§ 414.110 40 CFR Ch. I (7–1–00 Edition)
[52 FR 42568, Nov. 5, 1987, as amended at 58 PSES and PSNS 1 FR 36893, July 9, 1993] Maximum Effluent characteristics Maximum for any for any monthly Subpart K—Indirect Discharge one day average Point Sources Acenaphthene ...... 47 19 Anthracene ...... 47 19 SOURCE: 58 FR 36893, July 9, 1993, unless Benzene ...... 134 57 otherwise noted. Bis(2-ethylhexyl) phthalate ...... 258 95 Carbon Tetrachloride ...... 380 142 § 414.110 Applicability; description of Chlorobenzene ...... 380 142 Chloroethane ...... 295 110 the subcategory of indirect dis- Chloroform ...... 325 111 charge point sources. Di-n-butyl phthalate ...... 43 20 1,2-Dichlorobenzene ...... 794 196 The provisions of this subpart are ap- 1,3-Dichlorobenzene ...... 380 142 plicable to the process wastewater dis- 1,4-Dichlorobenzene ...... 380 142 charges resulting from the manufac- 1,1-Dichloroethane ...... 59 22 ture of the OCPSF products and prod- 1,2-Dichloroethane ...... 574 180 1,1-Dichloroethylene ...... 60 22 uct groups defined by § 414.11 from any 1,2-trans-Dichloroethylene ...... 66 25 indirect discharge point source. 1,2-Dichloropropane ...... 794 196 1,3-Dichloropropylene ...... 794 196 Diethyl phthalate ...... 113 46 § 414.111 Toxic pollutant standards for Dimethyl phthalate ...... 47 19 indirect discharge point sources. 4,6-Dinitro-o-cresol ...... 277 78 (a) Any point source subject to this Ethylbenzene ...... 380 142 Fluoranthene ...... 54 22 subpart must achieve discharges not Fluorene ...... 47 19 exceeding the quantity (mass) deter- Hexachlorobenzene ...... 794 196 mined by multiplying the process Hexachlorobutadiene ...... 380 142 Hexachloroethane ...... 794 196 wastewater flow subject to this subpart Methyl Chloride ...... 295 110 times the concentration listed in the Methylene Chloride ...... 170 36 following table. Naphthalene ...... 47 19 Nitrobenzene ...... 6,402 2,237 (b) In the case of lead, zinc, and total 2-Nitrophenol ...... 231 65 cyanide the discharge quantity (mass) 4-Nitrophenol ...... 576 162 shall be determined by multiplying the Phenanthrene ...... 47 19 concentrations listed in the following Pyrene ...... 48 20 Tetrachloroethylene ...... 164 52 table for these pollutants times the Toluene ...... 74 28 flow from metal-bearing waste streams Total Cyanide ...... 1,200 420 for metals and times the flow from the Total Lead ...... 690 320 Total Zinc 2 ...... 2,610 1,050 cyanide-bearing waste streams for 1,2,4-Trichlorobenzene ...... 794 196 total cyanide. The metal-bearing waste 1,1,1-Trichloroethane ...... 59 22 streams and cyanide-bearing waste 1,1,2-Trichloroethane ...... 127 32 Trichloroethylene ...... 69 26 streams are defined as those waste Vinyl Chloride ...... 172 97 streams listed in Appendix A of this 1 All units are micrograms per liter. part, plus any additional OCPSF proc- 2 Total Zinc for Rayon Fiber Manufacture that uses the vis- ess wastewater streams identified by cose process and Acrylic Fiber Manufacture that uses the zinc chloride/solvent process is 6,796 µg/l and 3,325 µg/l for max- the control authority on a case-by-case imum for any one day and maximum for monthly average, basis as metal or cyanide bearing based respectively. upon a determination that such streams contain significant amounts of APPENDIX A TO PART 414—NON- the pollutants identified above. Any COMPLEXED METAL-BEARING