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ANALYSIS OF GROUND-WATER DATA FOR SELECTED WELLS NEAR , , 1950-95 By G.F. Huff

U.S. GEOLOGICAL SURVEY Water-Resources Investigations Report 96-4116

Prepared in cooperation with HOLLOMAN AIR FORCE BASE

Albuquerque, New Mexico 1996 U.S. DEPARTMENT OF THE INTERIOR BRUCE BABBITT, Secretary

U.S. GEOLOGICAL SURVEY Gordon P. Eaton, Director

The use of firm, trade, and brand names in this report is for identification purposes only and does not constitute endorsement by the U.S. Geological Survey.

For addtional information write to: Copies of this report can be purchased from:

District Chief U.S. Geological Survey U.S. Geological Survey Branch of Information Services Water Resources Division Box 25286 4501 Indian School Road NE, Suite 200 Denver, CO 80225-0286 Albuquerque, NM 87110-3929 CONTENTS Page Abstract...... ^ 1 Introduction...... 2 Purpose and scope...... 2 Well-numbering system...... 6 Previous investigations...... 7 Geohydrology of the study area...... 7 Analysis of ground-water-level data...... 8 Analysis of ground-water-withdrawal data...... 16 Analysis of ground-water-quality data...... 21 Summary...... 31 Selected references...... 32

FIGURES 1-3. Maps showing: 1. Location of the study area...... 3 2. Location of the Boles wells, San Andres and Douglas wells, Frenchy wells, Escondido well, and major canyons...... 4

3. Location of selected public-supply and observation wells near Holloman Air Force Base, New Mexico...... 5

4. Diagram showing system of numbering wells in New Mexico...... 6

5. Graphs showing measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E.31.411 (Douglas 4) for 1972-90 and for well 17S.10E.32.113 (San Andres 1) for 1972-93...... 9

6. Graphs showing measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E.32.122 (San Andres 5) for 1972-94 and for well 17S.10E.32.143 (San Andres 6) for 1972-89...... 10

m FIGURES-Continued

Page

7-15. Graphs showing:

7. Measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E.19.123 (Boles 2) for 1972-94 and for well 17S.10E.19.144 (Boles 5) for 1972-94...... 11

8. Measured water levels and estimated temporal trends in water levels (if present) for well 17S.09E.25.213 (Boles 17) for 1972-93 and for well 17S.09E.24.343 (Boles 34) for 1955-88...... 12

9. Measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E.18.432A for 1954-86 and for well 17S.10E.19.323A for 1954-86...... 13

10. Measured water levels and estimated temporal trends in water levels (if present) for well 17S.09E.25.343 for 1986-94 and for well 18S.10E.32.143 (Escondido 1) for 1987-94...... 14

11. Measured water levels and estimated temporal trends in water levels (if present) for well 18S.10E.09.332 (Frenchy 1) for 1986-93 and for well 18S.10E.16.414 (Frenchy 2) for 1987-93...... 15

12. Ground-water withdrawal from the San Andres and Douglas wells and estimated ground-water recharge from San Andres Canyon minus ground-water withdrawal from the San Andres and Douglas wells for 1961-93...... 17

13. Ground-water withdrawal from the Boles wells and estimated ground- water recharge from Mule, Arrow, and Lead Canyons minus ground-water withdrawal from the Boles wells for 1950-93...... 18

14. Ground-water withdrawal from the Escondido well and estimated ground-water recharge from Escondido Canyon minus ground-water withdrawal from the Escondido well for 1987-93...... 19

15. Ground-water withdrawal from the Frenchy wells and estimated ground-water recharge from Dog and Deadman Canyons minus ground-water withdrawal from the Frenchy wells for 1986-93...... 20

IV FIGURES-Concluded

Page

16-24. Graphs showing:

16. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.31.411 (Douglas 4) for 1963-95...... 22

17. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.32.113 (San Andres 1) for 1964-94...... 23

18. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.31.244 (San Andres 3) for 1966-94...... 24

19. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.19.123 (Boles 2) for 1953-95...... 25

20. Concentrations of dissolved nitrate, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.19.144 (Boles 5) for 1952-90,,,,,,,,,,.. 26

21. Concentrations of dissolved nitrate, dissolved sulfate, and dissolved solids as a function of time for well 17S.09E.25.213 (Boles 17) for 1953-93,,,,. 27

22. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.18.442A (Boles 26) for 1961-94...... 28

23. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.09E.24.343 (Boles 34) for 1955-95...... 29

24. Concentrations of dissolved nitrate as a function of time for well 17S.10E.19.141 (Boles 15) for 1950-94 and for well 17S.09E.25.212 (Boles 35) for 1961-93.,,,,, 30 TABLES Page 1. Results of statistical analyses of water-level data for selected Douglas, San Andres, Boles, Escondido, and Frenchy public-supply wells and observation wells near the Boles wells...... 33

2. Chemical analyses of water from selected Douglas, San Andres, Boles, Frenchy, and Escondido public-supply wells in the Holloman Air Force Base area...... 34

3. Comparisons between historical (1955-70) and current (1990-95) water-quality data for selected Douglas, San Andres, and Boles public-supply wells...... 37

CONVERSION FACTORS AND VERTICAL DATUM

Multiply By To obtain foot 0.3048 meter mile 1.609 kilometer acre 4,047 square meter gallons per minute 0.06309 liters per second million gallons per year 3,785 cubic meter per year

Temperature in degrees Celsius (°C) can be converted to degrees Fahrenheit (°F) as follows:

°F = (1.8x°O + 32

Sea level: In this report "sea level" refers to the National Geodetic Vertical Datum of 1929~a geodetic datum derived from a general adjustment of the first-order level nets of the and Canada, formerly called Sea Level Datum of 1929.

VI ANALYSIS OF GROUND-WATER DATA FOR SELECTED WELLS NEAR HOLLOMAN AIR FORCE BASE, NEW MEXICO, 1950-95

By G.F. Huff

ABSTRACT

Ground-water-level, ground-water-withdrawal, and ground-water-quality data were evaluated for trends. Holloman Air Force Base is located in the west-central part of Otero County, New Mexico. Ground-water-data analyses include assembly and inspection of U.S. Geological Survey and Holloman Air Force Base data, including ground-water-level data for public-supply and observation wells and withdrawal and water-quality data for public-supply wells in the area.

