<<

Appendix 4 Everglades Interim Report

Appendix 4-5: Number of Pesticide Detections and Detection Percentages for Period of Record of the Pesticide Monitoring Program Data are number of sites a pesticide was detected in surface water samples taken from 1984 to current in the

SFWMD. Blank space indicates analyte was below detection limit.

(Sheet 1 of 4).

fy84 fy85 fy86 fy86 fy87 fy87 fy87 fy88 fy88 fy88 fy88 fy89 fy89 fy89 fy90 fy90

BA BA BA BA QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT

analyte Aug. '84 Jun. '85 Feb. '86 Jun. '86 Jan. '87 Apr. '87 Jul. '87 Oct. '87 Feb. '88 Apr. '88 Jul. '88 Nov. '88 Jan. '89 Jun. '89 Oct. '89 Jan. '90 2,4-D

2,4,5-T

2,4,5-TP 1

ametryn

2 aldrin

4 2 8 12 2 3

BHC alpha

BHC gamma

bromacil 123 carbaryl

carbofuran

chlordane

chlorothalonil 1

chlorpyrifos ethyl DDD- p,p'

DDE- p,p'

diazinon

dicofol

diuron 2

alpha 1

endosulfan beta

endosulfan sulfate ethion

ethoprop

ETU

linuron 2

malathion 1 metalax y l

methomyl

metolac hlor

monocrotophos

norflurazon

parathion methyl

prometryn

11 2

phosphide 1

total detections >m 000014208120022534

percent positive 0.0% 0.1% 0.1% 0.3% 2.0%

lab TSI TSI ENV PCT OLI U Miami U Miami U Miami U Miami U Miami U Miami U Miami U Miami U Miami PBSJ PBSJ PBSJ

sites 27 30 27 27 27

analytes 68 68 61 63 63

zinc phosphide 99099 total determinations 1845 2049 1647 1710 1710

author filesfilesrprprprprprprprprprprprprprp

sample group -- unit cost 740 740

contract #

A4-32 Everglades Interim Report Appendix 4

(Sheet 2 of 4)

fy90 fy90 fy90 fy91 fy91 fy91 fy91 fy91 fy91 fy92 fy92 fy92 fy92 fy92 fy92 fy92 QRTQRTQRTQRT/BMBMBMBMBMBMBMBMBMBMBMBMBM

analyte Mar. '90 May '90 Jul. '90 Oct. '90 Dec. '90 Feb. '91 Mar. '91 May '91 Jul. '91 Oct. '91 Nov. '91 Dec. '91 Feb. '92 Feb. '92 Apr. '92 Apr. '92 2,4-D 8 9 3 3 4 4 8 3 1 12 3 1 2,4,5-T 3 3 2,4,5-TP 11 ametryn 611 alachlor 1 2 aldrin 1 atrazine 4 4 3 12 19 16 4 4 5 19 10 23 BHC alpha 1 1 1 BHC gamma 1 bromacil 7 5 4 4 3 5 carbaryl 1 carbofuran 1 chlordane chlorothalonil 12 1 2 2 2 5 chlorpyrifos ethyl DDD- p,p' DDE- p,p' diazinon dicofol 21 dieldrin 1 diquat 2 diuron 2 1 2 1 2 3 endosulfan alpha 1 2 2 2 2 1 endosulfan beta 1 1 2 2 endosulfan sulfate 1 1 2 2 2 ethion 1

ethoprop

ETU 4 hexazinone linuron malathion metalax y l methomyl 1 metolac hlor 1 2 1

metribuzin 1 1 1 1 1

monocrotophos 1

norflurazon paraquat 1 parathion methyl prometryn 1 simazine 3 1 1 3 3 1 7 trifluralin 1 1 1 1 zinc phosphide 1 total detections >m 1 144117122732231810146 12412757 percent positive 0.1% 0.8% 2.4% 1.1% 0.7% 1.7% 1.9% 1.6% 1.1% 0.6% 0.8% 0.4% 0.7% 2.3% 1.6% 3.2%

lab PBSJ PBSJ PBSJ PBSJ PBSJ PBSJ PBSJ PBSJ PBSJ PBSJ DEP PBSJ PBSJ DEP PBSJ DEP sites 26272725252526262727272727272727 analytes 63636363636363636363646363666367 zinc phosphide9998990099099900 total determinations 1651 1710 1710 1609 1606 1606 1649 1449 1709 1710 1737 1710 1710 1780 1701 1809 author rprprprprprprp sample group------A--A-A unit cost 740 740 740 740 740 740 740 740 740 740 585 740 740 585 740 585 contract # 2555 2555 2555

