Gerashtv & Miller. Inc
(Red)
>f ' 'V HEALTH AND SAFETY PLAN 1 REMEDIAL INVESTIGATION/FEASIBILITY STUDY
PREPARED FOR: AVTEX FIBERS, INC. FRONT ROYAL, VIRGINIA
D" ^ I REVISION:! JANUARY 0,1987
Gerashtv & Miller. Inc. GROUNDWATER CONSULTANTS ANNAPOUS. MARYLAND AR300808 GERAGHTYtf MILLER. INC. 1 HEALTH -AND SAFETY Pt AN , REMEDIAX INVESTIGATION/FEASIBILITY STUDY I AVTEX FIBERS, INC. r FRONT ROYAL, VIRGINIA
REVISION:! JANUARY 9, 1987 E
R. H. Hughes Jeffrey P. Sgtrabit, C.P.G. i Vlce*Prcsldent and Associate and Project c Corporate Coordinator Consulting Coordinator
MikePisarclk Brian V. Moran, P.E. Corporate Environmental Site Safety Manager Coordinator
AR300809 I s GERAGHTV & MILLER, INC
. :.' TABLE OF CONTENTS | -. . • --;- . .-... „,.,.-., , . . Page i .".,-" - • - -.
1.0 INTRODUCTION...... 1-1 12.0 HEALTH AND SAFETY PLAN ENFORCEMENT...... 2-1 • ;,.'>. '' '...;." Jl ' r '' ' ' ' - •> •" • " - '' 3.0 SITE SECURITY...... * .'. . . . * ...... N .... 3-1 D- h , , . . - , K + . » »t ;M ', ... '"i.-' - • "• ' • • 4*0 HA2AEDZVALUATION...... ^..^...*.,.,, 4.1 Exposure Pathways...... 4-1 4.2 Health Effects...... 4-5 • i .':. • i ' . , ' ,. . • 5.0 WORK ZONES ...... V...... 5-1 .5.1 Safety Zones....-...... -.*...... *... 5-2 5.2 Access..*....*..**.**...... *...... : 5-3 6.0 PERSONNEL PROTECTION...... €-1 7.0 RESPIRATORY PROTECTION...... 7-1 " -. . i - - r;,' i- ::,--• "• ' ;;/-, ; 7.1 . Selection. . . . . v...... 7-1 7.2 Respirator Training and Fit Testing...... 7-4 -'.-.,, ' • •' •• V. " ' . •1r..1i>i'>-'- .; • . - - *' ' • B.t CONTAKIKANT KONITORIHG.**. .*.*..,..**.,*...... *..... 8-1 f '• 6.1 Perineter Monitoring* .*..••."....**»«•••*•».**••* 8—1 i 8.2 Work Area Air-Quality Aasessaent.. ».»**•-..-.*». 8-1 8.3 Action Xevels...... 8-3 Li 9.0 HEALTH MONITORING PROGRAM...... 9-1 9.1 Medical Surveillance...... 9-1 D9 . 2 Employee Stress Monitoring...... 9-3 9 . 3 Effects of Lover Temperature Exposure...... 9-4 9.4 Effects of Sulfide Vapors...... 9-5 9 . 5 Rest ...... 9-5 10.0 DECONTAMINATION...... 10-1 10.1 Personnel. .*..,.**,...... *.**•...•,.«.«....« 10-1 10.2 Equipment and Vehicles...... 10-5 10.3 Decontamination Personnel...... Q.* n !Qr7 n 10.4 Decontamination Waste Disposal...... fllw u Sfo*-? u ( . 10.5 .Equipment Keeds******.. *..**.****.*.*..*...... 10-7 11.0 CONTAMINANT CONTAINKENT. . . *...... 11-1 12.0 COMMUNICATIONS.. ^*. ..*...... 12-1 GERAGHTYtf MILLER, INC t"£-
TABLE OP CONTENTS '. . (Continued)
Page 13.0 EMERGENCY PROCEDURES...... 13-1 13.1 Medical Emergencies. .Y»**T.*...... 13-1 13.2 Fire or AtmosphericrRalated Jleleas A* *..*<...*«...... <. 13-5 13.3 Alerting and Evacuation...... A.... 13-5 13.4 Important Phone Numbers...... 13-6 _..~. 14*0 air'i.w]!MTA'ituuiOTBES••••••*• »«••*••*...••••••*«•*•*•*• 14-1 P " ,. - , . . - ' ' !' . I 14.1 Viscose-Basin Sampling...... 14-1 14.2 Trenching Within Viscose Basins...... 14-2 14.3 Air-Rotary Drilling Locations (Rivermont Acres). 14-2. L> 15.0 RECORDKEEPING...... 15-1 HJI 16.0 ON-SITE TRAINING...... 16-1 APPENDIX At SPECIFIC CHEMICAL HAZARD DATA...... A-l i APPENDIX B: COMPATIBILITY CHARTS FOR PROTECTIVE CLOTHING...... B-l i.. APPENDIX C: AMBIENT AIR CONTAMINANT MONITORING DEVICE*.* C-l
RR3003M I GERAGHTY & MILLER. INC. ( I "' ' "• ••• " •'"' "'-• OFJTABLES . - - „ ; •-- - -.r- ;-- - , page 4 . -•.'_-;- .-.'.'': \< ..t'-,J "--:_•---• • . • . - • 1. Viscose-Basin Liquid Analysis From Kos. 5 and 6+.....*...... *...... ,...... 4-2 . Ho. 11 Viscose-Basin Jtoalysis* **«<.« «<.<.<.*«<..... *<...***.*•.* 4-3 \ P 3. Selected Chemical Data and'Safety-Related Information for Hydrogen Sulfide, Carbon bisulfide, flno. Phenol* »*«« ****** »_* *•*•»*• *..*• ._. *•••••••**•.*•***•• 4—4 4. Levels of Personnel Protection to be Employed During the Avtex Remedial Investigation...... 5-4 5. Guidelines for Selection of Respiratory Protection Equipment. .•.*..*...*...... •.,...«. 7-2 §6. Atmospheric Monitoring Devices to be Employed During the Avtex Remedial Investigation...... 8-2
LTST OF FIGURES n - „ JL* . Avxcx Jteste -:lMisi7is* •*•»••-•<..•»,» »^«*»»**)**»*.*»^^*^^»»»^»^ ' 1—2 2. Ceneraliced Location Kap of Avtex Fibers Facility*. •» 1-4 1 3. Site Layout Plan — Basin'Contents Characteritation and On-Plant Monitor Well/Piezometer Locations...... 1-6 111' 4. Site Layout Plan - Geophysical Characterization Program and Rivermont Acres Drilling Program...... 1-7 l& 5. Minimum Decontamination Layout Level B and C Protection...... ***.*...... 10-2 6. Minimum Decontamination Layout Level D Protection.... 10-6 7. Emergency Response Flow Chart for Medical Emergency** 13-2 8. Emergency Response Flow Chart for Fire and/or Explosive Hazard...... 13-3 \ , -**•. - Emergenc, y Report*...*..*«.*...... *..*...*...... ,. - AR3008I. O3-4 2
iii I. GERAGHTY & MILLER. INC PISTRTBUTIOK LIST
James Miller, EPA Region III, Philadelphia, PA I Patricia Krantz, EPA T Regional Laboratory, Annapolis, MD Robert Ceilings, Morgan Lewis Bockius, Philadelphia, PA L R. R. Hughes, Avtex Fibers, Inc., Valley Forge, PA 1 Michael Pisarcik, Avtex Fibers, Inc., Front Royal, VA x Ken Hinkle, Virginia State Water Control Board, Bridgewater, VA
Q y y c Section: 1.0 ^ . Revision: 1 <•". T; GERAGHTYfi? MILLER, INC Pagfce W* _•* _ ori/i/l > f 7 ; i '' •" 1.0 HKCRDBUCTIO" y / N ' • .. The Avtex, Front Royal/ facility manufactures staple and i filament rayon fiber* In the manufacturing process, two major chemical byproducts are generated and land disposed in ". < i on-site unlined surface,,impoundments. These byproducts are sodium cellulose xanthate-based viscose and zinc-hydroxide sludge (hereinafter referred to as "tine sulfate veludge"). c Prior to 19BJ, the wasta ^ viscose was disposed in surface impoundments. Since then," the waste viscose has been piped directly to the facility wastewater treatment plant. The zinc-sulfate sludge is stored in specific basins for sub- * sequent recovery, reprocessing, and reuse. The remaining * ' major land-disposed .item at .the LFront Royal facility is fly ash and boiler room solids* - ,
- ' - ' - *" "** __...--——! » ' \
The practice of land -'='•','•'disposin. g waste byproduct' s has been ^ ongoing at the Front Royal facility since 1940. Figure 1 is an illustration of the various impoundments on the Front : . Royal property. Eleven impoundments have been .used for liquid waste viscose deposition since 1940. Viscose Basins 1 through 9 were used J?y American Viscose, while Basins 9, 10, and 11, were teed fey both American Viscose and THC. Since the ; * acquisition of the facility by Avtex in 1976, only Basins 9 y and 11 have been used. Avtex has undertaken to recover for reuse a large proportion of off-specification viscose; this practice has \ greatly reduced the amount of waste viscose which is treated or disposed. Since 1983, land disposal of , liquid waste viscose has *been discontinued and discharged directly to the on-site wastewater treatment plant. : • section; 1.0 Revision: 1 Date: 1/9/P*1 Page 1-2
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AR300815 ..,.-:.. - -. '*. •-,, . .-• tT:-. - .Section: 1.0 ; Revision: 1 GERAGHTYtf MILLER JNC paoa fe^'J/!/?7
Avtex has contractefl, for the performance of .hydro- geologic studies in order to evaluate the source and extent of contamination which was reported to exist in domestic water-supply welle at the Rivermont Acres subdivision, located on the South Fork o£ the Shenandoah River across from the Avtex facility (see Figure 2). Avtex and its contractors > have completed this work in cooperation with representatives of the Virginia State Water Control Board and the Virginia c Department of Health. "-. -'^-\-J.-.;,; • •-, . •. "•'-' , •..;.- •------.-;-'" e Although Avtex has presented information to EPA demon- strating that no threat to human health or the environment now exists, EPA,has placed the Avtex facility on the National Priorities List. .Avtex has discussed with ;EPA the tasks which EPA might require or perform in order to determine the - existence, nature, and extent of any imminent and substantial endangerment to human health or the environment. ; These discussions have .resulted in the preparation of the Remedial Investigation field study. The objective of the field study Is to gather sufficient information to implement _ . a feasibility study designed ,to select appropriate remedial measures at the site. .The: following irorfc tasks will t>e - performed as part ^of this field «tufly. L . Geophysical Survey - Cabphycieal aethods will be used y on the facility grounds, in and around the various impoundments, and on the Rivermont Acres floodplain, c in an, effort to collect data regarding fracture systems, cones of degraded ground water,, areas within each basin of concentrated wastes, and basin pro- ' :, filing.1.- ••7-"0':!Kr'''•-'•*: - " ' ' •: '•"/,•'•- ' ' - •;
,. ^:;4 AR3003I6 i y '.:.-"•• - - • . . .1 - -• V^_^ _j^ / ^ • • ••.-.-..- . , .„,.. \ ..'-.,.". £*. ~ •----
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Fiqure 2. Generalized Location Map o* Avtex Fibers Facility FdSpW. * —**.«. ..-.—.*.- Section: 1.0 £*/.? I ' Revision: 1 *'*' GERAGHTY & MILLERJNC *•••;• Fag._ e i—PaJ*»i'?/!p or i—/7 "• • .--. ?< . • • • ^Retaliation **Ten piezometers * vill be installed along the eastern bank of the Shenandoah River. /The piezometers vill be installed via hollow-stem auger drilling. Alluvial Monitor-Well Installation - Additional alluvial monitor veils vill be installed downgradient of suspected cource-area basins. The-monitor vill be installed via hollow-stem auger drilling. [ Trenching Within Viscose Basing •*»- test-pit excavation within selected basins vill be performed to improve/enlarge the existing basin dewatering system and to aid in characterizing the basin contents. j:7 \ • . .. ' .. "Hivermont Acres Well Drilling *»:Thrce bedrock veils will be installed via air-rotary techniques within ' '.";.-..•• ••*-.'-•• the Rivermont Acres subdivision contingent upon results of the geophysical study. Vie cose Basin Sampling - Core camples of the contents of Viscose Basins 1, 2, 3, 7, 8, 9, 10, and 11, will be performed via hand-operated sampling tools and/or a portable auger |rig and plug sampler. WorX vill be . frcfHi a jplntfionB or Jbaxae* t - ~ " ' . . Aquifer Prnnp Tests -± Will be performed on selected-' y veils to confirm/determine localized aquifer con- ditions. . Ground- and surface-water samples will be collected E ' and submitted for analysis upon completion of monitor veils>and piezometers. '
: Work task locations are presented in Figures 3 and 4 under "Exclusion Zones*. • ! . _ ' AR3008I8 Sections 1.0 Revision: 1 Date* 1/9' Page 11-6
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R3008I9 Section: 1.0 Revision: 1 Date: 1/9/87 Page:1-7 of 1- Section: 2.0 -.-A/U i Revision: 1 i#?rf) GERAGHTY # MILLER, INC Page JLi'of^i. J
2.0 HEALTH AND SAFETY PLAN ENFORCEMENT
Caraghty ft Miller, Inc.. (G&M) vill be responsible for its personnel and subcontractors' adherence to the Site Health and Safety Plan (HftS) during the investigation, and vill ensure that all vork is; performed in accordance with the health and safety requirements described herein, th£ current ' edition of the Standard Operating Safety Guides prepared by - ~the EPA Off ic e of Emergency and Remedial Response, Hazardous Response Support Division, and all Federal OSHA, State and local health and safety regulations.
The following personnel vill be responsible for imple- mentation, maintenance, and enforcement, of all aspects of the HftS prograa for this project. Mr. Jeffrey Sgambat, Geraghty ft Miller, Inc., Senior ^-^ Project Advisor Mr. Mark Wagner, Geraghty ft Miller, Inc., Project Manager - » Hr* Robert »rf#ht, Geraghty 1 Killer, Inc., Project Scientist --':•.. Mr. Brian Koran, Geraghty ft Miller, Inc., Site Safety . Manager Mr. Mike Pisarcik, Avtex Corporation, Environmental Coordinator - Mr. Andrew Barber, Geraghty ft Miller, Inc., Corporate Health and Safety Officer.
flR30032l wdtt-ji,•-....*, ... < Section: 3.0 I Revision: 2 wed) GERAGHTY # MILLER, INC. pa?e Wcf7^!7
3.0 -SITE SECURITY
All personnel, visitors, regulatory agency observers, etc., »ust first;be approved for site entry by the Avtex Environmental Coordinator and GtM Project Manager. All I individuals entering vork; areas and decontamination zones must meet medical surveillance and training criteria set • forth in this document, ac enforced by the Site Safety r Officer (£50)« The ^SO has the ^responsibility for ^ final Cite* entry approval and for removal of unauthorised person- [i nel, through the aid of Avtex security personnel.
Entry and exit from the Avtex cite is restricted to the - main plant yate, . vnere ^Avtex security personnel monitor-ail •individuals entering and leaving .the plant. Unauthorized individuals could conceivably enter the vork areas via river access along which there ie no security fence. Avtex b security personnel will be notified in the event of un- authorized entry and vill take appropriate measures to remove unauthorired .individuals* :
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SR300B22 Section: 4.0 Revision: 2 GERAGHTY & MILLER, INC. Pa. J1 Q|/9/.8s7
4.0 HAZARD EVAIAJATION
The principal substances of concern at the Avtex site and off-site investigation areas are hydrogen sulfida (H2S), carbon disulfide (CS2), and phenol. Representative tf analyses t of viscosa basin constituents .are given on Tables 1 and 2. Chemical handling and toxicological data for the^se three substances are presented in Appendix A, with selected c properties shown oa Table 3*
0 4.1 Exposure Pathways
The primary exposure pathway for both CS2 and H2S is via inhalation during drilling operations in the -viscose basins* As shown in Table 3, odor thresholds for H^S and CS^ are low; however, a deadening of the senses occurs upon exposure to H2S, rendering this, detection method unreliable. Given the ^^ low health-exposure limits for these substances, and their principal exposure pathway, respiratory protection, coupled with atmospheric monitoring in work areas, vill be employed. The degree of respiratory protection to be adopted vill be I dependent upon monitoring results and the drilling/excavation methods employed, but may consist of positive pressure- ; supplied air systems for high hazard areas or full-face, y canister-type, air-purifying respirators specifically for CS2 and HS2.
Carbon disulfide may also be absorbed via dermal exposure to CS2 -contain ing fluids or solids. Protective garments to be employed .within vork areas and contamination reduction areas will he chemically resistant to CS2j protec- tive garments and measures are outlined in the following sections. raSf~i ,
f ;•'.:.* r 1 Section: 4.0 Revisions 1 GERAGHTY & MILLER. INC. Datei 1/9/87 j ' . Page j 4-2 of 4-: . K _ TABLE 1. 1 VISCOSE BASIN LIQUID ANALYSIS FROM KOS. 5 jon><+
1. Parameter (mg/1) Basin 5 Basin 6
t Chloride " «,«70 2,297 E Sulfate ; 3,000 4, (fOO «_• Alkalinity a»isi M.44w ^* 9^ P TDS 47,108 18,014 r TKN 1.4 2.1 y Sulfide 932 291 Pbenolics ' ; .-'-" i'.B"" 1.0 •i /TOC) 2,350 540 '" 1^-^ Arsenic 0.3 0.1 E Zinc 0.2 0.3 Li .Sodium 16,100 5,600 ^ Hanganese ~ "'-Oil <0.1 n' :COD t^*20 3^550 TSS 796 65 t TVSS 150 40 E "a. <100* <100* ... . + January 1984 Analysis * * Measurements is in ug/1
flR30082l4 Section: 4.0 GERAGHTY & MILLER, INC Revision: 1 Date: 1/9/87 Page:4-3 of 4-5 TABLE 2 • NO. 11 VISCOSE BASIN ANALYSIS
June, 1984 1983 Composite Analysis _ ...... PH* 12.0 Total Solids 63,478 194,500V 6,556 88,400 Alkalinity as CaC03 45,000 31,718 Sulfide 2,574 1,834 Sulfate 2,600 308 Chlorides 6,000 4,732 Total Phenols 2.01 0.13 COD 6,580 11,500 TOC 1,730 5,712 CSj 46-15 Na 22,000 18,300 Sn 5.1 ~ 30 Nitrate as N <50 - As 0.40 <0.01
All results reported in mg/kg except *. Section: 4.0 GERAGHTY fir MILLER, INC. Revision: 1 Date: 1/9/87 Page: 4-4 of 4-5
I ••-..: SELECTED CHEMICAL;DATA AND SAFETY-RELATED INFORMATION I * FOt»rtR» HYDROGEirvft»«*^«»N» SULFIDE^»»» «••&«, CARBO—- —.—-— N DISULFID— — —— — - E AND PHENOL
I. ,_ Hydrogen Carbon : Parameter ' " Eulfide Disulfide Phenol
I Threshold Limit Value (TLV1) C —..SSLj ^ i?.-14 . i30? (vkin<«***)> ;U_ « (Bkin) Short-Term Exposure Limit (STEL)1 ^ ' 15 - 10 (Skin) 21 - 38 (skin) w Odor Threshold^ (ppm) .... . ,^,008-0,35 -, l^a -- .:• 0.05 ppm P Atmospheric Concentration - " Immediately Dangers to ' - ^ Life and Health (IDIfi), ppm ; 300 500 |j Merck Index Number2 4709 1795 7115 Explosive Limit, Percent .' - •-- • . -'••- -Lower - .• "*;" .*. .. 4- •.}. ^., -ti, ---^.-4. ,. «*« 3 •...., \~. * ----... -,-i „ ~ a. - LtY ••-• - -.--..•-••',-48 . 50 ( - .*: .,-*.6. Permissible Exposure Limit, -ppa , -;V.^j>;rCTaD/io-aiin- (OSHA Time Weighted Average), :
1985-1986 --,,-_——— and Industrial Hygienist
. . .•..'.'•••• ,'' }''r-..:- ?;-'•' • . ' -1 - - ' " - "• r *See Referenced Data, Appendix A
AR300826 i»»at-"i_ . -^.w«--*^ . Section: 4.*0 Revision: 2 '. GERAGHTY 6? MILLER, INC. p.g.
Phenol may ba absorbed - through dermal and respiratory I pathways* As shown on Tables 1 and 2, phenol concentrations are generally low, and do not approach the exposure limits I. given on Table 3. At these concentrations, exposure to phenol via respiratory pathways is believed to ba minimal. Protective clothing to b« used for protection against C$2 vill also serve as protection against phenol (Appendix B) . £ C Hydrogen sulfide and carbon disulfide primarily affect the central nervous systed, and produce similar effects upon exposure. Exposure to these substances above recommended i concentrations may,: lead to a variety of general symptoms, some of which are nausea, restlessness, vomiting, dizziness, and fatigue* Convulsions, unconsciousness, and death may \ result from high acute or chronic exposures to high levels of ^^ these compounds.