Well Douglas 4 shows a statistically significant decreasing trend in water levels for 1972-86 and a statistically significant increasing trend in water levels for 1986-90. Water levels in wells San Andres 5 and San Andres 6 show statistically significant decreasing trends for 1972-93 and 1981-89, respectively. A mixture of statistically significant increasing trends, statistically significant decreasing trends, and lack of statistically significant trends over periods ranging from the early 1970's to the early 1990's are indicated for the Boles wells and wells near the Boles wells. Well Boles 5 shows a statistically significant increasing trend in water levels for 1981-90. Well Boles 5 and well 17S.09E.25.343 show no statistically significant trends in water levels for 1990-93 and 1988-93, respectively. For 1986-93, well Frenchy 1 shows a statistically significant decreasing trend in water levels.

Ground-water withdrawal from the San Andres and Douglas wells regularly exceeded estimated ground-water recharge from San Andres Canyon for 1963-87. For 1951-57 and 1960-86, ground-water withdrawal from the Boles wells regularly exceeded total estimated ground-water recharge from Mule, Arrow, and Lead Canyons. Ground-water withdrawal from the San Andres and Douglas wells and from the Boles wells nearly equaled estimated ground-water recharge for 1989-93 and 1986-93, respectively. For 1987-93, ground-water withdrawal from the Escondido well regularly exceeded estimated ground-water recharge from Escondido Canyon, and ground- water withdrawal from the Frenchy wells regularly exceeded total estimated ground-water recharge from Dog and Deadman Canyons. Water-quality samples were collected from selected Douglas, San Andres, and Boles public-supply wells from December 1994 to February 1995. Concentrations of dissolved nitrate show the most consistent increases between current and historical data. Current concentrations of dissolved nitrate are greater than historical concentrations in 7 of 10 wells.

INTRODUCTION

Holloman Air Force Base is located in the in the west-central part of Otero County near Alamogordo, New Mexico (fig. 1). The base withdraws water from the Boles, San Andres, Douglas, Escondido, and Frenchy wells for domestic supply (figs. 2 and 3). Holloman Air Force Base is concerned about the future supply of potable ground water for domestic supply and other uses. The U.S. Geological Survey analyzed ground-water-level, ground-water- withdrawal, and ground-water-quality data for trends. This report was prepared in cooperation with Holloman Air Force Base.

Purpose and Scope

This report presents the analyses of ground-water-level, ground-water-withdrawal, and ground-water-quality data for trends that may affect the future availability of potable water for Holloman Air Force Base. The evaluation included assembly and inspection of data obtained from published reports and files of the U.S. Geological Survey and files of Holloman Air Force Base detailing ground-water levels in public-supply and observation wells and ground-water- withdrawal and ground-water-quality data for public-supply wells in the area of ground-water withdrawals by Holloman Air Force Base. Ground-water levels and selected ground-water- quality data were examined for temporal trends. 107*00' 106*00' r

34* 00'

LINCOLN COUNTY

SOCORRO! COUNTY !

SIERRA j COUNTY, ELEPHANT BUTTE RESERVOIR

TRUThLOR ONSEQUENCES OLLOMAN 33° BASE/- 00' ALAMOGQ

SANDS

MISSILE RANGE STUDYX. AREA

DONA COUNTY

FORT BLISS MILITARY RESERVATION HUECO r-l NEW MEXICO 32* f BOLSON/ _ _ 00'

EL PASO COUNTY CITY OF EL PASO 0 10 20 MILES 0 10 20 KILOMETERS

Figure 1.--Location of the study area. 106° 105°40' 106W 105°50'

T. 16 S.

T. 17 S.

T. 18 S.

T. 19 S.

EXPLANATION Boles wells San Andres and Douglas wells 10 KILOMETERS Frenchy wells Escondido well Sacramento Mountain Escarpment

Figure 2.-Location of the Boles wells, San Andres and Douglas wells, Frenchy wells, Escondido well, and major canyons. 106'05' 106W 105'55' I ALAMOGORDO T. 16 S.

32' 50' .10E.19.123 (Boles 2) ^.17S.10E.18.442A (Boles 26) T. 17S.09E.24.343 (Boles 34) > 17S.10E.18.432A 17 I7S.10E.19.141 (Boles 15) S. 17S.10E.19.144 (Boles 5) 17S.09E.25.213 (Boles 17) -17S.10E.19.323A 17S.C9E.25.212 (Boles 35) 17S.10E.32.113 (San Andres 1) 17S.OSE.25.343 17S.10E.31.411 O Q 17S.10E.32.122 (San Andres 5)

O 17S.10E.32.143 (San Andres 6) Ol7S.10E.31.244 (San Andres 3)

WHITE SANDS 18S.10E.09.332 (Frenchy 1) 32' MILITARY O 45' RESERVATION 18S.10E. 16.414 (Frenchy 2) O T. 18 S.

18S.10E.32.143 (Escondido 1) O

T. 19 32' S. 40'

R.8E. R.9E. R.10E.

EXPLANATION 1.5 3 MILES O PUBLIC-SUPPLY WELL 1.5 3 KILOMETERS OBSERVATION WELL 18S.10E.32.143 (Escondido 1) WELL NUMBER AND NAME

Figure 3.--Location of selected public-supply and observation wells near Holloman Air Force Base, New Mexico. TRACTS

Well 17S.10E.19.123 Figure 4.--System of numbering wells in New Mexico.

Well-Numbering System

Wells are located according to the system of common subdivision of sectionized land used throughout the State by the U.S. Geological Survey. The number of each well consists of four segments, separated by periods, that locate the well's position to the nearest 10-acre tract of land (fig. 4). The segments denote, respectively, the township south of the New Mexico base line, the range east of the New Mexico principal meridian, the section, and the particular 10-acre tract within the section. The fourth segment of the number consists of three digits denoting, respectively, the quarter section or approximate 160-acre tract, the quadrant (approximately 40 acres in size) of the quarter section, and the quadrant (approximately 10 acres in size) of the 40-acre tract in which the well is located. For example, well 17S.10E.19.123 is located in the SW1/4 of the NE1 / 4 of the NW1 /4, section 19, Township 17 South, Range 10 East. If more than one well within the 10-acre tract has the same location number, the letter "A" is assigned to the second well, the letter "B" to the third well, and so on. Previous Investigations

Ballance (1976) studied ground-water resources in the Holloman Air Force Base well-field area and discussed saline water that is present to the north and west of, as well as in a thin zone overlying, the area of freshwater in which the Boles, San Andres, and Douglas wells are located. Burns and Hart (1988) numerically simulated ground-water flow in a part of the southeastern Tularosa Basin, including the area of ground-water withdrawal by Holloman Air Force Base, and indicated water-level declines ranging from 26 to 60 feet from 1982 levels by the year 2001. Burns and Hart assumed ground-water withdrawal to be constant at 1981 rates. Estimated ground- water recharge from Mule, Arrow, Lead, San Andres, Dog, Deadman, and Escondido Canyons also was tabulated by Burns and Hart (1988).

