Gas Conversion Factor for 200 Series
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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Cylinder Valve Selection Quick Reference for Valve Abbreviations
SHERWOOD VALVE COMPRESSED GAS PRODUCTS Appendix Cylinder Valve Selection Quick Reference for Valve Abbreviations Use the Sherwood Cylinder Valve Series Abbreviation Chart on this page with the Sherwood Cylinder Valve Selection Charts found on pages 73–80. The Sherwood Cylinder Valve Selection Chart are for reference only and list: • The most commonly used gases • The Compressed Gas Association primary outlet to be used with each gas • The Sherwood valves designated for use with this gas • The Pressure Relief Device styles that are authorized by the DOT for use with these gases PLEASE NOTE: The Sherwood Cylinder Valve Selection Charts are partial lists extracted from the CGA V-1 and S-1.1 pamphlets. They can change without notice as the CGA V-1 and S-1.1 pamphlets are amended. Sherwood will issue periodic changes to the catalog. If there is any discrepancy or question between these lists and the CGA V-1 and S-1.1 pamphlets, the CGA V-1 and S-1.1 pamphlets take precedence. Sherwood Cylinder Valve Series Abbreviation Chart Abbreviation Sherwood Valve Series AVB Small Cylinder Acetylene Wrench-Operated Valves AVBHW Small Cylinder Acetylene Handwheel-Operated Valves AVMC Small Cylinder Acetylene Wrench-Operated Valves AVMCHW Small Cylinder Acetylene Handwheel-Operated Valves AVWB Small Cylinder Acetylene Wrench-Operated Valves — WB Style BV Hi/Lo Valves with Built-in Regulator DF* Alternative Energy Valves GRPV Residual Pressure Valves GV Large Cylinder Acetylene Valves GVT** Vertical Outlet Acetylene Valves KVAB Post Medical Valves KVMB Post Medical Valves NGV Industrial and Chrome-Plated Valves YVB† Vertical Outlet Oxygen Valves 1 * DF Valves can be used with all gases; however, the outlet will always be ⁄4"–18 NPT female. -
Gas Conversion Factor for 300 Series
300GasTable Rec # Gas Symbol GCF Density (g/L) Density (g/L) 25° C / 1 atm 0° C / 1 atm 1 Acetic Acid C2H4F2 0.4155 2.7 2.947 2 Acetic Anhydride C4H6O3 0.258 4.173 4.555 3 Acetone C3H6O 0.3556 2.374 2.591 4 Acetonitryl C2H3N 0.5178 1.678 1.832 5 Acetylene C2H2 0.6255 1.064 1.162 6 Air Air 1.0015 1.185 1.293 7 Allene C3H4 0.4514 1.638 1.787 8 Ammonia NH3 0.7807 0.696 0.76 9 Argon Ar 1.4047 1.633 1.782 10 Arsine AsH3 0.7592 3.186 3.478 11 Benzene C6H6 0.3057 3.193 3.485 12 Boron Trichloride BCl3 0.4421 4.789 5.228 13 Boron Triflouride BF3 0.5431 2.772 3.025 14 Bromine Br2 0.8007 6.532 7.13 15 Bromochlorodifluoromethane CBrClF2 0.3684 6.759 7.378 16 Bromodifluoromethane CHBrF2 0.4644 5.351 5.841 17 Bromotrifluormethane CBrF3 0.3943 6.087 6.644 18 Butane C4H10 0.2622 2.376 2.593 19 Butanol C4H10O 0.2406 3.03 3.307 20 Butene C4H8 0.3056 2.293 2.503 21 Carbon Dioxide CO2 0.7526 1.799 1.964 22 Carbon Disulfide CS2 0.616 3.112 3.397 23 Carbon Monoxide CO 1.0012 1.145 1.25 24 Carbon Tetrachloride CCl4 0.3333 6.287 6.863 25 Carbonyl Sulfide COS 0.668 2.456 2.68 26 Chlorine Cl2 0.8451 2.898 3.163 27 Chlorine Trifluoride ClF3 0.4496 3.779 4.125 28 Chlorobenzene C6H5Cl 0.2614 4.601 5.022 29 Chlorodifluoroethane C2H3ClF2 0.3216 4.108 4.484 30 Chloroform CHCl3 0.4192 4.879 5.326 31 Chloropentafluoroethane C2ClF5 0.2437 6.314 6.892 32 Chloropropane C3H7Cl 0.308 3.21 3.504 33 Cisbutene C4H8 0.3004 2.293 2.503 34 Cyanogen C2N2 0.4924 2.127 2.322 35 Cyanogen Chloride ClCN 0.6486 2.513 2.743 36 Cyclobutane C4H8 0.3562 2.293 2.503 37 Cyclopropane C3H6 0.4562 -
(12) United States Patent (10) Patent No.: US 8,911,640 B2 Nappa Et Al
USOO891. 1640B2 (12) United States Patent (10) Patent No.: US 8,911,640 B2 Nappa et al. (45) Date of Patent: Dec. 16, 2014 (54) COMPOSITIONS COMPRISING 5,736,063 A 4/1998 Richard et al. FLUOROOLEFNS AND USES THEREOF 5,744,052 A 4/1998 Bivens 5,788,886 A 8, 1998 Minor et al. 5,897.299 A * 4/1999 Fukunaga ..................... 417.316 (71) Applicant: E I du Pont de Nemours and 5,969,198 A 10/1999 Thenappan et al. Company, Wilmington, DE (US) 6,053,008 A 4/2000 Arman et al. 6,065.305 A 5/2000 Arman et al. (72) Inventors: Mario Joseph Nappa, Newark, DE 6,076,372 A 6/2000 Acharya et al. 6,111,150 A 8/2000 Sakyu et al. (US); Barbara Haviland Minor, Elkton, 6,176,102 B1 1/2001 Novak et al. MD (US); Allen Capron Sievert, 6,258,292 B1 7/2001 Turner Elkton, MD (US) 6,300,378 B1 10/2001 Tapscott 6.426,019 B1 7/2002 Acharya et al. (73) Assignee: E I du Pont de Nemours and 6,610,250 B1 8, 2003 Tuma Company, Wilmington, DE (US) 6,858,571 B2 2/2005 Pham et al. 6,969,701 B2 11/2005 Singh et al. 7,708,903 B2 5, 2010 Sievert et al. *) Notice: Subject to anyy disclaimer, the term of this 8,012,368 B2 9/2011 Nappa et al. patent is extended or adjusted under 35 8,070,976 B2 12/2011 Nappa et al. U.S.C. 154(b) by 0 days. -
