35.4 -111.2 -92.9 249.4 59.5 262.8 163.1 -528.9 351.1 102.4 68.5 90.4 174.1 134.0 119.5 95.8 309.7 57.7 24.0 -22.3 -5.0 220.9 130.7 23.8 8.0-32.8 330.9 71.2 -13.4 435.6 134.1 -59.8-13.6 163.2 126.0 -35.4 14.4 -26.3 246.4 42.4 254.1 44.1 108.9 125.0 112.8 70.6 135.1 124.7 201.8 35.9 -134.1 -73.7 201.7 114.2 -102.7 6.0 295.7 65.7 -124.2-104.9 177.8 101.2-425.0 -361.4 -95.4 129.0 99.0 270.2 -378.7 -61.5 51.0 358.1 86.4 ribromomethane richloromethane rifluoromethane riiodomethanerinitromethane -181.1 rithiocarbonic acid Iron carbideBromodichloromethane Bromodifluoromethane T Chlorodifluoromethane T Cesium hydrogen carbonate 25.1T T 20.1Potassium formatePotassium hydrogen carbonate 104.6 -966.1 105.9 T Sodium formateSodium hydrogen carbonate -963.2Methylene -863.5 -679.7 Dibromomethane 115.5 Dichloromethane -950.8Difluoromethane Diiodomethane -851.0 -666.5Diazomethane Cyanamide -599.9 101.7Dinitromethane 103.8Paraformaldehyde 87.6 Formic acid T 82.7 Methyl 58.8 -177.6 Dibromofluoromethane Dichlorofluoromethane Formaldehyde Fluoromethane Iodomethane 4 2 3 2 3 6 x Si Methyltrichlorosilane 2 2 O 2 3 ClF F Chlorodibromomethane 2 2 3 O 2 2 2 2 2 2 3 2 3 3 2 3 O) 2 3 2 3 BrClBrFBr ClFCl F Bromochloromethane I Bromofluoromethane N N Chlorofluoromethane N O O S BOBrClCl F I Borane carbonyl Bromomethane Chloromethane 3 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 CHI CH CH CH CHCsO CH CHKO CFe CHN CHBrF CHBr CHClF CHCl CHF CHNOCHNSCHNaO Isocyanic acid (HNCO) Isothiocyanic acid CH CH CH CH Methylidyne CHFOCHKO CHN Formyl fluoride CHNaO CHO Hydrogen cyanide Oxomethyl (HCO) CH CH CHBrClF Bromochlorofluoromethane CH CH CH CH CHBrCl CHBr CHBr CHCl CH CH CH CH (CH CH CH CH CH

5-27 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 256.5 65.9 S J/mol K Gas ° G f kJ/mol ° 22.9 -66.1 -74.6 -50.5 186.3 35.7 474.0 391.9 95.9 437.6 407.5 202.6 29.2 234.0 184.0 210.6 29.8 H f -110.5-142.0 -137.2-393.5 -169.2 -394.4 197.7 231.6 213.8 29.1 41.5 37.1 -245.8 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 54.2 180.0 165.9 134.9 94.7 187.0 278.8 71.1 89.0 64.6 151.3 76.4 116.7 67.1 237.8 45.4 38.4 82.4 503.7 176.1 -46.7-47.3 -7.7 35.7 169.2 150.2 90.5 102.1 -22.9 -22.5 -9.3 32.7 255.2 242.9 50.3 50.1 H f -254.0 -193.9 -112.6-156.3 -14.4 -43.4 171.8 217.1 106.6 157.3 -80.8 -122.0 282.9 305.8 55.5 76.6 -239.2 -166.6 126.8 81.1 -201.0 -162.3 239.9 44.1 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol etraiodomethaneetranitromethane -392.9 Nitromethane Methyl nitrite Methyl nitrate Methane Ammonium cyanideNitroguanidineAmmonium hydrogen carbonateGuanidine3-Amino-1-nitroguanidine 0.4Methylhydrazine -849.4Mercury(I) carbonate -92.4 -665.9T 120.9 22.1 Potassium carbonate 134.0 Lithium carbonate -56.0 Magnesium carbonateManganese(II) carbonate -553.5 -468.1T Sodium carbonate 180.0 -1151.0 -1063.5Carbon dioxide -1095.8 -1215.9 -894.1 -1012.1 -1132.1Rubidium carbonate 155.5 -816.7Thallium(I) carbonate 65.7 90.4 114.4 85.8 75.5 99.1 -1130.7Carbon disulfide 81.5 -1044.4 135.0 -1136.0 112.3 -1051.0 -700.0 181.3 -614.6 117.6 155.2 Methanol Methanethiol Methylamine UreaThioureaHydrazinecarbothioamide -333.1 -89.1 24.7 2 2 2 2 3 3 3 3 2 3 3 O S O S O 3 2 2 2 2 4 3 3 5 2 8 3 O O 2 2 O NONO NO NO N Formamide N N N O S N NO N N N ClNN Si Methylamine hydrochloride Methylsilane -298.1 O PbRb SrTl Zn Lead(II) carbonate Strontium carbonate Zinc carbonate -699.1 -1220.1 -625.5 -1140.1 131.0 -812.8 97.1 87.4 -731.5 81.4 82.4 79.7 O 2 3 3 3 3 4 4 4 4 4 4 4 5 5 5 5 5 6 6 6 4 2 3 3 3 3 3 2 2 4 CH CNa CKNCKNSCK Potassium cyanide Potassium thiocyanate -200.2 -113.0 -178.3 -101.9 124.3 128.5 88.5 66.3 CH CH CH CH COSCO CO Carbon oxysulfide CH CH CH CH CH CINCI CLi CMgO Cyanogen iodideCMnO CNCO Cyanide 166.2CO 185.0 Carbon monoxide CO 96.2 225.5 196.6 256.8 48.3 CH CH CNNaCNNaOCN Sodium cyanide Sodium cyanate -87.5 -405.4 -76.4 -358.1 115.6 96.7 70.4 86.6 Molecular Formula Name CHg CH CO CO CS Carbon monosulfide CH CH CS CH CH CH CH

5-28 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 336.6 96.1 387.1 102.7 441.9 139.3 352.8 102.5 311.3313.5 68.8 70.3 253.7 55.7 242.0 54.3 231.7 52.4 313.9 76.5 831.9 775.9 199.4 43.2 227.4 209.9 200.9 44.0 -658.9 300.1 80.5 -490.5 -497.9 298.1 77.9 -489.9 -407.0 382.9 123.4 -315.5 -289.1 303.0 72.1 -694.5 -1064.4 -1118.8 184.2 -1344.2 332.3 106.7 -1100.4 173.6 -50.6 3.0 266.9 143.4 -10.9 -43.6 228.4 124.4 -9.0 324.8 80.3 164.8 -280.8 -239.8 -234.5 151.0 -196.6 -522.7-367.6 -505.5 -523.8 -335.8 322.1 83.9 -187.6 173.8 -142.0 -280.4 -241.0 -1069.9 -1031.4 -1,2-Dibromoethene -1,2-Dibromoethene richloroacetonitrile richloroacetyl chloride etrabromoethene etrachloroethene etrafluoroethenerichloroethene -820.5 richloroacetic acidrifluoroethene rifluoroacetic acid -503.3 richloroacetaldehyde rifluoroacetonitrile Carbon diselenide Dicarbon Bromopentafluoroethane 1,2-Dibromo-1-chloro-1,2,2-trifluoroethane1,2-DibromotetrafluoroethaneT Hexabromoethane Calcium cyanideCalcium oxalateChlorotrifluoroethene Chloropentafluoroethane 1,2-Dichloro-1,1,2,2-tetrafluoroethaneOxalyl chloride 1,1,2-Trichloro-1,2,2-trifluoroethaneT 1,1,1,2-Tetrachloro-2,2-difluoroethane 1,1,2,2-Tetrachloro-1,2-difluoroethane -184.5 -1360.6 Hexachloroethane -691.7T Hexafluoroethane 1-Bromo-2-chloro-1,1,2-trifluoroethane -817.72-Bromo-2-chloro-1,1,1-trifluoroethane1-Chloro-2,2-difluoroethene 2,2-Dichloro-1,1,1-trifluoroethane -202.8T -960.2 -656.6 -745.0T Pentachloroethane 237.3T -789.1 T 198.2Pentafluoroethane Acetylene 111.72-Bromo-1,1,1-trifluoroethane cis -937.0 trans 170.1 -675.3 -716.8 -720.0 -143.6 -644.8 -690.4 1,1-Dichloro-2-fluoroethene Dichloroacetyl chloride 3 3 3 2 3 3 2 2 2 F F OT O O 2 2 2 4 4 4 3 2 2 2 2 3 3 3 3 5 O 5 3 5 ClF F F O F NT F F OT 3 3 5 BrF Br Br 2 2 4 6 2 2 3 3 4 4 4 4 6 NT 2 2 2 2 2 3 4 6 BrF Br Br Br Br CaCaN CaO ClF ClF Cl Cl Calcium carbideCl Cl Cl Cl Cl Cl Cl F F F HBr -59.8HBrClF HBrClF -64.9HClHClF HCl 70.0HCl Bromoacetylene HCl 62.7 HCl HCl Chloroacetylene HCl HCl HFHF HF HF H H H Fluoroacetylene H 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 C C C C C C C C C C C CSe C C C C C C C C C C C C C C C C C C C C C CSiCSiC Silicon carbide (cubic) Silicon carbide (hexagonal)C C -62.8 -65.3 -60.2 -62.8C 16.5 16.6 26.7 26.9 C C C C C C C

5-29 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 326.5 89.1 356.0 102.7 268.3 58.2 307.2 82.5 320.2 88.7 285.0 57.9 S J/mol K Gas ° G f kJ/mol ° 33.3 300.5 73.7 79.2 81.8 275.8 55.5 -36.9 300.0 275.8 255.3 54.7 H f -644.5 -335.0-207.4 -212.0 266.2 -189.7 60.1 272.5-383.5 60.6 -338.3-427.6 337.0 -368.5 80.5 325.9-744.6 78.8 -730.7 279.9 78.2 -552.3 -138.8 kJ/mol p 165.7 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 40.6 86.5 149.6 91.5 74.0 91.9 243.4 52.2 -23.9-26.4 24.1 201.5 198.4 111.3 116.4 2.8 4.6 25.4 289.0 67.1 289.6 65.1 -92.0 -67.9 -47.5 -48.3 247.6 51.8 -24.3 27.3 195.9 116.8 5.0 28.6 290.0 66.7 130.8 159.5 159.0 163.5 165.7 246.9 52.9 H f -223.5-272.9 -208.0 200.8-467.2 117.0 -242.8 -190.4 -205.8-163.5 295.1 67.8 -442.1 -126.4 -932.4 -888.4 -496.3 -195.0 246.9 162.3 -149.2 362.8 100.8 -177.4-190.8 227.4 232.6 144.3 150.9 -144.4 -151.3 323.1 337.2 93.3 89.0 -283.7 -244.8 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -1,2-Dichloroethene -1,2-Dichloroethene -1,2-Difluoroethene -1,2-Diiodoethene 1,1,1-Trifluoro-2-iodoethane 2,2,2-Trifluoroethanol 1,2-Dibromo-1,2-dichloroethane 1,1,2,2-Tetrabromoethane 2-Chloro-1,1,1-trifluoroethane 1,1-Dichloroethene cis trans Dichloroacetic acid 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane 1,1-Difluoroethene cis cis Glyoxal Oxalic acidBromoacetic acid 1-Chloro-1,1-difluoroethane Chloroacetic acid1,1,1-Trichloroethane 1,1,2-Trichloroethane -829.91,1,1-Trifluoroethane 1,1,2-Trifluoroethane 109.8 -509.7 Potassium acetate 91.0Nitroethene Oxamic acid -723.0 -731.8 -661.2 -662.7 320.6 86.2 Chloroacetyl chloride 1,1-Dichloro-1-fluoroethane Ketene Thiirene Fluoroethene Iodoethene Acetonitrile Isocyanomethane 2 2 2 2 3 2 2 3 2 Cl O O NO 2,2,2-Trichloroacetamide -358.0 F Sr Strontium formate -1393.3 2 4 2 2 2 2 2 3 4 4 2 3 3 I O 2 4 4 2 2 3 3 3 3 2 Br Br ClF Cl Cl Cl Cl Cl Cl Cl Cl F F F I O O O O S BrBrOBrO ClClF ClO Bromoethene ClO Acetyl bromide Cl Cl ChloroetheneCl F Acetyl chloride FOF F F I IO Acetyl fluoride KO N N NO -94.1NO Acetyl iodide NO Methyl isocyanate 59.4 14.6 37.2 53.6 264.0 53.7 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C

