Standard X-Ray Diffraction Powder Patterns
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Picromerite K2mg(SO4)2 • 6H2O C 2001-2005 Mineral Data Publishing, Version 1
Picromerite K2Mg(SO4)2 • 6H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Equant crystals, to 5 cm, showing {001}, {010}, {100}, {110}, {011}, {201}, {111}, several other forms; incrusting other salts; massive. Physical Properties: Cleavage: On {201}, perfect (synthetic). Hardness = 2.5 D(meas.) = 2.028 (synthetic). D(calc.) = 2.031 Soluble in H2O, taste bitter. Optical Properties: Transparent. Color: Colorless or white; pale red, pale yellow, gray due to impurities; colorless in transmitted light. Luster: Vitreous. Optical Class: Biaxial (+). Orientation: Y = b; X ∧ a =–1◦. Dispersion: r> v,weak. α = 1.461 β = 1.463 γ = 1.476 2V(meas.) = 47◦540 Cell Data: Space Group: P 21/a (synthetic). a = 9.066 b = 12.254 c = 6.128 β = 104◦470 Z=2 X-ray Powder Pattern: Synthetic. 3.71 (100), 4.06 (95), 4.16 (85), 3.06 (70), 2.964 (60), 3.16 (40), 2.813 (40) Chemistry: (1) (2) SO3 39.74 39.76 MgO 10.40 10.01 K2O 23.28 23.39 Cl 0.28 H2O 26.87 26.84 −O=Cl2 [0.06] Total [100.51] 100.00 • (1) Leopoldshall, Germany. (2) K2Mg(SO4)2 6H2O. Mineral Group: Picromerite group. Occurrence: Principally occurs in oceanic bedded salt deposits; a volcanic sublimate in fumaroles; in a sulfate-rich hydrothermal ore deposit. Association: Halite, anhydrite, kainite, epsomite (oceanic salt deposits); hohmannite, metavoltine, metasideronatrite (Chuquicamata, Chile). Distribution: From Vesuvius, Campania, Italy. In Germany, in Saxony-Anhalt, from the Leopoldshall-Stassfurt district, and at Aschersleben; large crystals from the Ellers mine, Neuhof, near Fulda, Hessen; in the Adolfsgl¨uck mine, Schwarmstedt, Lower Saxony. -
Lithium Carbonate
Right to Know Hazardous Substance Fact Sheet Common Name: LITHIUM CARBONATE Synonyms: Dilithium Carbonate; Carbolith CAS Number: 554-13-2 Chemical Name: Carbonic Acid, Dilithium Salt RTK Substance Number: 1124 Date: September 1998 Revision: January 2008 DOT Number: None Description and Use EMERGENCY RESPONDERS >>>> SEE BACK PAGE Lithium Carbonate is a white, light, odorless powder. It is Hazard Summary used in the production of glazes on ceramics and porcelain, in Hazard Rating NJDOH NFPA varnishes and dyes, as a coating on arc welding electrodes, HEALTH 1 - and in lubricating greases. It is also used as medication to FLAMMABILITY 0 - treat certain types of mental illness. REACTIVITY 0 - TERATOGEN POISONOUS GASES ARE PRODUCED IN FIRE Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; 4=severe Reasons for Citation f Lithium Carbonate is on the Right to Know Hazardous f Lithium Carbonate can affect you when inhaled. Substance List because it is cited by DEP and EPA. f Lithium Carbonate may be a TERATOGEN. HANDLE f This chemical is on the Special Health Hazard Substance List. WITH EXTREME CAUTION. f Contact can irritate the skin and eyes. f Inhaling Lithium Carbonate can irritate the nose and throat. f Lithium Carbonate can cause nausea, vomiting, diarrhea and abdominal pain. f Inhaling Lithium Carbonate can irritate the lungs. Higher exposures may cause a build-up of fluid in the lungs SEE GLOSSARY ON PAGE 5. (pulmonary edema), a medical emergency. f Lithium Carbonate can cause headache, muscle FIRST AID weakness, confusion, seizures and coma. Eye Contact f Lithium Carbonate may cause a skin allergy. -
Lithium Carbonate
SAFETY DATA SHEET Creation Date 26-Sep-2009 Revision Date 18-Jan-2018 Revision Number 3 1. Identification Product Name Lithium Carbonate Cat No. : L119-500 CAS-No 554-13-2 Synonyms carbonic acid lithium salt; Carbonic Acid Dilithium Salt Recommended Use Laboratory chemicals. Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute oral toxicity Category 4 Skin Corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system, Central nervous system (CNS). Label Elements Signal Word Danger Hazard Statements Harmful if swallowed Causes skin irritation Causes serious eye damage May cause respiratory irritation ______________________________________________________________________________________________ Page 1 / 7 Lithium Carbonate Revision Date 18-Jan-2018 ______________________________________________________________________________________________ Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. -
Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date 17.04.2015 Version Number 2 Revision: 17.04.2015
Page 1/10 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.04.2015 Version number 2 Revision: 17.04.2015 * SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Arcuplat Schnellversilberung m. 30g Ag/l Arcuplat silver bath with 30 g Ag/l · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Galvanic bath · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Wieland Dental + Technik GmbH & Co. KG Lindenstr. 2 75175 Pforzheim Telefon +49 (0) 7231-37050, Telefax +49 (0) 7231-357959 · Further information obtainable from: [email protected] · 1.4 Emergency telephone number: GIZ-Nord, Göttingen, Germany +49 551 19240 Member of EPECS Network * SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS06 skull and crossbones Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 1 H310 Fatal in contact with skin. Acute Tox. 3 H331 Toxic if inhaled. GHS05 corrosion Skin Corr. 1C H314 Causes severe skin burns and eye damage. GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC T+; Very toxic R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. C; Corrosive R34: Causes burns. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. -
Mineralogical Chemistry
View Article Online / Journal Homepage / Table of Contents for this issue 282 ABSTRACTS OF CHEMICAL PAPERS. Downloaded on 22 February 2013 Published on 01 January 1900 http://pubs.rsc.org | doi:10.1039/CA9007805282 Mineralogical Chemistry. Roumanian Petroleuws. By A LFONS 0. SALIGNY(Chem. Centy., 1900, 60 ; from Bul. Bozcmccnie, 8, 351 --365).-In the original paper, the physical and chemical properties of 12 kinds of Roumanian MINERALOGICAL CHEMISTRY View Article Online283 petroleum are described and tabulated. The flash points of the various fractions are given, and their suitability for use as burning oils is also discussed. These petroleums contain very variable amounts of volatile oils, and ethylisobutane and isopropane were found in the fractions boiling below 70”. E. w. w. Melonite from South Australia. By ALFREDJ. HIGGIN(Trans. Roy. Xoc. South Austdia, 1899, 23, 21 1-212).-This mineral, pre- viously only known from California, has now been found with quartz and calcite at Worturpa, South Australia. The thin lamells have a brilliant metallic lustre; the cleavage planes are silver-white to reddish- brown. H- 1.5 ; sp. gr., 7.6. Analyses I and IT: agree with the formula Ni,Te, (compare this vol., ii, 22). Te. Xi. Au. Insol. Total. I. 74.49 22.99 0.329 2.091 99.90 11. 71.500 21.274 0.018 7*319 100.11 Traces of bismuth and lead are present. On dissolving the mineral in nitric acid, the gold is left as bright spangles. L. J. S. Titaniferous Magnetites. By JAMESF. KENP(School of Mines Quart., 1899, 20, 323-356 ; 21, 56-65).-Titaniferous magnetites, with the exception of the occnrrences in sands, are almost invariably found associated with rocks of the gabbro type, and have originated by a process of segregation from the magma, The mineral, as a rule, contains vanadium, cbromium, nickel and cobalt, which together may amount to several per cent. -
Lithium Sulfate