In addition to direct physical affects upon exposure, disulfide has been shewn to be teratogenio and mutagenic. - neither H^S nor CS^ have been identified as carcinogenic to humans. Detailed tShenical, physical, and health effects of H2S and CS2 are presented in Appendix A.
Phenol is a highly toxic substance with serious physical C effects occurring with exposures in excess of established limits. Physical effects upon exposure include lung, kidney, liver, and spleen damage, or central nervous system collapse and death, with dermal exposure of as little as 64 square .inches of skin* Pulmonary edema may result from inhalation of elevated concentrations of phenol . Section: 5.0 I Revision: 2 GERAGHTY & MILLER. INC. Page s,t* *of -_
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_• The project vork site vill be divided into three basic vork rones: . ;- 1* Support Zone .,. i . 2. Contamination Reduction Zone 3. Exclusion Zone. ;: ; r Each vork xone- vill .£>« clearly .delineated ~by the use of signs, markers, rope and/or fencing, in accordance vith B Figures 3 and 4. The movement of equipment and personnel between zones vill be restricted to those both approved and Uil necessary. • • rrn . . .These vork -zones are defined as follows: m^ purport Zone - This area-includes the entry road> and |g all areas not included, within the Contamination Reduc- tion Zone and Exclusion Zones. On the Avtex site, this [' •--" area extends .eastward from the Norfolk and Western . Railroad ijrade, aiid vill InclTjfle lunc.h and shower areas.
T.efluctlon tone •• ttoe area between the Support Zone and the Exclusion Zone which serves as a y transition area betveen the contaminated and clean zones. This vill include the equipment decontamination c pad and personnel decontamination area and trailer. This .area vill be located at the vaste treatment plant (see Figures 3 and 4). ,..
Exclusion ?ones - These include all areas vhere investi- gative vork is to be performed, and are shown on the Site Layout Plan, Figures 3 and 4. 6R30Q828 Section: 5.0 Revision: 1 GERAGHTY & MILLER, INC. >
Due to the limited area involved for most tasks,- each exclusion zone vill be subdivided into work areas. Each work area within an exclusion zone will ba cordoned off via flagging, fluorescent cones, or other similar means during performance of the required task. Activities and resulting waste production (cuttings, eta.) will be contained within these work areas. Only authorized investigative tean members and individuals will be allowed within exclusion zones and/or vork :- areas during the field vork, > vith site security per- formed by the Site Safety Of fleer and plant security person- nel.
5.1 Safety Zones
Each exclusion zone has bean classified into safety zones, which corresponds to the levels of protection dis- .j cussed under PERSONNEL PROTECTION. Criteria for determining zones are listed below. Protective equipment will be specified for workers in the Exclusion Area on the basis of location or operation or both.
Zone R. Maximim. respiratory protection required sad low probability of skin contact. a* Where atmospheric concentration of contaminant is known, and the concentration of contaminants is greater than the protection factor (PF) for - air purifying respirators, or atmosphere is oxygen deficient (less than 19.5 percent oxygen) . Supplied air-respiratory protection is required in Zone B.
b. Safeguards preclude splashing of contaminant on the skin or in eyes of individuals. I Section: 5.0 I Revision: 1 f GERAGHTY # MILLER .INC. _a ?!|e:,yi/!7 i. • i .,,"•-' yage ^^_;[_ 01 jj^i»
• - . Zone C. ' •••- -.• '•"."" " _ . , • • [ a. Air-contaminant levels are being monitored and do not exceed the protection factors of air- : purifying respirators. :•>-•- b. The contaminants have good warning properties. i ' c. The contaminant is not known to be absorbed through, or be toxic to, skin. ' v d. A reliable history of prior entry exists t vithout acute or chronic effects on personnel. Tone D. Can only be Included inside the Exclusion Area, if there is no requirement for Level A protec- tive equipment, and if there is no requirement for Zone B or Level B protection other than a restricted area vith en oxygen deficient '-v.,t, ,. . atmosphere.- .__ '••"'•'""."" a. No known airborne hazards present; and, .there is little or no potential for release of an airborne contaminant. - b. Work function precludes splashing.
Safety rones ere presented on Figures 3 end 4 and ere .summarized in Table 4. Xo the case irficre multiple tasks vith I: varying safety requirements are performed concurrently vithin a zone, the higher level of protection vill be employed, unless monitoring of both activities :on an individual task C basis is being performed. 5.2 _ Access . ..;,, . .-*;' .":n^.vp...r ~^-.'.!"'; .^-_ \.... ^ -," ••:-. , .-. -
Access to and from vork area and. CR. zone are via established roadways. ^Access should not be a problem during this investigation. _ M^ 1 - , -, . flfi300830 Section: 5.0 Revision: 1 GERAGHTY.? MILLER, INC TABLE 4 y. " ' —. :~. . 1ZVELS OF PERSONNEL PROTECTION TO BE EMPLOYED DURING THE AVTEX REMEDIAL INVESTIGATION
] Zone of Designation Area of and Respiratory r Task Activity! Level of Protection Protection* *> Geophysical Survey E,0 B,C 3,4* Piezometer
Rivermont Acres Drilling 0 C 3,4* Source Area Monitor- Well Installation E C 2 Viscose'Basin Coring 1 Sampling £ B 3,4* Trench Excavation within Source Areas E B 3,4* Well/Piezometer/ Stream Sampling E,O C 2
Reduction Area rr C C Suppuxt Area *"' » D
E Exclusion Area/within Plant y C Contaminant Reduction Area 0 Offsite - Rivermont Acres s Support Area 2 1 No respirator protection required 2 Level C Protection with ongoing monitoring to determine the need for respiratory protection 3 Full Level C respiratory protection,with monitoring •*•-'«-. Positive-pressure, self-contained, breathing apparatus . with monitoring (Level B protection) •Special provisions - see text All respiratory protection levels may ba upgraded or downgraded, depending upon monitoring results and SSO approval RR3DQ83 I Section: 6.0 I • - * •• Revision: 2 ' v,"'< GERAGHTY (^MILLER, INC Pagfc-e 6*f^*'^?7,81 or fi-3 7 V I ..-.-.. _.. «.0 PERSONNEL PROTECTION .. / '. ., ; The level of personnel protection to be employed by the investigative team has been selected to provide for the safety of field crews performing specific tasks, vith tasks requiring greater potential to contaminant exposure to be I performed under higher levels" of protection. Levels of r protection correspond to the criteria set forthvfor the
[I The following protection levels will be employed vithln the Service, Contamination Reduction, and Exclusion Zones, as U given on Table 4. , - - ; -•,:,,.-•»••:• . . . . • ... L -'•*. •• • • ', {'-- * i- - • . * ... § Level P Protection:- * • ^ • r - Work Clothes ''***'* i •. **"' \^ - Work Boots - steel toe" and shank £j * Hard Hat and Goggles • B » Coveralls (Tyvek, TO), if required by the 6SO Level D protection vill _be employed within the Support Zone, ' / /end during certain• remedial investigation tasks, es-given [ . Table 4. ;
frevcl C Protect ion i ^^ ^ -Full-face, air-purifying, respirator, (MSHA/NIOSH . approved) with en " appropriate H2S and organic vapor canister (KSA No'. GKC-SS-1, color coded yellow with gray stripe around top and orange stripe around bottom, or approved equivalent. - Work Clothes --f^-r-,,. - Coveralls vith long eleeves .chemically resistant to acid, caustic, CS2 (Saranex *•*)
fiR300832 Section: 6.0 Revision: 2 tl'-« GERAGHTYfi? MILLER, INC. Page 6-2*' —— - Gloves .Outer-chemically resistant to acids, caustic CS2 (Nitrile) . Inner-chemically resistant (PVC) - Boots • ' :" ' . Inner-steel toe and shank . Outer-chemically resistant to acid, caustic, CS* (Buna-N, Nitrile) • - j- . - Hard Hat , v -.All boot, coverall* and glove Joints will ba sealed with . duet tape. Level C protection vill be employed for nearly all work- area tasks, except during specific high-hazard activities (trench and test pit excavations), and where Level D protec- tion is specified. Level c protection will ba upgraded to Level B by the Site Safety Officer, if found to be necessary . \ via monitoring results. Full-face, air-purifying, respira- tors may be required for work in Level C areas, a* determined , * via
• .Protection! - Pressure-demand-type, self-contained, breathing apparatus (MS HA, NIOSH approved) * Coveralls with long sleeves, chemically resistant to acids, bases and CS^ (Saranex™) • Gloves . Outer-chemically resistant to CS2, acids and bases (nitrile) « Inner-chemically resistant (PVC)
AH 3 0083 3^ I Section: 6.0 * Revision: 2 w• > GERAGHTY©' MILLER- ;,, INC •Pag _ e. 6-3*£• o»f —J/i/i6-3 7 . " - "Boots ' , . - . ..„';_.,...... ; J • Outer-chemically resistant to CS2, acids end bases * (Buna-N, nitrile) • Inner-steel toe and shank I - Hard hat a I- All boot, glove and coverall joints vill be sealed . vith duct tape. 7^ ^ Level B protection is to be employed for trenches and L test-pit, activities during -vhich potential exposure to CS_j r end:H2S 1« greatest i Other, ^vork areas may be upgraded to [. Level. , B, as .....required. '-Vi» a•'• - ,-•,-.-..-•-atmocpheri. c monitoring• - : - . Level B |\-- . protectio• -• n ma• y b• e downgrade...,a . - - d- . to Level C, based on the 1 decisio, • n of the• BS• O end vork-are•:.--•.-a aonitorin- g results. iHi ' . •. , " - • ,.....:.: -.,-;. . •-,".... .- • - . - ..--.-•. c
fiR30083l! Section,. Revision: GERAGHTY fir MILLER, INC. Pagft ffi'p
7.0 RESPIRATORY PROTECTION
The basic purpose of any respiratory protection equip- ment Is to protect the respiratory system front harmful * airborne physical or chemical agents. They provide this protection by removing contaminants from tha 'air before they are inhaled, or by supplying an independent source of respir- able air.
Due to the potential exposure levels and potentially poor combined warning properties of the contaminants present at Avtex, a program of judicious respirator use, combined vith vork-area atmospheric monitoring, will be implemented.
7.1 Selection
Two types of respirators are to be employed during the Avtex Remedial Investigation Program: 1) Full-face, canister-equipped, air-purifying, respira- tor 2) Positive pressure, self-contained, breathing appara- tus fSCBA). The selection of respirator type (air-supplying versus air-purifying) vill be dependent upon atmospheric levels of contaminants and oxygen, as determined by atmospheric monitoring. Air-purifying respirators (MSHA/NIOSH approved) vill be employed in those areas vhere atmospheric contamina- tion by CS2, H2S, and/or phenol, fall within tha ranga given on Table 5. Under no circumstances vill air-purifying respirators be used in work environments with less t*j£fi 3-8$ 8 3 5 I Section: 7, I ; Revision: *.„ GERAGHTY & MILLER, INC. pa ft fS****'*]?**
5 ] GUIDELINES FOR SELECTION OF RESPIRATORY PROTECTION EQUIPMENT
» L H "' r • . ,J •t1,^* ~ . ,'-'-" Action Level Maximum for Permissible Contaminant Protective Respiratory Contaminant Oxygen of Concern Device Protection1 Concentrations^ Content i ~ fupnrt f CS2, H2S Kone 10 A >1«.5 Full-face; 300 " : >19.5 air- purifying, respirators i . c •? ' ;• Phenol 550 X19.5 Pressure- ! 300 demand 6CEA § Phenol 250 j iKaximum permissible concentrations .for air-purifying respirators i are Threshold Limit Value x 50 (Protection Factor), 4or tha IDIfi — - -concentration, vhichever
. r f "',"> t •i- '
flR300836 Section: 7*0 / Revision: 1 *"';«• u'^i GERAGHTY & MILLER, INC ' ^ J
percent oxygen, or in areas where atmospheric contaminants exceed the maximum allowable concentrations on Table 5.
If ambient air conditions exceed maximum allowable concentrations for air-purifying respirators, tha personnel will withdraw froa the work area until concentrations of vapors ia the Jbreathing- zone .return to levels acceptable to Level C personnel protection. Should the concentrations of vapors in the breathing zone not return to acceptable levels within one-half hour, the SSO will inform the project manager to upgrade personnel protection to Level B Protection employing pressure-demand SCBAs In order to continue vork. Likewise, the level of respiratory protection nay ba down- graded, as determined by the SSO, based on on-going, work- area, air monitoring.
_ The only canisters to be used in conjunction vith full* face , air-purifying-type respirators are MSA-type GMC-SS-1 canisters, which combine organic vapor/acid gas-removing compatibilities with a high-efficiency filter. GMC-SS-2 canisters are color coded yellow with a gray stripe around the top and an orange stripe around the bottom of the canister. No other type of air-purifying canister vill ba permitted without proper review and authorization by the Site Safety Officer. A R 3 0 0 8^. Section: 7*0 Revision: T4 u . GERAGHTY & MILLER, INC Page i '°' J ' ,-- . . ••.."" -...' I Pressure-demand SCBA are to be used under conditions I vhere atmospheric-contamination exceeds maximum permissible concentration for air-purifying respirators, or when there is | less than 19.5 percent oxygen measured in the working area. r Suc. h area•s nay include •"th - e• f.'viscos. -..' e basi... n trenchin• '•g locations, L j basin sampling points, and ;jalr-«otary;tarilllng JBethods. I" ' ; • ' ; '••''"••:.••;:!." ; ".'." '.. ."-.':; Ei 7.' 2 Respirato' "• r "':Trainin" .''.'"':-'-•.g and "Fi t Testin• g-•'••• • • '• •••• " UJ ...... •-• - . - -...:. Each individual to be wearing a respirator vill be HI trained to use the device (c) to be used, which vill include ~ i . - • -•' j L v:;r:-1:* .' . ' : '' rS-^ proper respirator care and maintenance, limitations of the ** respirators, both air-purifying and air-supplying, and how to ( fit-test after donning the rcBpirator. All personnel I- • requiTe. .d -"-" t•o -use respirator' .-'.. y- - . protectioI"' •: ' - n. vil'"•••l hav> e a- recor->"'"' d of f ,' • • -r ; ' - ' '; ' " } , vritten .approval -:froan. a ijaalifif!d physician that -the ln- . dividual is capable of safely vearing a respirator. Ill r Prior to project startup, all field personnel vill be Issued a respirator, which shall remain in their possession • throughout the field program* Each respirator user vill be qualitatively f it-tested to .assure proper respirator selec- tion prior to vork startup. T -.- , \ &R3Q083B Section: 8.0 Revision: 1 Date: 1/9/87 GERAGHTY fir MILLER. INC Pag. 8-1 of 8-4 ,-
8.0 CONTAMINANT MONITORING
8.1 Perimeter Monitoring
Background atmospheric concentrations of CS2, H2S, and volatile organic substances, vill be conducted by Avtex personnel prior to _RX startup, using equipment identical to those employed by GUM during the RI field vork* Measurements vill be made downwind of the exclusion zone during daylight hottrs at one*honr Intervals for a period of one week. Results of the atmospheric monitoring program will be compared with perimeter monitoring program data collected during the RI field work to assess the migration of work- • released contaminants off-site and to aid in determining the potential for releases during remedial action. ~
Similar air-quality measurements will be made during \ field investigations, sampling locations vill be downwind of field activities, along the exclusion zone restricted-access- area boundary. In addition, to the .above-mentioned, perimeter monitoring, Avtex will monitor a weather station at the plant which vill measure and record, at a minimum, barometric pressure, vind speed, humidity, and wind directions, through- out the duration of the Remedial Investigation.
8.2 Work-Area Air-Quality Assessment
Air quality within active work areas will be con- tinuously monitored during activities with direct-reading instrumentation (see Table 6 and Appendix C) . Work-area atmospheric monitoring during high hazard opar at ions (vis- cose-basin sampling* excavation, and sampling of trenches in AR300839 L- Beetioni 8.0 Revisions 1 GERAGHTY & MILLER, INC. or *B- W ' • " •••-•• ' ' '
{ ATMOSPHERIC MONITORING DEVICES TO BE EMPLOYED DURING I. tHE AVTEX REMEDIAL INVESTIGATION ' .
r Monitoring , - ' Range of L' Parameters Method < . Instrument 'Detection
{j . Organic Vapors . Photoionltatlon BNu O-100 PT. Organic Vapors Photoionitation Photovac TIP 0-100 ^ Organic Vapors Flame OVA 0-100 lonization ^ - B, - - -., : : • • .-: . ;'.;.•:-.'. : - " -• ••'' ' ; •'-. -• Carbon Detector lube Draeger Pump 6-50 - Disulfide • . .__ :....-, .1" ,. and Tubes tm or Equivalent , Hydrogen Detector Tube Draeger Pump 0-1000 >^-^ Culfide . - •:'• »-.,:, tr;ci- - ;and Tube or -••• ' Lj Equivalent
^B , . • J.. .. *- •« * • ' ' ' ' ' •' ' l " ' • ' : ™^ ' " i C^* ' ' . - 1 f] E^losive Cft« H»at Filament KSA Model 2A 0-100 :.|,! " . - . ~~; ,. -,-Cr Xquivalmnt - . Percent
n oxygen ludox . J»ortable Com- « bustible Gas Percent and Oxygen Oxygen Alarm, KSA t - . * , .- , ' ;• •:-.'".v,;^b' • '.-Model 260:or~" •• Equivalent I
AR30Q81.0 Section: 8.0 Revision: 1 GERAGHTY & MILLER, INC
viscose material,, air-rotary drilling of Rivermont monitoring veils) will include tha following parameters: • ... CS2: CS2-specific Draeger Tubes _ . H2si direct-reading visual and audible H2S feftters (see Appendix B) . Combustible Gas: explosimater (MSA Model 6A or approved equivalent) > . O2: battery powered, direct reading oxygen meter • Organic Vapor: OVA, HNu, Photovac TIP, or equipment. .. . x. .
Monitoring during other wort tasks vill consist of the following: . CS2: CS2-spacific Draeger tubes . H2s: direct-reading visual and audible H2S maters • Combustible Cast explosimater • * Organic Vapors: OVA, HRu, or Photovac TIP* — - ' " ' \ Work-area atmospheric monitoring vill consist of measuring atmospheric contaminants in the worker breathing space, and down. Or alongside, boreholes and pits/trenches.
; i*3 Actlim Levels .-;*".
Where atmospheric contaminants exceed the threshold r limit value (TLV) for a substance,, full Level C Protection vill be donned. This protection consists of an air-purify- |. ing, full-face, respirator vith approved canister, as des- cribed tinder "Respiratory Protection*. !
