Surface Tension of Refrigerants. Selection of Data and Recommended Correlations.
I. Cachadiña, A. Mulero, and J. Tian
SUPPLEMENTARY MATERIAL.
This supplementary material includes detailed figures for both the surface tension data (points) and correlation (line), as well the percentage deviations for each refrigerant. For R10B1, R114B2, and R1130 no correlation is given, so only the surface tension data are shown. The fluids are ordered as given in Table 1, i.e. by numerical order of the refrigerant number (avoiding letters). Name, CAS number and Refrigerant number are given. The numbers of references are the same as given in the paper. The data that have not considered in the fit procedure are grey colored.
[CARBON TETRACHLORIDE,56−23−5, R10] 35 DIPPR32 DETHERM33
30
25
20 (mN/m) σ 15
10
5
0 250 300 350 400 450 5 4 3 2 1 0 −1 PD(%) −2 −3 −4 −5 250 300 350 400 450 T(K) [BROMOTRICHLOROMETHANE,75−62−7, R10B1] 45 DIPPR32 DETHERM33 40
35
30
25 (mN/m)
σ 20
15
10
5
0 250 300 350 400 450 500 550 T(K) [TRICHLOROFLUOROMETHANE,75−69−4, R11] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 150 200 250 300 350 400 450 10 8 6 4 2 PD(%) 0 −2 −4 150 200 250 300 350 400 450 T(K) [DICHLORODIFLUOROMETHANE,75−71−8, R12] 40 DIPPR32 DETHERM33 WW22 35 Ref. 34
30
25
20 (mN/m) σ
15
10
5
0 150 200 250 300 350 400 14 12 10 8 6 4 2 PD(%) 0 −2 −4 −6 150 200 250 300 350 400 T(K) [BROMOCHLORODIFLUOROMETHANE,353−59−3, R12B] 30 DIPPR32 WW22
25
20
15 (mN/m) σ
10
5
0 200 250 300 350 400 1 0.5 0 −0.5 PD(%) −1 −1.5 200 250 300 350 400 T(K) [DIBROMODIFLUOROMETHANE,75−61−6, R12B2] 30 DIPPR32 DETHERM33
25
20
15 (mN/m) σ
10
5
0 250 300 350 400 2 1.5 1 0.5 0 −0.5 −1 PD(%) −1.5 −2 −2.5 −3 250 300 350 400 T(K) [CHLOROTRIFLUOROMETHANE,75−72−9, R13] 35 DIPPR32 DETHERM33 WW22 30
25
20 (mN/m) σ 15
10
5
0 100 150 200 250 8 6 4 2 0 PD(%) −2 −4 −6 100 150 200 250 T(K) [BROMOTRIFLUOROMETHANE,75−63−8, R13B1] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 100 150 200 250 300 350 20 15 10 5
PD(%) 0 −5 −10 100 150 200 250 300 350 T(K) [CARBON TETRAFLUORIDE,75−73−0, R14] 30 DIPPR32 DETHERM33
25
20
15 (mN/m) σ
10
5
0 100 120 140 160 180 200 3 2 1 0 −1 PD(%) −2 −3 −4 100 120 140 160 180 200 T(K) [CHLOROFORM,67−66−3, R20] 35 DIPPR32 DETHERM33
30
25
20 (mN/m) σ 15
10
5