Influence of Silicon on High-Temperature
Solar Energy Materials & Solar Cells 160 (2017) 410–417 Contents lists available at ScienceDirect Solar Energy Materials & Solar Cells journal homepage: www.elsevier.com/locate/solmat Influence of silicon on high-temperature (600 °C) chlorosilane interactions with iron crossmark ⁎ Josh Allera, , Nolan Swainb, Michael Babera, Greg Tatarb, Nathan Jacobsonc, Paul Gannonb a Mechanical and Industrial Engineering, Montana State University, Bozeman, MT 59717, USA b Chemical and Biological Engineering, Montana State University, Bozeman, MT 59717, USA c NASA Glenn Research Center, Cleveland, OH 44135, USA ARTICLE INFO ABSTRACT Keywords: High-temperature ( > 500 °C) chlorosilane gas streams are prevalent in the manufacture of polycrystalline Iron silicon, the feedstock for silicon-based solar panels and electronics. This study investigated the influence of Chlorosilane metallurgical grade silicon on the corrosion behavior of pure iron in these types of environments. The Silicon experiment included exposing pure iron samples at 600 °C to a silicon tetrachloride/hydrogen input gas mixture Silicon tetrachloride with and without embedding the samples in silicon. The samples in a packed bed of silicon had significantly Iron silicide higher mass gains compared to samples not in a packed bed. Comparison to diffusion studies suggest that the Corrosion increase in mass gain of embedded samples is due to a higher silicon activity from the gas phase reaction with silicon. The experimental results were supported by chemical equilibrium calculations which showed that more- active trichlorosilane and dichlorosilane species are formed from silicon tetrachloride in silicon packed bed conditions. 1. Introduction most common material added to a chlorosilane gas stream is silicon. Silicon may be present in a fluidized bed reactor used to convert silicon Chlorosilane species are used at high temperatures in the refine- tetrachloride to trichlorosilane or deposition equipment used to deposit ment, manufacture, and deposition of silicon and silicon-containing silicon on a wafer. -
Fluorinated Butatrienes
Fluorinated Butatrienes Dissertation zur Erlangung des akademischen Grades des Doktors der Naturwissenschaften (Dr. rer. nat.) eingereicht im Fachbereich Biologie, Chemie, Pharmazie der Freien Universität Berlin vorgelegt von Dipl.-Chem. Christian Ehm aus Berlin Berlin, April 2010 1. Gutachter: Prof. Dr. Dieter Lentz 2. Gutachter: Prof. Dr. Beate Paulus Disputation am 28.6.2010 I Acknowledgements It would not have been possible to write this doctoral thesis without the help and support of the kind people around me, to only some of whom it is possible to give particular mention here. First and foremost I would like to thank my principal supervisor, Professor Dieter Lentz, for the opportunity of doing research in his group. Without his continuous support and encouragement this thesis would not be in the present state. I highly appreciate that Professor Beate Paulus has agreed to be co-referee of my thesis. I would like to cordially thank Lada for her love and patience as well as her interest in my research. Special thanks to my family for their continuous support and love. I would like to thank Mike Roland, Sten Dathe and Sven Wünsche for their friendship and the fun we have had every Sunday evening. Special thanks to Sebastian Freitag, Boris Bolsinger and Frederic Heinrich for their friendship. They deserve much gratefulness for keeping me on the right way. I would like to thank all my colleagues at the Institut für Chemie und Biochemie, Abteilung Anorganische Chemie. In particular I want to thank all members of the Lentz group, Thomas Hügle, Moritz Kühnel, Dr. Floris Akkerman, Dr. -
Dichlorosilane Safety Data Sheet
