Final Risk Evaluation for C.I. Pigment Violet 29, Supplemental File
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Mild Synthesis of Perylene Tetracarboxylic Monoanhydrides with Potential Applications in Organic Optoelectronics
City University of New York (CUNY) CUNY Academic Works All Dissertations, Theses, and Capstone Projects Dissertations, Theses, and Capstone Projects 5-2019 Mild Synthesis of Perylene Tetracarboxylic Monoanhydrides with Potential Applications in Organic Optoelectronics Xizhe Zhao The Graduate Center, City University of New York How does access to this work benefit ou?y Let us know! More information about this work at: https://academicworks.cuny.edu/gc_etds/3258 Discover additional works at: https://academicworks.cuny.edu This work is made publicly available by the City University of New York (CUNY). Contact: [email protected] Mild Synthesis of Perylene Tetracarboxylic Monoanhydrides with Potential Applications in Organic Optoelectronics By Xizhe Zhao A dissertation submitted to the Graduate Faculty in Chemistry in partial fulfillment of the requirements for the degree of Doctor of Philosophy The City University of New York. 2019 © 2019 Xizhe Zhao All Rights Reserved ii Mild Synthesis of Perylene Tetracarboxylic Monoanhydrides with Potential Applications in Organic Optoelectronics by Xizhe Zhao This manuscript has been read and accepted for the Graduate Faculty in Chemistry in satisfaction of the dissertation requirement for the degree of Doctor of Philosophy. 04/29/19 Prof. Shi Jin _________________________ __________________________________________________ Date Chair of Examining Committee 04/29/19 Prof. Brian R. Gibney _________________________ __________________________________________________ Date Executive Officer Supervisory Committee: Prof. Krishnaswami Raja Prof. Sanjai Kumar Pathak THE CITY UNIVERSITY OF NEW YORK iii ABSTRACT Mild Synthesis of Perylene Tetracarboxylic Monoanhydrides with Potential Applications in Organic Optoelectronics By Xizhe Zhao Advisor: Professor Shi Jin Perylene tetracarboxylic derivatives are considered good n-type semi-conductors. In past decades, there has been extensive study on their synthesis and electronic properties. -
328 United States Tariff Commission July 1970 UNITED STATES TARIFF COMMISSION
UNITED STATES TARIFF COMMISSION Washington IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS 1969 United States General Imports of Intermediates, Dyes, Medicinals, Flavor and Perfume Materials, and Other Finished Benzenoid Products Entered on 1969 Under Schedule 4, Part 1, of The Tariff Schedules of the United States TC Publication 328 United States Tariff Commission July 1970 UNITED STATES TARIFF COMMISSION Glenn W. Sutton Bruce E. Clubb Will E. Leonard, Jr. George M. Moore Kenneth R. Mason, Seoretary Address all communications to United States Tariff Commission Washington, D. C. 20436 CONTENTS (Imports under TSUS, Schedule 4, Parts 1B and 1C) Table No. pue_ 1. Benzenoid intermediates: Summary of U.S. general imports entered under Part 1B, TSUS, by competitive status, 1969 4 2. Benzenoid intermediates: U.S. general imports entered under Part 1B, TSUS, by country of origin, 1969 and 1968 3. Benzenoid intermediates: U.S. general iml - orts entered under Part 1B, TSUS, showing competitive status, 1969 4. Finished benzenoid products: Summary of U.S.general . im- ports entered under Part 1C, TSUS, by competitive status, 1969 24 5. Finished benzenoid products: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1969 and 1968 25 6. Finished benzenoid products: Summary of U.S. general imports entered under Part 1C, TSUS, by major groups and competitive status, 1969 27 7. Benzenoid dyes: U.S. general imports entered under Part 1C, TSUS, by class of application, and competitive status, 1969-- 30 8. Benzenoid dyes: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1969 compared with 1968 31 9. -
Bacterial Pigments and Its Significance