0 250 300 350 400 450 500 2.5 2 1.5 1 0.5 PD(%) 0 −0.5 −1 250 300 350 400 450 500 T(K) [TRIBROMOMETHANE,75−25−2, R20B3] 50 DIPPR32 DETHERM33 45
40
35
30
25 (mN/m) σ 20
15
10
5
0 300 350 400 450 500 550 600 1 0.8 0.6 0.4 0.2
PD(%) 0 −0.2 −0.4 −0.6 300 350 400 450 500 550 600 T(K) [DICHLOROFLUOROMETHANE,75−43−4, R21] 50 DIPPR32 DETHERM33 22 45 WW
40
35
30
25 (mN/m) σ 20
15
10
5
0 150 200 250 300 350 400 450 10 8 6 4 2 0 −2 PD(%) −4 −6 −8 −10 150 200 250 300 350 400 450 T(K) [CHLORODIFLUOROMETHANE,75−45−6, R22] 45 DIPPR32 DETHERM33 WW22 40 Ref. 34
35
30
25 (mN/m)
σ 20
15
10
5
0 100 150 200 250 300 350 25 20 15 10 5
PD(%) 0 −5 −10 −15 100 150 200 250 300 350 T(K) [BROMODIFLUOROMETHANE,1511−62−2, R22B1] 50 DIPPR32 DETHERM33 45
40
35
30
25 (mN/m) σ 20
15
10
5
0 150 200 250 300 350 0.5 0 −0.5 −1 PD(%) −1.5 −2 150 200 250 300 350 T(K) [TRIFLUOROMETHANE,75−46−7, R23] 35 DIPPR32 DETHERM33 WW22 30
25
20 (mN/m) σ 15
10
5
0 150 200 250 300 30 25 20 15 10 PD(%) 5 0 −5 150 200 250 300 T(K) [DICHLOROMETHANE,75−09−2, R30] 35 DIPPR32 DETHERM33
30
25
20 (mN/m) σ 15
10
5
0 250 300 350 400 450 2 1.5 1 0.5 0 PD(%) −0.5 −1 −1.5 250 300 350 400 450 T(K) [DIBROMOMETHANE,74−95−3, R30B2] 60 DIPPR32 DETHERM33 WW22
50
40
30 (mN/m) σ
20
10
0 200 250 300 350 400 450 500 550 14 12 10 8 6 4 PD(%) 2 0 −2 −4 200 250 300 350 400 450 500 550 T(K) [CHLOROFLUOROMETHANE,593−70−4, R31] 70 DIPPR32
60
50
40 (mN/m) σ 30
20
10
0 150 200 250 300 350 0.1 0.08 0.06 0.04 0.02 0 −0.02
PD(%) −0.04 −0.06 −0.08 −0.1 −0.12 150 200 250 300 350 T(K) [DECAFLUOROBUTANE,355−25−9, R31−10] 20 DIPPR32 DETHERM33 18
16
14
12
10 (mN/m) σ 8
6
4
2
0 200 220 240 260 280 300 320 340 0.5 0 −0.5 −1
PD(%) −1.5 −2 −2.5 200 220 240 260 280 300 320 340 T(K) [DIFLUOROMETHANE,75−10−5, R32] 25 DIPPR32 DETHERM33 WW22
20
15 (mN/m) σ 10
5
0 220 240 260 280 300 320 340 10 5 0 −5 PD(%) −10 −15 220 240 260 280 300 320 340 T(K) [METHYL CHLORIDE,74−87−3, R40] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 200 250 300 350 7 6 5 4 3 2 1 PD(%) 0 −1 −2 −3 200 250 300 350 T(K) [BROMOMETHANE,74−83−9, R40B1] 45 DIPPR32 DETHERM33 40
35
30
25 (mN/m)
σ 20
15
10
5
0 200 250 300 350 400 7 6 5 4 3 2 PD(%) 1 0 −1 −2 200 250 300 350 400 T(K) [METHYL FLUORIDE,593−53−3, R41] 30 DIPPR32
25
20
15 (mN/m) σ
10
5
