Handbook for the Application of the Caesium-137 Technique
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Gallium and Germanium Recovery from Domestic Sources
RI 94·19 REPORT OF INVESTIGATIONS/1992 r---------~~======~ PLEASE DO NOT REMOVE FRCJIiI LIBRARY "\ LIBRARY SPOKANE RESEARCH CENTER RECEIVED t\ UG 7 1992 USBOREAtJ.OF 1.j,'NES E. S15't.ON1"OOMERY AVE. ~E. INA 00207 Gallium and Germanium Recovery From Domestic Sources By D. D. Harbuck UNITED STATES DEPARTMENT OF THE INTERIOR BUREAU OF MINES Mission: As the Nation's principal conservation agency, the Department of the Interior has respon sibility for most of our nationally-owned public lands and natural and cultural resources. This includes fostering wise use of our land and water resources, protecting our fish and wildlife, pre serving the environmental and cultural values of our national parks and historical places, and pro viding for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also promotes the goals of the Take Pride in America campaign by encouragi,ng stewardship and citizen responsibil ity for the public lands and promoting citizen par ticipation in their care. The Department also has a major responsibility for American Indian reser vation communities and for people who live in Island Territories under U.S. Administration. TIi Report of Investigations 9419 Gallium and Germanium Recovery From Domestic Sources By D. D. Harbuck I ! UNITED STATES DEPARTMENT OF THE INTERIOR Manuel lujan, Jr., Secretary BUREAU OF MINES T S Ary, Director - Library of Congress Cataloging in Publication Data: Harbuck, D. D. (Donna D.) Ga1lium and germanium recovery from domestic sources / by D.D. -
The Development of the Periodic Table and Its Consequences Citation: J
Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1. -
Exploring Density
Exploring Density Students investigate the densities of different liquids and solids and understand how density may help identify a substance. Suggested Grade Range: 6-8 Approximate Time: 1 hour Relevant National Content Standards: Next Generation Science Standards Science and Engineering Practices: Developing and using Models Modeling in 6–8 builds on K–5 experiences and progresses to developing, using, and revising models to describe, test, and predict more abstract phenomena and design systems. • Develop and use a model to describe phenomena. Science and Engineering Practices: Analyzing and Interpreting Data Analyzing data in 6-8 builds on K-5 and progresses to extending quantitative analysis to investigations, distinguishing between correlation and causation, and basic statistical techniques of data and error analysis. • Analyze and interpret data to determine similarities and differences in findings. Disciplinary Core Ideas: PS1.A Structure and Properties of Matter Each pure substance has characteristic physical and chemical properties (for any bulk quantity under given conditions) that can be used to identify it. Common Core State Standard: 7NS 2. Apply and extend previous understanding of multiplication and division and of fractions to multiply and divide rational numbers. 3. Solve real-world and mathematical problems involving the four operations with rational numbers. Common Core State Standard: 7EE Solve real-life and mathematical problems using numerical and algebraic expressions and equations. 4. Use variables to represent -
Shortage of Germanium-68/Gallium-68 Generators for the Production of Gallium-68
August 6, 2018 US Food and Drug Administration 10903 New Hampshire Avenue Silver Spring, MD 20993 Re: Shortage of Germanium-68/Gallium-68 Generators for the Production of Gallium-68 Dear Dr. Marzella and Dr. Zadecky, The Society of Nuclear Medicine and Molecular Imaging (SNMMI) would like to provide the following information related to availability of GMP-grade germanium-68/gallium-68 generators in the United States. SNMMI, composed of 15,000 members, works to set standards for molecular imaging and nuclear medicine practice by creating guidelines, sharing information through journals, hosting meetings, and leading advocacy on key issues that affect molecular imaging and therapy research and practice. Germanium-68/Gallium-68 generators (68Ge/68Ga) Gallium-68 is currently milked from a 68Ge/68Ga generator. Several manufacturers produce these table top generators including Eckert & Ziegler (Germany), IRE ELiT (Belgium), Isotopen Technologien Munchen (ITG) (Germany), and iThemba (South Africa). The Eckert & Ziegler GalliaPharm® and the IRE ELiT Galli Eo® generators are both GMP grade and have type II drug master files on file with FDA. Use of Gallium-68 (68Ga) in the U.S. The radioisotope 68Ga is used in the production of NETSPOTTM, a kit for the preparation of gallium 68Ga dotatate injection, an FDA-approved radiopharmaceutical. NETSPOT was approved in June 2016 for localization of somatostatin receptor positive neuroendocrine tumors (NETs) in adult and pediatric patients using Positron Emission Tomography (PET). NETSPOT is currently approved for use only with the GalliaPharm 68Ga generator from Eckert & Ziegler. NETSPOT has experienced rapid adoption in the US. Advanced Accelerator Applications (AAA) has been expanding the network of pharmacies that distribute NETSPOT since its approval. -
