UNITED NATIONS ST
Distr. Secretariat GENERAL
ST/SG/AC.10/C.3/2002/33 12 April 2002
ORIGINAL : ENGLISH
COMMITTEE OF EXPERTS ON THE TRANSPORT OF DANGEROUS GOODS AND ON THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS Sub-Committee of Experts on the Transport of Dangerous Goods (Twenty-first session, 1-10 July 2002 agenda item 4)
TRANSPORT OF SOLID SUBSTANCES IN BULK IN CONTAINERS
Transport of solids in portable tanks
Transmitted by the expert from the United States of America
1. At the twentieth session of the Sub-Committee, the expert from the United States of America agreed to coordinate the development of requirements for the transport of solid dangerous goods in portable tanks and to lead a correspondence group to review proposed requirements and develop a proposal for submission to the twenty-first session. Many solids are not currently authorized for transport in portable tanks in the Model Regulations. Consignors that transport solid dangerous goods are required to acquire competent authority approvals to transport their solids in tanks which imposes unnecessary burdens and delays. Adoption of this proposal will result in the assignment of tank codes for the majority of solids dangerous goods listed in the Dangerous Goods List that are suitable and safe for transport in portable tanks. In developing the assignments, a rationalized approach was developed (see Annex 1) and other regulations that provide portable tank requirements for solids were considered (e.g. IMDG Code, ADR/RID and 49 CFR). Annex 2 of this paper provides proposed assignments that are based on the rationalized approach that is provided in Annex 1. As there are a few solids that are currently assigned tank codes in the Model Regulations, it is proposed that these tank codes be changed in accordance with the rationalized approach for consistency where necessary. Annex 3 is a list of currently assigned tank provisions that would need to be changed in the Model Regulations based on the rationalized approach. There are a number of proposed portable tank assignments for solid substances that may require further consideration by the Sub-Committee based on comments that were provided by correspondence group members. To facilitate the review of these substances, Annex 4 is provided. Annex 4 provides a list of substances and proposed tank assignments where one or more correspondence group members provided a comment relative to the tank assignment.
GE.02-
ST/SG/AC.10/C.3/2002/33 page 2
2. Tank assignments were not considered appropriate for the following items:
- explosives and desensitized explosives;
- certain blasting explosives and ammonium nitrate (this will be handled by a separate proposal);
- Division 6.2 substances;
- UN 3255, tert-Butyl hypochlorite and UN 2907, Isosorbide dinitrate mixture, which should be forbidden from transport in portable tanks;
- articles; and
- substances where it was not considered practical to transport them in portable tanks, including but not limited to:
UN 3314, Plastics moulding compound UN 2000, Celluloid UN 1379, Paper, Unsaturated oil treated UN 1386, Seed cake UN 1365, Cotton, wet UN 2793, Ferrous metal borings, shavings, turnings or cuttings UN 2217, Seed cake UN 1364, Cotton, waste oily UN 2002, Celluloid, scrap UN 2006, Plastics, nitrocellulose based, self-heating, n.o.s. UN 2016, Ammunition toxic, non-explosive
3. This paper proposes the following new portable tank special provision (TP) for solids. The Sub- committee is invited to consider this TP and take a decision on whether it is necessary for solids.
"TPXX The portable tank shall not be loaded with solid substances that are at a temperature outside of the portable tank’s design temperature range or that would exceed the portable tank’s maximum permissible gross mass when loaded in the portable tank. The substance should be so loaded that the weight is evenly distributed within the tank to prevent unsafe handling and transport conditions. If the substance is offered for transport under elevated temperature conditions, the degree of filling requirements prescribed in 4.2.1.9.5.1 and the requirements of 4.2.1.18 shall be met."
Additionally it is proposed that Division 4.3 PG I solids be assigned TP 7.
4. At its twentieth session the Sub-Committee indicated that portable tank requirements for molten substances and solids that are loaded molten and transported in the solid state should also be addressed. Provisions for these substances are proposed as follows:
ST/SG/AC.10/C.3/2002/33 page 3
Add a new paragraph 4.2.1.18 as follows:
"4.2.1.18 Additional provisions applicable to the transport of elevated temperature substances and solid substances transported above their melting point but below 100°C
4.2.1.18.1 Solid substances transported above their melting point but below 100°C and elevated temperature substances that are not assigned a portable tank instruction in column (10) of the Dangerous Goods List may be transported in portable tanks provided that the solid substances are:
(a) classified in Division 6.1 or Classes 8 or 9 and have no subsidia ry risk other than that of Division 6.1 or Class 8; and (b) are in packing group II or III; or (c) the solid substances are authorized for transport in portable tanks by the competent authority in accordance with the provisions of 6.7.1.3.
4.2.1.18.2 Unless otherwise indicated in the Dangerous Goods List of Chapter 3.2, portable tanks used for the transport of these solid substances shall conform to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II. An equally suitable portable tank may be selected according to 4.2.5.2.5. The maximum degree of filling (in %) shall be determined according to 4.2.1.9.5 (TP3). The shell shall be thermally insulated to ensure that the temperature of its outer surface excluding openings and their closures does not exceed 70 °C."
(Annexes in English only)
ST/SG/AC.10/C.3/2002/33 page 4 Annex 1
Annex 1 Proposed rationalized approach for the assignment of tank instructions for solids
The following is a proposed rationalized approach for the assignment of solids to portable tanks:
Tank Instructions for Solids – Rationalized Approach Class/SR PG TI TP 4.1 I Not Authorized II T3** TPXX III T1* TPXX 4.2 I T21* TPXX II T3 TPXX III T1 TPXX 4.3 I T6* TP7, TPXX 4.3/6.1 I Not Authorized II T3 TPXX III T1 TPXX 5.1 I Not Authorized II T3 TPXX III T1 TPXX 5.2 I Not Authorized II T23*** TPXX 6.1 I T6 TPXX II T3 TPXX III T1 TPXX 8 I T6 TPXX II T3 TPXX III T1 TPXX 9 II T3 TPXX III T1 TPXX
* Some substances in this category are not assigned a T-Code on the basis of the risk posed in transport. ** Wetted substances that may possess explosive properties are not authorized. Some substances in this category are not assigned a T-Code on the basis of the risk posed in transport. *** Only Type F organic peroxides are authorized.
ST/SG/AC.10/C.3/2002/33 page 5 Annex 2
X TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed UN T T3
6.1 6.1 6.1 8 8 SR
II II II II II II II II II II II II II II II II II II II II II PG II
Codes - 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 Class 4.1
Annex 2
25% water
Codes for Solids not Currently Assigned T Solids not Currently Codes for -
Proposed T Proposed ORGANIC, N.O.S. N.O.S.
