Poraz® an Emulsifiable Concentrate Containing 450 G/Litre Prochloraz

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MAPP 11701 An emulsifiable concentrate containing 450 g/litre (39.8% w/w) prochloraz. PorazA broad-spectrum fungicide for use on wheat, barley, winter rye and winter oilseed rape. The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. SAFETY PRECAUTIONS Environmental protection Do not contaminate surface waters or ditches with Operator protection Engineering control of operator exposure must be used chemical or used container. where reasonably practicable in addition to the following Storage and disposal personal protective equipment: DO NOT RE-USE CONTAINER for any purpose. WEAR SUITABLE PROTECTIVE GLOVES AND FACE KEEP AWAY FROM FOOD, DRINK AND ANIMAL PROTECTION (FACESHIELD) when handling the FEEDING STUFFS. concentrate. KEEP OUT OF REACH OF CHILDREN. However, engineering controls may replace personal KEEP IN ORIGINAL CONTAINER, tightly closed in a protective equipment if a COSHH assessment shows safe place. that they provide an equal or higher standard of WASH OUT CONTAINER THOROUGHLY, empty protection. washings into spray tank and dispose of safely. WHEN USING DO NOT EAT, DRINK OR SMOKE. Store in a safe, dry, frost-free place designated as an WASH CONCENTRATE from skin or eyes immediately. agrochemical store. WASH HANDS AND EXPOSED SKIN before meals PROTECT FROM FROST. and after work. IF YOU FEEL UNWELL, seek medical advice (show leaflet where possible). This label is compliant UN 3082 with the CPA Voluntary Packing Group III Initiative Guidance Environmentally hazardous substance, liquid, N.O.S. (contains solvent naphtha, prochloraz 40%) L Marine Pollutant 5Supplied by: BASF plc Crop Protection PO Box 4, Earl Road Cheadle Hulme, CHEADLE Cheshire SK8 6QG Tel: 0161 485 6222 Emergency Information: (24 hours freephone): 0049 180 2273112 Technical Enquiries: 0845 602 2553 (office hours) 81075028GB1033 ® = Registered trademark of BASF Poraz® An emulsifiable concentrate containing 450 g/litre prochloraz.

HARMFUL IF SWALLOWED MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS CAUSES SERIOUS EYE IRRITATION REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING CAUSES SKIN IRRITATION VERY TOXIC TO AQUATIC LIFE VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS WEAR PROTECTIVE GLOVES AND EYE / FACE PROTECTION IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF ON SKIN: WASH WITH PLEANTY OF SOAP AND WATER. IF SWALLOWED: IMMEDIATELY CALL POISONS CENTRE OR DOCTOR / PHYSICIAN. DO NOT INDUCE VOMITING. DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL REGULATIONS.

To avoid risks to human health and the environment, comply with the instructions for use.

This product is approved under the Control Of Pesticide Regulations 1986.

IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE, as directed below: Crops Maximum Maximum Maximum Latest Time Individual Number of Total Dose of Application Dose Treatments Wheat, Barley, 0.9 litres product / 2 per crop – Before grain milky ripe Winter rye. hectare stage and 6 weeks before harvest. Winter oilseed 1.0 litre product / – 2.0 litres product / 6 weeks before harvest. rape. hectare hectare / crop READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS. DIRECTIONS FOR USE IMPORTANT: This leaflet is approved as part of the label. All instructions on this leaflet and on the label should be read carefully in order to obtain successful results from the use of this product. All varieties of wheat, barley, winter rye and winter oilseed rape may be sprayed with Poraz.

1. Restrictions/Warnings A period of at least 3 hours (or longer in poor drying conditions) without rain should follow spraying otherwise results may be reduced. Avoid drift to areas outside those being sprayed having due regard to the prevailing weather conditions and spray quality being used. Tank-mixtures of Poraz with other fungicides should not be applied to crops suffering from any other stress such as drought or waterlogging otherwise the crop may suffer some scorch from which recovery may not be complete. Yellow and Brown rust are not effectively controlled by Poraz.

