DOCSLIB.ORG

Crystal Structure of the New Radical Cation Salt (DOET)4[Fe(CN)5NO]1.25(C6h5cl)0.75 L

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Crystal Structure of the New Radical Cation Salt (DOET)4[Fe(CN)5NO]1.25(C6h5cl)0.75 L Crystallography Reports, Vol. 49, No. 6, 2004, pp. 1010–1017. Translated from Kristallografiya, Vol. 49, No. 6, 2004, pp. 1107–1114. Original Russian Text Copyright © 2004 by Zorina, Khasanov, Shibaeva, Shevyakova, Kotov, YagubskiÏ. STRUCTURE OF ORGANIC COMPOUNDS Crystal Structure of the New Radical Cation Salt (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75 L. V. Zorina*, S. S. Khasanov*, R. P. Shibaeva*, I. Yu. Shevyakova**, A. I. Kotov**, and É. B. YagubskiÏ** * Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, NoginskiÏ raÏon, Moscow oblast, 142432 Russia e-mail: [email protected] ** Institute for Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, NoginskiÏ raÏon, Moscow oblast, 142432 Russia Received August 1, 2003 Abstract—A new radical cation salt based on 4,5-(1,4-dioxanediyl-2,3-dithio)-4',5'-ethylenedithiotetrathiaful- 2– valene (DOET) with the photochromic anion [Fe(CN)5NO] , namely, (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75, is synthesized. Single crystals of this salt are studied using X-ray diffraction [a = 10.398(2) Å, b = 11.168(2) Å, c = 18.499(4) Å, α = 103.14(3)°, β = 92.80(3)°, γ = 106.02(3)°, V = 1996.3(7) Å3, space group P1 , and Z = 1]. In the structure, radical cation layers alternate with anion layers along the c axis. The centrosymmetric dimers are formed by DOET radical cations in the donor layer with packing of the β type. Like the vast majority of DOET-based salts, the new salt possesses semiconductor properties. © 2004 MAIK “Nauka/Interperiodica”. INTRODUCTION this series of investigations and studied a new salt based on the donor 4,5-(1,4-dioxanediyl-2,3-dithio)-4',5'-eth- In recent years, considerable research attention has ylenedithiotetrathiafulvalene (DOET), C H S O . been focused on the design of new synthetic functional 12 10 8 2 (conducting and magnetic) materials that can serve as S S an alternative to traditional conductors and magnets. S S These materials are promising for technical application in new fields of engineering due to their specific fea- S S S S tures and (or) an unusual combination of properties. BEDT-TTF From this point of view, molecular organic conduc- S S O tors are especially interesting objects of investigation. S S Materials based on organic molecules exhibit a great variety of conducting properties. Among these materi- S S S S O als are semiconductors, stable metals, and supercon- DOET ductors with the highest superconducting transition The modification of parent donor molecules is an temperature TC = 14.2 K [1–4]. The unique properties manifested by compounds of this class have stimulated efficient method for synthesizing new salts, which a purposeful search for new methods of synthesizing allows an understanding of the influence of the donor multifunctional molecular materials with controlled nature on the structure and properties of organic con- properties, in particular, through introducing anions ductors. The majority of organic conductors and super- with specific physical properties into a conducting conductors were prepared on the basis of the organic organic matrix. donor BEDT-TTF. The DOET molecule differs from the BEDT-TTF molecule by an additional six-membered Following this idea, we synthesized and investigated heterocycle containing two oxygen atoms. Owing to a number of new radical cation salts with the photo- the presence of this heterocycle in the DOET molecule, 2– chromic nitroprusside anion [Fe(CN)5NO] on the first, the total number of heteroatoms increases and, basis of different π-electron organic donors, such as hence, the probability of forming side