High-Temperature Structural Evolution of Caesium and Rubidium Triiodoplumbates D.M
High-temperature structural evolution of caesium and rubidium triiodoplumbates D.M. Trots, S.V. Myagkota To cite this version: D.M. Trots, S.V. Myagkota. High-temperature structural evolution of caesium and rubidium tri- iodoplumbates. Journal of Physics and Chemistry of Solids, Elsevier, 2009, 69 (10), pp.2520. 10.1016/j.jpcs.2008.05.007. hal-00565442 HAL Id: hal-00565442 https://hal.archives-ouvertes.fr/hal-00565442 Submitted on 13 Feb 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Author’s Accepted Manuscript High-temperature structural evolution of caesium and rubidium triiodoplumbates D.M. Trots, S.V. Myagkota PII: S0022-3697(08)00173-X DOI: doi:10.1016/j.jpcs.2008.05.007 Reference: PCS 5491 To appear in: Journal of Physics and www.elsevier.com/locate/jpcs Chemistry of Solids Received date: 31 January 2008 Revised date: 2 April 2008 Accepted date: 14 May 2008 Cite this article as: D.M. Trots and S.V. Myagkota, High-temperature structural evolution of caesium and rubidium triiodoplumbates, Journal of Physics and Chemistry of Solids, doi:10.1016/j.jpcs.2008.05.007 This is a PDF file of an unedited manuscript that has been accepted for publication. -
Improvement in Retention of Solid Fission Products in HTGR Fuel Particles by Ceramic Kernel Additives
FORMAL REPORT GERHTR-159 UNITED STATES-GERMAN HIGH TEMPERATURE REACTOR RESEARCH EXCHANGE PROGRAM Original report number ______________________ Title Improvement in Retention of Solid Fission Products in HTGR Fuel Particles by Ceramic Kernel Additives Authorial R. Forthmann, E. Groos and H. Grobmeier Originating Installation Kemforschtmgsanlage Juelich, West Germany. Date of original report issuance August 1975_______ Reporting period covered _ _____________________________ In the original English This report, translated wholly or in part from the original language, has been reproduced directly from copy pre pared by the United States Mission to the European Atomic Energy Community THIS REPORT MAY BE GIVEN UNLIMITED DISTRIBUTION ERDA Technical Information Center, Oak Ridge, Tennessee DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. GERHTR-159 Distribution Category UC-77 CONTENTS page 1. INTRODUCTION 2 2. FUNDAMENTAL STUDIES 3 3. IRRADIATION EXPERIMENT FRJ2-P17 5 3.1 Results of the Fission Product 8 Release Measurements Improvement in Retention of Solid 3.2 Electron Microprobe Investigations Fission Products in HTGR Fuel Particles 8 by Ceramic Kernel Additives. 4. IRRADIATION EXPERIMENT FRJ2-P18 16 4.1 Release of Solid Fission Products 19 4.2 Electron Microprobe Studies 24 by R. Forthmann, E. Groos, H. GrObmeier 5. SUMMARY AND CONCLUSIONS 27 6. ACKNOWLEDGEMENT 28 7. REFERENCES 29 2 - X. INTRODUCTION Kernforschungs- anlage JUTich JOL - 1226 August 1975 Considerations of the core design of advanced High-Temperature Gas-cooled GmbH IRW Reactors (HTGRs) led to increased demands concerning solid fission product retention in the fuel elements. This would be desirable not only for HTGR power plants with a helium-turbine in the primary circuit (HHT project), but also for the application of HTGRs as a source of nuclear process heat. -
A.D. Pelton, the Ag-Cs (Silver-Cesium) System
Ge-Sb Ag-Cs 58Vas: V.N. Vasilevskaya and E.G. Miseluk. "Investigation of Germanium and Silicon," Sot,. Phys. Solid State, 10, 2247- Alloying Germanium with Some Elements." Ukr. Fiz. ZiT.. 3. 2249 (1969). (Crys Structure; Experimental) 183-187 [1958~ in Russian. tEqui Diagram: Experimental) *70Pre: B. Predel and D.W. Stein, "Thermodynamic Investiga- 58Wei: K. Weiser. "Theoretical Calculation of Distribution Coef- tion of the Systems Germanium-Zinc, Germanium-Indium, ficients of Impurities in Germanium and Silicon. Heats of and Germanium-Antimony,"Z. Metallkd., 61,909-914 (1970) Solid Solution." J. Phys. Chem. Solids. 7. 118-126 (1958L in German. (Thermo, Equi Diagram; Experimental; #) [Thermo: Theory~ 70Rao: M.V. Rao and W.A. Tiller, "Excess Free Energies in the 59Zhu: B.G. Zhurkin. V.S. Zemskov. D.A. Petrov. and A.D. Ge, Si, and Ga Binary Systems--the ~, Parameter Approach," Suchkova. Izc. Akad. Nauk SSSR Otd. Tekh. Nauk Met. To- J. Phys. Chem. Solids, 31,191-198 (1970). ~Thermo; Theory) plico t5). 