Koppers Coal Tar Pitch (KC 1830)

Koppers Carbon Materials & Chemicals Pty Ltd Chemwatch Hazard Alert Code: 4

Chemwatch: 57533 Issue Date: 25/01/2017 Version No: 6.1.1.1 Print Date: 01/02/2017 Safety Data Sheet according to WHS and ADG requirements S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Koppers Coal Tar Pitch (KC 1830) Synonyms anode binder pitch, electrode binder pitch, Product Code: KC-1830 (Liquid Pitch) ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash point (including molten metals, molten Proper shipping name salts, etc.) (contains coal tar pitch, high temperature)

Other means of Not Available identification

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified Used in the manufacture of carbon anodes for the aluminium smelting industry; in the manufacture of clay targets for skeet uses or clay pigeon shooting.

Details of the supplier of the safety data sheet

Registered company Koppers Carbon Materials & Chemicals Pty Ltd Koppers Carbon Materials & Chemicals Pty Ltd name Address Woodstock Street Mayfield NSW 2304 Australia PO Box 23 Mayfield NSW 2304 Australia Telephone +61 2 4968 7300 +61 2 4968 7300 Fax +61 2 4967 4998 +61 2 4967 4998 Website www.koppers.com.au www.koppers.com.au Email [email protected] [email protected]

Emergency telephone number

Association / Koppers Carbon Materials & Chemicals Pty Ltd Koppers Carbon Materials & Chemicals Pty Ltd Organisation Emergency telephone +61 2 4968 7300 (24 hours) +61 2 4968 7300 (24 hours) numbers Other emergency Not Available Not Available telephone numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

CHEMWATCH HAZARD RATINGS Min Max Flammability 1 Toxicity 1 0 = Minimum Body Contact 2 1 = Low Reactivity 1 2 = Moderate 3 = High Chronic 4 4 = Extreme

Poisons Schedule Not Applicable

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Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Skin Sensitizer Category 1, Germ cell mutagenicity Category 1B, Germ cell mutagenicity Category 2, Carcinogenicity Category 1A, Reproductive Toxicity Category 1B, Specific target Classification [1] organ toxicity - single exposure Category 3 (respiratory tract irritation), Acute Aquatic Hazard Category 1, Chronic Aquatic Hazard Category 1 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex Legend: VI

Label elements

GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)

H315 Causes skin irritation. H319 Causes serious eye irritation.

H317 May cause an allergic skin reaction. H340 May cause genetic defects.

H341 Suspected of causing genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P201 Obtain special instructions before use. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P261 Avoid breathing mist/vapours/spray. P273 Avoid release to the environment. P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P308+P313 IF exposed or concerned: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P302+P352 IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue P305+P351+P338 rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Precautionary statement(s) Storage

P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

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Substances See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name 65996-93-2 >90 coal tar pitch, high temperature A complex hydrocarbon mixture which includes:

191-24-2 1-8 benzo[ghi]perylene 129-00-0 0.5-5 pyrene

207-08-9 0.5-5 benzo[k]fluoranthene 50-32-8 0.5-5 benz[a]pyrene

218-01-9 0.5-5 chrysene 206-44-0 0.5-5 fluoranthene

85-01-8 0.1-2 phenanthrene 205-99-2 0.1-2 benzo[b]fluoranthene

56-55-3 0.1-1 benz[a]anthracene 193-39-5 1 indeno[1,2,3-cd]pyrene

120-12-7 0.1-0.5 anthracene 83-32-9 0.1-0.5 acenaphthene 86-73-7 0.1-0.5 fluorene 53-70-3 0.1-0.5 dibenz[a,h]anthracene 91-20-3 <0.1 naphthalene 208-96-8 <0.01 acenaphthylene

SECTION 4 FIRST AID MEASURES

Description of first aid measures

For THERMAL burns: Do NOT remove contact lens Lay victim down, on stretcher if available and pad BOTH eyes, make sure dressing does not press on the injured eye by placing thick pads under dressing, above and below the eye. Seek urgent medical assistance, or transport to hospital. Eye Contact If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. In case of burns: Immediately apply cold water to burn either by immersion or wrapping with saturated clean cloth. DO NOT remove or cut away clothing over burnt areas. DO NOT pull away clothing which has adhered to the skin as this can cause further injury. DO NOT break blister or remove solidified material. Quickly cover wound with dressing or clean cloth to help prevent infection and to ease pain. For large burns, sheets, towels or pillow slips are ideal; leave holes for eyes, nose and mouth. DO NOT apply ointments, oils, butter, etc. to a burn under any circumstances. Skin Contact Water may be given in small quantities if the person is conscious. Alcohol is not to be given under any circumstances. Reassure. Treat for shock by keeping the person warm and in a lying position. Seek medical aid and advise medical personnel in advance of the cause and extent of the injury and the estimated time of arrival of the patient. Skin contact causes photosensitisation which can last for 36-72 hours after exposure. Keep out of direct sunlight for the next two to three days to avoid sunburn to the photosensitised skin areas. Use a broad spectrum blockout cream to protect against UV alpha ray exposure. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid Inhalation procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.