Geohydrology of the Study Area

Unconsolidated sedimentary deposits of middle Tertiary to Holocene age, including alluvial-fan and basin-fill deposits, form the bolson aquifer in the central Tularosa Basin (fig. 1). The thickness of these unconsolidated sedimentary deposits ranges from 0 to 3,000 feet (Burns and Hart, 1988). Ground-water flow in the Tularosa Basin is generally to the south or southwest with the exception of westward to southwestward flow near the mouths of canyons cutting into the Sacramento Mountains. The Sacramento Mountains form the eastern boundary of the Tularosa Basin in the area of Holloman Air Force Base (fig. 1), and infiltration of runoff from the Sacramento Mountains is the primary source of recharge to the bolson aquifer. As a result, an area of freshwater in the bolson aquifer extends for 8 to 12 miles westward into the basin from the foot of the Sacramento Mountains, reaching depths as much as 1,200 feet below land surface (McLean, 1970). It is from this area of freshwater that Holloman Air Force Base withdraws water for domestic supply and other uses. More detailed information on the geology and hydrology of the central Tularosa Basin is presented in Hood (1958), McLean (1970), and Garza and McLean (1977). ANALYSIS OF GROUND-WATER-LEVEL DATA

The results of statistical analyses of water-level data for selected Douglas, San Andres, Boles, Escondido, and Frenchy public-supply wells and observation wells near the Boles wells are listed in table 1 (all tables are in the back of the report). Water-level data were examined for temporal trends using techniques described by Hirsch and others (1982) and Hirsch and Slack (1984). A p-value shown in table 1 less than 0.1 indicates a statistically significant temporal trend in water-level data at the 90-percent confidence level. The magnitude of temporal trends was estimated for water-level data where p-values were less than this 0.1 value. A positive estimated trend indicates increasing water levels, and a negative estimated trend indicates decreasing water levels. KendalTs tau value is a measure of how well the estimated trend represents the measured data near the mid-point of the data set. Increasing agreement between the estimated trend and the measured data is indicated as the value of KendalTs tau approaches 1.0 for a positive trend and -1.0 for a negative trend. Statistical analyses were performed on raw and log transformed data sets. In one data set (well 17S.09E.25.213, Boles 17), the p-values calculated on raw and log transformed data sets differed. However, both p-values were greater than 0.1, indicating the absence of a temporal trend at the 90-percent confidence level. For all other analyzed data sets, the p-values and KendalTs tau values calculated on raw and log transformed data sets were equal. Statistically significant estimated temporal trends in water levels for selected wells are listed in table 1. Well 17S.10E.31.411 (Douglas 4) shows a statistically significant decreasing trend in water levels for 1972-86 and a statistically significant increasing trend for 1986-90 (fig. 5). Water levels in wells 17S.10E.32.122 (San Andres 5) and 17S.10E.32.143 (San Andres 6) (fig. 6) show statistically significant decreasing trends in water levels for 1972-93 and 1981-89, respectively. The calculated rate of water-level change in San Andres 5 is small (0.5 foot per year) and may be caused by scatter in water-level data rather than an actual long-term decrease in water levels. Wells 17S.10E.19.123 (Boles 2) and 17S.10E.19.144 (Boles 5) show statistically significant increasing trends in water levels for 1972-93 and 1981-90, respectively (fig. 7). The calculated rate of water-level change in well Boles 2 also is relatively small (0.7 foot per year) and may be caused by scatter in water-level data rather then a long-term increase in water levels. Water levels in well Boles 5 show no statistically significant changes for 1990-93. For 1961-85, well 17S.09E.24.343 (Boles 34) shows a relatively small (0.4 foot per year) statistically significant decreasing trend in water levels (fig. 8). The relatively low scatter in water-level data for well Boles 34 suggests that this decreasing trend, although relatively small, may be real. Decreasing trends in water levels in well 17S.10E.18.432A are shown for 1960-70 and 1970-86 (fig. 9). The rate of decrease for 1970-86 is relatively small (0.2 foot per year) but may be real based on the low scatter in water-level data for that period. For 1960-73, well 17S.10E.19.323A shows a statistically significant decreasing trend in water levels (fig. 9). Water levels in wells 17S.09E.25.343 and 18S.10E.32.143 (Escondido 1) (fig. 10) show no statistically significant changes for 1988-93 and 1987-93, respectively. Well 18S.10E.09.332 (Frenchy 1) shows a statistically significant decreasing trend in water levels for 1986-93 (fig. 11). Although not a statistically demonstrable trend, visual inspection of water levels in well 18S.10E.16.414 (Frenchy 2) shows a decline between 1990 and 1993 (fig. 11). 150 UJ o WELL 17S.10E.31.411 (DOUGLAS 4); DATA FROM HOLLOMAN AIR FORCE BASE u.< oc D CO 160

2 170 UJ m

180

MEASURED WATER LEVEL ESTIMATED TREND FOR 1972-86 190 oc ESTIMATED TREND FOR UJ 1986-90

200 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

UJ 200 O< u. cc D CO 220

240

260 MEASURED WATER LEVEL

- 280

UJ UJ _l 300 cc WELL 17S.10E.32.113 (SAN ANDRES 1); DATA FROM HOLLOMAN AIR FORCE BASE I-UJ

320 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

Figure 5.-Measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E.31.411 (Douglas 4) for 1972-90 and for well 17S.10E.32.113 (San Andres 1) for 1972-93. WATER LEVEL, IN FEET BELOW LAND SURFACE WATER LEVEL, IN FEET BELOW LAND SURFACE Tj (Q Ft u u c co oo o o § 8 § & CD J O) IF m m CD ^ *> < Q) fflg CO o m O) ro CD o * *

