4D-Polytopes Described by Coxeter Diagrams and Quaternions
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Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš
Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš To cite this version: Stanislav Jendrol’, František Kardoš. Symmetry of Fulleroids. Klaus D. Sattler. Handbook of Nanophysics: Clusters and Fullerenes, CRC Press, pp.28-1 - 28-13, 2010, 9781420075557. hal- 00966781 HAL Id: hal-00966781 https://hal.archives-ouvertes.fr/hal-00966781 Submitted on 27 Mar 2014 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Symmetry of Fulleroids Stanislav Jendrol’ and Frantiˇsek Kardoˇs Institute of Mathematics, Faculty of Science, P. J. Saf´arikˇ University, Koˇsice Jesenn´a5, 041 54 Koˇsice, Slovakia +421 908 175 621; +421 904 321 185 [email protected]; [email protected] Contents 1 Symmetry of Fulleroids 2 1.1 Convexpolyhedraandplanargraphs . .... 3 1.2 Polyhedral symmetries and graph automorphisms . ........ 4 1.3 Pointsymmetrygroups. 5 1.4 Localrestrictions ............................... .. 10 1.5 Symmetryoffullerenes . .. 11 1.6 Icosahedralfulleroids . .... 12 1.7 Subgroups of Ih ................................. 15 1.8 Fulleroids with multi-pentagonal faces . ......... 16 1.9 Fulleroids with octahedral, prismatic, or pyramidal symmetry ........ 19 1.10 (5, 7)-fulleroids .................................. 20 1 Chapter 1 Symmetry of Fulleroids One of the important features of the structure of molecules is the presence of symmetry elements. -
Abstract Regular Polytopes
ENCYCLOPEDIA OF MATHEMATICS AND ITS APPLICATIONS Abstract Regular Polytopes PETER MMULLEN University College London EGON SCHULTE Northeastern University PUBLISHED BY THE PRESS SYNDICATE OF THE UNIVERSITY OF CAMBRIDGE The Pitt Building, Trumpington Street, Cambridge, United Kingdom CAMBRIDGE UNIVERSITY PRESS The Edinburgh Building, Cambridge CB2 2RU, UK 40 West 20th Street, New York, NY 10011-4211, USA 477 Williamstown Road, Port Melbourne, VIC 3207, Australia Ruiz de Alarc´on 13, 28014 Madrid, Spain Dock House, The Waterfront, Cape Town 8001, South Africa http://www.cambridge.org c Peter McMullen and Egon Schulte 2002 This book is in copyright. Subject to statutory exception and to the provisions of relevant collective licensing agreements, no reproduction of any part may take place without the written permission of Cambridge University Press. First published 2002 Printed in the United States of America Typeface Times New Roman 10/12.5 pt. System LATEX2ε [] A catalog record for this book is available from the British Library. Library of Congress Cataloging in Publication Data McMullen, Peter, 1955– Abstract regular polytopes / Peter McMullen, Egon Schulte. p. cm. – (Encyclopedia of mathematics and its applications) Includes bibliographical references and index. ISBN 0-521-81496-0 1. Polytopes. I. Schulte, Egon, 1955– II. Title. III. Series. QA691 .M395 2002 516.35 – dc21 2002017391 ISBN 0 521 81496 0 hardback Contents Preface page xiii 1 Classical Regular Polytopes 1 1A The Historical Background 1 1B Regular Convex Polytopes 7 1C Extensions -
Origin of Icosahedral Symmetry in Viruses
Origin of icosahedral symmetry in viruses Roya Zandi†‡, David Reguera†, Robijn F. Bruinsma§, William M. Gelbart†, and Joseph Rudnick§ Departments of †Chemistry and Biochemistry and §Physics and Astronomy, University of California, Los Angeles, CA 90095-1569 Communicated by Howard Reiss, University of California, Los Angeles, CA, August 11, 2004 (received for review February 2, 2004) With few exceptions, the shells (capsids) of sphere-like viruses (11). This problem is in turn related to one posed much earlier have the symmetry of an icosahedron and are composed of coat by Thomson (12), involving the optimal distribution of N proteins (subunits) assembled in special motifs, the T-number mutually repelling points on the surface of a sphere, and to the structures. Although the synthesis of artificial protein cages is a subsequently posed ‘‘covering’’ problem, where one deter- rapidly developing area of materials science, the design