2. Disease Control Poraz controls or gives protection against all the following diseases when applied as recommended: Winter Wheat Eyespot Glume blotch (Septoria nodorum) Leaf spot (Septoria tritici ) Powdery mildew Spring Wheat Powdery mildew Spring and Winter Barley Eyespot (Winter barley) Leaf blotch (Rhynchosporium) Net blotch Powdery mildew

Winter Rye Eyespot Leaf blotch (Rhynchosporium) Leaf spot (Septoria) Powdery mildew Adequate protection of winter cereals throughout the season against all the diseases listed above will usually require a programme of at least two fungicide treatments (see Timing section). Winter oilseed rape Dark leaf / pod spot (Alternaria brassicae) (reduction only) Light leaf spot (Cylindrosporium brassicae) Grey mould (Botrytis cinerea) Leaf spot / stem canker (Phoma lingam) Stem rot (Sclerotinia sclerotiorum) (moderate control) White leaf spot (Pseudocercosporella capsellae) 2.1 Resistance management Poraz contains a DMI fungicide. Resistance to some DMI fungicides has been identified in Septoria leaf blotch (Mycosphaerella graminicola) which may seriously affect the performance of some products. For further advice on resistance management in DMIs contact your agronomist or specialist adviser, and visit the FRAG-UK website. To reduce the risk of development of resistance, do not apply more than two full dose prochloraz- based treatments (oilseed rape, wheat, barley and rye) or for oilseed rape only, 2 split doses followed by a full dose. Use Poraz as part of an integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate, other fungicides with a different mode of action.

3. Crops Time of Application 3.1 Cereals Autumn sown wheat, autumn and spring sown barley and winter rye 3.1.1 Eyespot Control Spray in the spring, from when the leaf sheaths begin to become erect until the third node is detectable. Any over-wintering eyespot or Rhynchosporium, and mildew on rye or barley will be controlled by Poraz applied at this time, and protection will be given against Septoria (wheat, rye) or net blotch (barley). If weather conditions continue to favour eyespot development after treatment, a second spray may be necessary 4 to 6 weeks later. Poraz sprayed for control of eyespot (Pseudocercosporella) will often give good reduction of sharp eyespot (Rhizoctonia) and Fusarium if these diseases are developing at the time of application, but it is not yet known when this effect is likely to be of benefit. 3.1.2 Foliar Disease Control For protection against leaf spot (Septoria tritici ), glume blotch (Septoria nodorum) and powdery mildew on winter wheat, spray as soon as the ligule of the last leaf is visible if any of these diseases are present in the crop. If no disease is present, treatment should be delayed until the first signs of infection appear or Poraz should be applied as a protectant treatment at the end of ear emergence if the crop is still disease free. Best protection against ear diseases is achieved only by treatment at full ear emergence. For control of late infections of barley leaf diseases listed above including protection against net blotch; spray when disease appears on new growth, or as a protectant treatment when the ligule of the last leaf is visible if any of the diseases are present in the bottom of the crop. On spring wheat, spray if mildew begins to build up in the crop if this occurs before full ear emergence. For control of late infections of the rye leaf diseases listed above, spray if disease is present in the crop. Yellow and Brown rust are not effectively controlled by Poraz. If rust is present or anticipated on barley or on wheat a tank-mixture of Poraz with Corbel will give control and protection against further attack. 3.1.3 Autumn treatment – barley For the control of mildew and Rhynchosporium and protection against net blotch in the autumn, spray at the onset of disease infection. To achieve maximum yield response it is essential the autumn application is followed by spring application. If only net blotch is present a reduced dose of 0.7 l/ha may be used. Latest time of application: Up to before grain milky ripe (GS71) and six weeks before harvest.

