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Flexible Plasmonic Sensing Substrates and Their Application in Explosive Sensing Justin Bae Washington University in St Louis
Washington University in St. Louis Washington University Open Scholarship Engineering and Applied Science Theses & McKelvey School of Engineering Dissertations Spring 5-17-2017 Flexible Plasmonic Sensing Substrates and their application in Explosive Sensing Justin Bae Washington University in St Louis Srikanth Singamaneni Washington University in Saint Louis Follow this and additional works at: https://openscholarship.wustl.edu/eng_etds Part of the Engineering Commons Recommended Citation Bae, Justin and Singamaneni, Srikanth, "Flexible Plasmonic Sensing Substrates and their application in Explosive Sensing" (2017). Engineering and Applied Science Theses & Dissertations. 231. https://openscholarship.wustl.edu/eng_etds/231 This Thesis is brought to you for free and open access by the McKelvey School of Engineering at Washington University Open Scholarship. It has been accepted for inclusion in Engineering and Applied Science Theses & Dissertations by an authorized administrator of Washington University Open Scholarship. For more information, please contact [email protected]. WASHINGTON UNIVERSITY IN ST. LOUIS School of Engineering and Applied Science Department of Mechanical Engineering and Materials Science Thesis Examination Committee: Srikanth Singamaneni, Chair Guy Genin Jeremiah Morrissey Flexible Plasmonic Sensing Substrates and their application in Explosive Sensing by Sang hyun Justin Bae A thesis presented to the School of Engineering of Washington University in St. Louis in partial fulfillment of the requirements for the -
How to Fortify Beverages with Calcium by Dr
Ingredients How to Fortify Beverages With Calcium by Dr. Gerhard Gerstner Along with current developments of the overall functional foods market, the use of minerals and especially calcium salts is expected to exhibit strong growth rates. In contrary to other functional ingredients, calcium is widely known as being beneficial for human health and there is no need to explain its nutritional ad- vantages to the customer. According to Leatherhead International, future trends include growing consumer concern regarding osteoporosis and bone health, leading to increased sales of calcium salts. The con- observation is seen as being one of tinuous market growth drives mineral the main factors causing osteo- Common calium sources salt suppliers to offer not only one porosis 2 .As a consequence, national for beverage fortification product but rather a range of different authorities all over the world have calcium salts and granulations to be recently reconsidered recommend- Table 1 shows a typical range of able to tune them to industrial cus- ations in order to take remedial calcium fortified beverages which tomers’ applications. This article measures against calcium deficiency have been seen in European and US discusses important nutritional, and accordingly, to reduce the risk of supermarkets recently. Practically technological as well as economical osteoporosis. In this respect, the US every type of beverage such as aspects of calcium in beverages with National Institute of Health (NIH) has mineral water, soy milk, energy drink, a focus on our company’s products increased the amounts of optimal nectar or juice does have a fortified Tricalcium Citrate, Calcium Gluconate daily calcium intake and defined product line already. -
UNITED STATES PATENT OFFICE 2,629,746 PROCESS of PRODUCING PENTAERYTHRTOL Richard F
