Linear Trigonal Planar Tetrahedral Trigonal Bipyramid Octahedral Bent

Total Page:16

File Type:pdf, Size:1020Kb

Linear Trigonal Planar Tetrahedral Trigonal Bipyramid Octahedral Bent There are only FIVE possible electronic geometries which you establish by counting the number of electron regions surrounding the central atom electron electron electron electron electron 2regions 3regions 4regions 5regions 6regions AX2 AX3 AX4 AX5 AX6 3 sp sp2 sp sp3d sp3d2 linear trigonal planar tetrahedral trigonal bipyramid octahedral note that AX E AX4E the lone 5 AX E .. .. pairs all AX2E .. 3 go in the equatorial position occupied positions .. 1 by a lone pair bent trigonal pyramid see-saw square pyramid Molecular Geometries AX E can be any of the shapes on .. 4 2 AX2E2 .. .. .. the whole page. The .. AX E electronic geometries are only positions occupied 3 2 .. those in the box (and orbital 2 by a lone pair hybridizations). The molecular bent T-shaped square planar geometry will be different from the electronic when there is at least one or more lone pairs AX3E3 on the central atom. Look at the top of the table and go .. DOWN a column. As you change from bonding electrons .. AX E .. positions occupied .. 2 3 .. to lone pair electrons, the molecular shape is now different by a lone pair from the electronic because some of the positions are missing 3 .. atoms. The new shape is then renamed based on the shape of the atoms. linear T-shaped Remember, once you have estabilished the correct electronic geometry, the molecular .... AX2E4 geometry MUST be either the same as the electronic or one of the shapes listed directly positions occupied .. under the electronic geometry. In other words, each shape in a given column here has the 4 by a lone pair .. same electronic geometry given at the top of the column. linear Polarity If all the positions on the electronic geometry are the same (have the same atoms surrounding the central atom), the molecule is NOT polar because of the symmetry. Any of the other molecular geometries (except square planar and linear) under the box will be polar. McCord 10/2005.
Recommended publications
  • Build a Tetrahedral Kite
    Aeronautics Research Mission Directorate Build a Tetrahedral Kite Suggested Grades: 8-12 Activity Overview Time: 90-120 minutes In this activity, you will build a tetrahedral kite from Materials household supplies. • 24 straws (8 inches or less) - NOTE: The straws need to be Steps straight and the same length. If only flexible straws are available, 1. Cut a length of yarn/string 4 feet long. then cut off the flexible portion. • Two or three large spools of 2. Take six straws and place them on a flat surface. cotton string or yarn (approximately 100 feet total) 3. Use your piece of string to join three straws • Scissors together in a triangular shape. On the side where • Hot glue gun and hot glue sticks the two strings are extending from it, one end • Ruler or dowel rod for kite bridle should be approximately 20 inches long, and the • Four pieces of tissue paper (24 x other should be approximately 4 inches long. 18 inches or larger) See Figure 1. • All-purpose glue stick Figure 1 4. Tie these two ends of the string tightly together. Make sure there is no room for the triangle to wiggle. 5. The three straws should form a tight triangle. 6. Cut another 4-inch piece of string. 7. Take one end of the 4-inch string, and tie that end to a corner of the triangle that does not have the string ends extending from it. Figure 2. 8. Add two more straws onto the longest piece of string. 9. Next, take the string that holds the two additional straws and tie it to the end of one of the 4-inch strings to make another tight triangle.
    [Show full text]
  • THE GEOMETRY of PYRAMIDS One of the More Interesting Solid
    THE GEOMETRY OF PYRAMIDS One of the more interesting solid structures which has fascinated individuals for thousands of years going all the way back to the ancient Egyptians is the pyramid. It is a structure in which one takes a closed curve in the x-y plane and connects straight lines between every point on this curve and a fixed point P above the centroid of the curve. Classical pyramids such as the structures at Giza have square bases and lateral sides close in form to equilateral triangles. When the closed curve becomes a circle one obtains a cone and this cone becomes a cylindrical rod when point P is moved to infinity. It is our purpose here to discuss the properties of all N sided pyramids including their volume and surface area using only elementary calculus and geometry. Our starting point will be the following sketch- The base represents a regular N sided polygon with side length ‘a’ . The angle between neighboring radial lines r (shown in red) connecting the polygon vertices with its centroid is θ=2π/N. From this it follows, by the law of cosines, that the length r=a/sqrt[2(1- cos(θ))] . The area of the iscosolis triangle of sides r-a-r is- a a 2 a 2 1 cos( ) A r 2 T 2 4 4 (1 cos( ) From this we have that the area of the N sided polygon and hence the pyramid base will be- 2 2 1 cos( ) Na A N base 2 4 1 cos( ) N 2 It readily follows from this result that a square base N=4 has area Abase=a and a hexagon 2 base N=6 yields Abase= 3sqrt(3)a /2.
