UNITED STATES TARIFF COMMISSION Washington
IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS
1969
United States General Imports of Intermediates, Dyes, Medicinals, Flavor and Perfume Materials, and Other Finished Benzenoid Products Entered on 1969 Under Schedule 4, Part 1, of The Tariff Schedules of the United States
TC Publication 328 United States Tariff Commission July 1970 UNITED STATES TARIFF COMMISSION
Glenn W. Sutton
Bruce E. Clubb
Will E. Leonard, Jr.
George M. Moore
Kenneth R. Mason, Seoretary
Address all communications to
United States Tariff Commission
Washington, D. C. 20436
CONTENTS
(Imports under TSUS, Schedule 4, Parts 1B and 1C) Table No. pue_ 1. Benzenoid intermediates: Summary of U.S. general imports entered under Part 1B, TSUS, by competitive status, 1969 4 2. Benzenoid intermediates: U.S. general imports entered under Part 1B, TSUS, by country of origin, 1969 and 1968 3. Benzenoid intermediates: U.S. general iml - orts entered under Part 1B, TSUS, showing competitive status, 1969 4. Finished benzenoid products: Summary of U.S.general . im- ports entered under Part 1C, TSUS, by competitive status, 1969 24 5. Finished benzenoid products: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1969 and 1968 25 6. Finished benzenoid products: Summary of U.S. general imports entered under Part 1C, TSUS, by major groups and competitive status, 1969 27 7. Benzenoid dyes: U.S. general imports entered under Part 1C, TSUS, by class of application, and competitive status, 1969-- 30 8. Benzenoid dyes: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1969 compared with 1968 31 9. Benzenoid dyes: U.S. general imports of individual dyes entered under Part 1C, TSUS, by class of application, and showing competitive status where available, 1969 32 10. Benzenoid pigments (Toners and lakes): U.S. general imports entered under Part 1C, TSUS, showing competitive status, 1969 72 11. Benzenoid medicinals and pharmaceuticals: U.S. general imports entered under Part 1C, TSUS, by country of origin, 1969 compared with 1968 78 12. Benzenoid medicinals and pharmaceuticals: U.S. general imports entered under Part 1C, TSUS, showing competitive status, 1969 80 13. Benzenoid flavor and perfume materials: U.S. general imports entered under Part 1C, TSUS, showing competitive status, 1969 87 14. All other finished benzenoid products: U.S. general im- ports entered under Part 1C, TSUS, showing competitive status, 1969 90
IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS, 1969 1/
Introduction
This report presents statistics on U.S. imports of benzenoid chemi- cals and products entered in 1969 under the Tariff Schedules of the United States (TSUS)--title I of the Tariff Act of 1930, as amended. The data were obtained by analyzing invoices covering imports through the principal U.S. customs districts.
Items included in this report are referred to as "benzenoid chemicals" and products. The term "benzenoid chemicals" refers to cyclic organic chemicals having a benzenoid, quinoid, or modified benzenoid 2/ structure and to certain cyclic and acyclic chemicals obtained therefrom, provided for in part 1 of schedule -4 of the TSUS. Certain benzenoid chemicals, however, are specifically excluded from part 1 of schedule 4; among these are certain chemicals obtained from animal or vegetable products. 3/ The cyclic chemicals here considered are usually produced in whole or in part either from coal tar or petroleum.
Rates of duty on all imports of the benzenoid products covered by this report are compound rates except for certain colors,-dyes and stains, and color lakes and toners which are ad valorem rates. The specific portion of the compound rates of duty is assessed on the actual weight of the imported product, except that, for colors, dyes, and stains which ex- ceed the standards of strength established by the Secretary of the Treasury, the specific rate is computed on the weight of the product as if diluted to the standard strength.
Benzenoi .d products that are "competitive" with similar domestic products, because they accomplish results substantially equal to those accomplished by the similar domestic product when used in substantially the same manner, are subject to a special basis of valuation for customs purposes known as the "American selling price." If "noncompetitive," the benzenoid products are valued for customs purposes on the basis of the "United States value." The essential difference between these two values is that "American selling price" is based on the wholesale price
1/ The contents of this report are not copyrighted and may be reproduced without special permission. 2/ The term "modified benzenoid" describes a molecular structure having at leastone six-membered heterocyclic ring which contains at least four carbon atoms and having an arrangement of molecular bonds as in the benzene ring or in the quinone ring, but does not include any such molecular structure in which one or more pyrimidine rings are the only modified benze- noid rings present. 3/ Additional exceptions are provided in the headnotes to other parts of Schedule 4. For instance, the headnote to part 3 specifically exempts niacin, niacinamide, meso-inositol hexanicotinate, and pyridoxine (vitamin B6). in the United States of the "competitive" domestic product, whereas "United States value" is based on the wholesale price in the United States of the imported product less most of the expenses incurred in bringing the product to the United States and selling it.. When neither of these two valuation bases applies, then the "export value," "foreign value," or "constructed value" is used as the valuation basis under section '402 or 402a, Tariff Act of 1930, as amended.
The statistics in this report are based on an analysis of general imports through U.S. customs districts which account for most of the imports of benzenoid chemicals and products, whereas the official sta- tistics of the U.S. Department of Commerce are based on imports for consumption through all U.S. customs districts. General imports are the sum of the quantities entered for immediate consumption, plus the quan- tities entered into customs bonded warehouses. Imports for consumption, on the other hand, are the sum of the quantities entered for immediate consumption, plus the quantities withdrawn for consumption from-customs bonded warehouses. The import statistics in this report, therefore, are not comparable with official import statistics. The diffetences resulting from the above-mentioned methods of compiling import data should be taken into consideration when comparing figures in this report with those pub- lished by the U.S. Department of Commerce.
Statistics 1/ on the value of imports given in this and earlier re- ports are the invoice values and not necessarily the dutiable values as finally determined by the customs officials or (in the event of litigation) by a customs court. The invoice values given for "noncompetitive" products on the average roughly approximate dutiable values. For "competitive" products, on the other hand, the invoice values usually are lower than the dutiable values, since the duties on these products are assessed on the basis of the "American selling price." The competitive status of the individual chemicals, when available, is shown in a separate column of all pertinent :tables. The competitive status is determined by the Customs Service and the tables given herein reflect the latest determinations of the Service available to the Tariff Commission. In some instances the competi- tive status may not be in accord with the final determinations made by the customs officials or (in the event of litigation) by a customs court. In 1969 statistics on imports of benzenoid chemicals and products were classified according to the Tariff Schedules of the United States Annotated (1969) (TSUSA) 2/. The rates of duty in effect from January 1, 1969 may be ascertained by reference to the TSUSA, as supplemented.
