In German Zinc and Lead Production FINAL DRAFT

Total Page:16

File Type:pdf, Size:1020Kb

In German Zinc and Lead Production FINAL DRAFT Report on Best Available Techniques (BAT) in German Zinc and Lead Production FINAL DRAFT Deutsch-Französisches Institut für Umweltforschung (DFIU) French-German Institute for Environmental Research University of Karlsruhe (TH) o. Prof. Dr. O. Rentz Dipl.-Ing. Stephan Hähre, Dr. Frank Schultmann Karlsruhe, February 1999 On behalf of the German Federal Environmental Agency, Berlin (UBA) in the frame of the Research Project 109 05 006 Contents 3 Contents PREFACE.............................................................................................................................................................13 1 GENERAL INFORMATION.......................................................................................................................... 15 1.1 PRODUCTION AND USE OF ZINC AND LEAD ................................................................................................... 15 1.1.1 Zinc ..................................................................................................................................................... 15 1.1.2 Lead .................................................................................................................................................... 16 1.2 FIRST INDICATION OF ENVIRONMENTAL CONCERNS REGARDING THE PRODUCTION OF ZINC AND LEAD ........ 19 1.2.1 Emissions into the atmosphere............................................................................................................ 19 1.2.2 Potential releases into water............................................................................................................... 21 1.2.3 Solid materials generated ................................................................................................................... 21 2 APPLIED PROCESS TECHNOLOGY AND ABATEMENT TECHNIQUES IN GERMAN ZINC AND LEAD PRODUCTION........................................................................................................................................ 23 2.1 INTRODUCTION AND SCOPE OF THE STUDY................................................................................................... 23 2.2 BASIC DESCRIPTION OF ZINC AND LEAD PRODUCTION .................................................................................. 24 2.2.1 Zinc production................................................................................................................................... 24 2.2.1.1 Hydrometallurgical zinc production ............................................................................................................. 25 2.2.1.1.1 General process description.................................................................................................................. 25 2.2.1.1.2 Main outputs and environmental concerns of the hydrometallurgical zinc production processes ........ 27 2.2.1.2 Pyrometallurgical zinc production ................................................................................................................ 29 2.2.1.2.1 Imperial Smelting Process .................................................................................................................... 29 2.2.1.2.2 Waelz kiln process................................................................................................................................ 34 2.2.1.2.3 Reduction in vertical retorts (New Jersey retort process route) ............................................................ 36 2.2.1.2.4 Fuming plant......................................................................................................................................... 37 2.2.1.2.5 Melting of metallic raw materials ......................................................................................................... 37 2.2.1.2.6 Refining of crude zinc .......................................................................................................................... 38 2.2.1.3 Zinc production plants in Germany............................................................................................................... 38 2.2.2 Lead production.................................................................................................................................. 41 2.2.2.1 Lead-containing raw materials...................................................................................................................... 41 2.2.2.2 Sinter plant - blast furnace route for lead production.................................................................................... 42 2.2.2.3 New direct smelting processes for lead production....................................................................................... 44 2.2.2.4 Lead production from secondary raw material.............................................................................................. 45 2.2.2.4.1 Preparation of battery and scrap materials............................................................................................ 46 2.2.2.4.2 Smelting furnaces ................................................................................................................................. 47 2.2.2.5 Lead refining................................................................................................................................................. 48 2.2.2.6 Main outputs and environmental concerns of lead production plants........................................................... 49 2.2.2.6.1 New direct smelting plants (QSL process, Sirosmelt Process) ............................................................. 