Chapter 7 Polymeric Materials
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Polycarbonate Lenses
Polycarbonate Lenses The most impact resistant of all lens materials is polycarbonate. Children, athletes, anyone working at a job or hobby where they might get hit in the face and need safety glasses, people with only one eye, those who fall a lot, are natural candidates for polycarbonate lenses. If safety is a prime concern, choose polycarbonate lenses. Advantages of polycarbonate lenses : 1. Polycarbonate has four to five times the impact resistance of glass or plastic. When glass or plastic lenses break, they do not break into harmless granules, but can break into sharp shards that can enter your eye and destroy your vision. Poly- carbonate is far and away the safest of all the lenses made. 2. Polycarbonate is the lightest lens material made. 3. Polycarbonate lenses naturally provide protection against ultra-violet light, at no additional charge. 4. Polycarbonate lenses come with a scratch resistant coating (not scratch proof) at no additional charge. 5. Polycarbonate is a high index material, so the lenses will be thinner than if made with glass or plastic. Disadvantages of polycarbonate lenses : 1. People in prescriptions with higher powers sometimes have trouble seeing out the edges of the lenses--your clear field of vision is not as wide as with glass or plas- tic lenses. The lenses are made with different curves than are used to make the same pre- scription power in glass or plastic, so you will see out of these lenses a little dif- ferently. People with prescriptions up to plus or minus three diopters (most people) usually have no problem adjusting to polycarbonate lenses. -
Polyacrylonitrile Ternary System
Thermodynamic Study of a Water–Dimethylformamide– Polyacrylonitrile Ternary System Lianjiang Tan,1 Ding Pan,1 Ning Pan2 1State Key Laboratory for Chemical Fiber Modification and Polymer Materials, Donghua University, Shanghai 201620, People’s Republic of China 2Biological and Agricultural Engineering Department, University of California, Davis, California 65616 Received 23 October 2007; accepted 6 March 2008 DOI 10.1002/app.28392 Published online 15 September 2008 in Wiley InterScience (www.interscience.wiley.com). ABSTRACT: Experimental cloud-point data were ob- formation. The skin–core structure and fingerlike pores in tained by cloud-point titration. The phase diagram for a polyacrylonitrile fiber may be effectively eliminated if the ternary system of water–dimethylformamide–polyacryloni- composition of the spinning solution is properly chosen, trile was determined by numerical calculation on the basis and consequently, homogeneous polyacrylonitrile fiber of the extended Flory–Huggins theory and was found to with a bicontinuous structure and good mechanical proper- agree well with the cloud-point data. To construct the theo- ties can be obtained through the spinning process. Ó 2008 retical phase diagram, three binary interaction parameters Wiley Periodicals, Inc. J Appl Polym Sci 110: 3439–3447, 2008 were obtained with different methods. The ternary phase diagram was used to investigate the mechanism of fiber Key words: fibers; mixing; phase behavior; thermodynamics INTRODUCTION with the method of cloud-point titration.1–11 At high polymer concentration, however, the interaction Polyacrylonitrile (PAN) is soluble in many polar or- between macromolecules is so strong that the poly- ganic liquids, such as dimethylformamide (DMF), di- mer solution shows signs of crystallization or methyl sulfoxide, and dimethyl acetemide. -
The Effect of Conformation Order on Gas Separation Properties Of