    [Show full text]
  • Math 366 Lecture Notes Section 11.4 – Geometry in Three Dimensions
    Section 11-4 Math 366 Lecture Notes Section 11.4 – Geometry in Three Dimensions Simple Closed Surfaces A simple closed surface has exactly one interior, no holes, and is hollow. A sphere is the set of all points at a given distance from a given point, the center . A sphere is a simple closed surface. A solid is a simple closed surface with all interior points. (see p. 726) A polyhedron is a simple closed surface made up of polygonal regions, or faces . The vertices of the polygonal regions are the vertices of the polyhedron, and the sides of each polygonal region are the edges of the polyhedron. (see p. 726-727) A prism is a polyhedron in which two congruent faces lie in parallel planes and the other faces are bounded by parallelograms. The parallel faces of a prism are the bases of the prism. A prism is usually names after its bases. The faces other than the bases are the lateral faces of a prism. A right prism is one in which the lateral faces are all bounded by rectangles. An oblique prism is one in which some of the lateral faces are not bounded by rectangles. To draw a prism: 1) Draw one of the bases. 2) Draw vertical segments of equal length from each vertex. 3) Connect the bottom endpoints to form the second base. Use dashed segments for edges that cannot be seen. A pyramid is a polyhedron determined by a polygon and a point not in the plane of the polygon. The pyramid consists of the triangular regions determined by the point and each pair of consecutive vertices of the polygon and the polygonal region determined by the polygon.
    [Show full text]
  • VOLUME of POLYHEDRA USING a TETRAHEDRON BREAKUP We
    VOLUME OF POLYHEDRA USING A TETRAHEDRON BREAKUP We have shown in an earlier note that any two dimensional polygon of N sides may be broken up into N-2 triangles T by drawing N-3 lines L connecting every second vertex. Thus the irregular pentagon shown has N=5,T=3, and L=2- With this information, one is at once led to the question-“ How can the volume of any polyhedron in 3D be determined using a set of smaller 3D volume elements”. These smaller 3D eelements are likely to be tetrahedra . This leads one to the conjecture that – A polyhedron with more four faces can have its volume represented by the sum of a certain number of sub-tetrahedra. The volume of any tetrahedron is given by the scalar triple product |V1xV2∙V3|/6, where the three Vs are vector representations of the three edges of the tetrahedron emanating from the same vertex. Here is a picture of one of these tetrahedra- Note that the base area of such a tetrahedron is given by |V1xV2]/2. When this area is multiplied by 1/3 of the height related to the third vector one finds the volume of any tetrahedron given by- x1 y1 z1 (V1xV2 ) V3 Abs Vol = x y z 6 6 2 2 2 x3 y3 z3 , where x,y, and z are the vector components. The next question which arises is how many tetrahedra are required to completely fill a polyhedron? We can arrive at an answer by looking at several different examples. Starting with one of the simplest examples consider the double-tetrahedron shown- It is clear that the entire volume can be generated by two equal volume tetrahedra whose vertexes are placed at [0,0,sqrt(2/3)] and [0,0,-sqrt(2/3)].
    [Show full text]
  • The Mars Pentad Time Pyramids the Quantum Space Time Fractal Harmonic Codex the Pentagonal Pyramid
    The Mars Pentad Time Pyramids The Quantum Space Time Fractal Harmonic Codex The Pentagonal Pyramid Abstract: Early in this author’s labors while attempting to create the original Mars Pentad Time Pyramids document and pyramid drawings, a failure was experienced trying to develop a pentagonal pyramid with some form of tetrahedral geometry. This pentagonal pyramid is now approached again and refined to this tetrahedral criteria, creating tetrahedral angles in the pentagonal pyramid, and pentagonal [54] degree angles in the pentagon base for the pyramid. In the process another fine pentagonal pyramid was developed with pure pentagonal geometries using the value for ancient Egyptian Pyramid Pi = [22 / 7] = [aPi]. Also used is standard modern Pi and modern Phi in one of the two pyramids shown. Introduction: Achieved are two Pentagonal Pyramids: One creates tetrahedral angle [54 .735~] in the Side Angle {not the Side Face Angle}, using a novel height of the value of tetrahedral angle [19 .47122061] / by [5], and then the reverse tetrahedral angle is accomplished with the same tetrahedral [19 .47122061] angle value as the height, but “Harmonic Codexed” to [1 .947122061]! This achievement of using the second height mentioned, proves aspects of the Quantum Space Time Fractal Harmonic Codex. Also used is Height = [2], which replicates the [36] and [54] degree angles in the pentagon base to the Side Angles of the Pentagonal Pyramid. I have come to understand that there is not a “perfect” pentagonal pyramid. No matter what mathematical constants or geometry values used, there will be a slight factor of error inherent in the designs trying to attain tetrahedra.
