2018 Annual Survey of Biological and Chemical Agents Regulated by Homeland Security (And Carcinogens Regulated by OSHA)
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Chemical Disinfectants for Biohazardous Materials (3/21)
Safe Operating Procedure (Revised 3/21) CHEMICAL DISINFECTANTS FOR BIOHAZARDOUS MATERIALS ____________________________________________________________________________ Chemicals used for biohazardous decontamination are called sterilizers, disinfectants, sanitizers, antiseptics and germicides. These terms are sometimes equivalent, but not always, but for the purposes of this document all the chemicals described herein are disinfectants. The efficacy of every disinfectant is based on several factors: 1) organic load (the amount of dirt and other contaminants on the surface), 2) microbial load, 3) type of organism, 4) condition of surfaces to be disinfected (i.e., porous or nonporous), and 5) disinfectant concentration, pH, temperature, contact time and environmental humidity. These factors determine if the disinfectant is considered a high, intermediate or low-level disinfectant, in that order. Prior to selecting a specific disinfectant, consider the relative resistance of microorganisms. The following table provides information regarding chemical disinfectant resistance of various biological agents. Microbial Resistance to Chemical Disinfectants: Type of Microbe Examples Resistant Bovine spongiform encephalopathy (Mad Prions Cow) Creutzfeldt-Jakob disease Bacillus subtilis; Clostridium sporogenes, Bacterial Spores Clostridioides difficile Mycobacterium bovis, M. terrae, and other Mycobacteria Nontuberculous mycobacterium Poliovirus; Coxsackievirus; Rhinovirus; Non-enveloped or Small Viruses Adenovirus Trichophyton spp.; Cryptococcus sp.; -
Chemical Threat Agents Call Poison Control 24/7 for Treatment Information 1.800.222.1222 Blood Nerve Blister Pulmonary Metals Toxins
CHEMICAL THREAT AGENTS CALL POISON CONTROL 24/7 FOR TREATMENT INFORMATION 1.800.222.1222 BLOOD NERVE BLISTER PULMONARY METALS TOXINS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS • Vertigo • Diarrhea, diaphoresis • Itching • Upper respiratory tract • Cough • Shock • Tachycardia • Urination • Erythema irritation • Metallic taste • Organ failure • Tachypnea • Miosis • Yellowish blisters • Rhinitis • CNS effects • Cyanosis • Bradycardia, bronchospasm • Flu-like symptoms • Coughing • Shortness of breath • Flu-like symptoms • Emesis • Delayed eye irritation • Choking • Flu-like symptoms • Nonspecific neurological • Lacrimation • Delayed pulmonary edema • Visual disturbances symptoms • Salivation, sweating INDICATIVE LAB TESTS INDICATIVE LAB TESTS INDICATIVE LAB TEST INDICATIVE LAB TESTS INDICATIVE LAB TESTS INDICATIVE LAB TESTS • Increased anion gap • Decreased cholinesterase • Thiodiglycol present in urine • Decreased pO2 • Proteinuria None Available • Metabolic acidosis • Increased anion gap • Decreased pCO2 • Renal assessment • Narrow pO2 difference • Metabolic acidosis • Arterial blood gas between arterial and venous • Chest radiography samples DEFINITIVE TEST DEFINITIVE TEST DEFINITIVE TEST DEFINITIVE TESTS DEFINITIVE TESTS • Blood cyanide levels • Urine nerve agent • Urine blister agent No definitive tests available • Blood metals panel • Urine ricinine metabolites metabolites • Urine metals panel • Urine abrine POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS • Hydrogen Cyanide -
Air Contaminants – Permissible Exposure Limits (Pels)
SUBPART Z -- TOXIC AND HAZARDOUS SUBSTANCES 1910.1000-AIR CONTAMINANTS An employee’s exposure to any substance listed in Table Z-1-A of this section shall be limited in accordance with the requirements of the following paragraphs of this section. (a) Table Z-1-A. Limits for Air Contaminants (1) & (2) Enforcement of Transitional Limits has expired. See Paragraph (3) for Limits. (3) Limits for Air Contaminants Columns. An employee’s exposure to any substance listed in Table Z-1-A shall not exceed the Time Weighted Average (TWA), Short Term Exposure Limit (STEL) and Ceiling Limit specified for that substance in Table Z-1-A. (4) Skin Designation. To prevent or reduce skin absorption, an employee’s skin exposure to substances listed in Table Z-1-A with an “X” in the Skin Designation column following the substance name shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves, coveralls, goggles, or other appropriate personal protective equipment, engineering controls or work practices. (5) Definitions. The following definitions are applicable to the Limits for Air Contaminants columns of Table Z- 1-A: (i) Time weighted average (TWA) is the employee’s average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded. (ii) Short term exposure limit (STEL) is the employee’s 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified in a parenthetical notation below the limit. -