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Transport to hospital, or doctor, without delay. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Ingestion Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed Treat symptomatically. For sensitive skin areas product may be removed using cotton wool pad soaked in castor oil.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may Fire Incompatibility result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area. Fire Fighting Avoid spraying water onto liquid pools. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO). May emit acrid smoke. Mists containing combustible materials may be explosive. Combustion products include: Fire/Explosion Hazard , carbon dioxide (CO2) , nitrogen oxides (NOx) , sulfur oxides (SOx) , other pyrolysis products typical of burning organic material.

HAZCHEM 2Y

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures See section 8

Environmental precautions See section 12

Methods and material for containment and cleaning up

Remove all ignition sources. Clean up all spills immediately. Minor Spills Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

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Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Minor hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. No smoking, naked lights or ignition sources. Increase ventilation. Major Spills Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Containers, even those that have been emptied, may contain explosive vapours. Do NOT cut, drill, grind, weld or perform similar operations on or near containers. Electrostatic discharge may be generated during pumping - this may result in fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec). Avoid splash filling. Do NOT use compressed air for filling discharging or handling operations. Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Safe handling Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. DO NOT allow clothing wet with material to stay in contact with skin |Use protective skin cream on exposed skin before and during work shift. To reduce sun sensitivity a sun-blocking lotion (SPF 15plus) can also be applied prior to application of a protective cream. Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Other information Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Metal can or drum Suitable container Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storage Avoid reaction with oxidising agents incompatibility

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

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OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes Australia Exposure coal tar pitch, high Coal tar pitch volatiles (as Not Not 0.2 mg/m3 Not Available Standards temperature benzene solubles) Available Available Australia Exposure Fume (thermally generated) Not Not pyrene 2 mg/m3 Not Available Standards (respirable dust) Available Available

Australia Exposure Not Not benz[a]pyrene Benzo(a)pyrene Not Available Not Available Standards Available Available

Australia Exposure Not Not chrysene Chrysene Not Available Not Available Standards Available Available Australia Exposure Fume (thermally generated) Not Not phenanthrene 2 mg/m3 Not Available Standards (respirable dust) Available Available

Australia Exposure 52 mg/m3 / 10 79 mg/m3 / 15 Not Not naphthalene Naphthalene Standards ppm ppm Available Available

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3 coal tar pitch, high Coal tar pitch volatiles; (Particulate polycyclic aromatic hydrocarbons) 0.6 mg/m3 120 mg/m3 700 mg/m3 temperature benzo[ghi]perylene Benzo(ghi)perylene 30 mg/m3 330 mg/m3 2,000 mg/m3 pyrene Pyrene 0.15 mg/m3 1.7 mg/m3 7.5 mg/m3 benz[a]pyrene Benzo(a)pyrene; (Coal tar pitch volatiles) 0.6 mg/m3 120 mg/m3 700 mg/m3 chrysene Chrysene 0.6 mg/m3 12 mg/m3 69 mg/m3 fluoranthene Fluoranthene 4.1 mg/m3 45 mg/m3 400 mg/m3 phenanthrene Phenanthrene 2.1 mg/m3 23 mg/m3 360 mg/m3 benzo[b]fluoranthene Benz(e)acephenanthrylene; (Benzo(b)fluoroanthene) 0.12 mg/m3 1.3 mg/m3 7.9 mg/m3 benz[a]anthracene Benzo(a)anthracene 1.2 mg/m3 13 mg/m3 79 mg/m3 indeno[1,2,3-cd]pyrene Indeno(1,2,3-cd)pyrene 1.2 mg/m3 13 mg/m3 79 mg/m3 anthracene Anthracene 48 mg/m3 530 mg/m3 3,200 mg/m3 acenaphthene Acenaphthene 3.6 mg/m3 40 mg/m3 240 mg/m3 fluorene Fluorene, 9H- 6.6 mg/m3 72 mg/m3 430 mg/m3 dibenz[a,h]anthracene Dibenza(a,h)anthracene 0.093 mg/m3 1 mg/m3 2.9 mg/m3 naphthalene Naphthalene 15 ppm 83 ppm 500 ppm acenaphthylene Acenaphthylene 10 mg/m3 110 mg/m3 660 mg/m3