3.2 Winter oilseed rape Diseases of oilseed rape can develop and spread very rapidly. It is therefore important that crops are regularly inspected so as to detect sudden increases in disease levels. Poraz should be applied at the onset of disease development so as to contain the diseases at a low level and prevent them spreading. Poraz controls or gives protection against all the following diseases when applied as recommended: 3.2.1 Light Leaf Spot (Cylindrosporium brassicae) Poraz should be applied at the first sign of light leaf spot in the autumn or winter when cool wet conditions favour spread of the disease. A split dose treatment may be used. A Poraz application during or shortly after flowering will prolong the control of light leaf spot where there is a risk of late build up of disease. 3.2.2 Dark Leaf / Pod Spot (Alternaria brassicae) Alternaria mainly develops through the spring and summer, especially following hot humid weather. Apply Poraz as soon as Alternaria infection is seen on the upper leaves and stems, usually from mid-flowering but not later than the mottled seed stage. If disease pressure remains high, a second application of Poraz should be applied 2-3 weeks later. Poraz only gives a reduction of this disease. 3.2.3 Leaf Spot / Stem Canker (Phoma lingam) Phoma leaf spot is spread by rain splash and can be found from October onwards. Apply Poraz at the first sign of infection during the autumn or winter. 3.2.4 Stem Rot (Sclerotinia sclerotiorum) The spread of Sclerotinia is favoured by wet weather during flowering. For moderate control of the disease, spray Poraz from early flowering in high risk situations when spore release is occurring. Control is only achieved if Poraz is applied before the disease becomes established. 3.2.5 Grey Mould (Botrytis cinerea) Poraz may give control of grey mould, and should be applied as soon as Botrytis develops from stem extension onwards and if the infection continues, apply a second spray during or after flowering. 3.2.6 White Leaf Spot (Pseudocercosporella capsellae) Apply Poraz in the spring from stem extension, when infection is seen on the leaves and before it spreads onto the pods. Latest time of application: 6 weeks before harvest.

3.3 Rate of Application Wheat, Barley and Winter Rye: Maximum Individual Dose: 0.9 l/ha. Maximum Number of Treatments (per crop): 2. For broad-spectrum disease control use 0.9 l/ha. For control of Net Blotch only (Barley) use 0.7 l/ha. For control of established Mildew and / or Rust (Wheat and Barley) use 0.9 l/ha Poraz + 1 l/ha Corbel. A fungicide with a different mode of action to prochloraz should be used for further disease control.

Winter Oilseed Rape Maximum Individual Dose: 1.0 l/ha. Maximum Number of Treatments (per crop): 2 at normal dose, or 2 at split dose followed by one application at normal dose. The maximum total dose must not exceed 2.0 l product/hectare/crop. For broad-spectrum disease control use 1.0 l/ha. Split dose treatment – to control Light Leaf Spot only use 0.45 l/ha applied in autumn followed by 0.7 l/ha Poraz applied in spring when conditions favour disease spread. A fungicide with a different mode of action to prochloraz should be used for further disease control. 4. Mixing and Spraying Apply Poraz in 200–400 litres of water per hectare. In dense crops or for the second treatment, the volume should be increased to 400 litres per hectare. Apply as a MEDIUM quality spray. (For details see Boom Sprayers Handbook published by British Crop Protection Council). Poraz should be applied to give good foliar cover. Adjust the boom height to give the correct height above target; alternate spray fans or cones should meet just above the top of the crop. Even cover with a well mixed spray is essential for good results. Forward speed should not exceed 10 km/hour (6 mph). Check that the sprayer, spray bars and nozzles have been properly washed out to remove traces of the previous chemical. Ensure that the sprayer has been carefully calibrated. Nozzles should be selected to give MEDIUM spray quality. Half-fill the sprayer tank with clean water and start agitating. Add the required quantity of Poraz and complete filling to the final volume. Spray immediately after mixing and maintain agitation until the spray tank is empty. Even cover with a well- mixed spray is essential for good results. Wash out the sprayer with water and liquid detergent immediately after use. Finally wash out with water and drain.

