crystals Article Crystal Chemical Relations in the Shchurovskyite Family: Synthesis and Crystal Structures of K2Cu[Cu3O]2(PO4)4 and K2.35Cu0.825[Cu3O]2(PO4)4 Ilya V. Kornyakov 1,2 and Sergey V. Krivovichev 1,3,* 1 Department of Crystallography, Institute of Earth Sciences, St. Petersburg State University, University Emb. 7/9, 199034 Saint-Petersburg, Russia;
[email protected] 2 Laboratory of Nature-Inspired Technologies and Environmental Safety of the Arctic, Kola Science Centre, Russian Academy of Science, Fesmana 14, 184209 Apatity, Russia 3 Nanomaterials Research Center, Federal Research Center–Kola Science Center, Russian Academy of Sciences, Fersmana Str. 14, 184209 Apatity, Russia * Correspondence:
[email protected] Abstract: Single crystals of two novel shchurovskyite-related compounds, K2Cu[Cu3O]2(PO4)4 (1) and K2.35Cu0.825[Cu3O]2(PO4)4 (2), were synthesized by crystallization from gaseous phase and structurally characterized using single-crystal X-ray diffraction analysis. The crystal structures of both compounds are based upon similar Cu-based layers, formed by rods of the [O2Cu6] dimers of oxocentered (OCu4) tetrahedra. The topologies of the layers show both similarities and differences from the shchurovskyite-type layers. The layers are connected in different fashions via additional Cu atoms located in the interlayer, in contrast to shchurovskyite, where the layers are linked by Ca2+ cations. The structures of the shchurovskyite family are characterized using information-based Citation: Kornyakov, I.V.; structural complexity measures, which demonstrate that the crystal structure of 1 is the simplest one, Krivovichev, S.V. Crystal Chemical whereas that of 2 is the most complex in the family.