    [Show full text]
  • Pentagonal Pyramid
    Chapter 9 Surfaces and Solids Copyright © Cengage Learning. All rights reserved. Pyramids, Area, and 9.2 Volume Copyright © Cengage Learning. All rights reserved. Pyramids, Area, and Volume The solids (space figures) shown in Figure 9.14 below are pyramids. In Figure 9.14(a), point A is noncoplanar with square base BCDE. In Figure 9.14(b), F is noncoplanar with its base, GHJ. (a) (b) Figure 9.14 3 Pyramids, Area, and Volume In each space pyramid, the noncoplanar point is joined to each vertex as well as each point of the base. A solid pyramid results when the noncoplanar point is joined both to points on the polygon as well as to points in its interior. Point A is known as the vertex or apex of the square pyramid; likewise, point F is the vertex or apex of the triangular pyramid. The pyramid of Figure 9.14(b) has four triangular faces; for this reason, it is called a tetrahedron. 4 Pyramids, Area, and Volume The pyramid in Figure 9.15 is a pentagonal pyramid. It has vertex K, pentagon LMNPQ for its base, and lateral edges and Although K is called the vertex of the pyramid, there are actually six vertices: K, L, M, N, P, and Q. Figure 9.15 The sides of the base and are base edges. 5 Pyramids, Area, and Volume All lateral faces of a pyramid are triangles; KLM is one of the five lateral faces of the pentagonal pyramid. Including base LMNPQ, this pyramid has a total of six faces. The altitude of the pyramid, of length h, is the line segment from the vertex K perpendicular to the plane of the base.
    [Show full text]
  • Uniform Panoploid Tetracombs
    Uniform Panoploid Tetracombs George Olshevsky TETRACOMB is a four-dimensional tessellation. In any tessellation, the honeycells, which are the n-dimensional polytopes that tessellate the space, Amust by definition adjoin precisely along their facets, that is, their ( n!1)- dimensional elements, so that each facet belongs to exactly two honeycells. In the case of tetracombs, the honeycells are four-dimensional polytopes, or polychora, and their facets are polyhedra. For a tessellation to be uniform, the honeycells must all be uniform polytopes, and the vertices must be transitive on the symmetry group of the tessellation. Loosely speaking, therefore, the vertices must be “surrounded all alike” by the honeycells that meet there. If a tessellation is such that every point of its space not on a boundary between honeycells lies in the interior of exactly one honeycell, then it is panoploid. If one or more points of the space not on a boundary between honeycells lie inside more than one honeycell, the tessellation is polyploid. Tessellations may also be constructed that have “holes,” that is, regions that lie inside none of the honeycells; such tessellations are called holeycombs. It is possible for a polyploid tessellation to also be a holeycomb, but not for a panoploid tessellation, which must fill the entire space exactly once. Polyploid tessellations are also called starcombs or star-tessellations. Holeycombs usually arise when (n!1)-dimensional tessellations are themselves permitted to be honeycells; these take up the otherwise free facets that bound the “holes,” so that all the facets continue to belong to two honeycells. In this essay, as per its title, we are concerned with just the uniform panoploid tetracombs.