0 120 140 160 180 200 220 240 260 280 0.8 0.6 0.4 0.2 0 PD(%) −0.2 −0.4 −0.6 120 140 160 180 200 220 240 260 280 T(K) [HEXACHLOROETHANE,67−72−1, R110] 30 DIPPR32
25
20
15 (mN/m) σ
10
5
0 460 480 500 520 540 560 580 600 620 0.2 0.15 0.1 0.05
PD(%) 0 −0.05 −0.1 460 480 500 520 540 560 580 600 620 T(K) [PENTACHLOROFLUOROETHANE,354−56−3, R111] 35 DIPPR32
30
25
20 (mN/m) σ 15
10
5
0 400 450 500 550 1.2 1 0.8 0.6 0.4
PD(%) 0.2 0 −0.2 −0.4 400 450 500 550 T(K) [1,1,2,2−TETRACHLORODIFLUOROETHANE,76−12−0, R112] 30 DIPPR32 DETHERM33 WW22
25
20
15 (mN/m) σ
10
5
0 300 350 400 450 500 550 6 5 4 3 2 1 0 PD(%) −1 −2 −3 −4 300 350 400 450 500 550 T(K) [1,1,1,2−TETRACHLORODIFLUOROETHANE,76−11−9, R112A] 35 DIPPR32
30
25
20 (mN/m) σ 15
10
5
0 300 350 400 450 500 2 1.5 1 0.5 PD(%) 0 −0.5 300 350 400 450 500 T(K) [1,1,2−TRICHLOROTRIFLUOROETHANE,76−13−1, R113] 30 DIPPR32 DETHERM33 WW22 Ref. 35 25
20
15 (mN/m) σ
10
5
0 250 300 350 400 450 12 10 8 6 4 2 0 PD(%) −2 −4 −6 −8 250 300 350 400 450 T(K) [1,1,1−TRICHLOROTRIFLUOROETHANE,354−58−5, R113A] 30 DIPPR32 WW22
25
20
15 (mN/m) σ
10
5
0 280 300 320 340 360 380 400 420 440 1.6 1.4 1.2 1 0.8 0.6 0.4 PD(%) 0.2 0 −0.2 −0.4 280 300 320 340 360 380 400 420 440 T(K) [1,2−DICHLOROTETRAFLUOROETHANE,76−14−2, R114] 30 DIPPR32 DETHERM33 WW22 Ref. 35 25
20
15 (mN/m) σ
10
5
0 200 250 300 350 400 20 15 10 5
PD(%) 0 −5 −10 200 250 300 350 400 T(K) [1,1−DICHLOROTETRAFLUOROETHANE,374−07−2, R114A] 35 DIPPR32
30
25
20 (mN/m) σ 15
10
5
0 220 240 260 280 300 320 340 360 380 2.5 2 1.5 1 0.5
PD(%) 0 −0.5 −1 −1.5 220 240 260 280 300 320 340 360 380 T(K) [1,2−DIBROMOTETRAFLUOROETHANE,124−73−2, R114B2] 35 DIPPR32 DETHERM33 WW22 30
25
20 (mN/m) σ 15
10
5
0 200 250 300 350 400 450 500 T(K) [CHLOROPENTAFLUOROETHANE,76−15−3, R115] 25 DIPPR32 DETHERM33 WW22
20
15 (mN/m) σ 10
5
0 200 250 300 350 4 3 2 1 0 −1 −2
PD(%) −3 −4 −5 −6 −7 200 250 300 350 T(K) [HEXAFLUOROETHANE,76−16−4, R116] 18 DIPPR32 DETHERM33 Ref. 36 16
14
12
10 (mN/m)
σ 8
6
4
2
0 180 200 220 240 260 280 3 2 1 0
PD(%) −1 −2 −3 180 200 220 240 260 280 T(K) [PENTACHLOROETHANE,76−01−7, R120] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 300 350 400 450 500 0.8 0.7 0.6 0.5 0.4 0.3 0.2
PD(%) 0.1 0 −0.1 −0.2 −0.3 300 350 400 450 500 T(K) [2,2−DICHLORO−1,1,1−TRIFLUOROETHANE,306−83−2, R123] 25 DIPPR32 DETHERM33
20
15 (mN/m) σ 10
5