The following does not form part of the product label under the Control of Pesticides Regulations 1986. With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop- and use- connected ways of influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to. Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law. Section 6 of the Health and Safety at Work Act Additional Product Safety Information The product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has “off-label” approval or is otherwise permitted under the Control of Pesticides Regulations. The information on this label is based on the best available information including data from test results. Safety data sheet 1. Identiﬁ cation of the substance/mixture and of the company/undertaking Product identifier PORAZ Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: crop protection product, fungicide Details of the supplier of the safety data sheet Company: BASF SE 67056 Ludwigshafen GERMANY Contact address: BASF plc PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire SK8 6QG, UNITED KINGDOM Telephone: +44 161 485-6222 E-mail address: [email protected] Emergency telephone number International emergency number: Telephone: +49 180 2273-112

2. Hazards Identiﬁ cation Label elements Globally Harmonized System, EU (GHS) Pictogram: Signal Word: Danger Hazard Statement: H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. EUH066 Repeated exposure may cause skin dryness or cracking. H31J Causes skin irritation H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Precautionary Statements (Prevention): P280f Wear protective gloves and eye/face protection. P264 Wash with plenty of water and soap thoroughly after handling. P270 Do no eat, drink or smoke when using this product. Precautionary Statements (Response): P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P330 Rinse mouth. P391 Collect spillage. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: Prochloraz, SOLVENT NAPHTHA According to Directive 67/548/EEC or 1999/45/EC Classification/labelling in accordance with UK regulations. Hazard symbol(s) Xn Harmful. N Dangerous for the environment. R-phrase(s) R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. S-phrase(s) S2 Keep out of the reach of children. S13 Keep away from food, drink and animal feeding stuffs. S20/21 When using do not eat, drink or smoke. S24 Avoid contact with skin. S35 This material and its container must be disposed of in a safe way. S57 Use appropriate container to avoid environmental contamination. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Hazard determining component(s) for labelling: Prochloraz, SOLVENT NAPHTHA Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Asp. Tox. 1 Acute Tox. 4 (oral) Eye Dam./Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Harmful if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. For the classifications not written out in full in this section the full text can be found in section 16. Other hazards According to Regulation (EC) No 1272/2008 [CLP] See section 12 – Results of PBT and vPvB assessment. If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients Mixtures Chemical nature crop protection product, fungicide, Emulsifiable concentrate (EC) This product contains (a) substance(s) included on the candidate list according to article 59 (1,10) of regulation EC No. 1907/2006 (‘REACH’) in a concentration equal or above 0.1% w/w: N-methyl-2- pyrrolidone; 1-methyl-2-pyrrolidone Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Content (W/W): 39.8 % Acute Tox. 4 (oral) CAS Number: 67747-09-5 Aquatic Acute 1 EC-Number: 266-994-5 Aquatic Chronic 1 H302, H400, H410 solvent naphtha Content (W/W): < 40 % Asp. Tox. 1 CAS Number: 64742-94-5 Aquatic Chronic 2 REACH registration number: 01- H411, H304, EUH066 2119451097-39 Calcium bis(dodecylbenzenesulphonate), branched Content (W/W): < 10 % Skin Corr./Irrit. 