°"^i V.^* CD mm 6SANANDRES _LN) (0 o o

Q. 0)3 CD

^3

^0*3 CD " T3 I o

CO CD * =J to Q- 50.- w O 33 O m S» S CD = 5T 8 CO SI m

(£ m

LL CD 60 i i i i

UJ WELL 17S.10E.19.123 (BOLES 2); DATA FROM HOLLOMAN AIR FORCE BASE

80 CO Q

100

ffi 120

MEASURED WATER LEVEL ESTIMATED TREND FOR JJJ 140 1972-93 I

i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 160 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

60 UJ WELL 17S.10E.19.144 (BOLES 5); DATA FROM HOLLOMAN AIR FORCE BASE u.a DC D 70 CO Q Z 80

1 LJJ CO 90 LJJ LJJ

100 MEASURED WATER LEVEL ESTIMATED TREND FOR 1981-90 110

120 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

Figure 7.--Measured water levels and estimated temporal trends in water levels (if present) for well17S.10E.19.123(Boles2)for1972-94andforweN17S.10E.19.144(Boles5) for 1972-94.

11 WATER LEVEL, IN FEET BELOW LAND SURFACE WATER LEVEL, IN FEET BELOW LAND SURFACE CQ c CD 00 ^o 8 8 §CO -~

CD m 111 CD -L CD CO ^| Q. CO CO C/D < b CO m > CD" cotn <

oo m CD Q. CO O CD CD CO to -. -«J 0) -^^ <-* -*. CD O Q. -* ~ -L CD CO 3

Si 0) q- 3 CD Q. 3 oT* toQ.

II 03 _L « ^ -s CD

CO CD

2-^ CD CO CO CO c CD 3J m 100

102 WELL 17S.10E.18.432A; DATA FROM U.S. GEOLOGICAL SURVEY

104 o 106 UJ CO 108 f- MEASURED WATER LEVEL UJ UJ ESTIMATED TREND FOR 110 1960-70 ESTIMATED TREND FOR >UJ 1970-86 UJ 112

114

116 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000

70

UJ O WELL 17S.10E.19.323A; DATA FROM U.S. GEOLOGICAL SURVEY

CC 75 ID CO Qz 80 g UJ CQ I- 85 MEASURED WATER LEVEL UJ UJ ESTIMATED TREND FOR 1960-73 90 UJ> _JUJ cc UJ 95

100 1950 1955 1960 1965 1970 1975 1980 1985 1990

Figure 9.--Measured water levels and estimated temporal trends in water levels (if present) for well 17S.10E. 18.432A for 1954-86 and for well 17S. 10E. 19.323A for 1954-86.

13 WATER LEVEL, IN FEET BELOW LAND SURFACE WATER LEVEL, IN FEET BELOW LAND SURFACE CO C co CO o en o o 00 CO o o o o O) ro CO co en ui o o

CD

III O CO b CO co >m co £^2. o> o> m :r cn

ro . m 3 D o Ol 0) > 2 -n Im

OJ_L

co CO co CO o o ^. ^*

ll~ Q.

_L 0) 0)5'00

co CO co CO co ® o o ro^ "£ ^ ®< CO £ ^-v 0) m 0) O: O -* §^ Q. -«. O o CO Ol o

(D QJ TlO K 5 ^ $ S O^ Q. *< CO o> o m c 31- 3 m SOO co> o xL? m m CO Oo o o Oo 00 CO CO > F m

3 -JCO CO-J o m o CD ^-. m 33 _m

CD a. 1 -* o 3 -1 -a % CO m CO m -5 00 00 CO m o o C»

co 13 CO

O? - 0) cp_So -1 ~ CD"

00 CD CO co" ANALYSIS OF GROUND-WATER-WITHDRAWAL DATA

Because ground-water withdrawals are combined for groups of wells, changes in water levels in any particular well may be difficult to relate to ground-water withdrawal. Rather, the ground-water withdrawals as presented may correlate to the overall rates of water-level change in an area surrounding a particular group of wells. Ground-water withdrawal from the various wells are compared to estimated ground-water recharge from associated canyons (fig. 2) as tabulated by Burns and Hart (1988).

Ground-water withdrawal from the San Andres and Douglas wells regularly exceeded estimated ground-water recharge from San Andres Canyon for 1963-87 (fig. 12). For 1951-57 and 1960-86, ground-water withdrawal from the Boles wells regularly exceeded estimated total ground-water recharge from Mule, Arrow, and Lead Canyons (fig. 13). Ground-water withdrawal from the San Andres and Douglas wells and the Boles wells nearly equaled estimated ground-water recharge for 1989-93 and 1986-93, respectively. For 1987-93, ground- water withdrawal from the Escondido well regularly exceeded estimated ground-water recharge from Escondido Canyon (fig. 14), and ground-water withdrawal from the Frenchy wells regularly exceeded total estimated ground-water recharge from Dog and Deadman Canyons (fig. 15).

16 900

800

700

500

E§ 40°

if 300

200

0 1950 1960 1980 1990 2000

-700

-800 1950 1960 1970 1980 1990 2000

Figure 12.-Ground-water withdrawal from the San And res and Douglas wells and estimated ground-water recharge from San Andres Canyon minus ground-water withdrawal from the San Andres and Douglas wells for 1961-93. (Ground-water withdrawal for 1961-81 and estimated ground-water recharge from Burns and Hart (1988). Ground-water withdrawal for 1982-93 compiled from records supplied by Holloman Air Force Base, New Mexico.) 17 400

W 350 r

300

250

1950 1960 1970 1980 1990 2000

100

50

-50

-100

£xS

Oeo -250 OCD OZ

P < -300

-350 1950 1980 1970 1980 1990 2000

Figure 13.-Ground-water withdrawal from the Boles wells and estimated ground-water recharge from Mule, Arrow, and Lead Canyons minus ground-water withdrawal from the Boles wells for 1950-93. (Ground-water withdrawal for 1950-81 and estimated ground-water recharge from Bums and Hart (1988). Ground-water withdrawal for 1982-93 compiled from records supplied by Holloman Air Force Base, New Mexico.) 18 240

220

200

180

160

140

8 120

100

80

60

40

20

0 1950 1960 1970 1980 1990 2000

20

-20

-40

-60

-80

-100

-120

-140

-160 1950 1960 1970 1980 1990 2000

Figure 14.-Ground-water withdrawal from the Escondido well and estimated ground-water recharge from Escondido Canyon minus ground-water withdrawal from the Escondido well for 1987-93. (Estimated ground-water recharge from Burns and Hart (1988). Ground-water withdrawal for 1987-93 compiled from records supplied by Holloman Air Force Base, New Mexico.) 19 300

250

- 200

150

100

50

0 1950 1960 1970 1980 1990 2000

i i i i i i i i i | i i i i i i i i i | i i i i P i i i i | i ' r- i i i 80 \ .

