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Marion Heidi Emmert Marion H. Emmert - Curriculum Vitae 1 Marion Heidi Emmert Worcester Polytechnic Institute Department of Chemistry and Biochemistry 100 Institute Road Worcester, MA 01609-2280 Phone: (508) 831 4115 Fax: (508) 831 4116 [email protected] Research Experience Worcester Polytechnic Institute Associate Professor of Chemistry and Biochemistry, Mar 2017 - current Chemical Engineering, Mechanical Engineering, and Environmental Studies Assistant Professor of Environmental Studies Jan 2017 - Feb 2017 Assistant Professor of Chemical Engineering Mar 2014 - Feb 2017 Assistant Professor of Mechanical Engineering Jan 2013- Feb 2017 Assistant Professor of Chemistry and Biochemistry Aug 2011 - Feb 2017 University of Michigan, Ann Arbor May 2009 - Aug 2011 Advisor: Professor Melanie S. Sanford . Demonstrated reactivity of Pd(OAc)2/pyridine catalyst systems for a variety of C-H functionalization reactions: Acetoxylation, arylether formation, Fujiwara-Moritani reaction . Elucidated ligand and oxidant effects on selectivity of non-directed C-H acetoxylation and arene and alkyl H/D exchange reactions with Pd and Pt catalysts Westfälische Wilhelms-Universität Münster Oct 2005 - Apr 2009 Advisor: Professor Gerhard Erker . Developed synthetic methodology for the preparation of Cp-substituted Cp3ZrX compounds. Demonstrated novel reactivity in the ligand sphere of Cp3ZrX complexes: Hydroboration, cyclometallation, aminoborane elimination, functional group (alkene, amine)-Cp3Zr+ interactions Albert-Ludwigs-Universität Freiburg Advisor: Professor Bernhard Breit Aug 2003 - May 2004 . Investigated directed Pd-catalyzed allylic substitution. Advisor: Professor Reinhard Brückner Summer 2001 . Synthesized building blocks for butenolide natural products. Education Dr. rer nat. (Ph.D.) Chemistry March 2009 Westfälische Wilhelms-Universität Münster, Germany Thesis: Synthesis and Reactivity of Substituted Cp3ZrR Systems Diploma (Masters Degree equivalent) Chemistry June 2004 Certificate Grade: sehr gut (outstanding) Albert-Ludwigs-Universität Freiburg, Germany Thesis: Investigation of Directed Pd-catalyzed Allylic Substitution Reactions Marion H. Emmert - Curriculum Vitae 2 Honors and Awards ACS Young Investigator (ORGN) 2016 Diversity Faculty Fellow, NSF Center for Selective C-H 2016 Functionalization Gordon Research Conference Travel Award 2015, 2016, 2017 NIH (NIGMS) Grant Workshop Travel Award 2013 ACS PRF Doctoral New Investigator Award 2012 DFG (German Research Council) Postdoctoral Fellowship 2010 - 2011 CENTC Summer School Travel Award "Emerging 2010 Perspectives in Catalysis" Undergraduate Fellowship of the Bavarian Program for the 1999 - 2004 Promotion of Young Talent in Higher Education Book Prize of the Fonds der Chemischen Industrie (Fund 1999 of the German Chemical Industry) Independent Research Publications (20) Dong, J.; Wang, A.; Deskins, N. A.; Grimm, R. L.; MacDonald, J. C.; Emmert, M. H., Mechanistic Studies of C-N Bond Formation in the Reaction between PdII-Aryl Complexes and Hydroxylamine Reagents. 2018, in preparation. (19) Legacy, C. J.; Emmert, M. H., Mechanistic Insights into Fe Catalyzed α-C-H Oxidations of Tertiary Amines: Non-Radical Pathways For Base-Metal Catalyst. 