ATED
E SOLID, TOXIC, INORGANIC, N.O.S. E SOLID, TOXIC, INORGANIC, HAFNIUM POWDER, WETTED with not less than 25% water HAFNIUM POWDER, WETTED with not less than 25% water TITANIUM POWDER, WETTED with not less than ZIRCONIUM POWDER, WETTED TITANIUM HYDRIDE N.O.S. METAL HYDRIDES, FLAMMABLE, FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, FLAMMABLE SOLID, CORROSIVE, free from yellow and white phosphorus PHOSPHORUS HEPTASULPHIDE, powdered or granulated, not exceeding 840 RUBBER SCRAP or RUBBER SHODDY, 45% microns and rubber content exceeding N.O.S. FLAMMABLE SOLID, ORGANIC, LEAD PHOSPHITE, DIBASIC N.O.S. METAL POWDER, FLAMMABLE, FLAMMABL DECABORANE N.O.S. FLAMMABLE SOLID, TOXIC, ORGANIC, FERROCERIUM and white phosphorus SESQUISULPHIDE, free from yellow PHOSPHORUS and white phosphorus TRISULPHIDE, free from yellow PHOSPHORUS INORGANIC, FLAMMABLE SOLID, ZIRCONIUM HYDRIDE N.O.S. OF ORGANIC COMPOUNDS, FLAMMABLE, METAL SALTS Name/Description CO ALUMINIUM POWDER,
1326 1352 1358 1871 3182 3180 2925 1339 1345 1325 2989 3089 3179 1868 2926 1323 1341 1343 3178 1437 3181 UN# 1309 ST/SG/AC.10/C.3/2002/33 page 6 Annex 2
XX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TP TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 Proposed Proposed UN T T1 T1 T1 T1
8 5.1 8 6.1 SR
III III III III III III III III III III III III III III III III III III III III III PG III III III III
1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4. 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 Class 4.1 4.1 4.1 4.1
D
D, CORROSIVE, INORGANIC, N.O.S. D, CORROSIVE, INORGANIC,
ribbons METAL HYDRIDES, FLAMMABLE, N.O.S. METAL HYDRIDES, FLAMMABLE, ALUMINIUM POWDER, COATE N.O.S. FLAMMABLE SOLID, OXIDIZING, ORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, N.O.S. FLAMMABLE SOLID, TOXIC, INORGANIC, TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS TITANIUM SPONGE GRANULES COBALT RESINATE, PRECIPITATED FLAMMABLE SOLI PHOSPHORUS, AMORPHOUS CALCIUM RESINATE BORNEOL FLAMMABLE SOLID, INORGANIC, N.O.S. FLAMMABLE SOLID, INORGANIC, N.O.S. METAL POWDER, FLAMMABLE, DICYCLOHEXYLAMMONIUM NITRITE COBALT NAPHTHENATES, POWDER ZINC RESINATE METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. OF ORGANIC COMPOUNDS, FLAMMABLE, METAL SALTS PARAFORMALDEHYDE than 50% magnesium in pellets, MAGNESIUM ALLOYS with more MAGNESIUM or turnings or METALDEHYDE NITRONAPHTHALENE Name/Description DIBASIC LEAD PHOSPHITE, MANGANESE RESINATE HEXAMETHYLENETETRAMINE FUSED CALCIUM RESINATE,
3182 1309 3097 2925 3179 2878 1318 3180 1338 1313 1312 3178 3089 2687 2001 2714 3181 2213 1869 1332 2538 UN# 2989 1330 1328 1314 ST/SG/AC.10/C.3/2002/33 page 7 Annex 2
PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) T TPXX TPXX TPXX
Code -
T1 T1 T1 T21 T21 T21 T21 T21 T21 T21 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T1 T1 T1 T1
6.1 4.3 8 8 8 SR
III III III I I I I I I I II II II II II II II II II II II PG III III III III
4.1 4.1 4.1 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 Class 4.1 4.1 4.1 4.1
HEATING, CORROSIVE, N.O.S.
- INORGANIC, N.O.S. s than 25% water of crystallization
ANIC, N.O.S.
METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. METAL, N.O.S. or PYROPHORIC
DIMETHYLANILINE
HEATING SOLID, CORROSIVE, HEATING SOLID, CORROSIVE, - NITROSO (CYCLOOCTADIENE PHOSPHINES) PHOSPHABICYCLONONANES - - CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) CALCIUM DITHIONITE (CALCIUM FISH MEAL (FISH SCRAP), UNSTABILIZED SODIUM METHYLATE SELF SELF ALKALI METAL ALCOHOLATES, HAFNIUM POWDER, DRY p or SODIUM SULPHIDE with less than 30% water SODIUM SULPHIDE, ANHYDROUS of crystallization 9 les SODIUM HYDROSULPHIDE with BARIUM ALLOYS, PYROPHORIC PYROPHORIC N.O.S. PYROPHORIC SOLID, INORGANIC, ALUMINIUM BOROHYDRIDE XANTHATES FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. FLAMMABLE SOLID, ORG FLAMMABLE SOLID, SULPHUR TRIBUTYLPHOSPHANE DRY METAL CATALYST, DRY ZIRCONIUM POWDER, Name/Description synthetic CAMPHOR, CRUDE or NAPHTHALENE, REFINED NAPHTHALENE, AMORPHOUS SILICON POWDER, ALUMINIUM RESINATE
1923 1374 1431 3192 3206 2545 1369 1385 2940 2318 1854 1383 3200 2870 3342 2926 1325 1350 3254 2881 2008 UN# 2717 1334 1346 2715 ST/SG/AC.10/C.3/2002/33 page 8 Annex 2
X TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T1 T3 T3 T3 T1 T1 Proposed Proposed UN T T3 T3 T3 T3
8 8 8 SR 6.1 6.1 5.1 8
II II II II II II II II II II II II II II II III III III III III III PG II II II II
4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 Class 4.2 4.2 4.2 4.2
GANIC, N.O.S. HEATING, CORROSIVE, N.O.S.
-
HEATING -
HEATING, N.O.S.
- on
ELF
CATALYST, DRY HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. HEATING SOLID, CORROSIVE, OR HEATING SOLID, CORROSIVE, HEATING SOLID, INORGANIC, N.O.S. HEATING SOLID, INORGANIC, HEATING SOLID, ORGANIC, N.O.S. HEATING SOLID, ORGANIC, N.O.S. HEATING SOLID, TOXIC, ORGANIC, N.O.S. SOLID, TOXIC, HEATING TOXIC, INORGANIC, N.O.S. HEATING SOLID, OXIDIZING, N.O.S. HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. HEATING SOLID, ------SELF SELF ALKALI METAL ALCOHOLATES, SELF SPENT obtained from coal gas purification IRON OXIDE, SPENT or IRON SPONGE, THIOUREA DIOXIDE MAGNESIUM DIAMIDE CARBON, animal or vegetable origin N.O.S. ALKALINE EARTH METAL ALCOHOLATES, a visible excess of liquid METAL CATALYST, WETTED with SELF THIOUREA DIOXIDE METAL POWDER, S SELF SELF or POTASSIUM SULPHIDE with less than POTASSIUM SULPHIDE, ANHYDROUS 30% water of crystallizati POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) POTASSIUM DITHIONITE DRY TITANIUM POWDER, METAL DRY ZIRCONIUM POWDER, SELF ORGANIC PIGMENTS, (SODIUM HYDROSULPHITE) SODIUM DITHIONITE Name/Description SELF SELF SELF SELF
127
3192 3206 3126 1376 3341 2004 1361 3205 1378 3088 3341 3189 3190 3088 1382 1929 2546 2881 2008 3313 1384 UN# 3128 3191 3 3126 ST/SG/AC.10/C.3/2002/33 page 9 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
1 6 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T T1 T1 T1 T6 T6 T6 T6 T6 T T6 T6 Proposed Proposed UN T T1 T1 T1 T1
5.1 6.1 4.3 6.1 8 4.2 4.2 4.2 4.2 SR
III III III III III III III III III III III III III III I I I I I I I I PG III III III III
4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 Class 4.2 4.2 4.2 4.2
HEATING, N.O.S.
-
E or SYNTHETIC, N.O.S. with oil E or SYNTHETIC,
REACTIVE, SELF HEATING, N.O.S. - -
HEATING -
ALCOHOLATES, N.O.S. ALCOHOLATES, HEATING, N.O.S.
-
REACTIVE SOLID, CORROSIVE, N.O.S. REACTIVE SOLID, CORROSIVE, REACTIVE SOLID, SELF - - HEATING SOLID, OXIDIZING, N.O.S. HEATING SOLID, TOXIC, ORGANIC, N.O.S. HEATING SOLID, N.O.S. HEATING SOLID, TOXIC, INORGANIC, HEATING SOLID, INORGANIC, N.O.S. HEATING SOLID, - - - - WATER MAGNESIUM HYDRIDE ALLOYS POWDER MAGNESIUM POWDER or MAGNESIUM METALLIC SUBSTANCE, WATER ZINC POWDER or ZINC DUST WATER TITANIUM POWDER, DRY METAL CATALYST, DRY SELF CALCIUM CARBIDE CALCIUM HYDRIDE MANEB or MANEB PREPARATION with not less than 60% maneb MANEB or MANEB PREPARATION XANTHATES CARBON, ACTIVATED ZIRCONIUM POWDER, DRY HAFNIUM POWDER, DRY METAL POWDER, SELF METAL POWDER, METAL ALKALINE EARTH SELF SELF ORGANIC PIGMENTS, SELF TITANIUM DISULPHIDE Name/Description SCRAP ZIRCONIUM ANIMAL or VEGETABL FIBRES or FABRICS, or vegetable origin CARBON, animal SELF
31
31 2010 1418 3209 1436 3135 2546 2881 3191 1402 1404 2210 3342 1362 2008 2545 3189 3205 3127 3313 3128 3174 UN# 1932 1373 1361 3190 ST/SG/AC.10/C.3/2002/33 page 10 Annex 2
TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX TPXX TPXX TPXX Proposed TP Note(s) TP7, TPXX TP7, TPXX TP7, TPXX TP7, TPXX
Code -
T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T3 T3 T3 Proposed Proposed UN T T6 T6 T6 T6
4.2 8 SR 4.1 4.1
I I I I I I I I I I I I I I I I I I I II II II PG I I I I
4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 Class 4.3 4.3 4.3 4.3
RSION
REACTIVE, FLAMMABLE, N.O.S. REACTIVE, FLAMMABLE,
-
LID, WATER
REACTIVE, N.O.S.
