Common Name: DIETHYLALUMINUM

CAS Number: 96-10-6 RTK Substance number: 0689 DOT Number: UN 3052 Date: December 1995 Revision: June 2001 ------

HAZARD SUMMARY * Diethylaluminum Chloride can affect you when breathed * If you think you are experiencing any work-related health in. problems, see a doctor trained to recognize occupational * Contact can severely irritate and burn the skin and eyes diseases. Take this Fact Sheet with you. with possible eye damage. * Breathing Diethylaluminum Chloride can irritate the WORKPLACE EXPOSURE LIMITS nose, throat and lungs causing coughing, wheezing and/or The following exposure limits are for Aluminum Alkyls shortness of breath. (measured as Aluminum): * Diethylaluminum Chloride is a HIGHLY FLAMMABLE and REACTIVE chemical and a NIOSH: The recommended airborne exposure limit is DANGEROUS FIRE and EXPLOSION HAZARD. 2 mg/m3 averaged over a 10-hour workshift.

IDENTIFICATION ACGIH: The recommended airborne exposure limit is Diethylaluminum Chloride is a colorless liquid which 2 mg/m3 averaged over an 8-hour workshift. ignites instantly on contact with air. It is often shipped in solution with a Hydrocarbon solvent. It is used as a catalyst WAYS OF REDUCING EXPOSURE and as an intermediate in the production of other chemicals. * Where possible, enclose operations and use local exhaust ventilation at the site of chemical release. If local exhaust REASON FOR CITATION ventilation or enclosure is not used, respirators should be * Diethylaluminum Chloride is on the Hazardous worn. Substance List because it is cited by ACGIH, DOT, * Wear protective work clothing. NIOSH and NFPA. * Wash thoroughly immediately after exposure to * This chemical is on the Special Health Hazard Substance Diethylaluminum Chloride and at the end of the List because it is FLAMMABLE and REACTIVE. workshift. * Definitions are provided on page 5. * Post hazard and warning information in the work area. In addition, as part of an ongoing education and training HOW TO DETERMINE IF YOU ARE BEING effort, communicate all information on the health and EXPOSED safety hazards of Diethylaluminum Chloride to The New Jersey Right to Know Act requires most employers potentially exposed workers. to label chemicals in the workplace and requires public employers to provide their employees with information and training concerning chemical hazards and controls. The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees.

* Exposure to hazardous substances should be routinely evaluated. This may include collecting personal and area air samples. You can obtain copies of sampling results from your employer. You have a legal right to this information under OSHA 1910.1020. DIETHYLALUMINUM CHLORIDE page 2 of 6

This Fact Sheet is a summary source of information of all WORKPLACE CONTROLS AND PRACTICES potential and most severe health hazards that may result from exposure. Duration of exposure, concentration of the substance Unless a less toxic chemical can be substituted for a hazardous and other factors will affect your susceptibility to any of the substance, ENGINEERING CONTROLS are the most potential effects described below. effective way of reducing exposure. The best protection is to ------enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also HEALTH HAZARD INFORMATION reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is Acute Health Effects sometimes necessary. The following acute (short-term) health effects may occur immediately or shortly after exposure to Diethylaluminum In evaluating the controls present in your workplace, consider: Chloride: (1) how hazardous the substance is, (2) how much of the substance is released into the workplace and (3) whether * Contact can severely irritate and burn the skin and eyes harmful skin or eye contact could occur. Special controls with possible eye damage. should be in place for highly toxic chemicals or when * Breathing Diethylaluminum Chloride can irritate the nose, significant skin, eye, or breathing exposures are possible. throat and lungs causing coughing, wheezing and/or shortness of breath. In addition, the following controls are recommended:

Chronic Health Effects * Where possible, automatically pump liquid The following chronic (long-term) health effects can occur at Diethylaluminum Chloride from drums or other storage some time after exposure to Diethylaluminum Chloride and containers to process containers. can last for months or years: * Before entering a confined space where Diethylaluminum Chloride may be present, check to make sure that an Cancer Hazard concentration does not exist. * According to the information presently available to the New Jersey Department of Health and Senior Services, Good WORK PRACTICES can help to reduce hazardous Diethylaluminum Chloride has not been tested for its exposures. The following work practices are recommended: ability to cause cancer in animals. * Workers whose clothing has been contaminated by Reproductive Hazard Diethylaluminum Chloride should change into clean * According to the information presently available to the New clothing promptly. Jersey Department of Health and Senior Services, * Contaminated work clothes should be laundered by Diethylaluminum Chloride has not been tested for its individuals who have been informed of the hazards of ability to affect reproduction. exposure to Diethylaluminum Chloride. * Eye wash fountains should be provided in the immediate Other Long-Term Effects work area for emergency use. * No chronic (long-term) health effects are known at this * If there is the possibility of skin exposure, emergency time. shower facilities should be provided. * On skin contact with Diethylaluminum Chloride, immediately wash or shower to remove the chemical. At MEDICAL the end of the workshift, wash any areas of the body that may have contacted Diethylaluminum Chloride, whether Medical Testing or not known skin contact has occurred. There is no special test for this chemical. However, if illness * Do not eat, smoke, or drink where Diethylaluminum occurs or overexposure is suspected, medical attention is Chloride is handled, processed, or stored, since the recommended. chemical can be swallowed. Wash hands carefully before eating, drinking, smoking, or using the toilet. Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for PERSONAL PROTECTIVE EQUIPMENT damage already done are not a substitute for controlling exposure. WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT. However, for Request copies of your medical testing. You have a legal right some jobs (such as outside work, confined space entry, jobs to this information under OSHA 1910.1020. done only once in a while, or jobs done while workplace controls are being installed), personal protective equipment may be appropriate. DIETHYLALUMINUM CHLORIDE page 3 of 6

OSHA 1910.132 requires employers to determine the * Diethylaluminum Chloride must be stored under appropriate personal protective equipment for each hazard and or other inert gas blanket as it will catch on fire to train employees on how and when to use protective when exposed to AIR. equipment. * Protect containers from physical damage; outside or detached storage is preferred. The following recommendations are only guidelines and may * Sources of ignition, such as smoking and open flames, are not apply to every situation. prohibited where Diethylaluminum Chloride is used, handled, or stored. Clothing * Metal containers involving the transfer of * Avoid skin contact with Diethylaluminum Chloride. Diethylaluminum Chloride should be grounded and Wear protective gloves and clothing. Safety equipment bonded. Drums must be equipped with self-closing valves, suppliers/manufacturers can provide recommendations on pressure vacuum bungs, and flame arresters. the most protective glove/clothing material for your * Use only non-sparking tools and equipment, especially operation. when opening and closing containers of Diethylaluminum * All protective clothing (suits, gloves, footwear, headgear) Chloride. should be clean, available each day, and put on before * Wherever Diethylaluminum Chloride is used, handled, work. manufactured, or stored, use explosion-proof electrical equipment and fittings. Eye Protection * Wear indirect-vent, impact and splash resistant goggles QUESTIONS AND ANSWERS when working with liquids. * Wear a face shield along with goggles when working with Q: If I have acute health effects, will I later get chronic corrosive, highly irritating or toxic substances. health effects? * Contact lenses should not be worn when working with this A: Not always. Most chronic (long-term) effects result from substance. repeated exposures to a chemical.

Respiratory Protection Q: Can I get long-term effects without ever having short- IMPROPER USE OF RESPIRATORS IS DANGEROUS. term effects? Such equipment should only be used if the employer has a A: Yes, because long-term effects can occur from repeated written program that takes into account workplace conditions, exposures to a chemical at levels not high enough to make requirements for worker training, respirator fit testing and you immediately sick. medical exams, as described in OSHA 1910.134. Q: What are my chances of getting sick when I have been 3 * Where the potential exists for exposure over 2 mg/m (as exposed to chemicals? Aluminum), use a MSHA/NIOSH approved supplied-air A: The likelihood of becoming sick from chemicals is respirator with a full facepiece operated in a pressure- increased as the amount of exposure increases. This is demand or other positive-pressure mode. For increased determined by the length of time and the amount of protection use in combination with an auxiliary self- material to which someone is exposed. contained breathing apparatus operated in a pressure-

demand or other positive-pressure mode. Q: When are higher exposures more likely?

