Safety data sheet Issue Date 03-Jul-2020 Revision Date 03-Jul-2020 Version 2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier Product Name Formate tech

Chemical Name CAS No EC No REACH Registration Number Calcium diformate 544-17-2 208-863-7 01-2119486476-24-0000

Pure substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against Industrial Manufacture of substances. Formulations. Distribution and storage. Use as an intermediate, as a processing aid, as pH-regulator, in fillers, in putties, in mortar, in adhesives, in sealants, in glass, in ceramics, Leather tanning, dye, finishing, impregnation and care products and Printing and reproduction of recorded media.

Professional Use in fillers, in putties, in mortar, in fertilizers, in adhesives, in sealants, in laboratories, in washing and cleaning products, public domain and in washing and cleaning products, health services.

Consumer Use in fillers, in putties, in fertilizers, in mortar, in adhesives, in sealants, in glass and in ceramics.

Uses advised against Not identified.

1.3. Details of the supplier of the safety data sheet Manufacturer

Perstorp Chemicals GmbH Postfach 1409/1410 DE- 59704 Arnsberg, Germany Tel. +49 2932 498 0 Fax. +49 2932 498 www.perstorp.com

E-mail address [email protected]

1.4. Emergency telephone number Europe (+)1 760 476 3961 (contract no: 334101)

Asia Pacific (+)1 760 476 3960 (contract no: 334101)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation Category 1 - (H318)

2.2. Label elements Symbols/Pictograms

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Signal word Danger

Hazard statements H318 - Causes serious eye damage

Precautionary Statements P280 - Wear eye protection/ face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor

Contains: Calcium diformate

2.3. Other hazards This substance does not meet the criteria for classification as PBT or vPvB. May be harmful if swallowed.

SECTION 3: Composition/information on ingredients

3.1 Substances Chemical Name EC No CAS No REACH Registration Weight-% Classification according to Number Regulation (EC) No. 1272/2008 [CLP] Calcium diformate 208-863-7 544-17-2 01-2119486476-24-0000 >98 Eye Dam. 1 (H318)

Full text of H- and EUH-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice Immediate medical attention is required. Emergency eyewash facilities must be located in the vicinity of where the product is handled.

Inhalation Remove to fresh air. If irritation persists get medical advice/attention.

Skin contact First aid measures not required, but wash exposed skin with soap and water for hygienic reasons.

Eye contact Immediate medical attention is required. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Use lukewarm water if possible. Keep eye wide open while rinsing. Do not rub affected area.

Ingestion Clean mouth with water and drink plenty of water afterwards. If a large quantity has been ingested or you feel unwell, get medical advice/attention.

Self-protection of the first aider Not required.

4.2. Most important symptoms and effects, both acute and delayed Eye contact: Causes severe irritation with flood of tears and pain and strong redness and swelling of the eye. Risk of permanent eye damage.

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4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media Water with full jet as this can form a dust cloud.

5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating and toxic gases and vapors.

Hazardous combustion products (CO), Carbon dioxide (CO2), Calcium oxide (CaO).

5.3. Advice for firefighters In the event of fire, wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Wear tightly sealed goggles, protective gloves and if dusty conditions dust filter mask (minimum N95). Ensure adequate ventilation.

6.2. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Prevent further leakage or spillage if safe to do so. See Section 12 for additional ecological information.

6.3. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Small spill Vacuum or sweep material and place in a disposal container. Large spill Cover powder spill with plastic sheet or tarp to minimize spreading. Vacuum or sweep material and place in a disposal container.

Methods for cleaning up Clean contaminated surface thoroughly. After cleaning, flush away traces with water.

6.4. Reference to other sections See Section 7,8,13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling Ensure adequate ventilation. Wear tightly sealed goggles and protective gloves (chloroprene rubber, nitrile rubber). Avoid generation of dust.

General Hygiene Considerations Wash hands thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Keep tightly closed in a dry and cool place.

7.3. Specific end use(s) For details, see the separate exposure scenario(s).

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

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Exposure Limits Keep personal exposure levels below Derived No Effect Level (DNEL) and national exposure limit values (if existing).

Derived No Effect Level (DNEL) - Worker Calcium diformate (544-17-2) Type Exposure route DNEL Remarks Acute effects, systemic Inhalation 337 mg/m3 Chronic effects, systemic Inhalation 337 mg/m3 Acute effects, local Dermal 16.7 mg/cm 2 Acute effects, systemic Dermal 4780 mg/kg bw/day Chronic effects, local Dermal 16.7 mg/cm 2 Chronic effects, systemic Dermal 4780 mg/kg bw/day

Derived No Effect Level (DNEL) - Consumer Calcium diformate (544-17-2) Type Exposure route DNEL Remarks Chronic effects, systemic Oral 23.9 mg/kg bw/day Acute effects, local Dermal 8.3 mg/cm 2 Acute effects, systemic Dermal 2390 mg/kg bw/day Chronic effects, local Dermal 8.3 mg/cm 2 Chronic effects, systemic Dermal 2390 mg/kg bw/day Acute effects, systemic Inhalation 83.2 mg/m3 Chronic effects, systemic Inhalation 83.2 mg/m3

Predicted No Effect Concentration (PNEC) Calcium diformate (544-17-2) Environmental compartment Predicted No Effect Concentration Remarks (PNEC) Freshwater 2 mg/l Intermittent 10 mg/l Freshwater sediment 13.4 mg/kg dry weight Marine water 0.2 mg/l Marine sediment 1.34 mg/kg dry weight

8.2. Exposure controls

Appropriate engineering controls Eyewash stations. Ensure adequate ventilation, especially in confined areas.

Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Hand Protection Wear protective gloves. PPE - Glove material: Chloroprene rubber, CR, Nitrile rubber, NBR. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves.

Skin and body protection Body protection must be chosen depending on activity and possible exposure, e.g. apron, chemical resistant boots, chemical-protection suit. Respiratory protection Provide suction extractors if dust is formed or use dust filter mask (minimum N95).

Environmental exposure controls Not relevant since not classified as dangerous for the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Appearance powder crystalline white Odor Odorless

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Odor threshold Not applicable

Property Value Remarks • Method pH Not applicable Melting point / freezing point > 300 °C / 572 °F OECD Test No. 102: Melting Point/ Melting Range Boiling point / boiling range Not applicable; Decomposes Flash point Not applicable Evaporation rate Not applicable Flammability (solid, gas) Not flammable, Regulation (EC) No. 440/2008, Annex, A.10 Explosive limits Upper explosive limits Not applicable Lower explosive limits Not applicable Vapor pressure 0.00000022 kPa @ 20 °C Calculation method MPBWIN

Vapor density Not applicable; Solid powder Relative density 2.0 @ 20°C; ISO 1183-1 Water 172 g/L @ 20 °C OECD Test No. 105: Water Solubility Solubility(ies) No information available Partition coefficient -2.6 log POW (@20°C; OECD 107) Partition Coefficient (n-octanol/water) Autoignition temperature 292 °C / 558 °F Regulation (EC) No. 440/2008, Annex, A.16 Decomposition temperature 408 °C OECD Test No. 103: Boiling Point Kinematic viscosity Not applicable Dynamic viscosity Not applicable Explosive properties Not explosive. Oxidizing properties Not oxidizing. Density 2.0 g/cm 3 20°C (ISO 1183-1) Bulk density 1200 kg/m³ @ 20 °C

9.2. Other information No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter.

10.2. Chemical stability Stable under normal conditions.

10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid None known.

10.5. Incompatible materials None known.

10.6. Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapors.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure Dermal. Inhalation.

Symptoms related to the physical, chemical and toxicological characteristics See Section 4 for more information.

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Numerical measures of toxicity

Acute toxicity May be harmful if swallowed.

Calcium diformate (544-17-2) Method Species Exposure route Effective dose Remarks OECD Test No. 401: Acute Rat Oral 3050 LD50 (lethal dose) Oral Toxicity mg/kg OECD Test No. 402: Acute Rat Dermal >2000 LD0 mg/kg read-across Dermal Toxicity from supporting substance (structural analogue) EPA OTS 798.1150 Rat Inhalation >0.67 LC0 mg/l The maximal attainable dust concentration of 0.67 mg/l produced no signs of toxicity. read-across from supporting substance (structural analogue)

Skin corrosion/irritation Non-irritating to the skin.

Calcium diformate (544-17-2) Method Species Exposure route Results: OECD Test No. 404: Acute Dermal Rabbit Dermal Non-irritant Irritation/Corrosion

Serious eye damage/eye irritation Risk of serious damage to eyes.

Calcium diformate (544-17-2) Method Species Exposure route Results: OECD Test No. 405: Acute Eye Rabbit Eye Irritating to eyes Causes Irritation/Corrosion serious eye damage

Respiratory or skin sensitization No sensitising effects known.

Calcium diformate (544-17-2) Method Species Exposure route Results: OECD Test No. 406: Skin Guinea pig Skin Not a skin sensitizer Sensitization read-across from supporting substance (structural analogue)

Germ cell mutagenicity Not mutagenic.

Calcium diformate (544-17-2) Method Species Results: OECD Test No. 471: Bacterial Reverse in vitro Negative Mutation Test OECD Test No. 476: In vitro Mammalian Cell in vitro Negative read-across from supporting Gene Mutation Test substance (structural analogue) OECD Test No. 473: In vitro Mammalian in vitro Negative read-across from supporting

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Chromosome Aberration Test substance (structural analogue) OECD Test No. 477: Genetic Toxicology: in vivo Negative Sex-Linked Recessive Lethal Test in Drosophila melanogaster

Carcinogenicity Animal studies have not shown any carcinogenic potential.