2 CAS Number: 70528-83-5 Eye Dam./Irrit. 1 EC-Number: 274-654-2 Aquatic Chronic 2 H318, H315, H411 N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone Content (W/W): < 5 % Skin Corr./Irrit. 2 CAS Number: 872-50-4 Eye Dam./Irrit. 2 EC-Number: 212-828-1 Repr. 1B (unborn child) REACH registration number: 01- STOT SE 3 (irr. to respiratory syst.) 2119472430-46 H319, H315, H335, H360D INDEX-Number: 606-021-00-7 2-methylpropan-1-ol; iso-butanol Content (W/W): < 5 % Flam. Liq. 3 CAS Number: 78-83-1 Skin Corr./Irrit. 2 EC-Number: 201-148-0 Eye Dam./Irrit. 1 REACH registration number: 01- STOT SE 3 (drowsiness and dizziness) 2119484609-23 STOT SE 3 (irr. to respiratory syst.) INDEX-Number: 603-108-00-1 H318, H315, H226, H336, H335 Solvent Naphtha light Content (W/W): < 5 % Asp. Tox. 1 CAS Number: 64742-95-6 STOT SE 3 (drowsiness and dizziness) EC-Number: 265-199-0 STOT SE 3 (irr. to respiratory syst.) INDEX-Number: 649-356-00-4 Aquatic Chronic 2 H411, H304, H336, H335 naphthalene Content (W/W): < 0.5 % Acute Tox. 4 (oral) CAS Number: 91-20-3 Carc. 2 EC-Number: 202-049-5 Aquatic Acute 1 INDEX-Number: 601-052-00-2 Aquatic Chronic 1 M-factor acute: 1 M-factor chronic: 1 H302, H400, H410, H351 Hazardous ingredients according to Directive 1999/45/EC N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Content (W/W): 39.8 % CAS Number: 67747-09-5 EC-Number: 266-994-5 Hazard symbol(s): Xn, N R-phrase(s): 22, 50/53 solvent naphtha Content (W/W): < 40 % CAS Number: 64742-94-5 REACH registration number: 01-2119451097-39 Hazard symbol(s): Xn, N R-phrase(s): 65, 66, 51/53 Calcium bis(dodecylbenzenesulphonate), branched Content (W/W): < 10 % CAS Number: 70528-83-5 EC-Number: 274-654-2 Hazard symbol(s): Xi, N R-phrase(s): 38, 41, 51/53 N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone Content (W/W): < 5 % CAS Number: 872-50-4 EC-Number: 212-828-1 REACH registration number: 01-2119472430-46 INDEX-Number: 606-021-00-7 Hazard symbol(s): T R-phrase(s): 61, 36/37/38 Repr. Cat. 2 2-methylpropan-1-ol; iso-butanol Content (W/W): < 5 % CAS Number: 78-83-1 EC-Number: 201-148-0 REACH registration number: 01-2119484609-23 INDEX-Number: 603-108-00-1 Hazard symbol(s): Xi R-phrase(s): 10, 37/38, 41, 67 Solvent Naphtha light Content (W/W): < 5 % CAS Number: 64742-95-6 EC-Number: 265-199-0 INDEX-Number: 649-356-00-4 Hazard symbol(s): Xn, N R-phrase(s): 10, 37, 51/53, 65, 66, 67 naphthalene Content (W/W): < 0.5 % CAS Number: 91-20-3 EC-Number: 202-049-5 INDEX-Number: 601-052-00-2 Hazard symbol(s): Xn, N R-phrase(s): 22, 40, 50/53 Carc. Cat. 3 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid Measures Description of first aid measures Show container, label and/or safety data sheet to physician. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. On skin contact: Immediately wash thoroughly with soap and water, seek medical attention. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Do not induce vomiting due to aspiration hazard. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, carbon dioxide, foam, dry powder Special hazards arising from the substance or mixture carbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Environmental precautions Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters surface or ground waters. Keep people and animals away. Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