0 260 280 300 320 340 360 380 400 420 3.5 3 2.5 2 1.5 1 PD(%) 0.5 0 −0.5 −1 260 280 300 320 340 360 380 400 420 T(K) [1,2−DICHLORO−1,1,2−TRIFLUOROETHANE,354−23−4, R123A] 18 DIPPR32 Ref. 37 16
14
12
10 (mN/m)
σ 8
6
4
2
0 300 320 340 360 380 400 420 440 460 1.5 1 0.5 0 −0.5 PD(%) −1 −1.5 −2 300 320 340 360 380 400 420 440 460 T(K) [2,2−DICHLORO−1,1,2−TRIFLUOROETHANE,812−04−4, R123B] 45 DIPPR32
40
35
30
25 (mN/m)
σ 20
15
10
5
0 200 250 300 350 400 1.5 1 0.5 0 PD(%) −0.5 −1 200 250 300 350 400 T(K) [2−CHLORO−1,1,1,2−TETRAFLUOROETHANE,2837−89−0, R124] 14 DIPPR32 DETHERM33 Ref. 23 12
10
8 (mN/m) σ 6
4
2
0 280 300 320 340 360 380 400 3 2.5 2 1.5 1 0.5 PD(%) 0 −0.5 −1 −1.5 280 300 320 340 360 380 400 T(K) [PENTAFLUOROETHANE,354−33−6, R125] 16 DIPPR32 DETHERM33 14
12
10
8 (mN/m) σ
6
4
2
0 220 240 260 280 300 320 340 30 25 20 15 10 PD(%) 5 0 −5 220 240 260 280 300 320 340 T(K) [1,1,1−TRICHLOROFLUOROETHANE,2366−36−1, R131B] 80 DIPPR32
70
60
50
40 (mN/m) σ
30
20
10
0 150 200 250 300 350 400 450 500 1 0.5 0 −0.5
PD(%) −1 −1.5 −2 150 200 250 300 350 400 450 500 T(K) [2−CHLORO−1,1,1−TRIFLUOROETHANE,75−88−7, R133A] 45 DIPPR32
40
35
30
25 (mN/m)
σ 20
15
10
5
0 200 250 300 350 400 1.2 1 0.8 0.6 0.4 0.2 0 PD(%) −0.2 −0.4 −0.6 −0.8 200 250 300 350 400 T(K) [1,1,2,2−TETRAFLUOROETHANE,359−35−3, R134] 14 DIPPR32 Ref. 37
12
10
8 (mN/m) σ 6
4
2
0 300 320 340 360 380 1.5 1 0.5 0 −0.5 −1 −1.5 PD(%) −2 −2.5 −3 −3.5 300 320 340 360 380 T(K) [1,1,1,2−TETRAFLUOROETHANE,811−97−2, R134a] 30 DIPPR32 DETHERM33 WW22 Ref. 6 25 Ref. 38
20
15 (mN/m) σ
10
5
0 200 250 300 350 30 25 20 15 10 PD(%) 5 0 −5 200 250 300 350 T(K) [BIS(DIFLUOROMETHYL)ETHER,1691−17−4, RE134] 45 DIPPR32
40
35
30
25 (mN/m)
σ 20
15
10
5
0 150 200 250 300 350 3 2.5 2 1.5 1
PD(%) 0.5 0 −0.5 −1 150 200 250 300 350 T(K) [1,1−DICHLORO−1−FLUOROETHANE,1717−00−6, R141b] 25 DIPPR32 DETHERM33 Ref. 37
20
15 (mN/m) σ 10
5
0 300 350 400 450 6 5 4 3 2
PD(%) 1 0 −1 −2 300 350 400 450 T(K) [1−CHLORO−1,1−DIFLUOROETHANE,75−68−3, R142b] 40 DIPPR32 DETHERM33 WW22 35 Ref. 37
30
25
20 (mN/m) σ
15
10
5
0 150 200 250 300 350 400 8 6 4 2
PD(%) 0 −2 −4 150 200 250 300 350 400 T(K) [1,1,2−TRIFLUOROETHANE,430−66−0, R143] 40 DIPPR32
35
30
25
20 (mN/m) σ
15
10
5
0 200 250 300 350 400 2.5 2 1.5 1 0.5
PD(%) 0 −0.5 −1 −1.5 200 250 300 350 400 T(K) [1,1,1−TRIFLUOROETHANE,420−46−2, R143A] 30 DIPPR32 DETHERM33