criteria for mines the arrangement of N overlapping disks of minimum self-assembled shells that can reproduce the remarkable properties diameter that allow complete coverage of the sphere surface of viral capsids are only beginning to be understood. We present (13). In a similar spirit, a self-assembly phase diagram has been here a minimal model for equilibrium capsid structure, introducing formulated for adhering hard disks (14). These models, which an explicit interaction between protein multimers (capsomers). all deal with identical capsomers, regularly produced capsid Using Monte Carlo simulation we show that the model reproduces symmetries lower than icosahedral. On the other hand, theo- the main structures of viruses in vivo (T-number icosahedra) and retical studies of viral assembly that assume icosahedral sym- important nonicosahedral structures (with octahedral and cubic metry are able to reproduce the CK motifs (15), and, most symmetry) observed in vitro. -
Uniform Polychora
BRIDGES Mathematical Connections in Art, Music, and Science Uniform Polychora Jonathan Bowers 11448 Lori Ln Tyler, TX 75709 E-mail: [email protected] Abstract Like polyhedra, polychora are beautiful aesthetic structures - with one difference - polychora are four dimensional. Although they are beyond human comprehension to visualize, one can look at various projections or cross sections which are three dimensional and usually very intricate, these make outstanding pieces of art both in model form or in computer graphics. Polygons and polyhedra have been known since ancient times, but little study has gone into the next dimension - until recently. Definitions A polychoron is basically a four dimensional "polyhedron" in the same since that a polyhedron is a three dimensional "polygon". To be more precise - a polychoron is a 4-dimensional "solid" bounded by cells with the following criteria: 1) each cell is adjacent to only one other cell for each face, 2) no subset of cells fits criteria 1, 3) no two adjacent cells are corealmic. If criteria 1 fails, then the figure is degenerate. The word "polychoron" was invented by George Olshevsky with the following construction: poly = many and choron = rooms or cells. A polytope (polyhedron, polychoron, etc.) is uniform if it is vertex transitive and it's facets are uniform (a uniform polygon is a regular polygon). Degenerate figures can also be uniform under the same conditions. A vertex figure is the figure representing the shape and "solid" angle of the vertices, ex: the vertex figure of a cube is a triangle with edge length of the square root of 2. -
Platonic Solids Generate Their Four-Dimensional Analogues
1 Platonic solids generate their four-dimensional analogues PIERRE-PHILIPPE DECHANT a;b;c* aInstitute for Particle Physics Phenomenology, Ogden Centre for Fundamental Physics, Department of Physics, University of Durham, South Road, Durham, DH1 3LE, United Kingdom, bPhysics Department, Arizona State University, Tempe, AZ 85287-1604, United States, and cMathematics Department, University of York, Heslington, York, YO10 5GG, United Kingdom. E-mail: [email protected] Polytopes; Platonic Solids; 4-dimensional geometry; Clifford algebras; Spinors; Coxeter groups; Root systems; Quaternions; Representations; Symmetries; Trinities; McKay correspondence Abstract In this paper, we show how regular convex 4-polytopes – the analogues of the Platonic solids in four dimensions – can be constructed from three-dimensional considerations concerning the Platonic solids alone. Via the Cartan-Dieudonne´ theorem, the reflective symmetries of the arXiv:1307.6768v1 [math-ph] 25 Jul 2013 Platonic solids generate rotations. In a Clifford algebra framework, the space of spinors gen- erating such three-dimensional rotations has a natural four-dimensional Euclidean structure. The spinors arising from the Platonic Solids can thus in turn be interpreted as vertices in four- dimensional space, giving a simple construction of the 4D polytopes 16-cell, 24-cell, the F4 root system and the 600-cell. In particular, these polytopes have ‘mysterious’ symmetries, that are almost trivial when seen from the three-dimensional spinorial point of view. In fact, all these induced polytopes are also known to be root systems and thus generate rank-4 Coxeter PREPRINT: Acta Crystallographica Section A A Journal of the International Union of Crystallography 2 groups, which can be shown to be a general property of the spinor construction. -
