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Safety Data Sheet Safety Data Sheet Issue Date 16-Jun-2009 Revision Date: 22-Oct-2013 Version 1 1. IDENTIFICATION Product Identifier Product Name Calcium formate, 98% Other means of identification SDS # NC-019 Synonyms Calcium diformate; Calcoform; Formic acid, calcium salt. Recommended use of the chemical and restrictions on use Recommended Use No information available. Details of the supplier of the safety data sheet Supplier Address Neuchem Inc. 2062 Union Street, Suite 300 San Francisco, CA 94123 USA www.neuchem.com Emergency Telephone Number Company Phone Number Phone: 415-345-9353 Fax: 415-345-9350 Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) Account No. 100534 2. HAZARDS IDENTIFICATION Appearance Clear colorless powder Physical State Powder Odor Slight acetic acid Classification Serious eye damage/eye irritation Category 2 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Warning Hazard Statements Causes serious eye irritation _____________________________________________________________________________________________ Page 1 / 7 Revision Date: 22-Oct-2013 NC-019 - Calcium formate, 98% _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Calcium diformate; Calcoform; Formic acid, calcium salt. Formula C2H2CaO4 Chemical Name CAS No Weight-% Calcium formate 544-17-2 98 4. FIRST-AID MEASURES First Aid Measures General Advice Provide this SDS to medical personnel for treatment. Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin Contact Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Inhalation Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Most important symptoms and effects Symptoms Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes irritation of the mucous membrane and upper respiratory tract. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically and supportively. _____________________________________________________________________________________________ Page 2 / 7 Revision Date: 22-Oct-2013 NC-019 - Calcium formate, 98% _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Product is not flammable or combustible. Hazardous Combustion Products During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Wear protective clothing as described in Section 8 of this safety data sheet. Ensure adequate ventilation. Environmental Precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Avoid creating dust. Clean up spills immediately. Sweep up, then place into a suitable container for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wear eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Store in a tightly closed container. Store in a cool, dry area away from incompatible substances. Incompatible Materials Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines The following information is given as general guidance Appropriate engineering controls Engineering Controls Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. _____________________________________________________________________________________________ Page 3 / 7 Revision Date: 22-Oct-2013 NC-019 - Calcium formate, 98% _____________________________________________________________________________________________ Individual protection measures, such as personal protective equipment Eye/Face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and Body Protection Wear appropriate protective gloves / clothing to prevent skin exposure. Respiratory Protection A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Powder Appearance Clear colorless powder Odor Slight acetic acid Color Clear Odor Threshold Not determined Property Values 5HPDUNV 0HWKRG pH Not determined Melting Point/Freezing Point > 300 °C / 572 °F Boiling Point/Boiling Range Not determined Flash Point Not determined Evaporation Rate Not available Flammability (Solid, Gas) Not determined Upper Flammability Limits Not available Lower Flammability Limit Not available Vapor Pressure Not available Vapor Density Not available Specific Gravity 2.02 Water Solubility Soluble in water Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not applicable Decomposition Temperature Not available Kinematic Viscosity Not available Dynamic Viscosity Not available Explosive Properties Not determined Oxidizing Properties Not determined Molecular Weight 130.11 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Incompatible Materials. _____________________________________________________________________________________________ Page 4 / 7 Revision Date: 22-Oct-2013 NC-019 - Calcium formate, 98% _____________________________________________________________________________________________ Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye irritation. Skin Contact May cause temporary irritation on skin contact. Inhalation May cause irritation to the mucous membranes and upper respiratory tract. Ingestion May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Calcium formate = 2650 mg/kg ( Rat ) - - 544-17-2 Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Germ cell mutagenicity No information available. Carcinogenicity Carcinogenic potential is unknown. Reproductive toxicity No information available. Developmental toxicity No information available. Teratogenicity No information available. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Ecotoxicity An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea microorganisms Calcium formate 1000: 96 h Brachydanio rerio 544-17-2 mg/L LC50 static _____________________________________________________________________________________________ Page 5 / 7 Revision Date: 22-Oct-2013 NC-019 - Calcium formate, 98% _____________________________________________________________________________________________ Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with
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