A4-33 Appendix 4 Everglades Interim Report

(Sheet 3 of 4)

fy92 fy92 fy92 fy93 fy93 fy93 fy93 fy93 fy94 fy94 fy94 fy94 fy94 fy94 fy95 fy95 BM BM BM BM BM BM QRT QRT QRT QRT QRT QRT QRT QRT/BM QRT QRT

analyte Jun. '92 Jul. '92 Sep. '92 Nov. '92 Jan. '93 Mar. '93 Jun. '93 Sep. '93 Nov. '93 Feb. '94 Apr. '94 Jun. '94 Jul. '94 Sep. '94 Dec. '94 Mar . '95 2,4-D 2 2,4,5-T 2,4,5-TP ametryn25659544553654614 alachlor aldrin atrazine 23 18 8 10 16 18 11 4 9 13 15 12 10 6 12 21 BHC alpha BHC gamma bromacil4724733421 44327 carbaryl carbofuran chlordane 1 chlorothalonil chlorpyrifos ethyl DDD- p,p' DDE- p,p' 1 diazinon 1 dicofol 1 dieldrin diquat 1 diuron 1 2 2 2 3 2 4 5 4 1 1 endosulfan alpha 2 3 2 2 3 3 1 4 endosulfan beta 2 2 1 1 1 1 2 endosulfan sulfate 1 1 1 1 1 2 1 1 1 2 1 2 1 1 2 ethion 1 2 1 1 11

ethoprop 2

ETU

hexazinone 6 linuron malathion metalax y l 1 methomyl metolac hlor 2 1

metribuzin 1 2

monocrotophos

norflurazon 16 paraquat parathion methyl prometryn 1 simazine632435333 363215 trifluralin zinc phosphide total detections >m 39 40 23 29 44 37 27 18 23 24 31 36 29 17 30 69 percent positive 2.1% 2.2% 1.2% 1.6% 2.4% 2.0% 1.5% 1.0% 1.3% 1.3% 1.7% 2.0% 1.6% 0.9% 1.6% 3.8%

lab DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP sites 27272727272727272727272727272727 analytes 68686868686868686868686868686161 zinc phosphide0999900999000099 total determinations 1836 1845 1845 1845 1845 1836 1832 1845 1840 1840 1831 1831 1831 1831 1836 1836 author cjm cjm cjm cjm/rp cjm rp rp sample groupAAAAAAAAAAAAAAAA/AAA/A unit cost 585 585 585 630 630 630 630 630 630 630 630 630 630 630 680 680 contract # 2555 2555 2555 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 2555-A2 6699 6699

A4-34 Everglades Interim Report Appendix 4

(Sheet 4 of 4)

fy95 fy95 fy96 fy96 fy96 fy96 fy97 fy97 fy97 fy97 fy98 fy98 QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT QRT

analyte Jun. '95 Aug. '95 Oct. '95 Jan. '96 Apr. '96 Jul. '96 Oct. '96 Feb '97 May "97 Aug '97 Nov '97 Feb' 98 SUM RANK SUM RANK 2,4-D 1 1 63 7 5 15 2,4,5-T 617028 2,4,5-TP 325028 ametryn 12111011131411111514121425322532 alachlor 1617123 aldrin 133028 atrazine 21 18 18 19 25 17 17 25 26 24 22 35 627 1 520 1 BHC alpha 325028 BHC gamma 133028 bromacil 7 9 10 8 9 9 7 3 8 8 6 9 202 3 158 3 carbaryl 133028 carbofuran 133028 chlordane 133123 chlorothalonil 25 11 0 28 chlorpyrifos ethyl 2 2 30 2 21 DDD- p,p' 1 133123 DDE-p,p' 1 1 3 25 3 18 diazinon 1 2 1 5 20 5 15 dicofol 421318 dieldrin 133028 diquat 325123 diuron 4 1 2 8 55 8 48 7 endosulfan alpha 1 2 1 1 5 5 46 9 40 9 endosulfan beta 1 5 22 12 21 10 endosulfan sulfate 2 1 1 1 1 2 1 2 6 44 10 42 8 ethion 1 1 1 1 1 1 1 2 17 14 17 11 ethoprop 2 2 4 1 11 16 11 13 ETU 421028 hexazinone 10 9 5 7 11 5 6 4 5 16 5 3 92 5 92 5 linuron 230028 malathion 1 1 3 25 2 21 metalax y l 1 1 1421417 methomyl 133028 2 1 2 1 1 3 2 1 20131612 metribuzin 1 3 1 13 15 9 14 monocrotophos 133028 norflurazon5 7 855765 8 106 9886886 paraquat 133028 parathion methyl 1 133123 prometryn 1 1 4 21 3 18 simazine 6 4 528466 5 6 8 613941314 trifluralin 617028 zinc phosphide 230028 total detections >m 70 62 63 61 78 61 59 58 75 97 68 98 1788 percent positive 3.8% 3.4% 3.2% 3.1% 4.0% 3.1% 3.0% 1.6%

lab DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP DEP sites 272729292929293334343437 analytes 63 66 66 66/77 66/77 66/77 zinc phosphide0 9 990999 9 9 9 9 total determinations 1837 1839 1978 1978 1969 1978 1978 author rp rp rp rp rp rp rp rp rp rp rp rp 3.81% sample group AA/A AA/A AA/A AA/A/C AA/A AA/A AA/A AA/A AA/A AA AA AA unit cost 680 680 680 680 680 680 680 680 680 680 680 680 contract # 6699 6699 6699 6699 6699 6699 6699 6699 6699 6699 6699 6699

A4-35