7. Handling and Storage Precautions for safe handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Protection against fire and explosion: Vapours may form ignitable mixture with air. Prevent electrostatic charge – sources of ignition should be kept well clear - fire extinguishers should be kept handy. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Further information on storage conditions: Keep away from heat. Protect from direct sunlight. Protect from temperatures below: 0 °C The product can crystallize below the limit temperature. Protect from temperatures above: 30 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parameters Components with occupational exposure limits 872-50-4: N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone TWA value 103 mg/m3 ; 25 ppm (WEL/EH 40 (UK)) STEL value 309 mg/m3 ; 75 ppm (WEL/EH 40 (UK)) Skin Designation (WEL/EH 40 (UK)) The substance can be absorbed through the skin. TWA value 40 mg/m3 ; 10 ppm (OEL (EU)) indicative STEL value 80 mg/m3 ; 20 ppm (OEL (EU)) indicative Skin Designation (OEL (EU)) The substance can be absorbed through the skin. STEL value 80 mg/m3 ; 20 ppm (WEL/EH 40 (UK)) TWA value 40 mg/m3 ; 10 ppm (WEL/EH 40 (UK)) 78-83-1: 2-methylpropan-1-ol; iso-butanol TWA value 154 mg/m3 ; 50 ppm (WEL/EH 40 (UK)) STEL value 231 mg/m3 ; 75 ppm (WEL/EH 40 (UK)) 91-20-3: naphthalene TWA value 50 mg/m3 ; 10 ppm (OEL (EU)) indicative Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the following apply. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK). Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust). General safety and hygiene measures The statements on personal protective equipment in the instructions for use apply when handling crop- protection agents in final-consumer packing. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is recommended. Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties Information on basic physical and chemical properties Form: liquid Colour: brown Odour: aromatic Odour threshold: not determined pH value: approx. 6.4 – 8.4 (10 g/l, 20 °C) (as an emulsion) crystallization temperature: approx. 3 °C Boiling range: approx. 244 – 292 °C Information applies to the solvent. Flash point: 64 °C (DIN 51755) Evaporation rate: not applicable Flammability: Product is combustible. Lower explosion limit: 0.6 %(V) Upper explosion limit: 7.0 %(V) Ignition temperature: 460 °C (DIN 51794) Vapour pressure: approx. 0.028 hPa (50 °C) Information applies to the solvent. Density: approx. 1.13 g/cm3 (20 °C) Relative vapour density (air): not determined Solubility in water: emulsifiable Partitioning coefficient n-octanol/water (log Kow): not applicable Thermal decomposition: not determined Viscosity, dynamic: approx. 91 mPa.s (approx. 20 °C) Explosion hazard: not explosive Fire promoting properties: not fire-propagating Other information Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid See MSDS section 7 – Handling and storage. Incompatible materials Substances to avoid: strong oxidizing agents, strong bases, strong acids Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Information on toxicological effects Acute toxicity Assessment of acute toxicity: Of moderate toxicity after single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Experimental/calculated data: LD50 rat (oral): 1,715 mg/kg (OECD Guideline 401) (by inhalation):The product has not been tested. The statement has been derived from the properties of the individual components.