MOJ Bioequivalence & Bioavailability Review Article Open Access Bacterial pigments and its significance Abstract Volume 4 Issue 3 - 2017 Pigments are compounds that are widely used in industries that come in a wide variety Hizbullahi M Usman, Nafi’u Abdulkadir, of colors, some of which are water–soluble. Nontoxic nature of pigment produced by a number of microorganisms make them environmentally friendly for utilization Mustapha Gani, Hauwa’u M Maiturare Microbiology Department Sokoto State University, Nigeria in dye, foodstuff, pharmacy, cosmetics and other industrial purposes. Moreover natural pigments produced from biological origin have medicinal importance as been Correspondence: Nafi’u Abdulkadir, Microbiology used as antioxidant, antimicrobial, additives, color intensifiers, and anticancer as Department Sokoto State University, Along Birnin Kebbi road well as economically friendly. Some of Bacteria capable of producing pigment with near Airport Sokoto State Nigeria, different varieties of colors are Agrobacterium aurantiacum, Staphylococcus aureus, Email [email protected] Chromobacterium violaceum, Serratia marcescens, Bacillus Spp, Flavobacterium sp, etc. colors are Pink–red, Golden Yellow, Purple, red, Creamy and yellow respectively. Received: October 03, 2017 | Published: December 28, 2017 Industrial production of natural food colorants by microbial fermentation has several advantages such as cheaper production, easier extraction, higher yields through strain improvement, no lack of raw materials and no seasonal. Therefore the present study aimed at reviewing pigment produced by bacteria and its significance. Keywords: bacterial pigments, microorganism, antioxidants, non–toxic, antimicrobial activities, biocolorants Introduction add to their positive effects. The significant growth in the naturally derived colors has been attributed to their stability and consumer Pigments are compounds with characteristics of importance to perception. -
Highly Soluble Monoamino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties
Int. J. Mol. Sci. 2014, 15, 22642-22660; doi:10.3390/ijms151222642 OPEN ACCESS International Journal of Molecular Sciences ISSN 1422-0067 www.mdpi.com/journal/ijms Article Highly Soluble Monoamino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties Kew-Yu Chen * and Che-Wei Chang Department of Chemical Engineering, Feng Chia University, Taichung 40724, Taiwan; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +886-4-2451-7250 (ext. 3683); Fax: +886-4-2451-0890. External Editor: Dennis N. Kevill Received: 8 November 2014; in revised form: 21 November 2014 / Accepted: 1 December 2014 / Published: 8 December 2014 Abstract: Three dialkylamino-substituted perylene tetracarboxylic dianhydrides with different n-alkyl chain lengths (n = 6, 12 or 18), 1a–1c, were synthesized under mild conditions in high yields and were characterized by 1H NMR, 13C NMR and high resolution mass spectroscopy. Their optical and electrochemical properties were measured using UV-Vis and emission spectroscopic techniques, as well as cyclic voltammetry (CV). This is the first time that the structures and the properties of monoamino-substituted perylene tetracarboxylic dianhydrides have been reported. These molecules show a deep green color in both solution and the solid state and are soluble in most organic solvents. They all show a unique charge transfer emission in the near-infrared region, and the associated peaks exhibit solvatochromism. The dipole moments of the compounds have been estimated using the Lippert-Mataga equation, and upon excitation, they show slightly larger dipole moment changes than those of corresponding perylene diimides, 2a–2c. -
Polycyclic Aromatic Hydrocarbon Structure Index
United States Department of Commerce Technology Administration National Institute of Standards and Technology NIST Special Publication 922 Polycyclic Aromatic Hydrocarbon Structure Index Lane C. Sander and Stephen A. Wise This publication is available free of charge from: https://doi.org/10.6028/NIST.SP.922e2020 NIST Special Publication 922 Polycyclic Aromatic Hydrocarbon Structure Index Lane C. Sander and Stephen A. Wise Chemical Science and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899-0001 December 1997 revised August 2020 This publication is available free of charge from: https://doi.org/10.6028/NIST.SP.922e2020 U.S. Department of Commerce Wilbur L. Ross, Jr., Secretary National Institute of Standards and Technology Walter Copan, NIST Director and Under Secretary of Commerce for Standards and Technology Errata for SP 922 (printed document) Corrected entries are listed below 2 1 3 19 Acephenanthrylene CH 9 10 4 201-06-9 16 10 202 1.291 8 5 Cyclopenta[jk]phenanthrene 11.70 7 6 9.067 3.890 10 1 