50 2.2.2.6.2 Rotary and shaft furnace process plants using exclusively secondary raw materials ............................ 52 2.2.2.6.3 Refining of lead bullion from primary and secondary plants................................................................ 54 2.2.2.7 Lead production plants in Germany.............................................................................................................. 54 3 PROCESS TECHNOLOGY, ABATEMENT TECHNIQUES AND PRESENT CONSUMPTION/EMISSION LEVELS IN GERMAN ZINC AND LEAD PRODUCTION ...................... 57 3.1 ZINC PRODUCTION IN GERMANY.................................................................................................................. 57 3.1.1 Hydrometallurgical zinc production plants in Germany .................................................................... 57 3.1.1.1 Zinc electrolysis plant Z1.............................................................................................................................. 57 3.1.1.1.1 General information.............................................................................................................................. 57 3.1.1.1.2 Description of the main process units and environmental techniques .................................................. 59 3.1.1.1.3 Summarised data on outputs and environmental concerns ................................................................... 62 3.1.1.2 Zinc electrolysis plant Z2.............................................................................................................................. 63 4 Contents 3.1.1.2.1 General information.............................................................................................................................. 63 3.1.1.2.2 Description of the main process units and environmental techniques .................................................. 64 3.1.1.2.3 Summarised data on outputs and environmental concerns ................................................................... 69 3.1.2 Pyrometallurgical zinc production in Germany ................................................................................. 70 3.1.2.1 Imperial Smelting Process (ISP) plant Z3..................................................................................................... 70 3.1.2.1.1 General information.............................................................................................................................. 70 3.1.2.1.2 Description of the main process units and environmental techniques .................................................. 71 3.1.2.1.3 Summarised data on outputs and environmental concerns ................................................................... 76 3.1.2.2 Waelz plants operated in Germany (plants Z4, Z5, Z7) ................................................................................ 78 3.1.2.2.1 General information.............................................................................................................................. 78 3.1.2.2.2 Description of the main process units and environmental techniques .................................................. 81 3.1.2.2.3 Summarised data on outputs and environmental concerns ................................................................... 88 3.1.2.3 New-Jersey retort plant Z6............................................................................................................................ 89 3.1.2.3.1 General information.............................................................................................................................. 89 3.1.2.3.2 Description of the main process units and environmental techniques .................................................. 90 3.1.2.3.3 Summarised data on outputs and environmental concerns ................................................................... 92 3.1.2.4 Secondary zinc and zinc alloy production by remelting processes
Recommended publications
  • Metal Extraction Processes for Electronic Waste and Existing Industrial Routes: a Review and Australian Perspective
    Resources 2014, 3, 152-179; doi:10.3390/resources3010152 OPEN ACCESS resources ISSN 2079-9276 www.mdpi.com/journal/resources Review Metal Extraction Processes for Electronic Waste and Existing Industrial Routes: A Review and Australian Perspective Abdul Khaliq, Muhammad Akbar Rhamdhani *, Geoffrey Brooks and Syed Masood Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, VIC 3122, Australia; E-Mails: [email protected] (A.K.); [email protected] (G.B.); [email protected] (S.M.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +61-3-9214-8528; Fax: +61-3-9214-8264. Received: 11 December 2013; in revised form: 24 January 2014 / Accepted: 5 February 2014 / Published: 19 February 2014 Abstract: The useful life of electrical and electronic equipment (EEE) has been shortened as a consequence of the advancement in technology and change in consumer patterns. This has resulted in the generation of large quantities of electronic waste (e-waste) that needs to be managed. The handling of e-waste including combustion in incinerators, disposing in landfill or exporting overseas is no longer permitted due to environmental pollution and global legislations. Additionally, the presence of precious metals (PMs) makes e-waste recycling attractive economically. In this paper, current metallurgical processes for the extraction of metals from e-waste, including existing industrial routes, are reviewed. In the first part of this paper, the definition, composition and classifications of e-wastes are described. In the second part, separation of metals from e-waste using mechanical processing, hydrometallurgical and pyrometallurgical routes are critically analyzed.