Rhode Island Hazardous Substance List
Rhode Island Hazardous Substance List Source: T - ACGIH F - NFPA49 C - IARC Alphabetical Order C.A.S. ACGIH NFPA IARC CHEMICAL NAME 13010-47-4 C 1,-(2-Chloroethyl)-3-cyclohexyl-1-Nitrosourea 76-11-9 T 1,1,1,2-tetrachloro-2,2-difluoroethane 76-12-0 T 1,1,2,2-tetrachloro-1,2-difluoroethane 79-34-5 T 1,1,2,2-tetrachloroethane - skin 76-13-1 T 1,1,2-trichloro-1,2,2-trifluoroethane 79-00-5 T F C 1,1,2-trichloroethane - skin 594-72-9 T 1,1-Dichloro-1-nitroethane 74-34-3 T 1,1-dichloroethane 57-14-7 T 1,1-dimethylhydrazine (udmh) 96-18-4 T 1,2,3-trichloropropane 120-82-1 T 1,2,4-Trichlorobenzene 106-88-7 F 1,2-Butylene oxide 107-15-3 T F 1,2-Diaminoethane 96-12-8 C 1,2-Dibromo-3-chloropropane 106-93-4 T F C 1,2-Dibromoethane - skin 107-06-2 T F 1,2-Dichlorethane 540-59-0 T F 1,2-Dichloroethene 540-59-0 T F 1,2-Dichloroetylene 1615-80-1 C 1,2-Diethylhydrazine C 1,2-Dimethyl hydrazine - skin 106-99-0 T F 1,3-Butadiene 118-52-5 T 1,3-Dichloro-5,5-dimethylhydantoin 542-75-6 T F 1,3-Dichloropropene (cis and trans) 542-75-6 T F 1,3-Dichloropropylene 110-56-5 F 1,4-Dichlorobutane 123-91-1 T F C 1,4-Dioxane 1120-71-4 1-3-Propane sultone 110-53-2 F 1-Bromopentane 106-89-8 T F C 1-Chloro,2,3-epoxy-propane 600-25-9 T 1-Chloro-1-nitropropane 97-00-7 F 1-chloro-2,4-dinitrobenzene 543-59-9 F 1-Chloropentane 112-30-1 F 1-Decanol 111-27-3 F 1-Hexanol 141-79-7 T F 1-Isobutenyl methyl ketone 108-03-2 T F 1-Nitropropane 71-41-0 F 1-Pentanol 110-58-7 F 1-Pentylamine 111-40-0 T F 2,2'-Diaminodiethylamine 111-44-4 F 2,2'Dichlorodiethyl ether 75-99-0 T 2,2-dichloropropionic acid 556-52-5 T 2,3-Epoxy-1-propanol 93-76-5 T 2,4,5-T 95-95-4 F 2,4,5-trichlorophenol 88-06-2 F C 2,4,6-trichlorophenol 118-96-7 T F 2,4,6-Trinitro Toluene 479-95-8 T 2,4,6-Trinitrophenyl-methylnitramine 94-75-7 T 2,4-d (2,4-dichlorophenoxyacetic acid) 97-02-9 F 2,4-dinitroaniline 584-84-9 T F 2,4-Tolylene diisocyanate 108-83-8 T 2,6-Dimethyl-4-heptanone 108-83-8 T 2,6-Dimethyl-4-heptanone 128-37-0 T 2,6-Ditert. -
Downloads/DL Praevention/Fachwissen/Gefahrstoffe/TOXIKOLOGI SCHE BEWERTUNGEN/Bewertungen/Toxbew072-L.Pdf
Distribution Agreement In presenting this thesis or dissertation as a partial fulfillment of the requirements for an advanced degree from Emory University, I hereby grant to Emory University and its agents the non-exclusive license to archive, make accessible, and display my thesis or dissertation in whole or in part in all forms of media, now or hereafter known, including display on the world wide web. I understand that I may select some access restrictions as part of the online submission of this thesis or dissertation. I retain all ownership rights to the copyright of the thesis or dissertation. I also retain the right to use in future works (such as articles or books) all or part of this thesis or dissertation. Signature: _____________________________ ______________ Jedidiah Samuel Snyder Date Statistical analysis of concentration-time extrapolation factors for acute inhalation exposures to hazardous substances By Jedidiah S. Snyder Master of Public Health Global Environmental Health _________________________________________ P. Barry Ryan, Ph.D. Committee Chair _________________________________________ Eugene Demchuk, Ph.D. Committee Member _________________________________________ Paige Tolbert, Ph.D. Committee Member Statistical analysis of concentration-time extrapolation factors for acute inhalation exposures to hazardous substances By Jedidiah S. Snyder Bachelor of Science in Engineering, B.S.E. The University of Iowa 2010 Thesis Committee Chair: P. Barry Ryan, Ph.D. An abstract of A thesis submitted to the Faculty of the Rollins School of Public Health of Emory University in partial fulfillment of the requirements for the degree of Master of Public Health in Global Environmental Health 2015 Abstract Statistical analysis of concentration-time extrapolation factors for acute inhalation exposures to hazardous substances By Jedidiah S. -
Elemental Fluorine Product Information (Pdf)
