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(12) United States Patent (10) Patent No.: US 8,642,021 B2 Brautigam Et Al

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(12) United States Patent (10) Patent No.: US 8,642,021 B2 Brautigam Et Al USOO8642021B2 (12) United States Patent (10) Patent No.: US 8,642,021 B2 Brautigam et al. (45) Date of Patent: *Feb. 4, 2014 (54) CONDITIONING COMPOSITION FOR HAIR FOREIGN PATENT DOCUMENTS (75) Inventors: Ina Brautigam, Darmstadt (DE); Frank DE 2630560 1/1978 ............... A61K 7.48 EP O315541 5, 1989 ............... A61K 7.48 Hermes, Seeheim (DE) FR 241 1001 7, 1979 ............... A61K 700 JP O7327633. A * 12/1995 (73) Assignee: Kao Germany GmbH, Darmstadt (DE) WO WOOO28966 A1 * 5, 2000 WO WOO3,070208 A1 8/2003 ............. A61K 7,134 (*) Notice: Subject to any disclaimer, the term of this patent is extended or adjusted under 35 OTHER PUBLICATIONS U.S.C. 154(b) by 1520 days. Abstract Accession No. 2000:35.1345 from the CaPlus database on This patent is Subject to a terminal dis STN, the bibliography, abstract and indexing data for WO 200028966 claimer. A1, downloaded on Aug. 8, 2007, 2 pages.* Quest International: “Yogurtene” Cosmetic Ingredients (Jun. 2000) (21) Appl. No.: 11/001,840 pp. 1-17.* Machine translation of JP 07327633A dowloaded from the JPO Feb. (22) Filed: Dec. 2, 2004 14, 2012.* thehealthyeating.org website (www.healthyeating.org/Milk-Dairy/ (65) Prior Publication Data Nutrients-in-Milk-Cheese-Yogurt/Yogurt-Nutrition. aspx?Referer-dairycouncilofca (downloaded Feb. 28, 2013).* US 2005/O152863 A1 Jul. 14, 2005 Website: Clairol's Touch of Yoghurt Shampoo (http://brandfailures. (30) Foreign Application Priority Data blogspot.com/2006/12/other-famous-brand-idea-failures.html) downloaded Feb. 28, 2013).* Skin Deep website http://www.ewg.org/skindeepfingredient/ Dec. 5, 2003 (EP) ..................................... O3O27985 702759/GUAR HYDROXYPROPYLTRIMONIUM CHLO RIDE/downloaded Sep. 29, 2013.* (51) Int. Cl. European Search Report for application No. EP 03 027985 dated A6 IK 8/00 (2006.01) May 19, 2004. (52) U.S. Cl. USPC ... 424/70.1; 424/70.12: 424/93.1; 424/93.45 * cited by examiner (58) Field of Classification Search USPC ................ 424/70.1, 70.2, 70.4, 70.11, 70.12, Primary Examiner — Susan Hanley 424/70.121, 70.19, 70.21, 70.27, 70.28, (74) Attorney, Agent, or Firm — Norris McLaughlin & 424/70.31, 157.1, 535, 93.1, 93.45 Marcus PA See application file for complete search history. (57) ABSTRACT (56) References Cited The present invention is about conditioning compositions for U.S. PATENT DOCUMENTS hair comprising spray dried yoghurt powder and at least one cationic conditioning agent. With the compositions of the 3,984,566 A * 10/1976 Van Scott et al. ............. 514,460 present invention hair properties such as Smoothness, elastic 4,035,267 A * 7, 1977 Gleckler et al. ... 132,202 ity, Volume and body and shine is improved. According to the 4,268,500 A 5/1981 Cloninger ....................... 424f70 present invention the yoghurt powder comprising composi 5,385,743 A * 1/1995 Hans van der Schaft ....... 426,42 6,635,702 B1 * 10/2003 Schmucker-Castner tions can be applied to hair as a shampoo, conditioner either et al. ............................. 524,291 leave in and/or rinse off types. 6,923,954 B2* 8/2005 Doi et al. ... 424.70.19 2005/0074440 A1* 4/2005 Lin ............................ 424/9345 17 Claims, No Drawings US 8,642,021 B2 1. 2 CONDITIONING COMPOSITION FOR HAIR tioner, treatment, lotions, and gels. Those compositions used especially after shampooing can be applied to hair either as a This invention is about composition for hair with a natural leave-in or as a rinse off compositions. ingredient. Natural ingredient used is yoghurt powder. Hair cleansing preparation of the present invention can be Hair care compositions have been found their application 5 in the form of conventional liquid thickened shampoo, as well for many decades. Although the state of the art is quite well in the form of ready to use foam delivered either from a established there is still need for improvements. pump-foamer or from an aerosol bottle. In the case that an Natural ingredients have always been attractive to the con aerosol foam preparation is preferred, propellant gas must be Sumer. Compositions containing natural ingredients espe added to the formulation. cially derived from the edible ones have always been regarded 10 Cleansing shampoo composition of the present invention as safer than any other composition offered mainly based on comprises at least one Surfactant selected from anionic, non synthetic raw materials. Designing modern cosmetic formu ionic and/or amphoteric or Zwitterionic Surfactants at a con lations solely on the basis of natural ingredients will probably centration range of 2 to 60%, preferably 5 to 50% and more take more time in the future. preferably 5 to 40% by weight, calculated to the total com In cosmetic magazines, periodicals as well as textbooks, 15 position. the use of natural ingredients have been shown together