1 Forming New Substances
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												  Chapter 20 ElectrochemistryChapter 20 Electrochemistry Learning goals and key skills: Identify oxidation, reduction, oxidizing agent, and reducing agent in a chemical equation Complete and balance redox equations using the method of half-reactions. Sketch a voltaic cell and identify its cathode, anode, and the directions in which electrons and ions move. o Calculate standard emfs (cell potentials), E cell, from standard reduction potentials. Use reduction potentials to predict whether a redox reaction is spontaneous. o o Relate E cell to DG and equilibrium constants. Calculate emf under nonstandard conditions. Identify the components of common batteries. Describe the construction of a lithium-ion battery and explain how it works. Describe the construction of a fuel cell and explain how it generates electrical energy. Explain how corrosion occurs and how it is prevented by cathodic protection. Describe the reactions in electrolytic cells. Relate the amounts of products and reactants in redox reactions to electrical charge. Electrochemistry Electrochemistry is the study of the relationships between electricity and chemical reactions. • It includes the study of both spontaneous and nonspontaneous processes. 1 Redox reactions: assigning oxidation numbers Oxidation numbers help keep track of what species loses electrons and what species gains them. • An element is oxidized when the oxidation number increases • An element is reduced when the oxidation number decreases • an oxidizing agent causes another element to be oxidized • a reducing agent causes another element to be reduced. Assigning oxidation numbers (sect. 4.4) 1. Elemental form, each atom has ox. # = 0. Zn O2 O3 I2 S8 P4 2. Simple ions, = charge on ion. -1 for Cl-, +2 for Mg2+ 3.
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												  Constraint Closure Drove Major Transitions in the Origins of Lifeentropy Article Constraint Closure Drove Major Transitions in the Origins of Life Niles E. Lehman 1 and Stuart. A. Kauffman 2,* 1 Edac Research, 1879 Camino Cruz Blanca, Santa Fe, NM 87505, USA; [email protected] 2 Institute for Systems Biology, Seattle, WA 98109, USA * Correspondence: [email protected] Abstract: Life is an epiphenomenon for which origins are of tremendous interest to explain. We provide a framework for doing so based on the thermodynamic concept of work cycles. These cycles can create their own closure events, and thereby provide a mechanism for engendering novelty. We note that three significant such events led to life as we know it on Earth: (1) the advent of collective autocatalytic sets (CASs) of small molecules; (2) the advent of CASs of reproducing informational polymers; and (3) the advent of CASs of polymerase replicases. Each step could occur only when the boundary conditions of the system fostered constraints that fundamentally changed the phase space. With the realization that these successive events are required for innovative forms of life, we may now be able to focus more clearly on the question of life’s abundance in the universe. Keywords: origins of life; constraint closure; RNA world; novelty; autocatalytic sets 1. Introduction The plausibility of life in the universe is a hotly debated topic. As of today, life is only known to exist on Earth. Thus, it may have been a singular event, an infrequent event, or a common event, albeit one that has thus far evaded our detection outside our own planet. Herein, we will not attempt to argue for any particular frequency of life.