LD50 rat (dermal): > 4,100 mg/kg (OECD Guideline 402) Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Experimental/calculated data: LC50 rat (by inhalation): > 2.16 mg/l 4 h (OECD Guideline 403) No mortality was observed. ------Irritation Assessment of irritating effects: Not irritating to the skin. Eye contact causes irritation. Experimental/calculated data: Skin corrosion/irritation: Irritant. Serious eye damage/irritation: Irritant. Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Experimental/calculated data: Buehler test guinea pig: Skin sensitizing effects were not observed in animal studies. (OECD Guideline 406) Germ cell mutagenicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone Assessment of reproduction toxicity: As shown in animal studies, the product may cause damage to the testes after repeated high exposures that cause other toxic effects. ------Developmental toxicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone Assessment of teratogenicity: The substance caused malformations/developmental toxicity in laboratory animals. ------Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Assessment of repeated dose toxicity: Adaptive effects were observed after repeated exposure in animal studies. ------Aspiration hazard May also damage the lung at swallowing (aspiration hazard). Other relevant toxicity information Misuse can be harmful to health. 12. Ecological Information Toxicity Assessment of aquatic toxicity: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Toxicity to fish: LC50 (96 h) 1.2 mg/l, Cyprinodon variegatus (OECD Guideline 203, static) No observed effect concentration (36 d) 0.025 mg/l, Pimephales promelas (OPPTS 820.1075 (EPA- Guideline)) ------Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Aquatic invertebrates: EC50 (96 h) 0.77 mg/l, Americamysis bahia (OPP 72-3 (EPA-Guideline), Flow through.) ------Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Aquatic plants: No observed effect concentration (72 h) 0.0032 mg/l, Desmodesmus subspicatus (OECD Guideline 201) EC50 (72 h) > 0.032 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static) ------Persistence and degradability Assessment biodegradation and elimination (H2O): The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). ------Bioaccumulative potential Assessment bioaccumulation potential: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Bioaccumulation potential: Bioconcentration factor: 200, Oncorhynchus mykiss Accumulation in organisms is not to be expected. ------Mobility in soil (and other compartments if available) Assessment transport between environmental compartments: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1 H-imidazole-1-carboxamide; prochloraz Assessment transport between environmental compartments: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected. ------Results of PBT and vPvB assessment The product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative) criteria. Other adverse effects The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer. Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal Considerations Waste treatment methods Must be sent to a suitable incineration plant, observing local regulations. The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom). This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (United Kingdom) Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. 14. Transport Information Land transport ADR UN number UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA, PROCHLORAZ 40%) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: Tunnel code: E RID UN number UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA, PROCHLORAZ 40%) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known Inland waterway transport ADN UN number UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA, PROCHLORAZ 40%) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known Transport in inland waterway vessel: Not evaluated Sea transport IMDG UN number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA, PROCHLORAZ 40%) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Marine pollutant: YES Special precautions for user: None known Air transport IATA/ICAO UN number: UN 3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA, PROCHLORAZ 40%) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for user: None known Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated Further information This product is subject to the most recent edition of “The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations” and their amendments (United Kingdom). 15. Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture To avoid risks to man and the environment, comply with the instructions for use. The data should be considered when making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, for example, ‘COSHH Essentials’ (United Kingdom). This product is classified under the Chemicals (Hazard Information and Packaging) Regulations, (CHIP) (United Kingdom). This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and amendments if specific threshold tonnages are exceeded (United Kingdom). If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. Chemical Safety Assessment Advice on product handling can be found in sections 7 and 8 of this safety data sheet. 16. Other Information For proper and safe use of this product, please refer to the approval conditions laid down on the product label. Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3: Xn Harmful. N Dangerous for the environment. Xi Irritant. T Toxic. 22 Harmful if swallowed. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 38 Irritating to skin. 41 Risk of serious damage to eyes. 61 May cause harm to the unborn child. 36/37/38 Irritating to eyes, respiratory system and skin. 10 Flammable. 37/38 Irritating to respiratory system and skin. 67 Vapours may cause drowsiness and dizziness. 37 Irritating to respiratory system. 40 Limited evidence of a carcinogenic effect. Asp. Tox. Aspiration hazard Acute Tox. Acute toxicity Eye Dam./Irrit. Serious eye damage/eye irritation Aquatic Acute Hazardous to the aquatic environment – acute Aquatic Chronic Hazardous to the aquatic environment – chronic Skin Corr./Irrit. Skin corrosion/irritation Repr. Reproductive toxicity STOT SE Specific target organ toxicity — single exposure Flam. Liq. Flammable liquid Carc. Carcinogenicity Repr. Cat. 2 Reprotoxic substances (fertility or development) Category 2: Substances which should be regarded as if they cause developmental toxicity to in humans or substances which should be regarded as if they impair fertility in humans. Carc. Cat. 3 Carcinogenic substances Category 3: Substances which cause concern for man owing to possible carcinogenic effects. H302 Harmful if swallowed. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H304 May be fatal if swallowed and enters airways. EUH066 Repeated exposure may cause skin dryness or cracking. H318 Causes serious eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H360D May damage the unborn child. H226 Flammable liquid and vapour. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. If you have any queries relating to this MSDS, it‘s contents or any other product safety related questions, please write to the following e-mail address: [email protected] The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product’s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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