coatings Article Application of Ethylene Oxide Gas and Argon Gas Mixture System Method for Scale Deacidification of Cellulose-Based Cultural Heritage Collections Yunpeng Qi, Zhihui Jia *, Yajun Zhou, Yong Wang, Guangtao Zhao, Xiaolian Chao, Huiping Xing * and Yuhu Li * School of Materials Science and Engineering, Engineering Research Center of Historical Cultural Heritage Conservation, Ministry of Education, Shaanxi Normal University, Xi’an 710119, China;
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[email protected] (Y.L.); Tel.: +86-029-8153-0715 (Z.J. & H.X. & Y.L.) Abstract: Deacidification plays an important role in the conservation of paper-based cultural heritage objects. Herein, a novel approach for the conservation of scale paper-based cultural heritage objects is proposed using a mixture of argon and ethylene oxide (EO-Ar) for the first time. The optimum process conditions for deacidification of ethylene oxide and argon mixture system are determined by orthogonal testing. To evaluate the stabilization effect of paper treated with EO-Ar, the degradation of the mechanical properties (tensile strength, folding endurance and tearing strength tests) of paper after artificial aging was evaluated. The results show that the treated paper had better durability with respect to tensile strength, folding endurance and tearing strength. Additionally, thermal Citation: Qi, Y.; Jia, Z.; Zhou, Y.; stability, crystallinity and fiber wall thickness increased after EO-Ar treated, which was determined Wang, Y.; Zhao, G.; Chao, X.; Xing, H.; by scanning electron microscope (SEM), diffraction of X-rays (XRD), and thermo gravimetric (TG) Li, Y.