86-90 [1959) in Russian: cited in [Elliott]. (Equi Dia- 72Mah Y. Malmejac, P. Desre, and E. Bonnier, "Contribution to gram: Experimental) the Studies of the Ternary Phase Diagram Ge-Si-Sb," M~m. 60Thu: C.D. Thurmond and M. Kowalchik. "Germanium and Sei. Rev. Mdtall., 69, 565-577 (1972) in French. (Equi Diagram; Silicon Liquidus Curves." Bell Sys. Tech. J.. 39. 169-204 Experimental; #) [1960). (Equi Diagram: Experimental) 77Bar: I. Barin, O. Knacke, and O. Kubaschewski, Thermo- 60Tru: F.A. Trumbore. "Solid Solubilities of Impurity Elements chemical Properties of Inorganic Substances (Supplement), in Germanium and Silicon." Bell Svs. -
Of the Periodic Table
of the Periodic Table teacher notes Give your students a visual introduction to the families of the periodic table! This product includes eight mini- posters, one for each of the element families on the main group of the periodic table: Alkali Metals, Alkaline Earth Metals, Boron/Aluminum Group (Icosagens), Carbon Group (Crystallogens), Nitrogen Group (Pnictogens), Oxygen Group (Chalcogens), Halogens, and Noble Gases. The mini-posters give overview information about the family as well as a visual of where on the periodic table the family is located and a diagram of an atom of that family highlighting the number of valence electrons. Also included is the student packet, which is broken into the eight families and asks for specific information that students will find on the mini-posters. The students are also directed to color each family with a specific color on the blank graphic organizer at the end of their packet and they go to the fantastic interactive table at www.periodictable.com to learn even more about the elements in each family. Furthermore, there is a section for students to conduct their own research on the element of hydrogen, which does not belong to a family. When I use this activity, I print two of each mini-poster in color (pages 8 through 15 of this file), laminate them, and lay them on a big table. I have students work in partners to read about each family, one at a time, and complete that section of the student packet (pages 16 through 21 of this file). When they finish, they bring the mini-poster back to the table for another group to use. -
Density Functional Theory Metadynamics of Silver, Caesium and Palladium Diffusion at B-Sic Grain Boundaries ⇑ Jeremy Rabone A, , Eddie López-Honorato B
Journal of Nuclear Materials 458 (2015) 56–63 Contents lists available at ScienceDirect Journal of Nuclear Materials journal homepage: www.elsevier.com/locate/jnucmat Density functional theory metadynamics of silver, caesium and palladium diffusion at b-SiC grain boundaries ⇑ Jeremy Rabone a, , Eddie López-Honorato b a European Commission, Joint Research Centre, Institute for Transuranium Elements, D-76125 Karlsruhe, Germany b Centro de Investigación y de Estudios Avanzados del IPN (CINVESTAV), Unidad Saltillo, Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe 25900, Coahuila, Mexico highlights DFT metadynamics of diffusion of Pd, Ag and Cs on grain boundaries in b-SiC. The calculated diffusion rates for Pd and Ag tally with experimental release rates. A mechanism of release other than grain boundary diffusion seems likely for Cs. article info abstract Article history: The use of silicon carbide in coated nuclear fuel particles relies on this materials impermeability towards Received 22 May 2014 fission products under normal operating conditions. Determining the underlying factors that control the Accepted 9 November 2014 rate at which radionuclides such as Silver-110m and Caesium-137 can cross the silicon carbide barrier Available online 4 December 2014 layers, and at which fission products such as palladium could compromise or otherwise alter the nature of this layer, are of paramount importance for the safety of this fuel. To this end, DFT-based metadynam- ics simulations are applied to the atomic diffusion of silver, caesium and palladium along a R5 grain boundary and to palladium along a carbon-rich R3 grain boundary in cubic silicon carbide at 1500 K. For silver, the calculated diffusion coefficients lie in a similar range (7.04 Â 10À19–3.69 Â 10À17 m2 sÀ1) as determined experimentally. -
Study on the Correlation Between Microstructure Corrosion and Wear Resistance of Ag-Cu-Ge Alloys