Ingredient Original IDLH Revised IDLH coal tar pitch, high 700 mg/m3 80 mg/m3 temperature benzo[ghi]perylene Not Available Not Available pyrene Not Available Not Available benzo[k]fluoranthene Not Available Not Available benz[a]pyrene Not Available Not Available chrysene Not Available Not Available fluoranthene Not Available Not Available phenanthrene Not Available Not Available benzo[b]fluoranthene Not Available Not Available benz[a]anthracene Not Available Not Available indeno[1,2,3-cd]pyrene Not Available Not Available anthracene Not Available Not Available acenaphthene Not Available Not Available fluorene Not Available Not Available dibenz[a,h]anthracene Not Available Not Available naphthalene 500 ppm 250 ppm

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acenaphthylene Not Available Not Available

Exposure controls

For molten materials: Appropriate Provide mechanical ventilation; in general such ventilation should be provided at compounding/ converting areas and at engineering controls fabricating/ filling work stations where the material is heated. Local exhaust ventilation should be used over and in the vicinity of machinery involved in handling the molten material.

Personal protection

Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should Eye and face include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. protection Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]

Skin protection See Hand protection below The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). · When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use. · Contaminated gloves should be replaced. For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended. Hands/feet protection It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times. Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers’ technical data should always be taken into account to ensure selection of the most appropriate glove for the task. Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example: · Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of. · Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Neoprene gloves DO NOT use solvent to clean the skin Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber NOTE: The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

Body protection See Other protection below

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Overalls. P.V.C. apron. Other protection Barrier cream. Skin cleansing cream. Eye wash unit.

Thermal hazards Not Available

Respiratory protection Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Black viscous liquid at temperatures above melting point with a strong aromatic coal tar odour; does not mix with water.

Relative density Physical state Liquid 1.30-1.34 (Water = 1) Partition coefficient Odour Not Available Not Available n-octanol / water

Auto-ignition Odour threshold Not Available >400 temperature (°C) Decomposition pH (as supplied) Not Applicable Not Available temperature Melting point / 105-120 Viscosity (cSt) Not Available freezing point (°C) Initial boiling point Molecular weight Not Available Not Applicable and boiling range (°C) (g/mol) Flash point (°C) >270 (PMOC) Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Applicable Oxidising properties Not Available Upper Explosive Limit Surface Tension Not Available Not Available (%) (dyn/cm or mN/m) Lower Explosive Limit Volatile Component Not Available Not Available (%) (%vol) Vapour pressure (kPa) <0.133 Gas group Not Available Solubility in water Immiscible pH as a solution (1%) Not Applicable (g/L) Vapour density (Air = >1 VOC g/L Not Available 1)

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Unstable in the presence of incompatible materials. Chemical stability Product is considered stable. Hazardous polymerisation will not occur.

Possibility of See section 7 hazardous reactions Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition See section 5 products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to Inhaled the health of the individual.

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The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination. Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time, slurred speech and may progress to unconsciousness. Serious poisonings may result in respiratory depression and may be fatal. Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may Ingestion be fatal or may produce serious damage to the health of the individual. Skin contact with the material may damage the health of the individual; systemic effects may result following absorption. This material can cause inflammation of the skin on contact in some persons. Skin Contact The material may accentuate any pre-existing dermatitis condition Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye This material can cause eye irritation and damage in some persons. Principal routes of exposure are by accidental skin and eye contact and by inhalation of vapours especially at higher temperatures. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. There is ample evidence that this material can be regarded as being able to cause cancer in humans based on experiments and other information. The IARC Monograph (Vol 35) concludes that there is sufficient evidence for the carcinogenicity in experimental animals of Chronic untreated vacuum distillate, acid-treated oils, and aromatic oils, including extracts from solvent treatment of distillates and the high boiling fraction of catalytically cracked oils. Long term exposure to coal tar dusts may produce chronic bronchitis or lung cancer. Dust or fume contact with skin may result in photosensitisation of skin areas and sunburn on frequent exposure to sunlight or ultraviolet radiation. Constant or exposure over long periods to mixed hydrocarbons may produce stupor with dizziness, weakness and visual disturbance, weight loss and anaemia, and reduced liver and kidney function. Skin exposure may result in drying and cracking and redness of the skin.

Koppers Coal Tar TOXICITY IRRITATION Pitch (KC 1830) Not Available Not Available

TOXICITY IRRITATION coal tar pitch, high dermal (rat) LD50: >2000 mg/kg[1] Not Available temperature Oral (rat) LD50: >15000 mg/kg[1]

TOXICITY IRRITATION benzo[ghi]perylene Not Available Not Available

TOXICITY IRRITATION pyrene Oral (rat) LD50: 2700 mg/kg[2] Skin (rabbit): 500 mg/24h - mild