5-30 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 82.4 269.4 72.6 264.5 58.6 52.4 68.4 219.3 42.9 75.0 83.0 11.4 -84.0 -32.0 229.2 52.5 -313.4 -497.0-387.1 282.5 67.8 -583.0 -504.9 318.6 87.1 -392.1 130.1 123.8 63.659.8 139.0 140.3 201.9 209.0 132.0 101.6 146.9 94.4 303.0 146.1 306.0 83.3 51.691.9 82.0 96.8 255.2 126.5 53.3 -66.2-79.2 223.3 136.0 -37.5 327.7 80.8 -90.5 -25.8 198.7 100.8 -61.9 -23.9 286.7 64.5 -78.0 -11.8 153.9 88.0 -52.6 -13.0-40.0 242.5 14.7 47.9 211.7 115.1 -8.1 19.2 306.0 66.9 -216.9-136.8-295.4 -59.3 190.8 -175.1 104.3 -112.1 -60.4 276.0 62.8 -158.4-166.8 -73.8 211.8-148.2 126.3-165.2 -127.7 128.4 -70.8 -126.4 305.1-484.3-386.1 -389.9 76.2 159.8 308.4 123.3 78.7 -432.2 -374.2 119.1 -357.4 283.5-143.9 63.4 -350.7 -190.4 285.3 64.4 134.4 -103.8 -154.1 320.5 79.0 -192.2 -127.6 160.2 89.0 -166.2 -133.0 263.8 55.3 -277.6 -174.8 160.7 112.3 -234.8 -167.9 281.6 65.6 -1,2,4-Triazol-3-amine 76.8 -Methylformamide -Methylurea -332.8 H Sodium acetateEthylene 1,1-Dibromoethane 1,2-Dibromoethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Diﬂuoroethane 1,2-DiiodoethaneOxamide -708.8Ethanedial dioxime1,1-Dinitroethane -607.21,2-Dinitroethane Ethanedithioamide 123.01 79.9 Acetic acid Methyl formate 9.3 Peroxyacetic acid -90.5 Glycolic acid -504.4 -20.8 Nitroethane Glycine2-Nitroethanol Ethyl nitrate Ethane 1,2-HydrazinedicarboxamideOxalyl dihydrazide -528.5 -498.7 -295.2 Acetaldehyde Oxirane Thiirane Fluoroethane Iodoethane Ethyleneimine N Ethanol N 2 2 2 4 4 2 2 2 2 2 3 3 O O O O S O O O 2 2 2 2 2 2 2 2 2 4 2 2 3 3 2 4 4 2 2 NSNaO BrClBr Br Methyl isothiocyanateClFCl Cl 1-Bromo-2-chloroethane F I N 1-Chloro-1-ﬂuoroethane N N N N 79.4 N O O OSO O O O S Thioacetic acid SiBrClClOF I Ethynylsilane N Bromoethane NO Chloroethane NO 2-Chloroethanol NO NO NO NO AcetamideNSCdHgN N ThioacetamideN O Dimethyl cadmium Dimethyl mercury -317.0 -71.7 115.0 91.3 -238.3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-31 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° 313.1 70.3 S J/mol K Gas ° G f kJ/mol ° 265.5 190.5 184.9 277.1 H f -614.2 -1318.0 -1783.2 kJ/mol p 195.5 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 48.952.7 206.4 198.0 164.1 84.1 92.2 23.4 201.6 129.2 53.0 42.1 78.6 -54.3-62.6 235.4-63.0 146.1 -24.7 -9.7 172.6 -18.0 -73.3 -48.0 -15.5 -73.6-65.3 -5.5 207.0-74.1-43.9 196.4 117.9 70.0 118.1 -46.1 182.3 -37.4 -4.8 137.7 296.2 130.0 -18.8 72.7 -47.5 286.0 68.5 36.3 74.1 273.1 283.8 70.7 71.5 183.7 285.9 306.7 241.9 56.8 147.1 180.6 H f -204.2 -99.9 188.3 153.0 -151.3 -460.0 163.2 148.6 -392.2 303.8 82.7 -193.2 -459.9-101.8 -418.6 -203.3 -184.1 -112.6 266.4 64.4 -523.6-735.5 -483.4 -687.0 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol etraiodoethenerinitroacetonitrile 305.0 Ethylene glycol 1,2-Ethanedithiol Dimethyl disulfide 1,2-Ethanediamine 1,1-Dimethylhydrazine 1,2-Dimethylhydrazine Ammonium oxalateMercury(II) oxalateDiiodoacetylene T Potassium oxalateMagnesium oxalateCyanogen T Sodium oxalate -1123.0Perfluoropropane Malononitrile -678.2 2-Propynoic acid 1,3-Dioxol-2-one -1346.0 1,2,3-Trichloropropene -1269.0 3,3,3-Trifluoropropene 226.0 Allene Propyne Cyclopropene 2,3-Dichloropropene 186.4 1,1,1,3-Tetrachloropropane1,2,2,3-Tetrachloropropane -208.7 -251.8 Dimethyl ether Ethanethiol Dimethyl sulfide Ethylamine Dimethylamine Acrylonitrile Dimethyl sulfoneDimethyl sulfite Dimethyl sulfate -450.1 -302.4 142.0 -373.1 -272.7 310.6 100.0 4 4 4 S S S O 3 2 4 4 4 2 2 3 4 2 2 2 2 6 2 2 3 2 2 4 3 O 2 O OSO O O O S Dimethyl sulfoxide S S S ZnN N NOClNN Dimethyl zinc N N N Ethanolamine Dimethylamine hydrochlorideO Pb -289.3 N O O Cl Lead(II) oxalateF N NONOCl Oxazole Cl Isoxazole Cl -851.4 -750.1 146.0 105.4 O 6 6 6 6 6 6 6 6 6 6 6 7 7 7 8 8 8 8 8 2 4 4 2 2 2 3 3 3 3 3 4 4 4 4 4 4 2 8 2 4 H H H H H H H H H H H H H H H H H H H HgO I I K MgO N N Na O F H H H H H H H H H H H H H H 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C C

5-32 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 71.3 35.6 -21.0 132.9 192.0 482.4 230.2 -181.0 -130.5 -441.2 125.1 4.0 20.0 7.9 40.8 -9.0 35.2 53.3 104.5 237.5 55.6 12.2 45.2 53.715.5 119.3 91.5 51.7 105.4 179.4 205.7 108.6 141.7 -370.9 -279.1 545.9 234.2 -148.4 131.6 -107.8 -309.1-383.8-329.9-571.5 175.3 122.1-522.5 145.7 -282.9 -505.3 133.9 -271.0 -487.0-230.6 -508.4 -278.6 -475.8 -464.0 183.6 -462.9 -182.9 -444.0 -113.6-198.8-199.9-205.8-163.2 149.1-207.1 -181.2 -162.8 -71.6 -159.2 -173.2 -100.7 -381.5-385.3 -316.3 -318.4 -171.8 138.9 -124.5 -Pyrazole -1-Bromopropene -(Aminocarbonyl)acetamide -544.2 H rinitroglycerol 2,2,3,3-Tetraﬂuoro-1-propanol -1114.9 -1061.3 1 Imidazole1,2-Propanedione Acrylic acid 2-Oxetanone Ethylene carbonate 2-Chloropropanoic acid 49.8 3-Chloropropanoic acidEthyl chloroformate Methyl chloroacetate 1,2,3-Trichloropropane 3-Iodopropanoic acid -549.3 Nitroacetone Methyl nitroacetate T Propene Cyclopropane -460.0 1,2-Dibromopropane 1,2-Dichloropropane, (±) 1,3-Dichloropropane 2,2-Dichloropropane 1,2-Diiodopropane 1,3-Diiodopropane PropanediamideN 1,1-Dinitropropane 1,3-Dinitropropane 2,2-Dinitropropane Hexahydro-1,3,5-trinitro-1,3,5-triazine -546.1 2,3-Dichloro-1-propanol 1,3-Dichloro-2-propanol Acrolein cis 3-Iodopropene Propanenitrile 2-Propyn-1-amine Ethyl isocyanide Allyl alcohol 9 2 2 4 4 4 6 2 2 2 2 3 4 O O O O O O O O O 3 2 2 2 2 2 2 2 O 2 2 2 2 2 3 3 2 2 2 2 2 6 4 2 2 F N N O O O O O Br BrBrOClClClOClO 3-Bromopropene ClO Bromoacetone ClO 2-Chloropropene ClO 3-Chloropropene Cl Epichlorohydrin I IOIO N N N NO Iodoacetone NO NO N AcrylamideBr Cl Cl Cl Cl Cl I I N N N N -212.1N N O 110.6 -224.0 -130.2 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-33 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol 0.0 47.7 313.5 86.5 ° 10.080.0 54.7 130.4 323.3 336.4 84.7 111.3 H f -465.9 -259.0 -424.0 -367.3 -285.9 -293.5 kJ/mol p 149.3 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° 24.711.3 184.9 60.6 107.1 45.8 285.045.8 68.3 187.7 147.1 77.0 -66.0-74.8-10.0 -30.0 -40.3 H f -239.3 150.6 -192.4 -121.9-130.5-160.5-172.3 -87.0 -99.4 -131.9 -144.9 -510.7-445.9-333.5 191.0 152.8 -455.7 141.9 118.0 -413.3 -298.0 -525.3 -517.5 324.4 86.0 -167.2-180.3-214.5-229.7 170.3 -138.9 -124.3-120.9 350.0 104.1 -174.1 -191.0 -103.8 362.6 -23.4 123.2 270.3 73.6 -215.6-248.4-123.0-110.8 199.8 196.5 126.3 120.4 -217.1 -94.7 -185.6 -152.7 295.3 -80.5 74.5 286.9 304.5 72.6 80.7 -468.4 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -Dimethylformamide -Alanine-Serine -563.6 -739.0 -Alanine -561.2 -Alanine -558.0 -Cysteine -534.1 -Alanine-Serine -604.0 -732.7 L Propanoic acid Ethyl formate Methyl acetate 1,3-Dioxolane 1,3,5-Trioxane1,2-Dithiolane 1,3-Dithiolane 1,3,5-Trithiane 3-Chloro-1,2-propanediol 2-Chloro-1,3-propanediol -522.5 133.0 111.41-Nitropropane 2-Nitropropane Ethyl carbamateDL D L b SarcosinePropyl nitrate Isopropyl nitrate DL L -517.1Propane -465.9 -513.3 156.4 -497.3 -446.3 Propanal Acetone Methyloxirane Oxetane Thietane Methylthiirane 1-Fluoropropane 2-Fluoropropane 1-Iodopropane 2-Iodopropane Allylamine Cyclopropylamine N,N Thiolactic acid S 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 S 2 2 2 2 2 3 2 2 3 O O O O O O O O O O S S S S S BrBrClClClO ClO 1-Bromopropane F 2-Bromopropane F 1-Chloropropane I 2-Chloropropane I N N NO NONO NO NO NO NO PropanamideNO NO NO NO NO NO NO NO -338.2 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 8 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C