intermolecular bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) [5– contacts of the heteroatom···heteroatom type (in partic- 8], bis(ethylenedioxo)tetrathiafulvalene (BEDO-TTF) ular, additional contacts S···O and C···O) that provide [5, 9], ethylenedithiotetrathiafulvalene (EDT-TTF) interaction in the radical cation layer is higher. Second, [5, 10], bis(dithiolanylidene)tetrathiapentalene (BDH- the presence of oxygen atoms leads to the formation of TTP) [11], tetrathiotetracene (TTT), and tetraselenotet- C–H···O hydrogen bonds between the neighboring rad- racene (TSeT) [12]. In the present work, we continued ical cations. 1063-7745/04/4906-1010 $26.00 © 2004 MAIK “Nauka/Interperiodica” CRYSTAL STRUCTURE OF THE NEW RADICAL CATION SALT 1011 A distinguishing feature of the DOET molecule is its dc power supply. A platinum wire 1 mm in diameter strongly bent shape: carbon atoms of the oxygen het- was used as electrodes. erocycle form a plane nearly perpendicular to the plane Electrocrystallization was performed under direct of the central skeleton of the molecule. The formation current conditions (I = 0.5 µA) at a temperature of 25°C of such a conformation can easily be explained in terms for 12 days. Crystals grew on the anode in the form of of the geometry of bonds. In the BEDT-TTF molecule, black plates approximately 0.8 × 0.9 × 0.07 mm3 in all carbon atoms, except for the carbon atoms involved size. The crystals were filtered off, washed thoroughly in the outer ethylene groups, are characterized by a pla- with acetone, and dried in air. 2 nar Csp configuration. In the oxygen heterocycle of the DOET molecule, both the outer and inner C–C bonds X-ray Diffraction Analysis 3 are single bonds and the stable Csp electronic state of The main crystal data are as follows: a = 10.398(2) Å, the corresponding carbon atoms is provided by the b = 11.168(2) Å, c = 18.499(4) Å, α = 103.14(3)¡, β = attachment of an additional hydrogen atom. Therefore, 92.80(3)¡, γ = 106.02(3)¡, V = 1996.3(7) Å3, space the inner carbon atoms of the oxygen heterocycle adopt group P1 , Z = 1 for the formula composition a bulk tetrahedral coordination, which, in turn, deter- C H Cl Fe N O S , M = 2125.1, mines the bond directionality and the molecular shape. 58.75 43.75 0.75 1.25 7.5 9.25 32 ρ 3 µ F(000) = 1080, calcd = 1.768 g/cm , and (MoKα) = The influence of the specific features revealed in the 11.54 cm–1. The experimental set of diffraction data molecular structure of the DOET radical cation on the involving 7336 reflections (6999 unique reflections, structure and properties of the salts synthesized will be Rint = 0.012, Rσ = 0.022) was collected on an Enraf– demonstrated by using the example of a new radical cation Nonius CAD4 automated diffractometer (MoKα radia- salt, namely, (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75. In tion, λ = 0.71073, graphite monochromator, θ = 2.5¡Ð this work, we described the synthesis of the aforemen- 25.0¡, ω scan mode) at room temperature. The structure tioned new radical cation salt, performed an X-ray dif- was solved by direct methods with subsequent Fourier fraction analysis of its crystal structure, and investi- syntheses according to the SHELXS97 software pack- gated the conducting properties of the single crystals. age [16] and refined by the full-matrix least-squares procedure with the SHELXL97 software package [17]. All non-hydrogen atoms (except for the disordered EXPERIMENTAL atoms in positions with a low occupancy in the DOET molecule I and the anion) were refined in the anisotro- Synthesis of (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75 pic approximation. The hydrogen atoms were located from geometric considerations with the isotropic ther- 4,5-(1,4-Dioxanediyl-2,3-dithio)-4',5'-ethylenedi- mal parameters UH = 1.2UC. The final R factor is equal thiotetrathiafulvalene (DOET) was synthesized accord- to 0.056 and GOOF = 1.047 for 5483 unique reflections ing to the procedure described in [13] and purified chro- with I > 2σ(I) for 699 parameters refined. matographically. Potassium nitroprusside K2[Fe(CN)5NO] · 2H2O was prepared using the proce- dure proposed in [14]. Chlorobenzene (Aldrich) was Conductivity Measurements twice distilled over P2O5. 