Dichlorosilane Safety Data Sheet P-4587 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Issue date: 01/01/1980 Revision date: 01/27/2021 Supersedes: 03/09/2017 Version: 1.0 SECTION: 1. Product and company identification 1.1. Product identifier Product form : Substance Substance name : Dichlorosilane Chemical name : Dichlorosilane CAS-No. : 4109-96-0 Formula : SiH2Cl2 Other means of identification : Chlorosilane A-199, DCS 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial use; Use as directed. 1.3. Details of the supplier of the safety data sheet Praxair, Inc. 10 Riverview Drive Danbury, CT 06810-6268 - USA T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146 www.praxair.com 1.4. Emergency telephone number Emergency number : Onsite Emergency: 1-800-645-4633 CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729) SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS US classification Flam. Gas 1 H220 Press. Gas (Liq.) H280 Acute Tox. 2 (Inhalation: gas) H330 Skin Corr. 1B H314 Eye Dam. 1 H318 STOT SE 3 H335 2.2. Label elements GHS US labeling Hazard pictograms (GHS US) : GHS02 GHS04 GHS05 GHS06 Signal word (GHS US) : Danger Hazard statements (GHS US) : H220 - EXTREMELY FLAMMABLE GAS H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE H330 - FATAL IF INHALED CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT CGA-HG11 - SYMPTOMS MAY BE DELAYED CGA-HG01 - MAY CAUSE FROSTBITE. -
Interagency Committee on Chemical Management
DECEMBER 14, 2018 INTERAGENCY COMMITTEE ON CHEMICAL MANAGEMENT EXECUTIVE ORDER NO. 13-17 REPORT TO THE GOVERNOR WALKE, PETER Table of Contents Executive Summary ...................................................................................................................... 2 I. Introduction .......................................................................................................................... 3 II. Recommended Statutory Amendments or Regulatory Changes to Existing Recordkeeping and Reporting Requirements that are Required to Facilitate Assessment of Risks to Human Health and the Environment Posed by Chemical Use in the State ............................................................................................................................ 5 III. Summary of Chemical Use in the State Based on Reported Chemical Inventories....... 8 IV. Summary of Identified Risks to Human Health and the Environment from Reported Chemical Inventories ........................................................................................................... 9 V. Summary of any change under Federal Statute or Rule affecting the Regulation of Chemicals in the State ....................................................................................................... 12 VI. Recommended Legislative or Regulatory Action to Reduce Risks to Human Health and the Environment from Regulated and Unregulated Chemicals of Emerging Concern .............................................................................................................................. -
Environmental Health Criteria 166 METHYL BROMIDE
Environmental Health Criteria 166 METHYL BROMIDE Please note that the layout and pagination of this web version are not identical with the printed version. Methyl Bromide (EHC 166, 1995) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 166 METHYL BROMIDE This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. First draft prepared by Dr. R.F. Hertel and Dr. T. Kielhorn. Fraunhofer Institute of Toxicology and Aerosol Research, Hanover, Germany Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1995 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, -
Status of Numerical Modeling of Halocarbon Impacts on Stratospheric Ozone
THE STATUS OF NUMERICAL MODELING OF HALOCARBON IMPACTS ON STRATOSPHERIC OZONE Donald J. Wuebbles Department of Atmospheric Sciences University of Illinois, Urbana, IL 61801 Tel: 217-244-1568; Fax: 217-244-4393 [email protected] INTRODUCTION Numerical models of the chemistry and physics of the global atmosphere have played a key role in the scientific understanding of past, current and potential future effects of human-related emissions of halocarbons, including Halons, other brominated compounds and various replacement compounds on stratospheric ozone and climate change. As a result, these models have led directly to the Montreal Protocol and