25
20
15 (mN/m) σ
10
5
0 160 180 200 220 240 260 280 300 320 340 16 14 12 10 8 6 4 PD(%) 2 0 −2 −4 160 180 200 220 240 260 280 300 320 340 T(K) [1,1−DICHLOROETHANE,75−34−3, R150A] 40 DIPPR32 DETHERM33 35
30
25
20 (mN/m) σ
15
10
5
0 200 250 300 350 400 450 6 5 4 3 2 1 PD(%) 0 −1 −2 −3 200 250 300 350 400 450 T(K) [1,2−DIFLUOROETHANE,624−72−6, R152] 35 DIPPR32
30
25
20 (mN/m) σ 15
10
5
0 200 250 300 350 400 1 0.5 0 −0.5 −1
PD(%) −1.5 −2 −2.5 −3 200 250 300 350 400 T(K) [1,1−DIFLUOROETHANE,75−37−6, R152A] 35 DIPPR32 DETHERM33 WW22 Ref. 37 30
25
20 (mN/m) σ 15
10
5
0 150 200 250 300 350 400 20 15 10 5 0 −5 −10 PD(%) −15 −20 −25 −30 150 200 250 300 350 400 T(K) [ETHYL CHLORIDE,75−00−3, R160] 35 DIPPR32 DETHERM33
30
25
20 (mN/m) σ 15
10
5
0 250 300 350 400 0.3 0.25 0.2 0.15 0.1 PD(%) 0.05 0 −0.05 250 300 350 400 T(K) [ETHYL FLUORIDE,353−36−6, R161] 25 DIPPR32 Ref. 5
20
15 (mN/m) σ 10
5
0 240 260 280 300 320 340 360 380 5 4 3 2 1 0 PD(%) −1 −2 −3 −4 240 260 280 300 320 340 360 380 T(K) [1,3−DICHLOROHEXAFLUOROPROPANE,662−01−1, R216ca] 45 DIPPR32
40
35
30
25 (mN/m)
σ 20
15
10
5
0 150 200 250 300 350 400 3 2.5 2 1.5 1
PD(%) 0.5 0 −0.5 −1 150 200 250 300 350 400 T(K) [OCTAFLUOROPROPANE,76−19−7, R218] 25 DIPPR32 WW22 Ref. 39
20
15 (mN/m) σ 10
5
0 150 200 250 300 350 1.5 1 0.5 0
PD(%) −0.5 −1 −1.5 150 200 250 300 350 T(K) [1,1−Dichloro−2,2,3,3,3−pentafluoropropane,422−56−0, R225ca] 20 DETHERM33
18
16
14
12
10 (mN/m) σ 8
6
4
2
0 270 280 290 300 310 320 330 340 1 0.8 0.6 0.4 0.2 PD(%) 0 −0.2 −0.4 270 280 290 300 310 320 330 340 T(K) [1,3−Dichloro−1,2,2,3,3−pentafluoropropane,507−55−1, R225cb] 20 DETHERM33
18
16
14
12
10 (mN/m) σ 8
6
4
2
0 270 280 290 300 310 320 330 340 0.8 0.6 0.4 0.2 0
PD(%) −0.2 −0.4 −0.6 −0.8 270 280 290 300 310 320 330 340 T(K) [1,1,1,2,3,3,3−HEPTAFLUOROPROPANE,431−89−0, R227EA] 16 DIPPR32 DETHERM33 14
12
10
8 (mN/m) σ
6
4
2
0 240 260 280 300 320 340 360 380 3 2 1 0 −1 PD(%) −2 −3 −4 240 260 280 300 320 340 360 380 T(K) [1,1,1,2,3,3−HEXAFLUOROPROPANE,431−63−0, R236ea] 14 DIPPR32 Ref. 23
12
10
8 (mN/m) σ 6
4
2
0 300 320 340 360 380 400 420 5 0 −5 −10 −15 PD(%) −20 −25 −30 300 320 340 360 380 400 420 T(K) [1,1,1,3,3,3−HEXAFLUOROPROPANE,690−39−1, R236fa] 18 DIPPR32 DETHERM33 Ref. 23 16
14
12
10 (mN/m)
σ 8
6
4
2
0 260 280 300 320 340 360 380 400 2 1 0 −1 −2
