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Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date 17.04.2015 Version Number 2 Revision: 17.04.2015

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Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date 17.04.2015 Version Number 2 Revision: 17.04.2015 Page 1/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 * SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Galvanic bath · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Wieland Dental + Technik GmbH & Co. KG Lindenstr. 2 75175 Pforzheim Telefon +49 (0) 7231-37050, Telefax +49 (0) 7231-357959 · Further information obtainable from: [email protected] · 1.4 Emergency telephone number: GIZ-Nord, Göttingen, Germany +49 551 19240 Member of EPECS Network * SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS06 skull and crossbones Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 1 H310 Fatal in contact with skin. Acute Tox. 3 H331 Toxic if inhaled. GHS05 corrosion Skin Corr. 1C H314 Causes severe skin burns and eye damage. GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC T+; Very toxic R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. C; Corrosive R34: Causes burns. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R32: Contact with acids liberates very toxic gas. · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. (Contd. on page 2) GB 40.0 Page 2/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l (Contd. of page 1) · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05 GHS06 GHS09 · Signal word Danger · Hazard-determining components of labelling: potassium cyanide silver cyanide potassium carbonate · Hazard statements H300+H310 Fatal if swallowed or in contact with skin. H331 Toxic if inhaled. H314 Causes severe skin burns and eye damage. H411 Toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH032 Contact with acids liberates very toxic gas. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. * SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 151-50-8 potassium cyanide 5-10% EINECS: 205-792-3 T+ R26/27/28; N R50/53 R32 Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 2, H330; Aquatic Acute 1, H400; Aquatic Chronic 1, H410 (Contd. on page 3) GB 40.0 Page 3/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l (Contd. of page 2) CAS: 584-08-7 potassium carbonate 1-5% EINECS: 209-529-3 Xn R22; Xi R36/37/38 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335 CAS: 506-64-9 silver cyanide ≤ 5% EINECS: 208-048-6 T+ R26/27/28; N R50/53 R32 Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 2, H330; Aquatic Acute 1, H400; Aquatic Chronic 1, H410 · Additional information: For the wording of the listed risk phrases refer to section 16. * SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Immediately remove any clothing soiled by the product. In case of irregular breathing or respiratory arrest provide artificial respiration. · After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · Hazards Danger of circulatory collapse. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. * SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. · 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Hydrogen cyanide (HCN) · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. * SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. (Contd. on page 4) GB 40.0 Page 4/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l (Contd. of page 3) · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. · Information about fire - and explosion protection: Keep respiratory protective device available. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store only in the original receptacle. · Information about storage in one common storage facility: Do not store together with acids. Storage class 6.1 B (Non-combustible acutely toxic Cat. 1 and 2 substances) Only substances of the same storage class should be stored together. Collocated storage with the following substances is prohibited: - Pharmaceuticals, foods, and animal feeds including additives. - Infectious, radioactive und explosive substances. - Gases. - Flammable liquids of storage class 3. - Other explosive substances of storage class 4.1A. - Flammable solid substances or desensitized substances of storage class 4.1B. - Spontaneously flammable substances. - Substances liberating flammable gases in contact with water. - Strongly oxidizing substances of storage class 5.1A. - Ammonium nitrate and preparations containing ammonium nitrate. - Organic peroxides and self reactive substances. Under certain conditions the collocated storage with the following sub-stances is permitted (For more details see TRGS 510): - Oxidizing substances of storage class 5.1B. - Combustible solids of storage class 11. The substance should not be stored with substances with which ha-zardous chemical reactions are possible. (e.g. acids) · Further information about storage conditions: Keep receptacle tightly sealed. Store under lock and key and with access restricted to technical experts or their assistants only. · Storage class: LGK 6.1B · 7.3 Specific end use(s) No further relevant information available. * SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · DNELs 506-64-9 silver cyanide Oral DNEL(Com.)longterm 0.05 mg/kg (-) (CN) (Contd. on page 5) GB 40.0 Page 5/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l (Contd. of page 4) DNEL(Comm.)akut 4.5 mg/kg (-) (CN) DNEL(Indust.)longt. 0.05 mg/kg (-) (CN) DNEL(Industrie) akut 4.5 mg/kg (-) (CN) · PNECs 506-64-9 silver cyanide PNEC (Commercial) 0.03 µg/l (H2O) (CN) PNEC (Industrie) 0.03 µg/l (H2O) (CN) · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work.
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