Patented Feb. 24, 1953 r - 2,629,746 UNITED STATES PATENT OFFICE 2,629,746 PROCESS OF PRODUCING PENTAERYTHRTOL Richard F. B. Cox, Wilmington, Del, assignor to Hercules Powder Company, Wilmington, Del, a corporation of Delaware No Drawing. Application June 12, 1948, Serial No. 32,737 i Caim. (C. 260-635) 2 ihis application is a continuation-in-part of The process to which this invention relates my copending application Serial Number 459,709, may broadly be described as involving condensa filed September 25, 1942, and now abandoned. tion of acetaldehyde with formaldehyde in an This invention relates to an improved process aqueous medium in the presence of an alkaline for the preparation of pentaerythritol. More catalyst to form a reaction mixture comprising particularly, it is concerned with an improved pentaerythritol and the formate of the catalyst process for recovering pentaerythritol from a cation, Converting said reaction mixture to an Crude reaction mixture obtained by the alkaline aqueous Solution comprising pentaerythritol and Condensation of acetaldehyde and formaldehyde. free formic acid by addition of a substance yield Pentaerythritol is prepared commercially by O ing hydrogen ions in an amount at least chemi condensation of acetaldehyde with formaldehyde cally equivalent to the formate present, extract in an aqueous medium in the presence of an ing formic acid from Said solution with a formic alkaline catalyst such as Ca (CH)2, NaOH, etc. acid solvent substantially water-immiscible and in the resulting reaction mixture there is pres nonsolvent for the pentaerythritol, applying heat ent in addition to the pentaerythritol a metal 15 to evaporate said extracted solution at least to Salt of formic acid, the particular salt depend a point at which Crystallization takes place, and ing upon the catalyst enployed. -
Factors Affecting Precipitation of Calcium Lactate from Fermentation Broths and from Aqueous Solution
https://doi.org/10.3311/PPch.14043 Creative Commons Attribution b |533 Periodica Polytechnica Chemical Engineering, 63(4), pp. 533–540, 2019 Factors Affecting Precipitation of Calcium Lactate from Fermentation Broths and from Aqueous Solution Aladár Vidra1, Áron Németh1*, András Salgó1 1 Department of Applied Biotechnology and Food Science, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, H-1111 Budapest, Budafoki út 6-8, Hungary * Corresponding author, e-mail: [email protected] Received: 19 March 2019, Accepted: 22 May 2019, Published online: 28 June 2019 Abstract Lactic acid is one of the most important organic acids which is being extensively used around the globe in a range of industrial and biotechnological applications. Lactic acid can be produced either by fermentation or by chemical synthesis but the biotechnological fermentation process has several advantages compared to the other one. However fermentation broth contains a number of impurities which must be removed from the broth in order to achieve more pure lactic acid. Efficiency of recovery is crucial to the economy of the whole process as well since the costs of separation and recovery are responsible for more than half of the entire cost of production. In the traditional procedure, the heated and filtered fermentation broth is concentrated to allow crystallization or precipitation of calcium lactate, followed by addition of sulphuric acid to remove the calcium in form of calcium sulphate. The disadvantage of this procedure is the relatively high solubility of calcium lactate which causes product loss in the crystallization step. Therefore we investigated the effects of four operating parameters of the crystallization/precipitation process from two different fermentation broths and from an aqueous solution. -
No. 747 for Calcium Lactate in Potato and Vegetable Snacks and Sweetened Crackers
GRAS Notice (GRN) No. 747 https://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/NoticeInventory/default.htm Exponent 11 50 Connecticut Ave., NW EXponenr Suite 11 00 Washington, DC 20036 telephone 202-772-4900 facsim ile 202-772-4979 www.exponent.com November 14, 2017 Office ofFood Additive Safety (HFS-200) Center for Food Safety and Applied Nutrition Food and Drug Administration 500 l Campus Drive College Park, MD 20740 Subject: GRAS Notification for the Use of Calcium Lactate in Potato and Vegetable Snacks and Sweetened Crackers Project No. 1607280.000 Dear Sir/Madam: In accordance with 2 1 CFR part 170, subpart E, PepsiCo, hereby provides a notice of a claim that the food ingredient described in the enclosed notification document is excluded from the premarket approval requirement ofthe Federal Food, Drug, and Cosmetic Act because the notifier has