Coatings 2015, 5, 78-94; doi:10.3390/coatings5010078 OPEN ACCESS coatings ISSN 2079-6412 www.mdpi.com/journal/coatings Article Study on the Correlation between Microstructure Corrosion and Wear Resistance of Ag-Cu-Ge Alloys Antonio Cusma 1,*, Marco Sebastiani 2, Daniele De Felicis 2, Andrea Basso 3 and Edoardo Bemporad 2 1 Department of Chemistry and Materials Science, National Research Council of Italy, Via dei Taurini 19, Rome 00185, Italy 2 Engineering Department, “Roma TRE” University, Via della Vasca Navale 79, Rome 00146, Italy; E-Mails: [email protected] (M.S.); [email protected] (D.D.F.); [email protected] (E.B.) 3 Legor Group SRL, Via San Benedetto14-34, Bressanvido, VI 36050, Italy; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +39-06-4993-2317. Academic Editor: Alessandro Lavacchi Received: 23 December 2014 / Accepted: 9 March 2015 / Published: 13 March 2015 Abstract: In this work, a morphological and structural characterization of a ternary Ag-Cu-Ge alloy of known composition was performed with the aim of evaluating how the passivation parameters (time and temperature) influence the morphological features of the material surface. A nanomechanical characterization was performed in order to correlate the morphology and microstructure of the alloy with its tarnish, wear, and scratch resistance. It was found that the addition of germanium to the alloy not only provides the material with tarnish and fire-stain resistance, but it also improves the scratch and wear resistance owing to the formation of a dense and stable thin oxide layer. -
Physical and Chemical Properties of Germanium
Physical And Chemical Properties Of Germanium Moneyed and amnesic Erasmus fertilise her fatuousness revitalise or burrow incommunicatively. Creditable Petr still climbs: regarding and lissome Lazarus bully-off quite punctiliously but slums her filoplume devotedly. Zane still defilade venomous while improvident Randell bloodiest that wonderers. Do you for this context of properties and physical explanation of Silicon is sincere to metals in its chemical behaviour. Arsenic is extremely toxic, RS, carbon is the tongue one considered a full nonmetal. In nature, which name a widely used azo dye. Basic physical and chemical properties of semiconductors are offset by the energy gap between valence conduction! Other metalloids on the periodic table are boron, Batis ZB, only Germanium and Antimony would be considered metals for the purposes of nomenclature. Storage temperature: no restrictions. At room temperature, the semiconducting elements are primarily nonmetallic in character. This application requires Javascript. It has also new found in stars and already the atmosphere of Jupiter. Wellings JS, it is used as an eyewash and insecticide. He has studied in Spain and Hungary and authored many research articles published in indexed journals and books. What are oral health benefits of pumpkins? The material on this site may not be reproduced, germanium, the radiation emitted from an active device makes it locatable. Classify each statement as an extensive property must an intensive property. In germanium and physical chemical properties of the border lines from the! The most electronegative elements are at the nod in the periodic table; these elements often react as oxidizing agents. Atomic Volume and Allotropy of the Elements. -
Glossary of Terms
GLOSSARY OF TERMS For the purpose of this Handbook, the following definitions and abbreviations shall apply. Although all of the definitions and abbreviations listed below may have not been used in this Handbook, the additional terminology is provided to assist the user of Handbook in understanding technical terminology associated with Drainage Improvement Projects and the associated regulations. Program-specific terms have been defined separately for each program and are contained in pertinent sub-sections of Section 2 of this handbook. ACRONYMS ASTM American Society for Testing Materials CBBEL Christopher B. Burke Engineering, Ltd. COE United States Army Corps of Engineers EPA Environmental Protection Agency IDEM Indiana Department of Environmental Management IDNR Indiana Department of Natural Resources NRCS USDA-Natural Resources Conservation Service SWCD Soil and Water Conservation District USDA United States Department of Agriculture USFWS United States Fish and Wildlife Service DEFINITIONS AASHTO Classification. The official classification of soil materials and soil aggregate mixtures for highway construction used by the American Association of State Highway and Transportation Officials. Abutment. The sloping sides of a valley that supports the ends of a dam. Acre-Foot. The volume of water that will cover 1 acre to a depth of 1 ft. Aggregate. (1) The sand and gravel portion of concrete (65 to 75% by volume), the rest being cement and water. Fine aggregate contains particles ranging from 1/4 in. down to that retained on a 200-mesh screen. Coarse aggregate ranges from 1/4 in. up to l½ in. (2) That which is installed for the purpose of changing drainage characteristics.