The Cubic Groups
The Cubic Groups Baccalaureate Thesis in Electrical Engineering Author: Supervisor: Sana Zunic Dr. Wolfgang Herfort 0627758 Vienna University of Technology May 13, 2010 Contents 1 Concepts from Algebra 4 1.1 Groups . 4 1.2 Subgroups . 4 1.3 Actions . 5 2 Concepts from Crystallography 6 2.1 Space Groups and their Classification . 6 2.2 Motions in R3 ............................. 8 2.3 Cubic Lattices . 9 2.4 Space Groups with a Cubic Lattice . 10 3 The Octahedral Symmetry Groups 11 3.1 The Elements of O and Oh ..................... 11 3.2 A Presentation of Oh ......................... 14 3.3 The Subgroups of Oh ......................... 14 2 Abstract After introducing basics from (mathematical) crystallography we turn to the description of the octahedral symmetry groups { the symmetry group(s) of a cube. Preface The intention of this account is to provide a description of the octahedral sym- metry groups { symmetry group(s) of the cube. We first give the basic idea (without proofs) of mathematical crystallography, namely that the 219 space groups correspond to the 7 crystal systems. After this we come to describing cubic lattices { such ones that are built from \cubic cells". Finally, among the cubic lattices, we discuss briefly the ones on which O and Oh act. After this we provide lists of the elements and the subgroups of Oh. A presentation of Oh in terms of generators and relations { using the Dynkin diagram B3 is also given. It is our hope that this account is accessible to both { the mathematician and the engineer. The picture on the title page reflects Ha¨uy'sidea of crystal structure [4]. -
Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of F Orbitals
molecules Article Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals R. Bruce King Department of Chemistry, University of Georgia, Athens, GA 30602, USA; [email protected] Academic Editor: Vito Lippolis Received: 4 June 2020; Accepted: 29 June 2020; Published: 8 July 2020 Abstract: The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f orbital, and 12-orbital hexagonal prismatic hybridization can be shown to be sp3d5f2g requiring a g orbital. The twists to convert a cube to a square antiprism and a hexagonal prism to a hexagonal antiprism eliminate the need for the highest nodality orbitals in the resulting hybrids. A trigonal twist of an Oh octahedron into a D3h trigonal prism can involve a gradual change of the pair of d orbitals in the corresponding sp3d2 hybrids. A similar trigonal twist of an Oh cuboctahedron into a D3h anticuboctahedron can likewise involve a gradual change in the three f orbitals in the corresponding sp3d5f3 hybrids. Keywords: coordination polyhedra; hybridization; atomic orbitals; f-block elements 1. Introduction In a series of papers in the 1990s, the author focused on the most favorable coordination polyhedra for sp3dn hybrids, such as those found in transition metal complexes. Such studies included an investigation of distortions from ideal symmetries in relatively symmetrical systems with molecular orbital degeneracies [1] In the ensuing quarter century, interest in actinide chemistry has generated an increasing interest in the involvement of f orbitals in coordination chemistry [2–7]. -
COXETER GROUPS (Unfinished and Comments Are Welcome)