5-34 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 331.0 117.9 -28.8 196.1 340.2 -398.3 -216.4 309.2 93.3 -1542.6 189.9 171.1 127.2 -79.4-97.8 -29.8 -24.5 -53.6 -99.9-91.6 242.5 239.1 144.6 144.6 -67.8 -45.7 -59.6 208.5 137.9 -23.6 287.1 91.8 -62.3 177.0 114.8 -34.8 267.2 65.4 139.7145.9224.9 191.6 145.6 209.7 195.7 278.3 -136.4-143.1 -9.9-382.8 -32.1 209.4 -246.4 238.9 155.6 278.2 -74.1 -124.3 -352.8 -35.9 -243.5 314.7 369.1 88.5 -501.0-480.8-377.8-669.6 244.0 190.8 206.3 162.0 -429.8 218.9 -348.5 -408.0 -577.9 -233.1 -190.3 -302.6-318.1 193.6 181.1 143.9 156.5-105.9 -255.1 -272.6 233.5 322.6-101.5 309.2 145.3-112.3 85.6 89.3 -76.2 218.3 163.8 164.1 -83.7 -70.1 32.2 39.9 312.2 325.4 97.5 91.2 -2-Butenedinitrile 268.2 '-Dimethylurea -312.1 -Dimethylurea -319.1 N -Bromosuccinimide-Chlorosuccinimide -335.9 -357.9 -Ethylurea, -357.8 rimethyl borate rimethylborane rimethylamine Oxymethurea1,2-Propylene glycol 1,3-Propylene glycol Ethylene glycol monomethyl ether Dimethoxymethane Glycerol -717.0 1,3-Propanedithiol T 1,2-Propanediamine, (±) Hexachloro-1,3-butadiene Perfluorocyclobutane Perfluorobutane trans Maleic anhydride2-Butynedioic acid2-NitrofuranN N Succinonitrile PyrazinePyrimidine Pyridazine UracilBarbituric acid -469.8 -577.3 Diketene -104.1 139.8 -634.7 -429.4 120.5 -302.9 1-Propanol 2-Propanol Ethyl methyl ether 1-Propanethiol 2-Propanethiol Ethyl methyl sulfide Propylamine Isopropylamine Furan N N N,N 2 2 3 2 3 3 3 O O O O 2 O O 2 2 2 2 2 2 2 2 3 2 3 4 2 2 2 2 2 2 2 2 ClNClNN SiBNBN Propylamine hydrochloride hydrochloride Trimethylamine Trimethylsilane borane Trimethylamine Aminetrimethylboron -354.7 -282.9 -142.5 -284.1 70.7 -79.3 187.0 218.0 N N N N O O O O O O O O S S S S AlBT BO ClSiN N aluminum Trimethyl NT Trimethylchlorosilane N O O NO BrNO ClNO N N N N N N O O 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 9 9 9 9 9 10 10 10 10 12 12 2 2 2 3 4 4 4 4 4 4 4 4 4 4 8 10 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H Cl F F H H H H H H H H H H H H H H 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-35 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 156.7 H f -527.9 -375.4 -708.9 kJ/mol p 161.1 126.3 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -5.8 33.6 88.5 199.0 123.6 110.0 67.9 111.8 80.263.1 181.2 123.8 156.4 114.9 127.7 126.1 108.2 278.8 72.8 52.947.0 90.7 86.9 133.5 131.6 303.5 297.1 79.8 83.3 95.1 134.3 -39.8 -13.6 -13.8 23.4 138.6141.4119.1 162.3 165.2 145.7 117.8140.8 159.7 182.8 H f -208.1-120.9 -286.2 -169.5 -170.1 -130.5 -349.2-362.2-420.9-624.4-613.2 239.5 158.8-575.5 -333.0 -556.3 141.4-566.3 -314.4 -533.4 -366.5 218.6 -582.5 -572.5 -487.1 -492.7 -138.7 -100.6 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -2-Butenoic acid -2-Butenenitrile -2-Butenal -Butyrolactone Succinic anhydrideMaleic acidFumaric acidSuccinimide -608.6 1,2-Butadiene -789.41,3-Butadiene -811.71-Butyne 2-Butyne Cyclobutene 2,5-Piperazinedione 160.8 168.0trans 137.0 -459.0 Methacrylic acid 142.0Vinyl acetate Methyl acrylate g Acetic anhydride Propylene carbonate -446.5 Succinic acidDimethyl oxalate2-Chlorobutanoic acid 3-Chlorobutanoic acid 4-Chlorobutanoic acid Propyl chlorocarbonate -679.4 -675.8 -940.5 -756.3 Iminodiacetic acidEthyl nitroacetate 167.3 153.1 -932.6 -823.0 Thiophene trans 3-Butenenitrile 2-Methylacrylonitrile Pyrrole Cyclopropanecarbonitrile Divinyl ether trans 2,3-Dihydrothiophene 2,5-Dihydrothiophene Butanenitrile 2-Methylpropanenitrile Cytosine -221.3 132.6 2 2 2 2 2 2 4 4 O O 3 4 4 3 2 2 2 2 2 2 3 3 4 4 O O O S N N N N N NO NSN 4-Methylthiazole N O O O O O O O O O O O S S ClOClO ClO ClO ClO N 2-Chloroethyl vinyl ether N NONONONO NO Acetone cyanohydrin 2-Pyrrolidone 2-Methyl-2-oxazoline 4 4 4 4 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 7 7 7 7 7 7 7 7 7 7 7 7 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C

5-36 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 0.0 84.5 326.2 109.7 -10.0 72.4 333.5 110.4 187.9 568.8 275.5 173.0 171.2 220.9 180.0 3.71.7 27.7 -20.8-29.8-37.5 227.0 219.9 118.0 127.0 0.1 -7.1 -30.0 -16.9 -72.9 -34.1 45.8 309.6 92.5 -33.3 -11.4 -216.2 204.3 124.0 -184.1-143.8-154.9 302.4-164.4-188.1 76.3 -107.1 -120.3 -132.4 -154.4 -142.1-148.0 -140.3-139.6-237.3-229.8 -91.6 -237.5 -87.8 -102.0 -195.0 -183.4 -533.8-500.3-479.3-379.7 222.2-353.9-386.9 178.6 257.7 -475.9 170.7 270.2 -443.6 152.1 143.9 -462.7 -315.3 -340.6 -352.0 -268.2 -228.1 -167.4-168.9-239.2-247.3-273.3 230.9 246.6 147.0 239.1 163.7 -204.8 158.7 -140.8 -238.5 -215.7 343.7 339.9 103.4 101.7 -2-Butene -2-Butene -Glycylglycine -747.7 -Ethyl thioacetate -Aspartic acid -973.3 -Asparagine -789.4 etrahydrofuran etrahydrothiophene L 1-Butene cis trans Isobutene Cyclobutane Methylcyclopropane 1,2-Dibromobutane 1,3-Dibromobutane 1,4-Dibromobutane 2,3-Dibromobutane 1,2-Dibromo-2-methylpropane1,3-Dichlorobutane 1,4-Dichlorobutane 1,4-Diiodobutane SuccinamideDimethylglyoximeL N 1,4-Dinitrobutane Cyclotetramethylenetetranitramine -199.7 -581.2 Butanoic acid 2-Methylpropanoic acid Propyl formate Ethyl acetate -156.6Methyl propanoate 1,3-Dioxane 1,4-Dioxane 2-Methyl-1,3-dioxolane 1,3-Dithiane 1,4-Dithiane -113.3 Bis(2-chloroethyl) ether Ethyl vinyl ether 1,2-Epoxybutane Butanal Isobutanal 2-Butanone S Creatinine -238.5 Sulfolane 2 2 3 3 4 8 4 O O O O O O O O S 2 2 2 2 2 2 2 2 3 2 2 2 2 2 8 2 2 2 2 2 2 2 2 2 2 2 2 NO N Br Br Br Br Br Cl Cl Cl I N N N N N N O O O O O OT OS O O O O O O O O O ST S S BrBrBrCl 1-Bromobutane 2-Bromobutane, (±) 2-Bromo-2-methylpropane 1-Chlorobutane 7 7 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 9 9 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-37 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° H f -282.6 -471.4 -441.0 kJ/mol p 210.8 162.3 179.0 164.8 C J/mol K ° S J/mol K Liquid ° G f kJ/mol 5.6 41.2 ° 30.1 182.8 75.3 -41.1 204.1 156.6 -3.6 H f -106.2 -53.0 -278.3 175.6 -228.0 -192.8-191.1-211.3-335.6-346.9 -161.1 -159.3 -182.2 -301.3 -282.0 -268.0 -205.6 -192.5-217.2-390.0 -147.3-154.2 -143.9 -177.1 369.9 140.9 -125.7 115.1 -134.2 -523.6 -501.0-505.3-541.5-539.7 223.4 200.1 -428.7 213.0 -433.2 -482.3 -107.5 -72.1 -327.3-342.6-334.7-359.2-279.5-266.0 225.8-278.8 214.9 214.7 177.2 193.3 196.9 172.4 -274.9 181.5 262.9 -292.8 218.6 253.8 -283.8 175.6 -312.5 165.4 -252.1 161.9 -238.1 -252.0 359.5 326.7 112.7 342.7 113.6 119.5 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -Dimethylacetamide -Threonine -758.8 -Nitrodiethylamine -Methylpropanamide -Threonine-Asparagine, monohydrate -807.2 -1086.6 rimethylurea -330.5 1-Nitrobutane 2-Nitroisobutane Propyl carbamate4-Aminobutanoic acid3-Nitro-2-butanol 2-Methyl-2-nitro-1-propanolDL L CreatineButane Isobutane Piperazine -581.0 -552.6 -410.1 N L -537.2 1,2-Butanediol, (±) -45.6 1,3-Butanediol 1,4-Butanediol 2,3-Butanediol 2-Methyl-1,2-propanediol Ethylene glycol monoethyl ether 1-Iodo-2-methylpropane 2-Iodo-2-methylpropane Cyclobutanamine Pyrrolidine N N,N 1-Butanol 2-Butanol 2-Methyl-1-propanol 2-Methyl-2-propanol Diethyl ether Methyl propyl ether Isopropyl methyl ether 2 4 2 2 2 2 2 3 3 3 3 OT O O O 2 2 2 2 2 2 2 2 2 2 3 HgN N N N O Diethyl mercury O O O O O O OSO O O O O Diethyl sulfoxide O ClClClClOI I 2-Chlorobutane N 1-Chloro-2-methylpropane N 2-Chloro-2-methylpropane NO 2-Chloroethyl ethyl ether NO NONO NONO Butanamide NO NO 2-MethylpropanamideNO NO Morpholine NO NO NO N -368.6 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C C