other national and international policy decisions regarding halocarbon controls due to their effects on stratospheric ozone. The purpose of this paper is to provide a perspective on atmospheric models, the role they have played in studies of the effects of Halons and other halocarbons on ozone, and to discuss what role models will likely play in future studies of stratospheric ozone THE COMPLEXITY OF STRATOSPHERIC OZONE It is important to recognize that the stratospheric ozone layer is a naturally occurring phenomenon that has great benefits to life on Earth. In fact, the formation of the ozone layer is generally believed to have played an important role in the development of life here on Earth. The accumulation of oxygen molecules in the atmosphere allowed for the production of ozone. Gradually the increasing levels of ozone led to the formation of the stratosphere, a region of the upper atmosphere where temperature increases with altitude largely as a result of the absorption of solar radiation by ozone. -
Al-46% ATTORNEY
Aug. 20, 1963 H. A. WIIST 3,101,304 DISTILLATION PROCESS FOR FLUOROCARBONS Filed April 28, 1960 INVENTOR ... al-46%HERBERT A. WIST ATTORNEY 3, 2,304 United States Patent Office Paterated Aug. 20, 1963 2 17 to 53 inclusive by extractive distillation. Compounds 3,105,304 causing the separation of the perfluorocarbons from the DSTELLATION PRO-CESS FOR FLUORO CARBONS close boiling or azeotrope forming fluorocarbons are aro Herbert Albert Wist, Wilmington, Dei. assignor to matic hydrocarbons, halogenated aromatic hydrocarbons E. I. du Pont de Nemours and Company, Wilmington, and halogenated aliphatic hydrocarbons in which the halo Del, a corporation of Delaware gen has an atomic number of 17 to 53, and which are Filed Apr. 28, 1960, Ser. No. 25,362 liquid at distillation conditions. The process of the pres 17 Clains. (C. 202-39.5) ent invention is based on the discovery that the volatility The process of the present invention relates to the sepa of fluorocarbons boiling close to the volatile perfuoro ration of fluorocarbons, and, more particularly, to the ex 10 carbons, which generally have from 1 to 5 carbon atoms, tractive distillation of fluorocarbons. or form. azeotropes with the fluorocarbons, is so changed Fluorocarbons, i.e., compounds of carbon and fluorine by the addition of the extractive distillation agents of the which may also contain other elements, such as hydro present invention, that the separation of these groups of . gen and chlorine, and particularly, perfluorocarbons, i.e., compounds becomes a matter of simple distillation. The compounds consisting solely of carbon and fluorine, are 15 close boiling or azeotrope forming fluorocarbons generally highly useful as refrigerants and solvents. -
Hazardous Materials Descriptions and Codes
2012 Commodity Flow Survey Hazardous Materials Descriptions and Codes Hazardous Materials Descriptions and Proper Shipping Names UN or NA Code Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) Acetal 1088 Acetaldehyde 1089 Acetaldehyde ammonia 1841 Acetaldehyde oxime 2332 Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass 2789 Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by 2790 mass Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass 2790 Acetic anhydride 1715 Acetone 1090 Acetone cyanohydrin, stabilized 1541 Acetone oils 1091 Acetonitrile 1648 Acetyl bromide 1716 Acetyl chloride 1717 Acetyl iodide 1898 Acetyl methyl carbinol 2621 Acetylene, dissolved 1001 Acetylene tetrabromide, see Tetrabromoethane Acid butyl phosphate, see Butyl acid phosphate Acid, sludge, see Sludge acid Acridine 2713 Acrolein dimer, stabilized 2607 Acrolein, stabilized 1092 Acrylamide, solid 2074 Acrylamide solution 3426 Acrylic acid, stabilized 2218 Acrylonitrile, stabilized 1093 Actuating cartridge, explosive, see Cartridges, power device Adhesives, containing a flammable liquid 1133 Adiponitrile 2205 Aerosols, poison, Packing Group III (each not exceeding 1 L capacity) 1950 Aerosols, flammable, (each not exceeding 1 L capacity) 1950 Source: Electronic Code of Federal Regulations http://ecfr.gpoaccess.gov/cgi/t/text/text- idx?c=ecfr&sid=dfec99df9f21ef29b59a8565433a56cd&rgn=div6&view=text&node=49:2.1.1.3.8.2&idno=49 1 Hazardous Materials Descriptions and Proper Shipping Names UN or NA Code Aerosols, flammable, n.o.s.