TOXICITY IRRITATION benzo[k]fluoranthene Not Available Not Available

TOXICITY IRRITATION benz[a]pyrene Not Available Skin (mouse): 0.014 mg - mild

TOXICITY IRRITATION chrysene Not Available Not Available

TOXICITY IRRITATION

[2] fluoranthene Dermal (rabbit) LD50: 3180 mg/kg Not Available

Oral (rat) LD50: 2000 mg/kg[2]

TOXICITY IRRITATION phenanthrene Oral (rat) LD50: 1800 mg/kg[2] Not Available

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TOXICITY IRRITATION benzo[b]fluoranthene Not Available Not Available

TOXICITY IRRITATION benz[a]anthracene Not Available Not Available

indeno[1,2,3- TOXICITY IRRITATION cd]pyrene Not Available Not Available

TOXICITY IRRITATION

[1] anthracene dermal (rat) LD50: >1320 mg/kg Not Available

Oral (rat) LD50: >16000 mg/kg[1]

TOXICITY IRRITATION acenaphthene Not Available Not Available

TOXICITY IRRITATION fluorene Not Available Not Available

TOXICITY IRRITATION dibenz[a,h]anthracene Not Available Not Available

TOXICITY IRRITATION

[2] naphthalene dermal (rat) LD50: >2500 mg/kg Eye (rabbit): 100 mg - mild

Oral (rat) LD50: 490 mg/kg[2] Skin (rabbit):495 mg (open) - mild

TOXICITY IRRITATION acenaphthylene Oral (mouse) LD50: 1760 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The production of creosotes and coal tars stems from the incomplete combustion of carbon-containing materials. Physically, they are usually viscous liquids or semisolids that are black or dark brown with a naphthalene-like odour. They have an oily liquid consistency and range in colour from yellowish-dark green to brown and largely contain a COAL TAR PITCH, HIGH mixture of polycyclic aromatic hydrocarbons (PAHs) including phenol. It is likely that their toxicity is due largely to the TEMPERATURE major individual components, phenols, PAHs and others. There is sufficient evidence that coal tar pitches are carcinogenic in humans and there is sufficient evidence that occupational exposure to coal tars as it occurs during the destructive distillation of coal is causally associated with the occurrence of skin tumours in humans.

PYRENE Conjunctival irritation, excitement and muscle contraction recorded. BENZO[K]FLUORANTHENE Tumours at site of application. BENZ[A]PYRENE Exposure to the material for prolonged periods may cause physical defects in the developing embryo (teratogenesis). CHRYSENE Target organs in include skin (tumours at site of application). FLUORANTHENE Equivocal tumorigen bt RTECS criteria. Tumors at site of application recorded. PHENANTHRENE Tumors at site of application. Neoplastic and tumorigenic by RTECS criteria. BENZO[B]FLUORANTHENE Lung, kidney, skin tumors and tumors at site of application recorded. ANTHRACENE Oral (rat) TDLo: 20000 m g/kg/79w -I Skin (mouse): 0.118 mg - mild Equivocal tumorigen by RTECS criteria

DIBENZ[A,H]ANTHRACENE WARNING: This substance has been classified by the IARC as Group 2A: Probably Carcinogenic to Humans. The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure NAPHTHALENE to irritants may produce conjunctivitis.

Koppers Coal Tar Pitch (KC 1830) & PYRENE & Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due FLUORANTHENE & to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following PHENANTHRENE & exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of ANTHRACENE & preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within ACENAPHTHENE & minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence ACENAPHTHYLENE of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic

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inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production. The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other COAL TAR PITCH, HIGH allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the TEMPERATURE & contact allergen is not simply determined by its sensitisation potential: the distribution of the substance and the BENZ[A]PYRENE opportunities for contact with it are equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.

COAL TAR PITCH, HIGH TEMPERATURE & BENZO[GHI]PERYLENE & BENZO[K]FLUORANTHENE & No significant acute toxicological data identified in literature search. BENZO[B]FLUORANTHENE & INDENO[1,2,3- CD]PYRENE & ACENAPHTHENE & DIBENZ[A,H]ANTHRACENE COAL TAR PITCH, HIGH TEMPERATURE & WARNING: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS. BENZ[A]PYRENE BENZO[GHI]PERYLENE & PYRENE & BENZO[K]FLUORANTHENE & CHRYSENE & FLUORANTHENE & NOTE: Substance has been shown to be mutagenic in at least one assay, or belongs to a family of chemicals producing PHENANTHRENE & damage or change to cellular DNA. BENZO[B]FLUORANTHENE & INDENO[1,2,3- CD]PYRENE & ANTHRACENE & DIBENZ[A,H]ANTHRACENE BENZO[GHI]PERYLENE & PYRENE & FLUORANTHENE & The substance is classified by IARC as Group 3: PHENANTHRENE & NOT classifiable as to its carcinogenicity to humans. ANTHRACENE & Evidence of carcinogenicity may be inadequate or limited in animal testing. ACENAPHTHENE & FLUORENE PYRENE & BENZ[A]PYRENE & The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, ANTHRACENE & swelling, the production of vesicles, scaling and thickening of the skin. NAPHTHALENE BENZO[K]FLUORANTHENE & CHRYSENE & BENZO[B]FLUORANTHENE & BENZ[A]ANTHRACENE & WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. INDENO[1,2,3-CD]PYRENE & NAPHTHALENE BENZO[K]FLUORANTHENE & BENZ[A]PYRENE & BENZO[B]FLUORANTHENE Tenth Annual Report on Carcinogens: Substance anticipated to be Carcinogen & BENZ[A]ANTHRACENE & [National Toxicology Program: U.S. Dep. of Health & Human Services 2002] INDENO[1,2,3-CD]PYRENE & DIBENZ[A,H]ANTHRACENE