Calcium diformate (544-17-2) Method Species Exposure route Effective dose Remarks OECD Test No. 453: Rat Oral 2000 NOAEL mg/kg bw/day Combined Chronic Animal studies have Toxicity/Carcinogenicity not shown any Studies carcinogenic potential. read-across from supporting substance (structural analogue)

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Calcium diformate (544-17-2) Method Species Exposure route Effective dose Remarks OECD Test No. 416: Rat Oral 1000 P0; NOAEL, mg/kg Two-Generation bw/day, Effects on Reproduction Toxicity fertility. read-across from supporting substance (structural analogue) OECD Test No. 416: Rat Oral 1000 F1; NOAEL, mg/kg Two-Generation bw/day, Developmental Reproduction Toxicity effects. read-across from supporting substance (structural analogue) OECD Test No. 414: Prenatal Rabbit Oral 1000 NOAEL, mg/kg bw/day, Development Toxicity Study read-across from supporting substance (structural analogue) OECD Test No. 414: Prenatal Rat Oral 945 NOAEL, mg/kg bw/day, Development Toxicity Study read-across from supporting substance (structural analogue)

STOT - single exposure Slightly irritating to the respiratory system. No classification according to GHS criteria.

STOT - repeated exposure

Calcium diformate (544-17-2) Method Species Exposure route Effective dose Remarks OECD Test No. 407: Rat Oral 1000 NOAEL mg/kg bw/day Repeated Dose 28-day Oral Toxicity Study in Rodents OECD Test No. 408: Rat Oral 3000 NOAEL mg/kg bw/day Repeated Dose 90-Day Oral read-across from Toxicity Study in Rodents supporting substance (structural analogue) OECD Test No. 453: Rat Oral 2000 NOAEL, mg/kg bw/day Combined Chronic Toxicity/Carcinogenicity Studies

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Aspiration hazard No hazard from product as supplied.

SECTION 12: Ecological information

12.1. Toxicity Low toxicity to aquatic organisms.

Calcium diformate (544-17-2) Method Species Exposure route Effective dose Exposure time Remarks Draft guideline "Lethal Brachydanio rerio Freshwater >1000 48h LC0 mg/l effects towards zebrafish Brachydanio rerio (LC0, LC50, LC100; 48-96 h) of the German Federal Environmental Agency (UBA) (May 1984) EPA-660/3-75-009 Daphnia magna Freshwater >1000 48h EC50 (effective concentration) mg/l read-across from supporting substance (structural analogue) OECD Test No. 211: Daphnia magna Freshwater >=100 21d NOEC mg/l Daphnia magna Reproduction Test ASTM E-47.01 Pseudokirchneriell Freshwater >1000 72h EC50 (effective a subcapitata concentration) mg/l read-across from supporting substance (structural analogue) OECD Test No. 306: toxicity >/=22.1 29d NOEC mg/l Biodegradability in read-across from Seawater supporting substance (structural analogue)

12.2. Persistence and degradability Readily biodegradable.

Calcium diformate (544-17-2) Method Value Exposure time Results: OECD Test No. 306: 86% 28d Readily biodegradable Biodegradability in Seawater read-across from supporting substance (structural analogue) OECD Test No. 301D: Ready >75% 20d Readily biodegradable Biodegradability: Closed Bottle Test (TG 301 D)

12.3. Bioaccumulative potential No bioaccumulation potential.

Chemical Name Partition coefficient Bioconcentration factor (BCF) Calcium diformate -2.6

12.4. Mobility in soil The product is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Koc which

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Chemical Name Log Koc Calcium diformate 1.49*

12.5. Results of PBT and vPvB assessment This substance does not meet the criteria for classification as PBT or vPvB

12.6. Other adverse effects None known.

Additional information * read-across from supporting substance (structural analogue)

SECTION 13: Disposal considerations

13.1. Waste treatment methods Waste from residues/unused products This material and its container must be disposed of as hazardous waste. Disposal should be in accordance with applicable regional, national and local laws and regulations. Incinerate at a licensed installation.

Contaminated packaging Thoroughly emptied and clean packaging may be recycled.

Waste codes / waste designations according to EWC / AVV Waste from residues/unused products: 16 03 05*.

Other Information Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14: Transport information

ADR Road transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated Subsidiary class - 14.4 Packing Group Not regulated 14.5 Environmental hazard Not applicable 14.6 Special precautions for user None

RID Rail transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated Subsidiary hazard class - 14.4 Packing Group Not regulated 14.5 Environmental hazard Not applicable 14.6 Special precautions for user None

IMDG Sea transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Marine pollutant Not applicable 14.6 Special precautions for user None 14.7 Transport in bulk according No information available to Annex II of MARPOL 73/78 and the IBC Code

IATA Air transport Not regulated 14.1 UN number Not regulated

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14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Environmental hazard Not applicable 14.6 Special precautions for user None

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture International Regulations Not applicable.

European Union

Not applicable.

France

Occupational Illnesses (R-463-3, France) Not applicable

Germany Water hazard class (WGK) slightly hazardous to water (WGK 1)

15.2. Chemical safety assessment A Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3 H318 - Causes serious eye damage

Issue Date 03-Jul-2020

Revision Date 03-Jul-2020

Revision Note SDS sections updated; 8 National occupational exposure limits, 11 Acute Inhalation Toxicity, Reproductive toxicity

This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006, COMMISSION REGULATION (EU) No. 830/2015 of 20 May 2015.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

EGHS - EN

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