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												  Basic Concepts of Chemical BondingBasic Concepts of Chemical Bonding Cover 8.1 to 8.7 EXCEPT 1. Omit Energetics of Ionic Bond Formation Omit Born-Haber Cycle 2. Omit Dipole Moments ELEMENTS & COMPOUNDS • Why do elements react to form compounds ? • What are the forces that hold atoms together in molecules ? and ions in ionic compounds ? Electron configuration predict reactivity Element Electron configurations Mg (12e) 1S 2 2S 2 2P 6 3S 2 Reactive Mg 2+ (10e) [Ne] Stable Cl(17e) 1S 2 2S 2 2P 6 3S 2 3P 5 Reactive Cl - (18e) [Ar] Stable CHEMICAL BONDSBONDS attractive force holding atoms together Single Bond : involves an electron pair e.g. H 2 Double Bond : involves two electron pairs e.g. O 2 Triple Bond : involves three electron pairs e.g. N 2 TYPES OF CHEMICAL BONDSBONDS Ionic Polar Covalent Two Extremes Covalent The Two Extremes IONIC BOND results from the transfer of electrons from a metal to a nonmetal. COVALENT BOND results from the sharing of electrons between the atoms. Usually found between nonmetals. The POLAR COVALENT bond is In-between • the IONIC BOND [ transfer of electrons ] and • the COVALENT BOND [ shared electrons] The pair of electrons in a polar covalent bond are not shared equally . DISCRIPTION OF ELECTRONS 1. How Many Electrons ? 2. Electron Configuration 3. Orbital Diagram 4. Quantum Numbers 5. LEWISLEWIS SYMBOLSSYMBOLS LEWISLEWIS SYMBOLSSYMBOLS 1. Electrons are represented as DOTS 2. Only VALENCE electrons are used Atomic Hydrogen is H • Atomic Lithium is Li • Atomic Sodium is Na • All of Group 1 has only one dot The Octet Rule Atoms gain, lose, or share electrons until they are surrounded by 8 valence electrons (s2 p6 ) All noble gases [EXCEPT HE] have s2 p6 configuration.
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												  Ocw-5.112-Lec24 the Following Content Is Provided by MIT Opencourseware Under a Creative Commons LicenseMITOCW | ocw-5.112-lec24 The following content is provided by MIT OpenCourseWare under a Creative Commons license. Additional information about our license and MIT OpenCourseWare in general is available at ocw.mit.edu. Today I would like to start by discussing a timeline. And you will see in a moment what this timeline has to do with. It is obviously only a partial timeline. But let's start here in 1916, as we have done this semester, by talking about the Lewis theory of electronic structure. And his electron pair theory is something we are going to come back to a couple of times during lecture today. Let's move on to 1954. 1954 was an important year in electronic structure theory, because in that year there was awarded, to Linus Pauling, the Nobel Prize in chemistry. Let me write down Pauling here. And if you are interested in knowing something about what Pauling was awarded the Nobel Prize in chemistry for, I will show you over here on the side boards. What you are going to see here, if you read this citation for Linus Carl Pauling in 1954 for the Nobel Prize in chemistry, his prize was awarded principally for his contributions to our understanding of the nature of the chemical bond. If you think back to the elegant title of the paper by Lewis that we started out our discussion of acid-base theory with, it was a paper entitled "The Atom and the Molecule." And now we have gotten to Pauling, in 1954, who is being awarded a Nobel Prize in chemistry for the nature of the chemical bond.
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												  Introduction to ChemistryIntroduction to Chemistry Author: Tracy Poulsen Digital Proofer Supported by CK-12 Foundation CK-12 Foundation is a non-profit organization with a mission to reduce the cost of textbook Introduction to Chem... materials for the K-12 market both in the U.S. and worldwide. Using an open-content, web-based Authored by Tracy Poulsen collaborative model termed the “FlexBook,” CK-12 intends to pioneer the generation and 8.5" x 11.0" (21.59 x 27.94 cm) distribution of high-quality educational content that will serve both as core text as well as provide Black & White on White paper an adaptive environment for learning. 250 pages ISBN-13: 9781478298601 Copyright © 2010, CK-12 Foundation, www.ck12.org ISBN-10: 147829860X Except as otherwise noted, all CK-12 Content (including CK-12 Curriculum Material) is made Please carefully review your Digital Proof download for formatting, available to Users in accordance with the Creative Commons Attribution/Non-Commercial/Share grammar, and design issues that may need to be corrected. Alike 3.0 Unported (CC-by-NC-SA) License (http://creativecommons.org/licenses/by-nc- sa/3.0/), as amended and updated by Creative Commons from time to time (the “CC License”), We recommend that you review your book three times, with each time focusing on a different aspect. which is incorporated herein by this reference. Specific details can be found at http://about.ck12.org/terms. Check the format, including headers, footers, page 1 numbers, spacing, table of contents, and index. 2 Review any images or graphics and captions if applicable.