Acute Toxicity Carcinogenicity Skin Reproductivity Irritation/Corrosion Serious Eye STOT - Single Damage/Irritation Exposure

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Respiratory or Skin STOT - Repeated sensitisation Exposure

Mutagenicity Aspiration Hazard

Legend: – Data available but does not fill the criteria for classification – Data available to make classification – Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source

coal tar pitch, high NOEC 48 Fish 0.001mg/L 4 temperature benzo[ghi]perylene LC50 96 Fish 0.008mg/L 3

benzo[ghi]perylene EC50 48 Crustacea 0.0001326432mg/L 4 benzo[ghi]perylene EC50 96 Algae or other aquatic plants 0.010mg/L 3

benzo[ghi]perylene BCF 24 Crustacea 0.0002mg/L 4 benzo[ghi]perylene EC50 48 Crustacea 0.0010418018mg/L 4

pyrene LC50 96 Fish 0.249mg/L 3 pyrene EC50 48 Crustacea 0.004327936mg/L 4 pyrene EC50 96 Algae or other aquatic plants 0.256mg/L 3 pyrene BCF 24 Algae or other aquatic plants 0.5mg/L 4 pyrene EC50 24 Crustacea >=0.003- <=0.03mg/L 2 pyrene NOEC 168 Fish 0.0152mg/L 4 benzo[k]fluoranthene BCF 24 Crustacea 0.0014mg/L 4 benzo[k]fluoranthene NOEC 144 Fish 0.01mg/L 4 benz[a]pyrene LC50 96 Fish 0.026mg/L 3 benz[a]pyrene EC50 48 Crustacea 0.0009815248mg/L 4 benz[a]pyrene EC50 72 Algae or other aquatic plants 0.005mg/L 4 benz[a]pyrene BCF 12 Fish 7.51mg/L 4 benz[a]pyrene EC50 48 Crustacea 0.0016249408mg/L 4 benz[a]pyrene NOEC 360 Fish 0.00102mg/L 4 chrysene LC50 96 Fish 0.083mg/L 3 chrysene EC50 96 Algae or other aquatic plants 0.087mg/L 3 chrysene BCF 240 Crustacea 0.00136968mg/L 4 chrysene EC50 384 Crustacea 0.027mg/L 3 chrysene NOEC 2016 Fish 0.116331488mg/L 4

fluoranthene LC50 96 Fish 0.0001mg/L 4 fluoranthene EC50 48 Crustacea 0.003984522mg/L 4 fluoranthene EC50 72 Algae or other aquatic plants 0.103mg/L 4 fluoranthene BCF 672 Crustacea 0.125mg/L 4 fluoranthene EC10 144 Crustacea 0.0078mg/L 4 fluoranthene NOEC 744 Crustacea 0.0006mg/L 4 phenanthrene LC50 96 Fish 0.234mg/L 4 phenanthrene EC50 48 Crustacea 0.117mg/L 4 phenanthrene EC50 72 Algae or other aquatic plants 0.324mg/L 4 phenanthrene BCF 24 Algae or other aquatic plants 1mg/L 4 phenanthrene EC50 96 Fish 0.049mg/L 4 phenanthrene NOEC 2160 Fish 0.005mg/L 4 benzo[b]fluoranthene LC50 96 Fish 0.026mg/L 3 benzo[b]fluoranthene EC50 96 Algae or other aquatic plants 0.029mg/L 3 benzo[b]fluoranthene EC50 384 Crustacea 0.011mg/L 3 benz[a]anthracene LC50 96 Fish 0.083mg/L 3