WASTE such streams designated as metal or STREAMS AND CYANIDE-BEARING cyanide bearing must be treated inde- WASTE STREAMS pendently of other metal or cyanide Chromium bearing waste streams unless the con- trol authority determines that the Methylhydroabietate/Esterification of combination of such streams, prior to hydroabietic acid (rosin) with methanol treatment, with the Appendix A waste Acrylic acid/Oxidation of propylene via acro- streams will result in substantial re- lein N-butyl alcohol/Hydrogenation of n- duction of these pollutants. This deter- Butyraldehyde, Oxo process mination must be based upon a review Cyclohexanone/From phenol via of relevant engineering, production, cyclohexanol by hydrogenation-dehydro- and sampling and analysis information. genation
230
VerDate 11
Fatty amines/Hydrogenation of fatty nitriles Fatty amines/Hydrogenation of fatty nitriles (batch) (batch) Helioptropin/Oxidation of isosafrole, chro- Geraniol/B-Myrcene + Hydrogen chloride, mium catalyst esterification of geranyl chloride, hydrol- Isobutanol/Hydrogenation of ysis of geranyl acetate isobutyraldehyde, Oxo process Furfuryl alcohol/Hydrogenation of furfural Cyclohexyl Mercaptan/Cyclohexanol + Hy- Geranial (Citral)/Oxidation of geraniol (cop- drogen sulfide per catalyst) Ethyl Mercaptan/Ethanol + Hydrogen sulfide Glyoxal/Oxidation of ethylene glycol Methanol/H.P. Synthesis from natural gas Isobutanol/Hydrogenation of via synthetic gas isobutyraldehyde, Oxo process Oxo Alcohols, C7–C11/Carbonation & hydro- Isopropanol/Catalytic hydrogenation of ace- genation of C6–C10 Olefins tone Polyoxypropylene diamine/Polypropylene 2-Mercaptobenzothiazoles, copper salt/2- glycol + Ammonia Mercaptobenzothiazole + copper salt n-Propyl alcohol/Hydrogenation of Methanol/High pressure synthesis from nat- propionaldehyde, Oxo process ural gas via synthetic gas SAN resin/Suspension polymerization Methanol/Low pressure synthesis from nat- Styrene/Dehydrogenation of ethylbenzene ural gas via synthetic gas Styrene/Dehydration of methyl benzyl alco- Methyl ethyl ketone/Dehydrogenation of sec- hol (coproduct of propylene oxide) Butanol 1-Tetralol, 1-Tetralone mix/Oxidation of Oxo alcohols, C7–C11/Carbonation & hydro- tetralin (1,2,3,4-Tetrahydronaphthalene) genation of C6–C10 olefins 3,3,3-Trifluoropropene/Catalyzed hydrogen Phenol/Liquid phase oxidation of benzoic fluoride exchange with chlorinated pro- acid pane Polyoxyalkylene amines/Polyoxyalkylene Vinyl toluene/Dehydrogenation (thermal) of glycol + ammonia ethyltoluene Polyphenylene oxide/Solution polymeriza- tion of 2,6-xylenol by oxidative coupling Copper (cuprous salt catalyst) Methylhydroabietate/Esterification of Polyoxypropylene diamine/Polypropylene hydroabietic acid (rosin) with methanol glycol + Ammonia Acetaldehyde/Oxidation of ethylene with cu- Quinaldine (dye intermediate)/Skraup reac- pric chloride catalyst tion of aniline + crotonaldehyde Acetic acid/Catalytic oxidation of butane Silicones, silicone fluids/Hydrolysis and con- Acetone/Dehydrogenation of isopropanol densation of chlorosilanes Acrylamide/Catalytic hydration of acrylo- Silicones, silicone rubbers/Hydrolysis and nitrile condensation of chlorosilanes Acrylic acid/Oxidation of propylene via acro- Silicones, silicone specialties (grease, disper- lein sion agents, defoamers & other products) Acrylonitrile/Propylene ammoxidation Silicones: Silicone resins/Hydrolysis & con- Adipic acid/Oxidation of cyclohexanol- densation of methyl, phenyl & vinyl cyclohexanone mixture chlorosilanes Adipic acid/Oxidation of cyclohexane via Silicones: Silicone fluids/Hydrolysis of cyclohexanol-cyclohexanone mixture chlorosilanes to acyclic & cyclic Allynitrile/Allychloride + sodium cyanide organosiloxanes Aniline/Hydrogenation of nitrobenzene Styrene/Dehydration of a-Methylbenzyl alco- Benzofurans, 2,3-Dihydro-2,2-dimethyl-7- hol (coproduct of propylene oxide) benzofuranol/ from o-Nitrophenol + Meth- Tetrachloroethylene (perchloroethylene)/ allyl chloride Oxyhydrochlorination of tetrachloroethane n-Butyl alcohol/Hydrogenation of n- Tris(anilino)s-triazine/Cyanuric chloride + Butyraldehyde, Oxo process aniline + cogeners 1,4-Butanediol/Hydrogenation of 1,4- Trichloroethylene/Oxyhydrochlorination of butynediol tetrachloroethane Butryolactone/Dehydrogenation of 1,4- Unsaturated polyester resin/Reaction of ma- butanediol leic anhydride + phthalic anhydride + pro- Caprolactam/From cyclohexane via pylene glycol polyester with styrene or cyclohexanone and its oxime methyl methacrylate Lilian (hydroxydihydrocitronellal)/Hydra- Lead tion and oxidation of citronellol 1,2-Dichloroethane/Oxyhydrochlorination of Alkyd resin/Condensation polymerization ethylene Alkyd resins/Condensation polymerization of Dialkyldithiocarbamates, metal salts/ phthalic anhydride + glycerin + vegetable Dialkylamines + carbon disulfide oil esters 2-Ethylhexanol/from n-Butyraldehyde by Dialkydithiocarbamates, metal salts/ Aldo condensation and hydrogenation Dialkylamines + carbon disulfide
231
VerDate 11
Thiuram (dimethyldithiocarbamate) 2-Ethylhexanol/from n-Butyraldehyde by hexasulfide/Dimethyldithiocarbamate + Aldol condensation and hydrogenation sulfur Fatty acids, hydrogenated/tallow & coco Triphenylmethane dyes (methyl violet)/Con- acids + Hydrogen densation of Formaldehyde + N- Fatty amines/Hydrogenation of fatty nitriles Methylaniline + N,N-dimethylaniline, oxi- (batch) dation of reaction product Fatty amines/Hydrogenation of tallow & 4,4′-Bis-(N,N-dimethylaniline) carbinol, coco nitriles Michler’s hydrol/Oxidation of 4,4′-Meth- Glyoxal-urea formaldehyde textile resin/con- ylene-bis(N,N-dimethylaniline) with lead densation to N-bis(hydroxymethyl) ureas & oxide N,N′-(dihydroxyethyl) ureas Naphthenic acid salts 11-hexadecenal/Coupling rxns, low pressure Stearic acid, metal salts/Neutralization with hydrogenation a metallic base Hexahydrophthalic anhydride/Condensation of butadiene & maleic anhydride (Diels- Nickel Alder reaction) + hydrogenation Isobutanol/Hydrogenation of Acetates, 7,11-Hexadecadien-1-ol isobutyraldehyde, Oxo process (gossyplure)/Coupling reactions, low pres- Diisobutyl amine/Ammonolysis of isobutanol sure hydrogenation, esterification Isopropyl amines (mono, di)/Reductive Acetates, 9-dodecen-1-ol (pheromone)/Cou- ammination (Ammonia + Hydrogen) of pling reactions, low pressure hydro- isopropanol genation, esterification Linalool/Pyrolysis of 2-Pinanol Acrylic acid/oxidation of propylene via acro- Methanol/High pressure synthesis from nat- lein ural gas via synthetic gas Acrylonitrile/Propylene ammoxidation Methanol/Low pressure sythesis fron natural n-Alkanes/Hydrogenation of C6-C22 alpha gas via synthetic gas olefins (ethylene oligomers) Methanol/Butane oxidation Adiponitrile/Direct cyanation