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Iranian Fuel Cell Seminar Full Papers 6th Iranian Fuel Cell Seminar Shahid Rajaee Teacher Training University Faculty of Science Tehran – Iran March 12&13 , 2013 th 6 Iranian Fuel Cell Seminar Held in Shahid Rajaee Teacher Training University, Tehran, Islamic Republic of Iran, 12-13 March 2013. Conference Chairman: Dr Rasol Abdullah Mirzaie © Copyright 2013, Electrochemical Society of Iran Faculty of Science, Department of Chemistry, 3rd floor, Tarbiat Modares University, Tehran, Islamic Republic of Iran P.O. Box: 14115-111 Phone: +98-21-82884713 Fax: +98-21-82884713 Email: [email protected] Website: www.iranecs.ir Full papers proceedings of 6th Iranian Fuel Cell Seminar, 12-13 March 2013, Electrochemical Society of Iran. Event jointly organized by Development energy resources organization. All rights reserved. No part of this may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, without the prior written permission of the Electrochemical Society of Iran. Electrochemical Society of Iran is not responsible for the use which might be made of the information contained in this book. I Organizers II Welcome to 6th Iranian fuel cell seminar Dear colleague, On behalf of all members of scientific and organizing committees, it is my great honor to welcome you to the 6th Iranian fuel cell seminar. This seminar is hosted by the Electrochemical Society of Iran, Development energy resources organization and Shahid Rajaee Teacher Training University from 12 to 13 March 2013. The aim of this seminar is to get together and present the latest scientific findings and to share information in the field of fuel cell systems for professionals within academia, research and industry. Fuel cell is the best way for clean energy production in Hydrogen economy. It can help for producing electricity with low noise and good efficiency. As fuel cells generate electricity through a chemical reaction, rather than combustion, they do not produce harmful emissions. Currently, technologists are developing and adapting fuel cell technology for practical use in exhaust-free automobiles and in electricity-generating plants. Participants at this seminar celebrate 62 paper presentations, posters as well as workshop sessions. Professor Hossein Gharibi as an invited speaker provided insightful ideas and questions for many seminar participants by tackling issues in the innovation in fuel cell systems especially about materials of MEA. In this seminar, energy education workshop for children is provided interactive environment in order to learning energy concepts. This seminar would not be possible without your participation and support. We would like to thank you for your participation and also all those involved in the organization of this conference. We hope that you have had a fruitful and memorable seminar and a delightful stay in Tehran at Shahid Rajaee Teacher Training University. Dr Rasol Abdullah Mirzaie Hojat Aliloo Scientific Chairman Executive chairman III Organizing Committee Director of Electrochemical Society of Iran : Prof. JahanBakhshRaoof University of Mazandaran Scientific Chairman: Dr. Rasol Abdullah Mirzaie Shahid Rajaee Teacher Training University Fuel cell Research Laboratory Executive Chairman: Hojat Aliloo Development of energy resources organization Prof. Majid jafarian K. N. Toosi University of technology Prof.Hossein Gharibi Tarbiat Modares University IV Scientific Committee: Prof. Majid Jafarian , K. N. Toosi University of technology Prof. Hossein Gharibi , Tarbiat Modares University Prof. Jahan Bakhsh Raoof , University of Mazandaran Prof. Reza ojani , University of Mazandaran Dr Niloufar Bahrami Panah , Payame Noor University Dr Soosan Rowshanzamir , Iran University of science of Technology V Dr Mohsen Shakeri , Noshirvani University of Technology Dr Seyed Majid Hashemianzadeh, Iran University of science and technology Dr Mohammad J. Kermani , Amirkabir University of Technology Dr Amir Maghsoudipour , Materials and Energy Research Centre Dr Mohammad Zhiani , Isfahan University of Technology Dr Mehdi Kheirmand , Yasouj University Dr Mohammad Safi Rahmanifar , Shahed university Dr Mehran Javanbakht, Amirkabir University of Technology VI Dr Saeed Olyaee , Shahid Rajaee Teacher Training University Dr Mahmoud Ziarati , Malek Ashtar University of Technology Dr Soheila Javadian Farzaneh , Tarbiat Modares University Dr Mostafa Dehghani Mobarake , Research Institute of Petroleum Industry (RIPI) Dr Javad Beheshtian , Shahid Rajaee Teacher Training university Dr Pejman Kazempoor , Tarbiat Modares University Dr Rasol Abdullah Mirzaie , Shahid Rajaee Teacher Training university Dr Ahmad Nozad Goli-Kand, Material School, NSTRI VII Executive Committee: Hojat aliloo, Executive Secretary Arash Abdullah Mirzaie , The seminar secretariat