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												  10: Alkenes and Alkynes. Electrophilic and Concerted Addition Reactions(2/94)(8,9/96)(12/03)(1,2/04) Neuman Chapter 10 10: Alkenes and Alkynes. Electrophilic and Concerted Addition Reactions Addition Reactions Electrophilic Addition of H-X or X2 to Alkenes Addition of H-X and X2 to Alkynes Alkenes to Alcohols by Electrophilic Addition Alkenes to Alcohols by Hydroboration Addition of H2 to Alkenes and Alkynes Preview (To be added) 10.1 Addition Reactions We learned about elimination reactions that form C=C and Cº C bonds in Chapter 9. In this chapter we learn about reactions in which reagents add to these multiple bonds. General Considerations (10.1A) We show a general equation for an addition reaction with an alkene in Figure 10.01. Figure 10.01 (see Figure folder for complete figure) A¾ B A B | | C=C ® C¾ C This equation is the reverse of the general equation for an elimination reaction that we showed at the beginning of Chapter 9. This general equation does not show a mechanism for the addition process. There are a number of different types of mechanisms for addition reactions, but we can group them into the four broad categories of (1) electrophilic addition, (2) nucleophilic addition, (3) free radical addition, and (4) concerted addition. Electrophilic and nucleophilic addition reactions involve intermediate ions so they are ionic addition reactions. In contrast, free radical additions, and 1 (2/94)(8,9/96)(12/03)(1,2/04) Neuman Chapter 10 concerted addition reactions, are non-ionic addition reactions because they do not involve the formation of intermediate ions. Ionic Addition Reactions (10.1B) We compare general features of nucleophilic and electrophilic addition reactions here.
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												  Battle of the Acids Weak Acids and Bases SCIENTIFICBattle of the Acids Weak Acids and Bases SCIENTIFIC Introduction Not all acids are created equal. This demonstration compares the “frothing and foaming” activity of different acids with calcium carbonate and examines their behavior in the presence of their conjugate bases to distinguish strong versus weak acids. The use of a “rainbow acid” universal indicator produces a rainbow spectrum of color changes as the mixtures react. Concepts • Strong acid • Weak acid • Conjugate base • pH Materials (for each demonstration) Acetic acid, CH3COOH, 1 M, 400 mL Water, distilled or deionized Calcium carbonate, CaCO3, 40 g Demonstration tray, large Hydrochloric acid, HCl, 1 M, 400 mL Graduated cylinder, 250-mL “Rainbow acid” universal indicator, 5 mL Hydrometer cylinders, 600-mL, 4 (includes accompanying color chart) Pipet, Beral-type Sodium acetate, NaCH3CO2, 16 g Weighing dishes or small beakers, 6 Sodium chloride, NaCl, 12 g Safety Precautions Hydrochloric acid and acetic acid solutions are toxic and corrosive. Avoid contact with skin and eyes. “Rainbow-acid” universal indicator solution is an alcohol-based solution and is flammable. Avoid contact with flames or other ignition sources. Wear chemical splash goggles, chemical-resistant gloves, and a chemical-resistant apron. Please review current Material Safety Data Sheets for additional safety, handling, and disposal information. Preparation To save time in the presentation, pre-measure the amounts of solids needed for the demonstration. Weigh out 12 g of sodium chloride, 16 g of sodium acetate, and 4 × 10-g samples of calcium carbonate in separate, labeled weighing dishes or small beakers. Procedure 1. Obtain 4 large hydrometer cylinders or tall-form beakers and place them on a large demonstration tray.