- 60 % - 40 %

20

\ 0 -20 I - '$1 - -40 i%\^^ -60 &

-80

- 1 100 oo I 120 (£ 2 140 Q in 180 it. Q.

180 O ^_ 1 . I O ,,,...,., 1 ...... 1 ,,.,,,,.. 1 ..... ! , 7 \ i ( ! , ...ill 1950 1960 1970 1980 1990 2000 Figure 15.-Ground-water withdrawal from the Frenchy wells and estimated ground-water recharge from Dog and Deadman Canyons minus ground-water withdrawal from the Frenchy wells for 1986-93. (Estimated ground-water recharge from Bums and Hart (1988). Ground-water withdrawal for 1986-93 compiled from records supplied by Holloman Air Force Base, New Mexico.) 20 ANALYSIS OF GROUND-WATER-QUALITY DATA

Water-quality samples were collected by the U.S. Geological Survey from selected Douglas, San Andres, Boles, Frenchy, and Escondido public-supply wells from December 1994 to February 1995. Results of analyses on water-quality samples are listed in table 2. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids in water-quality samples collected by the U.S. Geological Survey and data provided by Holloman Air Force Base were compared with historical water-quality data to evaluate the presence of temporal trends. No historical water-quality data were available for the Frenchy and Escondido wells. Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for selected Douglas, San Andres, and Boles public-supply wells are shown in figures 16-24.

Historical water-quality data are available for 1955-70; current data are for 1990-95. The 20- year (or greater) gap between historical and current water-quality data and the limited amount of current water-quality data would result in a tenuous statistical trend analysis. Therefore, water-quality data were examined by quantifying current concentrations as greater than, less than, or within the range of concentrations in historical data. The results of comparisons between historical and current water-quality data are summarized in table 3. Where concentrations of dissolved nitrite in current water-quality data (table 2) were less than 0.01 mg/L (milligram per liter), concentrations of dissolved nitrite plus nitrate (table 2) were considered equivalent to concentrations of dissolved nitrate for comparison with historical nitrate data. Concentrations of dissolved nitrite in current water-quality data greater than or equal to 0.01 mg/L were subtracted from concentrations of dissolved nitrite plus nitrate to calculate concentrations of dissolved nitrate. Calculated concentrations of dissolved nitrate were then used for comparison with historical nitrate data. Concentrations of dissolved nitrate have the most consistent increases of the constituents listed in table 3. Current concentrations of dissolved nitrate are greater than historical concentrations in 7 of 10 wells. In all wells considered in this study, current concentrations of dissolved nitrate are less than the maximum contaminant level of 10 mg/L for drinking water established by the U.S. Environmental Protection Agency (1994).

21 DISSOLVED SOLIDS CONCENTRATION, DISSOLVED SULFATE CONCENTRATION, DISSOLVED CHLORIDE CONCENTRATION, DISSOLVED NITRATE CONCENTRATION, 3) IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER AS N 7=cncncn-j-g-ji\3i\3i\3i\3G3 n _i MM ^-gootoo-iiocn -g o> *.ODODOl O Ol O Ol o o o o 6 o II : on: 2- 3 ______a a - §3 I S - 3 St. n T\ ~* co _^ "1 33 33 _ s± a>58 o o o 3 a g I C - 0 Q.r> ______R w ? CO - a - a a -n1 1 s5 om - it a :n * ?o -_ = Q. : D : : D : i a ° - a D I : D a : _ i i ^2 1 D s ? : . JJj. 1 "~ . 33 CO - O JD n - l~l m 33 m" s n - -g

O 0 - - - - ~ ~ ~ ~ ~ """' Q. £ "1

- - - 01 E : : a - - - - V - - - "1 Q. 5 o o o o o » 8 ~. , , , i , , , , i , , , , i , , , , i , , . ,~ o 1~, , , , i , . , , i , . . , i , . , ,~ o i.i.i.i, O , , , , i , , , , i , , , , i , , , , DISSOLVED SOLIDS CONCENTRATION, DISSOLVED SULFATE CONCENTRATION, DISSOLVED CHLORIDE CONCENTRATION, DISSOLVED NITRATE CONCENTRATION, IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER AS N

CO CO j ..,,..., | , , , . | ,,,,,,,, CO 3 Ul Ul 3 Ul _ ' ' ' ' ' ' ' ' ' ' (Q 0 o o - o c 3 - - - -

- - - 6 : on: 0 B> => 00- V) 0 3* ^ (D ~ ~ ~ ~H ~H > > 0) 3 _ _ _ _ _ :* -. ~* ~* CO CO § S 1 33: § o o o o o a§ ~~ "" ~ ~ s s - 0 » ~ ~ I C - =>0 O co 0 "* F ' * a. 1 D - - n : 1 D : : n | § - s: eo" 18i" : n : -* ® :° : : D : : ° I 1 : 0 Q. ^ si.- 5 n CO - n : - n - «? -_ nggj »J »J rri ID - 0 - 0 - o ^~ - - |- - m _ K> cog.

0 CO m9_ - - - -

[0 Q. - - - - it o - - - - ~* ~* ^5" j CO S S CO If s - o - 0 - o - £- ______Q- w ______3 2. _ _ _ _ ^ °- ~ ~ *~ ~ _ _ _ : : _ _ : : Us CO ° - - - - ^ Q. ~ _ Q.' ^ : ° : 8 O : n : : n : : n : - § - - - - Q. ~ ~ (0 ~ ~ 2. ro - ro - ro - ro - o E § - ~ o - - co o 1 1 1 1 1 . , 1 1 , 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 , i 1 1 1 1 1 1 ,,, o 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 , o i i i i i i i i i i i i . 0.8 n i i i i i i i i i i i i i r cm n DATA FROM U.S. GEOLOGICAL SURVEY

O DATA FROM HOLLOMAN AIR FORCE BASE

0.4

D

0.2 D

I i I 1950 1960 1970 1980 1990 2000 70 D fEtc 85

Z £C qtu oo. tuco Q| 60

UJ Z 55 O CO CO

50 1950 1980 1970 1980 1990 2000 325 1 I I I I I I I 1 I I I I I D 320 D ztc 315

310 D 305

300 1950 1960 1970 1980 1990 2000 780

780

)CD ?i 740

720 1950 1960 1970 1980 1990 2000

Figure 18.-Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.31.244 (San And res 3) for 1966-94. 24 0.8 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I i i i i i i i i i i i i i i i i i i i z" 0 lz n DATA FROM U.S. GEOLOGICAL SURVEY

O DATA FROM HOLLOMAN AIR FORCE BASE LLJUJ 01- o Zj n O - P°- 0.4 - ITS D D D gl Q2 n i-|O o z ^ n (0~ " Q n o i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 1950 1960 1970 1980 1990 2000 80 i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i I I I I I I I I I I I I I I I I I I I O - I* : n ZP 50 o 2 : n - o£ off : n

CHLORIDE «t o MILLIGRAMS : D n : ui z 30 - _i~ : n O . w w Q 20 ' i - i --i i i- i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 1950 1980 1970 1980 1990 200G 280 i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i I I I I I I I I I I I I I I I I I I I z" g £ 260 - 0 crcr . uo 0 £ 240 8* -

cP Pi 220 n D |o n n rV n W d 200 O 2 III g 180 - n - (0 ~ Q 160 i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 1950 1960 1970 1980 1990 2000 620 i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i I I I I I I I I I I I I I I I I I I I z" g n 0 fp eoo - - §c n 5w On. n n n W2 580 g< OCD Q- n >j z 560 n O~ W W n Q

540 i i i i i i i i i i i i i i i i i i i-" i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 1950 1960 1970 1980 1990 2000

Figure 19.-Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E. 19.123 (Boles 2) for 1953-95. 25 2.0 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I -r-TT~

0 g P DATA FROM U.S. GEOLOGICAL SURVEY P| 1.6 ujj P P P O DATA m°M HOLLOMAN AIR FORCE BASE O

§» Pi 1.0 '- n a : ffiDC : n ° i al - - !>Z 0.5 O C/J C/J : n : 0 : i i Di i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 1950 1960 1970 1960 1990 2000 600

pffi 500 n Pi 400

300

r 1 200 1950 1960 1970 1980 1990 2000

1,200 a O a §« 1,000 ^ OIT z m a OCL O,_ 800 o 600

400 1950 1960 1970 1980 1990 2000

Figure 20.-Concentrations of dissolved nitrate, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.19.144 (Boles 5) for 1952-90.

26 DISSOLVED SOLIDS CONCENTRATION, DISSOLVED SULFATE CONCENTRATION, DISSOLVED NITRATE CONCENTRATION, IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER IN MILLIGRAMS PER LITER AS N

,,,,,, 1 , 1 , co 1 ' 1 ' 1 co , 1 , 1 1 en 01 0 0

to : % : : g : c : n D : 3 _ _ _ _ : o a : - - - DO- _ ~ o s 3 o co co o> O) o o 1 i i : 3 (D n : ° Z I : D ^ = n D - U*-i 0 co D - D g|§ sm ai(0 : Q : la : % : : D n : r cP a>o* i " ° 9: °8 o_ i n : co i D : co :° is: o o m 33 =is a. n m ~ CO "* N> §«

- i - i - 0 0 SBo> =s (0 0) -J"_i (D - _ : o : _i a. en(O tnV) co o_ co co «>S co co "g. o o o o a

a

- - - to i Pb> oo I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 'I I I I I I I I I I I I

JCENTRATION, ASJTERN n DATA FROM U.S. GEOLOGICAL SURVEY

O DATA FROM HOLLOMAN AIR FORCE BASE ~ Si O n p"1- 0.4 " il « - a&a D o z w~ D - 0 i i i i i i i i i I i i i i i i i i i I i i i i i i i i i I i i i i i i i i i i i i i i i i i i i I 0 1 950 1960 1970 1980 1990 2000 34 I I I I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I g D |oc z m nit: 0 32 - D D

CHLORIDEDC MILLIGRAMSP D

G> o D D - O DD w w o i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 28 1 950 1960 1970 1980 1990 2000

220 I I I I I I I I I 1 I I I I I I I I I I I I 1 I I I I I I I I I I I I

0 ecu _ ^p1 210 n D : nil] - §£ : n o 11- D j p"! 200 : 0%

- o~£ z 190 D ~- w - w o i i i i i i i i i I i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 180 1 950 * i960 1970 1980 1990 2000

570 I I I I I I I I I I I I I 1 I ri 1 1 I I I I I I I I I I I I I I I I I I I I I I I I I 1 1 1 1 1 1 1 1 z" o F - -

Figure 22.-Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.10E.18.442A (Boles 26) for 1961-94. 28 1.0 I I I I I 1 1 I I I I I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 z" 0 Q] DATA FROM U.S. GEOLOGICAL SURVEY Q & ^co CC ^ O DATA FROM HOLLOMAN AIR FORCE BASE uiui °t Ice n O Ul - P°- 0.6 n

320 . i i i i i i i i i i i LJ1 ' I I I I I I I I I I I I I I I I I I I I I I 1 1 I I I 1 I I I 1 I I 1 1 . z" g ircr 310 I-UI : D Zl- D :- UIIJ _ Ozcr " §0! 300 D ~ - ll : D 3^ 290 : C1 ^ ~ ol ; Ul " >.z ~ 0~ 260 D co " co " Q i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i 270 1950 1960 1970 1980 1990 2000 780 i i i i i i i i i i i > i i I I I 1 I I I I I i I I I I I I I I I I I I I 1 I I I 1 I 1 1 I I I I I

O 5cr ~ H^ 760 D

°w

COS 740 D Q< OC3 .

