Degradation in PV Encapsulation Transmittance: an Interlaboratory Study Towards a Climate-Specific Test Preprint David C
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Degradation in PV Encapsulation Transmittance: An Interlaboratory Study Towards a Climate-Specific Test Preprint David C. Miller, Eleonora Annigoni, Amal Ballion, Jayesh G. Bokria, Laura S. Bruckman, David M. Burns, Xinxin Chen, Lamont Elliott, Jiangtao Feng, Roger H. French, Sean Fowler, Xiaohong Gu, Peter L. Hacke, Christian C. Honeker, Michael D. Kempe, Hussam Khonkar, Michael Köhl, Laure-Emmanuelle Perret-Aebi, Nancy H. Phillips, Kurt P. Scott, Fanny Sculati-Meillaud, Tsuyoshi Shioda, Shigeo Suga, Shin Watanabe, and John H. Wohlgemuth See inside for authors’ affiliations Presented at the 42nd IEEE Photovoltaic Specialists Conference New Orleans, Louisiana June 14–19, 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications. 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Box 62 Oak Ridge, TN 37831-0062 OSTI http://www.osti.gov Phone: 865.576.8401 Fax: 865.576.5728 Email: [email protected] Available for sale to the public, in paper, from: U.S. Department of Commerce National Technical Information Service 5301 Shawnee Road Alexandria, VA 22312 NTIS http://www.ntis.gov Phone: 800.553.6847 or 703.605.6000 Fax: 703.605.6900 Email: [email protected] Cover Photos by Dennis Schroeder: (left to right) NREL 26173, NREL 18302, NREL 19758, NREL 29642, NREL 19795. NREL prints on paper that contains recycled content. Degradation in PV Encapsulation Transmittance: An Interlaboratory Study Towards a Climate-Specific Test David C. Miller1, Eleonora Annigoni2, Amal Ballion3, Jayesh G. Bokria4, Laura S. Bruckman5, David M. Burns6, Xinxin Chen7, Lamont Elliott8, JiangtaoFeng7, Roger H. French5, Sean Fowler9, Xiaohong Gu10, Peter L. Hacke1, Christian C. Honeker11, Michael D. Kempe1, Hussam Khonkar12, Michael Köhl3, Laure-Emmanuelle Perret-Aebi13, Nancy H. Phillips6, Kurt P. Scott8, Fanny Sculati- Meillaud2, Tsuyoshi Shioda14, Shigeo Suga15, Shin Watanabe15, and John H. Wohlgemuth1 1National Renewable Energy Laboratory (NREL), 15013 Denver West Parkway, Golden, CO 80401, USA 2École Polytechnique Fédérale de Lausanne (EPFL), Rue de la Maladière 71B, Ch-2002 Neuchâtel, Switzerland 3Fraunhofer Institute for Solar Energy Systems (ISE), Heidenhofstrasse 2, 79110 Freiburg, Germany 4Specialized Technology Resources, Inc. (STR), 10 Water Street, Enfield, CT, USA 06082 5Case Western Reserve University (CWRU), White 538, 10900 Euclid Avenue, Cleveland, OH 44106, USA 6The 3M Company, 3M Center, Building 235-67-15, St. Paul, MN, 55144, USA 7China National Electric Apparatus Research Institute Co., Ltd. (CEI), Guangzhou, 510663, P. R. China 8Atlas Material Testing Technology L.L.C., 1500 Bishop Court, Mount Prospect, IL 60056, USA, 9Q-Lab Corporation, 800 Canterbury Road, Cleveland, OH 44145 USA 10National Institute of Standards and Technology (NIST), 100 Bureau Dr., Gaithersburg, MD 20899-8615, USA 11Fraunhofer Center for Sustainable Energy Systems (CSE), 5 Channel Center, Boston, MA 02210, USA 12King Abdulaziz City for Science and Technology (KACST), 17 King Abdullah Road, Riyadh, 11442, Saudi Arabia 13Centre Suisse d'Electronique et Microtechnique S.A. (CSEM), Rue Jaquet-Droz 1, Ch-2002 Neuchâtel, Switzerland 14Mitsui Chemicals, Inc., 580-32 Nagaura-cho, Sodegaura-shi, Chiba, 299-0265, Japan 15Suga Test Instruments Co., Ltd., 5-4-14 Shinjuku, Shinjuku-ku, 160-0022, Tokyo Japan Abstract — Reduced optical transmittance of encapsulants previously [1], [2], [3] —particularly after the incident at the resulting from ultraviolet (UV) degradation has frequently been Carrizo Plains concentrator installation [4]. The former identified as a cause of decreased PV module performance studies, e.g., [1], highlight the reduction in transmittance and through the life of service in the field. The present module safety the effect on characteristics including gel content and and qualification standards, however, apply short UV doses only chemistry for poly (ethylene-co-vinyl acetate) (EVA) capable of examining design robustness or “infant mortality” encapsulant. The latter studies, e.g., [2], [3], confirm that the failures. Essential information that might be used to screen encapsulation through product lifetime remains unknown. For degradation of EVA results from interactions and example, the relative efficacy of xenon-arc and UVA-340 incompatibilities between formulation additives. The module fluorescent sources or the typical range of activation energy for safety (IEC 61730) and qualification (IEC 61215 series) tests degradation is not quantified. We have conducted an presently apply to only a short (up to 137 days equivalent of interlaboratory experiment to provide the understanding that the IEC 60904-3 AM 1.5 global UV-B radiation dose) UV will be used towards developing a climate- and configuration- exposure. To establish module reliability for relevant, long- specific (UV) weathering test. Five representative, known term use, e.g., comparable to the desired lifetime of 25 years, formulations of EVA were studied in addition to one TPU requires greater understanding. material. Replicate laminated silica/polymer/silica specimens are We are conducting a set of experiments to provide the being examined at 14 institutions using a variety of indoor chambers (including Xenon, UVA-340, and metal-halide light understanding that will be used to develop weathering sources) or field aging. The solar-weighted transmittance, exposures for PV encapsulants that account for stresses in yellowness index, and the UV cut-off wavelength, determined different use environments, including different terrestrial from the measured hemispherical transmittance, are examined to climates and mounting configurations. The effort and results provide understanding and guidance for the UV light source for an initial set of work studying the degradation in optical (lamp type) and temperature used in accelerated UV aging tests. transmittance of encapsulants are described here. Other Index Terms — reliability, durability, thermal activation. portions of the work examine the effect of weathering on adhesion of glass to encapsulants or edge seals. Because no single institution had all of the resources to run the numerous I. INTRODUCTION exposure conditions, 15 institutions are collaborating in this The degradation of encapsulants used for photovoltaic (PV) work, as represented by the authors of this paper. modules subject to weather - the combined factors of light, The goals of this encapsulant transmittance study include: especially that in the ultraviolet (UV), temperature, and •Quantify the activation energies, Ea, for the degradation moisture (relative humidity, %RH) has been examined of transmittance. This includes providing a sense of the range 1 This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications. of the Ea that may be present by examining “known bad,” baseline moisture concentration in the polymer similar to that “known good,” and “intermediate” material formulations. applied in indoor aging. Silica glass (transmitting above 202 •Determine if there is significant coupling between nm) was used rather than industry-standard soda-lime glass relevant stress factors, i.e., UV, temperature, and humidity. (transmitting above 295 nm), so that the glass would not This will identify what factors need to be considered in an attenuate UV radiation. accelerated test. Transmittance measurements were obtained at 0, 15, 30, 45, •Investigate the spectral requirements for different light 60, 75, 90, 120, and 180 days cumulative exposure. sources by comparing aged specimens, i.e., for Xe-arc, UVA- Transmittance measurements were obtained at the center and 340 fluorescent, and metal-halide