of butadiene Tris-(hydroxymethyl) methyl amine/Hydro- Alkyl amines/Amination of alcohols genation of tris(hydroxymethyl) 4-Aminoacetanilide/Hydrogenation of 4- nitromethane Nitroacetanilide N-Methyl morpholine/Morpholine + Meth- BTX/Hydrogenation of olefins (cyclohexenes) anol Terphenyls, hydrogenated/Nickel catalyst, N-Ethyl morpholine/Morpholine + Ethanol hydrogenation of terphenyl 2-Methyl-7,8-epoxy octadecane/Coupling re- Bisphenol-A, hydrogenated actions, low pressure hydrogenation, (Biscyclohexanol-A)/Hydrogenation of epoxidation Bisphenol-A Alpha-Olefins/Ethylene oligomer, & Zeigler Butadiene (1,3)/Extractive distillation of C–4 Cat. pyrolyzates Petroleum hydrocarbon resins, hydro- n-Butanol/Hydrogenation of n- genated/Hydrogenation of petroleum hy- Butyraldehyde, Oxo process drocarbon resin products 1,3-Butylene glycol/Hydrogenation of Pinane/Hydrogenation of A-Pinene acetaldol 2-Pinanol/Reduction of pinane hydroperoxide 1,4-Butanediol/Hydrogenation of 1,4- Bis-(p-Octylphenol) sulfide, Nickel salt/p- butynediol Octylphenol + sulfur chloride (S2C12), neu- Butylenes (mixed)/Distillation pf C4 tralize with Nickel base pyrolyzates Piperazine/Reductive amination of ethanol 4-Chloro-2-aminophenol/Hydrogenation of 4- amine (ammonia & hydrogenation, metal Chloro-2-nitrophenol catalyst) Lilial (hydroxydihydrocitronellal)/Hydration N,N-Dimethylpiperazine/Condensation piper- and oxidation of citronellol azine + formaldehyde, hydrogenation Cycloparaffins/Catalytic hydrogenation of Polyoxylalkylene amines/Polyoxyalkylene aromatics in kerosene solvent glycol + Ammonia Cyclohexanol/Hydrogenation of phenol, dis- Polyoxypropylene diamine/Polypropylene tillation glycol + Ammonia Cyclohexanone/From phenol via 2-Amino-2-methyl-1-propanol/Hydrogenation cyclohexanol by hydrogenation-dehydro- of 2-Nitro 2-methyl-1-propanol genation 3-Methoxypropyl amine/Reductive amination Dialkyldithiocarbamates, metal salts/ of acrylamide with methanol & hydrogen Dialkylamines + carbon disulfide N-Propylamine/Reductive ammination (am- Ethylamine/Reductive amination of ethanol monia + hydrogen) of n-propanol Ethylamines (mono, di, tri)/Reductive Sorbitol/Hydrogenation of sugars ammination (ammonia + hydrogen) of eth- Sulfolane/Condensation butadiene + sulfur anol dioxide, Hydrogenation Isoeugenol, high % trans/Separation of Thionocarbamates, N-Ethyl-o-isopropyl/Iso- mixed cis & trans isoeugenols propyl xanthate + Ethylamine
232
VerDate 11
Toluene diamine (mixture)/Catalytic hydro- Nylon 6 & 66 copolymers/Polycondensation of genation of dinitrotoluene Nylon salt + Caprolatam Methylated urea-formaldehyde resins (tex- Nylon 6 fiber/Extrusion (melt spinning) tile)/Methylation of urea-formaldehyde Oxo alcohols, C12-C15/Hydroformylation & adduct hydrogenation of C11-C14 olefins Methylated urea-formaldehyde glyoxol (tex- Phenolic urethan resins/Phenol + excess tile resin)/Reaction of methylated urea- formaldehyde + Methylene aniline formaldehyde + glyoxal diisocyanate Polystyrene (crystal) modified/Polystyrene + Zinc sulfonation, chloromethylation and/or Methylhydroabietate, diels-alder adducts/De- amination rivatives of abietic esters from rosin Rayon/Viscose process Acrylic resins/Emulsion or solution polym- SAN resin/Emulsion polymerization erization to coatings Silicones: Silicone rubbers/Hydrolysis and Acrylic resins (latex)/Emulsion polymeriza- condensation