concluded such use to be generally recognized as safe (GRAS), based on scientific procedures. One paper copy of the notification is provided as required; we also have provided a copy ofthe notification on the enclosed CD-ROM. Ifyou have any questions or require additional information, please do not hesitate to contact me at 202-772-4915, or [email protected]. Sincerely, (b) (6) Nga Tran, DrPH, MPH Principal Scientist ~~©~U~~~ 1607280.000- 04 16 NOV 16 20'7 000001 OFFICE OF FOOD A001TlVE SAFEi'Y ( GRAS Conclusion for the Use of Calcium Lactate in Potato and Vegetable Snacks and Sweetened Crackers SUBMITTED BY: PepsiCo, Inc 700 Anderson Hill Road Purchase, NY 10577 SUBMITTED TO: U.S. Food and Drug Administration Center for Food Safety and Applied Nutrition Office of Food Additive Safety HFS-200 5100 Paint Branch Parkway College Park, MD 20740-3835 CONTACT FOR TECHNICAL OR OTHER INFORMATION: Nga Tran Principal Scientist Exponent, Inc. -
GHS Calcium Lactate Gluconate MSDS.Pdf
Safety Data Sheet (Calcium Lactate Gluconate) DATE PREPARED: 7/9/2015 Section 1. Product and Company Identification Product Name Calcium Lactate Gluconate CAS Number 11116-97-5 Parchem - fine & specialty chemicals EMERGENCY RESPONSE NUMBER 415 Huguenot Street CHEMTEL New Rochelle, NY 10801 Toll Free US & Canada: 1 (800) 255-3924 (914) 654-6800 (914) 654-6899 All other Origins: 1 (813) 248-0585 parchem.com [email protected] Collect Calls Accepted Section 2. Hazards Identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC as amended: This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Classification according to Regulation (EC) No 1272/2008 as amended: This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended. Hazard and precautionary statements Hazard statements: The substance does not meet the criteria for classification. Precautionary statements: Not available. Appearance & Odor: White powder with no odor. Fire & Explosion Hazards Potential for dust explosion may exist. This product is not defined as flammable or combustible. However, the product may decompose under fire conditions to produce toxic oxides of carbon. Depending upon conditions, dusts may be sensitive to static discharge. Avoid possibility of dry powder and friction causing static electricity in presence of flammables (See NFPA-77, Chpt. 6) Primary Route of Exposure: Skin and eye contact are the primary routes of exposure to this product. Inhalation Acute Exposure: Inhalation of dust may cause mild irritation. Skin Contact - Acute: Skin contact is not expected to cause irritation. -
Fine Biocompatible Powders Synthesized from Calcium Lactate and Ammonium Sulfate
ceramics Article Fine Biocompatible Powders Synthesized from Calcium Lactate and Ammonium Sulfate Maksim Kaimonov 1,* , Tatiana Shatalova 1,2 , Yaroslav Filippov 1,3 and Tatiana Safronova 1,2 1 Department of Materials Science, Lomonosov Moscow State University, Building, 73, Leninskie Gory, 1, 119991 Moscow, Russia; [email protected] (T.S.); fi[email protected] (Y.F.); [email protected] (T.S.) 2 Department of Chemistry, Lomonosov Moscow State University, Building, 3, Leninskie Gory, 1, 119991 Moscow, Russia 3 Research Institute of Mechanics, Lomonosov Moscow State University, Michurinsky pr., 1, 119192 Moscow, Russia * Correspondence: [email protected]; Tel.: +7-952-889-11-43 Abstract: Fine biocompatible powders with different phase compositions were obtained from a 0.5 M solution of ammonium sulfate (NH4)2SO4 and calcium lactate Ca(C3H5O3)2. The powder ◦ after synthesis and drying at 40 C included calcium sulfate dehydrate CaSO4·2H2O and calcite ◦ CaCO3. The powder after heat treatment at 350 C included β-hemihydrate calcium sulfate β- CaSO4·0.5H2O, γ-anhydrite calcium sulfate γ-CaSO4 and calcite CaCO3. The phase composition of ◦ powder heat-treated at 600 C was presented as β-anhydrate calcium sulfate β-CaSO4 and calcite ◦ CaCO3. Increasing the temperature up to 800 C leads to the sintering of a calcium sulfate powder β β consisting of -anhydrite calcium sulfate -CaSO4 main phase and a tiny amount of calcium oxide CaO. The obtained fine biocompatible powders of calcium sulfate both after synthesis and after heat Citation: Kaimonov, M.; Shatalova, treatment at temperature not above 600 ◦C can be recommended as a filler for producing unique T.; Filippov, Y.; Safronova, T. -