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benz[a]anthracene EC50 48 Crustacea 0.000958776mg/L 4

benz[a]anthracene EC50 96 Algae or other aquatic plants 0.087mg/L 3 benz[a]anthracene BCF 24 Crustacea 0.006mg/L 4

benz[a]anthracene EC50 48 Crustacea 0.0014815372mg/L 4 anthracene LC50 96 Fish 0.00127mg/L 4

anthracene EC50 48 Crustacea 0.01119096mg/L 4 anthracene EC50 72 Algae or other aquatic plants >0.0078mg/L 2

anthracene BCF 48 Fish 1.0mg/L 4 anthracene EC50 24 Crustacea ca.0.0012mg/L 2

anthracene NOEC 22 Algae or other aquatic plants 0.0015-0.0017mg/L 2 acenaphthene LC50 96 Fish 0.58mg/L 4

acenaphthene EC50 48 Crustacea 1.275mg/L 4 acenaphthene EC50 96 Algae or other aquatic plants 0.5mg/L 1

acenaphthene EC50 384 Crustacea 0.178mg/L 3 acenaphthene NOEC 768 Fish 0.208-0.226mg/L 1

fluorene LC50 96 Fish 0.76mg/L 4 fluorene EC50 48 Crustacea 0.212mg/L 4

fluorene EC50 96 Algae or other aquatic plants 1.346mg/L 3 fluorene BCF 576 Crustacea 1.055mg/L 4 fluorene EC50 384 Crustacea 0.238mg/L 3 fluorene NOEC 336 Crustacea 0.0625mg/L 4 dibenz[a,h]anthracene LC50 96 Fish 0.008mg/L 3 dibenz[a,h]anthracene EC50 48 Crustacea 0.0005510934mg/L 4 dibenz[a,h]anthracene EC50 96 Algae or other aquatic plants 0.010mg/L 3 dibenz[a,h]anthracene BCF 6 Crustacea 0.00072mg/L 4 dibenz[a,h]anthracene EC50 48 Crustacea 0.001558648mg/L 4 dibenz[a,h]anthracene NOEC 144 Fish 0.01mg/L 4 naphthalene LC50 96 Fish 0.213mg/L 4 naphthalene EC50 48 Crustacea 1.6mg/L 4 naphthalene EC50 72 Algae or other aquatic plants ca.0.4mg/L 1 naphthalene BCF 12 Fish 10.2mg/L 4 naphthalene EC50 0.05 Crustacea 0.000000085mg/L 4 naphthalene NOEC 48 Fish 0.012817mg/L 4 acenaphthylene LC50 96 Fish 0.991mg/L 3 acenaphthylene EC50 96 Algae or other aquatic plants 1.450mg/L 3 acenaphthylene EC50 384 Crustacea 0.249mg/L 3 Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Legend: Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

For Hydrocarbons: log Kow 1. BCF~10. For Aromatics: log Kow 2-3. BCF 20-200. For C5 and greater alkanes: log Kow 3-4.5. BCF 100-1,500. For Alkanes, Benzene, Toluene, Ethylbenzene, Xylene (BTEX): Environmental Fate: Microbes found in many natural settings (e.g., soils, groundwater, ponds) have been shown to be capable of degrading organic compounds. Some hydrocarbons will become associated with marine sediments likely to be spread over a fairly wide area of sea floor. Under aerobic conditions, hydrocarbons degrade to water and carbon dioxide, while under anaerobic processes, they produce water, methane and carbon dioxide. Anaerobic degradation is slower than aerobic. Biodegradation can eliminate the contaminants without dispersing them throughout the environment. The rate of hydrocarbon degradation depends on the chemical composition of the product released to the environment as well as site-specific environmental factors. Hydrocarbons with condensed ring structures, such as PAHs (polycyclic aromatic hydrocarbons) with four or more rings, have been shown to be relatively resistant to biodegradation. PAHs with only 2 or 3 rings (e.g., naphthalene, anthracene) are more easily biodegraded. In almost all cases, the presence of oxygen is essential for effective biodegradation. Straight chain hydrocarbons and aromatics degrade more readily than highly branched aliphatic compounds. The n-alkanes, n-alkyl aromatics, and the aromatics in the C10-C22 range are the most readily biodegradable; n-alkanes, n-alkyl aromatics, and aromatics in the C5-C9 range are biodegradable at low concentrations by some microorganisms, but are generally preferentially removed by volatilization and thus are unavailable in most environments; n-alkanes in the C1-C4 ranges are biodegradable only by a narrow range of specialized hydrocarbon degraders; n-alkanes, n-alkyl aromatics, and aromatics above C22 are generally not available to degrading microorganisms. The ideal pH