Elemental Fluorine Contents 1 Introduction ............................................................................................................... 4 2.1 Technical Application of Fluorine ............................................................................. 5 2.2 Electronic Application of Fluorine ........................................................................... 7 2.3 Fluorine On-Site Plant ............................................................................................ 8 3 Specifications ............................................................................................................ 9 4 Safety ...................................................................................................................... 10 4.1 Maintenance of the F2 system .............................................................................. 12 4.2 First Aid ................................................................................................................ 13 5.1 Chemical Properties ............................................................................................. 14 5.2 Physical Data ....................................................................................................... 15 6 Toxicity .................................................................................................................... 18 7 Shipping and Transport ........................................................................................... 20 8 Environment ........................................................................................................... -
Aegls Brochure
4.85 5 5 About the Board on Environmental Studies and Toxicology The Board on Environmental Studies and Toxicology addresses Types of Chemicals Covered in the AEGLs Series environmental pollution problems affecting human health, human impacts on the environment, and the assessment and management of risks to AEGLs values for the chemicals listed below were published in the first human health and the environment. The board’s reports answer questions six volumes of the AEGLs series. AEGLs for additional chemicals will about air and water pollution; solid and hazardous waste; toxicology; continue to be published in subsequent volumes. epidemiology; risk assessment; applied ecology; natural resources; and environmental engineering, economics, law, and policy. Allylamine Hydrogen fluoride Ammonia Iron pentacarbonyl Aniline Methyl hydrazine Arsine Methyl isocyanate About NRC Reports from the National Academies Protecting Chlorine Nerve agents GA [tabun], The National Academies, through its National Research Council reports, Chlorine dioxide GB [sarin], GD [soman], GF, provides a unique public service by working outside the framework of Chlorine trifluoride and VX the Public and government to ensure independent, expert advice on matters of science, Crotonaldehyde Nickel carbonyl technology, and medicine. Today, the National Academies include three Cyclohexylamine Phosgene honorary societies that elect new members to their ranks each year- Diborane Phosphine Emergency the National Academy of Sciences, the National Academy of Engineering, 1,1-Dichloro-1-fluoroethane Propylene glycol dinitrate and the Institute of Medicine-and the National Research Council, the (HCFC-141B) Sulfur mustard operating arm that conducts the bulk of the institution’s Dimethylhydrazine 1,1,1,2-Tetrafluoroethane Workers science-policy and technical work. -
Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
Silica Material Safety Data Sheet
Distributed by: u.s. SILICA COMPANY Laguna Clay Company 14400 Lomitas Ave City of Industry, CA 91746 Material Safety Data Sheet 1-800-4Laguna Page 1 of 11 [email protected] • - www.lagunaclay.com Product Name: Silica Sand and Ground Silica Product Description: Crystalline Silica 11. Identification of the substance/preparation and of the company/undertaking 1.1. Identification of the substance or preparation Product Name/Trade Names: Sand and Ground Silica Sand (flour) sold under various names: ASTM TESTING SANDS, GLASS SAND' FLINT SILICA' DM-SERIES • F-SERIES • FOUNDRY SANDS· FJ-SERIES • H-SERIES' L-SERIES • N-SERIES' NJ SERIES, OK-SERIES' P-SERIES· T-SERIES' HYDRAULIC FRACING SANDS, MIN-U-SIL® Fine Ground Silica' MYSTIC WHITE® • #1 DRY' #1 SPECIAL' PENN SAND® • Q-ROK® • SIL-CO-SIL® Ground Silica' Supersil® • MASON SAND· GS SERIES' PER-SPEC Chemical Name or Synonym: Silicon Dioxide (SiOz). Sand, Silica Sand, Quartz, Crystalline Silica, Flint, Ground Silica (flour). White or tan sand or ground silica with no odor. 1.2. Use of the Substance / Preparation Main Applications (non-exhaustive list): abrasives, brick, ceramics, foundry castings, glass, grout, hydraulic frac (proppant) sand, mortar, paint and coatings, silicate chemistry, silicone rubber, thermoset plastics. 1.3. Company / Producer U.S. Silica Company P.O. Box 187 106 Sand Mine Road Berkeley Springs, West Virginia 25411 U.S.A. Phone: 304-258-2500 Emergency Phone: 304-258-2500 Fax: 304-258-8295 1 2. Hazards Identification 2.1. EMERGENCY OVERVIEW: The U. S. Silica Company material is a white or tan sand, or ground sand. It is not flammable, combustible or explosive. -
High Hazard Chemical Policy