    [Show full text]
  • Arxiv:2105.14305V1 [Cs.CG] 29 May 2021
    Efficient Folding Algorithms for Regular Polyhedra ∗ Tonan Kamata1 Akira Kadoguchi2 Takashi Horiyama3 Ryuhei Uehara1 1 School of Information Science, Japan Advanced Institute of Science and Technology (JAIST), Ishikawa, Japan fkamata,[email protected] 2 Intelligent Vision & Image Systems (IVIS), Tokyo, Japan [email protected] 3 Faculty of Information Science and Technology, Hokkaido University, Hokkaido, Japan [email protected] Abstract We investigate the folding problem that asks if a polygon P can be folded to a polyhedron Q for given P and Q. Recently, an efficient algorithm for this problem has been developed when Q is a box. We extend this idea to regular polyhedra, also known as Platonic solids. The basic idea of our algorithms is common, which is called stamping. However, the computational complexities of them are different depending on their geometric properties. We developed four algorithms for the problem as follows. (1) An algorithm for a regular tetrahedron, which can be extended to a tetramonohedron. (2) An algorithm for a regular hexahedron (or a cube), which is much efficient than the previously known one. (3) An algorithm for a general deltahedron, which contains the cases that Q is a regular octahedron or a regular icosahedron. (4) An algorithm for a regular dodecahedron. Combining these algorithms, we can conclude that the folding problem can be solved pseudo-polynomial time when Q is a regular polyhedron and other related solid. Keywords: Computational origami folding problem pseudo-polynomial time algorithm regular poly- hedron (Platonic solids) stamping 1 Introduction In 1525, the German painter Albrecht D¨urerpublished his masterwork on geometry [5], whose title translates as \On Teaching Measurement with a Compass and Straightedge for lines, planes, and whole bodies." In the book, he presented each polyhedron by drawing a net, which is an unfolding of the surface of the polyhedron to a planar layout without overlapping by cutting along its edges.
    [Show full text]
  • Hexagonal Antiprism Tetragonal Bipyramid Dodecahedron
    Call List hexagonal antiprism tetragonal bipyramid dodecahedron hemisphere icosahedron cube triangular bipyramid sphere octahedron cone triangular prism pentagonal bipyramid torus cylinder square­based pyramid octagonal prism cuboid hexagonal prism pentagonal prism tetrahedron cube octahedron square antiprism ellipsoid pentagonal antiprism spheroid Created using www.BingoCardPrinter.com B I N G O hexagonal triangular square­based tetrahedron antiprism cube prism pyramid tetragonal triangular pentagonal octagonal cube bipyramid bipyramid bipyramid prism octahedron Free square dodecahedron sphere Space cuboid antiprism hexagonal hemisphere octahedron torus prism ellipsoid pentagonal pentagonal icosahedron cone cylinder prism antiprism Created using www.BingoCardPrinter.com B I N G O triangular pentagonal triangular hemisphere cube prism antiprism bipyramid pentagonal hexagonal tetragonal torus bipyramid prism bipyramid cone square Free hexagonal octagonal tetrahedron antiprism Space antiprism prism square­based dodecahedron ellipsoid cylinder octahedron pyramid pentagonal icosahedron sphere prism cuboid spheroid Created using www.BingoCardPrinter.com B I N G O cube hexagonal triangular icosahedron octahedron prism torus prism octagonal square dodecahedron hemisphere spheroid prism antiprism Free pentagonal octahedron square­based pyramid Space cube antiprism hexagonal pentagonal triangular cone antiprism cuboid bipyramid bipyramid tetragonal cylinder tetrahedron ellipsoid bipyramid sphere Created using www.BingoCardPrinter.com B I N G O
    [Show full text]
  • Convex Polytopes and Tilings with Few Flag Orbits
    Convex Polytopes and Tilings with Few Flag Orbits by Nicholas Matteo B.A. in Mathematics, Miami University M.A. in Mathematics, Miami University A dissertation submitted to The Faculty of the College of Science of Northeastern University in partial fulfillment of the requirements for the degree of Doctor of Philosophy April 14, 2015 Dissertation directed by Egon Schulte Professor of Mathematics Abstract of Dissertation The amount of symmetry possessed by a convex polytope, or a tiling by convex polytopes, is reflected by the number of orbits of its flags under the action of the Euclidean isometries preserving the polytope. The convex polytopes with only one flag orbit have been classified since the work of Schläfli in the 19th century. In this dissertation, convex polytopes with up to three flag orbits are classified. Two-orbit convex polytopes exist only in two or three dimensions, and the only ones whose combinatorial automorphism group is also two-orbit are the cuboctahedron, the icosidodecahedron, the rhombic dodecahedron, and the rhombic triacontahedron. Two-orbit face-to-face tilings by convex polytopes exist on E1, E2, and E3; the only ones which are also combinatorially two-orbit are the trihexagonal plane tiling, the rhombille plane tiling, the tetrahedral-octahedral honeycomb, and the rhombic dodecahedral honeycomb. Moreover, any combinatorially two-orbit convex polytope or tiling is isomorphic to one on the above list. Three-orbit convex polytopes exist in two through eight dimensions. There are infinitely many in three dimensions, including prisms over regular polygons, truncated Platonic solids, and their dual bipyramids and Kleetopes. There are infinitely many in four dimensions, comprising the rectified regular 4-polytopes, the p; p-duoprisms, the bitruncated 4-simplex, the bitruncated 24-cell, and their duals.