5-38 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -390.0 254.0 97.9 135.9 -52.3 -18.8 500.4 529.2 100.2 132.7 140.4 -264.0 -100.0 277.3 204.1 -239.1 -99.9 359.0 143.9 -600.7-813.2 -552.2 -756.3 -420.6-293.6-628.5 244.8-105.7 -389.7 -120.1 -571.2 -245.9 305.0 204.0 -79.4 -50.6 -633.0-774.0 -588.2 -705.3 313.4 338.1 204.6 240.6 -201.6 -602.9 -587.2-504.5 410.6 145.2 163.2 -151.0 -447.2 -253.7 -203.6 -124.7-131.0-132.0-140.5-119.4-118.5-124.7-127.6 171.2 269.3-137.5 272.5-150.6 -88.0 263.1 171.4-132.6 171.6-103.7 -96.9 172.4 -83.5 -97.3 -82.2 -109.6 -90.5 179.2 368.1 192.1 -91.9 183.2 117.0 -121.0 169.2 -104.6 -98.7 -72.2 -Dimethylethanolamine -Butylamine -Butyl hydroperoxide -Butylamine -Purine 169.4 N , H ris(hydroxymethyl)methylamine -717.8 Diethyl sulfite Diethyl sulfate Ethylene glycol dimethyl etherDimethylacetal tert Diethylene glycol 1,4-Butanedithiol Diethyl disulfide Diethanolamine -376.6T 2-Methyl-1,2-propanediamine 193.3 Bis(2-aminoethyl)amine -493.82-Butynedinitrile Nickel carbonyl Iron pentacarbonyl Hexafluoroacetylacetone5-Nitro-2-furancarboxylic acid1 XanthineUric acidFurfural 233.52-Furancarboxylic acid3-Methyl-2,5-furandione -516.8 -2286.7 1,1,1-Trifluoro-2,4-pentanedione -133.9 -498.4 -379.6 -618.8 -397.1 161.1 173.2 151.3 166.1 -90.3 -1040.2 -993.3 Pyridine 1-Butanethiol 2-Butanethiol 2-Methyl-1-propanethiol 2-Methyl-2-propanethiol Diethyl sulfide Methyl propyl sulfide Isopropyl methyl sulfide Butylamine sec tert Isobutylamine Diethylamine N Hypoxanthine -110.8 145.6 134.5 2 3 2 3 2 2 5 S S 2 2 2 3 3 4 2 3 O O O 2 2 O O 5 4 4 4 4 2 3 3 4 6 3 O O O O O O S S S S S S S S S N N N N N NO NO NO BrNClNClNINN Pb bromide Tetramethylammonium Si Diethylamine hydrochlorideSn chloride Tetramethylammonium N iodide Tetramethylammonium lead Tetramethyl Tetramethylsilane -251.0 Tetramethylstannane -276.4 -358.6 -203.9 F NO N N N N O O O F N 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 11 11 11 11 11 11 11 11 12 12 12 12 12 12 12 12 13 2 2 3 4 4 4 4 4 4 4 5 5 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H N NiO FeO H H H H H H H H H H H 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 5 5 5 5 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-39 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 81.4 76.1 140.7 105.7 133.1 H f -387.0 614.7 294.8 kJ/mol p 220.2 184.1 191.2 C J/mol K ° S J/mol K Liquid ° G f kJ/mol 4.3 201.2 122.4 34.0 ° 48.293.8 229.3 152.6 75.5 121.6 44.643.162.423.3 218.520.5 149.8 83.5 82.5 103.1 74.0 70.2 33.5 80.9 125.7 -33.1-39.8 232.0 179.4 -2.3 10.5 226.5 228.2 105.9 134.3 101.2 157.5 193.7 134.5 185.2 103.0 147.4 H f -382.9 -341.9 -276.2 204.0 -211.8 -370.6-423.8-623.2 -515.5 -354.2 -382.0 -467.0 -235.9 -192.1 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol )-furanone -461.3 -406.5 H -pyran-2-one -436.7 -379.6 H -2-butenoate trans -3-Penten-1-yne -1-Propene-1,2-dicarboxylic acid -824.4 -1,3-Pentadiene -3-Pentenenitrile -3-Penten-1-yne -1,3-Pentadiene -Pyrrole-2-carboxaldehyde -106.4 H etrahydro-2 Adeninecis trans 1,3-Cyclopentadiene ThymineFurfuryl alcohol trans 96.9Ethyl cyanoacetate 1,2-Pentadiene cis -462.8trans 1,4-Pentadiene 2,3-Pentadiene 3-Methyl-1,2-butadiene 2-Methyl-1,3-butadiene 147.0Cyclopentene Spiropentane Methylenecyclobutane Pentaerythritol tetranitrate 150.84-Pentenoic acidAllyl acetate Ethyl acrylate Methyl Methyl methacrylate 2,4-Pentanedione Dihydro-4-methyl-2(3 -538.6 T Methyl acetoacetate Glutaric acidPropyl chloroacetate 205.7 -430.6 -328.7 -960.0 2-Methylthiophene 3-Methylthiophene trans Cyclobutanecarbonitrile 1-Methylpyrrole 2-Methylpyrrole 3-Methylpyrrole Cyclopentanone Pentanenitrile 2,2-Dimethylpropanenitrile 1,2,5,6-Tetrahydropyridine Guanine -183.9 2 12 2 2 O O O 5 5 2 2 4 4 2 2 2 2 2 2 2 2 3 4 NON N 1 N O O S S N N N N N NO N O O O O O O O O O O O ClO N N N 5 5 5 6 6 6 6 6 6 6 6 7 7 7 7 7 7 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 9 9 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C

5-40 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -366.2 -137.6 -491.3 -376.9 200.2 196.2 198.2 310.0 254.0 -31.1 16.6 -46.9-53.7-61.1-51.5-68.6 262.6 258.6-44.5 154.0-24.8 254.0 151.7-33.3 253.3 -21.1 251.0 157.2 -27.6 156.1 152.8 -35.2 -27.5 -41.7 -8.2 -93.0 -44.5 -58.2 256.5 157.0 -31.9 -435.7 -369.1 -262.2 307.8 -258.3-294.5 -223.4 -250.4 -105.1 204.5 128.8 -76.4 -559.4-554.5 -561.6 259.8-518.9-502.7 210.3-296.5 -491.9 -681.5 -510.0 199.4 -481.6 -463.4 -637.9 -300.1-267.2-297.3-296.5-299.5-182.2 204.1 182.5 266.0 268.5 -242.5 190.9 184.1 179.9 -257.9 -258.8 -228.4 -262.6 362.9 -148.2 -2-Pentene -1,2-Dimethylcyclopropane -30.7 -1,2-Cyclopentanediol -490.1 -2-Pentene -1,2-Dimethylcyclopropane -26.3 -1,2-Cyclopentanediol -485.0 -Nitrosopiperidine -Glutamic acid -1005.3 -Nitropiperidine -Methyl-2-pyrrolidone -Proline-Glutamic acid -515.2 -1009.7 -Glutamine -826.4 etrahydrofurfuryl alcohol etrahydropyran N L D L 1-Pentene cis trans 2-Methyl-1-butene 3-Methyl-1-butene 2-Methyl-2-butene Cyclopentane Methylcyclobutane Ethylcyclopropane 1,1-Dimethylcyclopropane cis trans 2,3-Dibromo-2-methylbutane N L Pentanoic acid 2-Methylbutanoic acid 3-Methylbutanoic acid 2,2-Dimethylpropanoic acidButyl formate Propyl acetate Isopropyl acetate Ethyl propanoate Methyl butanoate (Ethoxymethyl)oxirane 4-Methyl-1,3-dioxane -564.5 cis trans T Diethyl carbonate Ethylene glycol monomethyl ether acetate Ethyl lactate -416.1 N Cyclopentanol Pentanal 2-Pentanone 3-Pentanone 3-Methyl-2-butanone 3,3-Dimethyloxetane 2 3 2 4 4 O O O 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 Br N N N O O O O O O OT OSO O O O O S-Propyl thioacetate O O O O O O O O O O O O NONO NO NO NO 2-Piperidinone -306.6 9 9 9 9 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-41 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 44.9 H f -413.5 -455.1 -290.2 -313.1 -460.0 kJ/mol p C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -89.5 256.9-95.1-86.4 165.2 -48.1 241.0 210.0 181.2 179.9 -54.9 -47.1 H f -170.2-213.2-216.0-235.7-226.6 -128.9 -174.9 -179.7 -202.2 -185.1 -909.2 -215.4-173.5-178.4-190.2 -164.4 260.4 164.8 167.2 -153.6 -146.9 390.9 137.1 -168.0 -528.8-450.5 -450.8 -414.7 -106.3 218.2 163.3 -63.5 53.1 323.0 109.7 -351.6-365.2-368.9-356.6-356.4-379.5-366.6-399.4 -290.6-313.6 208.1-303.6 -294.6 239.7 -314.9 -311.0 295.3 247.1 265.3 -301.4 295.0 192.7 -329.3 -300.7 187.5 -258.1 197.2 -313.5 -283.7 -272.0 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol ) DL -butyl ether tert -Arabinopyranose -1057.9 -Diethylurea -372.2 -Butylurea -417.4 -Valine -628.9 D N - , -Ribose-Xylose -1047.2 -1057.8 -Methionine -577.5 -Valine -617.9 etramethylureaetramethylthiourea -262.2 -38.1 Butylureatert N -419.5 L Glycerol 1-acetate, ( D D a 1-Nitropentane DL L 5-Aminopentanoic acid2-Ethyl-2-nitro-1,3-propanediolPentane Isopentane Neopentane -606.4 -604.1 1,5-Pentanediol 2,2-Dimethyl-1,3-propanediolDiethoxymethane -551.2 Thiacyclohexane Cyclopentanethiol Cyclopentylamine Piperidine 1-Pentanol 2-Pentanol 3-Pentanol 2-Methyl-1-butanol, (±) 3-Methyl-1-butanol 2-Methyl-2-butanol 3-Methyl-2-butanol, (±) 2,2-Dimethyl-1-propanol Butyl methyl ether Methyl Ethyl propyl ether S 2 2 2 2 2 4 O O O OT ST 4 5 5 5 2 2 2 2 2 2 2 2 O O O O S S BrClClClClN 1-Bromopentane N 1-Chloropentane NO 1-Chloro-3-methylbutane NO 2-Chloro-2-methylbutane NO 2-Chloro-3-methylbutane NO NO NO PentanamideNO 2,2-DimethylpropanamideNO N N N N -399.7 N O O -379.5 O O O O O O O O O O O O 10 10 10 10 10 10 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C C C C C