AR3Q081+1 Section: 6.0 Revision: 1 ^ GERAGHTY & MILLER, INC PagPaoee l^fi-_ „ _„ (Red)
If ambient air conditions exceed vaxi&um allowable i- concentrations for air-purifying respirators, the personnel f will withdraw from the vork area, until concentrations of vapors in the breathing cone return to levels acceptable to L' Level C personnel protection. Should the concentrations of a - . . • . L, : >. i^ •• :-. ,• • .,.;•' * ' • • . ... vapors In the breathing cone not return to acceptable levels y -"--, vith in one-half ixour, the fiSO vill inform the project manager im to upgrade personnel protection" to Level fe Protection, - employing pressure-demand $CBA to continue .vork. Likewise, F] the level of respiratory protection may be downgraded, as • determined by the SSO, based on on-going vork-area air PJ • • '• ** -• >• " : ' aonitoring. Where oxygen level* less than 19.5 percent are ^~J measured, positive-pressure SCBA Bust be used. •IT *.•";•' Clf explosivity readings greater than 20 percent of the '...•*.,'-''' .'.--••'.' _ . -. Lower explosive Limit (I£L) are detected, a very careful [. • - aurvey of tha area Bust ;t>e/Bade. Readings approaching or exceeding 60 percent LEL are cause for immediately vith-' llii drawing personnel and notifying the emergency, fire, and n explosion units. The Site Safety Officer must be consulted before continuing operations.
flfi3008U2 Section: 9.0 Revision: 1 GERAGHTY tf MILLER, INC ' • f^'^'f^f 7 —— ———
9.0 .HEALTH MONITORING PROGRAM
9.1 Medical Surveillance
All. G&M employees participate in a comprehensive health- monitoring program. Each employee is given an annual medical I examination. Dependent on specific vork assignments, semi- annual and specific biological and/or chemical Boni-fibring may L also be required* - D The basic Bedical examination consists of tha following: • Personal, family, and environmental history . Hands-on physical examination * Snailen'a eye examination - • Pap smear (females over age 21) * Hemoccult testing (over age 40) . Laboratory testing: A. Complete Blood Count: Red blood count White blood count C .Differential screening HemogfloMji Hematocrit B. TJrinalysist . Sugar y Albumin Specific gravity c Microscopic C. Laboratory Chemistries: A/G Ratio Albumin Alkaline Phosphatase Bilirubin, Total . Calcium Chloride flR3008U3 [Section: 9,0 * . Revision: GERAGHTY # MILLER, INC of f Cholesterol ^ I Creatinine I. CGT Globulins - - - , •- - - ' ClttCOSa ,.-• '-.:*,—'•;:.! . - Iron Lactic Dehydrpgenase (LDH) I - Phosphorus L' Potassium — •• Protein, Total n SGOSGPTT :: ._ .•..&-. -.. , Ij . '""-••-•••-•- L__ Triglycerides EUrea Nitrogen {BUN) Uric Acid . The results of the examinations are reviewed by phy- L sicians who specialize in occupational health. A letter HI summarizing the physician's opinion regarding the employee's , health is issued; this letter Includes the physician 9s fc"N— - ' .opinio n- fa. s: - to whethe- r ..--•or• no: •t .•••f-1t<- the- employe. • e should.,.• be preclude"d r from wearin. g respirator.. /y - protectiov^ n as required by OSKA 4.. . .1910*134 and i»l 0.100 1-104 6. -Results of the physicals anfl n physicians1 written rerommendatlons are cco file vith the CtM U] ;• ' Bealth- and •,•-....Safety Manager- ^ ', ._£_.' •; ".-----•- '- • ' . ; - „,...— .. — ' ,- ~ _ . t '' "'""" "''"' ''.^,;.' .;,!'"'"-, ' Subcontractor physical examinations vill be the respon- C..;" k-~\in:r- '•- ' •. : " ' -' ' . sibility of the drilling contractor. Employee physicals vill r be performed at a hospital providing, at a minimum, the pre- |. - . -.; • ' -• -•;-,. .:,. :.-'iC ^ ^1^. "-'•'' viously outlined health-screening parameters. Dependent on ' operational employee exposures -during project vork, ad- ditional monitoring may be required. AR3003UAl U. I Section: 9.0 Revision: 1 GERAGHTY 9 MILLER. INC. Pag. J
9.2 Employee Stress Monitoring i Monitoring of employees for heat- and cold-related stresses vill be conducted during all ' breaks and lunch I periods, or as considered necessary by the Sita Safety . Officer based on weather and vorking conditions. Kpnitoring L of. field personnel for tha following list of - *y_- PI vill be carried out as described above, and additional rest • or warn-up periods vill be permitted, if necessary, to [1 protect the workers' health. Heat-belated-Problems UJ| - Heat Rash • Caused by continuous'exposure to heat and humid air and aggravated by chafing clothes and It • protective clothing. Decreases ability to tolerate Cheat, as vail as being a nuisance. .,-.-- ""'-•'*. : __ _ - Hcmt Crantpa +* Cansafl try profuse perspiration vith I inadequate - fluid Intake and chemical replacement (especially salts). Signs: muscle spasm and pain in y the extremities and abdomen. C- He at Exhau st i on - Caused by Increased stress on ; ,- - various organs to Beat increased demands to cool the P body. S igns: shallow breathing; pale, cool, moist i • - skin; profus. e sweating;.,•.•- dizzines. ...s. . an• d lassitude. t , • AR3008I45 I Section: 9.0 I- Revision: 1 GERAGHTY#MILLER,INC.
^— "^ . - Heat Stroke - The Bost severe form of heat stress . 1 '."" ' ". . • ' • ' . 1. Body Bust be cooled immediately to prevent severe | injury and/or death. Signs: red or fused akin; hot, i ',; dr.-,y skin:, and extremel, ,y hig, h body temperature. 9*3 Effects of Lower Temperature .Exposure .v L . «• Frostbite - Persons vorking -outdoors In temperatures H at or .below, freezing Bay be frostbitten. Extreme ~ cold for a short time Bay cause severe injury to the [' surface of the body, or result in profound yen- eralited cooling, causing -death. -Area* of the body III which have high «urface-area-to-volume ratio, euch as V^y fingers, toes, and ears, are the Best susceptible. IT'' • ' -' J'" •'•'•• • - Hypothermia - Systemic hypothermia is caused by £ exposure to freezing or rapidly dropping temperature. > " ... • •••*•• , Xts eyaptoms are usually exhibited -In five stages j f; ' ,..--., 2. Apathy, lie tlessness, sleepiness, and (sometimes) L rapid cooling jpf the body to less than 95°T; p 3* Unconsciousness, .glassy stare, slow pulse, and " slow respiratory rate; ^ , ; f" 4. Freezing of the extremities; and 5. Death.
AR3008U6 [Section: 9.0 Revision! 1 GERAGHTY 6f MILLER, INC. - .,,;-.
9.4 Effect of Sulfide Vaporg
'•*-• Carbon Pi sail fid a - Subacute exposure effects of inhaling carbon disulfide vapors Include nausea, restlessness, headaches, fatigue, and mood swings. Personnel on-site vill ba monitored tor these effects, -In addition, a;iodine~azide test on urine „ • .— specimens'Bay be performed daily* .*" - Hvdroaen Sulfide - Subacute exposure by Inhalation E include headache, vomiting, dizziness, nausea, * - - . - diarrhea and rotten egg breath. Monitoring for these In . effects vill be performed; and* the Iodine-aside test b on urine specimens may be part of the monitoring. L 9.5 Rest GA 15-minute rest period vill be taken by personnal la -— - -• •• . the morning and afternoon along vith a 3 0-ainute lunch iiil period. Breaks and lunch periods vill be taken within the p support zone, after decontamination. Additional breaks vill ba allotted based upon weather conditions and the amount of [. strenuous efforts required for some tasks.
flR3008U7 | Section: 10.0 I Revision: 1 GERAGHTY 6? MILLER, INC. Page JS'ofTS
10.0 DECOOTAHIKATIOH
All personnel performing work tasks within the Exclusion Zones Bust pass through the Contamination Reduction Zone (CRZ) Decontamination Proceedure, regardless of the vork task t or protection level used. - • Donning and doffing protective clothing vilV be per- C formed at -cr within a decontamination trailer, located vithin the CRZ, -vhich vill also serve as an equipment storage area and initial vashing location. All drilling equipment, tools, and vehicles, used within the vork areas vill, likewise, undergo decontamination prior to removal from the contaminant El reduction zone and between vork areas and .tasks. Final • - Inspection of vehicles and drilling equipment prior to leaving the CRZ is the responsibility of the SSO or his/her appointee.
10.1 Personnel
E The following personnel decontamination -procedure vill : .be employed for those vork Jtasks requiring Xevel B or C -protection (see Figure S)t
Station 1: Segregated Equipment Drop Deposit equipment used on site (tools, sampling devices C and containers, monitoring instruments, radios, clip- boards, etc.) on plastic drop cloths or In different f: containers vith plastic liners. Tools and devices vill be washed in a detergent solution and rinsed vith clean f vater, than stored or serviced for reuse. . Sampling ' tools and similar field equipment Bay require high- RR3003U8 I SectIoni lo.O Revision: 1 GERAGHTY.?MILLER,INC. _. ?**** i/?/87 Pags 10*2 of 10-9
' I EXCLUSION ZONE 1. 6 SEGREGATED EQUIPMENT DROP k1 ——X——X- -X——X——X—X——X—X——X—X——HOTLINE —— f 1 OUTER GARMENT, BOOTS. AND % C Af* GLOVES WAS* AND RINSE 0 CARTRIDGE CHANGE R)————G) %!?_? GLOVE REMOVAL FIGURE 5. li MINIMUM DECONTAMINATION LAYOUT LEVEL B AND C PROTECTION CONTAMINATION <& Vgojicffo? r REDUCTION ZONE T BOOTS, GLOVES. AND OUTER t GARMENT REMOVAL . ,...-, , , COMTAMIMATIOM ^ CONTROL tl~ 1 ., (3 FIELD WASH c" I SUPPORT ZONE
flR3008'49 Section i 10.0 Revisions 1 GERAGHTY 6?MILLER.INC. . temperature vater/steam wash. .This • station »ay be [ located outside the CRZ decontamination line, depending upon seasonal conditions. I Station 2s Outer Garment, Boots end Cloves, Wash end Rinse L • -' -'" * '•* '- ; '"-• *'•"-••" ' . •- " " D, ... , Scru- b. outer boots -end gloves vith decon .solution, consisting of detergent and water. Rinse gloves, boots, n and garment, with band-pximp spray bottle into plastic U bucket. This station vill, likewise, be located outside Dthe decon trailer,, weathe„. r.... condition.s permitting. The . .. remaining stations . will be located within the decon U -trailer. .O ' • ... ,< •- • - <•-• :>"*i:^." • - - - • -' • Station 3s Outer Boot 4 end Clove Removal r- Remove outer boots (if worn) and gloves with accompany- _. ing tape. Tape should be placed in a container with -a f ... plastic liner. Reusable cloves and-boots .will be stored t,i f ;..•-...__ - -•• • ^ Q for future use. p . Station 4s Canister Change If a worker . leaves the exclusion rone to change a P cannister/air bottle on his/her respirator, this is the last step in the decontamination procedure. Once the * ' • - . -**•-. * '• ' " r, ' ^ i vorker'B canister/air .bottle -i« «xchanged,tli« cuter . . . • ;•: flR300850 [Sections 10.0 Revisions 1 GERAGHTY & MILLER, INC.
glove and boot covers are donned and joints taped. The I worker may then return to the exclusion cons.
Station 5s Respiratory Protection Removal I . Air Purifyingt Remove the respirator face piece, deposit used cartridges in a plastic-lined ^ontainer, D' : -, sndl drop respirato, , r 4tt plnft.jp*lined cont^Jtfipr for p* -decontamination. ' ^ * Air Supplying} Remove respirator faca piece, fjl regulator, and air bottle, and store in rack for decontamination and 'recharging/inspections.
Station 6s Boots, Gloves, and Outer Garment Removal m Removal of boots, gloves (inner), and outer garment. r - -The outer, disposable, chemically-resistant, garment r should be deposited In a plastic-lined container. t,. . Reusable protective garments will be removed and stored y for future use. p Upon removal of inner protective gloves and boots and u protective clothing, personnel will pass Into the "clean11 I" portion of the trailer for washing1 of hands and face. - lockers for storage of; winter garments, etc., will be located I within this area. Respirators will, likeviss, be stored i . . •' flR30035i F Sections 10.0 Revisions 1 .,. /." • . r GERAGHTY & MILLER, INC. Page aJS'oJ'jffi •«u( LJ . within the clean area after being decontaminated.; -. The 1- procedure for decontamination of personnel wearing Level D | Protection is similar to that for .Level C and B Protection, I. ,- • -*•••••;.-.. it f< -..-'.I-'-' but without stations for respirator removal and storage (see I Figure C). All outer boots and coveralls will be stored or discarded within the decon trailer and not worn within the n ' , ••:, - ••' 't -V- areas.
Shower facilities and .lockers for storage of street S'f clothe'. -.s - wil. • l " be suppliev-- d -fo* r personne' l at the Avtex plant. Personnel leaving the CRZ 'at the end of the day will be ill required to shower prior to leaving the Avtex site. Person- ,- \^ nel will past through the'decontamination procedure prior to * eating lunch, and when leaving the CRZ. fl - . •:. '• ' . -. • ' '.-• ' ":-' '. •- ' 10.2 Equipment and Vehicles £ • -•. •'•.-. •... . - ....•, . .-,,.,^,-- F;, — ?•.--• •• -- ...... -. .. . - ,-., Tools and equipment will be washed with decon solution. r! ^ and rinsed vith clean water and, if required, steam cleaned P prior to reuse, to the satisfaction of the Site Safety Officer. Drilling rigs and vehicles leaving the CRZ will, J - likewise, be decontaminated via steam cleaning to the satisfaction of the Cite Safety Officer in a designated < steam-cleaning area. flR300852 [* . Sections 10.0 Revisions 1 GERAGHTY fif MILLER, INC. pa 01X|'loJ/JKf J
I i EXCLUSION ZONE
I ..'.... , : , ."j ,':-.: ' , . : - . • I .6 SEGREGATED EQUIPMENT DROP
I* x—x—x——x—x—x--x—x—-x—>x—x—x—<-x—x—HOTLINE—•*
OUTER GARMENT, BOOTS, AND GLOVES WASH AND RINSI
FIGURE 6. I MINIMUM DECONTAMINATION LAYOUT i LEVEL 0 PROTECTION
CONTAMINATIOjtrMi-i-A nit. A-T intN. -•-fsJ c) BOOTSAN^OUTE, CLOVESR , REDUCTION ZONE GARMENT REMOVAL li CONTAMINATION CONTROL LINE f E) FIELD WASH lit . : SUPPORT ZONE t* \: / '"" ,'.'
AR300853 r'jl'l7°''l'" *'-•• ' ••'•- •• . —.. _ —.—.. --—„__.»•—•—•»••»*.«•< L Sectiont 10.0 Revisions 1 GERAGHTY & MILLER, INC
. 10.3 Decontamination Personnel . .. I _i I- .; , "^-" - ^.^r^"-:- • . ' " (Personnel vor king in the CRZ outside of the "clean area* - • • " vill wear, as a ninismm, modified Level C Protection (no L' respiratory protection), including a splash shield to protect against splash during decontamination, and tape*, joints* Ln. . DecontaminBtion personnel yjll i>e yeqxiired to pass -through ft the decontamination procedure prior to entering tha "clean i area11 and leaving the CRZ. '. : . 10.4 ^contamination Waste Disposal fl '- . - . ,.,-.,,-.«,,«-. • --.. •:-• ••••- C^ Wastevater generated during steam cleaning and washing LT - , . , , .-._,•.-., vill fee discharged to the treatment plant for disposal. Solid Hastes vill .fee containerized and disposed of In en approved manner by Avtex personnel. f.! i. 10*5 Equipment Heeds
CThe following equipment vill be used during the deeon- .- tamlnation procedure for level B, C, and D Protection; f" ' • .-••-•:: I Station Is .-.*•. .Plastic drop cloths *-* .4' :" ' • Plastic 30* or 50-gallon containers Sections 10*0 L RevisiRevisiono s 1 GERAGHTY & MILLER, INC. Page iO"B of
Station 3i . I • Band-operated garden-type sprayers (2) I * • Large (30* to 50-gallon) tubes or vash basins * . Plastic buckets f" • Brushes ...... * • . Decon solution x Li «-5 percsnt Ba^ COj • 5 percent Ha^ PO^ L! "-1 H20 °percent CaOCl3 r station 3s . Plastic liners If - - * Plastic containers (30 to 50 gallon) • Bench k.. . Storage racks for boots and gloves
*"' Station 4t J' *• * TBuct tape . Respirator cannistsrs lii . Fully-charged air bottles r u Station 5s • Plastic liners • Plastic containers (30 to 50 gallons)
AR300855 I ••*'," Sections 10.0 L Revisions 1 GERAGHTY & MILLER, INC. Dates 1/J/S7 \^j Page 10*9 of 10-9 iv . ''•-.. - • Station €s . '• - - •"'• V':.,,: :" ~- - ••••." ;. .. _ _ . .ft 1. . Plastic liners * f . Plastic containers; (30 to SO gallons) _.. .-..-•
-"-•-: ^ ,--"" ." • - . - • ~ ' '' t Other equipments 1 ~ '• -. " . " " • '. ". " . '• *- • Hand-operated, garden-type, .sprayers, fo^ . vehicle (j ... equipment vashing and D* Steam cleaner -; - -' _ .. , *•.'; -•... L. * . Potable vater supply fj . Hash basins • lAdcers (P1 ,",, foilets ..' .'.: '. ""i .
r r
AR30Q856 Sections 11.0 Revisions 11 GERAGHTYffMILLEIUNC I GfiH shall implement a housekeeping prograa during tha course of the investigation to avoid tha spread of any I contaminants beyond the vork sita (exclusion area) .
I The prograa shall includes . Periodic policing of the vork areas fo£* debris, c .. including papftr rrr-dmrl'Sy cans* . Periodic changing of wash vatar and rinse for hand, face, and equipment, and disposal to the treatment plant
. Periodic removal (daily minimum) of all garbage bags ei and containers used to dispose of disposable cloth- \ ing, i.e., plastic inner gloves, and contaminated r clothing (Tyvek) . All contaminated materials vill be disposed of in compliance vith State and Federal r -' ... Regulations • All sample containers vill be cleaned and .impacted by i the Site Safety Office prior to removal from the CRZ. .
L In addition to the aforementioned measure, drill cuttings, vaste, and veil-development vater generated along G or vithin viscose basins vill be disposed of vithin tha viscose basins. Soils and vater generated during drilling in r off-site vork areas vill be containerized and removed to prevent exposure to the environment* Loose soil material vill be removed fron drilling rigs and vehicles prior to any travel, and the contaminated material properly disposed. AR300357 Sections 12.0 Revisions 1 GERAGHTY fir MILLER, INC. Page fiff'^jft7
12.0 COMMUNICATIONS
Communication between vork areas and the command post (C.P.), located vithin the CRZ, vill be via portable radios. Citizen-band radios vill be ^ used vhen the distance between i vash areas and C.P. exceeds the range of portable communica- tions. A telephone vill be located at the C.P., which shall c be used to communicate vith Avtex" security personnel* In the *v»nfc af-.•naygftncy, r*em+*r*tfag ^nftrgangy qtr yedi^l fttrill- I ^•tles will be the responsibility of Avtex'security. L
t. ".j",- I r L, G r
4R300858 Sections 13.0 i: Revisions 1 GERAGHTY fir MILLER, INC Page l 13.0 EHERGENCT PROCEDDBES * A step-visa approach for dealing vith emergency situa- tions has been developed to address the Immediate needs of l on-site emergency activities (Figures 7 and 8). The plan describes tha action that shall be Implemented in the event l of an emergency and a list of Emergency Information Telephone c Numbers to assist during the event. v . - 13.1 Medical Emergencies
In the event that medical/first aid treatment is B required, the Site Safety Officer or his appointee vill - notify Avtex security and Mr. Mike Fisarcik* Avtex security H| personnel vill contact the Warren Memorial Hospital and tha 1U ambulance service while the victim is removed from the exclusion zone and through decontamination for pickup by the j|' ambulance. Tha hospital is located vithin two block* of the plant site in Front Royal, Virginia.
la the event of chemical exposure, all personnel vithin f j the affected area vill ba evacuated, along vith removal of l< -..'the victim, until an Investigation by the SSO is conducted . I and the area declared safe for vork to continue. If Injuries Li era not Immediately life threatening, the SSO may elect to use tha Avtex infirmary, which is operated at the plant, five c days per week by Dr. Sizar, the Avtex company physician. Medical emergencies occurring after regular working hours or r on weekends must be transferred to Warren Memorial Hospital, located two blocks from tha plant. An emergency report must be completed and submitted to the SSO for each Instance of employee injury or possible exposure (sea Figure 9). flR30Q859 Sections 13.0 Revision: 1 r GERAGHTY & MILLER, INC MEDICAL EMERGENCY Dates l/p/87 " CHEMICAL EXPOSURE »*9« 13=2 Of Ifcl «etfj
REMOVE INJURED PERSONNEL FROM CONTACT SITE SAFETY WORK AREA AND PASS THROUGH OFFICER OR APPOINTEE CONTAMINATION REDUCTION ZONE !-':: AT COMMAND 1>OST c_ I— EVACUATE.AREA.I— •— F REQUIRE— D I , f——— LIFE THREATENIN1 G INCIDEN—T I 0 SITE SAFETY OFFICER INSPECTS SITE, IF REQUIRED
CALL CALL CALL CALL MIKE AVTEX MIKE AVTEX PISARCIK SECURITY PISARCIK SECURITY (AVTEX) (AVTEX)
SECURITY .SECURITY L CALL* - CALLS AMBULANCE INFIRMARY AND OR HOSPITAL HOSPITAL
TRANSFER TRANSFER PATIENT PATIENT - TO TO 0 ^HOSPITAL INFIRMARY OR r HOSPITAL
FILL OUT EMERGENCY REPORT
Mgnre -7i'. Emergency Response Tlow Chert for Heflical r Sections 13.0 Revisions 1 GERAGHTY & MILLER. INC FIRE OR IMMINENT Page i EXPLOSION HAZARD CONTACT SITE SAFETY | EVACUATE WORK AREA j OFFICER OR APPOINTEE i AT COMMAND POST i c -—= I FIRIE IN PROGRESS] D
CALL CALL - CALL CALL MIKE AVTEX AVTEX MIKE PISARCIK SECURITY SECURITY PISARCIK (AVTEX) (AVTEX)
SECURITY SECURITY IT CALLS CALLS FIRE AND FIRE AND f • EMERGENCY EMERGENCY RESPONSE RESPONSE PERSONNEL PERSONNEL E SITE SAFETY OFFICER CONDUCTS INSPECTION e RESUME RELOCATE WORK WORK AREA
FILL OUT EMERGENCY REPORT AR30086I .figure B. Emergency Response Plow Chart for Fira and/or Explosive Hazard Sections 13.0 Revisions 1 GERAGHTY & MILLER, INC FIGURE si =1- of J ^.-XHERGENOf REPORT
1. Date 3. Tine -of 'Accident Cli»atic- Conditions.• |3. On-Site Coordinator 4. Eaployee Injured , -. ••"•.- ' .• . , . r S* - CCTtff*itny Af f i A i B tlon
.'•-•-••.• 6. Social Security Kuntber 7. 'Insurance Company __j. 6. Kumber of Workers at Site Haae -of Workers . ^; Company Affiliation
2-
. . Circumstances of the Injory/Eaergency Action
||j 10. Emergency Actions Taken
F 11. -Whet first aid vac
12. Was.en emergency Phone call cade to the Project Safety Officer? Jf so, tiaet _____._ 13. Anbulance Service Psed-* / _____• ' Hotpital tlsad______•- 15. Attending Physician 16. -. Company Representatives Contacted 17. Contractor Rej————*-.*iv».. «—*scted Sections 13.0 Revisions 1 GERAGHTY.?MILLER,INC. Pagft JS'of'JlS
13.1 Tire or Atmospheric-Related Release
In the event of fire, the previously described procedure vill be followed, . including; the evacuation of CtH and subcontractor personnel. The Avtex security shift supervisor vill notify local, state, and/or Federal fire and emergency response personnel, as is required.