    [Show full text]
  • Principles of Extractive Metallurgy Lectures Note
    PRINCIPLES OF EXTRACTIVE METALLURGY B.TECH, 3RD SEMESTER LECTURES NOTE BY SAGAR NAYAK DR. KALI CHARAN SABAT DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING PARALA MAHARAJA ENGINEERING COLLEGE, BERHAMPUR DISCLAIMER This document does not claim any originality and cannot be used as a substitute for prescribed textbooks. The information presented here is merely a collection by the author for their respective teaching assignments as an additional tool for the teaching-learning process. Various sources as mentioned at the reference of the document as well as freely available material from internet were consulted for preparing this document. The ownership of the information lies with the respective author or institutions. Further, this document is not intended to be used for commercial purpose and the faculty is not accountable for any issues, legal or otherwise, arising out of use of this document. The committee faculty members make no representations or warranties with respect to the accuracy or completeness of the contents of this document and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. BPUT SYLLABUS PRINCIPLES OF EXTRACTIVE METALLURGY (3-1-0) MODULE I (14 HOURS) Unit processes in Pyro metallurgy: Calcination and roasting, sintering, smelting, converting, reduction, smelting-reduction, Metallothermic and hydrogen reduction; distillation and other physical and chemical refining methods: Fire refining, Zone refining, Liquation and Cupellation. Small problems related to pyro metallurgy. MODULE II (14 HOURS) Unit processes in Hydrometallurgy: Leaching practice: In situ leaching, Dump and heap leaching, Percolation leaching, Agitation leaching, Purification of leach liquor, Kinetics of Leaching; Bio- leaching: Recovery of metals from Leach liquor by Solvent Extraction, Ion exchange , Precipitation and Cementation process.
    [Show full text]
  • Corrosion of Refractories in Lead Smelting Reactors
    CORROSION OF REFRACTORIES IN LEAD SMELTING REACTORS By LINGXUAN WEI B.Sc, Wuhan University of Science & Technology, China 1986 M.Sc, University of Science & Technology Beijing, China 1997 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF APPLIED SCIENCE in THE FACULTY OF GRADUATE STUDIES DEPARTMENT OF METALS AND MATERIALS ENGINEERING We accept this thesis as conforming to the required standard THE UNIVERSITY OF BRITISH .UMB1A DECEMBER 2000 ©Lingxuan Wei, ZO0O UBC Special Collections - Thesis Authorisation Form http://www.library.ubc.ca/spcoll/thesauth.html In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the head of my department or by his or her representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. v 3 The University of British Columbia Vancouver, Canada Date lof 1 3/19/01 2:36 PM ABSTRACT Corrosion of refractories by slag is a complex phenomenon which, depending on the particular system, involves many processes, such as chemical wear (corrosion) and physical or mechanical wear (erosion), which may act synergistically. No single model can explain all cases of corrosion nor can it explain all corrosion mechanisms of a particular refractory in different environments, but the knowledge of the microstructure combined with the chemistry of the systems are necessary to understand the corrosion mechanism of a refractory material.
    [Show full text]
  • Table of Contents
    Table of Contents Preface ........................................... xi Chapter 1. Physical Extraction Operations .................... 1 1.1. Solid-solid and solid-fluid separation operations .............. 1 1.1.1. Flotation ................................... 1 1.1.2. Settling under gravity ........................... 3 1.1.3. Centrifugation ................................ 3 1.1.4. Filtration ................................... 4 1.2. Separation operations of the components of a fluid phase ........ 5 1.2.1. Condensation ................................ 5 1.2.2. Vacuum distillation ............................. 5 1.2.3. Liquation ................................... 6 1.2.4. Distillation .................................. 8 1.2.5. Extractive distillation ........................... 11 1.3. Bibliography ................................... 12 Chapter 2. Hydrometallurgical Operations .................... 15 2.1. Leaching and precipitation operations .................... 15 2.1.1. Leaching and precipitation reactors ................... 15 2.1.2. Continuous stirred tank reactor (CSTR) ................ 18 2.1.3. Models of leaching and precipitation operations ........... 20 2.1.4. Particle-size distribution (PSD) functions ............... 21 2.2. Reactor models based on particle residence time distribution functions ........................................ 24 2.2.1. Performance equations for a single CSTR ............... 24 2.2.2. Performance equations for multistage CSTRs ............. 28 2.3. Reactor models based on the population balance
    [Show full text]
  • Hg on Periodic Table
    Hg On Periodic Table Cameron never westernize any stairs carnalize externally, is Thomas unlovely and muddled enough? gloomingPeridermal backstage, Aubert regales: uncontrolled he globe-trots and coequal. his costrels contentiously and impassively. Martie buck her How is left over the california, on hg could melt quickly by electronic strain gauge sensors have very fine flakes of Mercury than the chemical element with symbol Hg and atomic no 0 Mercury was a transition metal A transition metal is feast of the elements found between Groups. Mercury news a naturally occurring element found an air, corps and soil. This website under most abundant elements into minamata bay, or out that immediately contained in a product can cause damage, as a highly poisonous. Starship like the plane? Mercury compound thimerosal is used to our wonder leave you. It has been shown significantly more about a periodic table is liquid form alloys, switches like from countries are kidneys damage a periodic table live in terms are there is. Mercury chemical symbol Hg is an liquid metallic element that historically was used in many medicines but has now restricted due for legitimate concerns about. Cinnabar was rubbed together with policy in paper clay dish. Glad you liked this one, Jordan! Some forms of tame are particularly potent poisons. Why take some elements on the Periodic Table represented by letters that have only clear connection to their names? Mif signatures in antiseptics, facts about being replaced by where did you think about chemical sedimentation may also. Doesn't the periodic table define it Not got is overcome an element.