5-42 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 3.8 -13.4 -776.7 -809.3 -128.1 -156.3 271.1 218.0 -63.1-20.7 -8.1 25.7 -17.5 162.4 30.2 -343.9 223.8 159.1 -309.2 -330.0-342.3 222.6 159.0 -293.8 157.5 -306.7 -443.6 -459.4 -429.9 -991.3 280.8-683.8 221.6 -955.4 -151.3-154.4-162.8-158.8-142.9-157.1-144.8 290.1-156.1 198.1 307.5 -110.0 276.1 -127.1 309.5 200.9 -114.9 199.9 -102.4 198.4 -121.3 -121.3 -104.8 -118.3 -1963.5-2406.3 -1932.7 -2370.4 -Tetramethylmethanediamine -51.1 -18.2 -Butyl methyl sulfide -Dichlorobenzene -Difluorobenzene -Dichlorobenzene -Dichlorobenzene-Difluorobenzene -Difluorobenzene -Benzoquinone -42.3 175.4 147.8 -185.7 129.0 22.5 -122.9 Pentafluorophenol -1024.1 -1007.7 1,1-Dimethoxypropane 2,2-Dimethoxypropane Diethylene glycol monomethyl ether 2-(Hydroxymethyl)-2-methyl-1,3-propanediolPentaerythritolXylitol -744.6 -920.6 N,N,N',N' -1118.5 ChloropentafluorobenzeneHexachlorobenzeneHexafluorobenzene Perfluorocyclohexene Perfluorocyclohexane Pentafluorobenzene1,2,4,5-Tetrafluorobenzene -858.4 1,2,3-Trichlorobenzene1,2,4-Trichlorobenzene 1,3,5-Trichlorobenzene -127.61,3,5-Trinitrobenzene2,4,6-Trinitrophenol2,4,6-Trinitro-1,3-benzenediol1-Chloro-4-nitrobenzene -852.7o 260.2m p -70.8 201.2o -78.4 m -467.5 -37.0p -217.91,2-Dinitrobenzene -48.71,3-Dinitrobenzene1,4-Dinitrobenzene2,4-Dinitrophenolp -841.8 214.6 239.7 250.2 -2.0 -27.0 -35.5 -38.0 -232.7 -806.5 200.4 197.5 200.0 -36.0 Pentachlorophenol -292.5 253.2 202.0 2,4-Dichlorophenol -226.4 1-Pentanethiol 2-Methyl-1-butanethiol, (+)3-Methyl-1-butanethiol 2-Methyl-2-butanethiol 3-Methyl-2-butanethiol 2,2-Dimethyl-1-propanethiolButyl methyl sulfide tert Ethyl propyl sulfide Ethyl isopropyl sulfide Pentylamine -154.4 -165.4 -114.9 -129.0 2 6 7 8 4 4 4 5 O 2 2 3 3 4 5 2 O O O O O O O O 3 3 3 2 2 2 2 3 3 3 2 2 2 2 2 5 O 4 2 2 2 5 O O O O O O S S S S S S S S S S N N 5 5 F Cl Cl Cl N N N ClNO Cl Cl Cl Cl F F F N N N N O 6 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 13 14 2 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 6 10 12 H H H H H H H H H H H H H H H H H H ClF Cl F F F HCl HF HF H H H H H H H H H H H H H H H H H H H H 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-43 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 335.5 H f -221.5 -267.5 -274.7 -434.2 -444.0 -452.9 kJ/mol p 188.7 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -4.6 12.5 185.849.1 68.5 124.5 173.4 136.0 348.8 82.9 120.4 129.7 269.2 82.4 85.1 128.7 149.5 60.911.1 219.2 154.3 150.1 52.0 63.731.656.761.959.2 222.8 173.2 216.3 209.1 111.3 191.9 158.7 158.6 159.0 87.5 106.4 99.2 103.8 -7.0 317.9 107.9 -20.3 198.7 -10.3 27.8 384.2 117.2 205.4 158.7 164.9 111.5 156.5 H f -150.6 205.9 146.4 -115.9 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -1-Propene-1,2,3-tricarboxylic acid -1232.7 -Benzotriazole 236.5 -1-Propene-1,2,3-tricarboxylic acid -1224.4 H -Hydroquinone -364.5 136.0 -265.3 Nitrobenzene 3-Pyridinecarboxylic acid2-Nitrophenol1 2,3-Dinitroaniline2,4-Dinitroaniline2,5-Dinitroaniline2,6-Dinitroaniline3,5-Dinitroaniline1,5-Hexadiyne -344.9 Benzene -202.4 2-Nitroaniline -11.7 3-Nitroaniline -67.8 4-Nitroaniline -44.3 -50.6 -38.9 p PyrocatecholResorcinol1,2,3-Benzenetriol1,2,4-Benzenetriol1,3,5-Benzenetriol3,4-Dimethyl-2,5-furandione -26.1cis -38.3trans -42.0 -354.1 -551.1 -581.4 -368.0 -563.8 Adiponitrile -584.6 166.0 158.8 167.0 -9.4 -14.4 -20.7 63.8 58.4 58.8 3,4-Dichloroaniline -89.1 Fluorobenzene Iodobenzene Phenol2-Vinylfuran Benzenethiol Aniline 2-Methylpyridine -165.13-Methylpyridine 4-Methylpyridine 1-Cyclopentenecarbonitrile 144.0 127.4 -96.4 4 4 4 4 4 2 2 2 2 2 3 N O O O O O O O O 2 3 3 3 3 3 3 2 2 2 2 2 2 3 3 3 3 6 6 2 BrClClOClOClOCl Bromobenzene F Chlorobenzene I 2-Chlorophenol NO 3-ChlorophenolNO 4-ChlorophenolNO N N N N N N ClN -206.4ClN -197.7ClNN N N 2-Chloroaniline O 3-Chloroaniline O 4-ChloroanilineO O O O O -189.3 O -181.3 O O O S N -33.3N N N N N 147.3 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 7 7 7 7 7 8 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C

5-44 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 263.2 248.0 310.0 212.5 0.7 44.1 54.178.4 84.2 96.3 -38.5-36.4-23.7-17.6 214.6 148.3 -5.0 -3.8 7.4 14.6 -74.2-83.9-78.9-90.0 295.2-78.2 183.3 -43.5 -52.3 -47.6 -59.4 -49.5 -16.7 39.8 -85.5-86.1 -53.9 -54.4 141.0 217.0 202.9 -610.5 -550.1 -207.2-293.0 -163.7 -545.8-553.4 -492.3 -500.2 -550.1-420.0-679.1-805.5-566.5 -497.8 -537.6-538.4 -375.6 -626.5 -742.0 -513.8 -485.7 -487.4 -271.2-265.2 182.2 -226.1 -2-butenoate trans -2-Hexene -3-Hexene -2-Hexene -3-Hexene -Ascorbic acid-Histidine -1164.6 -466.7 riacetamide 1,2-Benzenediamine1,3-Benzenediamine1,4-BenzenediaminePhenylhydrazine Dimethyl maleate L Citric acidButyl trichloroacetate Isobutyl trichloroacetate -0.3 -7.8 3.0 T Nitrilotriacetic acidL 1,5-Hexadiene 3,3-Dimethyl-1-butyne 154.5Cyclohexene -1543.8 1-Methylcyclopentene 159.6 3-Methylcyclopentene 4-Methylcyclopentene Butyl dichloroacetate -1311.9 Ethyl Methyl cyclobutanecarboxylateEthyl acetoacetate Propanoic anhydride Adipic acidDiethyl oxalate Ethylene glycol diacetate Ethyl 4-chlorobutanoate Propyl 3-chloropropanoate Butyl chloroacetate 1-Hexene cis trans -994.3 cis trans 2-Methyl-1-pentene 3-Methyl-1-pentene -395.0 -350.2 Cyclopentanecarbonitrile 2,4-Dimethylpyrrole2,5-Dimethylpyrrole -422.3 Cyclohexanone 2-Methylcyclopentanone Mesityl oxide Bis(2-cyanoethyl) sulﬁde 2 2 2 2 2 2 2 O 3 6 O O 2 S O 2 2 3 3 4 4 4 3 3 2 2 2 2 2 4 6 7 3 Cl O O O O O O O O O O ClClO ClO ClO NONO Chlorocyclohexane Caprolactam 1-Methyl-2-piperidinone -329.4 156.8 -239.6 N N N N N O O O Cl Cl N N N NO NO N 8 8 8 8 8 8 8 8 9 9 9 9 9 9 9 9 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 11 11 11 11 11 11 12 12 12 12 12 12 12 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-45 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° -65.8 79.4 363.5 131.3 H f kJ/mol p 233.8 228.0 221.3 376.0 213.3 C J/mol K ° 280.3 210.4 S J/mol K Liquid ° G f kJ/mol ° -80.0-98.5-94.5-94.6-87.0-91.6-87.1-93.2-87.5-59.0 -51.3 -66.9 -62.3 -63.1 -57.5 -61.5 -56.0 -62.4 -60.3 -27.5 H f -101.4-156.4-137.9 270.2 174.7 -68.1 154.9 -123.4 -106.2 -583.8-529.2-554.5-514.2-673.1 227.8 231.0 -485.3 -511.9 -516.5 229.3 -471.1 -631.7 -218.8-322.0-320.2-325.9-328.6-348.2-345.5 305.3 232.0 216.9 -182.6 213.3 -277.6 -278.9 208.2 -286.0 -286.2 -290.6 -140.7-109.8 255.6 192.6 -96.2 -64.7 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -2-pentene -2-pentene -2-pentene -2-pentene cis trans cis trans -Glucose -1273.3 -Fructose -1265.6 -Butyl acetate -2-Methylcyclopentanol D D - -Galactose-Mannose -1286.3 -1263.0 - -Cystine -1032.7 -Sorbose -1271.5 4-Methyl-1-pentene 2-Methyl-2-pentene 3-Methyl- 3-Methyl- 4-Methyl- 4-Methyl- 2-Ethyl-1-butene 2,3-Dimethyl-1-butene 3,3-Dimethyl-1-butene 2,3-Dimethyl-2-butene Cyclohexane Methylcyclopentane Ethylcyclobutane 1,1,2-TrimethylcyclopropaneL ThiramHexanoic acid Butyl acetate tert Isobutyl acetate 40.2Ethyl butanoate Methyl pentanoate Methyl 2,2-dimethylpropanoateDiacetone alcohol Ethylene glycol monoethyl ether acetate Paraldehyde b -96.2 D a 301.7 D L -530.0 257.9 -491.2 Butyl vinyl ether Hexanal 2-Hexanone 3-Hexanone 4-Methyl-2-pentanone 2-Methyl-3-pentanone 3,3-Dimethyl-2-butanone Cyclohexanol cis Thiepane Cyclohexanethiol Cyclopentyl methyl sulﬁde 2 S 4 4 O S 2 2 2 2 2 2 2 2 2 2 3 3 6 6 6 6 6 N N O O O O O O O O O O O O O O O O O O O O O O O O S S S 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C

5-46 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -313.9 336.0 281.0 301.0 274.1 248.0 275.9 293.4 159.0 11.5 51.3 -804.3 -725.0 -194.2-246.1-397.9-380.9 453.0 203.5 -148.3 -204.3 -324.2 -305.9 -329.4 -254.9 -859.0 -792.0 -198.7-204.6-202.4-213.8-207.4 290.6 292.5 272.5 193.7 195.6 287.8 190.7 -174.6 191.9 -166.9 -171.9 189.7 -185.9 -178.1 -577.1-491.4 -490.1 -453.5 -147.6-124.9 -104.0 -84.4 -377.5-392.0-392.4-394.7 287.4-396.4 240.4-328.8-351.5 -315.9 286.2 -333.5 323.9 273.0 221.6 -293.0 216.8 -319.2 -1317.0 -Butyl ethyl ether -Leucine-Isoleucine -640.6 -Lysine -635.3 -678.7 -Leucine -637.3 -Arginine -623.5 250.6 232.0 -Butylacetamide -Leucine-Isoleucine-Norleucine -637.4 -637.8 -639.1 200.1 -486.8 rimethylolpropaneriethylene glycol -750.9 Dipropyl sulfate DL D L DL L L 6-Aminohexanoic acidHexane 2-Methylpentane 3-Methylpentane 2,2-Dimethylbutane 2,3-Dimethylbutane Azopropane DL D -637.3 1,2-Hexanediol 1,6-Hexanediol2-Methyl-2,4-pentanediol Ethylene glycol monobutyl ether 1,1-Diethoxyethane Ethylene glycol diethyl etherDiethylene glycol monoethyl ether Diethylene glycol dimethyl ether T T Galactitol -569.9 -548.6 -451.4 259.4 -461.2 -408.1 Cyclohexylamine 2-Methylpiperidine, (±) N 1-Hexanol 2-Hexanol 3-Hexanol 2-Methyl-1-pentanol 3-Methyl-2-pentanol 4-Methyl-2-pentanol 2-Methyl-3-pentanol 3-Methyl-3-pentanol Dipropyl ether Diisopropyl ether Butyl ethyl ether tert 2 2 2 2 2 2 2 2 2 O O S 2 2 4 2 2 2 2 2 2 3 3 3 4 4 6 BrClN N NONO 1-Bromohexane NO 2-Chlorohexane NO NO NO Hexanamide NO NO NO N N N O O O O O O O O O O O O OSO O O O O Dipropyl sulfoxide O O O O O O O 13 13 13 13 13 13 13 13 13 13 13 13 13 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-47 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 33.2 44.8 705.0 181.7 243.0 H f -325.0 -342.3 -105.9 kJ/mol p 321.0 188.4 222.0 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -87.0 221.2 172.0 -36.7 163.2 209.1 165.2 215.7 H f -158.0 -103.2 -194.6 9.4-127.7-305.9 336.7 241.2 -157.7 16.1 219.9 437.8 -92.7 -171.5-815.0 -541.5 -118.3 433.8 311.4 -777.7 -534.5 535.0 238.5 -189.7 -175.7-188.3-181.6-172.3-167.1-156.1 313.0-178.5 232.0 -129.9 -142.0 -148.3 -127.8 -121.8 -116.0 -143.8 -1314.5 -1311.1-3420.0 355.5 561.8 262.3 419.0 -3383.6 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -Benzimidazole-Indazole 79.5 151.9 -Mannitol H H riethanolamineetracyanoethene -664.2 623.8 389.0 -558.3 riethylborane riethylamine D Dipropyl disulfide T 1,6-HexanediamineHexamethyldisiloxane Molybdenum hexacarbonylT Perfluorotoluene PerfluoromethylcyclohexanePerfluoroheptane 2,3,4,5,6-Pentafluorotoluene3,5-Dinitrobenzoic acid -205.0 -982.82-Chlorobenzoic acid3-Chlorobenzoic acid -877.74-Chlorobenzoic acid(Trifluoromethyl)benzene 325.9 242.32-Nitrobenzoic acid3-Nitrobenzoic acid -409.8 4-Nitrobenzoic acid2,4,6-Trinitrotoluene -404.5 1 -424.3 1 -428.91-Methyl-2,4-dinitrobenzeneBenzoic acidSalicylaldehyde -2931.1 -378.8 3-(2-Furanyl)-2-propenal -394.7 -883.8 -392.2 -63.2 -66.4 163.2 -912.1 -856.0 306.4 -182.0 353.1 490.0 225.8 -385.2 -2897.2 205.0 -842.7 243.3 167.6 146.8 -341.0 -294.0 3-Chlorobenzoyl chloride Benzonitrile Benzaldehyde 1-Hexanethiol 2-Methyl-2-pentanethiol 2,3-Dimethyl-2-butanethiolDiisopropyl sulfide Butyl ethyl sulfide Methyl pentyl sulfide Dipropylamine Diisopropylamine -187.1 -147.9 2 3 6 6 4 2 2 2 4 4 4 OP Hexamethylphosphoric triamide O 6 6 2 3 O O O 2 2 2 3 2 2 2 2 2 2 5 3 O S S S S S S S BT N N NT NONO N N OSi 2-Diethylaminoethanol F Cl N ClOClO ClO ClO F N Benzoyl chloride NONO NO NO N N BenzoxazoleN N O O O O -24.2 14 14 14 14 14 14 14 14 15 15 15 15 15 15 16 18 18 4 3 4 4 5 5 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 8 14 16 H H H H H H H H H H H H H H H H H MoO N F F F H H H H H H H H H H H H H H H H H H H H H 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C