1/ Imports amounting to less than 25 pounds are not shown separately in this report, except medicinals (including alkaloids and antibiotics) and flavor and perfume materials. 2/ U.S. Tariff Commission Publication 272. Imports Under Schedule 4, Parts 1B and 1C (TSUS)
The total quantity and invoice value 1/ of imports of benzenoid chem- icals and products under Schedule 4, Parts 1B and 1C (TSUS) in 1969 compared with 1968 were as follows:
1969 1968 Quantity Invoice Quantity Invoice (Pounds) . value (Pounds) value
Part 1B --- 78,187,654 $38,898,975 71,425,976 $38,819,595 Part 1C --- 59,969,029 77,711,914 55,414,473 68,436,243 Total --- 138,156,683 116,610,889 126,840,449 107,255,838
Imports Under Schedule 4, Part 1B, TSUS (Benzenoid Intermediates)
Chemicals that are entered under Schedule 4, Part 1B, TSUS, consist chiefly of benzenoid intermediates and small quantities of acyclic compounds which are derived in whole or in part from benzenoid compounds. The inter- mediates are benzenoid chemicals that have progressed only part way in the manufacturing process; derived from coal-tar and petroleum crudes (which enter free of duty under Schedule 4, Part 1A, TSUS), they are generally used , to make more advanced products. Small quantities of finished products, such as rubber-processing chemicals and mixtures containing a benzenoid product, are included under Part 1B. In 1969 general imports of benzenoid intermediates entered under Part 1B totaled 78.2 million pounds, with an invoice value of $38.9 million (table 1), compared with 71.4 million pounds, with an invoice value of $38.8 million, in 1968--an increase in quantity of 9.5 percent and a slight in- crease in value.
In 1969, 365 of the 653 benzenoid intermediates imported under Part 1B were declared to be "competitive" (duty based on "American selling price") and amounted to 62.6 million pounds, valued at $27.1 million. This is 80.1 percent of total imports, in terms of quantity, and 69.7 percent, in terms of value. "Noncompetitive" imports amounted to 14.0 million pounds, valued at $11.0 million. The competitive status of 1,601 thousand pounds of inter- mediates is not available. In terms of value, 46 percent of all the intermediates imported in 1969 came from West Germany; 21 percent, from Japan; and 10 percent, from Switzer- land (table 2). Imports from Japan in 1969 increased to $8.0 million from $5.3 million in 1968. In 1969 imports from Canada increased to $1.9 million, from $1.1 million in 1968. Imports in 1969 from West Germany decreased to $17.7 million from $19.9 million in 1968. Imports from the United Kingdom decreased•to $3.0 million in 1969 from $4.2 million in 1968; imports from Switzerland decreased to $3.9 million in 1969, compared with $4.0 million in 1968, and imports from Italy totaled $2.6 million, compared with $2.9 million in 1968. In 1969, sizable imports of intermediates came from the Netherlands ($639,000), France ($319,000), Yugoslavia ($232,000), Czechoslovakia ($171,000) and Sweden ($116,000). 1/ For explanation of the data used in this report, see Introduction. 4
Table 1.--Benzenoid intermediates: Summary of U.S. general imports entered under Schedule 4, Part 18, TSUS, by competitive status, 1969
Number Percent Invoice Percent unit Status of Quantity of total value of total value products quantity value
Per Pounds Dollars pound. Competitive (duty based on American selling price) 365 62,598,243 80.1 27,108,522 69.7 $0.43 . Noncompetitive (duty based on U.S. value) 163 5,385,990 6.9 6,969,479 17.9 1.29 Noncompetitive (duty based on export value) 81 8,602,674 11.0 4,043,161 10.4 .47 Competitive status not available 44 1,600,747 2.0 777,813 2.0 .49
Grand total 653 78,187,654 100.0 38,898,975 100.0 .50
Note.--The unit'values shown for imports of benzenoid intermediates listed in table are weighted averages. The numerous individual benzenoid intermediates vary widely in quality and unit value.
Table 2.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, by country of origin, 1969 compared with 1968
19 69 1 68
Country Percent Percent Invoice of total Invoice of total value value value value
West Germany $17,698,773 45.6 $19,919,075 51.3 Japan 7,976,591 20.6 5,310,972 13.7 Switzerland 3,932,511 10.1 3,973,108 10.2 United Kingdom- 2,976,205 7.7 4,213,768 10.8 Itdly 2,597,581 6,7 2,859,827 7.4 Canada 1,949,289 5.0 1,121,66] 2.9 Netherlands 638,700 1.6 371,083 1.0 France 319,490 .8 406,219 1.0 Yugoslavia 231,681 .6 126,334 .3 Czechoslovakia 171,193 .4 260,1A6 .7 Sweden 115,695 .3 149,325 .4 Belgium 97,444 .2 104,008' .3 All other 1/ 193,822 .4 4,029 Total 38,898,975 100.0 38,819,595 100.0
1/ Consists principally of imports from ! ■ exico, Israel, and Poland in 1969, and Israel, Mexico, and Poland in 1968.
Imports of intermediates by principal trading areas in 1969 were as follows: Unit Invoice invoice Area Pounds value value
European Economic Community 33,219,637 $21,351,988 $0.64 European Free Trade Association 5,416,068 7,036,549 1130 All Other' countries 1/ 39,551,949 10,510,438 .27 Total 78,187,654 38,898,975 . .50 j Principally Canada, Japan, and Yugoslavia.
In 1969, 15 chemicals accounted for approximately 61 percent of , the quantity of imports of benzenoid intermediates (table 3). The large-volume intermediates imported in 1969 and their principal sources are:
Intermediates Quantity Principal sources (1,000 pounds) (except as noted) Styrene monomer 13,629 Canada, Japan. Phthalic anhydride 7,451 Canada, Japan, the Netherlands, United Kingdom, France. Polyalkylbenzene 6,285 Italy (all). Ethylbenzene 3,788 Canada (all). 2-Naphthol 2,946 West Germany, Italy, Poland. Phthalocyanine crude, copper salt 2,400 Japan, West Germany. H acid and salts 2,243 Italy, Japan, West Germany. p-Cresol 2,078 Japan, France. B. 0. N. 1,293 West Germany, Italy. m, p-Cresol 1,269 Japan, United Kingdom, Canada. Decylbenzene 1,146 Mexico (all). Sodium naphthionate 1,089 Japan, West Germany. Acetoacetanilide 731 Switzerland, United Kingdom, Japan. 1-Aminoanthraquinone 706 West Germany, Italy, Japan. Bromamine acid and salts 616 West Germany, Switzerland, Japan.