HEATING, N.O.S. - -
REACTIVE, N.O.S. -
S, WATER
REACTIVE SOLID, SELF N.O.S. REACTIVE SOLID, CORROSIVE, REACTIVE SOLID, N.O.S. REACTIVE SOLID, FLAMMABLE, N.O.S. REACTIVE SOLID,
- - - - POTASSIUM METAL ALLOYS SODIUM BOROHYDRIDE METAL HYDRIDE WATER BARIUM WATER ALKALINE EARTH METAL AMALGAM WATER LITHIUM NITRIDE LITHIUM BOROHYDRIDE LITHIUM SODIUM HYDRIDE ALKALINE EARTH METAL DISPE ALKALI METAL DISPERSION or CAESIUM ALUMINIUM HYDRIDE LITHIUM ALUMINIUM HYDRIDE POTASSIUM SODIUM ALLOYS POTASSIUM SODIUM SODIUM POTASSIUM AMALGAM ALKALI METAL WATER METALLIC SUBSTANCE, LITHIUM HYDRIDE Name/Description BOROHYDRIDE POTASSIUM RUBIDIUM COMPOUND, SO ORGANOMETALLIC WATER
1420 1426 1409 3135 1400 3131 1392 2813 2806 1413 1415 1427 1391 1407 2463 1410 1422 1428 2257 1389 3208 1414 UN# 1870 1423 3372 3132 ST/SG/AC.10/C.3/2002/33 page 11 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3 T3
4.2 4.1 4.2 4.1 SR 6.1 6.1 4.2 4.1
I II II II II II II II II I II II II II II II II II II II II PG II II II II II
4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 Class 4.3 4.3 4.3 4.3 4.3
-
HEATING, N.O.S. - REACTIVE, FLAMMABLE, N.O.S. REACTIVE, FLAMMABLE, -
TIVE, SELF
REAC REACTIVE, N.O.S.
- -
TED
REACTIVE, N.O.S. - PRODUCTS or ALUMINIUM REMELTING BY PRODUCTS or ALUMINIUM REMELTING -
IDE
REACTIVE SOLID, N.O.S. REACTIVE SOLID, N.O.S. REACTIVE SOLID, FLAMMABLE, REACTIVE SOLID, TOXIC, N.O.S. SOLID, TOXIC, REACTIVE - - - CALCIUM CARBIDE METAL HYDRIDES, WATER LITHIUM SILICON ZINC POWDER or ZINC DUST free from yellow and white phosphorus PHOSPHORUS PENTASULPHIDE, WATER CERIUM, turnings or gritty powder ALUMINIUM CARBIDE LITHIUM HYDRIDE, FUSED SOLID ALUMINIUM POWDER, UNCOA ALKALI METAL AMIDES LITHIUM FERROSILICON SODIUM ALUMINIUM HYDRIDE ALUMINIUM SMELTING BY PRODUCTS METALLIC SUBSTANCE, WATER WATER WATER METALLIC SUBSTANCE, COMPOUND, SOLID, WATER ORGANOMETALLIC METAL ALLOY, N.O.S. ALKALINE EARTH CALCIUM SILICIDE MAGNESIUM SILIC Name/Description WATER POWDER ALUMINIUM FERROSILICON POWDER or MAGNESIUM ALLOYS MAGNESIUM POWDER CALCIUM
340
1402 1409 1417 1436 1 3132 3078 1394 2805 1396 1390 2830 2835 3170 3208 2813 3209 3372 1393 1405 2624 UN# 3134 1395 1418 1401 ST/SG/AC.10/C.3/2002/33 page 12 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T3 T3 T3 T3 T3 Proposed Proposed UN T T1 T1 T1 T1 T1
4.2 8 4.1 4.2 4.2 6.1 6.1 4.2 SR 4.1
III III III III III III III III III III III III III III III II II II II II PG III III III III III
.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 5.1 5.1 5.1 5.1 5.1 Class 4.3 4.3 4 4.3 4.3
heating - -
HEATING, N.O.S. - REACTIVE, FLAMMABLE, N.O.S. REACTIVE, FLAMMABLE,
-
REACTIVE, N.O.S. REACTIVE, SELF , N.O.S.
HEATING, N.O.S. - -
-
UND, SOLID, WATER PRODUCTS or ALUMINIUM REMELTING BY PRODUCTS or -
REACTIVE SOLID, CORROSIVE, N.O.S. REACTIVE SOLID, CORROSIVE, N.O.S. REACTIVE SOLID, FLAMMABLE, REACTIVE SOLID, SELF REACTIVE SOLID, TOXIC REACTIVE SOLID, N.O.S. REACTIVE SOLID, - - - - - LIC SUBSTANCE, WATER MAGNESIUM PERCHLORATE CHLORATE AND BORATE MIXTURE SODIUM CHLORITE SODIUM CHLORATE SODIUM BROMATE METAL WATER but less than 90% silicon FERROSILICON with 30% or more WATER than 0.1% calcium carbide CALCIUM CYANAMIDE with more ZINC POWDER or ZINC DUST PRODUCTS ZINC ASHES WATER ALUMINIUM POWDER, UNCOATED UNCOATED ALUMINIUM SILICON POWDER, WATER CALCIUM MANGANESE SILICON CALCIUM MANGANESE WATER METALLIC SUBSTANCE, COMPO ORGANOMETALLIC BY ALUMINIUM SMELTING POWDER or MAGNESIUM ALLOYS MAGNESIUM POWDER Name/Description SILICIDE CALCIUM WATER not less than 149 microns COATED, particle size MAGNESIUM GRANULES, STABILIZED against self or MANEB PREPARATION, MANEB, STABILIZED
496
1475 1458 1 1495 1494 3209 3135 1408 3134 1403 1436 1435 3131 1396 1398 3132 2844 3208 3372 3170 1418 UN# 1405 2813 2950 2968 ST/SG/AC.10/C.3/2002/33 page 13 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3 T3
8 8 6.1 6.1 6.1 SR
II II II II II II II II II II II II II II II II II II II II II PG II II II II II
.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 Class 5.1 5.1 5.1 5.1 5.1
RE
PEROXIDE ALCIUM PEROXIDE SILVER NITRATE ZINC AMMONIUM NITRITE N.O.S. OXIDIZING SOLID, CORROSIVE, BARIUM LEAD NITRATE THALLIUM CHLORATE HYPOCHLORITES, INORGANIC, N.O.S. HYPOCHLORITES, INORGANIC, SODIUM PEROXOBORATE, ANHYDROUS POTASSIUM PERMANGANATE POTASSIUM PERCHLORATE POTASSIUM NITRITE BROMATES, INORGANIC, N.O.S. CHLORATES, INORGANIC, N.O.S. C POTASSIUM BROMATE POTASSIUM CHLORATE DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID SALTS ACID, DRY or DICHLOROISOCYANURIC DICHLOROISOCYANURIC AMMONIUM DICHROMATE N.O.S. CHLORITES, INORGANIC, ANHYDROUS CHROMIUM TRIOXIDE, N.O.S. PEROXIDES, INORGANIC, STRONTIUM PEROXIDE Name/Description BROMATE MAGNESIUM LITHIUM PEROXIDE MIXTU DRY or LITHIUM HYPOCHLORITE LITHIUM HYPOCHLORITE, ACID, DRY TRICHLOROISOCYANURIC
1493 1512 3085 1449 1469 2573 3212 3247 1490 1489 1488 1450 1461 1457 1484 1485 2465 1439 1462 1463 1483 1509 UN# 1473 1472 1471 2468 ST/SG/AC.10/C.3/2002/33 page 14 Annex 2
PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX T TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3
6.1 6.1 6.1 6.1 6.1 SR 6.1 6.1 6.1 6.1
II II II II II II II II II II II II II II II II II II II II II PG II II II II
5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 Class 5.1 5.1 5.1 5.1
M NITRITE MIXTURE
PERCHLORATE RIUM BROMATE STRONTIUM PERCHLORATE CALCIUM CHLORITE N.O.S. PERCHLORATES, INORGANIC, POTASSIUM NITRATE AND SODIU CALCIUM CHLORATE ZINC NITRATE or CALCIUM HYPOCHLORITE, HYDRATED CALCIUM HYPOCHLORITE, HYDRATED, but not more than 10% water MIXTURE with not less than 5.5% ZINC PEROXIDE ZINC CHLORATE STRONTIUM CHLORATE PERMANGANATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, SODIUM PERCHLORATE SODIUM PERMANGANATE COPPER CHLORATE MAGNESIUM CHLORATE BARIUM PERMANGANATE BERYLLIUM NITRATE BARIUM CHLORATE BARIUM PERCHLORATE LEAD ZINC PERMANGANATE Name/Description N.O.S. SOLID, TOXIC, OXIDIZING available chlorine with more than 22% BARIUM HYPOCHLORITE BA BARIUM NITRATE
3
1508 1453 1481 1487 1452 1514 2880 1516 1513 1506 1482 1502 1503 2721 272 1448 2464 1445 1447 1470 1515 UN# 3087 2741 2719 1446 ST/SG/AC.10/C.3/2002/33 page 15 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX
Code -
1 T3 T3 T3 T3 T3 T3 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T T1 T1 Proposed Proposed UN T T3 T3 T3