COXETER GROUPS (Unfinished and comments are welcome) Gert Heckman Radboud University Nijmegen [email protected] October 10, 2018 1 2 Contents Preface 4 1 Regular Polytopes 7 1.1 ConvexSets............................ 7 1.2 Examples of Regular Polytopes . 12 1.3 Classification of Regular Polytopes . 16 2 Finite Reflection Groups 21 2.1 NormalizedRootSystems . 21 2.2 The Dihedral Normalized Root System . 24 2.3 TheBasisofSimpleRoots. 25 2.4 The Classification of Elliptic Coxeter Diagrams . 27 2.5 TheCoxeterElement. 35 2.6 A Dihedral Subgroup of W ................... 39 2.7 IntegralRootSystems . 42 2.8 The Poincar´eDodecahedral Space . 46 3 Invariant Theory for Reflection Groups 53 3.1 Polynomial Invariant Theory . 53 3.2 TheChevalleyTheorem . 56 3.3 Exponential Invariant Theory . 60 4 Coxeter Groups 65 4.1 Generators and Relations . 65 4.2 TheTitsTheorem ........................ 69 4.3 The Dual Geometric Representation . 74 4.4 The Classification of Some Coxeter Diagrams . 77 4.5 AffineReflectionGroups. 86 4.6 Crystallography. .. .. .. .. .. .. .. 92 5 Hyperbolic Reflection Groups 97 5.1 HyperbolicSpace......................... 97 5.2 Hyperbolic Coxeter Groups . 100 5.3 Examples of Hyperbolic Coxeter Diagrams . 108 5.4 Hyperbolic reflection groups . 114 5.5 Lorentzian Lattices . 116 3 6 The Leech Lattice 125 6.1 ModularForms ..........................125 6.2 ATheoremofVenkov . 129 6.3 The Classification of Niemeier Lattices . 132 6.4 The Existence of the Leech Lattice . 133 6.5 ATheoremofConway . 135 6.6 TheCoveringRadiusofΛ . 137 6.7 Uniqueness of the Leech Lattice . 140 4 Preface Finite reflection groups are a central subject in mathematics with a long and rich history. The group of symmetries of a regular m-gon in the plane, that is the convex hull in the complex plane of the mth roots of unity, is the dihedral group of order 2m, which is the simplest example of a reflection Dm group. -
Binary Icosahedral Group and 600-Cell
Article Binary Icosahedral Group and 600-Cell Jihyun Choi and Jae-Hyouk Lee * Department of Mathematics, Ewha Womans University 52, Ewhayeodae-gil, Seodaemun-gu, Seoul 03760, Korea; [email protected] * Correspondence: [email protected]; Tel.: +82-2-3277-3346 Received: 10 July 2018; Accepted: 26 July 2018; Published: 7 August 2018 Abstract: In this article, we have an explicit description of the binary isosahedral group as a 600-cell. We introduce a method to construct binary polyhedral groups as a subset of quaternions H via spin map of SO(3). In addition, we show that the binary icosahedral group in H is the set of vertices of a 600-cell by applying the Coxeter–Dynkin diagram of H4. Keywords: binary polyhedral group; icosahedron; dodecahedron; 600-cell MSC: 52B10, 52B11, 52B15 1. Introduction The classification of finite subgroups in SLn(C) derives attention from various research areas in mathematics. Especially when n = 2, it is related to McKay correspondence and ADE singularity theory [1]. The list of finite subgroups of SL2(C) consists of cyclic groups (Zn), binary dihedral groups corresponded to the symmetry group of regular 2n-gons, and binary polyhedral groups related to regular polyhedra. These are related to the classification of regular polyhedrons known as Platonic solids. There are five platonic solids (tetrahedron, cubic, octahedron, dodecahedron, icosahedron), but, as a regular polyhedron and its dual polyhedron are associated with the same symmetry groups, there are only three binary polyhedral groups(binary tetrahedral group 2T, binary octahedral group 2O, binary icosahedral group 2I) related to regular polyhedrons. -
Maximal Subgroups of the Coxeter Group W(H4) and Quaternions
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Elsevier - Publisher Connector Linear Algebra and its Applications 412 (2006) 441–452 www.elsevier.com/locate/laa Maximal subgroups of the Coxeter group W(H4) and quaternions Mehmet Koca a, Ramazan Koç b,∗, Muataz Al-Barwani a, Shadia Al-Farsi a aDepartment of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, Al-Khod 123, Muscat, Oman bDepartment of Physics, Faculty of Engineering, Gaziantep University, 27310 Gaziantep, Turkey Received 9 October 2004; accepted 17 July 2005 Available online 12 September 2005 Submitted by H. Schneider Abstract The largest finite subgroup of O(4) is the non-crystallographic Coxeter group W(H4) of order 14,400. Its derived subgroup is the largest finite subgroup W(H4)/Z2 of SO(4) of order 7200. Moreover, up to conjugacy, it has