18-Crown-6 (Flucka) was The conducting properties were investigated on an purified by recrystallization in acetonitrile and dried automated setup in the temperature range 315–4.2 K. under vacuum at a temperature of 30°C. Ethanol (Ald- The resistance was measured by the standard four-point rich) was allowed to stand for 10 h over freshly calci- probe method under direct current along the long crys- nated calcium oxide at the boiling temperature (78.3¡C) tal edge, which coincides with the a axis. The sample and was then distilled. All the solvents used were stored was cemented to platinum wires (10 µm in diameter) of in an inert atmosphere. the measuring unit with the use of a conducting graph- ite paste (Dotite paint, XC-12). The (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75 radical cation salt was prepared by electrochemical oxidation of DOET in the presence of a K2[Fe(CN)5NO] · 2H2O RESULTS AND DISCUSSION × –3 supporting electrolyte [15]. DOET (1.14 10 mol/l) and The (DOET)4[Fe(CN)5NO]1.25(C6H5Cl)0.75 crystals × –3 a mixture of K2[Fe(CN)5NO] · 2H2O (2.4 10 mol/l) have a layered structure in which the radical cation lay- with 18-crown-6 (4.9 × 10–3 mol/l) were placed in dif- ers alternate with the anion layers along the c axis. Fig- ferent arms of an H-shaped electrochemical cell and ure 1 shows the projection of the structure along the dissolved in a mixture of chlorobenzene (20 ml) with [110] direction. In the conducting donor layer, there are ethanol (1 ml). The dissolution was carried out at room two crystallographically independent radical cations temperature for 4 h in an argon atmosphere with contin- DOET I and II (Fig.
Load more

Recommended publications
  • New Publications
    WaTEn RESOURCESINVESTIGATIONS O'Brien and W J. Stone, 1984:Ground Water, Newpublications v.22, no. 6, pp.717-727. 83-4l18-B-Maps showing ground-water levels, Volcanogenic-exhalativetungsten mineralization springs, and depth to ground water, Basin and T{MBMMR of Proterozoic age near Santa Fe, New Mexico, Range Province, New Mexico, by B. T. Brady, *Circular L90--The skull of Sphenacodon and implicationsfor exploration,by M. S. Fulp ferocior, D. A. Mulvihill, D. L Hart, and W. H. Lan- and comoarisons with other sphenacodontines Jr., andJ.L. Renshaw,1985: Geology, v.73,pp.66- ger, 7984,6 pp., 2 sheets,scale 1:500,000 (ReptiliaiPelycosauria), by D.-A. Eberth, 1985, 69. 83-411.8-C-Maps showing distribution of dis- 39 pp., 2 tables, 39 figs $4.00 in Virtually complete, disarticulated cranial re- solved solids and dominant chemical type New 0pen-filereports ma\nsof Sohenacodonferociorfrom the Cutler and ground water, Basin and Range Province, and NMBMMR Abo Formations (Lower Permian) of north-cen- Mexico,by T. H. Thompson, R. Chappell, scale *215--Evaluation tral New Mexico are described in detail for the D. L. Hart, Jr., 7984, 5 pp., 2 sheets, of laboratory procedures for de- first time. These descriptions provide the basis 1:500,000. termining soil-water chloride, by B. E. McGurk for the most detailedcomparisons to datewithin 83-41.18-D-Map showing outcrops of granitic and W. f. Stone,1985, 36 pp., 12 tables,2 figs. and the subfamily Sphen- rocks and silicic shallow-intrusive rocks, Basin $7.20 the genus Sphenacodon *21.9-Geology acodontinae.
    [Show full text]
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • List of New Mineral Names: with an Index of Authors
    415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis.