SR
II II II II II II III III III III III III III III III III III III III III III PG II II II
5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 Class 5.1 5.1 5.1
E
E
UM PERCHLORATE NICKEL NITRITE CAESIUM NITRATE MAGNESIUM NITRATE NITRATE MIXTURE SODIUM NITRATE AND POTASSIUM CHROMIUM NITRATE AMMONIUM PERSULPHATE DIDYMIUM NITRAT ALUMINIUM NITRATE SODIUM PERSULPHATE ZINC BROMATE PEROXIDES, INORGANIC, N.O.S. FERRIC NITRATE POTASSIUM PERSULPHAT CHLORATE AND BORATE MIXTURE DRY with more than 10% but not more than CALCIUM HYPOCHLORITE MIXTURE, 39% available chlorine CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid AQUEOUS SOLUTION with not CHLORIC ACID, N.O.S. NITRITES, INORGANIC, N.O.S. NITRATES, INORGANIC, CALCI AMMONIUM PERCHLORATE MAGNESIUM CHLORIDE MIXTURE CHLORATE AND Name/Description PEROXIDE MAGNESIUM with HYPOCHLORITE MIXTURE, DRY DRY or CALCIUM CALCIUM HYPOCHLORITE, oxygen) available chlorine (8.8% available more than 39% CALCIUM PERMANGANATE
2726 1451 1474 1499 2720 1444 1465 1438 1505 2469 1483 1466 1492 1458 2208 2626 2627 1477 1455 1442 1459 UN# 1476 1748 1456 ST/SG/AC.10/C.3/2002/33 page 16 Annex 2
X TPXX TPXX TPXX TPX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T23 T23 T6 T6 T6 T6 T6 Proposed Proposed UN T T1 T1 T1 T1
6.1 SR 8 8 6.1
II II
III III III III III III III III III III III III III III III I I I I I PG III III III III
5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.2 5.2 6.1 6.1 6.1 6.1 6.1 Class 5.1 5.1 5.1 5.1
EROXIDE TYPE F, SOLID NITRATE ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, TOXIC TRIAZINE PESTICIDE, SOLID, N.O.S. DISINFECTANT, SOLID, TOXIC, CALCIUM CYANIDE FLUOROACETIC ACID SELENATES or SELENITES NITRATES, INORGANIC, N.O.S. N.O.S. PERMANGANATES, INORGANIC, GUANIDINE NITRATE CHLORIDE MIXTURE CHLORATE AND MAGNESIUM ORGANIC P NICKEL NITRATE SODIUM NITRATE LEAD DIOXIDE ZIRCONIUM NITRATE CALCIUM SODIUM NITRITE INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S PERCHLORATES, LITHIUM NITRATE POTASSIUM NITRATE MANGANESE NITRATE Name/Description NITRATE STRONTIUM PEROXIDE UREA HYDROGEN CORROSIVE, N.O.S. OXIDIZING SOLID, TOXIC, N.O.S. OXIDIZING SOLID,
3120 2763 1601 1575 2642 2630 1477 1482 1467 1459 3110 2725 1498 1872 2728 1454 1500 3215 1481 2722 1486 2724 UN# 1507 1511 3085 3087 ST/SG/AC.10/C.3/2002/33 page 17 Annex 2
X PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX T TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 Proposed Proposed UN T T6 T6 T6 T6
8 8 8 5.1 4.3 SR
I I I I I I I I I I I I I I I I I I I I I I PG I I I I
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
PESTICIDE, SOLID, TOXIC
REACTIVE, N.O.S.
- UND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. or NICOTINE PREPARATION, UND, SOLID, N.O.S.
DIPHENYLCHLOROARSINE, SOLID CADMIUM COMPOUND N.O.S. TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. TOXIC SOLID, CORROSIVE, INORGANIC, TOXIC SOLID, OXIDIZING, N.O.S. TOXIC SOLID, WATER TOXIC SOLID, INORGANIC, N.O.S. PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC, N.O.S. TOXIC SOLID, ORGANIC, N.O.S. CYANOGEN BROMIDE ARSENICAL PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE, SOLID, N.O.S. MERCURY COMPOUND, SOLID, ALUMINIUM PHOSPHIDE PESTICIDE N.O.S. PHENYLMERCURIC COMPOUND, TOXIC PYRETHROID PESTICIDE, SOLID, DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. N.O.S. or DYE INTERMEDIATE, DYE, SOLID, TOXIC, BRUCINE SOLID, TOXIC CARBAMATE PESTICIDE, PESTICIDE, SOLID, TOXIC THIOCARBAMATE BARIUM CYANIDE PESTICIDE, SOLID, TOXIC COPPER BASED Name/Description FLUOROACETATE SODIUM POTASSIUM FLUOROACETATE CHLOROARSINE DIPHENYLAMINE NICOTINE COMPO
1699 2570 2928 3290 3086 3125 3288 3345 2588 2811 1889 2759 2025 3048 2026 3349 3143 1570 2757 2771 1565 2775 UN# 2629 2628 1698 1655 ST/SG/AC.10/C.3/2002/33 page 18 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 Proposed Proposed UN T T6 T6 T6 T6
4.2 SR 4.1
I I I I I I I I I I I I I I I I I I I I I PG I I I I
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
C
HEATING, N.O.S. - ROPHENOL PESTICIDE, SOLID, TOXIC ROPHENOL PESTICIDE,
CYANIDES, SOLID
RGANOTIN COMPOUND, SOLID, N.O.S. RGANOTIN COMPOUND, SOLID, OXIC SOLID, SELF SODIUM CYANIDE BROMOBENZYL SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, TOXIC, N.O.S., solid ORGANOPHOSPHORUS COMPOUND, N.O.S., solid ORGANOARSENIC COMPOUND, ORGANOTIN PESTICIDE, SOLID, TOXIC ORGANOTIN PESTICIDE, SOLID, SODIUM CUPROCYANIDE, SOLID SOLID, TOXI ORGANOPHOSPHORUS PESTICIDE, N.O.S., inorganic, including: Arsenates, n.o.s.; ARSENIC COMPOUND, SOLID, n.o.s. Arsenites, n.o.s.; and Arsenic sulphides, POTASSIUM CYANIDE TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. TOXINS, EXTRACTED FROM LIVING ZINC CYANIDE MERCURIC POTASSIUM CYANIDE O N.O.S. CYANIDES, INORGANIC, SOLID, SUBSTITUTED NIT SUBSTITUTED SOLID, N.O.S. N.O.S. or ALKALOID SALTS, ALKALOIDS, SOLID, PESTICIDE, SOLID, TOXIC ORGANOCHLORINE SOLID, TOXIC BIPYRIDILIUM PESTICIDE, T OSMIUM TETROXIDE Name/Description N.O.S. ORGANIC, FLAMMABLE, TOXIC SOLID, PESTICIDE, SOLID, TOXIC MERCURY BASED SOLID, N.O.S. TEAR GAS SUBSTANCE, STRYCHNINE SALTS STRYCHNINE or
1689 1694 3027 3278 3280 2786 2316 2783 1557 1680 3172 1713 1626 3146 1588 2779 1544 2761 2781 3124 2471 UN# 2930 2777 1693 1692 ST/SG/AC.10/C.3/2002/33 page 19 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T6 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T6 T6 T6 T6
5.1 SR
I II II II II II II II II II II II II II II II II II II II II II PG I I I I
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
SOLID, TOXIC
ICIDE, SOLID, TOXIC olid
, p,) -
, m -
TICIDE, SOLID, TOXIC
CHLOROPHENOL - 4 - BSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC BSTITUTED NITROPHENOL PESTICIDE, AMINO - SODIUM AMMONIUM VANADATE TOXIC SOLID, OXIDIZING, N.O.S. AMMONIUM METAVANADATE NAPHTHYLTHIOUREA 2 VANADYL SULPHATE SU SOLID, TOXIC THIOCARBAMATE PESTICIDE, SOLID, TOXIC MERCURY BASED PESTICIDE, MERCURY CYANIDE ORGANOCHLORINE PESTICIDE, ORGANOTIN PES AMINOPYRIDINES (o TOXIC COPPER BASED PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, SELENIUM DISULPHIDE VANADIUM COMPOUND, N.O.S. VANADIUM COMPOUND, PEST ORGANOPHOSPHORUS SODIUM PENTACHLOROPHENATE N.O.S. TOXIC SOLID, ORGANIC, SOLID, TOXIC CARBAMATE PESTICIDE, POTASSIUM ARSENITE Name/Description s CARBONYLS, N.O.S., METAL solid COMPOUND, TOXIC, N.O.S., ORGANOMETALLIC N.O.S. SELENIUM COMPOUND, N.O.S. TELLURIUM COMPOUND,