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												  Stoichiometry of Chemical Reactions 175Chapter 4 Stoichiometry of Chemical Reactions 175 Chapter 4 Stoichiometry of Chemical Reactions Figure 4.1 Many modern rocket fuels are solid mixtures of substances combined in carefully measured amounts and ignited to yield a thrust-generating chemical reaction. (credit: modification of work by NASA) Chapter Outline 4.1 Writing and Balancing Chemical Equations 4.2 Classifying Chemical Reactions 4.3 Reaction Stoichiometry 4.4 Reaction Yields 4.5 Quantitative Chemical Analysis Introduction Solid-fuel rockets are a central feature in the world’s space exploration programs, including the new Space Launch System being developed by the National Aeronautics and Space Administration (NASA) to replace the retired Space Shuttle fleet (Figure 4.1). The engines of these rockets rely on carefully prepared solid mixtures of chemicals combined in precisely measured amounts. Igniting the mixture initiates a vigorous chemical reaction that rapidly generates large amounts of gaseous products. These gases are ejected from the rocket engine through its nozzle, providing the thrust needed to propel heavy payloads into space. Both the nature of this chemical reaction and the relationships between the amounts of the substances being consumed and produced by the reaction are critically important considerations that determine the success of the technology. This chapter will describe how to symbolize chemical reactions using chemical equations, how to classify some common chemical reactions by identifying patterns of reactivity, and how to determine the quantitative relations between the amounts of substances involved in chemical reactions—that is, the reaction stoichiometry. 176 Chapter 4 Stoichiometry of Chemical Reactions 4.1 Writing and Balancing Chemical Equations By the end of this section, you will be able to: • Derive chemical equations from narrative descriptions of chemical reactions.
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												  Organic and Biological ChemistryCHAPTER 23 Organic and Biological Chemistry CONTENTS HO H 23.1 ▶ Organic Molecules and Their C Structures: Alkanes H H C 23.2 ▶ Families of Organic Compounds: HO O O C C Functional Groups 23.3 ▶ Naming Organic Compounds H CC 23.4 ▶ Carbohydrates:HO A Biological Example HO OH of Isomers H 23.5 ▶ Valence Bond TCheory and Orbital OverlapH Pictures H C 23.6 ▶ Lipids:HO A Biological EOxample ofO Cis–Trans IsomerismC C 23.7 ▶ Formal Charge and Resonance in Organic CompoundsH CC 23.8 ▶ Conjugated SystemsHO OH 23.9 ▶ Proteins: A Biological Example of Conjugation 23.10 ▶ Aromatic Compounds and Molecular Ascorbic acid, also known as vitamin C, is an essential nutrient in the human diet Orbital Theory because it is not synthesized in our body. We can eat citrus fruits or take pills that contain vitamin C to maintain health. 23.11 ▶ Nucleic Acids: A Biological Example of Aromaticity ? Which Is Better, Natural or Synthetic? The answer to this question can be found in the INQUIRY ▶▶▶ on page 1021. STUDY GUIDE M23_MCMU3170_07_SE_C23.indd 978 27/11/14 2:11 AM f the ultimate goal of chemistry is to understand the world around us on a molecular level, then a knowledge of biochemistry—the chemistry of living organisms—is a central part Iof that goal. Biochemistry, in turn, is a branch of organic chemistry, a term originally used to mean the study of compounds from living organisms while inorganic chemistry was used for the study of compounds from nonliving sources. Today, however, we know that there are no fundamental differences between organic and inorganic compounds; the same principles apply to both.