polymers Article The Effect of Conformation Order on Gas Separation Properties of Polyetherimide Ultem Films Julia Kostina 1,*, Sergey Legkov 1, Alexander Kolbeshin 1, Roman Nikiforov 1, Denis Bezgin 1, Alexander Yu. Nikolaev 2 and Alexander Yu. Alentiev 1,* 1 A.V. Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences, 119991 Moscow, Russia; [email protected] (S.L.); [email protected] (A.K.); [email protected] (R.N.); [email protected] (D.B.) 2 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 119334 Moscow, Russia; [email protected] * Correspondence: [email protected] (J.K.); [email protected] (A.Y.A.) Received: 16 June 2020; Accepted: 7 July 2020; Published: 16 July 2020 Abstract: Changes of the spectral characteristics of absorption bands depending on the films’ treatment method were registered for polyetherimide Ultem films. The possibility of selection of structural criteria (the ratio of the functional groups absorption bands intensities) showing all conformational changes in elementary unit with metrological processing of the results is shown. It is demonstrated that film formation from chloroform solution leads to elementary unit fragments, Ph–O–Ph0, which have an effect on macromolecule conformation and result in increasing of space between fragments of macromolecules (local polymer matrix packing loosening). Desorption of residual chloroform from films by ethanol or supercritical CO2 leads to a change of conformers set in Im–Ph–Im0 units. Quantum chemical modeling showed the possibility of convergence of these fragments in neighboring macromolecules, and consequently of interchain π–π interaction (local densification of chain packing of the polymer matrix). -
Migration of Bisphenol a from Polycarbonate Plastic of Different Qualities
Migration of bisphenol A from polycarbonate plastic of different qualities Environmental project No. 1710, 2015 [Series Title and year] Title: Editing: Migration of Bisphenol A from polycarbonate Gitte Alsing Pedersen, DTU National Food Institute, plastic of different qualities Søren Hvilsted, DTU Danish Polymer Centre, Department of Chemical and Biochemical Engineering and Jens Højslev Petersen, DTU National Food Institute Technical University of Denmark Published by: The Danish Environmental Protection Agency Strandgade 29 1401 Copenhagen K Denmark www.mst.dk/english Year: ISBN no. 2015 978-87-93352-24-7 Disclaimer: When the occasion arises, the Danish Environmental Protection Agency will publish reports and papers concerning research and development projects within the environmental sector, financed by study grants provided by the Danish Environmental Protection Agency. It should be noted that such publications do not necessarily reflect the position or opinion of the Danish Environmental Protection Agency. However, publication does indicate that, in the opinion of the Danish Environmental Protection Agency, the content represents an important contribution to the debate surrounding Danish environmental policy. Sources must be acknowledged. 2 Migration of Bisphenol A from polycarbonate plastic of different qualities Contents Foreword .................................................................................................................. 5 Conclusion and Summary ......................................................................................... -
A Review of Electrospun Carbon Fibers As Electrode Materials for Energy Storage
A Review of Electrospun Carbon Fibers as Electrode Materials for Energy Storage The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Citation Mao, Xianwen, T. Hatton, and Gregory Rutledge. “A Review of Electrospun Carbon Fibers as Electrode Materials for Energy Storage.” COC 17, no. 13 (June 1, 2013): 1390–1401. As Published http://dx.doi.org/10.2174/1385272811317130006 Publisher Bentham Science Version Author's final manuscript Citable link http://hdl.handle.net/1721.1/92409 Terms of Use Creative Commons Attribution-Noncommercial-Share Alike Detailed Terms http://creativecommons.org/licenses/by-nc-sa/4.0/ A Review of Electrospun Carbon Fibers as Electrode Materials for Energy Storage Xianwen Mao, T. Alan Hatton, and Gregory C. Rutledge* Department of Chemical Engineering, Massachusetts Institute of Technology 77 Massachusetts Avenue, Cambridge Massachusetts, 02139, USA E-mail: [email protected] Abstract: The applications of electrospun carbon fiber webs to the development of energy storages devices, including both supercapacitors and lithium ion batteries (LIB), are reviewed. Following a brief discussion of the fabrication process and characterization methods for ultrafine electrospun carbon fibers, recent advances in their performance as supercapacitors and LIBs anode materials are summarized. Optimization of the overall electrochemical properties of these materials through choice of thermal treatment conditions, incorporation of additional active components (such as carbon nanotubes, metal oxides, and catalysts), and generation of novel fibrous structures (such as core-shell, multi-channel or porous fibers) is highlighted. Further challenges related to improving the conductivity, surface area, and mechanical properties of the carbon nanofiber webs, as well as the scale-up ability of the fabrication technique, are discussed. -