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range to promote biodegradation is close to neutral (6-8). For most species, the optimal pH is slightly alkaline, that is, greater than 7. Generally, as the temperature increases, biological activity tends to increase up to a temperature where enzyme denaturation occurs. Atmospheric Fate: Alkanes, isoalkanes, and cycloalkanes have half-lives on the order of 1-10 days, whereas alkenes, cycloalkenes, and substituted benzenes have half-lives of 1 day or less. Photochemical oxidation products include aldehydes, hydroxy compounds, nitro compounds, and peroxyacyl nitrates. Alkenes, certain substituted aromatics, and naphthalene are potentially susceptible to direct photolysis. Aquatic Fate: Volatilization half-life predicted as 7 days (ponds), 1.5 days (rivers), 6 days (lakes). Volatilization rate of naphthalene and its substituted derivatives estimated to be slower.The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm seas which is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Ecotoxicity: Effects on freshwater/saltwater organisms: Hydrocarbons are hydrophobic. Such substances produce toxicity in aquatic organisms by a mechanism referred to as "non-polar narcosis" or "baseline" toxicity. Toxic effects are often observed in species such as blue mussel, water fleas, freshwater green algae, marine copepods and amphipods. Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.). DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air benzo[ghi]perylene HIGH (Half-life = 1300 days) LOW (Half-life = 0.13 days)

pyrene HIGH (Half-life = 3800 days) LOW (Half-life = 0.33 days) benzo[k]fluoranthene HIGH (Half-life = 4280 days) LOW (Half-life = 0.46 days)

benz[a]pyrene HIGH (Half-life = 1060 days) LOW (Half-life = 0.18 days) chrysene HIGH (Half-life = 2000 days) LOW (Half-life = 0.33 days)

fluoranthene HIGH (Half-life = 880 days) LOW (Half-life = 0.84 days) phenanthrene HIGH (Half-life = 400 days) LOW (Half-life = 0.84 days) benzo[b]fluoranthene HIGH (Half-life = 1220 days) LOW (Half-life = 0.6 days) benz[a]anthracene HIGH (Half-life = 1360 days) LOW (Half-life = 0.33 days) indeno[1,2,3-cd]pyrene HIGH (Half-life = 1460 days) LOW (Half-life = 0.26 days) anthracene HIGH (Half-life = 920 days) LOW (Half-life = 0.21 days) acenaphthene HIGH (Half-life = 204 days) LOW (Half-life = 0.37 days) fluorene MEDIUM (Half-life = 120 days) LOW (Half-life = 2.84 days) dibenz[a,h]anthracene HIGH (Half-life = 1880 days) LOW (Half-life = 0.18 days) naphthalene HIGH (Half-life = 258 days) LOW (Half-life = 1.23 days) acenaphthylene MEDIUM (Half-life = 120 days) LOW (Half-life = 0.05 days)

Bioaccumulative potential

Ingredient Bioaccumulation coal tar pitch, high LOW (BCF = 0.13) temperature benzo[ghi]perylene HIGH (LogKOW = 6.697) pyrene HIGH (LogKOW = 4.88) benz[a]pyrene HIGH (LogKOW = 6.13) chrysene HIGH (LogKOW = 5.81) fluoranthene HIGH (LogKOW = 5.16) phenanthrene MEDIUM (LogKOW = 4.46) benzo[b]fluoranthene HIGH (LogKOW = 5.78) benz[a]anthracene HIGH (LogKOW = 5.76) anthracene HIGH (BCF = 10500) acenaphthene LOW (BCF = 387) fluorene MEDIUM (BCF = 830) dibenz[a,h]anthracene HIGH (LogKOW = 6.697) naphthalene HIGH (BCF = 18000) acenaphthylene MEDIUM (BCF = 545)

Mobility in soil

Ingredient Mobility benzo[ghi]perylene LOW (KOC = 2676000)

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pyrene LOW (KOC = 69410) benz[a]pyrene LOW (KOC = 786800)

chrysene LOW (KOC = 236100) fluoranthene LOW (KOC = 70850)

phenanthrene LOW (KOC = 20830) benzo[b]fluoranthene LOW (KOC = 803100)

benz[a]anthracene LOW (KOC = 231300) anthracene LOW (KOC = 20400)

acenaphthene LOW (KOC = 6123) fluorene LOW (KOC = 11290)

dibenz[a,h]anthracene LOW (KOC = 2622000) naphthalene LOW (KOC = 1837)

acenaphthylene LOW (KOC = 6123)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging Recycle wherever possible or consult manufacturer for recycling options.|Dispose of waste, residues, containers and disposal contaminated materials in accordance with all applicable regulations.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM 2Y

Land transport (ADG)

UN number 3257 UN proper shipping ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash point (including molten metals, molten name salts, etc.) (contains coal tar pitch, high temperature)

Transport hazard Class 9 class(es) Subrisk Not Applicable

Packing group III Environmental hazard Not Applicable

Special precautions Special provisions 232 274 for user Limited quantity 0

Air transport (ICAO-IATA / DGR)

UN number 3257 UN proper shipping Elevated temperature liquid, n.o.s. * at or above 100°C and below its flash point (including molten metals, molten salts, etc.) name (contains coal tar pitch, high temperature)