Imports of rubber-processing chemicals amounted to 508,000 pounds in 1969, compared with 313,000 pounds in 1968, and 307,000 pounds in 1967. In 1969, imports which were chiefly "competitive" items came principally from Japan, West Germany, and Israel. 6
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969
Competitive Intermediate Quantity status • (pounds)
2 4-Acetamido-2-aminobenzenesulfonic acid 1,617 5-Acetamido-2-aminobenzenesulfonic acid 10,373 3 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid 220 2 2-Acetamido-3-chloroanthraquinone 4,885 Acetoacetanilide 730,607 o-Acetoacetanisidide 285,775 2 Acetoacetbenzylamide 600 2 p-Acetoacetophenetidide 9,200 1 o-Acetoacetotoluidide 418,380 1, 2 p-Acetoacetotoluidide 10,200 1, 2 2',4'-Acetoacetoxylidide 192,194 3 N-Acetoxyethyl-N- cyanoethylaniline 186,098 1 N-Acetylsulfanilyl chloride 165,345 1 N-Acetyl-DL-tryptophan 792 3 Activator 130 3 Additive AC-45-C (Lubricating oil additive) 223,074 3 Adhesive 454,195 1 Adipic acid, 1,6-hexanediamine salt 4,331 3 Alkylbenzenesulfonic acid 33,069 3 6-Ally1-6,7-dihydro-5H-dibenz(c,e)azepine 550 2 3'-Aminoacetanilide 1,000 1 4'-Aminoacetanilide 414,841 1 3'-Aminoacetophenone 20,845 1 5-Amino-2-(p-aminoanilino)benzenesulfonic acid 8,752 3 5-Amino-2-anilinobenzenesulfonic acid 3,439 1 2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid 28,025 1 3-Amino-p-anisanilide 7,425 1 1-Aminoanthraquinone 705,859 1 2-Aminoanthraquinone 201,419 1, 2 p-Aminoazobenzene 69,005 1 p-Aminoazobenzenedisulfonic acid 10,691 1 Aminoazobenzenesulfonic acid 89,325 1 6-Amino-3,4'-azodi[benzenesulfonic acid] 104,943 1 7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic acid 6,512 1, 3 2-Amino-p-benzenedisulfonic acid 12,757 2 o-Aminobenzenesulfonic acid (Orthanilic acid) 28,260 1 m-Aminobenzoic acid tech 55 4 p-Aminobenzoic acid, ethyl ester 100 4 2-Aminobenzothiazole 2,205 2, 3 p-Aminobenzyldimethylamine 7,122 2, 3 p-Aminobenzylmethylamine 11,311 2, 3 Aminobisphenol ester 50,127 1 1-Amino-4-bromo-2-anthraquinonesulfonic acid (Bromamine acid) and salts 615,719
See footnotes at end of table. 7
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Quantity Competitive • Intermediate status (pounds) 1 1-Amino-2-bromo-4-hydroxyanthraquinone 105,626 3 4-Amino-6-chloro-m-benzenedisulfonamide 63,987 1 2-Amino-5-chlorobenzophenone 13,600 1 3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 7,260 1, 2 3-Amino-5-chloro-4-hydroxybenzenesulfonic acid 7,953 2 2-Amino-6-chloro-4-nitrophenol hydrochloride 5,024 1 2-Amino-4-chlorophenol 18,706 2 3-Amino-6-chloro-4-sulfobenzoic acid 4,412 1 2-Amino-5-chloro-p-toluenesulfonic acid (Lake Red C acid) 165,687 1 6-Amino-4-chloro-m-toluenesulfonic acid ISO2H=11 (2B acid) 182,406 1 6-Amino-4-chloro-m-toluenesulfonic acid, (2B acid) sodium salt 5,000 2 4-Amino-o-cresol 200 1 1-Amino-2,4-dibromoanthraquinone 14,811 2 1-Amino-9,10-dihydro-9,10-dioxo-2-anthracenesulfonic acid 8,718 4 2-(4-Amino-2,5-dimethoxyphenylsulfony1)ethanol 7,407 2 2-Amino-4,6-dinitrophenol (Picramic acid) 706 3 Aminoepoxy liquid 2,944 2 2-Amino-N-ethylbenzenesulfonanilide 82,744 1 N-(2-Aminoethyl)-3-hydroxy-2-naphthamide hydro- chloride 850 3 2-Amino-N-ethyl-5-nitrobenzenesulfonanilide 1,999 2 2-(3-Amino-4-hydroxyphenylsulfonyl)ethanol 10,250 2 Amino-J-pyrazolone 4,400 1, 2, 3 2-Amino-5-methoxybenzenesulfonic acid 17,987 3 2-Amino-6-methoxybenzothiazole 18,232 2 2-(2-Amino-4-methoxyphenylsulfonyl)ethanol . 2,998 1 4'-Amino-N-methylacetanilide 18,474 2 3-Amino-4-methylbenzamide 14,417 1 3-Amino-1,5-naphthalenedisulfonic acid (Cassella acid) and salt 402,316 1 3-Amino-2,7-naphthalenedisulfonic acid 5,103 2 •4-Amino-2,7-naphthalenedisulfonic acid 3,003 1 6-Amino-1,3-naphthalenedisulfonic acid (Amino J acid) 30,450 1 7-Amino-1,3-naphthalenedisulfonic acid (Amino G acid and salt) 239,585 1 2-Amino-l-naphthalenesulfonic acid (Tobias acid) 220,460 1 4-Amino-l-naphthalenesulfonic acid, sodium salt (Sodium naphthionate) 1,089,492 1, 2 5-Amino-l-naphthalenesulfonic acid (Laurent's acid) 24,245
See.footnotes at end of table. 8
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Competitive Intermediate Quantity status (pounds) 1 5-Amino-2-naphthalenesulfonic acid (1,6-Cleve's acid) 167,018 1 5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid mixed) 150,167 1 6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 6,295 1, 2 8-Amino-l-naphthalenesulfonic acid (Peri acid) 68,574 1 8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid) 111,897 1 8-Amino-2-naphthalenesulfonic acid, sodium salt (1,7-Cleve's acid, sodium salt) 38,278 2 8-Amino-1,3,6-naphthalenetrisulfonic acid (Koch's acid) 12,159 1, 2, 3 8-Amino-2-naphthol 19,222 2 6-Amino-l-naphthol-3,5-disulfonic acid 2,596 1 7-Amino-l-naphthol-3,6-disulfonie acid (2R acid) 20,373 3 8-Amino-l-naphthol-3,5-disulfonic acid (K acid) 4,346 1 8-Amino-l-naphthol-3,6-disulfonic acid (H acid) and salts 2,243,340 2 8-Amino-l-naphthol-5,7-disulfonic acid (Chicago acid) and salts 250,824 1 1-Amino-2-naphthol-4-sulfonic .acid (1,2,4-acid) 205,953 1 6-Amino- l-naphthol-3-sulfonic acid (J acid) 459,562 1 7-Amino-l-naphthol-3-sulfonic acid (Gamma acid) 393,854 1 8-Amino-l-naphthol-5-sulfonic acid (S acid) 2,685 1 2-Amino-5-nitrobenzenesulfonic acid [S03H=1] 14,780 1 2-Amino-5-nitrobenzenesulfonic acid, sodium salt 4,388 4 2-Amino-S-nitrobenzoic acid 121 2, 3 2-Amino-6-nitrobenzothiazole 11,494 2 2-Amino-5-nitro-N-(phenethyl)benzenesulfonamide 4,350 1, 2, 3 . 2-Amino-4-nitrophenol 138,085 1 2-Amino-5-nitrophenol 12,762 ' '1 4-Am.no-4'-nitro-2,2'-stilbenedisulfonic acid 46,703