2863 3086 2859 1651 2673 2931 2779 2771 2777 1636 2761 2786 2671 2775 2763 2657 3285 2783 2567 2811 2757 1678 UN# 3281 3282 3283 3284 ST/SG/AC.10/C.3/2002/33 page 20 Annex 2
XX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TP TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3
4.2 4.1 4.3 5.1 8 8 8 SR
II II II II II II II II II II II II II II II II II II II II II II PG II II II II
1 6.1 6.1 6.1 6.1 6. 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
REACTIVE, N.O.S. -
HEATING, N.O.S.
-
DICHLOROACETONE - TOXIC SOLID, WATER PHENYLMERCURIC NITRATE THALLIUM NITRATE CHLOROACETIC ACID, SOLID N.O.S. TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. TOXIC SOLID, CORROSIVE, INORGANIC, POTASSIUM CUPROCYANIDE SOURCES, SOLID, N.O.S. TOXINS, EXTRACTED FROM LIVING TOXIC SOLID, SELF N.O.S TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. MERCURY COMPOUND, SOLID, CADMIUM COMPOUND LEAD ARSENATES SILVER CYANIDE SODIUM ARSENITE, SOLID MEDICINE, SOLID, TOXIC, N.O.S. BENZOQUINONE TOXIC, N.O.S. PESTICIDE, SOLID, PHENACYL BROMIDE MALONONITRILE AMMONIUM POLYVANADATE 1,3 Name/Description SOLID, TOXIC PESTICIDE, ARSENICAL SOLID, TOXIC, N.O.S. N.O.S. or DYE INTERMEDIATE, DYE, SOLID, TOXIC, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, N.O.S. ORGANOTIN COMPOUND,
3125 1895 2727 1751 2928 3290 1679 3172 3124 2930 2025 2570 1617 1684 2027 3249 2587 2588 2645 2647 2861 2649 UN# 2759 3143 2781 3146 ST/SG/AC.10/C.3/2002/33 page 21 Annex 2
PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX T TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3
SR 4.1
II II II II II II II II II II II II II II II II II II II II II PG II II II II
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
ATE
NITE
CYANIDES, INORGANIC, SOLID, N.O.S. CYANIDES, INORGANIC, SOLID, DICHLOROANILINES, SOLID DINITROBENZENES, SOLID N.O.S. DISINFECTANT, SOLID, TOXIC, FERRIC ARSENATE SILVER ARSENITE PENTACHLOROPHENOL TOXIC PYRETHROID PESTICIDE, SOLID, NITROXYLENES, SOLID COPPER ARSE COPPER CYANIDE SODIUM ARSENATE TOXIC SOLID, INORGANIC, N.O.S. PHENYLMERCURIC HYDROXIDE MERCURY NUCLEATE N.O.S. TEAR GAS SUBSTANCE, SOLID, THALLIUM COMPOUND, N.O.S. THALLIUM COMPOUND, AND ZINC ARSENITE ZINC ARSENITE or ZINC ARSENATE ZINC ARSENATE, MIXTURE POTASSIUM METAVANADATE SODIUM CACODYL COMPOUND, N.O.S. PHENYLMERCURIC Name/Description POWDER BERYLLIUM BENZIDINE TETRAETHYL DITHIOPYROPHOSPHATE STRONTIUM ARSENITE
1588 1590 1597 1601 1606 1683 3155 3349 1665 1586 1587 1685 3288 1894 1639 1693 1707 1712 2864 1688 2026 UN# 1567 1885 1704 1691 ST/SG/AC.10/C.3/2002/33 page 22 Annex 2
X TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3 T3
SR
II II II II II II II II II II II II II II II II II II II II II PG II II II II II
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1 6.1
SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. NICOTINE PREPARATION, SOLID, SOLID, N.O.S. or
TE
URY IODIDE NITROTOLUENES, SOLID MERCURY OXYCYANIDE, DESENSITIZED CACODYLIC ACID MERCURY BENZOATE MERCURY THIOCYANATE MERCURY SULPHATE MERCURY ACETA MERCUROUS NITRATE MERCURIC NITRATE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE LEAD CYANIDE MERCURY GLUCONATE FERRIC ARSENITE MERCURY BROMIDES FERROUS ARSENATE MERCURY AMMONIUM CHLORIDE NICOTINE COMPOUND, NICOTINE COMPOUND, COPPER ACETOARSENITE solid NICOTINE HYDROCHLORIDE, NICOTINE SALICYLATE NAPHTHYLUREA MERC Name/Description N.O.S. COMPOUND, BARIUM NICKEL CYANIDE ACETATE PHENYLMERCURIC SOLID NICOTINE SULPHATE,
1664 1642 1572 1631 1646 1645 1629 1627 1625 3345 1620 1637 1607 1634 1608 1630 1655 1585 1656 1657 1652 1638 UN# 1564 1653 1674 1658 ST/SG/AC.10/C.3/2002/33 page 23 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3 T3
SR
II II II II II II II II II II II II II II II II II II II II II PG II II II II
1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6. 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. SOLID, N.O.S. or ALKALOID SALTS, CID, SOLID
ERCURIC ARSENATE ARSENIC BROMIDE ARSENIC A ARSENIC AMMONIUM ARSENATE SOLID CHLORODINITROBENZENES, BERYLLIUM COMPOUND, N.O.S. ARSENICAL DUST ARSENIC TRIOXIDE ARSENIC PENTOXIDE N.O.S., inorganic, including: Arsenates, n.o.s.; ARSENIC COMPOUND, SOLID, n.o.s. Arsenites, n.o.s.; and Arsenic sulphides, MERCURY OLEATE HEXAETHYL TETRAPHOSPHATE ALKALOIDS, CALCIUM ARSENATE LEAD ARSENITES MERCURY OXIDE MIXTURE, SOLID AND CALCIUM ARSENITE CALCIUM ARSENATE M NICOTINE TARTRATE MAGNESIUM ARSENATE LONDON PURPLE Name/Description SALICYLATE MERCURY POTASSIUM ARSENATE IODIDE MERCURY POTASSIUM MERCURIC CHLORIDE
1555 1554 1558 1546 1577 1566 1562 1561 1559 1557 1640 1611 1544 1573 1618 1641 1574 1623 1659 1622 1621 UN# 1644 1677 1643 1624 ST/SG/AC.10/C.3/2002/33 page 24 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T1 T1 Proposed Proposed UN T T3 T3 T3 T3
8 SR
II II II II II II II II II II II II II II II II II II II II III III PG II II II II
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
fused form -
) -
CRESOLATE - , p
- o -
, m -
ES, SOLID LAMINE METHYLPHENYL ISOCYANATE - 4 - NAPHTHY - CHLORO - SELENIUM COMPOUND, N.O.S. TELLURIUM COMPOUND, N.O.S. VANADIUM COMPOUND, N.O.S. CRESOLS, SOLID DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or VANADIUM PENTOXIDE, non SOLIDS CONTAINING TOXIC LIQUID, N.O.S. SOLIDS CONTAINING TOXIC LIQUID, TOXIC, N.O.S., solid ORGANOPHOSPHORUS COMPOUND, N.O.S., solid ORGANOARSENIC COMPOUND, METAL CARBONYLS, N.O.S., solid TOXIC, N.O.S., solid ORGANOMETALLIC COMPOUND, 3 XYLENOLS, solid solid NITROBENZOTRIFLUORIDES, CHLOROCRESOLS, solid SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, PHENOL, SOLID TOLUIDINES, SOLID XYLIDINES, SOLID AMMONIUM DINITRO CHLOROANILIN SOLID DINITROTOLUENES, Name/Description solid CHLORONITROBENZENES, DINITROANILINES beta (o NITROANILINES
3283 3284 3285 2076 3143 2862 3243 3278 3280 3281 3282 2236 2261 2306 2669 3027 1671 1708 1711 1843 2018 2038 UN# 1578 1596 1650 1661 ST/SG/AC.10/C.3/2002/33 page 25 Annex 2
PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) T TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 Proposed Proposed UN T T1 T1 T1 T1
SR
III III III III III III III III III III III III III III III III III III III III III III PG III III III III
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
, TOXIC
ATES, N.O.S.
