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Safety Data Sheet Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 - Europe SAFETY DATA SHEET Folanx Ca29 56259272 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name : Folanx Ca29 Hazardous ingredients : calcium formate 1.2 Relevant identified uses of the substance or mixture and uses advised against Suitable uses : fertiliser 1.3 Details of the supplier of the safety data sheet Supplier : LANXESS Distribution GmbH, Katzbergstr. 1 D-40764 Langenfeld Telephone: +49 2173 2033 0 Fax: +49 2173 2033 108 E-mail: [email protected] 1.4 Emergency telephone : +49 214 30 99300 (Sicherheitszentrale CHEMPARK Leverkusen) number SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification : Eye Dam. 1, H318 Classification according to Directive 1999/45/EC [DPD] Classification : Xi; R41 Human health hazards : Risk of serious damage to eyes. 2.2 Label elements Hazard pictograms : Signal word : Danger calcium formate Hazard statements : H318 - Causes serious eye damage. Additional warning : Not applicable. phrases Precautionary statements Prevention : Wear eye/face protection. Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Storage : Not applicable. Disposal : Not applicable. 2.3 Other hazards Other hazards which do : None known. not result in classification Date of issue : 2013-05-27 Page: 1/12 Folanx Ca29 56259272 / 4 SECTION 3: Composition/information on ingredients Product definition (REACH) : Mixture Classification Product/ingredient Identifiers % 67/548/EEC Regulation (EC) Type name No. 1272/2008 [CLP] calcium formate REACH #: 70 - 80 Xi; R41 Eye Dam. 1, H318 [1] 01-2119486476-24 EC: 208-863-7 CAS: 544-17-2 calcium chloride EC: 233-140-8 14 - 18 Xi; R36 Eye Irrit. 2, H319 [1] CAS: 10043-52-4 Index: 017-013-00-2 citric acid EC: 201-069-1 1 - 15 Xi; R36 Eye Irrit. 2, H319 [1] CAS: 77-92-9 See Section 16 for See Section 16 the full text of the for the full text of R-phrases the H statements declared above. declared above. Occupational exposure limits, if available, are listed in Section 8. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern SECTION 4: First aid measures 4.1 Description of first aid measures Inhalation : Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to- mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion : Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Date of issue : 2013-05-27 Page: 2/12 Folanx Ca29 56259272 / 4 Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms. 4.3 Indication of any immediate medical attention and special treatment needed See Section 11 for more detailed information on health effects and symptoms. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing : In case of fire, use water spray (fog), foam, dry chemical or CO2. media Unsuitable extinguishing : None known. media 5.2 Special hazards arising from the substance or mixture Hazards from the : No specific fire or explosion hazard. substance or mixture Hazardous combustion : Decomposition products may include the following materials: products carbon oxides halogenated compounds metal oxide/oxides,nitrogen oxides (NO, NO₂ etc.) ,sulphur dioxide 5.3 Advice for firefighters Special precautions for : Promptly isolate the scene by removing all persons from the fire-fighters vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self- equipment for fire-fighters contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: Accidental release measures 6.1 Personal precautions, : No action shall be taken involving any personal risk or without protective equipment and suitable training. Keep unnecessary and unprotected personnel emergency procedures from entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective equipment (see Section 8). 6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, precautions waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3 Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor. Date of issue : 2013-05-27 Page: 3/12 Folanx Ca29 56259272 / 4 Large spill : Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4 Reference to other : See Section 1 for emergency contact information. sections See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. SECTION 7: Handling and storage 7.1 Precautions for safe : Put on appropriate personal protective equipment (see Section 8). handling Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Empty containers retain product residue and can be hazardous. 7.2 Conditions for safe : Store in accordance with local regulations. Store in original storage, including any container protected from direct sunlight in a dry, cool and well- incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 7.3 Specific end use(s) Recommendations : Not available. Industrial sector specific : Not available. solutions Remarks : Protect from moisture. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Exposure limit values : Not available. Date of issue : 2013-05-27 Page: 4/12 Folanx Ca29 56259272 / 4 Derived effect levels Ingredient name Type Exposure Value Population Effects Remarks calcium formate DNEL Long term Oral 23,9 mg/ Consumers Systemic - kg bw/day DNEL Long term 337 mg/m³ Workers Systemic - Inhalation DNEL Short term 337 mg/m³ Workers Systemic - Inhalation DNEL Long term 83,2 mg/ Consumers Systemic - Inhalation m³ DNEL
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