five non-normal maximal subgroups of orders 144, two 240, 400 and 576. Two groups [W(H2) × W(H2)]Z4 and W(H3) × Z2 possess non- crystallographic structures with orders 400 and 240 respectively. The groups of orders 144, 240 and 576 are the extensions of the Weyl groups of the root systems of SU(3) × SU(3), SU(5) and SO(8) respectively. We represent the maximal subgroups of W(H4) with sets of quaternion pairs acting on the quaternionic root systems. © 2005 Elsevier Inc. All rights reserved. AMS classification: 20G20; 20F05; 20E34 Keywords: Structure of groups; Quaternions; Coxeter groups; Subgroup structure ∗ Corresponding author. Tel.: +90 342 360 1200; fax: +90 342 360 1013. -
Computing Invariants of Hyperbolic Coxeter Groups
LMS J. Comput. Math. 18 (1) (2015) 754{773 C 2015 Author doi:10.1112/S1461157015000273 CoxIter { Computing invariants of hyperbolic Coxeter groups R. Guglielmetti Abstract CoxIter is a computer program designed to compute invariants of hyperbolic Coxeter groups. Given such a group, the program determines whether it is cocompact or of finite covolume, whether it is arithmetic in the non-cocompact case, and whether it provides the Euler characteristic and the combinatorial structure of the associated fundamental polyhedron. The aim of this paper is to present the theoretical background for the program. The source code is available online as supplementary material with the published article and on the author's website (http://coxiter.rgug.ch). Supplementarymaterialsareavailablewiththisarticle. Introduction Let Hn be the hyperbolic n-space, and let Isom Hn be the group of isometries of Hn. For a given discrete hyperbolic Coxeter group Γ < Isom Hn and its associated fundamental polyhedron P ⊂ Hn, we are interested in geometrical and combinatorial properties of P . We want to know whether P is compact, has finite volume and, if the answer is yes, what its volume is. We also want to find the combinatorial structure of P , namely, the number of vertices, edges, 2-faces, and so on. Finally, it is interesting to find out whether Γ is arithmetic, that is, if Γ is commensurable to the reflection group of the automorphism group of a quadratic form of signature (n; 1). Most of these questions can be answered by studying finite and affine subgroups of Γ, but this involves a huge number of computations. -
Petrie Schemes
Canad. J. Math. Vol. 57 (4), 2005 pp. 844–870 Petrie Schemes Gordon Williams Abstract. Petrie polygons, especially as they arise in the study of regular polytopes and Coxeter groups, have been studied by geometers and group theorists since the early part of the twentieth century. An open question is the determination of which polyhedra possess Petrie polygons that are simple closed curves. The current work explores combinatorial structures in abstract polytopes, called Petrie schemes, that generalize the notion of a Petrie polygon. It is established that all of the regular convex polytopes and honeycombs in Euclidean spaces, as well as all of the Grunbaum–Dress¨ polyhedra, pos- sess Petrie schemes that are not self-intersecting and thus have Petrie polygons that are simple closed curves. Partial results are obtained for several other classes of less symmetric polytopes. 1 Introduction Historically, polyhedra have been conceived of either as closed surfaces (usually topo- logical spheres) made up of planar polygons joined edge to edge or as solids enclosed by such a surface. In recent times, mathematicians have considered polyhedra to be convex polytopes, simplicial spheres, or combinatorial structures such as abstract polytopes or incidence complexes. A Petrie polygon of a polyhedron is a sequence of edges of the polyhedron where any two consecutive elements of the sequence have a vertex and face in common, but no three consecutive edges share a commonface. For the regular polyhedra, the Petrie polygons form the equatorial skew polygons. Petrie polygons may be defined analogously for polytopes as well. Petrie polygons have been very useful in the study of polyhedra and polytopes, especially regular polytopes.