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Weblinks http://www.nios.ac.in/media/documents/313courseE/L30.pdf/ww http://chem.libretexts.org/Textbook_Maps/Organic_Chemistry_Textbook_Maps/Map %3A_Organic_Chemistry_(McMurry)/Unit_05%3A_Stereochemistry_at_Tetrahedral _Centers/5.10_Chirality_at_Nitrogen,_Phosphorus,_and_Sulfurw.nios.ac.in/media/do cumhttp://chem.libretexts.org/Textbook_Maps/Organic_Chemistry_Textbook_Maps/ Map%3A_ https://en.wikipedia.org/wiki/Cahn%E2%80%93Ingold%E2%80%93Prelog_priority_ rules https://en.wikipedia.org/wiki/Unsaturated_fat http://chem.libretexts.org/Textbook_Maps/Organic_Chemistry_Textbook_Maps/Map %3A_Organic_Chemistry_(Bruice)/05%3A_Stereochemistry%3A_The_Arrangement _of_Atoms_in_Space%3B_The_Stereochemistry_of_Addition_Reactions/5.17%3A_ Nitrogen_and_Phosphorus_Atoms_Can_Be_Asymmetric_Centers
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Suggested Readings
Tit TI Title: The arrangement of atoms in space Author : Jacobus Henricus van 't Hoff and Arnold Eiloart ISBN:9781316106426
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Title: Basic Stereochemistry of Organic Molecules Author: Subrata Sen Gupta ISBN13: 9780199451630
Title Stereochemistry of Organic Compounds: Principles and Applications
Author D. Nasipuri
ISBN 9788122405705
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Title Stereochemistry of Organic Compounds
Authors Ernest Ludwig Eliel, Samuel H. Wilen
ISBN 8126515708, 9788126515707
Glossary
ENATIOMERS: Enantiomers are chiral molecules that are mirror images of one another. CHIRALITY: An object or a system is chiral if it is distinguishable from its mirror image; that is, it cannot be superposed onto it. INVERTOMERS: Invertomer is a synonym of diastereomer. Diastereomerism occurs when two or more stereoisomers of a compound have different configurations at one or more and are not mirror images of each other. E-The highest priority group are on opposite sides of the double bond. Z- The highest priority group are on the same sides .R- clockwise. S- Anticlockwise v Time-Lines
Timelines Image
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Twentieth Sir Christopher kelk ingold century was a British chemist.His ground breaking work in the 1920s and 1930s on reaction mechanisms on reaction mechanisms and the electronic structure of organic compounds was responsible for the introduction into mainstream chemistry of concepts such as
nucleophile,electrophile,inducti Christopher kelk Ingold ve and resonance effects. He
also the co-author of the Cahn- ingold-prelog priority rules.Cahn is regarged as one of the chief pioneers of physical organic chemistry.Ingold began his scientific studies at Hartley university college at Southampton taking an external Bsc in 1913 with the university of London.During his study of alkyl halide,Ingold found evidence for two possible reaction mechanisms for nucleophilic substitution reactions
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Twentieth Vladimir prelog was a chemist century from the land of Bosnia.He was a swiss scientist.He received the 1975 noble prize in
chemistry for his research nto the stereochemistry of organic molecules and reactions.He
was the head of the laboratory in the swiss federal institute of technology. He continued
working on his theories,making V.prelog breakthroughs with british chemists Robert Sidney cahn
and Christopher kelk,Ingold,developing a new system of determining the structure of stereoisomers,and naming it as cahn-Ingold- Prelog priority rules.
Did You Know?
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
Description Image Why most of the food stuffs only contain trans fats? Figure-
Trans fats are unsaturated fats with a specific chemical structure,where the hydrogen atoms are on the opposite sides of the double bond. Trans fats are easily digested by the body because of the trans configuration enzymes can easily catalyse these fats.And also due to its non polar nature these are insoluble in water.Trans fats are also less expensive than the
alternatives and do not become
rancid. However,trans fats are harmful for our body.
Source SOURCE- http://makeofficework.com/why_trans_fats_do_harm.htm
Interesting facts
Essential fatty acids:
Linolenic acid is a type of fatty acid. It can refer to either of two octadecatrienoic acids that is with an 18-carbon chain and three double bonds, which are found in the cis configuration, or a mixture of the two. Linolenate in the form of esters of linolenic acid is often found in vegetable oils; traditionally, such fatty acylates are reported as the fatty acids: α-Linolenic acid and γ- Linolenic acid,
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus
They are so necessary for health, and they cannot be produced within the human body. They must be acquired through diet.
Figure -2 Alpha-linolenic acid
Source : https://www.google.co.in/webhp?sourceid=chrome- instant&rlz=1C1NHXL_enIN704IN706&ion=1&espv=2&ie=UTF- 8#q=linolenic%20acid
CHEMISTRY PAPER No. 1: Organic Chemistry-I (Nature of bonding and Stereochemistry) MODULE No. 35: Stereochemistry of the compounds containing Nitrogen, Sulphur and Phosphorus