PD(%) −3 −4 −5 −6 260 280 300 320 340 360 380 400 T(K) [1,1,1,2,2−PENTAFLUOROPROPANE,1814−88−6, R245] 40 DIPPR32
35
30
25
20 (mN/m) σ
15
10
5
0 150 200 250 300 350 2.5 2 1.5 1 0.5
PD(%) 0 −0.5 −1 −1.5 150 200 250 300 350 T(K) [1,1,2,2,3−PENTAFLUOROPROPANE,679−86−7, R245ca] 20 DIPPR32 Ref. 23 18
16
14
12
10 (mN/m) σ 8
6
4
2
0 300 320 340 360 380 400 420 440 1 0.5 0 −0.5 −1 PD(%) −1.5 −2 −2.5 300 320 340 360 380 400 420 440 T(K) [1,1,1,3,3−PENTAFLUOROPROPANE,460−73−1, R245fa] 25 DIPPR32 DETHERM33 Ref. 23
20
15 (mN/m) σ 10
5
0 260 280 300 320 340 360 380 400 420 1.5 1 0.5 0 −0.5 −1 −1.5 PD(%) −2 −2.5 −3 −3.5 260 280 300 320 340 360 380 400 420 T(K) [PENTAFLUOROETHYL METHYL ETHER,22410−44−2, RE245cb2] 30 DIPPR32
25
20
15 (mN/m) σ
10
5
0 200 250 300 350 0.6 0.4 0.2 0 −0.2 −0.4 −0.6 PD(%) −0.8 −1 −1.2 −1.4 200 250 300 350 T(K) [2−(DIFLUOROMETHOXY)−1,1,1−TRIFLUOROETHANE,1885−48−9, RE245fa2] 50 DIPPR32
45
40
35
30
25 (mN/m) σ 20
15
10
5
0 150 200 250 300 350 400 2.5 2 1.5 1 0.5
PD(%) 0 −0.5 −1 −1.5 150 200 250 300 350 400 T(K) [OCTAFLUOROCYCLOBUTANE,115−25−3, RC318] 18 DIPPR32 DETHERM33 16
14
12
10 (mN/m)
σ 8
6
4
2
0 240 260 280 300 320 340 3.5 3 2.5 2 1.5 1 0.5
PD(%) 0 −0.5 −1 −1.5 −2 240 260 280 300 320 340 T(K) [HEPTAFLUOROPROPYL METHYL ETHER,375−03−1, R347mcc] 35 DIPPR32 DETHERM33 Ref. 8 Ref. 40 30
25
20 (mN/m) σ 15
10
5
0 150 200 250 300 350 400 2.5 2 1.5 1 0.5 0 −0.5 PD(%) −1 −1.5 −2 −2.5 150 200 250 300 350 400 T(K) [1,1,1,3,3−pentafluorobutane,406−58−6, R365mfc] 25 DETHERM33 Ref. 8
20
15 (mN/m) σ 10
5
0 260 280 300 320 340 360 380 4 3 2 1 0 PD(%) −1 −2 −3 260 280 300 320 340 360 380 T(K) [DIETHYL ETHER,60−29−7, R610] 40 DIPPR32 DETHERM33 WW22 35 Ref. 41
30
25
20 (mN/m) σ
15
10
5
0 150 200 250 300 350 400 450 20 15 10 5
PD(%) 0 −5 −10 150 200 250 300 350 400 450 T(K) [METHYLAMINE,74−89−5, R630] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 200 250 300 350 400 4 3.5 3 2.5 2 1.5 1 PD(%) 0.5 0 −0.5 −1 200 250 300 350 400 T(K) [ETHYLAMINE,75−04−7, R631] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 200 250 300 350 400 6 4 2 0 −2 −4 PD(%) −6 −8 −10 −12 200 250 300 350 400 T(K) [AMMONIA,7664−41−7, R717] 50 DIPPR32 DETHERM33 45 Ref. 20 Ref. 42
40
35
30
25 (mN/m) σ 20
15
10
5
0 200 250 300 350 400 4 2 0 −2 −4