D, INORGANIC, N.O.S. D, INORGANIC, BUTYNEDIOL - ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. ALKALOIDS, SOLID, N.O.S. or CADMIUM COMPOUND TOXIC ORGANOTIN PESTICIDE, SOLID, 1,4 SOLID THIOCARBAMATE PESTICIDE, TOXIC TRIAZINE PESTICIDE, SOLID, BIPYRIDILIUM PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, ANTIMONY LACTATE AMMONIUM FLUOROSILICATE ANILINE HYDROCHLORIDE ANTIMONY POTASSIUM TARTRATE FLUOROSILIC ZINC FLUOROSILICATE N.O.S. ORGANOTIN COMPOUND, SOLID, PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE TOXIC SOLID, ORGANIC, N.O.S. MAGNESIUM FLUOROSILICATE TOXIC NITROPHENOL PESTICIDE, SOLID, SUBSTITUTED TOXIC SOLI SOLUBLE, N.O.S. LEAD COMPOUND, N.O.S. INORGANIC, SOLID, ANTIMONY COMPOUND, SOLID, N.O.S. FROM LIVING SOURCES, TOXINS, EXTRACTED Name/Description N.O.S. SOLID, TOXIC, MEDICINE, ANTIMONY POWDER HEXACHLOROPHENE RESORCINOL
1544 2570 2786 2716 2771 2763 2781 1550 2854 1548 1551 2856 2855 3146 3345 2811 2853 2779 3288 2291 1549 3172 UN# 3249 2871 2875 2876 ST/SG/AC.10/C.3/2002/33 page 26 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 Proposed Proposed UN T T1 T1 T1 T1
SR
III III III III III III III III III III III III III III III III III III III III III PG III III III III
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1
)
-
, p -
, m RUS PESTICIDE, SOLID, TOXIC RUS PESTICIDE, -
TOLUIDINE HYDROCHLORIDE - o -
ARSANILATE CHLORO - PESTICIDE, SOLID, TOXIC, N.O.S. TOXIC PYRETHROID PESTICIDE, SOLID, BARIUM COMPOUND, N.O.S. CHLORONITROANILINES N.O.S., inorganic, including: Arsenates, n.o.s.; ARSENIC COMPOUND, SOLID, n.o.s. Arsenites, n.o.s.; and Arsenic sulphides, CHLOROANISIDINES AMINOPHENOLS (o AMMONIUM FLUORIDE SODIUM NITROCRESOLS CYANIDES, INORGANIC, SOLID, N.O.S. CYANIDES, INORGANIC, SOLID, SODIUM CHLOROACETATE POTASSIUM FLUOROSILICATE TOXIC ARSENICAL PESTICIDE, SOLID, TOXIC CARBAMATE PESTICIDE, SOLID, MERCURY BASED PESTICIDE, SOLID, TOXIC MERCURY BASED 4 PESTICIDE, SOLID, TOXIC COPPER BASED ACRIDINE SODIUM FLUOROSILICATE (MONO) NITROTOLUIDINES Name/Description TETRABROMIDE CARBON N.O.S. BERYLLIUM COMPOUND, SOLID, TOXIC, N.O.S. DISINFECTANT, ORGANOPHOSPHO
2588 3349 1564 2237 1557 2233 2512 2505 2473 2446 1588 2659 2655 2759 2757 2777 1579 2775 2713 2674 2660 UN# 2516 1566 1601 2783 ST/SG/AC.10/C.3/2002/33 page 27 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 Proposed Proposed UN T T1 T1 T1 T1 T1
SR
III III III III III III III III III III III III III III III III III III III III III PG III III III III III
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 Class 6.1 6.1 6.1 6.1 6.1
TOXIC
S.
) -
, p -
)
, m - -
, p - , m
- IAMINE
UINONE DIAMINODIPHENYLMETHANE TOLUYLENED - - ETHYLBENZYLTOLUIDINES, SOLID - NITROBROMOBENZENES, SOLID N SOLID, COUMARIN DERIVATIVE PESTICIDE, TOXIC, N.O.S., solid ORGANOPHOSPHORUS COMPOUND, N.O.S., solid ORGANOARSENIC COMPOUND, METAL CARBONYLS, N.O.S., solid CHLOROTOLUIDINES, solid 4,4' HYDROQ HEXACHLOROBENZENE NITROANISOLES, SOLID SODIUM FLUORIDE 2,4 POTASSIUM FLUORIDE ACRYLAMIDE CHLOROBENZYL CHLORIDES NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. PREPARATION, SOLID, SOLID, N.O.S. or NICOTINE NICOTINE COMPOUND, SOLID CHLORONITROTOLUENES, PESTICIDE, SOLID, TOXIC ORGANOCHLORINE LEAD ACETATE (o NITROPHENOLS (o PHENYLENEDIAMINES Name/Description N.O.S. COMPOUND, PHENYLMERCURIC SOLID, N.O. MERCURY COMPOUND, SOLID CHLOROPHENOLS, BARIUM OXIDE
2732 2753 3027 3278 3280 3281 2239 2651 2662 2729 2730 1690 1709 1812 2074 2235 1655 2433 2761 1616 1663 1673 UN# 2026 2025 2020 1884 ST/SG/AC.10/C.3/2002/33 page 28 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX TPXX
Code -
T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T6 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T1 T1 T1 T1 T6
5.1 6.1 4.3 4.1 4.2 SR
I I I I I I I I I I I I I II II II II II II PG III III III III I
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 Class 6.1 6.1 6.1 6.1 8
omologues) olid
C12 h -
N.O.S.
REACTIVE, -
HEATING, N.O.S. -
N.O.S.
LID, OXIDIZING, N.O.S.