    [Show full text]
  • Third-Generation Synchrotron X-Ray Diffraction of 6- M Crystal of Raite, Na
    Proc. Natl. Acad. Sci. USA Vol. 94, pp. 12263–12267, November 1997 Geology Third-generation synchrotron x-ray diffraction of 6-mm crystal of raite, 'Na3Mn3Ti0.25Si8O20(OH)2z10H2O, opens up new chemistry and physics of low-temperature minerals (crystal structureymicrocrystalyphyllosilicate) JOSEPH J. PLUTH*, JOSEPH V. SMITH*†,DMITRY Y. PUSHCHAROVSKY‡,EUGENII I. SEMENOV§,ANDREAS BRAM¶, CHRISTIAN RIEKEL¶,HANS-PETER WEBER¶, AND ROBERT W. BROACHi *Department of Geophysical Sciences, Center for Advanced Radiation Sources, GeologicalySoilyEnvironmental, and Materials Research Science and Engineering Center, 5734 South Ellis Avenue, University of Chicago, Chicago, IL 60637; ‡Department of Geology, Moscow State University, Moscow, 119899, Russia; §Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, 117071, Russia; ¶European Synchrotron Radiation Facility, BP 220, 38043, Grenoble, France; and UOP Research Center, Des Plaines, IL 60017 Contributed by Joseph V. Smith, September 3, 1997 ABSTRACT The crystal structure of raite was solved and the energy and metal industries, hydrology, and geobiology. refined from data collected at Beamline Insertion Device 13 at Raite lies in the chemical cooling sequence of exotic hyperal- the European Synchrotron Radiation Facility, using a 3 3 3 3 kaline rocks of the Kola Peninsula, Russia, and the 65 mm single crystal. The refined lattice constants of the Monteregian Hills, Canada (2). This hydrated sodium- monoclinic unit cell are a 5 15.1(1) Å; b 5 17.6(1) Å; c 5 manganese silicate extends the already wide range of manga- 5.290(4) Å; b 5 100.5(2)°; space group C2ym. The structure, nese crystal chemistry (3), which includes various complex including all reflections, refined to a final R 5 0.07.
    [Show full text]
  • New Mineral Names*,†
    American Mineralogist, Volume 100, pages 1649–1654, 2015 New Mineral Names*,† DMITRIY I. BELAKOVSKIY1 AND OLIVIER C. GAGNE2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada IN THIS ISSUE This New Mineral Names has entries for 10 new minerals, including debattistiite, evdokimovite, ferdowsiite, karpovite, kolskyite, markhininite, protochabournéite, raberite, shulamitite, and vendidaite. DEBATTISTIITE* for 795 unique I > 2σ(I) reflections] corner-sharing As(S,Te)3 A. Guastoni, L. Bindi, and F. Nestola (2012) Debattistiite, pyramids form three-membered distorted rings linked by Ag atoms in triangular or distorted tetrahedral coordination. Certain Ag9Hg0.5As6S12Te2, a new Te-bearing sulfosalt from Len- genbach quarry, Binn valley, Switzerland: description and features of that linkage are similar to those in the structures of crystal structure. Mineralogical Magazine, 76(3), 743–750. trechmannite and minerals of pearceite–polybasite group. Of the seven anion positions, one is almost fully occupied by Te (Te0.93S0.07). The Hg atom is in a nearly perfect linear coordination Debattistiite (IMA 2011-098), ideally Ag9Hg0.5As6S12Te2, is a new mineral discovered in the famous for Pb-Cu-Ag-As-Tl with two Te/S atoms. One of five Ag sites and Hg site, which are bearing sulfosalts Lengenbach quarry in the Binn Valley, Valais, very close (separation 1.137 Å), are partially occupied (50%). Switzerland. Debattistiite has been identified in two specimens Thus there is a statistical distribution (50:50) between Hg(Te,S)2 from zone 1 of the quarry in cavities in dolomitic marble with and AgS2(Te,S)2 polyhedra in the structure.