1 6-Aminopenicillanic acid- -- - 52,033 2 m-Aminophenol 348,509 1 o-Aminophenol 42,482 1 p-Aminophenol 280,133 2 p-Aminophenol hydrochloride-. 165 1 p-[(p-Aminophenyl)azojbenzenr.sulfonic acid, sodium salt. 76,857 1 2-(p-Aminopheny1)-6-methylbenzotzo1e 29,586 2 2-(3-AminophenylSulfonyl)thanc1 38,279 2 Amino sulfon BR 2,010 1 6-Amino-m-toluenesulfonic acid 66,760
See footnotes at end of table. 9
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
Quant ty ompetitive Intermediate status ( minds 1 8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid) and salts 202,141 6-Anilino-1-naphthol-3-sulfonic acid (Phenyl J acid) 14,393 2 7-Anilino-l-naphthol-3-sulfonic acid (Phenyl gamma acid) 4,568 3 Anis base 1,116 1, 2 -1-Anisic acid 2,332 2 m-Anisidine 100 1 o-Anisidine 247,180 1 p-Anisidine 27,120 1 Anthracene, refined 2/ 120,151 1 Anthranilic acid (o-Tminobenzoic acid) 62,070 2 Anthra[1,9-cd]pyrazol-6(2H)-one (Pyrazolanthrone) 1,000 1 Anthraquinone 501,165 2 Antioxygene MTBZ 500 2, 4 Antistatic agent 25,188 1 AP Condensation product 218,592 3 L-Aspartic acid 110 1, 2 Azobenzene 4,864 1 4 1 ,4"F-Azobis[4-biphenylcarboxylic acid] (Azo yellow acid) 16,466 1 4',4'"-Azobis[4-biphenylcarboxylic acid], disodium salt (Azo yellow acid, disodium salt) 4,730 1 Benzaldehyde tech 105,821 4 1-Benzamido-4-chloroanthraquinone 1,000 1 4-Benzamido-5-hydroxy-1,7-naphthalenedisulfonic acid (Benzoyl-K-acid) 3,410 1 Benzenesulfonic acid, sodium salt 7,047 1 Benzenesulfonyl chloride 92,171 1 Benzidine 549 1 Benzidine dihydrochloride 94,884 2 3-Benzidinesulfonic acid 2,531 4 Benzil (Bibenzoyl) 5,511 1 Benzilic acid 2,800 1 Benzoic anhydride 1,102 4 DL-Benzoyl acid 9,921 1 Benzoyl-m-hydroxyacetophenone 20,905 3 Benzyldiethyl(2,6-xylylcarbamoylmethyl)ammonium benzoate (Bitrex) 427 2 N-Benzyl-3,7-dioctyl phenothiazine 880 1 N-Benzyl-N-ethyl-m-toluidine 150 3 Biligrafin acid 4,848 1 [1X-Binaphthalene]-8,8'-dicarboxylic acid (Dina 19,440 acid)------ 2, 3 4-Biphenylcarboxylic acid 6,999
See footnotes at end of table. 1 0
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
ompetit Ve Intermediate Quantity status (pounds) 1 2,2',4,4'-Biphenyltetrol 1,953 4 4,4'-Bis[p-dimethylamino]benzophenone (Michler's ketone) 5,016 4 Bleaching agent E3M 500 4 Blue K base 1,323 3 Brake fluid 28,140 3 Brilliant blue 4G base 19,795 1 2-Bromo-4,6-dinitroaniline 10,315 2 4-Bromo-3,5-resorcylamide 75 1 2-Bromo-a-resorcylic acid 1,200 2 N-Butylacetanilide 2,225 4 p,n-Butylaminobenzoic acid, ethyl ester 2,200 1 p-Butylaniline 3,188 1 4-tert-Butylcatechol 38,444 1 p-tert-Butylcyclohexanol 198 1 p-tert-Butylphenol 16,049 2 BYK-P-104 27,482 3 Calcium benzoate tech 1,220 1 Carbazole 2/ 192,138 3 Castrol 3C 16,650 3 Catalyst A 111 1 Cellulose acetate phthalate 9,351 1 2'-Chloroacetoacetanilide 38,228 1 4'-Chloroacetoacetanilide 24,200 4 a-Chloroacetophenone 4,409 1 5-Chloro-2-aminobenzotrifluoride 11,803. 1 o-Chloroaniline 29,024 1 p-Chloroaniline 75,288 1 5-Chloro-o-anisidine UNTH2=11 88,835 1 1-Chloroanthraquinone 19,922 4 o-Chlorobenzaldehyde 5,000 1 o-Chlorobenzoic acid 1,598 2 o-Chlorobenzonitrile 222 1 p-Chlorobenzoyl chloride 3,300 3 p-Chloro-2-benzylpyridine 3,637 3 4'-Chlorochalcone 9,510 1 •-Chloro-m-cresol 3,373 1 2-Chloro-1,4-dibutoxy-5-nitrobenzene 1,102 1 2-Chloro-1.4-diethoxy-5-nitrobenzene 6,352 1 4'-Chloro-2,5'dimethoxyacetoacetanilide 51,862 1 4-Chloro-2,5-dimethoxyanilihe 276,309 1 2-Chloro-4,6-dinitroaniline 21,436 2 1-Chloro-2,4-dinitrobenzene 88,184 1 [(2-Chloroethyl)methylamino]benzildehyde 500
See footnotes at end of table. 1 1
Table 3.--Benzenoid intermediates: U.S. general imports entered under. Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Competitive Quantity Intermediate (poufids) status ■ $101111 0 1 Ch lorohydroquinone 1,100 1 5-Chloro-2-hydroxybenzophenone 2,200 1 4-Chlorometanilic acid 6,703 1 6-Chlorometanilic acid 1.2;818 1 1-Chloro-2-methylanthraquinone 6,035 1 6-Chloro-2-methylpyrazolone 46,632 2, 3 4-Chloro-5-nitro-2-aminophenol 5,826 1 2-Chloro-4-nitroaniline 54,780 1 4-Chloro-2-nitroaniline 144,754 4 Chlorophenamidine 25,132 1 o-Chlorophenol 11,023 1 p-Chlorophenol 60,002 2 2-Chlorophenothiazine 66 3 4-(p-Chlorophenoxy)phenyl isocyanate 254,805 1 4-Chloro-m-phenylenediamine 1,555 1 2-Chloro-p-phenylenediamine sulfate 3,520 4 (o-Chlorophenol)hydrazine hydrochloride 1,504 1, 2 1-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 51,590 2 1-(o-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 15,398 1 2-Chloropyridine 1,378 2 5-Chloro-8-quinolinol hydrochloride 8,760 1 o-Chlorotoluene 199,403 1 4-Chloro-o-toluidine [N1-1 2=11 56,142 1 5-Chloro-o-toluidine [NH 2=11 329,555 1 p-Chloro-a,a,a-trifluorotoluene 14,985 1, 2 4-Chloro-a,a,a-trifluoro-o-toluidine 11,082 1 2-Chloro-p-xylene 21,019 1, 2 Chlor products 646,965 3 Cofill 1,984 3 Compound STE 286 859 3 Corinac A 10,000 3 Corrosion controller 16,128 1, 2 Couplers 3, 31, 2736 1,450 1 m-Cresol 2/ 128,910 1 m,p-Cresol 2/ 1,268,667