SIGMA-ALDRICH sigma-aldrich.com Material Safety Data Sheet Version 4.1 Revision Date 09/14/2012 Print Date 03/12/2014 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Lithium sulfate Product Number : 203653 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For : (314) 776-6555 both supplier and manufacturer) Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region 1-800-521-8956 2. HAZARDS IDENTIFICATION Emergency Overview OSHA Hazards Target Organ Effect, Harmful by ingestion. Target Organs Central nervous system, Kidney, Cardiovascular system. GHS Classification Acute toxicity, Oral (Category 4) GHS Label elements, including precautionary statements Pictogram Signal word Warning Hazard statement(s) H302 Harmful if swallowed. Precautionary none statement(s) HMIS Classification Health hazard: 1 Chronic Health Hazard: * Flammability: 0 Physical hazards: 0 NFPA Rating Health hazard: 1 Fire: 0 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Aldrich - 203653 Page 1 of 7 Skin Harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Ingestion Harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula : Li2O4S Molecular Weight : 109.94 g/mol Component Concentration Lithium sulphate CAS-No. 10377-48-7 - EC-No. 233-820-4 4. FIRST AID MEASURES General advice Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. -
Download Author Version (PDF)
Journal of Materials Chemistry A Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/materialsA Page 1 of 9 Journal of Materials Chemistry A ARTICLE JMCA Safer Salts for CdTe Nanocrystal Solution Processed Solar Cells: The Dual Roles of Ligand Exchange and Grain Growth Received 00th January 20xx, a b c d e Accepted 00th January 20xx Troy K. Townsend, † William B. Heuer, Edward E. Foos, Eric Kowalski, Woojun Yoon and Joseph G. Tischler e DOI: 10.1039/x0xx00000x Inorganic CdSe/CdTe nanocrystals for solid-state photovoltaic devices are typically sintered into a bulk-like material after www.rsc.org/ annealing in the presence of solid cadmium chloride. -
Management and Treatment of Lithium-Induced Nephrogenic Diabetes Insipidus
REVIEW Management and treatment of lithium- induced nephrogenic diabetes insipidus Christopher K Finch†, Lithium carbonate is a well documented cause of nephrogenic diabetes insipidus, with as Tyson WA Brooks, many as 10 to 15% of patients taking lithium developing this condition. Clinicians have Peggy Yam & Kristi W Kelley been well aware of lithium toxicity for many years; however, the treatment of this drug- induced condition has generally been remedied by discontinuation of the medication or a †Author for correspondence Methodist University reduction in dose. For those patients unresponsive to traditional treatment measures, Hospital, Department several pharmacotherapeutic regimens have been documented as being effective for the of Pharmacy, University of management of lithium-induced diabetes insipidus including hydrochlorothiazide, Tennessee, College of Pharmacy, 1265 Union Ave., amiloride, indomethacin, desmopressin and correction of serum lithium levels. Memphis, TN 38104, USA Tel.: +1 901 516 2954 Fax: +1 901 516 8178 [email protected] Lithium carbonate is well known for its wide use associated with a mutation(s) of vasopressin in bipolar disorders due to its mood stabilizing receptors. Acquired causes are tubulointerstitial properties. It is also employed in aggression dis- disease (e.g., sickle cell disease, amyloidosis, orders, post-traumatic stress disorders, conduct obstructive uropathy), electrolyte disorders (e.g., disorders and even as adjunctive therapy in hypokalemia and hypercalcemia), pregnancy, or depression. Lithium has many well documented conditions induced by a drug (e.g., lithium, adverse effects as well as a relatively narrow ther- demeclocycline, amphotericin B and apeutic range of 0.4 to 0.8 mmol/l. Clinically vincristine) [3,4]. Lithium is the most common significant adverse effects include polyuria, mus- cause of drug-induced nephrogenic DI [5]. -
Chemical List