2018, submitted. (18) Narayanan, R. P. N.; Kazantzis, N. K.; Emmert, M. H., Scandium Recovery from Bauxite Residue (Red Mud): Cost Analysis as a Tool for Process Development. 2018, in revision. (17) Tyufekchiev, M.; Duan, P.; Schmidt-Rohr, K.; Granados Focil, S.; Timko, M. T.; Emmert, M. H., Cellulase-Inspired Solid Acids for Cellulose Hydrolysis: Structural Explanations for High Catalytic Activity. ACS Catalysis 2018, 8, 1464-1468. (16) Narayanan, R. P.; Kazantzis, N. K.; Emmert, M. H., Selective Process Steps for the Recovery of Scandium from Jamaican Bauxite Residue (Red Mud). ACS Sustainable Chemistry & Engineering 2018, 6, 1478 (15) Wang, A.; Venditto, N. J.; Darcy, J. W.; Emmert, M. H., Non-Directed, Cu Catalyzed sp3 C-H Aminations with Hydroxylamine-Based Amination Reagents: Catalytic and Mechanistic Studies. Organometallics 2017, 36, 1259-1268. (14) Horsley, C.; Emmert, M. H.; Sakulich, A., Influence of alternative fuels on trace element content of ordinary portland cement. Fuel 2016, 184, 481-489. (13) Legacy, C. J.; Emmert, M. H., Cα-H Oxidations of Amines to Amides: Expanding Mechanistic Understanding and Amine Scope through Catalyst Development. Synlett 2016, 27, 1893-1897 (Invited Contribution as Synpacts article). Marion H. Emmert - Curriculum Vitae 3 (12) Zhang, X.; Desrochers, S. J.; Carl, A. D.; Geagea, N.; Zielinski, K.; Emmert, M. H., Low Temperature Dehydrations of Non-Activated Alcohols via Halide Catalysis. Org. Chem. Frontiers 2016, 3, 701-708. (11) Bandara, H. M. D.; Jin, D.; Mantell, M. A.; Field, K. D.; Wang, A.; Narayanan, R. P.; Deskins, N. A.; Emmert, M. H., Non-Directed Aromatic C-H Aminations: Catalytic and Mechanistic Studies Enabled by Pd Catalyst and Reagent Design. Catal. Sci. Techn. 2016, 6, 5304-5310. (10) Kerr, M. E.; Ahmend, I.; Gunay, A.; Venditto, N. J.; Zhu, F.; Ison, E. A.; Emmert, M. H., Non-Directed, Carbonate-Mediated C-H Activation and Aerobic C-H Oxygenation with Cp*Ir Catalysts. Dalton Trans. 2016, 45, 9942-9947. (9) Bandara, H. M. D.; Field, K. D.; Emmert, M. H., Rare Earth Recovery from End-of- Life Motors employing Green Chemistry Design Principles. Green Chem. 2016, 18, 753-759. Highlighted by BBC World News/Horizons (May 2016) http://www.bbc.com/specialfeatures/horizonsbusiness/seriessix/circular- economy/?vid=p03w0tp4&video_diary=true http://www.bbc.com/specialfeatures/horizonsbusiness/seriessix/circular- economy/?vid=p03vs4k9 (8) Legacy, C. J.; Wang, A.; O’Day, B. J.; Emmert, M. H., Iron Catalyzed Cα-H Oxidation of Tertiary, Aliphatic Amines to Amides under Mild Conditions. Angew. Chem. Int. Ed. 2015, 49, 14907-14910. (7) Bandara, H. M. D; Mantell, M.; Darcy, J. W.; Emmert, M. H., Rare Earth Recycling: Forecast of Recoverable Nd from Shredder Scrap and Influence of Recycling Rates on Price Volatility. J. Sust. Met. 2015, 1, 179-188. (6) Bandara, H. M. D.; Mantell, M. A.; Darcy, J. W.; Emmert, M. H., Closing the Lifecycle of NdFeB Magnets: Discovery of Neodymium in Slag from Steel Mills. Energy Techn. 