A: Conditions which increase risk of exposure include HANDLING AND STORAGE physical and mechanical processes (heating, pouring, spraying, spills and evaporation from large surface areas * Prior to working with Diethylaluminum Chloride you such as open containers), and "confined space" exposures should be trained on its proper handling and storage. (working inside vats, reactors, boilers, small rooms, etc.). * Diethylaluminum Chloride reacts violently with WATER to produce flammable and explosive gases. Q: Is the risk of getting sick higher for workers than for * Diethylaluminum Chloride must be stored to avoid community residents? contact with ; ALLYL CHLORIDE; A: Yes. Exposures in the community, except possibly in ; and OXIDIZING AGENTS (such as cases of fires or spills, are usually much lower than those PERCHLORATES, PEROXIDES, PERMANGANATES, found in the workplace. However, people in the CHLORATES, NITRATES, CHLORINE, BROMINE and community may be exposed to contaminated water as well FLUORINE) since violent reactions occur. as to chemicals in the air over long periods. This may be * Diethylaluminum Chloride is not compatible with a problem for children or people who are already ill. STRONG (such as HYDROCHLORIC, SULFURIC and NITRIC); STRONG BASES (such as HYDROXIDE and POTASSIUM HYDROXIDE); ALCOHOLS; and OXYGEN.

DIETHYLALUMINUM CHLORIDE page 4 of 6

------The following information is available from:

New Jersey Department of Health and Senior Services Occupational Health Service PO Box 360 Trenton, NJ 08625-0360 (609) 984-1863 (609) 292-5677 (fax)

Web address: http://www.state.nj.us/health/eoh/odisweb/

Industrial Hygiene Information Industrial hygienists are available to answer your questions regarding the control of chemical exposures using exhaust ventilation, special work practices, good housekeeping, good hygiene practices, and personal protective equipment including respirators. In addition, they can help to interpret the results of industrial hygiene survey data.

Medical Evaluation If you think you are becoming sick because of exposure to chemicals at your workplace, you may call personnel at the Department of Health and Senior Services, Occupational Health Service, who can help you find the information you need.

Public Presentations Presentations and educational programs on occupational health or the Right to Know Act can be organized for labor unions, trade associations and other groups.

Right to Know Information Resources The Right to Know Infoline (609) 984-2202 can answer questions about the identity and potential health effects of chemicals, list of educational materials in occupational health, references used to prepare the Fact Sheets, preparation of the Right to Know Survey, education and training programs, labeling requirements, and general information regarding the Right to Know Act. Violations of the law should be reported to (609) 984-2202. ------DIETHYLALUMINUM CHLORIDE page 5 of 6

DEFINITIONS

ACGIH is the American Conference of Governmental NAERG is the North American Emergency Response Industrial Hygienists. It recommends upper limits (called Guidebook. It was jointly developed by Transport Canada, the TLVs) for exposure to workplace chemicals. United States Department of Transportation and the Secretariat of Communications and Transportation of Mexico. It is a A carcinogen is a substance that causes cancer. guide for first responders to quickly identify the specific or generic hazards of material involved in a transportation The CAS number is assigned by the Chemical Abstracts incident, and to protect themselves and the general public Service to identify a specific chemical. during the initial response phase of the incident.

A combustible substance is a solid, liquid or gas that will burn. NCI is the National Cancer Institute, a federal agency that determines the cancer-causing potential of chemicals. A corrosive substance is a gas, liquid or solid that causes irreversible damage to human tissue or containers. NFPA is the National Fire Protection Association. It classifies substances according to their fire and explosion hazard. DEP is the New Jersey Department of Environmental Protection. NIOSH is the National Institute for Occupational Safety and Health. It tests equipment, evaluates and approves respirators, DOT is the Department of Transportation, the federal agency conducts studies of workplace hazards, and proposes standards that regulates the transportation of chemicals. to OSHA.

EPA is the Environmental Protection Agency, the federal NTP is the National Toxicology Program which tests agency responsible for regulating environmental hazards. chemicals and reviews evidence for cancer.

A fetus is an unborn human or animal. OSHA is the Occupational Safety and Health Administration, which adopts and enforces health and safety standards. A flammable substance is a solid, liquid, vapor or gas that will ignite easily and burn rapidly. PEOSHA is the Public Employees Occupational Safety and Health Act, a state law which sets PELs for New Jersey public The flash point is the temperature at which a liquid or solid employees. gives off vapor that can form a flammable mixture with air. PIH is a DOT designation for chemicals which are Poison HHAG is the Human Health Assessment Group of the federal Inhalation Hazards. EPA. ppm means parts of a substance per million parts of air. It is a IARC is the International Agency for Research on Cancer, a measure of concentration by volume in air. scientific group that classifies chemicals according to their cancer-causing potential. A reactive substance is a solid, liquid or gas that releases energy under certain conditions. A miscible substance is a liquid or gas that will evenly dissolve in another. A teratogen is a substance that causes birth defects by damaging the fetus. mg/m3 means milligrams of a chemical in a cubic meter of air. It is a measure of concentration (weight/volume). TLV is the Threshold Limit Value, the workplace exposure limit recommended by ACGIH. MSHA is the Mine Safety and Health Administration, the federal agency that regulates mining. It also evaluates and The vapor pressure is a measure of how readily a liquid or a approves respirators. solid mixes with air at its surface. A higher vapor pressure indicates a higher concentration of the substance in air and A mutagen is a substance that causes mutations. A mutation is therefore increases the likelihood of breathing it in. a change in the genetic material in a body cell. Mutations can lead to birth defects, miscarriages, or cancer. page 6 of 6 >>>>>>>>>>>>>>>>> E M E R G E N C Y I N F O R M A T I O N <<<<<<<<<<<<<<<<<