1 EXHIBIT 1 2 CHEMICAL CLASSIFICATION LIST 3 4 1. Pyrophoric Chemicals 5 1.1. Aluminum alkyls: R3Al, R2AlCl, RAlCl2 6 Examples: Et3Al, Et2AlCl, EtAlCl2, Me3Al, Diethylethoxyaluminium 7 1.2. Grignard Reagents: RMgX (R=alkyl, aryl, vinyl X=halogen) 8 1.3. Lithium Reagents: RLi (R = alkyls, aryls, vinyls) 9 Examples: Butyllithium, Isobutyllithium, sec-Butyllithium, tert-Butyllithium, 10 Ethyllithium, Isopropyllithium, Methyllithium, (Trimethylsilyl)methyllithium, 11 Phenyllithium, 2-Thienyllithium, Vinyllithium, Lithium acetylide ethylenediamine 12 complex, Lithium (trimethylsilyl)acetylide, Lithium phenylacetylide 13 1.4. Zinc Alkyl Reagents: RZnX, R2Zn 14 Examples: Et2Zn 15 1.5. Metal carbonyls: Lithium carbonyl, Nickel tetracarbonyl, Dicobalt octacarbonyl 16 1.6. Metal powders (finely divided): Bismuth, Calcium, Cobalt, Hafnium, Iron, 17 Magnesium, Titanium, Uranium, Zinc, Zirconium 18 1.7. Low Valent Metals: Titanium dichloride 19 1.8. Metal hydrides: Potassium Hydride, Sodium hydride, Lithium Aluminum Hydride, 20 Diethylaluminium hydride, Diisobutylaluminum hydride 21 1.9. Nonmetal hydrides: Arsine, Boranes, Diethylarsine, diethylphosphine, Germane, 22 Phosphine, phenylphosphine, Silane, Methanetellurol (CH3TeH) 23 1.10. Non-metal alkyls: R3B, R3P, R3As; Tributylphosphine, Dichloro(methyl)silane 24 1.11. Used hydrogenation catalysts: Raney nickel, Palladium, Platinum 25 1.12. Activated Copper fuel cell catalysts, e.g. Cu/ZnO/Al2O3 26 1.13. Finely Divided Sulfides: Iron Sulfides (FeS, FeS2, Fe3S4), and Potassium Sulfide 27 (K2S) 28 REFERRAL -
Boiling Rubidium A8 a Reactor : Coolant
UNITED STATES ATOMlC ENERGY CUMMISSiON -F - - 71013 BOILING RUBIDIUM A8 A REACTOR : COOLANT. PREPARkTION OF RUBDIUM adETAL, PHYBICAL AND 33PBER.MO~AMIcC PROFERTLES, AND COMPATIBILITY WITH INCONEL , technical Infor~ionEx?snsion, Oak Ridgs, Timnessee DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. This mprt em~~$utrraf 2 gtwks, Pcljrt I asd Pea*t 11. *. .I. I *** .* ** . ... .. : :: . :*:. *::: /f- 8. .* .*** . e.. 0.. .* 0.. * *. 0... 0.. *I *to.. 0 *a ** . ..a . .a* .* - -8 OPSE RIDCE SCHOOL OF REACTOR TECHNOUXY ''BOI~RUBIDIUM AS A BEACTOR.COOLANT : , PREPAMTION OF RUBIDIUM METALg PHYSICAL AND THERMJDYNAMIC PROPERTIESg AND COMPATIBILI!PY WII"H INCONEX" This report cont~insinformaticg. geiierated by E. group of @$SORT students under .the leadershim df S; Reed Nixon aa part of an assigned summer project. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
The Mineralogy of the British Permian Evaporites
460 The mineralogy of the British Permian evaporites By F. H. STEWART Department of Geology, University of Edinburgh Summary. The occurrence of the minerals is reviewed. Consideration of their genesis leads to a tentative list of primary minerals, and of early diagenetie, later diagenetic and geothermal metamorphic, and late near-surface changes. N 1943 Professor Tilley recorded the occurrence of po]yhalite in the I rocks of the D'Arcy Exploration Company's E.2 borehole at Aislaby, near Whitby; this was the first published record of a potassium-bearing salt in British evaporites. The occurrence of rocks containing sylvine (Lees and Taitt, 1946) prompted further exploration by Imperial Chemical Industries and Fisons Ltd. after the war, and this showed the presence of large deposits of potassium ores in the Whitby region. There is now a considerable literature related to these, and it seems timely to give a short review of the mineralogy of the British Permian evaporites. The writer is most grateful to Fisons Ltd. who have kindly allowed him to use unpublished information from his study of their boreholes F.1 at Robin Hood's Bay, F.2 at Staintondale, F.3 at Little Beck, and F.4 at Hawsker, in the Whitby Scarborough district. The position of these and the other boreholes mentioned in this paper can be found in the map of Dunham (1960). Dist~'ibution of the minerals The evaporites occur in two principal areas east and west of the Pennine Hills. In the western area (the Vale of Eden, west Cumberland, and the Furness district of Lancashire), where four evaporite beds have been recognized (Hollingworth, 1942), the mineralogy is relatively simple; carbonates, anhydrite, and gypsum are the main constituents.