Where combustible gas levels exceeding 20 percent of the LEL are detected, a careful survey of the area vlU be made. Where concentrations approach or exceed 50 percent LEL, personnel vill bs evacuated and the Site Safety Officer and Avtex security vill be notified. Work cannot proceed unless concentrations return to below 50 percent LEL, and, pre- ferably, below 20 percent XEL. Avtex security vill notify local emergency,. fire, and explosion units of the condition.
Where atmospheric. contaminant levels exceed the maximum allowable concentrations (MAC) for Level C Protection In a Utvel C area, . personnel vill bs evacuated and ths sso notified. If ambient air-contaminant concentrations do not drop below the JttC within one-half hour, Tipgradlng of the vork area to Level B Protection vill be considered.
13.3 Alerting and Evacuation
The SSO or his appointee has responsibility for evacuat- ing employees from vork areas during emergency conditions. Evacuation notification vill be via established communication channels; and/or audible siren or horn located at the Command Post. Evacuated personnel vill meet at the C.P. upon bsing removed from the vork area in question. AR300863 r Sections 13.0 | Revisions 1 GERAGHTY S MILLER, INC.
13.4 Important Phone numbers . -
Avtex Security I _ Mr. Rick Wagner - During days - (703) €35-2142 ' . Shift Supervisor - All ether times - (703) €35-2141 I. Kike Pisarcik - Environmental Coordinator - (703) €35-2141 Warren Memorial Hospital x L .«-. qooo fihennndnnh Ave Ambulance Service - (703) €35-2100 Trent Royal Tire Department « (703) €35-2100 front Royal Police - (703) 635-2111 EPA Region III Emergency Response - (215) 597*0807 C £ AR300B6U Sections 14.0 I Revisions 1 GERAGHTY ff MILLER, INC. J)age - ..,, , 14 . 0 SPECIAL PROCEDURES 1 Special procedures vill be employed to assure employee safety on specific tasks which have a high risk of physical barm. '.-rj, '--•^-ii ... - ' I 14.1 Viscose-Basin Sampling C . Due to the potentially insufficient strength of lagoon surface crust, a barge or similar -platform vill be used - to support samples and equipment during viscose-basin sampling. The barge/platform vill be moved between sampling locations via wenches from the basin dikes. *--*.,.'.. ... - • ' All personnel entering the basins and not working on the sampling barge/platform vill be attached to a shared approved harness and rope, vith a support crew on the basin berm to provide any help required by the personnel on the basin 1 surface. - • . r :...,. • *-• "^. . '. - • • : . ~ . . Viscose basin sampling-crews -vill vear, ee * minimum, full Level C Protection, vith pressure-demand ECBA readily available on -the platform or barge. Continuous atmospheric .monitoring of CS2, H$S, oxygen, end percent-explosive gases y vill be performed during all viscose-basin sampling activi- c ties. Personnel involved in the geophysical survey of Viscose Basins 9, 10, and 11, shall vear large sice snov shoes, as veil as harness and rope, due to the uncertainty in the bearing capacity of the basin crust to safely support them. A minimum of two people vill remain on the berm of the .basin 4R300865 I Sections 14,0 1. ' Revisions 1 , GERAGHTY fif MILLER. INC. Pag.^'of'JS to pull in the geophysical investigator, should the crust { fail to support the person. A hand-powered-type viTich vill be available for this purpose. 14.2 Trenching Within Viscose Basins l Personnel operating vithin trenches or test pits vill vear Level B Protection (positive-pressure SCBA), along vith o an OSRA-approved safety harness and rope* Ko vork vithin the test pits or trenches is expected. Continuous monitoring of CS2, H2S, O2 explosive gases and organic vapors vill be performed near and vithin trenches and test pits during vork activities* Based upon previous fir trenching vork In the viscose basin, Level C Protection vill »• be vorn by equipment operators, vith Level B Protection r readily available for use. 14.3 Air Rotary Drilling Locations (Rivermont Acres) Pull Level C Protection vill be vorn during drilling in r conjunction vith vork-area air monitoring. Positive-pressure SCBA vill be on hand, should monitoring indicate the need for r Level B Protection. Monitoring vill include ambient oxygen lii concentration, as veil as CS2, H2S, explosive gases, and C organic vapors. AR300366 ( Sections 15.0 GERAGHTY & MILLER, INC. Page ___>rL of 15-1 15.0 —RECORDKEEPII1G • ' ' shall establish and maintain records of all neces- J sary.and prudent nonitorlng activities as described belovt . The dates, number, .duration, and results of air l: ««=?!«* taken, ttese measurements shall be vritten in an instrument log book that shall be available for n Inspection at all times v * -• • .. „ ,..',t Hi, * * description of the sampling and analytical methods £, • Type ?of respiratory protective devices vom for specific vork tasks , (f . " lratte' •ocial "curity tiuiflser, and job classification V-> of the employees Involved en specific tasks *'•• .' ," ' ., . "'' _,, ;"" f •*" r. * Emergency report sheets describing any Incidents or [.. accidents ml' • • ." : ..... -, .,: .-.:' .-'.:." ;- .- " • [: • R*cordB of maintenance , and report of monitorina Ll1 devices. ' ' >-'.'«••--"--• :-.--•-. . . -- - ;--. ' .- - Hi . Exposure levels indicated on non-reusable chemical" - indicator tubes. . : L - ..-. •• , .. r .-..— ''.- • • . ' . Sections 16.0 Revisions 1 GERAGHTY & MILLER, INC. c f* I 1«.0 OH-SITE TRAINIOT . "** fi&N vill provide necessary training to all members of the drilling crew prior to the start "of vork, at vhlth time 1 applicable portions of the Health and Safety Plan vill be provided to all site workers. The training session vill t include all the items listed below and emergency instruction for chemical exposure or release, fire or explosion, and C personal injury. All new operations shall be rehearsed prior to performing actual procedures. . Site Health and Safety Plan . Physical health hazards identified at the site, in- eluding acute and chronic effects of vaste con- - stituents identified at the site . Personnel hygiene . Safety equipment and procedures required for person- nel protection . Proper use and fitting of respirators . Vork zones established at the site tr HTPJ nnt ed areas s 1) Bewda and long sideburns f • 2) Eating, smoking, chewing j 3) Personal articles, e.g., watches and rings L 4) Working when ill L. Buddy system •* . Medical surveillance Li G&M vill not allow personnel to enter the site to r. perform vork who have not successfully completed the required training, or who have not met the medical checlc/approval criteria previously outlined. Subcontractors must provide medical monitoring, which is equivalent, at a minimum, to -those specified tax CtM employees as specified obr> r oo vorkplan. t G '•*., S •- I t c APPENDIX A f. " . ' ; i ; ' ' •' ••.--': ---• ","'•". -• * : t- SPECIPiC CHCTTCAI. J&ZARO 4DATA f.! t t, G r flR3DDS6S A-1 * GERAGHTY # MILLER. INC c CARBON BISULFIDE LG REFERENCES UFIRE .PROTECTION GUIDE ON HAZARDOUS MATERIALS NATIONAL FIRE PROTECTION ASSOCIATION fljl HANDBOOK OF ENVIRONMENTAL DATA ON ORGANIC CHEMICALS VERSCHUEREN ; L- MERCK INDEX OHMTADS DATABASE c AR300870 MAtAKDOltt CHtMtCAU DATA______.______49-V CYANIDE f^fCNi yS^v fuaoNAi. Paoncnoii: !• tforty alrrx»ph«r«i wear CTAWIDE GiECN). W® nepirator and full protect* vt alolwSt t , : White powder ««7iiAk. ^^ F-« FWMTWO Piuan: Awid water «nla« aefleeeur|ojM«'-w ^^P;--.t. ;Z£tirithac» Rnuia: Sw Cbenlml Stfcty D»U Sheet S1WO. Sodium- ^l«i w mkturw fa »Ir »w • ^e Aaodttion, !«.) lor «^F. FUiuubk Kmitawt 1J{% - future h -Unrrowly b., IW»J MfT'Q . V«or it fc»ic r than air {vapor-fcir dciwtjr at 100* F^ IS) and nay « •oni'idenblc tfUunce to ft •ource «f knitton «id tub [r' CALCIU*..trtftMu DtCKROMATntmfDAMAiTZ CaOiOf*.rwi, Seft-..,~.™..—e »ICBMMU*M. «lfiBoUine r»«tyg poin,t U)la .low »n. d||5 to Tnot Liqui eofubdk b f heaviea waterr .tha Vaporn wate.r may |^K-£ u knited by wataet with an ardinary Iffht bulb. Not aohible A. . HACAW: Toxic bjr «nl faUU, Inhalation «r woloated CALCIUM -lYTOCHLOftZTE -Wrtaefrtlh *in. .«ii^^ DwcwrnoN* WhHc powder. rrinitUa tr -^^ ^^* peUete wHh itraaf ehlori»4ike «dor. ««£» >n Fimr FioirnNO PMABEI: Foam h fcejRoetin. Vee.^ «l*emici3, ™* -^-" »«• «»rt»n dioxide or otUrtoertt"- CooUng atwJ b-uletia( with ANA Exrteaioir HACAKM: Powerful oiWUinj julertal water •pray b effective fat «aee of AIM fa neta! •nntafaera or With add* tvolvw ehloriiw at ardinaqr lemperatum <•« tank* to help prevent Ktpiilion fey hot wrfaoea. Chlorine). Not opmbjatible but tvolw oxycen at hlfher tern- U*«*i SMimiio CONTAIMCM: Small fr* or wtal aootalnen Readily fcnitai oombutUble or ori»nt« materUli packed iude fiber or wood bone and bancle, HaUoa oan*. . . fcoiuoc: rratee- t ac^nrt vitnittl damace. CtonwaU4eta«bed ruwnAi,PMracnoN:W«rMtr-eonUlMdbnatiiiuupai«titt; «T better, oonetnietion witi floor bnl tutitetioo. Avoid ww*«W if v« protection aotpmided. ^^*^ *r«t«ittUiht. £-"^>"«Mthtf,4HVjtnima wS&water .. .- -• -te keep «urarprHn0t down. Tanki ttouJd be oubmeJiw in Via* namsMi Piuau: Vie water, prefermMjr In Ibrmtfvray. water «r focaled over foncrete baaini amtaTnlng w»tw rf -. _ ^ . . . - aufficient «padty to bold all of the tank oontenU In addition l"?^l>nm^? CcwTAnrBw:,Airticbt «uu, woodaa bamle, lolbewater. WaUr «r toert (u ahould be provided owr IU •teeldninu.Cberdnima. .. . «wUn MiwUde In aD tuka. Ko aJectcied Iwtattatiou or . «_^ _ £_•_. . . . j », >^ • j__ . * b«*tiDf feeilitice ehould be permitted fa or Mar Monie ana. : Pmtoet u^hut pbnJcal *>-h Aoia(4ire piMcnt, aaa «awe-kia bora*...... Chapter S3 actorffaetoyi Mvtital Enrwerinf Divkioa). AR30087I 940 CARBONOISULFIDI CB-bondbuHid* (carboobisulfide) CS, Ustrt mnl formulation mff. nyon. cellophane, carton tetracfclorfde, rubba chemicals and flotation chemlcili, soil disinfectants, electronic vacuum tubes; •ohent (phosphorus, sulfur, bromto^ Iodine, selenium, fatt, rains, nbben): I grain Aimlpote, toO eonditlono^ herbicide*; paper mff.; A. rxorERTlESi coloritM liquid; m.w. 76.14.-.; m^. -101 Vc/-. 1 16.6 C; b.p.^6 VC: ' T.P. 260 mm at 20'C, 430 mm at 30*C; 200 mm rt 10'CjT-d. 2.64; a. AixrouunoMfACTOUSt lmi/»m-aj-5ppm.lpp_a«X17n-i/c» -Odor: durtcterirtk: Quality: TtteUble sulfid*, aromatfe hedonlc tone: dl^iUy punfent D (73;210;307;612;637;662;686;74M OX 100% rtcopiitlon: 1^00,000 C» USSR: human odor perception: DOB perception: 0.04m|/cam perception: O.OSmj/ciim" Uppb human reflex responsa: BO respoiut: 0.03 mj/cu m .- .. adventmpeaia: OJMme/aim E —Naturri jouraec biojenic carboB diniHWe emisdott'&om nOslB U3JU cry. _ aoO ortfea Wadenflte.ni aUStol ^ Stpt.-oct WTT 0.002 PMlo,OH feceptisol .Oct. 1977 0.0012 Diimal Swamp, NChistosol Oct 1977 0.0001 Ceder Island. NC freshly clipped mar* 1.131 Cox's Undins. NC freshly clipped marsh 0.0215 O**5' —Control methods: catalytic combustion: platinized cenmk honeycomb catalyst; fenltioa teMV C 350*C, Inlet temp, for 90% convenient 375-400*C (V> -Samplins and analysis: . , u$l * non dispersht I.R.: min. fuM scale: J7 ppm {?« j pholometiy: mln. fuM scale: 2000 ppm }*JJ I r detector tubes: UN1CO: 10 ppm » det UmJt ' DKACER: 13 ppa * del fimtt . iir/30 min: i , - tioa cf diethyUmlne and coppemitfato t *-"*-'..'-• ARC'00872 _ ' 141 Y v- 1 (tradition processes: , "['.. , f •„ , • ^ reduction of the nitrification procen to activated sludit at 35 m|/l ' (30) gSiiiction of amenities: faint odor: 0.0026 mi/1 (129) t v*S6_*'--. eotnolepticttmtt: i.Oof/1 ... (1S1) i: Tin (24-96 far) 162-135 BS/T . (41) {£: tevere toxic effects: 500 ppm »1600 sn«/cu sn, 60 mln ' T.. symptoms of JDnec: 150 ppm «4BO mi/cum •nsslirfectory: >JOppm»32mi/cu» (US) hlorlde «e hexacUoroetKtne Kt earbonylsulfide ;'*«richJorkJe (tetncUoromet-iane) ;, „ ! M!;. ' 4 .jT*n4 formulation: fire txtintuisher mfj; «ry eleaninj «perations; fft^l. ef ceo^eruts, aerosols and propeDintt; mfj. of dilorofluoromethanes; txtnctaat; •^pJt; feterinuy medldne; netal decreitfni; fum^int; cUoiinstini ovule ... . •• .,, ,*_"*;•»-'' _ _, rotTlES: eolortess liquid; B.W. 15J.I2; mp. -^3*C; b^. 76.7*C; v.p. 90 mm — 0 '£•" °* 5£ mm Bt IO*C, I" am at 2S*C, |37 mm at 30*C;vJ. 54;sp«r. L tt^5? ** tt'C; aolub. 1,160 mj/l at 25*C. tOO Ml st 20*C; tstxonc. 754 t/cu * S^ltlt20*C,"W«/c«'n»tSO'C;k)j^,2.64al20*C (57;73;210;«02;617;M3;740;74I;749;767) aetbods: A.C: retentirity: 45 wt%of idsorbent . (83) : and analysis: ^- '•- .--.*> ,.>*--- j ^-'' -: *' »• ,--\ • -; - »««t.lim.i 0.005ppmw r ; • . ;., | * - (56) C »cale: I7N hM. oik. mine. «e* wdv aBhablt ooBdhiaiw; (4) ^ctfMMtf IB the cvtonattoB flf bawvtoK ma«d of oarhoB* jtnM*^ i f • f*"1—iff1"* **-*r-r*i "—*! *V—*rt "**"•- aadatilaciiaatior fa inim !!••••»< . ' JIT*** prtpd from mod and vttvtftbtaa. Mooosraph: H watcfUs durina mamvt, bandUng and tfwultn M pnpcfiaM I w. D»vtd*a« ar ct. MamOkcffMi OwftM (FVrfamoB PrcM, h oeraMkrae dry lee tor nbifntiaBt IB prodwt hanah* I , , M0l*e»Ve-hv YWfc., IMfe Amfn^ •ache or fyrna «• H*«« M riet fiHttlcaolt aa OBtJatpta* ai ML V, tt 1 B. TBrooka. Brooka. A. t. DUMUB. Eds. (Oxford btctorietoty and* 01-hi fratoi food tatettT; tM«. rnea. I9S3X pp Tt^f. Smtefc. Cfeny. <«ate Gvtw ntBurcATi PTTf1—'"T r'laalairt abeviw PublUMnf Co. AAimUrdaiBi , 1 fTOfc IMSSAP CAT (vnk lt««i-aiory Mimdaal Oi «» Nmb* UX eft Merit. Ou*or»Hta. fc net* efcWly to darif>to» *ortorii.ii». dgnlo-ijim and Bhartag. Tbt «H.QtAeaPlactoitaa. ChrtMMfcolft QM »id« I «hM« ore wad ca a pftmort far rubber ttraa; for pctartnj, 169.91. C7^T3kSen.*39k Prtpd by lhaoctfaBof «Mth^- __*Bcilmt T-Y 1*-"J"t ^*-,-«~'—'fc^j^^T*"'* yAft»*- «e chlorid* vapor M htattd ado&Mt !«• «r«CJtCtam nph ncord*. deemed iotuUUni apponlue. Activated SK 1MT. lOSOt or frwo a mbture of CO, ond HJt to a £barcod Orem the dcMrudrn d-MttUtfco of «artou» organta .. . Meuur.. , I • •MuriateflMttrlili)} h1)* vaa md d ttaa mtdidBf m-didoc* CA *&*. Opocartwt Opocarbyt* ;Norif Norttc ;Ultra Ifltit*- IrcM tht ••lanceta * by tltcufal dbdunt oa Se v^or la the I •rboft. CmtOmv CvhoM MadTebtdBtd b* lha Imping prtimcn df wear chanod: 9tmtAm» TL A*** JMttm. \ •l pMiBMItI «or chanochanodd prcnmprcnm.. alt altoo l*owknow** M M (atat Uack aod dtaa- Out* Ml. 1*5 (1961). * •4 black. haa baaa honmd fey tha PDA far MM M a color Ufht-atHitiv*, celdflB ycDow. etroBffy nfradl.% Squid. I ^dii-** !