9 2 27208-37-3 226 1.200 33 8 3 Cyclopenta[cd]pyrene CH18 10 7 4 11.52 6 5 Acepyrene Acepyrylene 9.602 3.887 10 9 1 34 Benz[mno]aceanthrylene 203-13-4 CH 226 8 2 18 10 1.222 7 3 Naphtho[1,8,7,6-cdef]fluorene 11.83 6 5 4 9.679 3.884 2 HC2 1 3 41 11 4 1H-Cyclopenta[e]pyrene 109587-09-9 CH19 12 240 10 5 9 8 6 7 11 1 10 2 9 3 52 5H-Benzo[cd]pyrene 191-34-4 CH19 12 240 1.233 8 5 4 7 6 Pyrenindene 11.92 C 9.674 H2 4.207 14 1 13 2 12 3 160 4 Cyclopent[b]indeno[4,5-g]- 72088-81-4 CH24 14 302 10 11 9 phenanthrene 8 5 7 6 2 3 1 4 14 5 Cyclopent[b]indeno[5,6-g]- 72088-82-5 CH 302 161 6 24 14 12 13 phenanthrene 11 10 7 89 Polycyclic Aromatic Hydrocarbon Structure Index Lane C. -
Polycyclic Aromatic Hydrocarbons (Pahs)
Polycyclic Aromatic Hydrocarbons (PAHs) Factsheet 4th edition Donata Lerda JRC 66955 - 2011 The mission of the JRC-IRMM is to promote a common and reliable European measurement system in support of EU policies. European Commission Joint Research Centre Institute for Reference Materials and Measurements Contact information Address: Retiewseweg 111, 2440 Geel, Belgium E-mail: [email protected] Tel.: +32 (0)14 571 826 Fax: +32 (0)14 571 783 http://irmm.jrc.ec.europa.eu/ http://www.jrc.ec.europa.eu/ Legal Notice Neither the European Commission nor any person acting on behalf of the Commission is responsible for the use which might be made of this publication. Europe Direct is a service to help you find answers to your questions about the European Union Freephone number (*): 00 800 6 7 8 9 10 11 (*) Certain mobile telephone operators do not allow access to 00 800 numbers or these calls may be billed. A great deal of additional information on the European Union is available on the Internet. It can be accessed through the Europa server http://europa.eu/ JRC 66955 © European Union, 2011 Reproduction is authorised provided the source is acknowledged Printed in Belgium Table of contents Chemical structure of PAHs................................................................................................................................. 1 PAHs included in EU legislation.......................................................................................................................... 6 Toxicity of PAHs included in EPA and EU -
Supplemental Comments on EPA's Draft Risk Evaluation for C.I. Pigment Violet 29
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Supplemental Comments of Safer Chemicals Healthy Families, Earthjustice, Environmental Health Strategy Center, Natural Resources Defense Council and the Undersigned Groups on EPA’s Draft Risk Evaluation for C.I. Pigment Violet 29 under the Amended Toxic Substances Control Act Submitted via Regulations.gov (May 17, 2019) Docket ID EPA-HQ-OPPT-2018-0604 INTRODUCTION AND SUMMARY Safer Chemicals Healthy Families (SCHF), Earthjustice, Environmental Health Strategy Center, Natural Resources Defense Council, and the undersigned groups submit these supplemental comments on the Environmental Protection Agency (EPA) draft risk evaluation for C.I. Pigment Violet 29 (PV29) under section 6(B) of the Toxic SuBstances Control Act (TSCA).1 Our organizations are committed to assuring the safety of chemicals used in our homes, schools and workplaces and in the many products to which our families and children are exposed each day. During the legislative process to amend TSCA, we worked hard to maximize public health protection and to assure that EPA has the necessary authority to evaluate and eliminate the risks of unsafe chemicals. We strongly support a proactive approach to implementing the new law that uses the improved tools that Congress gave EPA to deliver significant health and environmental benefits to the American public. On April 17, 2019,2 EPA reopened the comment period on the PV29 evaluation for 30 days in order to receive feedback on supplemental materials it had added to the PV29 docket. These materials include portions of 24 studies on PV29 that the Agency had initially withheld as Confidential Business Information (CBI), as well as updated systematic review files and backup scoring sheets. -
Benzo(G,H,I)Perylene Worksheet