of chlorosilanes tion of acrylonitrile with polybutadiene Silicones: Silicone specialties (grease, dis- Acrylic fibers (85% polyacrylonitrile) by so- persion agents, defoamers & other prod- lution polymerization/Wet spinning ucts) Alkyd Resins/Condensation polymerization Silicones: Silicone resins/Hydrolysis & con- of phthalic anhydride + glycerin + vege- densation of methyl, phenyl & vinyl table oil esters chlorosilanes Benzene/By-product of styrene by Silicones: Silicone fluids/Hydrolysis of ethylbenzene dehydrogenation chlorosilanes to acyclic & cyclic Benzene/By-product of vinyl toluene (from organosiloxanes ethyltoluene) Stearic acid, metal salts/Neutralization with n-butyl alcohol/Hydrogenation of n- a metallic base Butyraldehyde, Oxo process Styrene/Dehydrogenation of ethylbenzene Coumarin (benz-a-pyrone)/Salicylaldehyde, Styrene-butadiene resin/Emulsion polym- Oxo process erization Cycloparaffins/Catalytic hydrogenation of Vinyl acetate/Reduction of acetylene + ace- aromatics in kerosene solvent tic acid Dithiocarbamates, zinc salt/Reaction of zinc Vinyl toluene/Dehydrogenation (thermal) of oxide + Sodium dithiocarbamates ethyltoluene Dialkyldithiocarbamates, metal salts/ Xylenes, mixed/By-product vinyl toluene Diakylamines + Carbon disulfide (from ethyltoluene) Dithiocarbamates, metal salts/ Cyanide Dithiocarbamic acid + metal oxide Thiuram (dimethyldithiocarbamate) Acetone cyanohydrin/Acetone + Hydrogen hexasulfide/Dimethyldithiocarbamate + cyanide sulfur Acetonitrile/By-product of acrylonitrile from Fluorescent brighteners/Coumarin based propylene by ammoxidation Ethyl acetate/Redox reaction (Tschenko) of Acrylic resins/Solution polymerization acetaldehyde Acrylic fiber (85% acrylonitrile)/Suspension Ethylbenzene/Benzene alkylation in liquid polymerization, and wet spinning phase Acrylic fiber (85% acrylonitrile)/Solution po- Ethylbenzyl chloride/Chloromethylation lymerization, and wet spinning (Hydrogen chloride + formaldehyde, zinc Acrylonitrile/Ammoxidation of propylene chloride) of ethylbenzene Adiponitrile/Butadiene + Hydrogen cyanide 2-Ethyl hexanol/Aldol condensation-hydro- (direct cyanation) genation of n-Butyraldehyde Allylnitrile/Allyl chloride + Sodium cyanide Glyoxal-urea formaldehyde textile resin/Con- Dimethoxybenzaldehyde/Hydroquinone di- densation to N-bis (hydroxymethyl) ureas methyl ether + Hydrogen cyanide, hydrol- + N,N′-(Dihydroxyethyl) ureas ysis Isobutanol/Hydrogenation of Benzyl cyanide/Benzyl chloride + Sodium cy- isobutyraldehyde, Oxo process anide Isopropanol/Catalytic hydrogenation of ace- Coal tar products/Distillation of coal tar tone condensate Methallylidene diacetate/Condensation of 2- Cyanoacetic acid/Chloracetic acid + sodium Methypropenal + acetic anhydride cyanide Methanol/Low pressure sythesis from nat- Cyanuric chloride/Catalyzed trimerization of ural gas via synthetic gas cyanogen chloride Methyl chloride/Hydrochlorination of meth- Vat dyes, Indigo paste as Vat Blue 1/Sodam- anol ide + potassium N-Phenylglycine, fused Methylethyl ketone/Dehydrogenation of sec- with caustic/N-phenylglycine + Aniline + Butanol Formaldehyde + Sodium bisulfite, sodium Naphthenic acid salts cyanide, hydrolysis with potassium hy- Nylon droxide
233
VerDate 11