    [Show full text]
  • Subject Index, Volume 81, 1996
    American Mineralogist, Volume 81, pages 1543-1551, 1996 SUBJECT INDEX, VOLUME 81, 1996 Ag3TeS 1013 geikielite 485 florencite-(La) 1263 4°Ar 940 hornblende 928 glass 229 AuO(OH) 1282 hyttsj6ite 743 granitic melt 202 AuO(OH,Cl)onH20 766 kalsilite 561, 1360 kaolin 26 Achtarandite 516 kaolinite 26 migmatite 141 Afghanite 1003 kinoshitalite 485 orendite 229 Albite 92, 452, 789, 1133, 1344, laumontite 658 peridotite 79 1413 leonhardite 658, 668 rhyolite 158 Alkali feldspar 92, 719, 800, 1425 liandratite 1237 rhyolitic glass 158, 1249 Almandine 418 magnesiochromite 1186 sandstone 213 Altisite 516 magnesite 181 serpentinite 79 Aluminate sodalite 1375 medenbachite 505 volcanic glass 1176 Aluminosilicate glasses 265 muscovite 141, 1460 volcanic rocks 982 Alumoklyuchevskite 249 namuwite 238 Analysis, surface (mineral) Amphibole 135, 495, 1126 nanpingite 105 calcite 1 Analcime 39 nepheline 561, 1360 pyrite 261 Analysis, chemical (mineral) olivine 194, 1519 Anatexis 141 albite 92 omphacite 181 Androsite-(La) 735 alkali feldspar 719 orthopyroxene 676, 842 Ankerite 1141 almandine 418 pentlandite 187 Annite 475 amphibole 135, 495 phlogopite 202, 485,913 Annite-sanidine-magnetite 415 androsite-(La) 735 pigeonite 1166 Anorthoclase 1332 apatite 515 plagioclase 141, 913, 982, 1460 Antimonselite 1013 augite 1166 potassium feldspar 141 Antitaenite 766 bechererite 244 pumpellyite 603 Apatite 864, 1476 betafite 1237 pyralspitic garnet 418 Aragonite 181, 611 biopyribole 404 pyrite 119, 187 Arsenogorceixite 249 biotite 135, 141, 495, 1396, pyrope 418, 706 Asteroid
    [Show full text]
  • Chemical Composition and Petrogenetic Implications of Eudialyte-Group Mineral in the Peralkaline Lovozero Complex, Kola Peninsula, Russia
    minerals Article Chemical Composition and Petrogenetic Implications of Eudialyte-Group Mineral in the Peralkaline Lovozero Complex, Kola Peninsula, Russia Lia Kogarko 1,* and Troels F. D. Nielsen 2 1 Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia 2 Geological Survey of Denmark and Greenland, 1350 Copenhagen, Denmark; [email protected] * Correspondence: [email protected] Received: 23 September 2020; Accepted: 16 November 2020; Published: 20 November 2020 Abstract: Lovozero complex, the world’s largest layered peralkaline intrusive complex hosts gigantic deposits of Zr-, Hf-, Nb-, LREE-, and HREE-rich Eudialyte Group of Mineral (EGM). The petrographic relations of EGM change with time and advancing crystallization up from Phase II (differentiated complex) to Phase III (eudialyte complex). EGM is anhedral interstitial in all of Phase II which indicates that EGM nucleated late relative to the main rock-forming and liquidus minerals of Phase II. Saturation in remaining bulk melt with components needed for nucleation of EGM was reached after the crystallization about 85 vol. % of the intrusion. Early euhedral and idiomorphic EGM of Phase III crystalized in a large convective volume of melt together with other liquidus minerals and was affected by layering processes and formation of EGM ore. Consequently, a prerequisite for the formation of the ore deposit is saturation of the alkaline bulk magma with EGM. It follows that the potential for EGM ores in Lovozero is restricted to the parts of the complex that hosts cumulus EGM. Phase II with only anhedral and interstitial EGM is not promising for this type of ore.
    [Show full text]
  • New Minerals Approved Bythe Ima Commission on New
    NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI.