CHEMICAL UPDATE WORKSHEET Chemical Name: Benzo(g,h,i)perylene CAS #: 191-24-2 Revised By: RRD Toxicology Unit Revision Date: September 15, 2015 (A) Chemical-Physical Properties Part 201 Value Updated Value Reference Source Comments Molecular Weight (g/mol) 276.34 276.34 EPI EXP Physical State at ambient temp Solid Solid MDEQ Melting Point (˚C) --- 278.00 EPI EXP Boiling Point (˚C) 500 500.00 EPI EXP Solubility (ug/L) 0.26 0.26 EPI EXP Vapor Pressure (mmHg at 25˚C) 1.0E-10 1.00E-10 EPI EXP HLC (atm-m³/mol at 25˚C) 5.34E-8 3.31E-07 EPI EXP Log Kow (log P; octanol-water) 6.7 6.63 EPI EXP Koc (organic carbon; L/Kg) 3.86E+6 1.951E+06 EPI EST Ionizing Koc (L/kg) NR NA NA Diffusivity in Air (Di; cm2/s) 0.08 2.39E-02 W9 EST Diffusivity in Water (Dw; cm2/s) 8.0E-6 6.0922E-06 W9 EST Soil Water Partition Coefficient NR NR NA NA (Kd; inorganics) CHEMICAL UPDATE WORKSHEET Benzo(g,h,i)perylene (191-24-2) Part 201 Value Updated Value Reference Source Comments Flash Point (˚C) NA NA NA NA Lower Explosivity Level (LEL; NA NA NA NA unit less) Critical Temperature (K) NA NA NA Enthalpy of Vaporization NA NA NA (cal/mol) Density (g/mL, g/cm3) 1.3 PC EXP EMSOFT Flux Residential 2 m NA 4.48E-09 EMSOFT EST (mg/day/cm2) EMSOFT Flux Residential 5 m NA 4.48E-09 EMSOFT EST (mg/day/cm2) EMSOFT Flux Nonresidential 2 m NA 4.88E-09 EMSOFT EST (mg/day/cm2) EMSOFT Flux Nonresidential 5 m NA 4.88E-09 EMSOFT EST (mg/day/cm2) 2 CHEMICAL UPDATE WORKSHEET Benzo(g,h,i)perylene (191-24-2) (B) Toxicity Values/Benchmarks Source*/Reference Comments/Notes Part 201 Value Updated Value /Date /Issues Reference Dose 7.1E-3 2.0E-3 MDEQ, 2015 (RfD) (mg/kg/day) Tier 3 Source: Complete MDEQ: Basis: In the absence of chemical-specific toxicity data for benzo (g, h, i) perylene, NYDEC and TCEQ identify pyrene as an appropriate chemical surrogate and recommend the pyrene IRIS RfD (3.0E-2 mg/kg/d) without modification. -
Download Our Sales Range Brochure
Sales Range FOR PRINTING, PAINTS, PLASTICS INDUSTRIES AND SPECIAL APPLICATIONS Pigments, pigment preparations and dyes FROM CLARIANT For the standard range of pigments we give a general Suitability e. g. for the coloration and printing of food Clariant supplies pigments and dyes. overview indicating their possible technical uses in packa ging or use in cosmetic products is subject to the main fields of application. statutory requirements which differ from country to These ranges, supplemented by country. It is the customers responsibility to comply It is not appropriate to treat the special grades, with applicable laws and regulations. pigment preparations and special pigment preparations, dyes and intermediates/ chemicals in the same way as the standard ranges NOTES ON DIARYL PIGMENTS grades, offer a wide variety of products and therefore they appear in the brochure as It has been known for some considerable time that separate ranges with less details of their special diaryl pigments can release 3,3’-DCB when they are for the printing ink, paint, plastics, fields of application. processed in polymers at temperatures above 200 °C. rubber, office supplies, wood and THE SYMBOLS MEAN: The following pigments supplied by Clariant are Main field of application diaryl pigments: detergents industries as well as for Additional field of application Limited suitability Pigment Yellow 12 Pigment Yellow 126 other special fields. — Not recommended Pigment Yellow 13 Pigment Yellow 127 Pigment Yellow 14 Pigment Yellow 174 We would however point out that this classification Pigment Yellow 16 Pigment Yellow 176 is simply a general guide that is intended to make Pigment Yellow 17 Pigment Orange 13 it easier to select suitable products from our range Pigment Yellow 81 Pigment Orange 34 of colorants. -
Rate Constant for Fluorescence Quenching: Anthracene
The Rate Constant for Fluorescence Quenching1 Purpose This experiment utilizes fluorescence intensity measurements to determine the rate constant for the fluorescence quenching of anthracene or perylene by CCl4 in an ethanol solvent. Introduction The fluorescence intensity of a substance depends on the natural lifetime of its first excited singlet state and on the rate that the first excited state is deactivated by nonradiative processes. Much of the nonradiative deactivation comes about because of collisions of the excited molecule with solvent molecules. However, some substances are particularly efficient at deactivating, or quenching, excited states. These tend to be substances with heavy atoms (for example halogens) or paramagnetic compounds. Oxygen is a particularly good quencher, therefore