Environmental Health & Safety Policy Manual Issue Date: 2/23/2011 Policy # EHS-200.09 High Hazard Chemical Policy 1.0 PURPOSE: To minimize hazardous exposures to high hazard chemicals which include select carcinogens, reproductive/developmental toxins, chemicals that have a high degree of toxicity. 2.0 SCOPE: The procedures provide guidance to all LSUHSC personnel who work with high hazard chemicals. 3.0 REPONSIBILITIES: 3.1 Environmental Health and Safety (EH&S) shall: • Provide technical assistance with the proper handling and safe disposal of high hazard chemicals. • Maintain a list of high hazard chemicals used at LSUHSC, see Appendix A. • Conduct exposure assessments and evaluate exposure control measures as necessary. Maintain employee exposure records. • Provide emergency response for chemical spills. 3.2 Principle Investigator (PI) /Supervisor shall: • Develop and implement a laboratory specific standard operation plan for high hazard chemical use per OSHA 29CFR 1910.1450 (e)(3)(i); Occupational Exposure to Hazardous Chemicals in Laboratories. • Notify EH&S of the addition of a high hazard chemical not previously used in the laboratory. • Ensure personnel are trained on specific chemical hazards present in the lab. • Maintain Material Safety Data Sheets (MSDS) for all chemicals, either on the computer hard drive or in hard copy. • Coordinate the provision of medical examinations, exposure monitoring and recordkeeping as required. 3.3 Employees: • Complete all necessary training before performing any work. • Observe all safety -
Abrin Fact Sheet
ABRIN FACT SHEET What is abrin? Abrin is a natural poison that is found in the seeds of a plant called rosary pea. Abrin can be made in the form of a powder, a mist and a pellet, or it can be dissolved in water. Abrin is a stable substance that can last for a long time in the environment regardless of extreme hot or cold temperature conditions. Avoid exposure to abrin because there is no antidote that exists. How can you be exposed to abrin? It will take a deliberate act to obtain abrin from rosary pea seeds and use it to poison people. Breathing in abrin (mist or powder) can expose you. You could be exposed if you touch any surfaces where the particles or droplets have landed or if the droplets have landed on your skin or in your eyes. You could ingest abrin if it is in the food or water. Abrin poisoning is not contagious. It cannot be spread from one person to another through casual contact. What are the immediate symptoms of exposure to abrin? If you inhale abrin, within a few hours you may have the following symptoms: difficulty breathing, fever, cough, nausea, heavy sweating, tightness in the chest and fluid building up in the lungs. If you ingest a large amount of abrin, you will develop vomiting and diarrhea that may become bloody. Next, severe dehydration followed by low blood pressure. Other symptoms may include hallucinations, seizures and blood in the urine. If you have skin and eye exposure, the mist or powder abrin can cause redness and pain of the skin and the eyes. -
Chlorine Trifluoride Ctf
CHLORINE TRIFLUORIDE CTF CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: 99+% Common Synonyms Liquefied compressed Greenish yellow liquid Strong sweetish Not flammable, but may cause fire on 7.2 Storage Temperature: Ambient CTF gas or colorless gas odor contact with some materials. 7.3 Inert Atmosphere: No requirement 4.2 Flammable Limits in Air: Not pertinent 7.4 Venting: Safety relief Sinks and may boil in water. Reacts violently with water to produce 4.3 Fire Extinguishing Agents: Dry chemical 7.5 IMO Pollution Category: Currently not available poisonous gas. Boiling point is 53°F. 4.4 Fire Extinguishing Agents Not to Be Used: Do not use water on adjacent fires 7.6 Ship Type: Currently not available KEEP PEOPLE AWAY. AVOID CONTACT WITH LIQUID AND VAPOR. unless well protected against hydrogen 7.7 Barge Hull Type: Currently not available Avoid inhalation. fluoride gas. Wear chemical protective suit with self-contained breathing apparatus. 4.5 Special Hazards of Combustion Evacuate area in case of large discharge. Products: If released from container, 8. HAZARD CLASSIFICATIONS Call fire department. fumes are toxic and irritating. 8.1 49 CFR Category: Poison Gas Notify local health and pollution control agencies. 4.6 Behavior in Fire: If released from 8.2 49 CFR Class: 2.3 Protect water intakes. container, can increase the intensity of 8.3 49 CFR Package Group: Not pertinent. fire. Containers may explode. Not flammable. 8.4 Marine Pollutant: No Fire May explode on contact with combustibles. 4.7 Auto Ignition Temperature: Not pertinent 8.5 NFPA Hazard Classification: Not listed POISONOUS GASES ARE PRODUCED WHEN HEATED.