• faod^ tfnift *a4 roinirrifBi Odor of rotu» ndithea. Tune brow* IB black M won*. ' Tuatf CATI Activated diaraod aa ootldete; odurptiv*. df>.U24idf 2.4624, *»-419". bp 125424. bf^j ! nmur finT PTTir teUraaDy aa aa adtorpth* ta diarrhea; Mf I.M5. Hmt ef fonratioBi 34 kcd/«cL MbdSe vltk D carboB latrMMorfda, oarboa dJ*ulBd*> lohMiM, ochvortade JTML Chrtoa OanUk ^rtmhodd fan torboMfaa*. b wbydrida. C3^ w* vl T4.M. C IS.71%, S M.23%. ta iht otmof many pUoaa. ta our aolar mtcm. •.(« OB MimNt wnowtt ooew ta ootl tar aW ta crude pttrattua. E Vonut, tht opticd layer thkkiwH due la OO( to 10OOOO Prdpd OB BB taduftrlal acale by tooting chareool with vopor- oo/atm. butooJy 220cw/atmOB Earth. Andjvoiofdrtmie ara IBM! wlhm tnm eulror and wtunl p*t Paith. lUyei A ibt wnptralc MM* ef iht Earth show 04127 IB9.036% (v/v) OaA'a Mmoriml &*mlc*b. p. A. Low«b*«. M. K. MOTH. Ed*. (W!ky4oundceft NewYorfc. 4th td. 1975) pr *«.A « li nCkie*| csp.iiitw.VKUao rrcw. 194. «i% htandell-Bormuiii «d^ IM» PP M. 224-229. taboratocy pjftftcatioo: Okouv ta l-M^ooft V 5U. OMutitiMBt ef cvboute type of mtocrab aad daafa Prm. Ntw York, ted ad* I«*3)'p 452. *IU«(e* if •reducu «l wiiiMl McubelMm. NMMMT far U» mpfra* prodiifUnB a>4 mm toxbdLOt**. mJm*. (Tt*tm)lM, «e a 1465: R. W. TimnierauB ta KlrkOthmv fttyhyrfie V by-predwct te tbt Muntf of line dufteg At "burning' «T OWmfat/ r«dUafcn> wL 4 (WibvlBUnd«» Nev York. ttnMtoM (OCQiX Ate produced bjr bnndit| eokt or 3rdad, 1«7S)»M3-7S7. ••tat mtiBMBBBM «w«W. te tte VJJL tut* *»«««» HifUy rdraei** oaobOt ««« flaouBabta Hq. Aftmnmf «* piodnoid by fvvMBtMiaa (BMfc« propgi Tbt purw diuiUat* •«« obtatatd aro nporud M how • proMii). Wha fJueaet ll fanncBtcd by yMM. tbt tibM ptcaafnf. Hid cthanal odoc. *hlb tht «autl •rodyctt are ethyl afeobal Md OOW Prcpd ia the laboratory dd aod reafont tntfce are fed tmcfllng. DM OB euadtaa V V by dro^plni acid om a mlMAatct B. H. Archibald. TVV far a too| time. Bone with a blue flame IB CO, aad SO, ^-^ ^_ rrwfmrwtmt mt rm*w timnwmnu. juaiianiM \v*UKjt. r*« Neww ««r> York,, Xotir >v oid ovfacfM AomAcaa) be Ifnfud by • 19)2) p 194: Loon*. Wdur* / Am. Ohm, Sm\ *», 3IOpipJ» Flash pi. doted cupi -2TP<-3(rCX K . (1926). PurificaUoB: Qlmu* to *!•*&*<* ttf fnf»~tl*t ICKT. Eiphxiw ranee: I to 50ft (v/v) ta air. 4IO9272I df tmorfmmie CWmtefy O. BniMr, Ed. CAeadcoik Prcu. Ntw U70S5; df U632; df 1J4SIT. Vapor* dnfc M th* pnM- Yorfc. 2nd «d^ 1M)> p U7. X^Wnv B. L. Quio*. / CWnVapot r d«iitr2.47 Wr - IX fr -—- ' ~~ _ . 151*162 oad 403-41* (1930); X JC«pri«ort. Xte/oW C JCoMr«jJbmt fTncfaocfef (Eofco. StuttBoff. lt39)G L 1» QuhM. C U Jttua. Ckrtm JDteMr (K-wkbold. Ne» York. 1 _fs9! «r» 1.1210* «« UZ5U. fcrfaot Mi- U47k W. ]L Ballot ta Kirk^lteM AqdMdto VGbmt t »JX OiiffiiJtm of ifau*lt| -at M^i OJ4I. Hat «f nportatioa at bpi 14.1 od/a. Hm* of IwiaK 1*71) pp 725-742. 1A49 kcd/oiole. Hat capacity at 24Jft 11.17 edtoeltr* CetorW nrtnrlra* »M»c«ibuftible pa. FaiMaddtuta. B tliiMT% -o •ooouppomt of •aaBbualioBh oihortifl bvraii^ mtft fnwm, MaBO^-Aur -*<«.. OW*oi . JUfc. J^ 300 (11971. -aijaidMB ccoiiput* IB bare wfcai madtrrad «MO COk frequ I. I '-." :.'- • • . D " . ._••:-• p HYDROGEN SULFIDE ~ REFERENCES [" FIRE PROTECTION GUIDE ON HAZARDOUS MATERIALS L NATIONAL FIRE PROTECTION ASSOCIATION fir HANDBOOK OF ENVIRONMENTAL DATA ON ORGANIC CHEMICALS VERSCHUEREN i.p. MERCK INDEX c OHMTADS DATABASE E - - Q C AR300878 Q t <9-S4 _____„______H AtAKDOttt CHEMtCAU PAT*______m______^___ HYDROGEN FLUORIDE (HydiofltfOik Add) . tnx am fecfiMiOM BASJKKM: fcwtrful atfd&nc agent & HF >TOX •ooeeatmtiooa above «5% HA* toauftdent water 6 pnmt _ ___ ._ .'_.•»• i * »*»^ -. «•!«»«»the beat af «eeompoatioa by vapatitatfea. Tbe I I>»c«m»M: Dear. aobrW Annfe* Squid (bofllnf ^5^ adUUti* dteompc«iti« lernpermlurt rf BO^H^O, m WWF, point frFO^quoou»*oIuUoaar(u. >^ ao that mert aombu^Jble matciiala fa oonuet vith DM 4»- _ _ •,_*_. _^i L . j-« .. ._ aompoeitioo produeta viD ^uieilr bant fato tame. ftttAN»ExnouoMiHAtAnpe:NonoombiMtibli,but.bffieultto • buteomaercialprodoeUaormaflyanfahibiud. A. aootaln aa h oorrodee moet wbctaneee tieept bad, wai, poly- fa tempermture focmeca the deeompoeition tate ef I aavlene and platinum. May nnemte hydrafcn to «ootart pemide about 1W timta f«r oach lON^VWeol deeou,___ wilh eoroe meUla. Soluble fa water. } . mty be «au*ed by oontaet with many tuUuneoi web aa koo, j-f,., : •- • - - topper,chromium, braoi, bronae, toad, ailverf man|aneee.i\t•_. b*a Has*an: HifMy toxle and farltatlaf to •?••,,akin and and their Mh*. At ardinary *rf p*ff*gfw, fcW>^t^" pfrMtifa Mpimtory tract Jo both liquid and vapor lUtee. lu iharp fc, timf-'fptrf tlnrti -rr t* tV--* f^%il'^t r** n^'Vfy ^*VtH t penetmtinf odor ordinarily prevent! voluntary tohaUtion HicherooooentrationaaralevatedtereperaiuniimayladliUU •f toik quantitiea. Contact with *m «UM* very painful detonation. SeaaJUve and powerful ctploeive auxtune an and mediealty aenoiu burnt. Uquxl aMtaet with tyee aan abtained aa ^'v-n many arfftnie material* with " * C Lire HAMW: E«t«me.r fcriuUng to .ret, gt b. and wu or potyoUurlette bottW H/drocen luonde in rto*J b»ct; «« iwuH fa •erfoui boriu. Avoid inUIatioa af «mpor rt and teak Uiftn. 7 ud liquid contact vUb •kin ar Protect acthut pbjR*«l duucc. Store to wtH-Wntl- FBKBOKAtPaoncnoK:WMra ktcd area, aeptntcd fram atacr *ton«c. ', vov cocsl« tf «yt protoctkxi aoi prorid^ AnuaaifSee Chemical Safety Dtta &Uf t SP^5 (Minufirtur- . ftarFwrnifo *«*•*•: Uie wtar In anmk auintitm to dflut* fat ChtmiiU* A»oriatioiii, feej. and w»jb «w»y tpOk «w! wmbot €rw fcvofriof tha material. Other •Ktiapiiibinc apnta will probably aot be affoetivn. •HYDROGEN IODIDE 4««fMioDteaci0 U«o »a:y bi..is*e tavo.v«i.1 ->"B • t . luniinj ar alreni aHrfc add aw! power(.J aiidl IbuALCturriMoCoKTAtHturGlaji bottles and tarbora. ahuni- . ., »,.. . . aum drum* and tank *n, potytthyJerve wntaJnera. AH ft*-: t« ""*»;. Hi«M' . _ r* • telaen muct be v*nt*d. ' - " *-**<• H I HYDROGEN SULFIDB 749 '• fathead minnow, egp: 96-fc LC»: 121-352 p«/I P: . •' swlmapfry: 96-hLC,.: 12-122 p*/l F I Juvenile: 96-b LC(9: S2-137 jig/I F - Juvenile (wild stock): 96-hLC,t: 1 57-191 pi/1 F (1512) _)lsmmalia: guinea pig: inhalation: no symptoms: 200 ppm, ij br """•.;• fatal: 31$ ppra I rabbit: inhalation: no marked symptom*: 120 ppm nousa: inhalation: death: 1.300 ppm, 1-2 min 45 ppm. 2.5-4 hr e , .. cat: inhalation; death; ISO ppm ;- toxic: 125 ppm, 6-7 ml» .- dog: InhalsUon: may bt fatal: 0.04-0.07 ppm may be tolerated: 0.03$ ppm * (211) ,' rat: inhalitkm: LCse' I42ppm.30min mouse: single oral LD,g : 1.5 mi/k| , (54) -Mm: deadly doses by insertion: 0.7*3.5 m|/kf body weight (ax-CN) <54) Kvcre toxk affects: 40 ppm « 44 m|/cu m, I min i , symptoms of illness: 20 ppm • 22 mj/c*m onntisfactory: 10 ppm » II mg/cu m (115) immediately fatal: 270 .ppm , fatal after 10 min: 111 ppm fatal after 30 min: 135 ppm ' dangerous to life: 1 10-135 ppm tolerated for 1-1 J hr: 45-54 ppm slight symptoms: 1 8-36 ppm (211) hydrogen sulfida "a. eimat-oVC.20ilmat25-5*C;v.d. I.I89atO'C a. AJBroLtimoMrACTOU: I pjua • 1.42 mt/»m,lffli/a»m" 0.704 ppm c -Odor: characteristic: quality: rottea egg odor y 18*§ »0** 18-* 10"' ID"1 c m;73;|70;210;279;6I2;616;630;644;652;677;67g;710;733;74l;742;744; 793; 801; 803; 121; S43; »S7; S5S; 863; W7) OJ. at 20*O 17.000.000 UI6) •Natural sources: . estimated rmiuioa from natural sources !• tht USA: 0.07 ton/day/ljDOOaQ.«QB (110) RR300880 744 HYDROGEN SULFIDE feiogenlc HXS amlxsloni from tolls In U.S.A. (1*77): aimpling sites ~ aoD orders wnpllng dates Wadesville.lN «!fi_oj 9/20-10/3 t fhiJo.OH fnceptisol 10/7-10/10 JMsmal Swamp. NC fcistosol 10/14*10/17 Cedar Island. NC .saline twamp 10/19-10/28 Cox's landing, NC Uline nirsh 11/1-11/9 c aarkadate.AJt «Hurialel*y . J 1/16*11/2' Island. NC InaWy dipped jnanh —tianmade sources: : ' glc*s in yard of oD refinery at Owase: 0.66 ppb In cigarette smoke: 40 ppm (66) | from combustion: source emission factor coal 0.0045 Ib/lb coal HYDROGEN gULFIDI T4» -Insects: £>A«m*r*: TLm (96 hr): OJ16 mg/1 (no effect levels art 8-12* of tha 7la (96 M values for fba above uihropoda and insects) (219) flies: inhalation: LC«: 380 mg/cu m,>960 mm flies: Inhalatioa: LCj»: 1,500 mg/cu m, 7 min -Fish: goldfish: toxic: 100 mg/1 (155) lethal: 10 mg/1,96 hr (154) LD»: I mg/U long time exposure ia hart water ($45) trout: toxte: 0.86 mg/1.24 hr _ . i: toxic: l^ng/tTfer ting salmon? *f»hg 1.0 mg/1. Thr * cutthroat trout: toxic: 1.0 mg/1, T hr fatheads minnows: TLm. 48 hr: 1.38 mg/1 carp: toxic: 33 mg/1,24 hr goldfish: toxic: 4 Jmg/1,24 hr sunfish: toxic: 4.9 to 5J mg/1,1 hr I oldfish: toxic: 5 mg/1.200 hr [; mjnaowa: toxic: 5-6 mg/1,24 hr carp: toxic: 6-25 mg/1.24 hr trout: ioxlc: JO mg/1. If mia goldfish: toxk: 25 mg/1,24 hr tench: toxic: 100 mg/1.3 hr (226) bhiegilt, eggs: flow through btoassay: 72 hrTtm: 0.0190 mg/1 at 21*22*C 35 d old fry: flow through bloassay: 96 hrTUn: 0.0191 mg/1 at 21-22'C juveniles: flow through bioassay: 96 hr TLm: 0.0478 mg/1 at 21-22'C adults: flow through btoatsay: 96 hr TLm: 0.0448 mg/1 at 2I-22*C (469) I fathead minnow: flow thrautthrough bloamvbtoassay:; 96 hr TLm: 0.0071-0.55 ag/1 at 6-54*C MATC: 0.0037 mg/1 at 6-24*C bhiegfll: flow through bioassay: L » to TUn: 0.0090-0.0140 mgflal20-23"C MATC: 0.0004 mg/1 at 20-22'C brook trout: flow through bioassay: 96 hrTLm: 0.0216-0.0308 mg/1 at 8-12.5*C y WMt: D.TjOSS mg/1 at S-I24*C (468) Mifflmalia: mica: inhalation: LC(t: MOO mg/cu m. 18 min 380 zrig/cu m;4lOmin c 96 rng/cu m, 804 min 24 mg/cu m;>960 mia rats: inhalation: LCje: 1^00 mg/cu m. 14 mia 380 mg/cu m.>960 min (105) -Man: seven toxic effects: 200 ppm • 280 mg/cu m, 1 mia symptoms of illness: 50 ppm • 70 mg/cu m unatisfactoiy;20ppm»2S.BC/c»a (185) lethal; 600 ppm. 30 min 800 ppm. Immediately . . (186) AR300882 I: . u '• rfflde , 4709 - CWeyy. •afford•afford.. AHPK $ •ow. hoM. aatauiwood te-tU. bWiK jwinieibj m^mmm- PowiH. Campbell. A 4m. C*tm. toe. «, 1227taft. •ricravtaft; M Mldiier fa naaoauaitff tfye 4yKK tfttiofectiotfttimctinii wo w»-- I oliohepnpdbyttMtiiiCooaedhydrlodieocld Mr and hide*; _ wtaca, •qnon. olo* nfintac fcbS-uZi fe ««ufte<* _/ _*nF«nf/« ofU ood bta; M Mttehlor. with nmnphoayfaaediMolne M n fiWML 1* O. BniMr, Bd. (Andcnte Pnw. 4yc br hm. dud hair, oicj b pbodifraphy M hypo otimt- Lob pnp«: Noff •Hth K*OH tor «fc*nbf mtUt iwtMo. far I ale. In •harmoooutfcol tHUAT CAT frm Topical MlbqKfc a*d rfi Ulllij hydrMM haltdet: HilU ta MMbr'* C*W'v*mi..r TMHfer iSl£Sa«f™» -^ c> onr_ fj Tiic-MtofCVrmtoi/w•• __->__. *• __•___——Zt H M, Mppt..——_*1 * Cart t—*d 4707. H7 07 4710 HydrofaTdteUt Uttrf w 7Vo«9ar»f«M J-W/i* fMMr* hydroowrpUeo: Rapopoit af ol. A CXSA^fr 73-* FB 2J447&. (1930k Homa«. De b MaUr. UJt Jra*too Ttafcfgr Extrcndy OMorikM. CblUpi ood *Mlh IKM rapiroiory bBm onoy oomo withia o tow ofur MO «r two iMpbotlooa. lotidloua potto*. fcta •tact MOM of M»dl moy bt btitu«d nnd ttl to |ho wanios AAJtoft* Jl^a Supyt no. SIX M FF ttMl ? of hlfh OOOCBO. Low COMM prodwoo IrrUatloo of oeeih-no- aS» aad Muooua monbroAM. Hcufeche. dinfacai. oanM. _ oft* «poe«f% Ofefeof Ttafacfefp 4 K ft. B. OoMdb ffoLEdi. (WOUomoi WUUoamt .r Bdtlmon. 4th ot. 1970 faction HI, pp Itt-ITf, 4711 HriroteO TcBvtti. B,T« M| wt UM& H t.M%. Te 9C44%. Fnp4 hy tht netks of H p ot HO «• t olumwnm unuride by dMtrotyito of o SO* tob d nlrurto or phocpborte odd with o Te cothodct Dcnnb. A»deno% A Sat M. W2 09l4fc ~ mvfUm /*~xmJr Chtmtay nL 1, O. Bnner, Bd. iontePrcM. New York. 2nd *d- |»63) pp4U-«4l. D ColorkMfM. Offmriv*, (arlk-fiko odor, Uq^dHAfdMlmmedbldybytlshC. the a.wTS'SLSS. "~ ** **M*n Wr"*1* • dfyyobotabb«oiiifa,»uiwMbthc|iiiiniii^4Mt. HvdrodUorkta. o»MidmolM«»nibbcr.eorlucio. Sd b wai« with fttrV JM»Aonynraciuona CrystalM * dM 303- J1F (menauril taM. t-V ^vick dMompo. A Mtd o% Mb to kbooi MM -»r. Cd ta 1 pam waun •putoaDr M! ta alt. Cmtlont Impnna oltouivo odor W hnoth. Sympt^mo GntCM: Abwe kodi to babituoitao Ot orlrHfttBo dmOar to hydrefM iJMJd» f^» - tHEBAT CATl ^MtjnJt, MTCOCla. 4711. Hydrofea TetrocarbooTtttrratcCDDL !«• hydra- •rboayl; Iran tctnccrhonyl dibydrtdo. CMfiOj md wt 4711. HHrMe9. Am •&** 15% Na od 4» f* 1*9.91. C 28.27%. H 1.19%. Ft 22.87%. O 1747%. HJV Smatt. trrtfular tump* which on contact with waur fwM C (CO)'——* Frcp~ n fro• m FoCOO~ '——V Blanchard. ColMiaa. /AM pwo hydroaco (M (2.4 co It per IbX bnwM o midM d too* «M2,249(IM6XStcmbero m*L,J.A*t. ChML&oTfc cponge and MaOH tdo. . • tig* Aaaaou-BOofhydratMiarbbBrataf ColorlcM cmtalfc tnp —70. eoIoricM tt«. «vy aortal!* hb blowpipes ond boHNn. daebdow—lOTooeipamrtloalr. Sithltraemorbcocnr- 4711 Hydroontk AcU. henyU Import 0 rad or ydlow cdcr. Oaiuonuandyooo* Ulmtarteryttt nctdf 4.5-dlbydroorotto odd. Meunf odor. Sol ta alkaliw oeutnl 04 oolM of Mitt tum- md wt IS8.1I. C 37.»J%, H J-13%, N 17.72%, ble at room tanp; Mronfly olkallM «otes of Mlu. M. K,Fo* Frcpn from carbetboxyupanftoK MUkr m oL * Am (OO)«. ora atablt at room temp whM an tree* tt mt on a- 0*m. SM. n. MM (1933X US. paL 2,77X171 (193* m ctad* hot dM cradua&y ot IOOT to CO Md H,. McrchACfcX 47IL Hyfrohcrderlto. berytUum pbotphate owoohydnio. 4711 Hydrobydrartialoo. C » 09%, H 4.13%, N 7.33%. O 14.73%. Sorrd vndtf Hy C drutiniM. Cotamioe. Hydroeournloc. Frcpn from cotor* nine: Topdilcv. Jl Afpt CWm VSSH 4.52» U933X C-4. % JfW <19>4fc Ocyeoo. /. <»CM. SM l*4t, **'*• «-—-*— MUlW. 4«a «!»; J4 O93tt Koabo. Ac* Mcmv M, Ul —«—.jcojo, cryMaht . . mm MC. . ___ »-Form, crytub from waur. dM 2*T. (.»* - b • 2.01 to 1% NeHCOJ. __ ftt-Form. oyiulh M* 251^. Forma o wow .0071j 96(WALLEYi E fRY ITLSj O (1invvcT5 DEGREEM -. S^ CELSIUS IWATRAG 0027 e I I if* I A ( />"V-i- 96!WALLEYE FRY .(TL50 (IS DEGREES CELSIUS IWATRAG 0027 ''•>_?, ''*. ( ( (OXYGEN - 6 PPM ( v ("FISHES" (TOXIC I (G21*W 0001 96ISUCKER FRY ITLSO 115 DEGREES CELSIUS (WATRAG 0027 \J I I (OXYGEN - 6 PPM I 24! NORTHERN PJKE J.HJI JFLOW1N0 D.O. 2 PPM ITAFSAI 0012 IEGGS „ I 4 _._• (99(3)501»70XADE TCIRAIfiBOW TROUT ITLSO (15 DEGREES CELSIUS (WATRfrS 0027 (FRfc ( I OXYGEN - 6 PPM I 48INORTHERN PIKE (TLH (FLOWING D.O. £ PPM ITAFSAI 0012 (EGGS 199(3)501*70XRDE 721 I 961 241 (FLOWING D.O. 6 PPM 491 t 721 96( 24(NORTHERN PIKE (FLOWING D.D. £ PPM (SAC FRY I 431 J 72* 96( 24! (FLOWING D.O. 6 PPM 481 961 <61GOLDFISH (LETHAL( 0001 ,75-( * (SURVIV1HARD 0001 J.OI *AL ! I (TIME I 3-4! " I " I " 10! 96! " I " I " 0001 -_.iT> CHRONIC AQUATIC TOXICITY LIMIT /PPM)I £ <.MU.GxD EtAR) CHRONIC AQUATIC TOXICITY LIMIT (REFERENCE)* THE 1976 PROPOSED EPA WATER QUACITY CRITERIA WAS 2 .MU.GxL UNDISSOCIATED HES FOR FISH AND OTHER AQUATIC LIFE. (XPRRD6 77/CLE) ,*T1> SALT WATER TOXICIT.Y TEXT* £ONC.JEXP.DSJSPECIE t EFFECTS TEST ENVIRONMEMt PREFERENCE 4 L.t AR300W! GERAGHTY & MILLER. INC. O '• • " .:".'