    [Show full text]
  • Crystal Growth, Structure and Physical Properties of Crystals
    Crystal growth, structure and physical properties of crystals Kurazhkovskaya V.S., Dorokhova G.I., Zyk- W – univalent and bivalent anions. Structures of vesuvi- ova T.B. Change of vezuvianit structural pe- anites are studied in dependence on a character of cation ordering in different sites within three space groups: culiarity at isomorphism. P4/nnc and its two sub-groups P4nc (C4ν) and P4/n (C4h). M.V. Lomonosov Moscow State University, Geological Depart- It is found earlier [1, 2], that two “garnet blocks” (GB), i.e. ment, Vorobjovy Gory, Moscow, 119899, Russia crys- volume bar, outsets from the grossular garnet structure, are [email protected] the basis of the vesuvianite structure. Junction of two GB key words: [vezuvianite, infrared spectroscopy, iso- leads to formation of diorthogroups [Si2O7]. Cation com- morphism] position of GB {Ca18Al8Si18} is practically constant. Cations of the “vesuvianite filling” (VF) occupy cavities Vesuvianite is an ortho-diorthosilicate of a general formed within the frame-work. Isomorphic substitutions schematic formula X~19Y13Z18O68W10, where X – Ca and are characteristic feature of VF (Table 1). Hypothetical other cations, which occupy sites of coordination number position R is suggested for vesuvianites with an excess 8, Y – cations occupying octahedrons and pentagonal cations (>19). polyhedrons: Al, Fe, Mg, Ti, etc., Z – Si in tetrahedrons, Table 1. Positions of cations CN Garnet block (GB) Vezuvianite filling (VF) 8 (Ca1)2 (Ca2)8 (Ca3)8 (Ca4)1 6 (Al1)8 (Al2)4 (R?)2 and > 5 (Al3)1 Table 2. Positions of “vezuvianite filling” N of sample (Ca4)1 (Al2)4 (Al3)1 (R?)2 and > 1 Ca1 Al2.93Fe1.07 Ca0.66Na0.34 Fe2.1Mn0.11 2 Ca1 Al3.72Fe0.24Ti0.04 Ca0.58Na0.23Mg0.14Zn0.05 Fe0.38Mg2.03 3 Ca1 Al2.16Fe0.93Ti0.92 Ca0.92Na0.39? Fe0.91Mg1.88Mn0.1 4 Ca1 Al1.16Fe2.05Mg0.84 Ca0.61Na0.18Mn0.1Zn0.02 Mg2.12 Table 3.
    [Show full text]
  • 2(Si4o12)O(O,F), a New K-Nb-Cyclosilicate from Chuktukon Carbonatite Massif, Chadobets Upland, Krasnoyarsk Territory, Russia
    minerals Article Rippite, K2(Nb,Ti)2(Si4O12)O(O,F), a New K-Nb-Cyclosilicate from Chuktukon Carbonatite Massif, Chadobets Upland, Krasnoyarsk Territory, Russia Victor V. Sharygin 1,2,3,* , Anna G. Doroshkevich 1,4 , Yurii V. Seryotkin 1,3 , Nikolai S. Karmanov 1, Elena V. Belogub 5,6, Tatyana N. Moroz 1, Elena N. Nigmatulina 1, Alexander P. Yelisseyev 1, Vitalii N. Vedenyapin 1 and Igor N. Kupriyanov 1,3 1 V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the RAS, 3 Acad. Koptyuga pr., 630090 Novosibirsk, Russia; [email protected] (A.G.D.); [email protected] (Y.V.S.); [email protected] (N.S.K.); [email protected] (T.N.M.); [email protected] (E.N.N.); [email protected] (A.P.Y.); [email protected] (V.N.V.); [email protected] (I.N.K.) 2 ExtraTerra Consortium, Institute of Physics and Technology, Ural Federal University, 19 Mira str., 620002 Ekaterinburg, Russia 3 Department of Geology and Geophysics, Novosibirsk State University, 1 Pirogov str., 630090 Novosibirsk, Russia 4 Geological Institute, Siberian Branch of the RAS, 6a Sakhyanova str., 670047 Ulan-Ude, Russia 5 South Urals Federal Research Center of Mineralogy and Geoecology, Uralian Branch of the RAS, 456317 Miass, Russia; [email protected] 6 Faculty of Geology, National Research South Ural State University, Miass Branch, 20 8-July str., Bldg. 10, 456304 Miass, Russia * Correspondence: [email protected]; Tel.: +7-383-330-80-84 Received: 9 November 2020; Accepted: 3 December 2020; Published: 8 December 2020 Abstract: Rippite K2(Nb,Ti)2(Si4O12)(O,F)2, a new K-Nb-cyclosilicate, has been discovered in calciocarbonatites from the Chuktukon massif (Chadobets upland, SW Siberian Platform, Krasnoyarsk Territory, Russia).