ICAO/IATA Class 9 Transport hazard ICAO / IATA Subrisk Not Applicable class(es) ERG Code 9L

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Packing group III

Environmental hazard Not Applicable

Special provisions Not Applicable

Cargo Only Packing Instructions Forbidden Cargo Only Maximum Qty / Pack Forbidden Special precautions Passenger and Cargo Packing Instructions Forbidden for user Passenger and Cargo Maximum Qty / Pack Forbidden

Passenger and Cargo Limited Quantity Packing Instructions Forbidden Passenger and Cargo Limited Maximum Qty / Pack Forbidden

Sea transport (IMDG-Code / GGVSee)

UN number 3257 UN proper shipping ELEVATED TEMPERATURE LIQUID, N.O.S. at or above 100°C and below its flashpoint (including molten metals, molten name salts, etc.) (contains coal tar pitch, high temperature)

Transport hazard IMDG Class 9 class(es) IMDG Subrisk Not Applicable

Packing group III

Environmental hazard Marine Pollutant

EMS Number F-A, S-P Special precautions Special provisions 232 274 for user Limited Quantities 0

Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

COAL TAR PITCH, HIGH TEMPERATURE(65996-93-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia Hazardous Substances Information System - Consolidated Lists International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

BENZO[GHI]PERYLENE(191-24-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

PYRENE(129-00-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

BENZO[K]FLUORANTHENE(207-08-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Hazardous Substances Information System - Consolidated Lists Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

BENZ[A]PYRENE(50-32-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Hazardous Substances Information System - Consolidated Lists (other than lead) requiring health monitoring Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

CHRYSENE(218-01-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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Australia Exposure Standards Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Hazardous Substances Information System - Consolidated Lists (other than lead) requiring health monitoring Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

FLUORANTHENE(206-44-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

PHENANTHRENE(85-01-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

BENZO[B]FLUORANTHENE(205-99-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Hazardous Substances Information System - Consolidated Lists Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

BENZ[A]ANTHRACENE(56-55-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Hazardous Substances Information System - Consolidated Lists Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

INDENO[1,2,3-CD]PYRENE(193-39-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

ANTHRACENE(120-12-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

ACENAPHTHENE(83-32-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

FLUORENE(86-73-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified Australia Work Health and Safety Regulations 2016 - Hazardous chemicals by the IARC Monographs (other than lead) requiring health monitoring

DIBENZ[A,H]ANTHRACENE(53-70-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Hazardous Substances Information System - Consolidated Lists Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Inventory of Chemical Substances (AICS) (other than lead) requiring health monitoring International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

NAPHTHALENE(91-20-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Work Health and Safety Regulations 2016 - Hazardous chemicals Australia Hazardous Substances Information System - Consolidated Lists (other than lead) requiring health monitoring Australia Inventory of Chemical Substances (AICS) International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs

ACENAPHTHYLENE(208-96-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) Australia Work Health and Safety Regulations 2016 - Hazardous chemicals (other than lead) requiring health monitoring

National Inventory Status Australia - AICS Y

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N (fluoranthene; benz[a]anthracene; dibenz[a,h]anthracene; indeno[1,2,3-cd]pyrene; benzo[k]fluoranthene; acenaphthylene; Canada - DSL benzo[b]fluoranthene; benzo[ghi]perylene) N (benz[a]pyrene; pyrene; acenaphthene; naphthalene; chrysene; phenanthrene; coal tar pitch, high temperature; fluorene; Canada - NDSL benzo[k]fluoranthene; benzo[b]fluoranthene; benzo[ghi]perylene; anthracene)

China - IECSC N (chrysene; indeno[1,2,3-cd]pyrene; benzo[k]fluoranthene; acenaphthylene; benzo[b]fluoranthene; benzo[ghi]perylene) Europe - EINEC / Y ELINCS / NLP

N (benz[a]pyrene; chrysene; benz[a]anthracene; dibenz[a,h]anthracene; indeno[1,2,3-cd]pyrene; benzo[k]fluoranthene; Japan - ENCS benzo[b]fluoranthene; benzo[ghi]perylene) N (fluoranthene; benz[a]anthracene; dibenz[a,h]anthracene; indeno[1,2,3-cd]pyrene; benzo[k]fluoranthene; acenaphthylene; Korea - KECI benzo[b]fluoranthene; benzo[ghi]perylene)

New Zealand - NZIoC Y N (fluoranthene; chrysene; benz[a]anthracene; dibenz[a,h]anthracene; indeno[1,2,3-cd]pyrene; benzo[k]fluoranthene; Philippines - PICCS benzo[b]fluoranthene; benzo[ghi]perylene) USA - TSCA N (benzo[k]fluoranthene; benzo[b]fluoranthene; benzo[ghi]perylene)

Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS