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New Data on Minerals FOUNDED in 1907 RUSSIAN ACADEMY OF SCIENCE FERSMAN MINERALOGICAL MUSEUM VOLUME 40 New Data on Minerals FOUNDED IN 1907 MOSCOW OCEAN PICTURES Ltd. 2005 ISSN 5900395626 UDK 549 New Data on Minerals. Moscow.: Ocean Pictures, 2005. volume 40, 168 pages, 15 color and 99 b/w drawings, schemes, photos. The volume 40 includes articles on new mineral species, among which chukhrovite(Nd), tsepiniteSr, senkevichite, and kyrgyzstanite are described. The new data on rare minerals calcurmolite and turanite, easily oxidizable chalcopyrite from black smokers of the Rainbow hydrothermal field (MidAtlantic Ridge), vanadium hematite associated with minerals of precious metals, copper, zinc, and iron is given; also there is data on fahlores from the Kvartsitovye Gorki deposit and the nickelinebreithauptite mineral series from the Norilsk ore field. Features of bismuth mineralization of the Djimidon deposit (North Osetia) and raremetal mineralization connected with bituminous matters from pegmatites of the Khibiny and Lovozero massifs are revealed. The results of study of metacolloidal gold and delhayelite crystals are published. In the «Mineralogical Museums and collections» part, the minerals named in honour of collaborators of the Fersman Mineralogical Museum, specimens of platinum of the Ugolnyi stream (Norilsk) from the Museum collection are described; interesting historical data on the items of Decorative and Precious Stones collection (PDK) is given. «Mineralogical Notes» part includes the mineralogical summary of main mineral types of ores of Europe and the article devoted to mineral drawings of Victor Slyotov and Vladimir Makarenko. In new «Discussions» part, the polemics on the theme «What are the mineral and mineral species» is opened. The review of new books is published. The volume is of interest for mineralogists, geochemists, geologists, and also collaborators of naturalhistorical museums, collectors and amateur of minerals. EditorinChief Margarita I .Novgorodova, Doctor in Science, Professor EditorinChief Elena A.Borisova, Ph.D of the volume: Editorial Board Moisei D. Dorfman, Doctor in Science Svetlana N. Nenasheva, Ph.D Marianna B. Chistyakova, Ph.D Elena N. Matvienko, Ph.D Мichael Е. Generalov, Ph.D N.A.Sokolova Secretary Translator: Yiulia Belovistkaya Photo: Michael B. Leybov, Michael E. Generalov Leader of publishing group Michael B. Leibov Executive Editor Ludmila А. Cheshko Art Director Nikolay О. Parlashkevich Editor Ekaterina V. Yakunina Design (idea) Dmitrii Ershov Layout Elena Yurlova LIBRARY OF CONGRESS CATALOGINGIN PUBLICATION DATA Authorized for printing by the Fersman Mineralogical Museum of the Russian Academy of Science © Text, photo, drawings, Fersman Mineralogical Museum Russian Academy of Science, 2005 © Design, Ocean Pictures, 2005 Published by: Fersman Mineralogical Museum RAS Ocean Pictures Ltd Bld. 18/2 Leninsky Prospekt, 4871 S. Dudley St., Littleton Moscow, 117071, Russia CO 80123, USA phone (7495) 9520067; tel/fax (303) 9042726 fax (7495) 9524850 phone/fax (7495) 2033574 email [email protected] email: [email protected] website: www.fmm.ru website: www.minbook.com Printed in Russia CONTENT New Minerals and Their Varieties, New Finds of Rare Minerals, Mineral Paragenesis Pautov L.A., Bekenova G.K., Karpenko V.Yu., Agakhanov A.A. Chukhrovite(Nd), Ca3(Nd,Y)Al2(SO4)F13·12H2O, a New Mineral . .5 Pekov I.V., Chukanov N.V., Zadov A.E., Rozenberg K.A., Rastsvetaeva R.K. TsepiniteSr, (Sr,Ba,K)(Ti,Nb)2(Si4O12)(OH,O)2·3H2O, a New Mineral of the Labuntsovite Group . .11 Agakhanov A.А., Pautov L.A., Uvarova Y.A., Sokolova E.V., Hawthorne Frank, Karpenko V.Yu. Senkevichite, CsKNaCa2TiO[Si7O18(OH)], a New Mineral . .17 Agakhanov A.A., Karpenko V.Yu., Pautov L.A., Bekenova G.K., Uvarova Y.A., Sokolova E.V., Hawthorne Frank Kyrgyzstanite, ZnAl4(SO4)(OH)12·3H2O, a New Mineral from the KaraTangi Deposit, Kirgizia . .23 Sidorenko G.A., Chistyakova N.I., Chukanov N.V., Naumova I.S., Rassulov V.A. Calcurmolite: New Data on Chemical Composition and Constitution of the Mineral . .29 Karpenko V.Yu., Agakhanov A.A., Pautov L.A., Sokolova E.V., Hawthorne Frank, Bekenova G.K. Turanite from TyuyaMuyun, Kirgizia: New Data on Mineral . .37 Fardoost F., Mozgova N.N., Borodaev Y.S., Organova N.I., Levitskaya L.A. Easily Oxidizable Chalcopyrite from Black Smokers of the Rainbow Hydrothermal Field (MidAtlantic Ridge, 36°14'N) . .44 Gritsenko Y.D., Spiridonov E.M. Minerals of the NickelineBreithauptite Series from Metamorphogenichydrothermal Veins of the Norilsk Ore Field . .51 Chernikov A.A., Dubinchuk V.T., Chistyakova N.I., Naumova I.S., Zaitsev V.S. New Data on Vanadium Hematite Associated with Micro and Nanocrystals of Noble Metals, Copper, Zinc, and Iron Minerals . .65 Groznova E.O., Dobrovol'skaya M.G., Kovalenker V.A., Tsepin A.I., Razin M.V. Bismuth Mineralization of PbZn Ores at the Djimidon Deposit (North Osetia) . .72 Chukanov N.V., Ermolaeva V.N., Pekov I.V., Sokolov S.V., Nekrasov A.N., Sokolova M.N. Raremetal Mineralization Connected with Bituminous Matters in Late Assemblages of Pegmatites of the Khibiny and Lovozero Massifs . .80 Filimonov S.V., Spiridonov E.M. Fahlores from the Kvartsitovye Gorki Hypabyssal Goldantimonite Deposit (North of Central Kazakhstan) . .96 Crystal Chemestry, Minerals as Prototypes of New Materials, Physical and Chemical Properties of Minerals Novgorodova M.I. Metacolloidal Gold . .106 Sokolova M.N., Smol'yaninova N.N., Golovanova T.I., Chukanov N.V., Dmitrieva M.T. Delhayelite Crystals from Ristschorrites of the Rasvumchorr Plateau (Khibiny Massif) . .115 Mineralogical Museums and Collections Generalov M.E., Pautov L.A. Platinum of the Ugolnyi Stream (Norilsk) from the Fersman Mineralogical Museum Collection . .120 Nenasheva S.N. Minerals Named in Honour of the Collaborators of the A.E. Fersman Mineralogical Museum . .125 Chistyakova M.B. What are Exhibits Silent About . .142 Mineralogical Notes Semenov E.I. Mineral Types of Ore of Europe . .151 Dymkov Y. M. Wonderful Drawings of Minerals by Victor Slyotov and Vladimir Makarenko . .154 Discussion Borutzky B.Ye. Essays on Fundamental and Genetic Mineralogy: 1. What is the Mineral and Mineral Species? . .159 Books view . .167 New Minerals and Their Varieties New Finds of Rare Minerals, Mineral Paragenesis New Data on Minerals. М., 2005. Vol. 40 5 UDK 549.45 CHUKHROVITE(Nd), Ca3(Nd,Y)Al2(SO4)F13·12H2O, A NEW MINERAL Leonid A. Pautov Fersman Mineralogical Museum RAS, Moscow, [email protected] Galiya K. Bekenova Satpaev Institute of Geological Sciences KAS, Almaty, Kazakhstan, [email protected] Vladimir Yu. Karpenko Fersman Mineralogical Museum RAS, Moscow, [email protected] Atali A. Agakhanov Fersman Mineralogical Museum RAS, Moscow, [email protected] In specimens from the oxidized zone of the KaraOba deposit (Central Kazakhstan), a new neodymiumdominant analogue of chukhrovite(Y) and chukhrovite(Ce) has been found; it has been named chukhrovite(Nd). The new mineral occurs in the form of isometric grains and small crystals represented by a combination of {100} and {111} faces, with sizes ranging from 0.05 to 0.4 mm; it forms zones within the larger crystals of chukhrovite(Y) also. Chukhrovite(Nd) is associated with quartz, fluorite, halloysite, chukhrovite(Y), anglesite, gearksutite, creedite, and the jarosite group minerals. The mineral is colourless, rarely white. Streak is white. Hardness is 3.54 on Mohs' scale. Density (meas.) is 2.42(3) g/cm3, density (calc.) is 2.42 g/cm3. The mineral is transparent, and in thin sections it has anomalous grey interference colours, n=1.443(2) (589 nm). Chemical composition (electron microprobe instrument, wt %) is following: CaO – 20.03; Y2O3 – 1.94, La2O3 – 2.32; Ce2O3 – 1.37; Pr2O3 – 1.37; Nd2O3 – 6.26; Sm2O3 – 1.90; Gd2O3 – 1.12; Dy2O3 – 0.44; Ho2O3 – 0.10; Al2O3 – 12.09; SO3 – 9.38; F – 28.93; H2O (by difference) – 24.93, less O=F 12.18, total 100.00 wt%.Empirical formula is Ca3.06(Nd0.32Y0.15La0.12Sm0.09Ce0.07Pr0.07Gd0.05Dy0.02Ho0.01)0.90 Al2.03S1.01O3.96F13.06·11.87H2O. Ideal formula is Ca3(Nd,Y)Al2(SO4)F13·12H2O. Cubic, space group Fd3, a=16.759(3) Å, V=4707.0(1) Å3, Z=8. Strong lines of Xray pouder pattern are following (dI(hkl)): 9.710(111); 5.927(220); 3.228(511); 2.5557(533); 2.2405(642); 2.1806(731); 1.8275(842). The IR spectrum is as follows: 3548, 3423, 1630, 1090, 586, 465 cm1. The type specimen of the new mineral is at the Fersman Mineralogical Museum, RAS (Moscow). 3 tables, 3 figures, and 11 references. During the study of samples from the oxi- and mineralogy of the deposit have been consid- dized zone of ore deposits in Kazakhstan, a new ered in a number of publications (Shcher ba, neodymiumdominant analogue of chukhro - 1960; Ermilova et al., 1960; Ermilova, 1964; vite(Y) and chukhrovite(Ce) has been found; it Shcherba et al., 1988; etc.). Chukhrovite(Y) from was named chukhrovite(Nd)* according to the the oxidized zone of this deposit was described protocol in force for names of rareearth miner- as chukhrovite by L.P. Ermilova with coauthors als (Levinson, 1996). (1960). We have found chukhrovite(Nd) in the spe - cimens formed by columnar milkywhite quartz Occurrence and mineral assemblages i. Within the quartz there are small (up to 5 mm in length) lamellar grains of huebnerite. In num - Chukhrovite(Nd) has been found in speci- erous small cavities and interstitions of columnar mens from the oxidized zone of a molybde- quartz crystals, are powdery and microcrys- numtungsten deposit in KaraOba (Central Ka - talline crusts of jarosite, poorly shaped crystals of za khstan). The KaraOba ore field is located on anglesite (up to 4 mm in size), druses of small the northeastern flank of the ChuIliisk ore belt crystals of creedite, massive snowywhite in the central part of a volcanotectonic struc- finegrained aggregations of gearksutite or hal- ture. The deposit is connected with the multi- loysite are often observed. In these specimens phase Late Permian (260±5 Ma) intrusive massif chukhrovite(Nd) is presented by aggregations of leucocratic granites breaking the effu- of isometric colourless grains and small, often sivefragmental series of LowerMiddle poorly shaped crystals formed seemingly by a Devonian.
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