Chemical Representation Biovia Databases 9.5
CHEMICAL REPRESENTATION BIOVIA DATABASES 9.5 Copyright Notice ©2015 Dassault Systèmes. All rights reserved. 3DEXPERIENCE, the Compass icon and the 3DS logo, CATIA, SOLIDWORKS, ENOVIA, DELMIA, SIMULIA, GEOVIA, EXALEAD, 3D VIA, BIOVIA and NETVIBES are commercial trademarks or registered trademarks of Dassault Systèmes or its subsidiaries in the U.S. and/or other countries. All other trademarks are owned by their respective owners. Use of any Dassault Systèmes or its subsidiaries trademarks is subject to their express written approval. Acknowledgments and References To print photographs or files of computational results (figures and/or data) obtained using BIOVIA software, acknowledge the source in an appropriate format. BIOVIA may grant permission to republish or reprint its copyrighted materials. Requests should be submitted to BIOVIA Support, either through electronic mail to [email protected], or in writing to: BIOVIA Support 5005 Wateridge Vista Drive, San Diego, CA 92121 USA No-Structures 28 Contents Chapter 2: Reaction Representation 29 Introduction 29 Overview 1 Reaction Mapping 29 Audience for this Guide 1 Mapping Reactions Automatically 30 Prerequisite knowledge 1 Mapping Reactions Manually 31 Related BIOVIA Documentation 1 Stereoconfiguration Atom Properties in Chapter 1: Molecule Representation 3 Mapped Reactions 32 Substances, structures and fragments 3 Properties of Bonds in Mapped Reactions 32 The BIOVIA Periodic Table 3 Simple Bond Properties 32 Atom Properties 3 Combined Bond Properties 33 Charges, Radicals and Isotopes -
Blends of Polycarbonate Containing Fluorinated-Bisphenol-A and Polyvinyl Chloride
Europaisches Patentamt European Patent Office © Publication number: 0 576 057 A1 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 93201533.2 int. Ci.5; C08L 69/00, C08L 27/06, C08G 64/10, //(C08L69/00, @ Date of filing: 28.05.93 27:06),(C08L27/06,69:00) © Priority: 01.06.92 US 891032 © Applicant: ENICHEM S.p.A. Piazza della Repubblica, 16 @ Date of publication of application: 1-20124 Milano(IT) 29.12.93 Bulletin 93/52 @ Inventor: Drzewinski, Michael A. © Designated Contracting States: 371 Clarksville Road, Princeton Junction AT BE CH DE DK ES FR GB GR IE IT LI LU MC New Jersey 08850(US) NL PT SE © Representative: Roggero, Sergio et al Ing. Barzano & Zanardo Milano S.p.A. Via Borgonuovo 10 1-20121 Milano (IT) © Blends of polycarbonate containing fluorinated-bisphenol-A and polyvinyl chloride. © Bisphenol A polycarbonate containing at least 15 mole % of 2,2-bis-(4-hydroxyphenyl)hexafluoropropane (6F-Bisphenol A) can be blended with polyvinyl chloride (PVC) to form a thermodynamically miscible, transpar- ent, single phase blend at all compositions. Such blends are flame resistant as well as resistant to attack by acids, bases and many organic solvents. CO Rank Xerox (UK) Business Services (3. 10/3.6/3.3. 1) EP 0 576 057 A1 BACKGROUND OF THE INVENTION Field of the Invention: 5 This invention pertains to mixtures of polyvinyl chloride (PVC) and polycarbonates which contain at least 15 mole % of fluorinated bisphenol monomer units (F-PC) such as 2,2-bis-(4-hydroxyphenyl)- hexafluoropropane (6F-bisphenol A), herein referred to as 6F-PC. -
Synthesis and Some Solution Properties of Block Copolymer Styrene—Acrylonitrile
Synthesis and some solution properties of block copolymer styrene—acrylonitrile V. CHRÁSTOVÁ, D. MIKULÁŠOVA, P. CITOVICKÝ, and J. SCHENKMAYER Department of Chemical Technology of Plastics and Fibres, Slovak Technical University, CS-812 37 Bratislava Received 19 June 1986 Styrene—acrylonitrile block copolymers were synthesized by emulsion polymerization at 30 °C, in which peroxide of powdered isotactic polypropyl ene as a heterogeneous initiator, disodium salt of ethylenediaminetetraace- tic acid as an activator, and Slovasol 2430 as a nonionic emulsifier were used. For the preparation of the block copolymer one of the characteristic proper ties of the mentioned polymerization system, i.e. the existence of long-living polystyrene radical in emulsion was evaluated. After removing of the initia tor the first monomer — styrene was polymerized up to a certain conversion and then acrylonitrile was added to the growing polystyrene radicals. A block copolymer was formed, which contained a pure polystyrene block and an acrylonitrile sequence with fragments of styrene. The obtained co polymers with various styrene—acrylonitrile ratio were characterized by IR spectroscopy. By means of viscometry and light scattering some of their properties in methyl ethyl ketone and ^TV-dimethylformamide were stud ied. Блок-сополимеры стирола и акрилонитрила были получены по средством эмульсионной полимеризации при 30 °С, в которой применя лись перекись порошкообразного изотактического полипропилена в качестве гетерогенного инициатора, двунатриевая соль этилен- диаминтетрауксусной кислоты в качестве активатора и Словасол 2430 в качестве неионного эмульгатора. В целях получения блок-сополимера оценивалось одно из характеристических свойств упомянутой по- лимеризационной системы, а именно присутствие долгоживущих по листирол ьных радикалов в эмульсии. После устранения инициатора первый мономер — стирол — полимеризовался до определенной степени конверсии, а затем к растущим полистирольным радикалам добавлялся акрилонитрил. -
United States Patent (19) 11 Patent Number: 4,481,333 Fleischer Et Al
United States Patent (19) 11 Patent Number: 4,481,333 Fleischer et al. 45 Date of Patent: Nov. 6, 1984 54 THERMOPLASTIC COMPOSITIONS 58 Field of Search ................................ 525/192, 199 COMPRISING WINYL CHLORIDE POLYMER, CLPE AND FLUOROPOLYMER 56) References Cited U.S. PATENT DOCUMENTS 75) Inventors: Dietrich Fleischer, Darmstadt; Eckhard Weber, Liederbach; 3,005,795 10/1961 Busse et al. ......................... 525/199 3,294,871 2/1966 Schmitt et al. ...... 52.5/154 X Johannes Brandrup, Wiesbaden, all 3,299,182 1/1967 Jennings et al. ... ... 525/192 of Fed. Rep. of Germany 3,334,157 8/1967 Larsen ..................... ... 525/99 73 Assignee: Hoechst Aktiengesellschaft, Fed. 3,940,456 2/1976 Fey et al. ............................ 525/192 Rep. of Germany Primary Examiner-Carman J. Seccuro (21) Appl. No.: 566,207 Attorney, Agent, or Firm-Connolly & Hutz 22 Filed: Dec. 28, 1983 57 ABSTRACT 30 Foreign Application Priority Data The invention relates to a thermoplastic composition which comprises vinyl chloride polymers and chlori Dec. 31, 1982 (DE Fed. Rep. of Germany ....... 3248.731 nated polyethylene and which contains finely divided 51) Int. Cl. ...................... C08L 23/28; C08L 27/06; fluoropolymers and has a markedly improved process C08L 27/18 ability, particularly when shaped by extrusion. 52 U.S. C. .................................... 525/192; 525/199; 525/239 7 Claims, No Drawings 4,481,333 2 iaries and do not provide a solution to the present prob THERMOPLASTC COMPOSITIONS lem. COMPRISINGVINYL CHLORIDE POLYMER, -
SARAN™ Polyvinylidene Chloride (PVDC) Resins
Product Safety Assessment SARAN™ Polyvinylidene Chloride (PVDC) Resins Product Safety Assessment documents are available at www.dow.com/productsafety/assess/finder.htm. Select a Topic: Names Product Overview Manufacture of Product Product Description Product Uses Exposure Potential Health Information Environmental Information Physical Hazard Information Regulatory Information Additional Information References Names CAS Nos. 25038-72-6, 9011-06-7 Vinylidene chloride copolymer SARAN polyvinylidene chloride (PVDC) resins Vinylidene chloride/methyl acrylate copolymer SARAN resins Vinylidene chloride/vinyl chloride copolymer Back to top Product Overview SARAN™ resins are white, odorless granules.1 These resins are polyvinylidene chloride (PVDC) copolymers made from polymerizing vinylidene chloride with comonomers like vinyl chloride and alkyl acrylates.2 For further information, see Product Description. SARAN resins are used extensively in packaging applications for food, pharmaceuticals, hygiene products, and sterilized medical products. They offer excellent barrier performance to moisture, oxygen, and odors.3 For further information, see Product Uses. Because SARAN resins are used extensively in food packaging, it is possible for consumers to come into contact with them. Workplace exposure is also possible.4 For further information, see Exposure Potential. SARAN resins are essentially nonirritating to the eyes and skin. Dust from SARAN products may cause temporary mechanical irritation to the skin and eyes under extreme conditions. However, the products are considered to present no significant health hazard.5 For further information, see Health Information. SARAN resins are expected to be inert in the environment. They are unlikely to accumulate in the food chain, and are practically nontoxic to aquatic organisms on an acute basis.6 For further information, see Environmental Information. -
Toxicity of the Pyrolysis and Combustion Products of Poly (Vinyl Chlorides): a Literature Assessment
FIRE AND MATERIALS VOL. II, 131-142 (1987) Toxicity of the Pyrolysis and Combustion Products of Poly (Vinyl Chlorides): A Literature Assessment Clayton Huggett and Barbara C. Levin* us Department of Commerce, National Bureau of Standards, National Engineering Laboratory, Center for Fire Research, Gaithersburg, MD 20899, USA Poly(vinyl chlorides) (PVC) constitute a major class of synthetic plastics. Many surveys of the voluminous literature have been performed. This report reviews the literature published in English from 1969 through 1984 and endeavors to be more interpretive than comprehensive. pve compounds, in general, are among the more fire resistant common organic polymers, natural or synthetic. The major products of thermal decomposition include hydrogen chloride, benzene and unsaturated hydrocarbons. In the presence of oxygen, carbon monoxide, carbon dioxide and water are included among the common combustion products. The main toxic products from PVC fires are hydrogen chloride (a sensory and pulmonary irritant) and carbon monoxide (an asphyxiant). The LCso values calculated for a series of natural and synthetic materials thermally decomposed according to the NBS toxicity test method ranged from 0.045 to 57 mgl-l in the flaming mode and from 0.045 to > 40mgl-l in the non-flaming mode. The LCso results for a PVC resin decomposed under the same conditions were 17 mg 1- 1 in the flaming mode and 20 mg 1- 1 in the non-flaming mode. These results indicate that PVC decomposition products are not extremely toxic when compared with those from other common building materials. When the combustion toxicity (based on their HCI content) of PVC materials is compared with pure HCI experiments, it appears that much of the post-exposure toxicity can be explained by the HCI tha t is genera ted. -
Plastic Materials List Original.Xlsx
Partec Institute 1030 Cavendish Rd. Mt. Gravatt East. Brisbane Qld 4122 Ph 07 3849 7878. www.partec.qld.edu.au ABREVIATIONS OF POLYMER MATERIALS AAS acrylonitrile acrylic styrene PE polyethylene ABS acrylonitrile butadiene styrene PEO poly (ethylene oxide) AES acrylonitrile ethylene ester PEP polyethylene propylene A/MMA acrylonitrile / methyl methacrylate PESU polyether sulphone AS acrylonitrile styrene PET polyethylene terephthalate ASA acrylonitrile styrene acrylate PETP crystaline pet (tetramethylene terephthalate) BMC bulk moulding compound PEX polyethylene crosslinked CA cellulose acetate PF phenol formaldehyde resin CAB cellulose acetate butyrate PI polyimide CAP cellulose acetate propionate PIB polyisobutylene CF cresol formadehyde PMMA polymethyl methacrylate CLPE chlorinated polyethylene PMP poly (4-methylpentene- I ) CLPVC /CPVC chlorinated polyvinyl chloride POB polypoxybenzoate CMC carboxymethyl cellulose POM polyoxymethylene (polyacetal) CN cellulose nitrate PP polypropylene CP cellulose propionate PPC polypropylene compound CPE chlorinated polyethylene PPE polypropylene ethylene CS casein PPF polypropylene foam DAP diallyl phthalate PPO polyphenylene oxide modified DMC dough molding compound PPDX polypropylene oxide EC ethyl cellulose PPS polyphenylene sulphide E/EA, EEA ethylene / ethyl acetate PPSU polyphenylene sulphone EEBC polyester (ether ester block copolymer) PS polystyrene E / MA ethylene methacrylate acid PSU polysulphone EP epoxide, epoxy resin PTFE polytetrafluoethylene EPS polystyrene - expandable ethylene