Comparison of Zinc Acetate and Propionate Addition on Gastrointestinal Tract Fermentation and Susceptibility of Laying Hens to S
ENVIRONMENT, HEALTH, AND BEHAVIOR Comparison of Zinc Acetate and Propionate Addition on Gastrointestinal Tract Fermentation and Susceptibility of Laying Hens to Salmonella enteritidis During Forced Molt R. W. Moore,*,†,1 S. Y. Park,†,2 L. F. Kubena,* J. A. Byrd,* J. L. McReynolds,* M. R. Burnham,*,3 M. E. Hume,* S. G. Birkhold,† D. J. Nisbet,* and S. C. Ricke†,4 *USDA-ARS, Southern Plains Agricultural Research Center, Food and Feed Safety Research Unit, College Station, Texas 77845; and †Department of Poultry Science, Texas A&M University, College Station, Texas 77843 ABSTRACT Feed deprivation is the most common Body weight losses were significantly higher in the M, method used to induce molting and stimulate multiple ZPR, and ZAC treatments than in the NM treatment. egg-laying cycles in laying hens for commercial egg pro- Crop lactic acid decreased more in M, ZPR, and ZAC duction. Unfortunately, an increased risk of Salmonella treatments than in NM hens in trial 2. Crop pH was < enteritidis (SE) colonization may result from the use of significantly (P 0.05) lower in NM hens than in M, ZAC, this method. Methods to stimulate multiple egg-laying and ZPR hens in trial 2. Although cecal individual or total volatile fatty acids (VFA), and lactic acid were not cycles without increasing the risk of SE are needed. In > each of 3 experiments, hens over 50 wk of age were di- significantly (P 0.05) different between NM hens and M, ZAC and ZPR hens in trial 1, lactic acid was signifi- vided into groups of 12 and placed in individual laying cantly (P < 0.05) higher in NM hens than in M, ZAC and cages. -
Zinc Acetate MSDS # 793.00
Material Safety Data Sheet Page 1 of 2 Zinc Acetate MSDS # 793.00 Section 1: Product and Company Identification Zinc Acetate Synonyms/General Names: Acetate Salt of Zinc; zinc acetate dihydrate Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. 24 Hour Emergency Information Telephone Numbers CHEMTREC (USA): 800-424-9300 CANUTEC (Canada): 613-424-6666 ScholAR Chemistry; 5100 W. Henrietta Rd, Rochester, NY 14586; (866) 260-0501; www.Scholarchemistry.com Section 2: Hazards Identification White crystalline granules; slight acetic acid odor. HMIS (0 to 4) Health 2 WARNING! Severe body tissue irritant and moderately toxic by ingestion. Fire Hazard 0 Target organs: None known. Reactivity 0 This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 3: Composition / Information on Ingredients Zinc Acetate (5970-45-6), 100% Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing. Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. Section 5: Fire Fighting Measures When heated to decomposition, emits acrid fumes. 0 Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire. 1 0 Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). -
Protective Effects of Zinc-L-Carnosine /Vitamin E on Aspirin- Induced Gastroduodenal Injury in Dogs
PROTECTIVE EFFECTS OF ZINC-L-CARNOSINE /VITAMIN E ON ASPIRIN- INDUCED GASTRODUODENAL INJURY IN DOGS MASTER’S THESIS Presented in Partial Fulfillment of the Requirements for the Master of Science Degree in the Graduate School of the Ohio State University By Mieke Baan, DVM, MVR ***** The Ohio State University 2009 Master’s Examination Committee: Professor Robert G. Sherding, Adviser Professor Stephen P. DiBartola Associate Professore Susan E. Johnson Approved by Adviser Veterinary Clinical Sciences Graduate Program ! Copyright by Mieke Baan 2009 ABSTRACT Zinc plays a role in many biochemical functions, including DNA, RNA, and protein synthesis. The dipeptide carnosine forms a stable complex with zinc, which has a protective effect against gastric epithelial injury in-vitro and in-vivo. This randomized double-blinded placebo-controlled study investigated the protective effects of zinc-L-carnosine in combination with alpha-tocopheryl acetate (vitamin