Common Name: DIETHYLALUMINUM Contact your state Department of Environmental Protection CHLORIDE (DEP) or your regional office of the federal Environmental DOT Number: UN 3052 Protection Agency (EPA) for specific recommendations. NAERG Code: 135 * If employees are required to clean-up spills, they must be CAS Number: 96-10-6 properly trained and equipped. OSHA 1910.120(q) may be applicable. ======Hazard rating NJDHSS NFPA FOR LARGE SPILLS AND FIRES immediately call your fire FLAMMABILITY - 4 department. You can request emergency information from the - 3 following: REACTIVITY FLAMMABLE AND REACTIVE CHEMTREC: (800) 424-9300 SPONTANEOUSLY COMBUSTIBLE IN AIR NJDEP HOTLINE: 1-877-WARN-DEP DO NOT USE WATER ======POISONOUS GASES ARE PRODUCED IN FIRE HANDLING AND STORAGE (See page 3) CONTAINERS MAY EXPLODE IN FIRE Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; FIRST AID 3=serious; 4=severe In NJ, for POISON INFORMATION call 1-800-764-7661

FIRE HAZARDS Eye Contact * Immediately flush with large amounts of water. Continue * Diethylaluminum Chloride is a FLAMMABLE and without stopping for at least 30 minutes, occasionally REACTIVE LIQUID. lifting upper and lower lids. Seek medical attention * Use dry chemical extinguishers, soda ash, lime, or sand. immediately. * DO NOT USE WATER, FOAM or HALOGENATED extinguishing agents. Skin Contact * POISONOUS GASES ARE PRODUCED IN FIRE, * Quickly remove contaminated clothing. Immediately wash including and Aluminum Oxide fumes. area with large amounts of soap and water. Seek medical * CONTAINERS MAY EXPLODE IN FIRE. attention immediately. * Use water spray only to keep fire-exposed containers cool. Do not get water inside containers. Breathing * FIRE MAY RESTART AFTER IT HAS BEEN * Remove the person from exposure. EXTINGUISHED. * Begin rescue breathing (using universal precautions) if * If employees are expected to fight fires, they must be breathing has stopped and CPR if heart action has stopped. trained and equipped as stated in OSHA 1910.156. * Transfer promptly to a medical facility.

SPILLS AND EMERGENCIES PHYSICAL DATA

If Diethylaluminum Chloride is spilled or leaked, take the Vapor Pressure: 3 mm Hg at 140oF (60oC) following steps: Flash Point: Ignites spontaneously in air Water : Reactive * Evacuate persons not wearing protective equipment from area of spill or leak until clean-up is complete. OTHER COMMONLY USED NAMES * Remove all ignition sources. * Spills involving Diethylaluminum Chloride present a Chemical Name: highly dangerous fire and explosion hazard. Only Aluminum, Chlorodiethyl- personnel specifically trained should respond to situations Other Names: where this material is spilled. Chlorodiethylaluminum; Diethylaluminum Monochloride * Cover with dry lime, sand or soda ash, and place in covered ------containers for disposal. Not intended to be copied and sold for commercial * DO NOT USE WATER OR WET METHOD. * Ventilate area after clean-up is complete. purposes. * Keep Diethylaluminum Chloride out of a confined space, ------such as a sewer, because of the possibility of an explosion, NEW JERSEY DEPARTMENT OF HEALTH AND unless the sewer is designed to prevent the build-up of SENIOR SERVICES explosive concentrations. Right to Know Program * It may be necessary to contain and dispose of PO Box 368, Trenton, NJ 08625-0368 Diethylaluminum Chloride as a HAZARDOUS WASTE. (609) 984-2202 H4985 ------