Clay Mineralogy, Provenance, and Sequence Stratigraphy of Upper Ordovician Shales in Eastern

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Clay Mineralogy, Provenance, and Sequence Stratigraphy of Upper Ordovician Shales in Eastern Clay Mineralogy, Provenance, and Sequence Stratigraphy of Upper Ordovician Shales in Eastern Ohio A thesis presented to the faculty of the College of Arts and Sciences of Ohio University In partial fulfillment of the requirements for the degree Master of Science Devin R. Fitzgerald April 2016 © 2016 Devin R. Fitzgerald. All Rights Reserved. 2 This thesis titled Clay Mineralogy, Provenance, and Sequence Stratigraphy of Upper Ordovician Shales in Eastern Ohio by DEVIN R. FITZGERALD has been approved for the Department of Geological Sciences and The College of Arts and Sciences by Gregory Nadon Associate Professor of Geological Sciences Robert Frank Dean, College of Arts and Sciences 3 ABSTRACT FITZGERALD, DEVIN R., M.S., April 2016, Geological Sciences Clay Mineralogy, Provenance, and Sequence Stratigraphy of Upper Ordovician Shales in Eastern Ohio. Director of Thesis: Gregory Nadon A combination of x-ray diffraction analyses of core data and spectral gamma ray logs were used to interpret the largely shale succession of the Late Ordovician between the top of the Trenton Limestone and the Queenston Shale in the subsurface of east-central Ohio. The four county study area is within the back-bulge region of the foreland basin associated with the Taconic Orogeny. The XRD data from the basal portion of the section reveal an increase upward in chlorite and quartz along with a decrease in carbonate, which is consistent with an increase in detrital rather than authigenic clays. Detrital chlorite is a common clay mineral in sediments shed from mountain belts and the appearance of the clay allows constraints to be placed on the transition from under to overfilled foreland basin. Correlation of six 4th-order sequences from 300 wells allowed construction of isopach maps throughout the 450 m interval. The isopach maps show that subsidence across the area was consistent and augmented by some combination of compaction over pre-existing structural and depositional features. 4 ACKNOWLEDGMENTS The author wishes to recognize first and foremost, Eastern Mountain Fuel, the company that has employed and paid for this research project and a full time opportunity on completion of the research. Eastern Mountain Fuel’s owner/geologist Bob Thomas has provided me with guidance, opportunity, and encouragement. I appreciate his never ending enthusiasm for the industry and academic side of Geology. I also want to thank geologist Tom Thomas (EMF) for his support and help when problems arise with my GeoGraphix Software, and for being extremely helpful in creating the files to be easily used and analyzed within the data section. Eastern Mountain Fuel has employed me since 2011, and I am extremely grateful for all the opportunities they have given me. I also want to acknowledge Artex Energy Group for helping to provide all data necessary in this research project including funding. I look forward to working as a team over many years to come in the Appalachian Basin. In addition to my employers this thesis would not have been possible without the assistance of Dr. Greg Nadon, my advisor on the research project. I thank you for being particularly patient with me over the last two years in the finishing of this project. Your knowledge of sedimentology, tectonics, and sequence stratigraphy has been wonderful in helping me develop my skills. A big thank you also goes out to my committee members Dr. Kidder and Dr. Nance for their advice on the research. Another thank you to Ohio University professor Dr. Gierlowski- Kordesch for making me read and write so many papers that advanced my knowledge of broad, complex sedimentary processes and environments. Lastly, I would like to acknowledge my friends and family for being so persistent with me during my time at Ohio University and my entire academic career. Without your love and continuing support I would not be in the position I am today. 5 TABLE OF CONTENTS Page Abstract………………………………………………………………………………………………………………………………………3 Acknowledgments……………………………………………………………………………………………………………………...4 List of Tables……………………………………………………………………………………………………………………………….7 List of Figures………………………………………………………………………………………………………………………………8 Chapter 1: Introduction……………………………………………………………………………………………..................10 Chapter 2: Previous Studies………………………………………………………………………………………………………13 2.1 Introduction……………………………………………………………………………………………………………13 2.2 Upper Ordovician Stratigraphy of East-Central Ohio……………………………………………….13 2.2.1 Trenton/Lexington Limestone………………………………………………………………...13 2.2.2 Point Pleasant Shale………………………………………………………………………………..17 2.2.3 Utica Shale………………………………………………………………………………………………17 2.2.4 Kope Formation………………………………………………………………………………………19 