    [Show full text]
  • Occurrence and Extraction of Metals MODULE - 6 Chemistry of Elements
    Occurrence and Extraction of Metals MODULE - 6 Chemistry of Elements 16 Notes OCCURRENCE AND EXTRACTION OF METALS Metals and their alloys are extensively used in our day-to-day life. They are used for making machines, railways, motor vehicles, bridges, buildings, agricultural tools, aircrafts, ships etc. Therefore, production of a variety of metals in large quantities is necessary for the economic growth of a country. Only a few metals such as gold, silver, mercury etc. occur in free state in nature. Most of the other metals, however, occur in the earth's crust in the combined form, i.e., as compounds with different anions such as oxides, sulphides, halides etc. In view of this, the study of recovery of metals from their ores is very important. In this lesson, you shall learn about some of the processes of extraction of metals from their ores, called metallurgical processes. OBJECTIVES After reading this lesson, you will be able to : z differentiate between minerals and ores; z recall the occurrence of metals in native form and in combined form as oxides, sulphides, carbonates and chlorides; z list the names and formulae of some common ores of Na, Al, Sn, Pb ,Ti, Fe, Cu, Ag and Zn; z list the occurrence of minerals of different metals in India; z list different steps involved in the extraction of metals; * An alloy is a material consisting of two or more metals, or a metal and a non-metal. For example, brass is an alloy of copper and zinc; steel is an alloy of iron and carbon.
    [Show full text]
  • Liquation Cracking in the Heat-Affected Zone of IN738 Superalloy Weld
    metals Article Liquation Cracking in the Heat-Affected Zone of IN738 Superalloy Weld Kai-Cheng Chen 1, Tai-Cheng Chen 2,3 ID , Ren-Kae Shiue 3 ID and Leu-Wen Tsay 1,* ID 1 Institute of Materials Engineering, National Taiwan Ocean University, Keelung 20224, Taiwan; [email protected] 2 Nuclear Fuels and Materials Division, Institute of Nuclear Energy Research, Taoyuan 32546, Taiwan; [email protected] 3 Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan; [email protected] * Correspondence: [email protected]; Tel.: +886-2-24622192 (ext. 6405) Received: 7 May 2018; Accepted: 25 May 2018; Published: 27 May 2018 Abstract: The main scope of this study investigated the occurrence of liquation cracking in the heat-affected zone (HAZ) of IN738 superalloy weld, IN738 is widely used in gas turbine blades in land-based power plants. Microstructural examinations showed considerable amounts of γ’ uniformly precipitated in the γ matrix. Electron probe microanalysis (EPMA) maps showed the γ-γ’ colonies were rich in Al and Ti, but lean in other alloy elements. Moreover, the metal carbides (MC), fine borides (M3B2 and M5B3), η-Ni3Ti, σ (Cr-Co) and lamellar Ni7Zr2 intermetallic compounds could be found at the interdendritic boundaries. The fracture morphologies and the corresponding EPMA maps confirmed that the liquation cracking in the HAZ of the IN738 superalloy weld resulted from the presence of complex microconstituents at the interdendritic boundaries. Keywords: IN738 superalloy; welding; HAZ cracking; microconstituent 1. Introduction The superior tensile strength, creep and oxidation resistance at elevated temperature make Ni-base superalloys used extensively in industrial gas turbines [1].