1 p-Cresol 2/T. 2,077,575 2 2,3-Cresotic acid 64,975 2, 3 2,3-Cresotic acid, methyl ester 225,000 1 Cresylic acid, refined 7/ 584,219 2 Crisvon assorted 548 1, 3 p-Cumenylphenol 13,670 1 p-[(2-Cyanoethyl)methylaminolbenzaldehyde 12,645 3 Cycloheptanone 2,646 3 1,4-Cyclohexanediamine 3,352 1 Cyclohexanesulfamic acid, calcium salt 11,023
See footnotes at end of table. 12
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
ompet t ye Intermediate status (pounds) 1 Cyclohexanesulfamic acid, sodium salt 47,000 1 Cyclohexanone oxime 661 1 Cyclopentanone 4,410 4. Decachlorobiphenyl 11,023 3 Decacyclene 2,287 1 Decahydronaphthalene (Decalin) 97,002 2 Decaltal N - 3,696 2 Decaltal S 14,300 4 Decylbenzene 1,146,321 1 Dental chemicals 433 4 Dequart A 2,205 2 Desmodur R, RF, TT 42,728 1 3,5-Diacetamido-2,4,6-triiodobenzoic acid (Urografin acid) 109,938 1 2,6-Diaminoanthraquinone 26,621 2 4,4'-Diaminobenzanilide 445 1 2,4-Diaminobenzenesulfonic acid 32,531 1 2,5-Diaminobenzenesulfonic acid 9,008 2 4,4'-Diamino-1,1'-bianthraquinone-3,3'-disulfonic acid, disodium salt 40,835 1 4,4'-Diamino-2,2'-biphenyldisulfonic acid 27,811 4 1,4-Diamino-2,3-dihydroanthraquinnne 14,583 2, 3 1,8-Diaminonaphthalene 24,255 1 4,4'-Diamino-2,2'-stilbenedisulfonic acid 600,916 1 6,8-Dianilino-l-naphthalenesulfonic acid 14,207 3 2,5-Dianilinoterephthalic acid 990 4 p-Diazo-3-ethoxydiethylaniline 298 1, 3 2-Diazo-l-naphthol-5-sulfonic acid sodium salt 1,326 1 2,6-Dibenzamidoanthraquinone 13,892 1 4,5-Dibenzamido-1,1'-iminodianthraquinone 102,738 2 (1,2-Dibromoethyl)benzene 600 1 2,6-Di-tert-butyl-p-cresol 9,205 1 2,5-Dichloroaniline 169,879 1 3,4-Dichloroaniline 180,782 1 1,5-Dichloroanthraquinone . 183,052 1 1,8-Dichloroanthraquinone 79,771 4 1,5(and 1,8)-Dichloroanthraquinone 112 2 2,6-Dichlorobenzaldehyde 3,411 1 m-Dichlorobenzene 19,728 1, 2 3,3'-Dichlorobenzidine, base and salts 476,675 1 2,5-Dichloro-4-(3-methy1-5-oxo-2-pyrazolin-l-y1)- benzenesulfonic acid 129,116 2 5,8-Dichloro-l-naphthol 3,712 2 2,3-Dichloro-1,4-naphthoquinone (Dichlone) 148,079 1 2,6-Dichloro-4-nitroaniline 2,100 3 1,3-Dichloro-4-nitrobenzene 200 See flatmates at end of table. 13
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
Competitive Intermediate Qwntity status oUnds) 1,2 1-(2,5'-Dichloropheny1)-3-methy1-2-pyrazolin-5-one---- 6,949 2, 3 2,3-Dichloro-6-,quinoxalinecarbonyl chloride 48,657 1 2,5-Dichlorosulfanilic acid 44,022 1 p,a-Dichlorotoluene 12,320 4 (Dicyclohexanol propane) 2,205 1 4-(2,5-Diethoxy-4-nitrophenyl)morpholine 6,208 1 p-(Diethylaminolbenzaldehyde 15,601 1 m-(Diethylamino)phenol 241,961 1 ' 9,10-Dihydro-]-nitro-9,10-dioxo-2-anthroic acid 3,960 1 1,4-Dihydroxyanthraquinone (Quinazarin) 136,529 1 1,5-Dihydroxyanthraquinone (Anthrarufin) 82,295 1 1,8-Dihydroxyanthraquinone (Chrysazin) 100,805 1 2,6-Dihydroxyanthraquinone 1,600 1 1,5-Dihydroxy-4,8-dinitroanthraquinone (4,8-Dinitro- anthrarufin) 10,917 1-- 1,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro- chrysazin) 23,844 2 3-Dihydroxyethylamino-4-ethoxyacetanilide 85,547 1 2,5-Dihydroxy-N-(2-hydroxyethyl)benzamide 655 1,2 3,6-Dihydroxy-2,7-naphthalenedisulfonic acid 4,546 1 3,6-Dihydroxy-2,7-naphthalenedisulfonic acid, sodium salt 7,000 1 4,5-Dihydroxy-2,7-naphthalenedisulfonic acid (Chromotropic acid) 40,369 1 6,7-Dihydroxy-2-naphthalenesulfonic acid 147,645 1, 2, 3 6,7-Dihydroxy-2-naphthalenesulfonic acid, sodium salt 39,855 2, 3 1,4-Dimes idinoanthraquinone 53,100 2 2',4'-Dimethoxyacetoacetanilide 41,685 2, 3 2',5'-Dimethoxyacetoacetanilide 30,065 2 2,4-Dimethoxyaniline 125,905 1, 2 2,5-Dimethoxyaniline 18,979 1 p-Dimethoxybenzene 14,550 1 3,3'-Dimethoxybenzidine (o-Dianisidine) 36,948 3 N-(3,4-Dimethoxyphenethyl)-2-(3,4-dimethoxypheny1)- acetamide 16,536 1, 2 2,5-Dimethoxysulfanilanilide 70,950 2 3,4-Dimethoxytoluene 27,756 1 p-(Dimethylamino)benzaldehyde 5,124 2 4-(Dimethylamino)pyridine 110 3 5,5-Dimethy1-1,3-cyclohexadione- 66 3 N,N-Dimethy1-4-hydroxymetanilamide 1,425 1 NO-Dimethyl-p-phenylenediamine 2,314 2 N,N-Dimethyl-p-toluidine 2,200 2 2,4-Dinitroacetanilide 4,400
See footnotes at end of table. 14
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
Competitive Intermediate Quantity status (pounds)