., L D . ;; PHENOL " . • • •- •'; MTEREKCES , FIRE PROTECTION GUIDE ON HAZARDOUS MATERIALS NATIONAL FIRE JKOTECTION ASSOCIATION HANDBOOK OF XNVIRONKENXAL SATA ON ORGANIC CHEMICALS VERSCHUEREN . • - . . -• v .- -' ' . ' • • KERCK INDEX ' ;....,' ' : ' • OHMTADS BMABASE AR.30089I ' ______»*»AKDOUt CHEMICALI DAT* SH Flammable and Combustible Ilqukb OwU PHENYLMERCURIC ACXTATB *».N.^i^B«tikrf|C«l.05FPAN*.70L CAHgOCOCH, firt-Hacard Propertta* of flammable lJquld% DIM tad Volatile SoGdi (NFPA N*. 32SM). an! ffe and Eipl«to» DncurnoN: mite powder; or deer eel* Baavd* of Organfe Pfenudet (American lonumiw* Aaeooia- {fan to eo_veot * Diy 8ohrOaa Pkas AK» ExrtouoN RAKAKM: Solid material b eombiutiblt. Solution hae the oambuetibOttj of ti» tolvent, Flaifc poiat (mrito) SeiArrmaA * wlat-B*. aim l«f Ft*.- WuMt h water. I tm HAIAU: HiiMy torie. May bt aheorbed through Iht ath with delayed effftrta, Irritating to the akto. PHENO•UTMIVL /rwt^ft(CkrboUc. Add a*M)i rC.H.O WJMHI .A-.. PKUOXAL rioncnoii: Wear fuO proteetln dotfcb^. Oothiog S«!kf^irim|writiei*Itprtieiltflf3r*ubj*Ud 'V "lio«*^<3y8Sruiw»tor£ w ognft. ^ limited and controlled to present thfe highly toxic moony ft Pus am ExnoatoM HAXABM: YWde flammaMt vmpoit when wmpound from entering etnamt or 11 ODMSAIHEM O»um wwt twut bm. Uthil STOUOI: Protect ic^ut phyrfol duuf* tad Hon to dry b- ^tion. Bep«»te fro w Wdi-in miteruk Oirt*.U or modialdy by properly proteetod pcnoaiwl; M other* ihould Un RASAK»: Potoa ni; inbilAtioo m«y bt fatal or MUM femaiBfearea. Atuh with fioodini quuUtkt of watar. UMB bytd luog injury. Strm tyt, rvpintacy tnet aad •kil Mt eauftk aoda aoJution fur otutrtJiutkw. ritanritantt Jtnum: Set Fire-Huud JProperttaj BfFtanmibW UquSdi. pxaaoMAL Paoncnox: Wotr «p«Ul protoetbi dotUag. Cam and Volatilt Solid* (NFPA No. X25M), and Chemical Safety Data Sheet SIM (Jblaaufacturiai CbemkU' Aitoei> Put Jiom*9 P_usn: UN vater to keep tit-upotad cylindere •tioa,Iae.). «ooL If it b necessary to ttop tit* flow of (u, UM water rany to protect tbt men effecting •hut-off. Sodium feydroxidt or ubydrout •»*iyii*i* hart beta used to atutraliit phoi|cae. TJnALfiMimm ConTAurua: Bted eyliadciB and tank can. -HDWLCIHANOUM1N1 CANHOWIWH >K . fco™,: ft.,*, Hllnl, ,*„,„, d^ Bte, „,*,„ „ L Dttourno«: YeQowiA liquid with a fnttfai Mb* *&\y • to a weB-vtntilat«d ana of aonoombmtible eooetn*ctioa. (d 81* P ~~ — ^ ' ~ ^^J' - ' __ H _ „ .. _ . Rimiirt: Set Chemical Safety Data Sheet BD-M (llaaufto- Pkis AJO EZPLOHOH Hum*: Combuitlbk Bquid. Vlaih turing CbemUta* Aiaoeiatioa, Inc.) and Hycwate Guide point. 305* P. (oc). Liquid le digbtly bee Tier thin watar (Am^u.. lywf.^^-i Hrrr" A-^Hr^fMi} L {•peeISc pmvity. U09). SlighUy eolubb to water. . ^^ Lm RASAS*: Avoid any Bauid or vapor eontaot with eyie; •void prolooged or reputed eontaoft witk akla. PHOSPHORIC ACID H*POi PCMOKAL Paoracnon: Weer tetf-eontabed bwathing an. Datournoii: Hygroeeopk ttyawtat, (olid at room y^&s. C parataa;wttrgocit«ilf ^protection not providedT^ {gP**?^ ^SS!rl£Sl!^.ff m^ XX Pku Ptomwa PEAan: Vie water epru, dry ehemkal, "aloohoT Bolt, of pboepborit adl ^ foam, or carbon dioxidt. Water or foam may eauet frothing. - _ _ „ „.. . ~. . . . _ Vte water to keep firt-cxpooed oontahwn otiol. If n leakor fa* urn EXFUWOM BAZAUS: Not oombuttibk but wotert ^_fai «. _ _ _ ^* •__f. i .. _ _ T. _.•*_» k «Mtth *m+fm\mmjtfi •MMAM VABtfhlfltlAAA KWnPtf^***! MltaAK ••••» WfmVmm ___ Wmtfm flammaMt mixture* with air. Pboephonc acid and hi aqueow "£^Z**£m^'^'K?S£mZmL •olutk>M ^^ th" ^ (VKific Cimvity, U-1.V>. &lub)t ^B^^C^^C^d^.^tanl.* to^;MooW^b.itat^toWakto.^m»c« BroiAoc: Protect apiut pfcyifeal damagt. Store to n tool, dry, nembnnea. Conccntnted tolutiow moderately tofc by to- wtD-vtnuIated location, away from any ana* when tbt ftn gectioo. Under ftit oooditiom, toxit vapor* may fat formed. naaard may bt acute. Outeide or dffarhud itofait I* pt^ —_ u fvnd. Smarato from OKidictni matariak PBaaoMAt Paorxcnon: Weir edf-eooUined breathing an» Volatile Solid* (NFPA Na. _C22U>, Au Ptovnra Putia: UN water on I add i* involved. Uet water to keep Stftxpoied eoataiao* «.«. ™ — •°°1 Water «pray may bt ueed to fluati epUb away from •- PHENYLPLUOROPORM See ntaananoMm poturea. I: i. PHENOL t73 i. (1,10-phensnthroIine) L Vie: metal chelating agent , - ' PROPERTIES: n.w,180.21;m.p.U4-117*C WATER roLivnoN FACTORS: D ••Impact en biodegradatfon: \ 1407) phtnoehlor DP<6 A polycblozinated WphenyL•. • " , -. • D, ilOLOGICAtSFFSCTS: ,.^i : - r •' -Sediment dwelling polychaete fftrtts jiventcotor accumulated DP-5 from sedi- ments up to a concentration factor ef 3.5 (worm/wet aedimenO-equflibrium was reached after 40-60 days. A Wbloglcal halMife of about 27 days was com- puted ^X;fl O388) fhtnohep uthexachloroetbane , J,;^ ?j > , frWnot (carbolic add, kydroxybenxeae, phenlc add, phenylic add) C*H|OH A. PROPERTIES: colorless tffl brown-black; B.w. 94.1l;m.p. 4rC; b.p. 112.0 C; v.p. 0.2 mm at 20'C. Imm at 40*C; T,d. S.24; sp^r. l.07;aolub. 12 g/1 at 15*C; sit .eonc. 0.77 g/cu m at 20*C, 2,0 g/cu m at 30*C; log P#ct 1 •*& G a. AIR POLLUTION FACTORS: 1 mg/cu m « 0.26 ppm, 1 ppm • 3.92 mg/cu m -Odor: ehancterirtic: nedidnal, tfcfcenlng sweet and acrid with a aJurp and turning taste . • to-' «-• to-»Lto-* tp-» to-» w1 i to to» to" to* druciien y f»H c I? a;3;4;5;9i57;73;279;307;602;613;670;«76;704;709;749;7SS;.t28) USSR: fcunun odor perception: con perception: 0.022 mg/cu m ' '] perception: 0.184 mg/cu m fcurotn reflex response: adverse response: 0.015 mg/cu m «nkul chronic exposure: ao effect: 04)1 mg/cu B . - itfverae effect: O.I mg/casn G70) AR30Q893 I •74 PHENOL 1 OJ.at20'C«I6 -Uanmade sourcea: . to exhaust of a 1970 Ford Uaverick gasoline engine operated.oa a ch "~ mometcr following the 7-modt California cycle: i from API #7 gasoline: 1.4 ppm from API #8 gasoline: 2.0 ppm -Control methods: activated carbon: retentivity: 30 wt* of adsorbent I wet scrubber: water at pH 8.5 " 11 odor unlts/scf in effluent : XMnO« at pH 84 • 1 odor uniti/icf to effluent •Sampling and analysis: photometry: mia. full acafe: 105 ppa C. WATER POLLUTION FACTORS: c -Oxidation parameters: . :-'M 0.05 manom, sewage, at 1,000 ppm 2.0 manom, adapted sewage at 1,000 ppm E 1.88 slerp, adapted sewage at 1,000 ppm 4 days: 0.54 sterp, sewage at 500 mg/1 . 1.84 slerp, adapted sewage at 500 mg/1 lOdaya: 2.1 .,-' ' r&flSS? BOD,: 33%ThOD;90%bio.ox*;55%bto.o*** 10 days: 89* bio. ox'; 74* bio. ox" 15 days: 87% bio. ox. (•); 78% I 20 days: 96% bio. ox. (•); 86% *nonacclimated. fresh dilution water **nonacclimated, salt dilution water bio. ox. • biological oxidation k BOD,: 1.68 KEN 3235-5.4 COD: 2.33 NEN 3235-5.3 COD:; 2.28;3.2;2J8;2JO;2.37 100%ofjThOD KMnO« nlue: add: 84% of ThOD alkaline: 80% of ThOD 9.66 TOD: 2.35 TOC: 100* of ThOD ThOD: 2.26:2.40 —Biodegradation: L pathway of breakdown: C - 0 -COOH CHi-COOH CH|-COOH -Btodetradatloa to COs ta estuirine water r ; . ,-,... ffHEIHOL 91* """cone, incubation , -degradationnte (kig/I) snonth time (hr) (ffg/Vday) X JO* 5 lan. 34 270*20 10 J*n. 24 150*10 5 March ,24 : n ,,100*10 10 lune 24 580*40 17 (381) i: cone, mg/1 BOD at 30*C, to % ThOD* 94 kr 2 3 £,' VU: * 0 10 ^: 13 2 15 ^- 14 3 30 15 4 35 16 .7 10, 36 •-. f (172) inhibition of cellulose degradation — at!7hr at200hr by nitunl aoH populations .' 500ppm phenol - ; 73 i% 44JD% 1000 ppm phenol .- ^.; 97^ % , 56 J % • 1500 ppm phenol 98.4% 60 J% 2000 ppm phenol .' 98.6* $9.1% 5000 ppm phenol ' 98.7ft 99.5 % (1*67) Inhibition of starch degradation { at 20 hr at 140 hr by natural aoS populations ' 500 ppm pheno: .:, 41 * , 40 J% 1000 ppm phenol " 96 ft 52.7* 1500 ppm pheuoJ 97.4% 851* 5000 ppm phenol 98.4% 98.4ft (1167) i I7» fHtNOt I Inhibition of photosynthesis of a freshwater, aon-axenk vnlalgd culture- 5«.«nurnfin capricornutum: at lOmi/1: 105*carbo»44fIxaUcaXn. 30 XJ 29J 98.5 1J5 40 34 J7JO 92.5 ! 3J3 70 8.0 62.0 85.5 3.88 80 8.0 72.0 90.0 4-53 100 , 30.0 70-0 70.0 4.40 115 40.0 75.0 C5.0 4.72 120 60.0 «0.0 50.0 3.77 140 80.0 «0.0 42.8 3.77 190 132.0 «8.0 30.0 3.65 * 270 , 3344 $4.0 30.0 2.14 .phenol removal by forced .drift cooling towcn flow ample location Mgil/day cone, mg/1 % removal (26) makeup 0440 17.0 - Mowdown 0.144 0.202 98.8 makeup 1-590 8.6 - Slowdown 0.875 0.167 98.1 makeup 1.648 12.7 - ' tlowdown 0.175 0.261 99.6 makeup 0.865 41.0 - . Wowdown -0.144 0.238 99.4 U makeup 1.440 47.8 blowdown 0.720 ^ ^ 0.231 99.5 (26) degradation by ffrudomonoJ'. 500 mifl at 30*C : parent: 100* ring disruption to 25 hr'! '. mutant: IOOStrinj disruption ta 8 hr (152) A.C.: adsorbability: 0.161 g/g C. 80.61 reduction; ind.: 1,000 mg/1. cffl.: 194 «V/1 (32) A.C.: Influent carbon dosage affluent ft removal 1.000 ppm 10X Jppm 99+ 300 ppm IOX 2 ppm 99* 100 ppm IOX I ppm 99 (192) km exchange: adsorption on AmberUte X AD-4 at 25*C Infl.: 250 ppm; eoluie adsorbed for aero leakage; 0.78 Ib/cu ft for 10 ft>m leakage: 0.83 Ib/cu ft adsorption on ambertite X AD-2: infl.: 0.4 ppm, effl.: 0.22 ppm; 45% Tetention efficiency ^^t r; adsorption on amberlite X AD-7: retention efficiency: 86* ton.: 0.4 ppm, effl.: 0.06 ppm " (40) solvent extraction '" L influent affluent K phenol aolvent mg/1 mg/1" removal remuts aromatki?5* 2OO fl, 99g aolvent regenerated paraffins 25ft *w w<* **'* with ctuctic;bb study aliphatic asters 4^00 40 . 98 J regeneration by 4istilL feenzene :;.-.> »0-95 tegenention by AR3008S7 •?• PHENOL benzene 750 34 95 J caustic ngtncra Ught cycle ofl , >300 130 9ff _ electrostatic ax^a^™,._ also removes oB C ''* water at the same light ofl 13.000 ±35 98-99 J centrifugal extra ! caustic regeneration I TMcresylphosphat* 3,000 '300-150 90-95 steam or caustie very high extraction ' ' coefficient I aolvent extraction: distribution coefficients for a 2ft phenol solution ta wlittf 1 " aolvent . distribution coefficient iemp.*C benzene 2.2 20 Imonochlorobenzene 2.0 30 tricresylphosphate 38.0 20 diethylether 17.0 30 dilsepropylether 17.0 30 [ • butanol 19.0 30 , ethylacetate 36.0 32 Isopropylether 433 33 phenosohtn 49.0 22 yphenosolvan 38.0 60 diphenylxylenylphosphate 26.6 30 •" coagulation: NIL* BOD reduction with 3 Ib alum/1,000 gal air flotation after chemical addition: 40% removal reverse osmosis: 0* rejection from a 0.01 M solution' • y percent recovery of phenol by iron copredpitattom ft phenol recovered by coprecipititior.1 distilled Lake . Fedt.Jf water llendota water 1 0.005 21 60 0.01 39 63 0.015 32 66 0.02 J* « 0.025 40 70 •Initial phenol concentration 1.06 X 10"* JT with a pH of 8 J. : i effect of pH on recovery of phenol by Iron coprecipttatton: L J ft phenol recovered by copredpltatfon*. Lake Wendota LpH water m 7.5 57 8.0 56 r*- ,i.-**V" ^"fv<^K 8.5 62 '••?**].?**v V«2?i 9.0 63 • c _ '.» 10.0 unidtpted A.S.: at 1 mg/1: 100% removal after 3 hr 10 mg/1: 1 00% removal after 3 hr } 00 mg/1: 20% removal after 6 hr 3003 • . " _ -Aquitic reactions: ' .""V •'•' • • '..•'• -" .•..'•: ..'--^ '.-•" '"•""' photooxidation by U.V, ttjht in aqueous medium at 30*p i6.9fijt degradation •v toCO1aftfer34fcr -. •'..'- ..;L :\ '.• ^(1628) autoxldatioh at 25*C r|/»r 286 fcrat pH 9.0 • 629 hi at pH 7.0 (1908) -Water quality: ' V in Delaware liver (U.S.A.): cone, range: winter: 2-4 ppb ' - ' . • - • /' • •"• ••; •' ,:.:.','..'."• ." .summer:».d. •' • '.'- (1051) -Sampling and analysis: ' ; - - U.V. photometry: min. full scale: 0.7 X 10~*mole/l |53) differential U.V. photometry: min. fun scale: 100 ppb (75) extraction efficiency of macroreticular resins: ample .flow; JO al/min; pH 5.7; cone. 10ppm: XAD-2:27ft ' X AD-7:45% (370) breakthrough capacities with "Vi .-5.1 900 rHENOL M1 bluegills: aoft water: 24-48-96 hr: 25.8/23.9/23.9 mg/I goldfish: aoft water: 24-48-96 hr: 49,9/49.1/44.5 mg/1 guppie.: aoft water: 24-48-96 hr: 49.9/49.9/39.2 mg/I (158) rainbow trout: lethal cone.: 5mg/l, 3 hr (154) perch: fethat cone.; 9 mg/I, Ikt cruclin carp: TLm 24 hr: 25 mg/1 roach: TLm 24 hr: 15 mg/I'.-.. ; tench:TLm 24hr: |7mx/l •*. "irout** embryos: TLffl 24 kr;J mg/I (222) Ctrasifut gunrut (goldfish); TLm 48 hr: 44.5 mg/1 rainbow trout: TLm 18 weeks: 4.0 mg/1 (222) creek cftub: LD9:10 mg/1 in Detroh river water LDiM: 20 mg/1 in Detroit river water (243) blue gill sunfish: TLm 24 hr: 22.7 mg/1 in std. ref. water (253) goldfish: LD«, 24 hr: 46 mg/1 - modified ASTM-D1345 (277) goldfish: approx. fatal cone.: 28.9 mg/1; 48 hr (226) Cobiut mtnutut in ses water at 15*C exposure time; ECf e after recovery period in unpolluted aea water Omin ; Ito3br 24 hr 1 min >J 8,000 ppm 1,000 ppm 400 ppm 3 min >18,000 ppm ' 400 ppm 400 ppm 9 min ±18,000 ppm (328) Cobiut mtnutut in sea water at I5*C: exposure time; LC«0, «ig/l 9 min ±18,000 ;! IfcT 85 .... j 3hr 20 V ; 6hr 15 I2hr 13 • ,i 24 tor 10 ,48hr 10 "• V ..- -.72hr - 9 96 kr 9 (328) LCjo , ,..,:. 48br 96hr 10 d ! ang/l mg/I mg/l fc- trout: flow through bioassay: , ,|1.6 .114 11.6 atl5*C aebrafish: flow through bioassiy: ' 30.9 39.0 29.0 at25*C L fl*gfish: flow through bioaasy: 36J 36.3 36 -3 at25*C Vordanetta Jloridat) i * - (479) fathead minnow: flow through biowssy: 24 hr TLm: 8.21 mg/1 at 20-25*C 96 hr Tim: 5.02 mg/I at 20-25'C (442) fathead minnow: static bioassay an Lake Superior Water at 18-22*C: LCse (l;24;48;72;96hr):>50;>50;>50;33;32mg/l (350) Ophicephclut pvnetetvt: 48 hr LCM:46.0 mg/I (stalk bloasssy) (941) ,3 (1833) RR30090I' •82 p+HENOLSULFONATE. SODIUM fathead minnow: flow through bkumy: 48hrTLm: 41 mg/lat 15*C 28mg/lat25*C • 96hrTL»: 36mg/tatl5*C 34mg/lat35*C goldfish: 244 LC,,: 60-200 mg/I (S) golden shiner: 244 LCM: 35-129 mg/I (S) bluegffl: 244 LCM: 19*160 mg/1 (S) rainbow trout: 244 LC«: 5.6-11J mg/I (S) (| i -Mammalia: rat: single oral LD|«: 0.53 g/kg rabbit: single oral LDft: 0.4-0.6 g/kg cat: single oral LDM: O.I g/kg '*J™™ ... dog: single onlLD»: 03 g/kg «J»*.'», -Man: oral, ingestioa: tg dose may be lethal p-phenolsulfonate, aodkim O D. BIOLOGICAL EFFECTS: [,"* —Crustacean: Daphnm magiu: 24 hr, TLm: 13410 mg/1 48 hr.TUa: 13^10 mg/1 72hr,TLm: 3,494 mg/1 96hr.TLm: 1,471 mgA -MoQuscs: snatteggs, l?fflMet4p.: 24hrtTLm: 10,700 mg/1 48hr,TLa: 9,122 mg/1 72hr.TUn: 8,828 mg/1 96hr.TLm: 1^28 mg/1 -Fish: LcpomU macrochlnu: 100 hi, TLm: 19.616 mg/1 1-ph«nol-4-4utfonlc add *e* 44ydroxybeazeae wlfonk add phenoxyaoette add o1,COOH A. rxorEXTXES: solub. I2tOOOppmat 10'CiJog^oct l.26at20*C •••< 7117 tummll F«w mmrtm. Sweettott CoforUw, wkuhr cryttat* «r vlriu. «(ytf to WO punt ooJ4. JO pan, bot water •eritlk odor. JWiMMtf «•/ wuMfer PTMC «0 »idd«n M ttx brdrachloridc with wWUM« faeampat with •ipoture 10 air «»d Nshb kuieMd by fn»»ot «f atkatiafty. 