Aida khajeh , Staff of Electrochemical Society of Iran Dr. Hamid Mesgarani , Deputy of Shahid Rajaee Teacher Training University Dr. Ayoub Esmailpour , Head of Faculty of Basic science, Shahid Rajaee Teacher Training University Dr. Mehdi Saadat , Deputy of Faculty of Basic science, Shahid Rajaee Teacher Training University Dr. Ali Zaeembashi tajAbadi of Faculty of Basic science, Shahid Rajaee Teacher Training University Shahla manouchehrian Zohreh babaei Fatemeh shakeri Mojtaba safari Ali Zali Mohammad Reza Jafarpanah Mahmood Darvishi Arezo Vaez Arezo Asfa Behjat Ghasemi Shirin Shakeri Post Graduate students Yekta Majidifard Ilqar Abdollahi Neda Zerafat Doost Farmand Farzin Ehsan Mahnani Samane Sajediniya Kumarse Shamkhali Fatemeh Hamedi Nasrin Farshadi Elena Yashmi Behnam Moeini Maryam Azamiyan Narges Mohammadkhani VIII Key Speaker Professor Hossein Gharibi “How is our approach for materials of MEA” Department of Chemistry Faculty of Science Tarbiat Modares University Tehran, Iran Biography Gust Editor of International Journal of Hydrogen Energy (International Association of Hydrogen Energy, USA 2009 up to now) Chairman of Electrochemical society of Iran 2004 –Jan 2012 Visiting Professor, Dept of Material Sci. & Eng. , University of UTAH 2012, USA Chairman of Department of Chemistry 4 years Director of IRANDOC, www. Irandoc.ac.ir (1992-2008) Organizer of too many scientific conferences B.Sc. 1985 from Shiraz University (IRAN) M.Sc .1987 from Salford University (UK) PhD 1990 from Salford University (UK) IX Contents Page Modeling Local Structure and Dynamics of Aromatic Sulfonated poly(2,6- 1 Dimethyl-1,4-Phenylene Oxide) Fuel Cell Membranes Mathematical modeling of plate solid oxide fuel cell 9 Electrosynthesis of Pt-Co alloy catalyst on the carbon-ceramic electrode for 25 methanol oxidation Comparison conductivity between Yb and Dy co-doped CeO2-Gd2O3 systems for 34 IT-SOFCs Electricity Generation and Sulfide Removal by dual chamber Microbial fuel cell 46 simultaneously Economical comparison of power generation in microbial fuel cell by Nafion 117 53 and SPEEK as proton exchange membranes A technical assessment of the CO2 capture modeling for GT/SOFC/CHP hybrid 67 cycles Comparative Study of Platinum and Non-Platinum Cathode Nanocatalysts in Direct 77 Borohydride Fuel Cell Electrochemical oxidation of hydrazine on the surface of silver particles/polymer 85 modifed carbon paste electrode in alkaline media Experimental Study on the effect of Bipolar Plates Substance on the Performance 91 of Poroton Exchange Membrane Fuel Cells Membraneless Mixed Reactant Direct Methanol Fuel Cell 98 Manufacturing of yttria stabilized Zirconia based solid electrolyte thin films by 105 Combined tape casting/Impregnation method An analytic and numerical modeling of a membrane humidifier for PEM fuel cell 111 Synthesis of nanocatalysts of graphene oxide/TiO2/Pt and study of its 120 characterization Polybenzimidazole/MnTiO3 nanocomposite membranes for polymer electrolyte 127 membrane fuel cells Corrosion Behavior and Interfacial Contact Resistance of TiN Coated Type 316L 137 Stainless Steel as Bipolar Plate for Proton Exchange Membrane Fuel Cell Electrooxidation of Sodium Borohydride on Porous Nano Structured Ni/PtNi 151 electrode in basic media Investigation the Stability and Methanol Oxidation Activity of Alloy Nanoparticles 160 Electrocatalytic oxidation of methanol on semiconducting polymer nanocomposite 167 in alkaline media Electrophoretic deposition of NiFe2O4 spinel on SOFC interconnect 175 Hybrid Genetic Algorithm-Neural Network for Membrane RI Measurement Error 181 Modeling in PEM Fuel Cells Study of ORR kinetic on Pt/C at the presence of super paramagnetic of Fe3O4 192 nanoparticles in PEMFC Modification of Nafion Membranes with Different Clays for Direct Methanol Fuel 200 Cell Applications Electrocatalytic activity of graphene- carbon nanotube supported Pt3Co as an 210 electrocatalyst for oxygen reduction reaction in PEM fuel cell gas diffusion electrodes Study of adsorption of oxygen molecule on the structures of Ptn/Graphene as an 215 electrode in the PEM Fuel Cell Parametric study and optimization of the cathode catalyst layer in PEM fuel cells 220 Characterization and preparation of single wall nanotubes materials for hydrogen 230 storage Study of synergism effect in platinum – Gold alloy electrocatalyst for glucose 246 oxidation in direct glucose alkaline fuel cell Lactose Electrooxidation on the Nickel Oxide Nanoparticles Electrocatalyst 253 Prepared on the Multi-walled Carbon Nanotubes Modified Electrode Hydrogen Evolution Reaction on Graphene Supported Pt Hollow Nanospheres 263 Designing H4KIDS software for hydrogen energy teaching to children 272 Theoretical Study of Hydrogen Bonding in Blend Membranes Based
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