1 2,4-Dinitroaniline 105,784 1 p-(2,4-Dinitroanilino)phenol-- 600 1 3,5-Dinitrobenzoic acid tech 29,983 3 3,5-DinitrObenzoyl chloride 55 1 Dinitrostilbenedisulfonic acid 72,821 1 4,4'-Dinitro-2,2'-stilbenedisulfonic acid 368,872 3 Dioctylphenothiazine 8,850 2 Dioxamino acid 20,710 1 Diphenylacetonitrile 990 3 1,1-Dipheny1-2-propanone 396 2 Diresorcyl sulfide 551 1 1,5-Di(o-toluidino)anthraquinone 300 2 Ditoluidinoterephthalic acid 29,105 4 Dodecenylsuccinic anhydride 3,968 3 Dyestuffs 1,742 3 EDM 383 3,968 3 Electrolube No. 2G 4,850 4 BP-Enerj et lubricant 720 1, 4 (Epoxyethyl)benzene 2,646 4 3-Ethoxy-2-hydroxybenzaldehyde 19,414 2 6-Ethoxy-2-merraptobenzothiazole 1,980 1 3-(Ethylamino)-p-cresol 4,270 1 2-(N-Ethylanilino)ethanol 2,205 1 2- Ethylanthraquinone 88,867 1 Ethylbenzene 3,788,120 2 N-Ethyl-N,N'-dimethyl-N'-phenethylenediamine 20,177 2 2-Ethylisonicotinonitri1e 2,646 4 2-Ethylnitrobenzene 1,014 4 p-Ethylphenol 10,148 2 N-Ethyl-5-sulfoanthranilic acid 3,123 4 Ethylsulfonylbenzoxazolinone 6,598 1 1-Ethylnylcyclohexanol 2,783 3 Fluorene-9-one 716 3 F luorob en zene 221 1 o-Formylbenzenesulfonic acid, sodium salt 79,951 3 Galvaplan 1416 37,258 2 Gentisic acid (2,5-Dihydroxybenzoic acid) 1,102 3 Glycerol, monocresyl ether 4,240 2 Glycerol trimellitate anhydride (GTMA) 336 2, 3 Hardener 2,901 1 Heliographic chemical 1,506 1 Hexamethylene diisocyanate 15,874 1 1,6-Hexanediamine (Hexamethylenediamine) 2,000 2 Hippuric acid 10,100 2 HK base of J acid Urea 12,446
See footnotes at end of table. 15
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
ompetitive Intermediate Quant ty status ounds
3 Hydrazine reagent 660 2 2-Hydroxy-m-apisaldehyde (o-Vanillin) 8,806 1 p-Hydroxybenzoic acid 534,704 1 p-Hydroxybenzoic acid, ethyl ester 1,100 1 p-Hydroxybenzoic acid, methyl ester 24,230 1 p-Hydroxybenzoic acid, propyl ester . 17,075 2, 3 2-Hydroxy-3-carbazolecarboxylic acid 39,072 2 2-Hydroxy-3-dibenzofurancarboxylic acid 31,377 1 N-(2-Hydroxyethyl)-a-resorcylamide 400 1 N-(2-Hydroxyethyl)-6-resorcylamide 1,605 1 3-Hydroxy-N-(2-hydroxyethyl)-2-naphthamide 400 1 4-Hydroxymetanilamide 74,036 1, 3 4-Hydroxymetanilic acid 51,895 4 2-Hydroxy-4=methoxybenzophenone, sulfonated 600 2 4-Hydroxy-N-methylquinolone - 4,351 2 1-Hydroxy-N-morpholinoethy1-2-naphthamide hydrochloride 700 1 8-Hydroxy-l-naphthalenesulfonic acid 29 1, 2 1-Hydroxy-2-naphthoic acid 6,614 1 3-Hydroxy-2-naphthoic acid (B.O.N.) 1,293,250 1 3-Hydroxy-2-naphthoic acid (B.O.N.) sodium salt 9,500 1 3-Hydroxy-2-naphthoic acid, methyl ester 2,880 1 1-Hydroxy-2-naphthoic acid, phenyl ester 1,984 2 2-Hydroxy-1,4-naphthoquinone 100 1, 2 N-(7-Hydroxy-l-naphthyl)acetamide 22,127 1 2-Hydroxy-5-nitrometanilic acid 27,650 4 2-Hydroxy-4-n-octoxylbenzophenone 220 2, 3 Imidopyrazol-3-sulfonic acid 48,766 1 1,1'-Iminobis[4-benzamidoanthraquinone] 4 28,162 1 7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid]. (J acid imide) 1, 803 1 7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid]- disodium salt 7,213 1 1,1-Iminodianthraquinone (Dianthrimide) 2,000 2 Iminodibenzyl (10,11-Dihydro-5H-dibenzib,flazepine) 5,292 1, 3 5-Imino-3-methyl-1-phenylpyrazol 12,213 2 Implenal AP 6,600 4 5-Indanol 110 1 Indole-2,3-dione 28,040 3 Inkoleum 136 2 Irganox 103,431 2 Irisol ether 11,457 4 4-Isocyanatotoly1-2-ethyl carbamoyl chloride 3,360 3 Isoplast 2,150
See footnotes at end of table. 16
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Quantity Competitive Intermediate status (pounds) 1 4,4!-Isopropylidenediphenol (Bisphenol A) 121,826 1 Isoquinoline 24,475 1 Isothiocyanic acid, phenyl ester 4,571 1 Isoviolanthrone (Isodibenzanthrone) 16,249 3 a-Ketoglutaric acid 220 2 Kleenfuel AS 95,810 2 Lekutherm hardener M 21,398 1 Leuco-1,4-diaminoanthraquinone 29,086 1 Leuco-1,4,5,8-tetrahydroxyanthraquinone 11,988 1 Maleic hydrazide 206,318 2 Mandelonitrile 55 1 Marking ink thinner 2,450 1 Metanilamide 16,208 1 Metanilanilide 51,760 1 Metanilic acid (m-Aminobenzenesulfonic acid) 426,317 2 m-Methoxybenzaldehyde 4,142 4-Methoxymetanilic acid 4,656 1, 2 4-Methoxy-m-phenylenediamine 26,114 2 4-Methoxy-m-phenylenediamine sulfate 11,799 1 5-Methoxy-m-phenylenediamine sulfate 220 3 5'-Methyl-o-acetanisidide 18,000 1 1-(Methylamino)anthraquinone 5,018 2, 3 6-(Methylamino)-1-naphthol-3-sulfonic acid 85,355 1-Methylamino-4-(p-toluidino)anthraquinone 7,275 1 N-Methylaniline 45,200 2 2-Methyl-p-anisidine [NH 2.1] (m-Cresidine) 3,087 1 5-Methyl-o-anisidine [NH2.1] (p-Cresidine) 91,139 3 4-Methylcatechol 15,040 1 Methylcyclohexanol 441 3 Methylcyclohexylmethyl phenol 5,767 2 4,4'-Methylenebis(cyclohexylamine) 149,954 Methylhydroquinone 19,841 2-Methylindole 32,518 2, 3 2-Methylindoline 16,102 1 p-(3-Methy1-5-oxo-2-pyrazolin-l-y1)benzenesulfonic acid 26,198 1 1-Methyl-2-phenylindole 29,654 1, 3 3-Methyl-l-pheny1-2-pyrazolin-S-one 224,779 1 Methylphenylpyrazolone 188,919 4 1-Methyl-4(1H)-quinolone 2,381 2 2-Methylresorcino1 2,283 2 2-(Methylsulfony1)-4-nitroaniline 7,250 1 4-(Methylthio)phenol 251,327 2 Methyl-p-toluenesulfonate 14,139 2, 3 3-Methyl-l-p-toly1-2-pyrazolin-5-one 84,972
See footnotes at end of table. 17