2.2.5 Cincinnati Group……………………………………………………………………………………..19 2.2.6 Queenston Shale…………………………………………………………………………………….20 2.3 Sequence Stratigraphy……………………………………………………………………………………………20 2.4 Tectonics………………………………………………………………………………………………………………..23 2.5 Clay Mineralogy………………………………………………………………………………………………………25 Chapter 3: Methodology……………………………………………………………………………………………………………30 3.1 Introduction……………………………………………………………………………………………………………30 3.2 Well Logs………………………………………………………………………………………………………………..30 3.3 XRD Data………………………………………………………………………………………………………………..33 6 Page 3.4 Well Log Evaluation of Mineralogy………………………………………………………………………….34 Chapter 4: Results…………………………………………………………………………………………………………………….41 4.1 Introduction……………………………………………………………………………………………………………41 4.2 Correlation of Lithofacies……………………………………………………………………………………….41 4.3 Isopach Maps………………………………………………………………………………………………………….46 4.4 Sequence Stratigraphy……………………………………………………………………………………………57 4.5 XRD Mineral Abundance Data…………………………………………………………………………………60 4.6 Well Log Analysis of Clay Mineralogy………………………………………………………………………64 Chapter 5: Discussion………………………………………………………………………………………………………………..70 5.1 Introduction……………………………………………………………………………………………………………70 5.2 The Creation of Infilling of Accommodation……………………………………………………………70 5.3 Provenance…………………………………………………………………………………………………………….70 Chapter 6: Conclusions……………………………………………………………………………………………………………..76 References ……………………………………………………………………………………………………………………….........77 Appendix A: XRD Data……………………………………………………………………………………………………………….82 Appendix B: Wells………………………………..……………………………………………………………………………………87 7 LIST OF TABLES Page Table 3.1: Summary of Log Functions………………………………………………………………………………………..40 Table 4.1: Average Thickness…………………………………………………………………………………………………….45 Table 4.2: XRD LePage……………………………………………………………………………………………………………….63 8 LIST OF FIGURES Page Figure 1.1: Map of Study Area…………………………………………………………………………………………………..12 Figure 2.1: Stratigraphic Equivalents in the Appalachian Basin………………………………………………….14 Figure 2.2: Depositional Setting…………………………………………………………………………………………………15 Figure 2.3: LePage #1 Cored Interval…………………………………………………………………………………………18 Figure 2.4: Sequence Stratigraphic Diagram………………………………………………………………………………21 Figure 2.5: Contacts of the clastic wedge of the Upper Ordovician…………………….……………………..22 Figure 2.6: Foreland Basin Evolution…………………………………………………………………………………………24 Figure 2.7: Dynamic Subsidence……………………………………………………………………………………………....26 Figure 2.8: Clay Minerals Chart………………………………………………………………………………………………….28 Figure 3.1: Map of Data Points………………………………………………………………………………………………….31 Figure 3.2: Example of XRD Data……………………………………………………………………………………………….35 Figure 3.3: Quirein et al. (1982) Clay Mineralogy Chart……………………………………………………………..36 Figure 3.4: Corrected Gamma-Ray…………………………………………………………………………………………….37 Figure 3.5: Study Outline…………………………………………………………………………………………………………..39 Figure 4.1: Utica/Point Pleasant Lithostratigraphy………………………………………………………………….…43 Figure 4.2: Average Percent Minerals……………………………………………………………………………………….44 Figure 4.3: Point Pleasant Isopach…………………………………………………………………………………………….47 Figure 4.4: Utica Isopach…………………………………………………………………………………………………………..48 Figure 4.5: Mud A Isopach…………………………………………………………………………………………………………49 Figure 4.6: Mud B Isopach…………………………………………………………………………………………………………50 9 Page Figure 4.7: Mud C Isopach………………………………………………………………………………………………………...51 Figure 4.8: Mud D Isopach…………………………………………………………………………………………………………52 Figure 4.9: Queenston Isopach………………………………………………………………………………………………….53 Figure 4.10: Total Sequence Isopach…………………………………………………………………………………………54 Figure 4.11: Thickness Trends Summary …………………………………………………………………………………..55 Figure 4.12: Appalachian structural trends………………………………………………………………………………..56 Figure 4.13: Sequence Stratigraphy Concepts……………………………………………………………………………58 Figure 4.14: Upper Ordovician Sequence Stratigraphy………………………………………………………………61 Figure 4.15: Sequence Stratigraphy Cored Interval……………………………………………………………………62 Figure 4.16: Spectral Gamma-Ray Plots…………………………………………………………………………………….65 Figure 4.17: Illite vs. Gamma-ray…….…………………………………………………………………………………………66 Figure 4.18: Clay minerals vs. Quartz……………………………………………………………………………………….68 Figure 4.19: Clay Minerals Plot…...................................................................................................69 Figure 5.1: Depositional Model…………………………………………………………………………………………………74 Figure 5.2: Global Sea Level………………………………………………………………………………………………………75 10 CHAPTER 1: INTRODUCTION The sedimentary rock record is dominated by mudstones (Blatt, 1982). These fine- grained sedimentary rocks can serve as sources, reservoirs, and seals of hydrocarbons; influence the flow of groundwater; and can be rich in metals (Bohacs and Lazar, 2010). Investigation of “shales” or “mudrocks” can provide information about provenance, climate, and sea level rise and
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