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												  1: Organic Molecules and Chemical Bonding(4,5,9,11,12/98)(1,9,10/99) Neuman Chapter 1 1: Organic Molecules and Chemical Bonding Organic Molecules Chemical Bonds Organic Chemistry Bon voyage Preview Organic chemistry describes the structures, properties, preparation, and reactions of a vast array of molecules that we call organic compounds. There are many different types of organic compounds, but all have carbon as their principal constituent atom. These carbon atoms form a carbon skeleton or carbon backbone that has other bonded atoms such as H, N, O, S, and the halogens (F, Cl, Br, and I). We frequently hear the term "organic" in everyday language where it describes or refers to substances that are "natural". This is probably a result of the notion of early scientists that all organic compounds came from living systems and possessed a "vital force". However, chemists learned over 170 years ago that this is not the case. Organic compounds are major components of living systems, but chemists can make many of them in the laboratory from substances that have no direct connection with living systems. Chemically speaking, a pure sample of an organic compound such as Vitamin C prepared in a laboratory is chemically identical to a pure sample of Vitamin C isolated from a natural source such as an orange or other citrus fruit. Your journey through organic chemistry will be challenging because of the large amount of information that you will need to learn and understand. However, we will explore this subject in a systematic manner so that it is not a vast collection of isolated facts.
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												  15-1 SECTION 15 ELECTROCHEMISTRY Electrochemistry: the Branch of Chemistry That Covers the Relative Strengths of Oxidants and R15-1 SECTION 15 ELECTROCHEMISTRY Some systems involving redox reactions can be designed so that the reactants (and products) are partially separated from each other, and the reaction leads to an electric current being produced in an external circuit, and which can be used for many useful purposes. Batteries and their many uses are the obvious examples. Electrical energy can also be used to drive non-spontaneous chemical reactions to produce desired products in processes known as electrolysis. This section introduces the language and concepts of these processes collectively known as electrochemistry. Electrochemistry: The branch of chemistry that covers the relative strengths of oxidants and reductants, the production of electric current from chemical reactions, and the use of electricity to produce chemical change. Electrochemical cell: A system made up of two electrodes in contact with an electrolyte. Electrode: A conductor of electricity, commonly a metal or graphite in contact with an electrolyte in an electrochemical cell. Electrolyte: A medium (phase) which conducts electricity by the movement of ions [e.g. a molten salt] or a substance which dissolves in a solvent to give a conducting solution [e.g. aqueous sodium chloride, NaCl or any other soluble ionic compound]. Electrode reaction: A chemical reaction occurring at an electrode involving gain or loss of electrons. It is called a half-reaction. [e.g. Cu2++ 2e– → Cu; Zn → Zn2+ + 2e– ] (See page 12-4.) Redox couple: The two species of a half- reaction involving oxidation or reduction. (See 2+ – page 12-3.) Represented as oxidised species/reduced species [e.g. Cu /Cu; Cl2/Cl ; Fe3+/Fe2+].
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												  Chemical Bonding and Molecular Structure100 CHEMISTRY UNIT 4 CHEMICAL BONDING AND MOLECULAR STRUCTURE Scientists are constantly discovering new compounds, orderly arranging the facts about them, trying to explain with the existing knowledge, organising to modify the earlier views or After studying this Unit, you will be evolve theories for explaining the newly observed facts. able to • understand KÖssel-Lewis approach to chemical bonding; • explain the octet rule and its Matter is made up of one or different type of elements. limitations, draw Lewis Under normal conditions no other element exists as an structures of simple molecules; independent atom in nature, except noble gases. However, • explain the formation of different a group of atoms is found to exist together as one species types of bonds; having characteristic properties. Such a group of atoms is • describe the VSEPR theory and called a molecule. Obviously there must be some force predict the geometry of simple which holds these constituent atoms together in the molecules; molecules. The attractive force which holds various • explain the valence bond constituents (atoms, ions, etc.) together in different approach for the formation of chemical species is called a chemical bond. Since the covalent bonds; formation of chemical compounds takes place as a result • predict the directional properties of combination of atoms of various elements in different of covalent bonds; ways, it raises many questions. Why do atoms combine? Why are only certain combinations possible? Why do some • explain the different types of hybridisation involving s, p and atoms combine while certain others do not? Why do d orbitals and draw shapes of molecules possess definite shapes? To answer such simple covalent molecules; questions different theories and concepts have been put forward from time to time.