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
Competitive Intermediate Qua77.t ty status (poUnds) 2 Monobenzylphenyl malonate 3,858 3 MS 339 330 3 Napof 50 123,769 1 1,5-Naphthalenediol .18,202 4 1,6-Naphthalenediol 291 2 2,3-Naphthalenediol 4,935 2 2,7-Naphthalenediol 2,870 1 1,5-Naphthalenedisulfonic acid, sodium salt 8,039 1, 2 2,7-Naphthalenedisulfonic acid 48,996 2 2,7-Naphthalenedisulfonic acid, disodium salt 1,000 3 1-Naphthalenesulfonic acid, sodium salt 4,361 2 1,3,6-Naphthalenetrisulfonic acid, sodium salt 60,000. 2 1,3,6-Naphthalenetrisulfonic acid, trisodium salt 20,676 2 1,3,6(and 1,3,7)-Naphthalenetrisulfonic acid, sodium salt 192,727 1, 2, 3 Naphthalic anhydride 102,742 1 1-Naphthol 96,509 1 2-Naphthol 2,945,909 2 1-Naphthol-3,6-disulfonic acid 34,851 1 2-Naphthol-3,6-disulfonic acid, disodium salt (R salt) 198,694 1 2-Naphthol-6,8-disulfonic acid, disodium and dipotassium salt (G salt) 221,760 3 1-Naphthol-3-sulfonic acid 2,492 1 1-Naphthol-4-sulfonic acid (Neville-Winther acid) 59,390 1 1-Naphthol-5-sulfonic acid (L acid) and salts 43,187 2 2-Naphthol-7-sulfonic acid, sodium salt 46,845 1, 2, 3 1,4-Naphthoquinone 64,559 4 N-(1-Naphthyl)acetoacetamide 100 1 1-Naphthylamine 33,904 3 NC base 8,405 3 Nitrazin GRL 13,287 1 m-Nitroaniline 112,715 1 o-Nitroaniline 75,936 1 p-Nitroaniline 32,000 1 '2-Nitro-p-anisidine [NH 2=1] 15,000 1 4-Nitro-o-anisidine [NH 2=1] 3,307 1. 5-Nitro-o-anisidine [NH2=1] 21,000 1 o-Nitroanisol 165,790 1 m-Nitrobenzaldehyde 1,200 2 p-Nitrobenzenearsonic acid 3,000 1 m-Nitrobenzoic acid 15,542 1 p-Nitrobenzoic acid 29,983 1 p-Nitrobenzoyl chloride 20,944 1 Nitronaphthol-(5-Nitro-l-diazo-2-naphthol-4- sulfonic acid) 33,058 See footnotes at end of table. 18
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Competitive Intermediate Quantity status (pounds) 3 3-Nitro-p-phenetidine 3,750 3 m-Nitrophenol 220 1 o-Nitrophenol 11,561 1 2-Nitro-p-phenylenediamine 675 3 4-Nitro-m-phenylenediamine 639 2 p-(Nitrophenyl) hydrazine hydrochloride 630 3 p-Nitrophenylphosphate, disodium salt 173 4 Nitro sulfon A-TRF 13,400 4 Nitro sulfon B - 130,138 1 p-Nitrotoluene 18,020 1, 2 4-Nitro-o-toluidine [NH 2=1] 1,151 1 5-Nitro-o-toluidine [NH 2-1] 31,477 4 Norclean 19,582 1 5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester 46,982 1 5-0xo-1-(p-sulfopheny1)-2-pyrazolin-3-carboxylic acid (Pyrazolone T) 56,457 1, 3 p,p'-Oxybis(benzenesulfonhydrazide) 13,700 1 4,4'-Oxydianiline 1,112 1 4,4'-Oxydibenzenesulfonyl chloride 2,319 2 Palio fast green 8G, crude 46,498 1, 2 3,4,9,10-Perylenetetracarboxylic acid 22,757 1 o-Phenetidine 4,851 1 p-Phenetidine 88,200 1 Phenol 2/ 4,783 2 Phenolene 30,423 1 Phenylacetic acid 11,023 3 N,W-m-Phenylenebistacetoacetamidel 200 1 m-Phenylenediamine 6,450 1 o-Phenylenediamine 119,151 1 p-Phenylenediamine 16,219 3 m-Phenylenediisopropylidinebis[tert-butyl peroxide] 6,609 1 DL-2-Phenylglycine 12,400 2 Phenylhydrazine 530,538 2 2-Phenylimidazole 396 2 2-Phenylindole 55,270 1 N-Pheny1-2-naphthylamine 60,060 1 N-Phenyl-p-phenylenediamine hydrochloride 1,000 1 p-Phenylphenol 317,026 1 Phenyl sulfone 12,500 3 1-Pheny1-2-thiourea 2,204 1 Phloroglucinol (1,3,5-Trihydroxybenzene) 5,970 1 Phthalic anhydride 2/ 7,450,580 1 Phthalocyanine crude, copper salt 2,399,789 1 Phthalocyanine crude, copper salt, monochlorinated 30,000
See footnotes at end of table. 19
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued
Competitive Quantity status Intermediate (pounds) 1 Phthalocyanine green 192,597 Phthalo green crude 186,963 2 Phthalonitrile 59,524 1 Pigment Violet BL base 400 3 Polyalkylbenzene 6,285,150 4 Polystyrene sodium sulfonate 4,061 2, 3 Printing pastes and mixtures 2,487 2, 4 Products, other 12,297 4 Pyrazinecarboxylic acid 1,500 2, 3 2-Pyridinecarboxaldehyde 2,812 2 2,5-Pyridinedicarboxylic acid 18,736 3 3-Pyridinesulfonic acid 110 1, 2, 3 Pyrocatechol (1,2-Dihydroxybenzene) 488,297 1 Pyromellitic dianhydride 82,099 1 Quinoline 970 1, 2 2,4-Quinolinediol and sodium salt 133,051 1 8-Quinolinol, tech 22,612 1 8-Quinolinol sulfate 1,982 1 Quinuclidinol 324 2 Resolin black developer RL 313,098 2 E3-Resorcylami.de 2,801 1, 2 a-Resorcylic acid 5,449 2 y-Resorcylic acid 104 1, 3 Rexoquin 44,533 Rubber-processing chemicals: Accelerators: 1 Accelerator HX (N-Ethylcyclohexylamine) 551 3 Accelerator P extra N 1,323 4 Vulkacit CZ 4,409 2 Vulkacit P Extra N 1,323 2 Ureka base (2-(2,4-Dinitrophenylthio)benzo- thiazole) 15,510 Antioxidants: 1 Antioxidant AP (Aldol-a-naphthylamine condensate) 1,102 2 Antioxidant DOD (4,4'-Dioxydiphenyl) 220 2 Antioxidant MB (2-Benzimidazolethiol) 8,378 2 Antioxidant ZMB (2-Benzimidazolethiol, zinc salt) 5,733 1 1,2-Dihydro-6-ethoxy-2,2,4-Trimethylquinoline 167,648 1 N,N'-Di-2-naphthyl-p-phenylenediamine 7,480 2 Nonox WSL 2,860 2 Nonox WS0 4,664 1 Nonox ZA 2,310 1 N-Phenyl-2-naphthylamine 67,606 1 Blowing agents: Porofor BSH (Benzenesulfonyl 1 hydrazide) 2,205
See footnotes at end of table.