LITHIUM HYDROXIDE MONOHYDRATE CAESIUM HYDROXIDE PHOSPHORUS PENTABROMIDE N.O.S. CORROSIVE SOLID, ACIDIC, ORGANIC, TITANIUM TRICHLORIDE MIXTURE CORROSIVE SOLID, FLAMMABLE, N.O.S. CORROSIVE SOLID, FLAMMABLE, CORROSIVE SOLID, SELF N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, (including C2 ALKYLPHENOLS, SOLID, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, DYE, SOLID, CORROSIVE, N.O.S. N.O.S. CORROSIVE SO N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. AMINES, SOLID, CORROSIVE, CORROSIVE SOLID, TOXIC, N.O.S. SELENIC ACID CORROSIVE SOLID, WATER CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. CORROSIVE SOLID, CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. CORROSIVE SOLID, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, DYE, SOLID, CORROSIVE, N.O.S. BASIC, ORGANIC, N.O.S. CORROSIVE SOLID, Name/Description N.O.S., s TOXIC, COMPOUND, ORGANOMETALLIC N.O.S. SELENIUM COMPOUND, N.O.S. TELLURIUM COMPOUND, N.O.S. VANADIUM COMPOUND,
2680 2682 2691 3261 2869 2921 3095 3262 2430 3147 3084 3259 2923 1905 3096 3260 1759 3261 3147 3263 UN# 3282 3283 3284 3285 ST/SG/AC.10/C.3/2002/33 page 29 Annex 2
PXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX T Proposed TP Note(s) TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 T3 Proposed Proposed UN T T3 T3 T3
6.1 5.1 4.3 4.2 4.1 SR
II II II II II II II II II II II II II II II II II II II II II II PG II II II
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 Class 8 8 8
allization
S.
REACTIVE, N.O.S.
-
HEATING, N.O.S. -
HLOROACETIC ACID HLOROACETIC UMINIUM BROMIDE, ANHYDROUS CYANURIC CHLORIDE AMMONIUM HYDROGEN SULPHATE SODIUM MONOXIDE CORROSIVE SOLID, N.O.S. POTASSIUM HYDROGEN SULPHATE CORROSIVE SOLID, OXIDIZING, N.O. CORROSIVE SOLID, OXIDIZING, CORROSIVE SOLID, WATER CORROSIVE SOLID, SELF N.O.S. CORROSIVE SOLID, FLAMMABLE, PHOSPHORUS PENTACHLORIDE AL LEAD SULPHATE with more than 3% free acid LEAD SULPHATE with more than with not less than 30% water of cryst POTASSIUM SULPHIDE, HYDRATED N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. AMINES, SOLID, CORROSIVE, DIPHENYLMETHYL BROMIDE CORROSIVE SOLID, TOXIC, N.O.S. CHROMIC FLUORIDE, SOLID CHROMIC FLUORIDE, BASIC, INORGANIC, N.O.S. CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. CORROSIVE SOLID, TRIC N.O.S. HYDROGENDIFLUORIDES, POTASSIUM MONOXIDE Name/Description with more ACIDS, SOLID SOLID or ARYLSULPHONIC ACIDS, ALKYLSULPHONIC acid than 5% free sulphuric RUBIDIUM HYDROXIDE BASIC, ORGANIC, N.O.S. CORROSIVE SOLID,
2670 2506 1825 1759 2509 3084 3096 3095 2921 1806 1725 1794 1847 3259 1770 2923 1756 3262 3260 1839 1740 2033 UN# 2583 2678 3263 ST/SG/AC.10/C.3/2002/33 page 30 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX TPXX
Code -
T3 T3 T3 T3 T3 T3 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 Proposed Proposed UN T T3 T3 T3 T3
6.1 SR
II II II II II II III III III III III III III III III III III III III III III PG II II II II
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 Class 8 8 8 8
C12 homologues)
-
m hydroxide
PHORUS OXYBROMIDE .S. AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. AMINES, SOLID, CORROSIVE, CORROSIVE SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, DYE, SOLID, CORROSIVE, N.O.S. N.O PHOSPHORUS TRIOXIDE or PHENOLATES, SOLID CHLOROPHENOLATES, SOLID CORROSIVE SOLID, N.O.S. HYDROGENDIFLUORIDES, N.O.S. N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, TITANIUM TRICHLORIDE MIXTURE sodiu SODA LIME with more than 4% MOLYBDENUM PENTACHLORIDE N.O.S. CORROSIVE SOLID, BASIC, ORGANIC, PHOSPHORIC ACID, SOLID DISODIUM TRIOXOSILICATE FERRIC CHLORIDE, ANHYDROUS PHOSPHORUS PENTOXIDE PHOSPHORUS PHOS ACID, SOLID NITROSYLSULPHURIC SOLID, N.O.S. (including C2 ALKYLPHENOLS, SODIUM HYDROGENDIFLUORIDE CORROSIVE LIQUID, N.O.S. SOLIDS CONTAINING Name/Description SOLID HYDROXIDE, POTASSIUM SOLID SODIUM HYDROXIDE, SOLID AMMONIUM HYDROGENDIFLUORIDE, ANHYDROUS ALUMINIUM CHLORIDE,
3259 2923 3147 2578 2905 1759 1740 3262 2869 1907 2508 3263 1805 3253 1773 1807 1939 2308 2430 2439 3244 UN# 1813 1823 1727 1726 ST/SG/AC.10/C.3/2002/33 page 31 Annex 2
TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T1 T3 Proposed Proposed UN T T1 T1 T1
SR
III III III III III III III III III III III III III III III III III III III III II PG III III III
8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 Class 8 8 8
D with not more
C12 homologues) -
TONIC ACID CHLOROPROPIONIC ACID, SOLID - PIPERAZINE CRO PHOSPHOROUS ACID N.O.S. AVIATION REGULATED SOLID, or CASTOR POMACE or CASTOR FLAKE CASTOR BEANS or CASTOR MEAL STANNIC CHLORIDE PENTAHYDRATE than 0.05% of maleic anhydride PHTHALIC ANHYDRIDE with more MALEIC ANHYDRIDE HEXAMETHYLENEDIAMINE, SOLID (including C2 ALKYLPHENOLS, SOLID, N.O.S. 2 CALCIUM OXIDE with more than 0.05% of maleic anhydride TETRAHYDROPHTHALIC ANHYDRIDES SULPHAMIC ACID SODIUM ALUMINATE, SOLID GALLIUM HYDROXYLAMINE SULPHATE HYDROXYLAMINE COPPER CHLORIDE ACID, SOLID CHLOROPLATINIC ZIRCONIUM TETRACHLORIDE VANADIUM TRICHLORIDE ANHYDROUS ZINC CHLORIDE, Name/Description N.O.S. INORGANIC, SOLID, ACIDIC, CORROSIVE ACIDS, SOLI ACIDS, SOLID or ARYLSULPHONIC ALKYLSULPHONIC ACIDIC, ORGANIC, N.O.S. CORROSIVE SOLID, than 5% free sulphuric acid than 5% free sulphuric
215
2579 2823 2834 3335 2969 2440 2214 2 2280 2430 2511 1910 2698 2967 2812 2803 2865 2802 2507 2503 2475 2331 UN# 3260 2585 3261 ST/SG/AC.10/C.3/2002/33 page 32 Annex 2
TPXX TPXX TPXX TPXX TPXX Proposed TP Note(s) TPXX TPXX TPXX
Code -
T1 T1 T1 T1 T1 Proposed Proposed UN T T3 T3 T1
SR
III III III III III PG II II III
9 9 9 9 9 Class 9 9 9
ite, mysorite)