it is often necessary to remove the oxygen from solution before measuring fluorescence spectra. Fluorescent probes, such as dansyl chloride, are used in biochemistry to study the various binding sites in large macromolecules through the difference of the quenching rates of the bound verses free probe. Theory Aromatic hydrocarbons generally show intense fluorescence but no phosphorescence in fluid solution at room temperature. The fluorescence of most of these compounds is efficiently quenched by halogenated alkanes such as carbon tetrachloride and chloroform (2-5). To a certain extent these quenching events result in photochemical reactions between the aromatic hydrocarbon and the quencher. The object of this experiment is to determine the rate constant for this quenching reaction through measurements of the fluorescence intensity of the aromatic hydrocarbon in ethanol with various amounts of the quencher. The theory will be discussed with reference to the quenching of anthracene fluorescene with CCl4 in ethanol. -
(12) Patent Application Publication (10) Pub. No.: US 2014/0378585 A1 Let Al
US 20140378585A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0378585 A1 Let al. (43) Pub. Date: Dec. 25, 2014 (54) INKJET INK COMPOSITION FOR PRINTING CSK 5/3465 (2006.01) RREMOVABLE TRACE MARKSON CSK 5/4I (2006.01) SUBSTRATES FOR ENHANCING PRODUCT CSK 5/23 (2006.01) AUTHENTICITY AND TRACEABILITY (52) U.S. Cl. CPC ................ C09D 1 1/322 (2013.01); C08K 5/41 (71) Applicant: Kwai Sang NG, Hong Kong (CN) (2013.01); C08K 5/235 (2013.01); C08K 5/3465 (2013.01); C08K 5/18 (2013.01) (72) Inventors: PEI LI, Hong Kong (CN); Kin Man USPC ............................................. 524/90; 524/159 HO, Hong Kong (CN); Chun Ho YAM, Hong Kong (CN); Kwai Sang NG, Hong (57) ABSTRACT SN Siu Sun CHAN, Hong Provided herein is an inkjet ink composition for printing 9. irremovable color trace marks on polymer substrates. The composition disclosed herein comprises a Surface colorant, a (73) Assignee: Kwai Sang NG, Hong Kong (CN) hydrophobic colorant capable of staining the polymer Sub strates disclosed herein, a hydrophobic colorant carrier which (21) Appl. No.: 14/308,708 provides good solubility for the hydrophobic colorant, a 1-1. binder and an ink solvent system. Printing with the composi (22) Filed: Jun. 18, 2014 tion disclosed herein on multilayered plastic packaging pro O O vides a double layered print. The surface colorants can be Related U.S. Application Data removed by an organic solvent, while the hydrophobic colo (60) Provisional application No. 61/837,378, filed on Jun. rant can stain the nonporous Substrates, giving a watermark of 20, 2013. -
Ep 1146094 B1
(19) TZZ__Z_T (11) EP 1 146 094 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: C09D 11/00 (2006.01) C09B 67/22 (2006.01) 16.11.2011 Bulletin 2011/46 (21) Application number: 01302034.2 (22) Date of filing: 06.03.2001 (54) Water-based pigment dispersion, use thereof and process for the production thereof Pigmentdispersion auf Wasserbasis, ihre Verwendung sowie Verfahren zu deren Herstellung Dispersion pigment à base d’eau, son utilisation et procédé de leur production (84) Designated Contracting States: • Suzuki, Eriko, DE FR GB c/o Toyo Ink MFG Co Ltd., Tokyo (JP) (30) Priority: 06.03.2000 JP 2000059754 • Negishi, Takashi, 21.03.2000 JP 2000077499 c/o Toyo Ink MFG Co Ltd., 09.08.2000 JP 2000241015 Tokyo (JP) 09.08.2000 JP 2000241016 • Aida, Seiji, 11.12.2000 JP 2000375362 c/o Toyo Ink MFG Co Ltd., 11.12.2000 JP 2000375363 Tokyo (JP) 22.01.2001 JP 2001012581 (74) Representative: Woods, Geoffrey Corlett (43) Date of publication of application: J.A. Kemp & Co. 17.10.2001 Bulletin 2001/42 14 South Square Gray’s Inn (73) Proprietor: TOYO INK MANUFACTURING CO., London LTD. WC1R 5JJ (GB) Tokyo (JP) (56) References cited: (72) Inventors: EP-A- 0 603 132 EP-A- 0 636 666 • Uemura, Toshiyuki, EP-A- 0 659 842 EP-A- 0 787 775 c/o Toyo Ink MFG Co Ltd., EP-A- 0 834 537 EP-A- 0 851 005 Tokyo (JP) DE-A- 4 321 693 US-A- 3 386 843 • Kaneda, Jun, US-A- 5 271 759 c/o Toyo Ink MFG Co Ltd., Tokyo (JP) Note: Within nine months of the publication of the mention of the grant of the European patent in the European Patent Bulletin, any person may give notice to the European Patent Office of opposition to that patent, in accordance with the Implementing Regulations.