    [Show full text]
  • Toxicological Profile for Zinc
    TOXICOLOGICAL PROFILE FOR ZINC U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service Agency for Toxic Substances and Disease Registry August 2005 ZINC ii DISCLAIMER The use of company or product name(s) is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry. ZINC iii UPDATE STATEMENT A Toxicological Profile for Zinc, Draft for Public Comment was released in September 2003. This edition supersedes any previously released draft or final profile. Toxicological profiles are revised and republished as necessary. For information regarding the update status of previously released profiles, contact ATSDR at: Agency for Toxic Substances and Disease Registry Division of Toxicology/Toxicology Information Branch 1600 Clifton Road NE Mailstop F-32 Atlanta, Georgia 30333 ZINC vi *Legislative Background The toxicological profiles are developed in response to the Superfund Amendments and Reauthorization Act (SARA) of 1986 (Public law 99-499) which amended the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA or Superfund). This public law directed ATSDR to prepare toxicological profiles for hazardous substances most commonly found at facilities on the CERCLA National Priorities List and that pose the most significant potential threat to human health, as determined by ATSDR and the EPA. The availability of the revised priority list of 275 hazardous substances was announced in the Federal Register on November 17, 1997 (62 FR 61332). For prior versions of the list of substances, see Federal Register notices dated April 29, 1996 (61 FR 18744); April 17, 1987 (52 FR 12866); October 20, 1988 (53 FR 41280); October 26, 1989 (54 FR 43619); October 17, 1990 (55 FR 42067); October 17, 1991 (56 FR 52166); October 28, 1992 (57 FR 48801); and February 28, 1994 (59 FR 9486).
    [Show full text]
  • Refining of Non-Ferrous Metals
    REFINING OF NON-FERROUS METALS J. G. BERRY- Abstract Fundamentals and Examples The fundamentals of refining of non - ferrous How, then, is the objective achieved ? It metals have been outlined . Examples of removal may be achieved by using the affinity of an electrolysis, of impurities by selective oxidation , undesirable element for another element, thus distillation , volatilization , etc., have been given. Refining of copper, lead, zinc, tin, and some other forming a compound, which is insoluble in the metals have been described . The importance of metal to be refined and which can easily be economics and time involved in refining process removed. Selective oxidation, electrolysis, has been stressed, distillation or volatilization may be used, while flotation, magnetic separation or chemi- cal reaction may be used to remove undesir- Introduction able elements prior to the reduction stage. T will be my endeavour in this paper to One of the earliest attempts at refining I indicate the fundamentals of refining would be the ` purification' of gold by as. they are applied to the more common thermal methods, while the most recent members of this group, with a description of development in this field is the solution and some of the processes, and, in doing so, I precipitation of metals under controlled hope to promote discussion which, after all, pressures from ores and concentrates or is the objective of this symposium. scrap, such as brass. In the fire-refining of copper; many im- purities are oxidized and removed in the Definition slag, these impurities being oxidized in pre- What, then, is the definition of ` refining ' ? ference to the copper itself.
    [Show full text]
  • The Metallurgy of Antimony
    Chemie der Erde 72 (2012) S4, 3–8 Contents lists available at SciVerse ScienceDirect Chemie der Erde journal homepage: www.elsevier.de/chemer The metallurgy of antimony Corby G. Anderson ∗ Kroll Institute for Extractive Metallurgy, George S. Ansell Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO 80401, United States article info abstract Article history: Globally, the primary production of antimony is now isolated to a few countries and is dominated by Received 4 October 2011 China. As such it is currently deemed a critical and strategic material for modern society. The metallurgical Accepted 10 April 2012 principles utilized in antimony production are wide ranging. This paper will outline the mineral pro- cessing, pyrometallurgical, hydrometallurgical and electrometallurgical concepts used in the industrial Keywords: primary production of antimony. As well an overview of the occurrence, reserves, end uses, production, Antimony and quality will be provided. Stibnite © 2012 Elsevier GmbH. All rights reserved. Tetrahedrite Pyrometallurgy Hydrometallurgy Electrometallurgy Mineral processing Extractive metallurgy Production 1. Background bullets and armory. The start of mass production of automobiles gave a further boost to antimony, as it is a major constituent of Antimony is a silvery, white, brittle, crystalline solid that lead-acid batteries. The major use for antimony is now as a trioxide exhibits poor conductivity of electricity and heat. It has an atomic for flame-retardants. number of 51, an atomic weight of 122 and a density of 6.697 kg/m3 ◦ ◦ at 26 C. Antimony metal, also known as ‘regulus’, melts at 630 C 2. Occurrence and mineralogy and boils at 1380 ◦C.