Q 5 ^Z 720 - S~ n n co Q L] n 1 1 1 1 1 1 1 1 1 1 1 1 T-" 1 i i i i i 1 i i i i i i i i i 1 i i i i i i i i i 1 i i i i i i i i i 1 1950 1960 1970 1980 1990 2000

Figure 23.-Concentrations of dissolved nitrate, dissolved chloride, dissolved sulfate, and dissolved solids as a function of time for well 17S.09E.24.343 (Boles 34) for 1955-95. 29 DISSOLVED NITRATE CONCENTRATION, DISSOLVED NITRATE CONCENTRATION, IN MILLIGRAMS PER LITER AS N IN MILLIGRAMS PER LITER AS N

(D c D

D D D D D D =d> (02. D -I w °- -D D b = to ~ m 3 D D ro 2* O D 2. =

21 21 O O "o *+3 I C O to t co

-J CO o m

O CD o O SUMMARY

Ground-water-level, ground-water-withdrawal, and ground-water-quality data were evaluated for trends. Data for well Douglas 4 indicate a statistically significant decreasing trend in water levels for 1972-86 and a statistically significant increasing trend in water levels for 1986- 90. Water levels in wells San Andres 5 and San Andres 6 show statistically significant decreasing trends for 1973-93 and 1981-89, respectively. A mixture of statistically significant increasing trends, statistically significant decreasing trends, and a lack of statistically significant trends over periods ranging from the early 1970's to the early 1990's is indicated for the Boles wells and observation wells near the Boles wells. Data for well Boles 5 show a statistically significant increasing trend in water levels for 1981-90. Data for well Boles 5 and observation well 17S.09E.25.343 indicate no statistically significant trends in water levels for 1990-93 and 1988-93, respectively. Data for well Frenchy 1 indicate a statistically significant decreasing trend in water levels for 1986-93.

Ground-water withdrawal from the San Andres and Douglas wells regularly exceeded estimated ground-water recharge from San Andres Canyon for 1963-87. For 1951-57 and 1960-86, ground-water withdrawal from the Boles wells regularly exceeded total estimated ground-water recharge from Mule, Arrow, and Lead Canyons. Ground-water withdrawal from the San Andres and Douglas wells and the Boles wells nearly equaled estimated ground-water recharge for 1989-93 and 1986-93. For 1987-93, ground-water withdrawal from the Escondido well regularly exceeded estimated ground-water recharge from Escondido Canyon, and from the Frenchy wells regularly exceeded total estimated ground-water recharge from Dog and Deadman Canyons.

Concentrations of dissolved nitrate show the most consistent increases between historical (1955-70) and current (1990-95) data. Current concentrations of dissolved nitrate are greater than historical concentrations in 7 of 10 wells. Current concentrations of dissolved nitrate in all wells considered in this study are below the maximum contaminant level of 10 mg/L for drinking water established by the U.S. Environmental Protection Agency.

31 SELECTED REFERENCES

Ballance, W.C, 1976, Ground-water resources of the Holloman Air Force Base well-field area, 1967, New Mexico, with a section on Geophysical exploration, by Robert Mattick: U.S. Geological Survey Open-File Report 76-807,90 p.

Burns, A.W., and Hart, D.L., Jr., 1988, Simulated water-level declines caused by ground-water withdrawals near Holloman Air Force Base, Otero County, New Mexico: U.S. Geological Survey Water-Resources Investigations Report 86-4324,44 p.

Garza, Sergio, and McLean, J.S., 1977, Fresh-water resources in the southeastern part of the Tularosa Basin: New Mexico State Engineer Technical Report 40,67 p.

Hirsch, R.M., and Slack, J.R., 1984, A nonparametric trend test for seasonal data with serial dependence: Water Resources Research, v. 20, no. 6, p. 727-732.

Hirsch, R.M., Slack, J.R., and Smith, R.A., 1982, Techniques of trend analysis for monthly water quality data: Water Resources Research, v. 18, no. 1, p. 107-121.

Hood, J.W, 1958, Ground-water resources and related geology in the vicinity of Holloman Air Force Base, Otero County, New Mexico: U.S. Geological Survey Open-File Report, 261 p.

McLean, J.S., 1970, Saline ground-water resources of the Tularosa Basin, New Mexico: U.S. Department of the Interior, Office of Saline Water Research and Development Progress Report 561,128 p.

U.S. Environmental Protection Agency, 1994, National primary drinking water standards: EPA 810-F-94-001A.

32 Table 1. Results of statistical analyses of water-level data for selected Douglas, San Andres, Boles, Escondido, and Frenchy public-supply wells and observation wells near the Boles wells

[Negative values of estimated trends indicate decreasing water levels; positive values indicate increasing water levels. Data from Holloman Air Force Base unless otherwise noted. --, no value computed. Well locations shown in figure 3]

Time Raw data Log transformed data period Estimated Well location of data Kendall's Kendall's trend (feet number and name analyzed p-value tau value p-value tau value per year) 17S.10E.31.411 1972-86 0.0000 0.77 0.0000 0.77 -2.0 (Douglas 4) 17S.10E.31.411 1986-90 .0929 -1.0 .0929 -1.0 5.3 (Douglas 4) 17S.10E32.113 1973-93 .1129 -.15 .1129 -.15 (San Andres 1) 17S.10E.32.122 1972-93 .0014 .28 .0014 .28 -0.5 (San Andres 5) 17S.10E.32.143 1981-89 .0000 .73 .0000 .73 -3.7 (San Andres 6) 17S.10E.19.123 1972-93 .0015 -.31 .0015 -.31 .7 (Boles 2) 17S.10E.19.144 1981-90 .0000 -.85 .0000 -.85 2.6 (Boles 5) 17S.10E.19.144 1990-93 .1781 .34 .1781 .34 (Boles 5) 17S.09E.25.213 1978-93 .2607 -.14 .2614 -.14 ~ (Boles 17) 17S.09E.24.343* 1961-85 .0000 .65 .0000 .65 -.4 (Boles 34) 17S.10E.18.432A* 1960-70 .0000 .88 .0000 .88 -1.1 17S.10E.18.432A* 1970-86 .0165 .67 .0165 .67 -.2 17S.10E.19.323A* 1960-73 .0000 .93 .0000 .93 -1.0 17S.09E.25.343* 1988-93 .1833 -.54 .1833 -.54 - 18S.10E.32.143 1987-93 .1368 .28 .1368 .28 -- (Escondido 1) 18S.10E.09.332 1986-93 .0181 .43 .0181 .43 -5.7 (Frenchy 1) 18S.10E.16.414 1986-93 .1274 .32 .1274 .32 (Frenchy 2)

*U.S. Geological Survey data 33 Table 2.--Chemical analyses of water from selected Douglas, San Andres, Boles, Frenchy, and Escondido public-supply wells in the Holloman Air Force Base area