E) on the development of aspirin-induced gastrointestinal (GI) lesions in dogs. Eighteen mixed-breed dogs (mean 20.6 kg) were negative for parasites, and had normal blood work evaluations, and gastroduodenoscopic exams. On days 0 – 35, dogs were treated with 1 tablet (n=6) or 2 tablets (n=6) of 30 mg zinc-L-carnosine/ 30 IU vitamin E q12h PO, or a placebo (n=6). On days 7 – 35, all dogs were given 25 mg/kg buffered aspirin q8h PO. Endoscopy was performed on Days -1, 14, 21, and 35, and GI lesions (hemorrhages, erosions, or ulcers) were scored using a 12-point grading scale. Repeated measures ANOVA was used for statistical evaluation. The significance level was set at p ! 0.05. -
Preferred Drug List 4-Tier
Preferred Drug List 4-Tier 21NVHPN13628 Four-Tier Base Drug Benefit Guide Introduction As a member of a health plan that includes outpatient prescription drug coverage, you have access to a wide range of effective and affordable medications. The health plan utilizes a Preferred Drug List (PDL) (also known as a drug formulary) as a tool to guide providers to prescribe clinically sound yet cost-effective drugs. This list was established to give you access to the prescription drugs you need at a reasonable cost. Your out- of-pocket prescription cost is lower when you use preferred medications. Please refer to your Prescription Drug Benefit Rider or Evidence of Coverage for specific pharmacy benefit information. The PDL is a list of FDA-approved generic and brand name medications recommended for use by your health plan. The list is developed and maintained by a Pharmacy and Therapeutics (P&T) Committee comprised of actively practicing primary care and specialty physicians, pharmacists and other healthcare professionals. Patient needs, scientific data, drug effectiveness, availability of drug alternatives currently on the PDL and cost are all considerations in selecting "preferred" medications. Due to the number of drugs on the market and the continuous introduction of new drugs, the PDL is a dynamic and routinely updated document screened regularly to ensure that it remains a clinically sound tool for our providers. Reading the Drug Benefit Guide Benefits for Covered Drugs obtained at a Designated Plan Pharmacy are payable according to the applicable benefit tiers described below, subject to your obtaining any required Prior Authorization or meeting any applicable Step Therapy requirement. -
GALZIN CAPSULES Generic Name: Zinc Acetate
CENTER FOR DRUG EVALUATION AND RESEARCH Approval Package for: Application Number : 020458 Trade Name : GALZIN CAPSULES Generic Name: Zinc Acetate Capsules Sponsor : Lemon Company Approval Date: January 28, 1997 NDA 20-458 Lemmon Company JAN 28 IW? Attention: Deborah Jaskot 650 CathillRoad ScIIersville, PA 18960 Dear Ms. Jaskot: Please refer to your Jue 21, 1994 new dmg application submitied under section 505(b) of the Federal FOOL Drug, ad Cosmetic Act for Galzk (Zinc Acetate) Capsules, 25 and 50 mg. We acknowledge receipt of your amendments dated September 6 and October 31, 1995, January 3 and 29, March 27, April 8, August 7, September 13 and 24, october 8 and 14, 1996. - This new drug apphcation provides for Galzin at a dose of 25-50 mg three times daily as maintenance treatment for patients with Wilson’s disease initially treated with a chelating agent. We have completed the review of this application and have concluded that adequate information has been presented t.odemonstrate that the drug is safe and effective for use as recommended in the fwl printed labeling submitted cm October 8, 1996. Accordingly, the application is approved effective on the date of this letter. We remind you of your Phase 4 commitments specified in your submission dated August 29, 1995 and confirmed in our letter of January 27, 1997. These commitments, along with any completion dates agreed upon, are listed below. protocols, dab, and final repoflsshould be submitted to your IND for this product and a COPY of the cover l~er sent to this NDA. Should an IND not be required to meet your Phase 4 co[~tments, please submit pr~ioco], data, and final reports to this NDA as correspondences.