2015, 3, 118-120. Highlighted in C&En News http://cen.acs.org/articles/93/i6/Recovering-Neodymium- Steel-Mill-Slag.html (5) Gunay, A.; Mantell, M. A.; Field, K. D.; Wu, W.; Chin, M.; Emmert, M. H., Oxidation Catalysis in Air with Cp*Ir: Influence of Added Ligands and Reaction Conditions on Catalytic Activity and Stability. Catal. Sci. Techn. 2015, 5, 1198-1205. (4) Bandara, H. M. D.; Darcy, J. W.; Apelian, D.; Emmert, M. H., Value Analysis of the Neodymium Content in Shredder Feed: Evaluating the Feasibility of Rare Earth Magnet Recycling. Environ. Sci. Techn. 2014, 48, 6553-6560. (3) Darcy, J. W.; Bandara, H. M. D.; Mishra, B.; Blanplain, B.; Apelian, D.; Emmert, M. H., Challenges in Recycling End-of-Life Rare Earth Magnets. JOM 2013, 65, 1381- 1382. (2) Bandara, H. M. D.; Sosin, M. H.; McKeogh, B. J.; Emmert, M. H., Non-directed, Pd- catalyzed C-H amination of simple arenes. GSTF J. Chem. 2013, 1, 18-31. (1) John, L. C.; Gunay, A.; Wood, A. J.; Emmert, M. H., Catalysts for convenient aerobic alcohol oxidations in air: systematic ligand studies in Pd/pyridine systems. Tetrahedron 2013, 69, 5758-5764. Marion H. Emmert - Curriculum Vitae 4 Book Chapters (3) Field, K. F.; Narayanan, R. P.; Emmert, M. H. “Designing a Process fo RE Recycling from Motors through Green Chemistry” in Critical Rare Earth Elements in Secondary Resources, Abilash, D., Akcil, A. (ed.s), CRC Press, 2018, in print. (2) Emmert, M. H. “Introduction,” in C-H Bond Activation In Organic Synthesis, Li, J. J. (ed.), Taylor & Francis, 2015, pp. 1-20. (1) Emmert, M. H.; Legacy, C. L. “Chelate-Assisted Arene C-H Bond Functionalizations,” in Arene Chemistry: Reaction Mechanisms and Methods for Aromatic Compounds, Mortier, J. (ed.), Wiley-VCH, 2015, pp. 647-674. Patents Separation of Recycled Rare Earths, Marion H. Emmert, H. M. Dhammika Bandara. US Patent Application No. 14/996,538, filing date Jan. 15, 2016. Method of Recovery of Scandium from Bauxite Residue, Marion H. Emmert, Remya P. Narayanan. US Preliminary Patent Application No. 62/504,703, filing date May 11, 2017. Publications from PhD/Postdoctoral Work (6) Cook, A. K.; Emmert, M. H.; Sanford, M. S., Steric Control of Site Selectivity in the Pd-Catalyzed C-H Acetoxylation of Simple Arenes. Org. Lett. 2013, 15, 5428-5431. (5) Kubota, A.; Emmert, M. H.; Sanford, M. S., Pyridine Ligands as Promoters in PdII/0- Catalyzed C-H Olefination Reactions. Org. Lett. 2012, 14, 1760-1763. (4) Emmert, M. H.; Cook, A. K.; Xie, Y. J.; Sanford, M. S., Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected C-H Oxygenation of Arenes. Angew. Chem. Int. Ed. 2011, 50, 9409-9412. Highlighted on the back cover of issue 40. (3) Emmert, M. H.; Gary, J. B.; Villalobos, J. M.; Sanford, M. S., Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation. Angew. Chem. Int. Ed. 2010, 49, 5884-5886. (2) Emmert, M.; Kehr, G.; Fröhlich, R.; Erker, G., Facile Cyclometalation Reactions of Cp-Zirconium Complexes with Weakly Lewis Acidic Pendent Boron Functionalities. Chem. Eur. J. 2009, 15, 8124-8127. (1) Emmert, Marion, "Synthese und Reaktivität von Zr-Komplexen mit Cp3- Ligandgerüst", Westfälische Wilhelms-Universität Münster, Germany, Dissertation, (March 2009). Board Membership & Consulting Greene Lyon Group, 2015 - present. Invited Talks at International Meetings (9)
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