    [Show full text]
  • Chemistry As a Tool for Historical Research: Identifying Paths of Historical Mercury Pollution in the Hispanic New World
    Bull. Hist. Chem., VOLUME 37, Number 2 (2012) 61 CHEMISTRY AS A TOOL FOR HISTORICAL RESEARCH: IDENTIFYING PATHS OF HISTORICAL MERCURY POLLUTION IN THE HISPANIC NEW WORLD Saúl Guerrero, History Department, McGill University, Montreal, QC H3A 2T7, Canada, [email protected] Introduction silver ores to identify and quantify the different mercury loss vectors that resulted from the amalgamation process This article is the first of a series that explore the as practiced in the Hispanic New World. potential of chemistry as an efficient tool for historical research. Basic chemical principles such as the The Scale of Anthropogenic Emissions of stoichiometry of chemical reactions provide the historian Mercury in the New World with a powerful tool to judge the reliability of archival records and interpret better the historiography of events From 1521 to 1810 Spain produced nearly 69% of that relate directly to processes of production based the total world output of silver from its mines in New on chemical reactions. Chemical mass balances have Spain (present day Mexico) and in the Vice-Royalty of determined both revenue streams and environmental Peru (present day Peru and Bolivia). During this period consequences in the past. there was no other non-Hispanic major silver produc- A very appropriate case study to apply this ap- tion in the New World (2). The global economic impact proach is the first industrial scale chemical process to of these exports of silver to Europe and China during have caused a global economic impact. The application the Early Modern Era has received wide coverage in of mercury amalgamation to extract silver from the ores the historiography of this period (3).
    [Show full text]
  • Lead Dross Bismuth Rich (Updated 15.11.2019).Xlsx 1
    Lead Dross, Bismuth Rich Substance Name: Substance Information Page: Lead, dross bismuth rich https://echa.europa.eu/registration-dossier/-/registered-dossier/14687 Legend Decisive substance sameness criterion Indicative substance sameness criterion Substance description: EC description: A scum formed on the surface of molten lead during the process of removing No substance sameness bismuth by the addition of calcium and magnesium. It consists of lead containing calcium and criterion magnesium bismuthides. Original / SIEF description: Lead, dross bismuth rich is formed when calcium and/or magnesium are added to molten lead bullion to remove bismuth. Lead dross, bismuth rich consists of variable amounts of lead, zinc, silver, bismuth and other metals in either alloy form or as compounds such as oxides. Substance Identity EC/list name: Lead, dross, bismuth SMILES: not applicable rich IUPAC name: InChl: not applicable Other names Type of substance: UVCB EC/List no.: 273-792-0 origin: Inorganic CAS no.: 69029-46-5 Molecular formula: not applicable Substance listed SID parameters Sameness criteria Indication of variability (fixed, low or high variation) Sources (input materials) The main starting material is lead, bullion (EC 308-011-5) typically from the primary sector but Low may include lead, bullion produced from non-battery scrap and other secondary sources. The lead, bullion starting material has usually been desilverised via the Parkes Process and dezinced by vacuum distillation, as required); calcium and/or magnesium are added to the molten lead bullion bath. Process The manfacture of 'lead, dross, bismuth rich' relies on the formation of high melting point Fixed intermetallic compounds which have lower density than lead via the Kroll-Betterton process in a refining kettle.
    [Show full text]