with Anionic surfactants suitable within the scope of the inven synthetic raw materials. Chemically modified active ingredi tion are preferably present in an amount from 1 to about 30%, ents gained from natural resources are as well found their preferably 2 to 25% and most preferably 2-20% by weight, applications in cosmetics. calculated to the total composition. DE 44.29928 is on the use of gingko extract in skin care 20 These are anionic Surfactants of the Sulfate, Sulfonate, car compositions for preventing wrinkle formation. Green tea boxylate and alkyl phosphate type, especially, of course, extract containing hair treatment composition is disclosed in those customarily used in shampoo compositions, for DE 19735 865. The same extract has as well been found to example, the known Co-C-alkyl sulfates, and in particular deliver beneficial effects in permanent shaping process the respective ether Sulfates, for example, Ca-Ca-alkyl ether including reducing and oxidative treatments of hair (DE 197 25 sulfate, lauryl ether sulfate, especially with 1 to 4 ethylene 49 164). oxide groups in the molecule, monoglyceride (ether) Sulfates, In a U.S. Pat. No. 4,268,500, use of yoghurt as a natural fatty acid amide sulfates obtained by ethoxylation and sub product for treating scalp and hair is disclosed. Natural sequent Sulfatation offatty acid alkanolamides, and the alkali yoghurt is used simply by rubbing onto hair and Scalp accord salts thereof, as well as the salts of long-chain mono- and ing to the method disclosed therein. The document does not 30 dialkyl phosphates constituting mild, skin-compatible deter disclose any use of yoghurt or its extracts and its powders in gents. any modern cosmetic formulation. Additional anionic surfactants useful within the scope of In recently published PCT application, WO 03/070208, the invention are C-olefin sulfonates or the salts thereof, and use of yogurt is disclosed for improvement of non-oxidative in particular alkali salts of SulfoSuccinic acid semesters, for hair colouring. The disclosure contains as well shampoo and 35 example, the disodium salt of monooctyl SulfoSuccinate and conditioner compositions to be used for improving colour alkali salts of long-chain monoalkyl ethoxysulfoSuccinates. retention on non-oxidatively coloured hair. The document, Suitable surfactants of the carboxylate type are alkyl poly however does not deal with hair conditioning compositions ether carboxylic acids and the salts thereof of the formula for hair. It has surprisingly been found out that by incorporating 40 yoghurt powder into a hair cleansing and/or caring/condition wherein R is a Cs-Co-alkyl group, preferably a C-C- ing compositions such as shampoo, conditioner, rinse off alkyl group, n is a number from 1 to 20, preferably 2 to 17, and treatment, leave-in treatment, properties of hair is improved X is H or preferably a cation of the group sodium, potassium, dramatically in terms of smoothness, combability, shine, Vol magnesium and ammonium, which can optionally be ume and body and elasticity. 45 hydroxyalkyl-substituted, as well as alkyl amido polyether Thus, the subject matter of the present invention is provid carboxylic acids of the general formula ing compositions for hair comprising yoghurt powder and a cationic conditioning ingredient. It is yet another subject of the present invention that the use R-C-N-CH-CH-(CHO)-CHCOOX of conditioning compositions comprising yoghurt powder 50 and at least one cationic conditioning agent for improving O H hair properties mentioned above. Yoghurt powder is a raw material prepared by spray drying wherein R and X have the above meanings, and n is in of natural yoghurt after completion of fermentation. Yoghurt particular a number from 1 to 10, preferably 2.5 to 5. powder comprises the following major components: 55 Such products have been known for Some time and are on approximately 53.5% lactose, the market, for example, under the trade name “AKYPOR” approximately 25% proteins, and AKYPO-SOFTR). approximately 7.5% lactic acid, Also useful are Cs-Co-acyl isethionates, alone or in approximately 5% minerals and trace elements, admixture with otheranionic Surfactants, as well as Sulfofatty approximately 1% vitamines, and 60 acids and the esters thereof. approximately 2% lipids. It is also possible to use mixtures of several anionic Surfac Compositions of the present invention comprise yoghurt tants, for example, a mixture of an O-olefin Sulfonate and a powder in a concentration range of 0.01 to 10%, preferably sulfosuccinate, preferably in a proportion of 1:3 to 3:1, or of 0.01 to 5%, more preferably 0.01 to 3 by weight calculated to an ether sulfate and a polyether carboxylic acid or alkyl total composition. 65 amidoether carboxylic acid. Compositions for hair according to the present invention An overview of the anionic surfactants used in liquid body are any of those well-known types such as shampoo, condi cleansing compositions can furthermore be found in the US 8,642,021 B2 3 4 monography of K.
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