[deg. C, degrees Celsius; gal/min, gallons per minute; jiS/cm, microsiemens per centimeter at 25 degrees Celsius; mg/L, milligrams per liter; jig/L, micrograms per liter; --, no data; <, less than. All samples collected by U.S. Geological Survey and analyzed by Holloman Air Force Base. Well locations shown in figure 3]

Pump or flow Altitude of period Specific Specific land Depth of prior to conduct­ conduct­ pH water, Well location number Date of surface well, total sampling Well yield ance, field ance, lab whole, and name sample (feet) (feet) (minutes) (gal/min) OiS/cm) (uS/cm) field

17S.10E.31.411 (Douglas 4) 02-09-95 ______997 992 7.4 17S.10E.32.113 (San Andres 1) 12-21-94 4,212 370.00 ~ 450 1,390 1,410 7.5 17S.10E.31.244 (San Andres 3) 12-20-94 4,191 966.00 - 900 1,180 1,120 7.8 17S.10E.32.122 (San Andres 5) 12-20-94 4,298 995.00 ~ 975 1,090 1,200 7.5 17S.10E.19.123(Boles2) 02-08-95 4,161 240.00 - - 835 838 7.5 17S.10E.18.442A (Boles 26) 12-21-94 - - - - - 805 7.5 17S.09E.24.343 (Boles 34) 02-08-95 4,140 255.00 - - 1,030 1,040 7.5 18S.10E.32.143 (Escondido 1) 12-22-94 4,198 1,000 40 1,250 771 757 7.6 18S.10E.09.332 (Frenchy 1) 12-28-94 4,202 1,000 30 1,700 958 960 7.3 Table 2.~Chemical analyses of water from selected Douglas, San Andres, Boles, Frenchy, and Escondido public-supply wells in the Holloman Air Force Base area Continued

Nitro­ pH Nitro­ gen, water, Cal­ Magne­ Potas­ gen, NO2+ whole, Alka­ cium, sium, Sodium, sium, nitrite, NQj, lab Temper­ Temper­ linity dis­ dis­ dis­ dis­ dis­ dis­ (stand­ ature, ature, (mg/L solved solved solved solved solved solved Well location number Date of ard air water as (mg/L (mg/L (mg/L (mg/L (mg/L (mg/L and name sample units) (deg.C) (deg.C) CaCCty asCa) asMg) asNa) asK) asN) asN)

17S.10E.31.411 (Douglas 4) 02-09-95 7.7 24.5 23.0 167 98 44 43 1.9 0.010 2.10 17S.10E.32.113 (San Andres 1) 12-21-94 7.5 18.0 22.5 159 150 66 55 2.2 <0.010 2.80 en 17S.10E.31.244 (San Andres 3) 12-20-94 7.7 16.0 26.0 175 100 47 62 2.5 <0.010 0.740 17S.10E.32.122 (San Andres 5) 12-20-94 7.6 16.5 24.5 164 120 54 61 2.5 <0.010 0.600 17S.10E.19.123 (Boles 2) 02-08-95 7.7 18.0 20.5 180 89 37 30 1.2 0.010 0.520 17S.10E.18.442A (Boles 26) 12-21-94 7.6 20.5 21.0 180 88 34 29 1.4 <0.010 0.440 17S.09E.24.343 (Boles 34) 02-08-95 7.7 16.0 19.5 171 110 46 46 1.9 0.020 0.910 18S.10E.32.143 (Escondido 1) 12-22-94 7.7 17.5 27.0 195 59 30 54 2.7 <0.010 0.160 18S.10E.09.332 (Frenchy 1) 12-28-94 7.5 15.5 25.0 200 100 38 48 2.2 <0.010 0.370 Table 2.~Chemical analyses of water from selected Douglas, San Andres, Boles, Frenchy, and Escondido public-supply wells in the Holloman Air Force Base area Concluded

Man­ Chlo­ Solids, Fluo- Bro­ ga­ ride, Sulfate, residue at ride, mide, Silica, Iron, nese, dis­ dis­ 180 deg. dis­ dis­ dis­ dis­ dis­ solved solved C, dis­ solved solved solved solved solved Well location number Date of (mg/L (mg/L solved (mg/L (mg/L (mg/Las

17S.10E.3 1.411 (Douglas 4) 02-09-95 56 270 682 0.50 0.15 21 <3 3 17S.10E.32.113 (San Andres 1) 12-21-94 66 500 1,040 0.40 0.19 20 11 3 17S.10E.31.244 (San Andres 3) 12-20-94 67 320 778 0.50 0.15 22 6 2 17S.10E.32.122 (San Andres 5) 12-20-94 66 360 858 0.60 0.15 21 <3 2 17S.10E.1 9.123 (Boles 2) 02-08-95 35 210 566 0.20 0.070 20 6 1 17S.10E.18.442A (Boles 26) 12-21-94 32 190 540 0.30 0.070 19 6 1 17S.09E.24.343 (Boles 34) 02-08-95 62 280 718 0.30 0.11 23 <3 5 18S.10E.32.143 (Escondido 1) 12-22-94 32 150 486 0.50 0.090 21 38 37 18S.10E.09.332 (Frenchy 1) 12-28-94 40 250 660 0.40 0.13 21 15 3 Table 3.-Comparisons between historical (1955-70) and current (1990-95) water-quality data for selected Douglas, San Andres, and Boles public-supply wells

[+, current concentrations greater than the range of concentrations in historical data; -, current concentrations less than the range of concentrations in historical data; 0, current concentrations within the range of concentrations in historical data; +/-, current concentrations both greater than and less than the range of concentrations in historical data; +/0, current concentrations both greater than and within the range of concentrations in historical data; N, no data available. Well locations shown in figure 3]

Dissolved Dissolved Dissolved Dissolved Well location number and name nitrate chloride sulfate solids 17S.10E.31.411 (Douglas 4) + + - 0 17S.10E.32.113 (San Andres 1) +/- + + + 17S.10E.31.244 (San Andres 3) + + 0 + 17S.10E.19.123 (Boles 2) + 0 +/0 +/0 17S.10E.19.144 (Boles 5) 0 N 0 0 17S.10E.19.141 (Boles 15) 0 N N N 17S.09E.25.213 (Boles 17) + N - 0 17S.10E.18.442A (Boles 26) +0-0 17S.09E.24.343 (Boles 34) +/0 + - 0 17S.09E.25.212 (Boles 35) 0 N N N

*U.S. GOVERNMENT PRINTING OFFICE: 1996-776-760/45067 37