FISH MEAL (FISH SCRAP), STABILIZED FISH MEAL (FISH (ZINC HYDROSULPHITE) ZINC DITHIONITE AMMONIA ACETALDEHYDE SOLID, N.O.S. HAZARDOUS SUBSTANCE, ENVIRONMENTALLY flammable vapour EXPANDABLE, evolving POLYMERIC BEADS, Name/Description (amos ASBESTOS or BROWN (crocidolite) BLUE ASBESTOS TERPHENYLS, BIPHENYLS, SOLID or POLYHALOGENATED POLYHALOGENATED SOLID tremolite) (chrysotile, actinolite, anthophyllite, WHITE ASBESTOS
2216 1931 1841 3077 2211 UN# 2212 3152 2590 ST/SG/AC.10/C.3/2002/33 page 33 Annex 3
TP TP7, TPXX TPXX TPXX TPXX TPXX TPXX TP7, TPXX TP7, TPXX
PROPOSED TI
T6 T3 T3 T3 T3 T3 T6 T6
TP
TP3 TP7 TP1 TP1 TP1 TP2 TP2 TP3 TP7 TP3 TP7 EXISTING
TI T9 T4 T4 T4 T7 T7 T9 T9
Risk -
Sub
6.1 6.1 6.1 6.1 8
PG
I II II II II II I I Annex 3
Class 4.3 5.1 5.1 5.1 8 6.1 4.3 4.3
Name
POTASSIUM BARIUM CHLORATE BARIUM PERCHLORATE LEAD PERCHLORATE POTASSIUM HYDROGENDIFLUORIDE CRESOLS, SOLID POTASSIUM SODIUM ALLOYS POTASSIUM SODIUM SODIUM
2257 1445 1447 1470 1811 2076 1422 1428 UN# Currently assigned tank provisions that would need to be changed in the Model Regulations based on the rationalized approach based on the rationalized Regulations changed in the Model need to be provisions that would assigned tank Currently
ST/SG/AC.10/C.3/2002/33 page 34 Annex 4
Annex 4 - Solid substances proposed for transport in tanks that were addressed by comments from the Working Group as requiring further consideration
UN# PROPER SHIPPING NAME PG Class SR Proposed UN T-Code UN1374 Fish meal, unstablized [or] Fish scrap, unstabilized II 4.2 T3, TPXX UN2008 Zirconium powder, dry II 4.2 T3, TPXX UN2545 Hafnium powder, dry II 4.2 T3, TPXX UN2546 Titanium powder, dry II 4.2 T3, TPXX UN2008 Zirconium powder, dry III 4.2 T1, TPXX UN2545 Hafnium powder, dry III 4.2 T1, TPXX UN2546 Titanium powder, dry III 4.2 T1, TPXX UN2881 Metal catalyst, dry III 4.2 T1, TPXX UN1389 Alkali metal amalgam, solid I 4.3 T6, TP7, TPXX UN1391 Alkali metal dispersions, [or] Alkaline earth metal I 4.3 T6, TP7, TPXX dispersions UN1392 Alkaline earth metal amalgams I 4.3 T6, TP7, TPXX UN1402 Calcium carbide I 4.3 T6, TP7, TPXX UN1404 Calcium hydride I 4.3 T6, TP7, TPXX UN1407 Cesium [or] Caesium I 4.3 T6, TP7, TPXX UN1409 Metal hydrides, water reactive, n.o.s. I 4.3 T6, TP7, TPXX UN1410 Lithium aluminum hydride I 4.3 T6, TP7, TPXX UN1413 Lithium borohydride I 4.3 T6, TP7, TPXX UN1414 Lithium hydride I 4.3 T6, TP7, TPXX UN1415 Lithium I 4.3 T6, TP7, TPXX UN1420 Potassium, metal alloys I 4.3 T6, TP7, TPXX UN1422 Potassium sodium alloys I 4.3 T6, TP7, TPXX UN1423 Rubidium I 4.3 T6, TP7, TPXX UN1426 Sodium borohydride I 4.3 T6, TP7, TPXX UN1427 Sodium hydride I 4.3 T6, TP7, TPXX UN1428 Sodium I 4.3 T6, TP7, TPXX UN1870 Potassium borohydride I 4.3 T6, TP7, TPXX UN2010 Magnesium hydride I 4.3 T6, TP7, TPXX UN2257 Potassium I 4.3 T6, TP7, TPXX
ST/SG/AC.10/C.3/2002/33 page 35 Annex 4
UN# PROPER SHIPPING NAME PG Class SR Proposed UN T-Code UN2463 Aluminum hydride I 4.3 T6, TP7, TPXX UN2806 Lithium nitride I 4.3 T6, TP7, TPXX UN2813 Water-reactive solid, n.o.s. I 4.3 T6, TP7, TPXX UN3208 Metallic substance, water-reactive, n.o.s. I 4.3 T6, TP7, TPXX
UN3132 Water-reactive solid, flammable, n.o.s. I 4.3 4.1 T6, TP7, TPXX
UN1418 Magnesium, powder [or] Magnesium alloys, powder I 4.3 4.2 T6, TP7, TPXX UN1436 Zinc powder [or] Zinc dust I 4.3 4.2 T6, TP7, TPXX UN3135 Water-reactive solid, self-heating, n.o.s. I 4.3 4.2 T6, TP7, TPXX
UN3209 Metallic substance, water-reactive, self-heating, n.o.s. I 4.3 4.2 T6, TP7, TPXX
UN3131 Water-reactive solid, corrosive, n.o.s. I 4.3 8 T6, TP7, TPXX
UN1402 Calcium carbide II 4.3 T3, TPXX UN1409 Metal hydrides, water reactive, n.o.s. II 4.3 T3, TPXX UN2813 Water-reactive solid, n.o.s. II 4.3 T3, TPXX UN3208 Metallic substance, water-reactive, n.o.s. II 4.3 T3, TPXX
UN3132 Water-reactive solid, flammable, n.o.s. II 4.3 4.1 T3, TPXX
UN1418 Magnesium, powder [or] Magnesium alloys, powder II 4.3 4.2 T3, TPXX UN1436 Zinc powder [or] Zinc dust II 4.3 4.2 T3, TPXX UN3135 Water-reactive solid, self-heating, n.o.s. II 4.3 4.2 T3, TPXX
UN3209 Metallic substance, water-reactive, self-heating, n.o.s. II 4.3 4.2 T3, TPXX
UN3134 Water-reactive solid, toxic, n.o.s. II 4.3 6.1 T3, TPXX UN3131 Water-reactive solid, corrosive, n.o.s. II 4.3 8 T3, TPXX
UN2813 Water-reactive solid, n.o.s. III 4.3 T1, TPXX UN3208 Metallic substance, water-reactive, n.o.s. III 4.3 T1, TPXX
UN3132 Water-reactive solid, flammable, n.o.s. III 4.3 4.1 T1, TPXX
UN1418 Magnesium, powder [or] Magnesium alloys, powder III 4.3 4.2 T1, TPXX UN1436 Zinc powder [or] Zinc dust III 4.3 4.2 T1, TPXX
ST/SG/AC.10/C.3/2002/33 page 36 Annex 4
UN# PROPER SHIPPING NAME PG Class SR Proposed UN T-Code UN3135 Water-reactive solid, self-heating, n.o.s. III 4.3 4.2 T1, TPXX
UN3209 Metallic substance, water-reactive, self-heating, n.o.s. III 4.3 4.2 T1, TPXX
UN3134 Water-reactive solid, toxic, n.o.s. III 4.3 6.1 T1, TPXX UN3131 Water-reactive solid, corrosive, n.o.s. III 4.3 8 T1, TPXX
UN1442 Ammonium perchlorate II 5.1 T3, TPXX UN1479 Oxidizing solid, n.o.s. II 5.1 T3, TPXX UN3087 Oxidizing solid, toxic, n.o.s. II 5.1 6.1 T3, TPXX UN3085 Oxidizing solid, corrosive, n.o.s. II 5.1 8 T3, TPXX UN1479 Oxidizing solid, n.o.s. III 5.1 T1, TPXX UN3087 Oxidizing solid, toxic, n.o.s. III 5.1 6.1 T1, TPXX UN3085 Oxidizing solid, corrosive, n.o.s. III 5.1 8 T1, TPXX UN2930 Toxic solids, flammable, organic, n.o.s. I 6.1 4.1 T6, TPXX
UN1611 Hexaethyl tetraphosphate, [solid] II 6.1 T3, TPXX UN2930 Toxic solids, flammable, organic, n.o.s. II 6.1 4.1 T3, TPXX
UN3095 Corrosive solids, self-heating, n.o.s. I 8 4.2 T6, TPXX
1811 Potassium hydrogendifluoride T3 8 II 6.1 UN1847 Potassium sulfide, hydrated [with not less than 30 percent II 8 T3, TPXX water of crystallization]
UN3095 Corrosive solids, self-heating, n.o.s. II 8 4.2 T3, TPXX
UN1910 Calcium oxide III 8 T1, TPXX UN2812 Sodium aluminate, solid III 8 T1, TPXX UN2216 Fish meal, stabilized [or] Fish scrap, stabilized III 9 T1, TPXX
______