1.071. Wfc«i free Irem mter Md urmol* k «ons»J- M 41* •nd HielU *l 4r. Ultnpur* fill ttnoctUc mcrdaisrl. product •onuiiw ao Impurity •fcJefa fal*e§ Ihe •a • 10.0. pHoteqsotM about 4.0 ky w with about »% water. One fram atUMiv* fa **>J*rr-ociylphcnoKyetliyldfcthylben- about 15 ait water, 13 ml kenaenc vary ad fa atoobot. ahlo* c 75.03%ahloride. K 9.10%; Oclaphea. a ajiV. C-H^CC-H^CINON i,}i,}4%I4 .; o mo X7o%t w.t reform, ether, ffyeerel, aarbon alitulfidc, pctroUtum, *oletttc my. Rrft. •«. 7W.477 OM4 to Ward and fUod «ik. ao alkali bydiwWm; abnovt faaol to petr . C-tM, I14S* (1*60). aiher. U>H arallnb«r.ao.aii(i944)y fa nu: 910 •s/kcT . Pdchoiana. / Fbenol Ma(uUt« aollodioni H^ucrm *r Mmlliqiild whan MtwraHd wlih •oeuiiUidc ebloral hydrate, camphor* VMoobromaiad •mpkor. aktent -«w* er kydnta, tfurMla. had aertata. M^tbol. Mpbthalaae. Mpfe- Ihol, aoctophAcUdifi, nrafillol. iworc-Ml. aaloL aodim pbocpluu. Ibymot, «r«th*n«, cbloralutUdfc wrpin hydrau, Ammonium _alt, df^NO, mmmftUmm fh WWu to pio* aryii mum*. Sol to viler. Cryrult from *M aotuu. vp 112-114- (Goldbc.* Hum** TtMictijc Isseatioa ei «wn amall anotnu nay alyli mp *r (Enekaev). MOM*, vomltiag. tfrculaiory oolbpw. udtypoaa, Ortbophoephaie w lubricant: Sanmcai. gunmen- IMratytis. , Brit. pel. 790.056 (I93S to LCD. vriiw, Mcro»is cf noutli Md O4. fnct, kunit. tfoatb Iraai failure, aomclimei from Mrrflae anvt. A«vra(e fcial tfoM U 13 s but death from af Nttic M «ac awn hat keen reported. Fatal pojwelnf nay abo woiir by afcia aUorpdea followioc application to krtc Afvu. tfiuftyl-aionopMnetbylfuanfdiac. _ with reoaJ and kepatic COMPATIBILITY CHARTS 70S PROTECTIVE CLOTHING L. I AR30090ij BFGoodrich chemical comparison chart o Mml lefeHntBoMlof V Acetate Merit Aott A^_._m — — •^•••Wi AeetiMeneftee Acetylene VetfBcMoriee PJ AetvtonMflle AMMol ' — fli*m»Hp*iMi AfWyf AfCOnOl MMneON . R •~B»nenaOri •eniawehyae fteniene « IrwrnCenMAete Ven^i Alcohol Meuri ft«fi*yl Ven*e»le •eniytCMoMoe B . ftiaeoeoNc fodwwi TMMulohMe •wlane V*vf9*vi . '- fttrtytAottato •elweeeoe •utytAleonoi •leeneAeW BtftyleMenyae •ftwtyfene l-lnof9»niea*Ha B Wywi** C-Calcium Hy«nMWe ho 'Octane p CanMfccAe*0 . tooereoMoi • - .- • . -. • a Cerftori Otoitte awatoovtAieoitoi • •~Kefaeene- '- - ' 'B Certton VMrecMenOe Ketonea ft VMraethylUM UciwAeW a l»»ene ft taacyanate Ce«o-Soive Acetate B Quo roe hen ytene QiiBnoe Chlorine VrtcMeraethane [i CMCrtneOei Mefc'wrtc OMofWe ft IMcreiyi Pheiaheie M CMOfOftencene Mercunr o TrWeeytAleotiol Chieroecetone Methane ftei • Iheinenela mine Methenol - B MeihylAceMte ft IMmtrowlwol Methyl Alcond B tHaiene Duorothene Chromic *e*0 Methyl **em«e ft TwreeNo t9M Methyl CeHoaolwe O V»raenHne CHrtcAeW atethyi ChierMe ft W-_ . Cotton feed Oil Methyl tthyl KetOM ft Dimethyt MyOrattM Creoeoie •ethyl Petmate B V-Mrnelme «•• Methytene Bwnige ft CupricMnnte Methyiene CMonoe ft N Methyl MethecyUte ft IrhOOtf rV^Mfvffwv^^ wWvOn^ AtfvOflC t—Oeceborene Meneehief»eniene f Menoelhanotmilna B KyMene deeelofte Mcohoi B Btetnytiwnine N-Neahtha»ene ft Biberene PHYSICAL Mewyl fitter MeahthM'Aromatic ft CHARACTERISTICS Oibwiy< Pnihaieie C L, V»neHe ktrenf th • P DietitereaereaeBe « • MMtoaenMMe P V»er Aesietenee 9 9 MitroettMne ' p Abretion ojeeittenoe B ft DieihyfamMo O * OUlObwtyt Ketone MMromethane f ft B ft • [ Diociyl PntMieie Oioeent ft B r OMliC ACM g P_fWniTrWnnert ft KEY: BmaneOae Aemoxeft ^ Bthanel •then B •in - Bthyt Acetate Parattwene TJito oomMrfton ahan ano»i the tetetive w- BthytAtoofMl eietaMe tetinft at verioue f*o*« meie*iai« to Bthyt tther f aoivertt* commonly me* Ml iMwetry. Wt eec* Bthyl Poratate Pentene B •mmentf mieiion at f*ove* in aervir BttiytenHme la arevetint com Perchi*r«ihytene 9 N N •ecurt. chenae lo B M m «enera' ctowee •houK be eteene* fcumee*- •toenel ~' | after «ee. e«rt EAST WIND INDUSTRIES. INC. """*"" ^""^ •»•••» . t , : . . Specification ^200. Adendum A CHEMTCM. RESISTANCE OF NKOmnNB, f.VeC. K BOTTL. Tties« tables, based on data from laboratory teats and records of service performance, have been prepared as a guide to the service** Ability of properly compounded products in contact with a variety of chemicals* • The*tables should bo used as a guide only* All requirements necessary { to satisfactory performance oust be taken into consideration* 'Tern* I perature; intermittent or continuous exposure to the chemical involved} and area of the resilient part which will be In direct . contact with the chemical are all-factors which affect serviceability* I The effect of those chomicals listed as injurious to these compounds ' nay be of such nature that these compounds will deliver adequate service life* The fact that these compounds are found satisfactory for a given service Is no assurance that the same compounds will be successful under different service conditions* I To determine whether these products will be satisfactory for a given [ application, test it in actual service* If this is Impractical, then devise tests which simulate actual service conditions as closely as . possible*- I- - NEO- tii P.V.C* PI.ENE niTTYI. . —————. ———— ———— \J Acetaldeyde * NR I. R Acetamide • L L Acetate * L L Acetic Acid, 80S R R U Acetone Nt( L II Acetophenone1 • * NR Acetyl Cloride • . • NR Acetylene Gas • R R Acetylene Totracloride • NR NR Aerylonitrile . NR L . -t Aluainua Chloride R R * Aluminum Nitrate . R R • Aluminum Sulfate R R . ' Amidol . * L K Aniine hardeners N!* NR L L Ammonia Gas-Dry • H R * Ammonia, Aqua - 1O# R R * Ammonia, Liquid Ml R * Ammonium Hydroxide R R R Amyl Acetate Nl» NR Nit Amyl Alcohol * R R Anhydrous Ammonia • L R Aniline Nit Nit NH Aniline HydrocloririA. Nil NR NR Animal Oils R L Anodex L R Anthracene _NR .___ Nil •Aromatic Fuels Arsenic Acid KKO- rage 2 ''-v-c- • R R • L KR Bnnena Oil * KR KR Barium Chloride R ,Jl , • • Ben*Aldehyde, 10* R KR L Bcnzaldehydo, above 10# . NK KR • Benxcne KR KR KR Demon* Benzol . Kit KR . .. •» Benzene Sulfonic Acid, 10# R R • Benzol NR KR .Benzyl Alcohol R R Benzyl Bcnzoate L NR Benzyl Chloride NR . I. [ Dlacosolve I. V Kn I JJoric Acid : R • Boron Tribromide L NR | Bromine L NR [ Bronofora L KR Butane ' R R KR • . 2-Butanone * L L Butyl Acetate * L KR K37 . I Butyl Alcohol L R It ButylAidehyde • t . I. IiiRutyleue • -Nil R L Butyric Acid, 50?i ' R R « fltniun Oxide FUJI* • • R R ' ium ftydroxide, 505. . • 1C R -I. . i^arbolic Acid • • R . « R •'Carbon Bisulfide -, " KR KTl • ; Carbon Dioxide, Dry ', R R U Carbon Disulfide . NR NR < Wl i Carbon Tetrocloride Nil NR NT. , Castor Oil R NR KT. Ccllosolvc L KR L Cellosolve Acetate NU L L Chlerdane , * L KR • Chlorine ..• KR L .. R 1 Thlorino GAS, Dry KU KR L 'Chlorine Gas, Wet NK KR R v Chlorine^ , Liquid Kit NR *R ' ^hlorobenzene • • KH KR NU ^ \* L;^hloreAcetone ... * I* R Chlorobromom*thnne • NR NU Chloroform NT. KR K» Chlorophtnyl^ne Dianinc • -,L KR Chleropicrin Nil NR KR :iilorothene KP. KR NH Chromic Acid N NU KR Chromic Acid, JO* K KR •-. *^rA«ip».ex . a » t nionnon? l/ric Acid - ._ . R ArioUUbU_/^ x^il T*r Pitch Volatile* Kit y& » Cottonseed Oil " • . L - Nn AJ :olton Dust (It.jw) • ^____n R /* Creosote .: I. * .. ' ' "^ . NEO- '•--' ^_> P.VeC. I'RRNE BUTYL Cresylic Acid, 50* « NR • Cupric Mtrate * L R Cyanide • L L ~ Cyclohexane • L NR Cyclohexanol KR L L Cycloliexanoiio KR L L Drcuhorane NU Nil Decreasing Fluids . NR NT. Dtac*tone Alcohol R R PiborAne .Nil NR IDibvnzyl Ether • X I, Dibutyl Phthalate - NR Nil L Dichlorobcmzcne (Ortho) Nit Wl • Dicliloroethantf * NR NR Dlchloropropene * KR NR Dies el Fuol It II NR * Dicthanolamine •• R R Difttltylamino • ' NU L L DJethyltriatninc * L L lUJsobutyl Ketone " NR NU L Diisocyanat* • 1, U Dimethyl Formanide NR NU L Dioctyl Phthalate NR L NR . (j Dicixane * R L ^^ Fmtilsifyinf; Agfint • L R Cmnlthogene . * L R Eptchlorohydrin * L L Epoxy Uosir.s, Dry • R R Esters * NR NT: Ethane Gas • R U Elhanol I. R R Ethers % » R L Ethyl Acetate NR W L Kthvl Alcohol ' * R R Kthyl Ether Kll L K Ethyl Formate • NU L L r.thylaniline . • Ml L Ethylvne Iliamine * It L i Eth}-1«ne Dichloride Krt KR Nit Ethyl one Ga*. * I: U Bfhylene Giycol L R R Elhylene Oxide 7*'U L • rthvlene Trichloride • XR NR Tatty Acids II n Kit ferric Chloride H 1- * Ferric Nitrate . . R H • Ferric Sulfnt* U R * - Perrocyanide • • NU ft R 3?) 090, Ferrous Sulfato Ii R • \^s KJunrino Gas, Vet - H L : 1* Fl.ir»ric Acid R R It Fluorine ' • » L L Fluosilicic Acid R R • formaldehyde, 50* . ^Jt______U^ Formic Acid ^ J»age 4 P»V.C. PRENE BUTYL ; Kreon F-21 KR L *, KR , Freon F-22 KR L . KR Fuel Oil "" R R Rr • Furfural NR L L Gallic Acid R * * Gasoline, Leaded R L KR Gasoline, Unleaded R L • KR * ' Glycerine " • R R I Glycerol * R R Glycol * R x R ;• f Geld Fluorine * L R I Grain Alcohol . * R R Halogens • L L M Hoxamethylenetetramine * KR L | Hexane NR KR KR Hexl Acetate * KR KR Hydraulic Oil j .Ester Base m • R - ' L 1; Petroleum Base . " KR L KR Hydrazine , • KR .L rm Hydrochloric Acid * R L |>'J Hydrofluoric Acid • R L i lydrofluoric Acid, $0*A R R • ^-Hydrofluoric Acid, 50# L R • " Hydrofluosilicic Acid R NR L . Hydrogen Gas * * R * R Hydrogen Peroxide - }Q% • . L L Hydroquinone R L L I Inorganic Salts * R I. Zodine . KR L L . Isooctane * 'R NR - Zcopropanal ' • .R . R Zsopropyl Alcohol R R R . . Kerosene n R KR . Ketones . , ' KR L R Li Lacquer Thinners NR L NR Lactic Acid L R J, Lactic Acid, 25^ II R R t La uric Acid , - L R R Lineoleic Acid * R KR I.insecd Oil R R NR Lubricating Ofl R R * Magnesium Hydroxide • R R * Magnesium Nitrate R R • Magnesium Sulfate R R * ' Maleic Acid ' L R R Mercuric Chloride R L R II L Gas * R lethanel L R Methylamine NR ' KR Methyl Acetate • L Methyl Alcohol •______R Mothylanine Mctliyl Bromide —-'—«?.*,' i£«...... fc_». .»_.._ .,.."„ ,.... _._. _J__'_1' ' '' " • • • •• • , - .._ ...... _.. _. ————.IT.Tt..™« "•——————*l»l*« ---.C. * f ege 5 P.V.C. NEOPRENE BUTTL Methyl Chloride NR KR NR Methyl Ethyl Xetone . NR L R Methyl Formate * L L Methyl Zsobutyl Ketone • NR L R Methyl Methacrylate NR L £ Methylene Bromide • NR L Methylene Chloride ' NR NR L Minderal Oil R R NR Monoehlorobenzene • ... * NR NR Monoethanolanine L R R Morpholin* R R Muriatic Acid R R Naptha . WR v R • Napthalene L NR Napthas, Aliphatic R NR Napthas, Aromatic L NR Napthalene NR NR NR Niclcel Acetate R R * NieVel Chloride R R » Nickel Nitrate R R • Nickel Sulfate * R R * Nitric Acid . NR L NR Nitric Acid, red & white fuming » NR NR Nitrobenzene NR NR NR Nitroethane • NR NR Nitrogen Gas * R R Nitromethane . NR NR NR Nitropropane NR NR NR Nitrous Oxide R L L Octyl Alcohol NR R R Olelc Acid NR R L Oxalic Acid NR R R Oxygen, Liquid • NR NR Ozone • R L L Paint Thinner s . NR L NR Paint & Varnish Removers NR L . NR Palmitic Acid L R R L Paradichlorobenzene • R R Parathion * KR NR Pentaborane * NR NR L Pentaehlorophenol * NR L Pentane R R L Perchloric Acid NR R 1* Perchloroethylene NR NR NR Perklene * R NR Permachlor NR L KR Petroleum Spirits NR , R ^ Phenol L R H Penylenediane » L L Penylhydrazine NU A R 40 0 9 I (J Phil-solve • R £ Phosphoric Acid L L J Pickling Solution L L Picric Acid( NR » Pine Oil 1* * , Wtch NR R NR • " KEO* Page 6 PeV.C. PRENE BOTYL ( 1 at ing Solution* R R R V^otassiuro Alum ?t V ft Potassium Bisulfate • R R • Potassium Bromide R L R Potassium Carbonate R R . . » Potassium Chloride . R R • potassium Chrome Alum . e . j, R Potassium Cyanide R R e Potassium Dichreiuu>o R L NR potassium Ferrocyanide R L R ' Potassium Hydroxide R R R ' Potassium Iodide ' e R potassium Nitrate R R e [ Potassium Sulfate R R • | Printing Inks • • R ' L Propane Gas e R H Propanol (iso) * R R Propyl Acetate KR L L Propyl Alcohol L R R Propyl Alcohol (iso) L R R Propylene Gas * R R Propyne Gas R R Pyrethrum KR NR Red Fuming Nitric Acid R R Rhodium Fume t Dust R R Silver Nitrate KR L ^kydrol 500 Sodium Carbonate Metol * L** R« 'Sodium Hydroxide L R R Sodium Kypoehlorite R mi * Sodium Sulfite ' R L R Sodium Thiosulfide • L R Solvarsol • R KR Solvessos * KR KR Stearic Acid R L R Stoddard'a Solvent KR L L Styrene KU KR KR Styrne 1005C • KR KR Sulfu" " r Trioxid" ' —e— LR L R Sulfuric Acid, 80% MR Nil R Sulfuric Acid, 9k% R R R Tannie Acid R R L L Tetraethyl Lead . KR KR Tetrahydroborane KR L KR 'Tetrahydrofuran KR KR KR Toluene NR KR L Toluene Diieocyanate KR KR KR Toluol • KR KR Trichlof»• »WII»W*- . e0 L^ L Trichloroacetic AciAi d ^ Trichloroethylene Jen KR . Trichloroethane ._ V^/Tricresyl Phosphate £" Tridecy,^__ » M ^ __'_l• AlcohoA • __•___l* L -R X- Triethanolamine , R . KR Trinitrotoluene ^ L UK Trinitrotoluol -————————-—————-WR „- Triptane ' ~ , ^S*** » ft 4 \ ... MEO- r«s« 7 P.Y.C. I'RENE "™^^^™*Burn.* l^1^ >^ Turco No. 299S * Turpentine L KR • NR Unaymmotrical- Dimethylhydrazin'- ' — ' e NR KR Varnoline Gas R NR Vanadium Fume ft Dust R R Varsol L NR Vegetable Oil*; A L Wood Alcohol 1* R R Voodyouth * * KR L Xylei.e (Xylol) NR NR NR Xylol NR NR NR Zinc Chloride * R R R R - Recommended L - Limited Resistance NR* Not Recommended • - Information Not Available I, -VI AR3009I2 -?-_, j;~' : APPENDIX C ' :' ' '• " :• ' ?> ,K -f • - ' ; '. ; ' ' '' ' ' AMBIENT t AIR CONTAMINANT MONITORING DEVICES ^ - V ' • 1 '• •• '•* 'i AR300SI3 - .... . [in £^&£?&jj$& & B3U ^.'v'' -4*S'- . *S*&%3; *'% »] > 0__..._. ._..._... 5F?4li/1^ ?*-•>••-'«^s^. •*+#?-;-j.:^r<•~r<^J±; ^ • ————— "••<•- —— tf.« ;>^r,-&:t £ -:v -:^^.-^^af^v^.^^^K^;^ -• .- •"a-*-.*1- "tiskf«''« 11 • - S-i v. -•.•>"1 - -'•'»*•~" T•«» is '*> ^^y^"1.*'* '-"VV-^ i'- ^ -W*^,**1 vv^ \ ';*•, tj,*; h ^J^*"'^u ••<..* * /* • '"; .... J«SSM'"'i?31 i ^ .-'-*" MONITOR > \^ IDEL241 -T.^;.-"'.*.- ••-•%,>••? -?.n' Specifications Interferents Ordering information Temperature range: 0 to 125*F (CO); CO: Any gases or vapors that are Catalog numbers 40 to 90°F (NHj); strong reducing agents could increase »».,. 40 to 90°F (SO,); the length of stain, thus indicating a «937» 32 to 120°F (NO,); higher CO concentration than actually *-AMM 82 to 120°F (H,S). exists. Some specific examples are 469405 Relative humidity: 10 to 90% hydrogen sutfide and acetylene. Most ^CQ*BB Accuracy: *25% . common gases 6r vapors at their «WBB Range: CO-0 to 250 ppm. Threshold Umit Value (TLV) levels ^ce,BC NHj-0 to 125 ppm cause no significant errors. «M*« SOt—0 tO 25 DOm - - - , ,..