    [Show full text]
  • Mineralogicai, Radiographic and Uranium Leaching Studies on the Uranium Ore from Kvanefjeld, Ilimaussaq Complex, South Greenland
    T><2too/t6' Risø-R-416 Mineralogicai, Radiographic and Uranium Leaching Studies on the Uranium Ore from Kvanefjeld, Ilimaussaq Complex, South Greenland Milota Makovicky, Emil Makovicky, Bjarne Leth Nielsen, Svend Karup-Møller, and Emil Sørensen Risø National Laboratory, DK-4000 Roskilde, Denmark June 1980 RISØ-R-416 MINERALOGICAL, RADIOGRAPHIC AND URANIUM LEACHING STUDIES ON THE URANIUM ORE FROM KVANEFJELD, ILIMAUSSAQ. COMPLEX, 'SOUTH GREENLAND Milota Makovickyl , Emil Makovicky2, Bjarne Leth Nielsen-! , Sven Karuo-Møller^ and Emil Sørensen^ Abstract. 102 samples of low-grade uranium ore from 70 drill holes at Kvanefjeld, Ilimaussaq alkaline intrusion, South Green­ land were studied by means of autoradiography, fission-track investigations, microscopy, microprobe analyses and uranium- leaching experiments. The principal U-Th bearing mineral, steen- strupine, and several less common uranium minerals are dis­ seminated in lujavrite 'nepheline syenite) and altered volcanic rocks. Stenstrupine has a/erage composition Na6.7HxCai.n e Al (REE+Y)5.8(Th,l')o.5 ( ""1 . 6*" 1 . S^Q. 3^0. l 0. 2 ) Sii2036 (P4.3Si-) ,7 )024 (F,OH). nH20; n and x are variable. It either is of magmatic origin (type A) or connected with metasomatic processes (type B), or occurs in late veins (Type C). Preponder­ ance of grains are metamict (usually 2000-5000 ppm U3O8) or al­ tered (usually above 5000 ppm U3O8), sometimes zoned with both (continue on next page) June 1980 Pisø National Laboratory, DK-4000 Roskilde, Denmark components present. Occasionally they are extremely altered with U content falling to 500-5000 ppm U3O8 and local accumulations of high-U minerals formed.
    [Show full text]
  • Geology of Greenland Survey Bulletin 190, 25-33
    List of all minerals identified in the Ilímaussaq alkaline complex, South Greenland Ole V. Petersen About 220 minerals have been described from the Ilímaussaq alkaline complex. A list of all minerals, for which proper documentation exists, is presented with formulae and references to original publications. The Ilímaussaq alkaline complex is the type locality for 27 minerals including important rock-forming minerals such as aenigmatite, arfvedsonite, eudialyte, poly- lithionite, rinkite and sodalite. Nine minerals, chalcothallite, karupmøllerite-Ca, kvanefjeldite, nabesite, nacareniobsite-(Ce), naujakasite, rohaite, semenovite and sorensenite appear to be unique to the Ilímaussaq complex. Geological Museum, University of Copenhagen, Øster Voldgade 5–7, DK-1350 Copenhagen K, Denmark. E-mail: [email protected] Keywords: agpaite, Ilímaussaq, mineral inventory, minerals type locality The agpaitic complexes Ilímaussaq (South Greenland), world. Most of the minerals for which Ilímaussaq is Khibina and Lovozero (Kola Peninsula, Russia), and the type locality have later been found in other com- Mont Saint-Hilaire (Quebec, Canada) are among the plexes of agpaitic rocks. areas in the world which are richest in rare minerals. Two minerals were described simultaneously from About 700 minerals have been found in these com- Ilímaussaq and the Kola Peninsula, tugtupite and vi- plexes which hold the type localities for about 200 tusite. Tugtupite was published from the Lovozero minerals. complex by Semenov & Bykova (1960) under the name About 220 minerals have been found in the Ilímaus- beryllosodalite and from Ilímaussaq by Sørensen (1960) saq complex of which 27 have their type localities under the preliminary name beryllium sodalite which within the complex. In comparison Khibina and Lov- was changed to tugtupite in later publications (Søren- ozero hold the type localities for 127 minerals (Pekov sen 1962, 1963).
    [Show full text]