5-48 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 55.3 167.7 347.0 126.2 -54.8 -100.9 -494.8 285.0 166.8 207.1 -9.7 -6.3-8.1 56.4 54.6 167.6 165.4 351.0 352.5 130.2 125.5 12.4 157.3 50.5 12.0 34.248.119.416.118.712.718.322.5 243.7 248.5 94.4 248.8 189.5 244.2 184.8 240.7 184.7 67.1 241.7 185.2 63.6 101.6 191.8 66.5 184.5 58.1 68.8 72.0 -31.5 -22.8 30.7 -61.3-34.8 -53.3 -25.2 -19.8 -32.5 18.9 -47.2 4.8 -194.0 212.6 224.9 -132.3 -380.4-389.8-391.9 -296.0 -283.6 -296.7 -301.8-242.7 -580.9-422.6-571.7 -250.3 -523.1 251.0 -375.3 -517.3 -186.9 171.2 -147.4 -160.7-114.8 216.7 217.9 -100.4 -67.9 -Cresol -Methylaniline -Cresol-Cresol -204.6 -199.3 165.4 167.3 154.6 150.2 -128.6 -125.4 oluene 2-Hydroxybenzoic acidAniline-2-carboxylic acid Aniline-3-carboxylic acid Aniline-4-carboxylic acid 2-Nitrotoluene -589.9 3-Nitrotoluene 4-Nitrotoluene(Nitromethyl)benzene SalicylaldoximeT -48.1 -183.7 172.3Ethyl 2-pentynoate Methyl 2-hexynoate Isopentyl trichloroacetate Bicyclo[2.2.1]heptane1-Methylbicyclo(3,1,0)hexaneMethylenecyclohexane Vinylcyclopentane 1-Ethylcyclopentene Butyl acrylate Diethyl malonate Butyl 2-chloropropanoate -95.1 31.0 -33.2 1.7 4-Fluorotoluene o m p Benzyl alcohol Anisole Benzylamine 2-Methylaniline 3-Methylaniline 4-MethylanilineN 1-Cyclohexenecarbonitrile 2,3-Dimethylpyridine 2,4-Dimethylpyridine 2,5-Dimethylpyridine 2,6-Dimethylpyridine 3,4-Dimethylpyridine 3,5-Dimethylpyridine -23.5 Cyclohexanecarbonitrile 2-Methylenecyclohexanol -277.6 Phenylurea -218.6 2 2 O 2 2 2 2 2 2 2 2 3 O 2 2 2 4 3 2 O O Cl N O O O ClO O BrClClF NONO 4-Bromotoluene NO 2-Chlorotoluene NO (Chloromethyl)benzene NO NO BenzamideNO NO NO N O O O O O N N -202.6 N N N N N N N N N N 6 7 7 7 7 7 7 7 7 7 7 7 7 7 8 8 8 8 8 8 8 9 9 9 9 9 9 9 9 9 9 9 9 10 10 11 11 12 12 12 12 12 12 12 12 13 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-49 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° H f -297.1 -298.3 kJ/mol p 232.6 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -97.9 327.6 211.8 -62.3 -82.8 -31.0 H f -557.9-630.7-105.1 -109.5 -104.3 -109.3 -100.0-115.9-112.7-117.0 -502.3 -110.6-123.1 -578.4 -114.1-117.7-156.6-190.1-163.4 -65.7 -172.1 -79.4 -76.8 -83.8 -81.6 279.9 -88.7 -212.3 184.8 -79.5 -85.5 -154.7 -118.1 -126.9 -138.2 -157.9 -610.2 265.4 -536.2 -311.5-356.1-352.9 335.4-390.2 230.1 -263.8 -413.2 318.0 233.7 -311.3 -313.6 -327.0 -347.5 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -2-Heptene -3-Heptene -3-Methyl-3-hexene -4,4-Dimethyl-2-pentene-1,2-Dimethylcyclopentane-1,3-Dimethylcyclopentane -121.7 -171.2 -168.1 -88.8 -136.6 -133.6 -2-Methylcyclohexanol, (±)-3-Methylcyclohexanol, (±)-4-Methylcyclohexanol -415.7 -394.4 -433.3 -352.5 -329.1 -367.2 -2-Heptene -3-Heptene -3-Methyl-3-hexene -4,4-Dimethyl-2-pentene-1,2-Dimethylcyclopentane-1,3-Dimethylcyclopentane -105.3 -165.3 -170.1 -72.6 269.2 -129.5 -135.8 -2-Methylcyclohexanol -3-Methylcyclohexanol, (±)-4-Methylcyclohexanol -416.1 -350.9 Isobutyl 2-chloropropanoateButyl 3-chloropropanoate Isobutyl 3-chloropropanoatePropyl 2-chlorobutanoate 1-Heptene cis trans cis trans 5-Methyl-1-hexene cis trans 2,4-Dimethyl-1-pentene 4,4-Dimethyl-1-pentene 2,4-Dimethyl-2-pentene cis trans 2-Ethyl-3-methyl-1-butene 2,3,3-Trimethyl-1-butene Cycloheptane Methylcyclohexane -603.1Ethylcyclopentane 1,1-Dimethylcyclopentane -572.6cis trans cis trans 1,1,2,2-Tetramethylcyclopropane1,2-Dibromoheptane -549.6 -517.3 Heptanoic acid -119.8 Heptanenitrile 1-Heptanal 2-Heptanone 3-Heptanone 4-Heptanone 2,2-Dimethyl-3-pentanone 2,4-Dimethyl-3-pentanone cis trans cis trans cis trans 2 2 2 2 2 2 ClO ClO ClO ClO N Br O O O O O O O O O O O O O 13 13 13 13 13 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C C

5-50 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 166.3 156.5 -717.9 -696.3 261.0 248.5 249.0 -12.3-25.4 183.2 183.0 29.9 17.3 -24.4-24.4 186.1 181.5 19.1 18.0 -26.2 22.7 103.8334.4 182.0 147.9 -218.4 -167.8 -553.0-571.0-540.2-224.2-229.5-226.4-224.9-238.3-233.1-234.6 -505.9 323.3-234.2 -527.0 -236.5 314.5 222.9 224.7 -492.2 300.3 -194.5 219.6-574.2 -187.6 303.2 221.1-538.9 -189.5 292.2 -205.7 224.2 -191.3 -201.6 213.5 -198.7 -204.4 -201.0 -506.9 -343.5 221.3 -287.9 -142.5 -86.7 -403.3-392.8-200.5 272.1 -336.5 -358.1 -149.9 -208.8-214.3 -145.2 -146.1 -Butyl isopropyl ether -Indole-2,3-dione -268.2 -Indole 86.6 -Toluic acid-Toluic -Xylene -426.1 163.6 -Methylglucoside -1233.3 H acid-Toluic acid-Toluic -Xylene -Xylene -416.5 -429.2 174.9 169.0 H erephthalic acid -816.1 Pentyl acetate Isopentyl acetate Ethyl pentanoate Ethyl 3-methylbutanoate Ethyl 2,2-dimethylpropanoateMethyl hexanoate a Heptane 2-Methylhexane 3-Methylhexane 3-Ethylpentane 2,2-Dimethylpentane 2,3-Dimethylpentane 2,4-Dimethylpentane 3,3-Dimethylpentane 2,2,3-Trimethylbutane 1,7-Heptanediol 2,2-Diethoxypropane Phthalic anhydride1 Phthalic acidIsophthalic acid -577.2T Styrene o -460.1m p Methyl benzoate -782.0 -803.0 Methyl salicylate 180.0 -536.0 1,7-Octadiyne Ethylbenzene 160.0o m 207.9p 188.1 -371.4 Benzo[b]thiophenePhenyl vinyl ether Acetophenone 100.6 1-Heptanol tert 1-Heptanethiol 2-Ethylphenol 3-Ethylphenol 4-Ethylphenol -224.4 206.9 -144.1 2 2 2 2 2 2 2 6 2 2 3 4 4 4 2 2 2 2 3 O O O O O O O Br 1-Bromoheptane O O O O S O O O O NO O O O S N1 O O O O O O O NO Acetanilide -209.4 179.3 14 14 14 14 14 14 14 15 16 16 16 16 16 16 16 16 16 16 16 16 16 16 4 5 6 6 6 6 7 8 8 8 8 8 8 8 8 9 10 10 10 10 10 10 10 10 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-51 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° H f -307.6 -157.2 -161.6 -162.1 -157.3 -162.4 kJ/mol p 283.7 252.6 238.9 C J/mol K ° S J/mol K Liquid ° G f kJ/mol 8.2 56.3 ° 46.0 100.5 -64.5 -24.1 -39.2 -38.9 140.7 124.3 166.5 H f -290.3-103.5 -223.3 -124.5-135.7-135.7-126.4 -59.5 -145.9-142.4-167.7-212.1 241.0-218.7 239.0 239.0 -81.3 280.9 267.2 -89.3 211.8 209.2 -110.5 -171.5 -104.9 -180.9 -124.4 -228.7-152.6 -163.8 228.5 -101.6 -107.3 -50.5 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -1,2-Divinylcyclobutane-2-Octene -2,2-Dimethyl-3-hexene 101.3-1,2-Dimethylcyclohexane-1,3-Dimethylcyclohexane-1,4-Dimethylcyclohexane 143.5 -144.9 -218.2 -215.7 -222.4 -107.7 273.2 276.3 209.4 268.0 -179.9 212.8 -176.5 210.2 -184.5 -Dimethylaniline -1,2-Divinylcyclobutane -2-Octene -2,2-Dimethyl-3-hexene -1,2-Dimethylcyclohexane-1,3-Dimethylcyclohexane-1,4-Dimethylcyclohexane -211.8 -222.9 -215.6 274.1 272.6 210.2 271.1 -172.1 209.4 -184.6 212.1 -176.6 -Ethylaniline 1,2-Dimethoxybenzene 1-Octen-3-yne cis trans 2,2'-Azobis[isobutyronitrile]2,2,4,4-Tetramethyl-1,3-cyclobutanedioneEthylidenecyclohexane Allylcyclopentane AtrazineButanoic anhydride -379.9 3-Methylbutyl 2-chloropropanoate3-Methylbutyl 3-chloropropanoate 228.9 1-Octene cis trans cis trans 3-Ethyl-2-methyl-1-pentene2,4,4-Trimethyl-1-pentene 2,4,4-Trimethyl-2-pentene -125.4 Cyclooctane Ethylcyclohexane 1,1-Dimethylcyclohexane cis trans cis trans cis trans -627.3 -593.4 -137.9 -575.0 -539.4 -100.3 2,3-Xylenol2,4-Xylenol 2,5-Xylenol2,6-Xylenol3,4-Xylenol3,5-XylenolBenzeneethanol Ethoxybenzene N N,N 2,4-Dimethylaniline -241.1 2,5-Dimethylaniline 2,6-Dimethylaniline -246.6 -237.4 -242.3 -244.4 Octanenitrile 5 2 2 2 4 2 3 O O O O O O O O O N N N N N N O ClN O ClO ClO N 10 10 10 10 10 10 10 10 10 11 11 11 11 11 12 12 12 12 12 14 14 14 14 15 15 15 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C C