-,.:" , - . . vowmvivr wwca. wo* »• iw H,S-Oto50DDm ,NH>: Acid flases may decrease stain 469414 VaporGard nitrogen dioxide uru_n»A«n^m length; other amines may increase dosimeter tubes, box of 10 : stain length. . 469062 Tube holder assembly SO,t Acid gases may give a positive . ' indication; other common gases within r ' • -I' their allowable limits do not interfere. HiS does not Interfere. H,S: Other common gases within their L - allowable limits do not Interfere. i. , NO,: Halogens will interfere by Increasing stain length. , Note: This Data Sheet contains a genera) Bnflr^^f"** 600 Penn Center Boulevard _ - -. . - , ,- I description ot VaporGard doiimeter tubes | ifj UTf * 1 Pittsburgh. P«. 15235 USA fl R 3 0 0 9 I 5 •no mciuoes a MSI 01 representative nazaros jj fj,1 f|Bi Phone (412) 273-5000-Telex 8124 ^^ lr»aS*!^uJ!eiflJJ?!^™?fVrnltti.v?_h*z'rdt can be detected; however, underlie s il >il f<.M •. Phone(412)273-5000• TelexB12453* circumstances thouKJ the products be used , worldwide aerv.ce: Breneh offices throuohout the On»ed States. except by qualified, trained pertonnef and Subsidiaries Nc Amsterdam > Barcelona • Berlin • Calcutta • not until the instructions, labels, or other Glasgow • Johannesburg - Uma • Me*teoCrty • Milw • Ndolt - literature accompanying them have been Fari§ . gmtlage • Sao Paulo • Singapore • Sydney - Tokyo - carefuHy read and understood and the Toronto. Representatives In principal cities throughout the world. precautions therein aet forth followed Only they contain the complete and detailed VaporGard™ Inorganic'; Vapor Dosimeter Tubes Application Description A tube holder assembly is used for personal sampling. A molded rubber VaporGard inorganic vapor dosimeter VaporGard tubes are passive dosl- holder retains the detector tube Inside tubes from MSA provide a simple and meters. They work by diffusion; thus. a Lucite protective sleeve, and an economical method for measuring the no pumps are required, The user simply alligator clip allows the tube holder to exposure of workers to the toxic vapors breaks off one end of the detector tube, be easily attached to the worker's of inorganic compounds, such as car- Inserts the tube into the holder, and clothing. bon monoxide (CO), hydrogen sulfide attaches the holder to his clothing. The „.___-„.- ...^ .,. «aH. ~i «i.*« (H,S). sulfur dioxide (SO,), ammonia tube can then be used to sample the ^Sf^S^KS^mSf^JKi^ mi. and nitrogen dioxide (NO.), atmosphere for up to eight hour,. •* f^Sly^ If the gas being tested for is present. packed in boxes of 10. Their shelf life the VaporGard tube will change color. Is 30 months. To determine the gas concentration. L the user measures the length of the color stain in millimeters from the scale printed on the tube. A graph gives the average gas concentration as a function of stain length and sampling time. No separate read-out device la required. VaporGard tubes operate by color- Imetry. The vapor of interest reacts with a chemical within the tube to pro- a p O O H 0 I duce a color change. VaporGard tubes • H n J U u -* * use two different methods for con- taining this colorimetric chemical. In . the CO tube, the chemical la an impreg- , nated silica get. In the other tubes. a paper strip is impregnated with the . appropriate ch—»*-*' , Data Shee' . fWb««™ttrtfr«flD|A*n^«*f^ 6aS and Vapor Defection PrOI-llCU " To nature air pollution directly at worlclne places. «kvr torn . • . ' : ; jnj^Bn and fc/v-ferm tnttsurcmentt to determine average con- - eentrattooj ere carried out, predominantly according to tht . — ~~ ; LI ', .4, i&sfcsfef- L.I THE STANDARD DRAEGER OUTFIT .'..., nO 1 The atancUrd Mutti-Gas Detector outfit has 1. Hanfit-operated bellows ptfnp. B R 3 0 0 9 " th«e eomponenu: Z Rugged vlnyrcarrylng ease. • * 1. Spare parts 'Wt. •penjtfng In- . * «tfwctions. tool kh. BGI INCORPORATED $8 Culnan Street/Waltham. Masnehwem 02IM/Ttieohon* ftfcw«/»«*^tocfta/v*.vflfto(.f/»^ DRAEGER . .. INFERENCE A J •MSCmmmi-- PRICE NUMBER ^** Multl-Cas Detector Modal 21/31 Deluxe Pump Kit fwtth stroke counter) 9 255.00 CH3040 Multi-Gas Detector Model 21/31 Pumo Kit 230.00 CH304 Pumo. CM Detector Model 31 150.00 6726065 CO Kit (Model 31 Pump with Carrying Pouch »nd1 txw-CH 25601 Tubes! 177.00 CH150 Carbon Pretube 21,00 CH 24101 Activated Charcoal Tubes (Tvoe G) 11.00 6728831 Activated Charcoal Tubes (Tvpe B! ,11.00 6733011 Silicaael Tube* 11.00 6728811 SilicaoelTubttfTrpeG) i 11.00 6728851 Smcaoef Tubes fTvPe B) 11.00 6733021 I CO Breath Kit - 32.00 CH270 Dosalert 295.00 4034002 * Oosatert Battery Pack 59.00 4000003 Dosalert Barterv Crtaraer 34.00 4000002 Polvmeter with Caie 695.00 6729044 Quantimeter 1000 1,430.00 8101000 Universal Charoer for Quint imetef & Polvmeter 125.00 6806430 Air Current Kit 35.00 CH 00216 Aspirator Bub 10.75 CH 12867 Half MuC-Frt Tetter (Model HMT/Canoov tvoel 525.00 4054024 Mask-Fit Tester (Model FMT for full masks) 400.00 4054068 Aerotest (Type A for low-pressure aoolteations. 150 cni max.) . 455.00 4054001 Aerotesi (Type B for high-pressure applications. 4.500 wfmaxj 1,740.00 D 20700-R i- Has Mat Std. Pump/Tube Kit 825.00 4054208 ^ J PRICE PEA DRAEGEA . THRESHOLD * OASES AND VAPORS NATIONAL DRAEGEA PACK OF REFERENCE MEASURING LIMIT VALUE TO BE MEASURED TUBE TO BE USED 10 TUBES NUMBER RANGE (USJL1W5-M) AcetaBehyde AeetaWeriyde 10CVa $26.00 6726665 100— 1000 ppm 100 ppm Acetteacd Acetic acid S* 27.00 6722101 s—eoppm 10 ppm Acetone Acetone lOCVb 27.00 CH 22901 100-12,000 ppm 750 ppm Acetylene Hydrocarbon* 0.1 NIOSH Certified Tube 'NtwTutx* 9*SfntOc»tinttubtt.9pn ...—,..,*_ *;.7lV/C*ff6* 1 O-crfptlon 1986 f * fete RefartneaNo. OucriptlM fete* ~ fUftrtneaNo. CH«728 • * Ad-ptar to waNIOSHafea total : •IBM • CwryInf l CM* for Pump 47.00 4039001 ' «*9!*w"" /-" "• Btoufd* Strap for Gmvtne eate 6.00 4039007 ScfWwdrhNK.Speciat. Model 31 4.00 4039003 Automatic Stroke Counter 40.00 •726124 Wrench, SpecieLModet 31 3.00 CM 6764 Carrying Bag tor OetoctorTubf, . . 31.00 4031001 , Pack with Cpara •««. Model 31 31.00 •727211 V rvmp. and Stroke Counter • Peek w/10 Rubber dpt. Model 31 3.76 CH16G3I Adwtor nut for axtenvlon ho** V.fM CH6291 - Accessories for the Ouantlmeter "- ~ ' •SwOO CM 7271 t Chargfrtg Adapter •1 00270 E«ten«lon>*of*<3 meter) 47.00 CH 7274 Battery Pack •9.00 Evtemfon Hot* 110 meter) •100 •9 40015 •1 00230 - Enentfon how 1 1 Mewl 32.00 •727995 ^mention Hoc* (16 meterp 70.00 •940083 Extemion hoe* (3 Nwter) 47.00 CH7274 1 Br*ak4j>ff Hu ( -t ...... PRICE PER ORAEGER THRESHOLD f CASES' AND VAPORS NATIONAL DRAEGER PACK OF REFERENCE MEASURING 1 %pnwbV ^wW vr^ mml *Vl IftC tff\ Bf£ 1 Ifftf^ 10 TUBES NUMBER RANGE 1LLSJL wai-el) ^J^^Atf^k --'-,-- ' ^v*V^**Jwil^ •yWVVwWlpv i -pinyl chloride •• Vinyl chloride O.S/a 25X0 67 28061 025-6 ppm Boom Vinyl chloride I/a 28X0 67 28031 1—50 PPm Sown Vinyl tfiloridt 100/a . 26X0 CH 19601 100*3X00 ppm S ppm a^- ^ _____ falai vafiQf Water vapor 0.1 28X0 CH 23401 1-40 mp/l Water vapor I/a 27X0 81 01081 0.1 -20 mg/I - -— —^— — ———— _ ^nnq^ p-Xylent 10/a 27X0 6733161 10-400 ppm 100 ppm 1/ *"0$M Certified Tuba towM* "SlndicMttogtutxt.*?**** •••*rasoltubet C-TLV/C^ffinfUmit ^ f>fl/Y<«'on Ptognm tor Drfacror fi/ter A» AM» discontinue. * »* *OrtBlnaf(yNIOSHCartrf»adTybe 'HcwTutxs **S indenting tubes. Cpntubes **'«e/mo/li/tef C • TLV/CfMng Utnh The NIOSH Ctftlfktthn frognm for Dettctor tubes hn been discontinued. ^tfeootes tubes present^ ftehff dovvtooed Superior rumben desJgntte totti number of indicating tubes. ,,- .- :T PRICE PER DRAEGER THRESHOLD OASES AND VAPORS NATIONAL ORAEGER PACK OF REFERENCE MEASURINd . UMIT VALUE TO BE MEASURED TUBE TO BE USED 10 TUBES NUMBER RANGE PJLSJL 196S5*t Carbon dioxlda Caiton dioxide 0.01%fe 26.09 CH 30801 0.01-0 J Vol. % 6.000 pfn^J Carbon dlox We 0.1%/a 26X0 CH 23501 0.1-6 Vol. % Carbon dioxide 05 Va 26.00 CH 31401 0.5-10 Vol. % B.OOO PPnt Carbon dtoxtde 1% 26X0 CH 25101 1-20 Vol. * !. 000 nom, Carbon dioxide 1 X/b 26X0 67 28971 1-18 Vol.* ILOOOpprfl Carbon dioxide 5%/A • 32.00 CH 20301 S-€OVol.% 5 .000 pom Carbon dioxide* Simultaneous Tube 37X0 67 18301 200-2,500 ppm CO. 60 ppm Carbon monoxide (CO200/a*CO>2Va) ft-ttVoM.OS* 5 000 oom Carbon disulfide Carbon dituiride S/a 27X0 67283S1 25-120 porn 10 pom Carbon disulfide 0.04 27X0 CH 26001 3-95 oom lOoorn Carbon disulfide 30/a 27X0 CH 23201 32-3.200 oom 10 oom Carbon monoxide Carbon monoxide 2/a 25.00 67 33051 2-300 oom SOoorn^ Carbon monoxide 5/e 27.00 CH 25601 5-700 pom SOoom, Carbon monoxide 8/a 27X0 CH 19701 6-150ppm 50 ppm (onlv for CO to H*) " ~ " Carbon monoxide 10/b 27X0 CH2060? 10-3.000 oom 60 pom Carbon monoxide 0.1%/a 27X0 CH 29601 0.1-1.2 Vol. tt 50 oom Carbon monoxide 0.3%/a 27.00 CH 24901 0.3-4 Vol. % 50 ppm Carbon monoxide 0.5%/a 27X0 CH 29901 OS-7 Vol.* 50 pom Carbon tetrachbride •Carbon tetrachbride I/a 32.00 61 01021 1—15 com Sppm \ Carbon telracNorfde 5te 27.00 CH 27401 5— 50 com Sppm Chlorine Chlorine 0.3/b 27.00 6728411 0.3-5 own IPPHI Chlorine 0.2/a 27.00 CH 24301 0.2—30 opm 1 ppm M Chlorine 50/a 27.00 CH 20701 S0-500pom 1 poni! : mi Chtorobenzen* * "Chlorobenrene S/e - 31.00 67 28761 5-200 com 75 pom Chloroform •'Chloroform 2/a 27X0 67 28861 7-10 oom 10 pom Chforoformatm Chl oroformates 0.2/b • 2S.OO 67 18601 0.2— 10 oom _ if Chloroorent Chloroprene 5/a 27X0 67 18901 6-90 oom lOoom Chromfc acid •"•Chromic acid O.I/a 34.00 67 28681 0.1— O.Sma/m* • ,.-•- Cvanide •••Cvanide 2/a 30X0 o/ 2079 i z^15rnwm* offlvrn* V J Cvanooen chloride Cvanooen chloride 0.25/a 27X0 CH 19801 0.25-5 oom C0.3oom "^IP' y- Cvcfohexane Cvclohexane 10Q/a 27X0 6725201 100-1. 500 oorn 300 oom Cydohexylamlne . Cydohtxyfamfna 2/a • 27X0 6728931. 2-30 ppm . 10 ppm Diborane' Diborane 0.05/a 25X0 67 18101 0.05-3 ppm ' 0.1 oom • Diethvl ether Diethvl ether 100/a 27X0 6730501 100-4 .000 oom 400 com Dimethvl acetamtde Dimethyl acetamide 10/a 36.00 6728011 10-40 oom lOoom Dimethyl form amide Dimethvt formamide 10/b 39X0 67 18501 10-40 oom 10 oom Dimethvt tulfata •Dimethvt tulfate 0.005/c 26.00 67 18701 0.005-0.05 oom 0.1 own Dimethyl sutfida "Dimethyl Aitfide I/a 26X0 6728451 1-15 ppm -. EolcMorohvdrln . Eoichforohvdrln S/b 2*XO 6728111 5- 50 oom 2oom Ethyl acetate Ethvl acetate 200/a 26.00 CH 20201 200-3.000 pom 400 oom L Ethvt alcohol (Ethvratl Alcohol 100/a 28.00 CH 29701 100-3.000 com 1.000 com Ethvt benzene Ethyl benzene 30/e 27X0 6728381 30— 600 own lOOppnf Ethvt olvcol acetate ' Ethvl etvcof acetate 50/a 26.00 6726801 56-700 oom _ Ethylene •*£thv!ene05/a 27X0 6728481 0.5-10 oom ' _ Ethvtene 50/a 27X0 6728051 5Q~2.SOODom . Ethvtene oxide "ithvlene oxide 1/e 29.00 6728961 1—30 ppm loom Ethylem oxide 2Va 29X0 6728241 25-500 ppm 1ppm Formaldehyde Formaldehyde OJ2/e 30X0 6733081 05-5 pom 1pom Formaldehyde 61 01141 to extend measuring Activation Tube 24X0 ranoetoO.04 Ippm Formaldehyde 0.5/a 30.00 6726760 0.5—10 ppm Ippm Formaldehyde OD02 30X0 CH 26401 2-40 ppm Ippm Formic acid Formic acid I/a 27X0 6722701 1-15 ppm ft R J U U ^ Ififrn n-Hexane n-Hexane 100/a 29.00 6728391 100—3.000 ppm BOppmi / Hydrazlne Hvdraztne 0.2/a 28.00 6733121 0.2— 10 oorn 0:1 oom "— ' Hvdrazint 0.2S/a 28.00 CH 31801 0.25— 3 oom 0.1 pprn Originally NIOSH Certified Tube *New Tubes •*$lntfc*tfrigtvbetf8pf9tube* w*rotaltube$ C-TLV/OtttinfUmlt Tb*NIQSHCMif^onftoywfortetmnorwb«hMbM£scontlnumi. Superior number* designttt tool number ofin&crtng tubes.
|_____ I (______t SAT. I \3IBULLIfT (LETHAL(H2S BUBBLED (NATUAS 0001 (ATB) ANIMAL TOXICITY TEXT* . ( fALUEl TIMEJSPECIES - IPARAH. (ROUTE - (REP. * ' W PPM( IHMW ITCLO INH IJWPFA5 0017 -1500! (RAT tLCLO •-/..• • ..-- |JIS/M3! . ( 1 . " ;' '" : U 7121 fll • ILC30 •' . '•.. R46+++ 0001 PPM! HOUR! • f- 634( .•'(MUS • ; • * • j. PPM! ..-.*•!?*..*• --•=;-* • • i* •>'-'' • • 600! 300IHMN LC - ftPD**+ 0001 PPrttMIMUTI •" •—• »-' ---.- 1J . -' . .- - : % •;. . ' - . . • | 1 r^Bt- •••-.-•-• • ' •• 11 - ' . :. m*mmt mm*m mm,±.mmmi^m. m^m*.m * mm.mmt ittyflOHa^fwtsiil?r^INJURED IF EXPOSED^ T O > 5 PPM IN AIR OVER 2:4 •HOUR(R173* * OOOI)ariOnnA R 3 U Un cx j-> **2pm*nt*^m$&T^*i^ ONCE ONLY IF K) OTHER MEASUREABLE EXPOSURE OCCURS (29CFRO 1910) OSHA CEILING 20 PPM (29CFR* 1910). RECOMMENDATIONS— NIOSH CEILING 15 M6XM3X10 MIN 10 PPMxtO MIN (CRSOE* 77-158>77xNIO^H> EVftCUATIOW REQUIRED IF CONCENTRATION IS EQUAL TO OR GREATER THAN 70 M6XM3 (CRSOE* 77-l58*77xNIOSH) NIDSH IDLH 300 PPM (PKTGD*- 80XMAC) ACGIH TLV (TWAV14 MGxN3 10 PPM (TLVADM t (IRT) IRRITATION LEVELS (TEXT) l PPM! J PR I TAT ION BEGINS! SYMPTOMS Of- I EXPOSURE BEGIN (85FHA9 0001)• . % *D*C>"-'DIRECT CONTACT! ^INHALAnON W/^RNIN&-PROPERTIES ARD MULLIFJED BY .v ; •*LiouiD;:!;i:cEAM+-EVENTUAL*DEADEHIWG43+ eoxB«EF )SENSES. LOCAL*' FREEZINCONJUNCTIVITISG TYPE *BURN JCERAHTISS TO $KI*N $KI WITWH . .BURNS* PHDTOPHOBIAr'LTiCRIMATION* CORNEAL VESICULATION. *JNS*'**3£NERAL'SENSATnJN: RESPIRATORY* RHINITIS* PHARYNGITIS* OLFACTORY I FATIGUE* BRONCHITIS* PNEUMONIA* PULMONARY EDEMA* APNEA* COUGH* 1 CYANOSIS* DYSPNEA. SYSTEMIC* ANOREXIA* ATAXIA* DIARRHEA* NAUSEA* VOMITING* HEADACHE* DIZZINESS* FATIGUE* INSOMNIA* , " IRRITABILITY* HYPERREFLEXIA* PARASTHESIAS* WEAKNESS* TREMORS* AND NUMBNESS IN EXTREMITIES*;SHOCK* CONVULSIONS* 1 UNCONSCIOUSNESS. (8SEUA9 0001> (PKTGD+ 0001) (THIDD6 0002> IN HUMANS (INHALATION)! 600 PPM IMMEDIATELY LETHAL* 600 PPM FOR 30 MINUTES LETHAL* £00 PPM SEVERE TOXIC EFFECTS IN ONE MINUTE* 50 PPM SYMPTOMS OCCUR* £0 PPM UNSATISFACTORY. (65FHA9 0001) 300 MG/CU M INHALED* NEAR FATALf 60 PPM FOR 10 MINUTES INHALED* FATAL. £0 TO 150 PPM CAUSES EYE IRRITATION* RESPIRATORY TRACT IRRITATION* AND PULMONARY EDEMA IF EXPOSURE IS PROLONGED. 500 E PPM FOR 30 MINUTES CAUSES HEADACHE* DIZZINESS* STAG6ERIMG* DIARRHEA* DYSURIA* BRONCHITIS* AND BRDNCHOPNEUMQNIA. 600 TO 1000 PPM IS FATAL IN 30 MINUTES. H3S IS BOTH AN IRRITANT AND AN ASPHYXIANT. IN SMALL AMOUNTS IT REPRESSES THE NERVOUS SYSTEM! IN LARGER AMOUNTS IT STIMULATES! AND IN VERY HIGH AMOUNTS IT PARALYSES THE RESPIRATORY CENTER. REPEATED EXPOSURE TO LOW , LEVELS CAUSES CONJUNCTIVITIS* PHOTOPHOBIA* LACRIMATION* PAIN* L AND SLURPED VISION. CHRONIC'POISONING CAUSES HEADACHE* INFLAMMATION OF CDNJUNCTIVAE AND EYELIDS* DIGESTIVE DISTURBANCES* WEIGHT LOSS* AND GENERAL DEBILITY. (DPMADX 0001) •'ODOR THRESHOLDKxiXIIriER^P^tt^jrO.OOe TO 0.35 ODOR THRESHOLD* LOWER (REFERENCE)* (H2SHE+ 0001) TfiSTE THRESHOLD* LOWER (PPM> * . 001 ,^TR) TASTE THRESHOLD* LOWER (REFERENCE)* (85FHA9 0001) (SAF) PERSONAL SAFETY PRECAUTIONS! SELF-CONTAINED BREATHING APPARATUS (INCLUDING FULL EYE PROTECTION) AND FULL BODY SUIT VITH A MATERIAL OF RUBBER* NEDPRENE*^OR PLASTICIZED PVC. ALSO GLOVES "