20
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
Competitive Intermediate Quantity status (pounds) Rubber-processing chemicals--Continued Peptizers: 1, 2 Pentachlorobenzenethiol 124,697 1 Pentachlorobenzenethiol, zinc salt 89,916 Total, rubber-processing chemicals 507,05 3 Rust inhibitors 460 3 SA 509 99 1 Salicyclic acid tech. B grade 5,512 2, 3 Scintillators 282 3 SD 2236 33 1 Sevriton 915 3 5-(3-Sodiumsulphopropoxy)isophthalic acid, dimethyl ester 13,036 1 Sopanox 162,802 2 Stabaxol 1 10,911 2 Stabaxol PCD 8,058 2 Stabilizer 1097 1,323 1 Styrene monomer 2/ . 13,628,773 1 m-SulfamidopyrazolOpe 6,482 2 Sulfanilic dicarbonic acid 3,813 1 4-Sulfoanthranilic acid 486 2 4,4'-Sulfonyldiphenol(4,4'-Dihydroxydiphenylsulfone) 15,432 1 5-Sulfosalicylic acid 7,000 4 Sun screen agent 772 3 Synt-a-lube 99 2, 3 Tamol NNOK 440 1 p-Terphenyl (Phenylbiphenyl) 686 3 Tetraarylsilicate 11,990 2 Tetrahydrolene 7,406 1 1,2,3,4-Tetrahydronaphthalene 48,546 2 Tetramethy1enediaminebis[acetoacetamide] 50 1 2,2',4,4'-Tetraoxydiphenyl 25 2 Thianthrenedicarboxylic acid 18,075 2 Thiazole 8,179 1 Miocarbanilide 43,199 1 p-Thiocresol 702 1, 2 4,4'-Thiodiresorcinol (Diresorcyl sulfide) 5,503 2 2,5-Thiophenedicarboxylic acid 101,478 2 Tinuvin 326 2,205 2, 3 Tinuvin 328 3,748 3 Tinuvin P 35,274 1 (3,3'-Dimethylbenzidine) 80,595 1 o-Tolidine dihydrochloride 52,388 1 3,3'-Tolidine-6,6'-disulfonic acid 13,915 1 Toluene-2,4-diamine 227,017 See footnotes at end of table.
21.
Table .--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued '
C ompetitive Intermediate Quant ty status (pounds) 2 Toluene-2,5-diamine 1,124 1 Toluene- 2, 5-diamine sulfate 55,561 1 p-Toluenesulfonic acid, ethyl ester 3,927 2 p-Toluenesulfonic acid, methyl ester 27,450 1 m-Toluidine 184,136 1 p-Toluidine . 5,060 1 p-Toluidine-m-sulfonic acid 21,097 1 8-(p-Toluidino)-1-naphthalenesulfonic acid 8,556 2 p-Tolunitrile 2,250 2 2,2'-(p-Tolyimino)diethanol 868 1 1,2,4-Trichlorobenzene 264,60G 1 a,a,a-Trifluoro-m-toluidine 441 1 3,4,5-Trimethoxybenzoic acid 5,509 1 2,3,3-Trimethy1-3V-indole 13,92E 1 1,3,3-Trimethyl-A -a-indolineacetaldehyde 2,288 1 1,3,3-Trimethy1-2-methyleneindoline (Trimethyl base) 2,280 1 Triphenylphosphine 82,300 2 DL Tryptophane - 660 2 Ultramid activator 5,060 1 7,7 1 -Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] (Urea J acid) 186,226 2 U.V. Absorbers 121 2 Vinylcarbazole, mono 393 2 Vulcafor ZEP 1,078 4 Watch repair oil 579 2 Wevo wax assorted blocks 431 2 m-Xylenediamine 551 3 2,6-Xylenol 44,092 3 2,3-Xylidine 44,084 1 2,4-Xylidine (m-Xylidine) 29,423 3 2,5-Xylidine (p-Xylidine) 13,218 2 2,6-Xylidine 20,567 1 Xylidine mixtures 12,012 3 'Xylylenediisocyanate 550 4 Z-3604 14,458 2 Zupin 88,184 1, 2, 3, 4 All other intermediates 115,076 Total quantity 78,187,654 Total invoice value--- $38,898,975
See footnotes on following page. 22
Table 3.--Benzenoid intermediates: U.S. general imports entered under Schedule 4, Part 1B, TSUS, showing competitive status 1/, 1969 --Continued •
See footnotes below for table 3 (Intermediates)
1/ Competitive status of imports valued for duty purposes: 1. Competitive - duty based on American Selling Price. 2. Noncompetitive - duty based on U.S. value. 3. Noncompetitive - duty based on export value or foreign value. 4. Not available. 2/ Statistics on imports for consumption by quantity, value, and country of origin of this item, which is specifically named in the TSUSA, are published by the U.S. Department of Commerce. For additional information on the statistics in this report, see the Introduction.