5-52 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -362.7 -291.9 365.4 282.8 273.3 330.1 -40.1 9.2 -252.3 362.6 250.2 -212.5 -245.1-291.3 -189.3 -238.9 -188.8 310.8 216.3 -147.7 -636.0-635.1-587.4-583.0-592.2-567.1 297.9-250.1-255.0 -554.3 -251.6 -559.5 -250.4-261.9 285.1 -542.9 -252.6 -533.6 356.4-257.0 -515.5 -544.9 -260.4 252.0-257.5 254.6-251.8 -215.3 -249.6 -208.5 -252.8 251.1-256.9-259.2 -211.9 -253.5-255.0 -210.7 249.2 -224.5 246.6 -213.8 -222.5 -219.2 -219.9 329.3 -212.8 239.1 -211.0 247.3 245.6 -214.8 -224.0 -220.0 -217.3 -216.3 -348.5 -299.6 -426.5-432.8-377.9-401.5-399.6-409.1 347.0 305.2 317.5 -355.6 -365.3 278.2 -332.8 276.1 -362.0 -360.6 -369.0 ) S -butyl ether -butyl ether -1-Ethyl-2-methylcyclopentane-1-Ethyl-3-methylcyclopentane -195.1 -196.0 -156.2 sec tert -Butyl isobutyl ether -1-Ethyl-2-methylcyclopentane-1-Ethyl-3-methylcyclopentane -190.8 -194.4 Propylcyclopentane 1-Ethyl-1-methylcyclopentanecis trans cis trans Octanoic acid 2-Ethylhexanoic acid Hexyl acetate Isobutyl isobutanoate Propyl pentanoate Isopropyl pentanoate Methyl heptanoate Octane 2-Methylheptane 3-Methylheptane, ( -193.8 4-Methylheptane 3-Ethylhexane 2,2-Dimethylhexane 2,3-Dimethylhexane 2,4-Dimethylhexane 2,5-Dimethylhexane 3,3-Dimethylhexane 3,4-Dimethylhexane 3-Ethyl-2-methylpentane 3-Ethyl-3-methylpentane 2,2,3-Trimethylpentane 2,2,4-Trimethylpentane 2,3,3-Trimethylpentane 2,3,4-Trimethylpentane 2,2,3,3-TetramethylbutaneAzobutane -269.0 273.7 239.2 -226.0 Octanal 2-Ethylhexanal 2-Octanone 2,2,4-Trimethyl-3-pentanone -381.61-Octanol 2-Octanol 2-Ethyl-1-hexanol Dibutyl ether Di- -338.3 Di- tert 2 2 2 2 2 2 2 2 O O O O O O O O O O O BrClNO 1-Bromooctane 1-Chlorooctane Octanamide -473.2 N O O O O O O O 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 17 17 17 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-53 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° -25.5 H f kJ/mol p 287.8 298.1 354.9 341.4 246.0 148.5 C J/mol K ° 533.1 364.4 S J/mol K Liquid ° G f kJ/mol ° 11.5 234.4 190.2 60.3 52.7 464.6 307.4 109.6 -38.3-41.1-46.4-48.7-49.8-58.5 287.8-61.8-63.4 214.7 210.7 7.9 267.9 216.4 4.0 215.0 1.3 -9.5 -1.8 209.3 -3.2 -13.8 -15.9 110.6100.3 215.3 186.9 163.4 150.5 141.2144.3 216.0 196.2 204.6 200.5 H f -981.7 428.8 -883.0 -693.1 -625.3 -222.9-255.2 -160.6 -201.0 -220.7-220.7-232.6-229.2 405.1-206.0-218.5 284.3 -167.7 -167.7 -188.8 292.9 -180.5 -156.6 -179.2 -233.7-252.5 -182.2 -196.0 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -butyl sulfide -butyl disulfide -butyl sulfide tert sec tert -Phenylalanine-Tyrosine -466.9 -685.1 213.6 203.0 214.0 216.4 -312.9 etraethylene glycol oluene-2,4-diisocyanate Dibutyl sulfite 1,8-Octanediol2,5-Dimethyl-2,5-hexanediolDiethylene glycol monobutyl ether Diethylene glycol diethyl ether T -681.7 Dibutyl disulfide Di- -626.6 T Indene 2-(Acetyloxy)benzoic acidCyclopropylbenzene Indan 2,2'-DipyrrolylmethaneEthyl benzoate Benzyl acetate L L -815.6 Propylbenzene Isopropylbenzene 2-Ethyltoluene 3-Ethyltoluene 4-Ethyltoluene 126.2 1,2,3-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Quinoline Isoquinoline Diuron -329.0 Dibutyl sulfide Di- Di- Diisobutyl sulfide Dibutylamine Diisobutylamine 2-Isopropylphenol 3-Isopropylphenol O 2 2 2 3 N S Si Ethyl silicate 2 2 2 3 3 3 5 4 O 2 2 2 2 2 2 4 O O O O O O S S S S S S N N BrNO PbSi bromide Tetraethylammonium lead Tetraethyl Tetraethylsilane -342.7 Cl N O O NO NO O O N N N NONOO 2-Quinolinol 8-Quinolinol -144.9 82.1 18 18 18 18 18 18 18 18 18 18 18 18 19 19 20 20 20 20 6 7 7 7 7 8 8 10 10 10 10 10 10 11 11 12 12 12 12 12 12 12 12 12 12 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C C C C C C C

5-54 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -212.1 -273.4 -560.2 253.5 16.3 62.3 -171.8 -207.1 -161.0 -237.4-659.7 311.9-624.2 242.0-620.0-590.3 -192.3 -274.7-288.1 -282.7 362.4-282.8 -293.3 -577.3 -281.1 -284.0-280.2 -573.2 -277.5 -568.6 -275.4 284.4 -533.9 -228.2 278.2 -242.6 -233.3 -265.9 -209.4 -397.2-398.2-408.5 401.4 303.6 -344.9 297.3 -340.7 -357.6 -453.4 -376.5 -1330.8 458.3 384.7 -1245.0 -1,3,5-Trimethylcyclohexane b ,5 a -Butyl pentanoate ,3 -Butylpiperidine a riacetin ripropylamine etraethylurea -403.0 Isopropylbenzene hydroperoxideEthyl 3,5-dimethylpyrrole-2-carboxylateEthyl 2,4-dimethylpyrrole-3-carboxylateEthyl 2,5-dimethylpyrrole-3-carboxylateEthyl 4,5-dimethylpyrrole-3-carboxylateT -474.5 -463.2 1-Nonyne -478.7 Nonanedioic acid -470.3 Propylcyclohexane 1 Nonanoic acid Butyl pentanoatesec Isobutyl pentanoate -1054.3 Methyl octanoate -148.3Nonane 2,2-Dimethylheptane 2,2,3-Trimethylhexane 2,2,4-Trimethylhexane 2,2,5-Trimethylhexane -613.3 2,3,3-Trimethylhexane 2,3,5-Trimethylhexane 2,4,4-Trimethylhexane 3,3,4-Trimethylhexane 3,3-Diethylpentane 3-Ethyl-2,2-dimethylpentane -78.4 3-Ethyl-2,4-dimethylpentane2,2,3,3-Tetramethylpentane2,2,3,4-Tetramethylpentane2,2,4,4-Tetramethylpentane2,3,3,4-Tetramethylpentane1,9-Nonanediol2-Quinolinecarbonitrile3-Quinolinecarbonitrile -657.6 246.5 242.3 -272.7 -269.7 -278.3 -277.7 -280.0 -277.9 271.5 -237.1 266.3 -241.6 -236.9 -236.1 4-Isopropylphenol Isophorone 3-Ethyl-2,4,5-trimethylpyrrole2-Nonanone 5-Nonanone -89.2 2,6-Dimethyl-4-heptanone N 2,2,6,6-Tetramethylpiperidine1-Nonanol -206.9 -159.9 2 2 2 2 OT 2 6 4 2 2 2 2 2 2 2 2 2 O O NO NO NO NO O O N O NOO O O 2,2,6,6-Tetramethyl-4-piperidinoneO O O O O N -334.2 N N O O NT N N 6 6 12 12 13 13 13 13 14 14 15 16 16 17 18 18 18 18 18 18 18 18 18 18 19 19 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 21 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 10 10 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-55 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° -20.6 111.2 289.1 235.1 132.8 134.3 137.4 H f -218.5 kJ/mol p 303.1 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -7.7 38.7 71.6 84.2 54.6 212.6 119.8 -63.2-71.9-69.8 321.2 243.4-73.5 -11.8 -23.0 -21.9 -50.8 249.4 -2.6 -66.4-68.5 -72.8 -18.4 -54.5 249.0 -16.4 28.3 161.5 233.8 H f -124.1 -29.9 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -Butylbenzene, (±) -Butylbenzene -Diethylbenzene -Pinene -Terpinene -Pinene -Diethylbenzene -Diethylbenzene -Limonene 1,5-Dinitronaphthalene1,8-Dinitronaphthalene1-NitronaphthaleneNaphthaleneAzulene 29.8 39.7 1,2-Dihydronaphthalene 1,4-Dihydronaphthalene Dimethyl phthalate 42.6 Dimethyl isophthalateDimethyl terephthalate1,2,3,4-Tetrahydronaphthalene 78.5Butylbenzene sec 212.3 201.6tert Isobutylbenzene 167.41-Isopropyl-2-methylbenzene1-Isopropyl-3-methylbenzene 165.71-Isopropyl-4-methylbenzene -730.9 o -732.6m p 3-Ethyl-1,2-dimethylbenzene4-Ethyl-1,2-dimethylbenzene2-Ethyl-1,3-dimethylbenzene2-Ethyl-1,4-dimethylbenzene1-Ethyl-2,4-dimethylbenzene1-Ethyl-3,5-dimethylbenzene1,2,4,5-Tetramethylbenzene 261.1 Dipentene d a -29.2b 150.6a 224.1 -119.9 -73.3 333.1 -78.6 -78.0 131.9 245.6 217.5 215.1 -80.5 26.0 -86.0 -80.1 -84.8 -84.1 236.4 -87.8 1-Tetralone -209.6 Thymol -309.7 1-Iodonaphthalene 2-Iodonaphthalene1-Naphthol2-Naphthol 1-Naphthylamine2-Naphthylamine 144.3 -121.5 67.8 60.2 166.9 -30.4 4 4 2 O O 4 4 4 2 2 O O O O O N N ClClI I NO 1-Chloronaphthalene 2-ChloronaphthaleneO O N N 55.4 6 6 7 7 7 7 7 8 8 8 8 9 9 10 10 10 10 10 10 12 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 16 16 16 16 16 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C C C