    [Show full text]
  • [ENTRY POLYHEDRA] Authors: Oliver Knill: December 2000 Source: Translated Into This Format from Data Given In
    ENTRY POLYHEDRA [ENTRY POLYHEDRA] Authors: Oliver Knill: December 2000 Source: Translated into this format from data given in http://netlib.bell-labs.com/netlib tetrahedron The [tetrahedron] is a polyhedron with 4 vertices and 4 faces. The dual polyhedron is called tetrahedron. cube The [cube] is a polyhedron with 8 vertices and 6 faces. The dual polyhedron is called octahedron. hexahedron The [hexahedron] is a polyhedron with 8 vertices and 6 faces. The dual polyhedron is called octahedron. octahedron The [octahedron] is a polyhedron with 6 vertices and 8 faces. The dual polyhedron is called cube. dodecahedron The [dodecahedron] is a polyhedron with 20 vertices and 12 faces. The dual polyhedron is called icosahedron. icosahedron The [icosahedron] is a polyhedron with 12 vertices and 20 faces. The dual polyhedron is called dodecahedron. small stellated dodecahedron The [small stellated dodecahedron] is a polyhedron with 12 vertices and 12 faces. The dual polyhedron is called great dodecahedron. great dodecahedron The [great dodecahedron] is a polyhedron with 12 vertices and 12 faces. The dual polyhedron is called small stellated dodecahedron. great stellated dodecahedron The [great stellated dodecahedron] is a polyhedron with 20 vertices and 12 faces. The dual polyhedron is called great icosahedron. great icosahedron The [great icosahedron] is a polyhedron with 12 vertices and 20 faces. The dual polyhedron is called great stellated dodecahedron. truncated tetrahedron The [truncated tetrahedron] is a polyhedron with 12 vertices and 8 faces. The dual polyhedron is called triakis tetrahedron. cuboctahedron The [cuboctahedron] is a polyhedron with 12 vertices and 14 faces. The dual polyhedron is called rhombic dodecahedron.
    [Show full text]
  • Solid Geometry Object Instruction Manual
    Solid Geometry Object Instruction Manual Swivel-Snaps® Solid Geometry Object Instruction Manual Fundamental Shapes Type Definition/Figure 2D Layout Edges all same length; same number edges at every vertex; all faces same Platonic Solids shape and size. Cube 6 12 Tetrahedron 4 6 Octahedron 8 12 Cannot be made with one 74 piece Dodecahedron Swivel-Snaps kit. Icosahedron 20 30 2 | P a g e Copyright Creative Toys LLC, all rights reserved Swivel-Snaps® Solid Geometry Object Instruction Manual Pyramids Triangular sides. Polygon base. Triangle Base For equilateral triangles, See Platonic solids Pyramid this is a tetrahedron. above Equilateral Square Base 3 1 8 Pyramid Pentagonal or 5 5 Base Pyramid (base not included) Archimedean Same as Platonic solids except two different face types. Solids Cuboctahedron 8 6 24 Rhombicub- 8 18 48 octahedron Two kits needed Snub 32 6 60 hexahedron Two kits needed Other Archimedean solids with pentagon faces cannot be made with Others the 74 piece Swivel-Snaps® kit. 3 | P a g e Copyright Creative Toys LLC, all rights reserved Swivel-Snaps® Solid Geometry Object Instruction Manual Convex All faces equilateral triangles; no adjacent faces in same plane. Deltahedra Regular tetrahedron, octahedron, These are also Platonic solids. See above. Deltahedra icosahedron Johnson Five shown below These are not Platonic solids. Deltahedra Triangular 6 9 Bipyramid Pentagonal 10 15 Bipyramid Snub 12 18 Disphenoid Triaugmented Triangular 14 21 Prism Gyroelongated Square 16 24 Bipyramid 4 | P a g e Copyright Creative Toys LLC, all rights reserved Swivel-Snaps® Solid Geometry Object Instruction Manual Composite Shapes Type Definition/Figure 3D Layout All faces equilateral triangles; two or more adjacent faces in the same plane.
    [Show full text]