PD(%) −6 −8 −10 −12 200 250 300 350 400 T(K) [CARBON DIOXIDE,124−38−9, R744] 18 DIPPR32 DETHERM33 22 16 WW
14
12
10 (mN/m)
σ 8
6
4
2
0 220 230 240 250 260 270 280 290 300 10 5 0 −5 PD(%) −10 −15 220 230 240 250 260 270 280 290 300 T(K) [SULFUR HEXAFLUORIDE,2551−62−4, R846] 14 DIPPR32 DETHERM33 Ref. 20 Ref. 43 12
10
8 (mN/m) σ 6
4
2
0 220 240 260 280 300 320 15 10 5 0
PD(%) −5 −10 −15 220 240 260 280 300 320 T(K) [CHLOROTRIFLUOROETHYLENE,79−38−9, R1113] 60 DIPPR32
50
40
30 (mN/m) σ
20
10
0 100 150 200 250 300 350 1 0.5 0 −0.5 −1
PD(%) −1.5 −2 −2.5 −3 100 150 200 250 300 350 T(K) [TETRAFLUOROETHYLENE,116−14−3, R1114] 40 DIPPR32
35
30
25
20 (mN/m) σ
15
10
5
0 140 160 180 200 220 240 260 280 0.2 0.1 0 −0.1
PD(%) −0.2 −0.3 −0.4 140 160 180 200 220 240 260 280 T(K) [TRICHLOROETHYLENE,79−01−6, R1120] 80 DIPPR32 DETHERM33 70
60
50
40 (mN/m) σ
30
20
10
0 200 250 300 350 400 450 500 3 2 1 0
PD(%) −1 −2 −3 200 250 300 350 400 450 500 T(K) [trans−1,2−DICHLOROETHYLENE,156−60−5, R1130] 45 DIPPR32 DETHERM33 40
35
30
25 (mN/m)
σ 20
15
10
5
0 250 300 350 400 450 T(K) [1,1−DIFLUOROETHYLENE,75−38−7, R1132A] 40 DIPPR32 DETHERM33 35
30
25
20 (mN/m) σ
15
10
5
0 120 140 160 180 200 220 240 260 280 8 6 4 2 0 PD(%) −2 −4 −6 120 140 160 180 200 220 240 260 280 T(K) [VINYL CHLORIDE,75−01−4, R1140] 35 DIPPR32 DETHERM33
30
25
20 (mN/m) σ 15
10
5
0 220 240 260 280 300 320 340 360 380 16 14 12 10 8 6 4
PD(%) 2 0 −2 −4 −6 220 240 260 280 300 320 340 360 380 T(K) [VINYL FLUORIDE,75−02−5, R1141] 40 DIPPR32 DETHERM33 WW22 35
30
25
20 (mN/m) σ
15
10
5
0 100 150 200 250 300 6 5 4 3 2 1 PD(%) 0 −1 −2 −3 100 150 200 250 300 T(K) [HEXAFLUOROPROPYLENE,116−15−4, R1216] 60 DIPPR32
50
40
30 (mN/m) σ
20
10
0 150 200 250 300 0.8 0.6 0.4 0.2 0 PD(%) −0.2 −0.4 −0.6 150 200 250 300 T(K) [2,3,3,3−tetrafluoroprop−1−ene,754−12−1, R1234yf] 12 Ref. 44
10
8
6 (mN/m) σ
4
2
0 270 280 290 300 310 320 330 340 4 3 2 1 0 −1 PD(%) −2 −3 −4 −5 270 280 290 300 310 320 330 340 T(K) [trans−1,3,3,3−tetrafluoropropene,29118−24−9, R1234ze(E)] 16 Ref. 6 Ref. 45 Ref. 46 14
12
10
8 (mN/m) σ
6
4
2
0 260 280 300 320 340 360 380 14 12 10 8 6 4 PD(%) 2 0 −2 −4 260 280 300 320 340 360 380 T(K) [3,3,3−TRIFLUOROPROPENE,677−21−4, R1243zf] 60 DIPPR32
50
40
30 (mN/m) σ
20
10
0 150 200 250 300 350 0.4 0.2 0 −0.2 −0.4
PD(%) −0.6 −0.8 −1 −1.2 150 200 250 300 350 T(K)