5-56 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES 83.4 -67.2 328.8 205.1 -921.9 -223.1 -232.5 418.4 350.0 344.9 250.0 379.0 56.3 254.8 224.4 14.5 -53.6 -1.6 -163.6 -178.9 -219.4-173.8 265.0-263.1 232.0-616.2-351.5 425.0 -169.2 -300.9-309.8 345.0 300.8-307.9 -123.3 271.0 -213.7 420.1 423.8 313.3 314.4 314.4 -554.2 -260.2 -249.5 -258.6 -244.5-640.5-327.2 344.9 -188.3 -270.8 -573.8 -158.4-478.1 -91.5 -266.4-281.8-232.8 370.6 -396.6 -204.9 -221.5 -504.8 -butylethene tert -2,6-Dimethyl-2,4,6-octatriene -24.0 -Butyl-3-methylbenzene-Butyl-4-methylbenzene -109.7 -109.7 -57.0 -Decahydronaphthalene -230.6 264.9 228.5 -182.1 cis , -Decahydronaphthalene -1,2-Di- tert tert -Myrcene -Tryptophan -415.3 251.0 238.1 ris(perfluorobutyl)amine b cis Ethylenediaminetetraacetic acid1,1'-Bicyclopentyl cis trans Sebacic acid -1759.5 1-Decene cis Butylcyclohexane Decanoic acidMethyl nonanoate 1-Nitrodecane Decane 2-Methylnonane 5-Methylnonane -1082.6 1,10-DecanediolEthylene glycol dibutyl ether -713.71-Naphthalenecarboxylic acid2-Naphthalenecarboxylic acid1-Methylnaphthalene 2-MethylnaphthaleneL -678.9 1,1-Dimethylindan 1- 1- -333.5 Pentamethylbenzene -346.1 -684.3Spiro[5.5]undecane 1-Undecene Methyl decanoate Undecane 44.9AcenaphthylenePhenazine -144.6 220.0 196.0 -594.9 186.7 237.0 166.4 106.7 259.7 Camphor, (±)Camphor, Decanenitrile -319.41-Decanol Dipentyl ether Diisopentyl ether 1-Decanethiol 271.2Dipentyl sulfide Diisopentyl sulfide Octyldimethylamine -309.9 -267.5 1-Undecanol -276.5 476.1 350.4 -211.5 DibenzofuranDibenzothiophene 120.0 -5.3 8 2 2 O O 2 4 2 2 2 2 2 2 2 2 2 N O O N O O NO O O O O O S S S N N O O NT O O N O S 16 16 16 16 18 18 18 18 19 20 20 20 20 20 21 22 22 22 22 22 22 22 22 22 22 22 23 8 8 10 10 12 14 16 16 16 20 22 22 24 24 8 8 8 8 27 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H F H H H H 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 11 11 11 11 11 11 11 11 11 11 11 11 11 11 12 12 12 12 12 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-57 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 286.0 219.3 184.4 200.7 273.9 240.5 233.7 342.0 201.0 H f -976.9 kJ/mol p 379.4 452.0 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° -76.6 -16.7 197.8 181.5 H f -344.7-392.3-281.6 -269.9 -321.1 -776.6 425.1-273.7 366.1 -688.4 -226.2-665.2 484.8-350.9 360.7 -215.7 -165.4 -593.8 375.8 -289.4 -528.5 438.1 -436.6 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f kJ/mol -carbazole 105.5 H -Butyl-3,5-dimethylbenzene -146.5 -Azoxybenzene 243.4 -Lactose -2236.7 -Fluorene 89.9 207.3 203.1 175.0 173.1 D tert -Lactose monohydrate -2484.1 -Nitrosodiphenylamine 227.2 - -Benzidine 70.7 H ributylamine ributyl phosphate trans N ThianthreneAcenaphtheneBiphenyl1-Naphthaleneacetic acid2-Naphthaleneacetic acidp 182.0 Diethyl phthalate 70.3Cyclohexylbenzene Diethyl 3,5-dimethylpyrrole-2,4-dicarboxylate -359.2 3,9-Dodecadiyne 99.4 -371.9 5,7-Dodecadiyne 1- -916.7 Hexamethylbenzene 188.9Cyclohexylcyclohexane Dodecanedioic acid 190.4 209.4Sucroseb 198.41-Dodecene Dodecanoic acidMethyl undecanoate a -162.4Dodecane -1130.0 Diethylene glycol dibutyl ether -2226.1 306.3Xanthone -774.6 245.6 156.0 9 9-Acridinamine 181.4 404.3 -737.9 -191.5 159.2 -77.4 -642.0 Diphenyl etherDiphenylamine2-Aminobiphenyl4-Aminobiphenyl -32.1 130.2 93.8 81.0 233.9 216.6 -14.91-Dodecanol 52.0 Benzophenone9-Methyl-9 -34.5 224.8 54.9 Carbazole 101.7 AcridinePhenanthridineBenzo[f]quinoline 141.9 150.6 179.4 4 O O PT 2 2 2 2 2 4 4 11 11 2 2 12 3 4 2 2 2 N N O O O N N N N O NO O O O O O O BrClO O NT 1-Bromododecane O 1-Chlorododecane N O N S N O N N N 8 9 10 10 10 10 10 10 10 11 11 11 12 14 16 17 18 18 18 18 22 22 22 22 24 24 24 24 25 25 26 26 26 27 27 8 9 9 9 10 10 10 11 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 13 13 13 13 13 13 13 13 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C C C

5-58 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES -75.7 -46.6 -55.5 142.9 236.1 -471.7 -281.7 -296.9 406.7 391.8 48.7 183.3 252.3 -260.2 -174.9 -444.5 -350.2 -693.0 -614.9 -188.8 -717.9-367.3 -743.9-842.6 -635.3 -218.3-328.7-771.0-456.1 -656.9 587.9 488.9 -750.9 -248.4 -138.6 501.6 -680.0 -374.8 -butylbenzene -butylbenzene-butyl-5-methylbenzene -212.0 -245.8 -butyl-4-methylphenol -410.0 tert tert tert tert -Stilbene 136.9 -Glucose pentaacetate -2249.4 -Glucose pentaacetate -2232.6 -Stilbene D D - -Benzylaniline 101.4 - ridecanedioic acidridecane -1148.3 etradecanoic acid -833.5 432.0 -788.8 -693.7 etradecanenitrile Diphenylmethane4,4'-DiaminodiphenylmethaneT 1-Tridecene Methyl dodecanoate T 9,10-Anthracenedione9,10-Phenanthrenedione1,4-Dihydroxy-9,10-anthracenedioneAnthracene 71.5PhenanthreneDiphenylacetyleneBenzilBenzoyl peroxide -595.8 cis 239.3trans -188.5 -154.7 1,1-Diphenylethane 1,2-Diphenylethane1,3-Di- 270.9 1,4-Di- Pentetic acid 89.7 129.2 312.4 116.2T Methyl tridecanoate -369.4 2,2-Bis(4-hydroxyphenyl)propane -153.9 1,3-Di- 207.5 215.1 51.5 Decylcyclopentane 210.5Pentadecanoic acid 220.6Methyl tetradecanoate 225.9 -2225.2 -368.6 FluoranthenePyrene 139.0 Dibutyl phthalate a b Decylbenzene 1-Hexadecene Hexadecanoic acid -861.7Methyl pentadecanoate Hexadecane 189.9 230.9 207.5 125.5 443.3 -891.5 230.6 -811.7 230.2 224.9 229.7 452.4 460.7 -838.1 -699.0 289.0 225.7 -737.1 N 1-Tridecanol -599.4 1-Tetradecanol2,6-Di- 1-Pentadecanol -629.6 -658.2 1-Hexadecanol 388.0 -580.6 -686.5 422.0 -517.0 10 O 2 4 2 2 4 3 2 2 2 2 2 4 11 11 2 2 2 2 4 N N O O O O O N NT O O O O O O O O O O O O O BrO 1-Bromohexadecane O O O 12 13 14 24 26 26 28 28 8 8 8 10 10 10 10 10 12 12 14 14 22 22 23 27 28 28 30 16 24 24 30 30 30 32 10 10 22 22 22 26 32 32 32 33 34 34 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 13 13 13 13 13 13 13 13 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 15 15 15 15 15 15 15 16 16 16 16 16 16 16 16 16 16 16 16 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C

5-59 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL SUBSTANCES p 254.8 283.9 C J/mol K ° S J/mol K Gas ° G f kJ/mol ° 293.0 269.8 465.6 454.3 326.8 H f kJ/mol p 577.0 619.0 704.7 C J/mol K ° S J/mol K Liquid ° G f kJ/mol ° H f -544.1-433.0 -446.0 -585.0 -734.5-775.8 -816.9 -649.9 -713.5-716.0-848.0-968.3 -587.6 -593.4 -705.8 -697.2 kJ/mol p C J/mol K ° S J/mol K Crystal ° G f kJ/mol ° H f 2327.02555.0 2302.0 2537.0 426.0 464.0 520.0 650.0 2502.0 2755.0 2442.0 2692.0 544.0 614.0 512.0 585.0 kJ/mol ) ) 60 70 -butylbenzene -320.0 -9-octadecenoate -737.0 -9-octadecenoate -773.3 tert trans trans -13-Docosenoic acid -960.7 -cresyl phosphate 570.0 578.0 o -Terphenyl-Terphenyl 163.0 285.6 298.8 278.7 274.8 337.1 369.1 279.0 riphenylamineriphenylphosphinerihexylamine riphenylmethanol 234.7 -2.5 312.5 rioctylamine riphenyl phosphate 397.5ri- 356.2 Heptadecanoic acidBenz[a]anthraceneChryseneo p 1,3,5-Tri- Oleic acid -924.4Dibutyl sebacate Stearic acid 170.8 Octadecane 145.3 Methyl oleate Methyl PeryleneBenzo[a]pyrene 475.7Diphenyl phthalate -865.6 Ethyl oleate Ethyl -947.7Eicosanoic acid -567.4Dibenz[a,h]anthracene trans Butyl oleate Butyl stearate Bis(2-ethylhexyl) phthalate -489.2 480.2 182.89,10-Diphenylanthracene 501.55-Butyldocosane 485.611-Butyldocosane -1011.9 -884.79,9'-Bianthracene11-Decylheneicosane Dotriacontane 264.6Carbon (fullerene-C Carbon (fullerene-C 274.9 308.7 545.1 -940.0 326.2 -781.2 -414.6 -812.4 PT PT 2 4 2 4 2 2 2 4 2 2 2 4 2 2 2 4 INO iodide Tetrabutylammonium NT O PT O O O Cl -498.6 NT OT O O 1-Chlorooctadecane O O O O O O O O O NT 36 34 12 12 14 14 15 15 15 30 34 34 36 37 38 39 16 36 36 12 12 14 38 38 40 21 14 42 42 44 38 51 18 54 54 18 64 66 H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 16 17 18 18 18 18 18 18 18 18 18 18 18 18 18 18 19 19 19 20 20 20 20 20 20 21 22 22 22 22 24 24 26 26 26 28 31 32 60 70 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Molecular Formula Name C C

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