Disperse dyes, Azo and Vat Vat dyes Ethylenediamine tetraacetic acid/Ethylene- Acid dyes diamine + Formaldehyde + Sodium cyanide Azo dyes, metallized/Azo dye + metal acetate Diethylenetriamine pentaacetic acid/ Acid dyes, Azo (including metallized) Diethylenetriamine + Formaldehyde + So- Organic pigments, miscellaneous lakes and dium cyanide toners N,N′-bis(o- Acetamidophenol)ethylenediamine, ferric Copper complex/ Salicyladehyde + Ethylene- diamine + Hydrogen cyanide, hydrolysis to Disperse dyes amide Acid dyes Diethylenetriamine pentaacetic acid, Direct dyes pentasodium salt/Diethylenetriamine Vat dyes pentaacetic acide + caustic Sulfur dyes Ethylenediamine tetraacetic acid, metal Disperse dye coupler/N-substitution of 2- salts/Ethylenediamine tetraacetic acid + Amino-4-acetamidoanisole metal bases Azo dyes, metallized/Azo dye + metal acetate Hydroxyethyl ethylenediamine triacetic Direct dyes, Azo acid, trisodium salt/ Ethylenediamine + Disperse dyes, Azo and Vat Ethylene oxide + Formaldehyde + Sodium Organic pigment Green 7/Copper cyanide, hydrolysis phthalocyanine 5,5-Dimethyl hyantoin/Acetone + ammonia + Organic pigments carbon dioxide + hydrogen cyanide Organic pigments/Phthalocyanine pigments Hydrogen cyanide/By-product of acrylo- Organic pigments/Copper phthalocyanine nitrile by ammoxidation of propylene Iminodiacetic acid/Hexamethylene (Blue Crude) tetraamine + Hydrogen cyanide, hydrolysis Organic pigments, miscellaneous lakes and of iminoacetonitrile salt toners Methionine/Acrolein + Methyl mercaptan, Lead with hydrogen cyanide and ammonium car- bonate Organic pigments, Quinacridines Nitrilotriacetic acid/Hexamethylene Organic pigments, Thioindigoids tetraamine + Hydrogen cyanide, hydrolysis Tetraethyl lead/Alkyl halide + sodium-lead of nitrilotriacetonitrile salt alloy Picolines, mixed/Condensation of acetal- Tetramethyl lead/Alkyl halide + sodium-lead dehyde + formaldehyde + ammonia alloy Organic pigments, Azo/Diazotization of ani- line cogener, coupling to B-Napthol Nickel Pyrimidines, 2-Isopropyl-4-methoxy-/ Isobutyronitrile + methanol, ammonia and Azo dyes, metallized/Azo dye + metal acetate methylacetoacetate (ring closure) Zinc Pyridine (synthetic)/Condensation of acetal- dehyde + ammonia + formaldehyde Organic pigments/Azo pigments by Cyanopyridine/Ammoxidation of picoline diazotization and coupling Sarcosine (N-Methyl glycine), sodium salt/ Hexamethylene tetraamine + Sodium cya- [52 FR 42568, Nov. 5, 1987, as amended at 54 nide, hydrolysis FR 27352, June 29, 1989; 57 FR 41844, Sept. 11, Thiophene acetic acid/Chloromethylation 1992] (Hydrogen chloride + Formaldehyde) + So- dium cyanide, hydrolysis PART 415—INORGANIC CHEMI- Tris(anilino)S-triazine/Cyanuric chloride + Aniline and its cogeners CALS MANUFACTURING POINT Triethylorthoformate/Ethanol + Hydrogen SOURCE CATEGORY cyanide Trimethylorthoformate/Methanol + Hydro- Subpart A—Aluminum Chloride Production gen cyanide Subcategory [52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989; 55 FR 26692, June 29, Sec. 1990; 57 FR 41844, Sept. 11, 1992] 415.01 Compliance dates for pretreatment standards for existing sources. APPENDIX B TO PART 414—COMPLEXED 415.10 Applicability; description of the alu- minum chloride production subcategory. METAL-BEARING WASTE STREAMS 415.11 Specialized definitions. [Reserved] Chromium 415.12–415.13 [Reserved] 415.14 Pretreatment standards for existing Azo dye intermediates/Substituted diazo- sources (PSES). nium salts + coupling compounds 415.15 [Reserved]
234
VerDate 11