64021 Ammonium Carbonate

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64021 Ammonium Carbonate Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 1 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 1. Identification of the Substance/Mixture and of the Company/Undertaking 1. 1. Product Identifier Product Name: Ammonium Carbonate Article No.: 64021 1. 2. Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical for different applications Food additive Uses advised against: 1. 3. Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Kremer Pigmente GmbH & Co. KG Address: Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: www.kremer-pigmente.com EMail: [email protected] Importer: -- 1. 4. Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00) 1. 4. 2 Poison Center: 2. Hazards Identification 2. 1. Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Acute toxicity (oral), hazard category 4 Eye irritation, hazard category 2 H302 Harmful if swallowed. Cat.: 4 H319 Causes serious eye irritation. Cat.: 2 Possible Environmental Effects: 2. 2. Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: GHS07-1 Signal word: Warning Hazard designation: next page: 2 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 2 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 H302 Harmful if swallowed. H319 Causes serious eye irritation. Safety designation: P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ clothing/ eye/ face protection. P301+P330+P331 If swallowed: Rinse mouth. Do not induce vomiting. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. P337+P313 If eye irritation persists: Get medical advice/ attention. Hazardous components for labelling: Ammonium carbamate Ammonium bicarbonate 2. 3. Other Hazards 3. Composition/Information on Ingredients 3. 1. Substance 3. 2. Mixture Chemical Characterization: CAS No. 10361-29-2; EINECS 233-786-0 Mixture of the following substances. Information on Components / Hazardous Ingredients: Ammonium carbamate (Acute Tox. 4, H302- Eye 50 % CAS-Nr: 1111-78-0 Dam. 1, H315); REACH 01-2119493982-22 EINECS-Nr: 214-185-2 EC-Nr: Ammonium bicarbonate (Acute Tox. 4, H302); 50 % CAS-Nr: 1066-33-7 REACH 01-2119486970-26 EINECS-Nr: 213-911-5 EC-Nr: Additional information: 4. First Aid Measures 4. 1. Description of the First Aid Measures General information: Remove contaminated clothes. Take person away from hazardous area. After inhalation: Supply fresh air. Consult physician if symptoms persist. After skin contact: Wash with soap and rinse with plenty of water. If symptoms persist, consult a physician. After eye contact: Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. After ingestion: Rinse mouth with water and drink plenty of water. next page: 3 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 3 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Immediately get medical help. 4. 2. Most important Symptoms and Effects, both Acute and Delayed Symptoms: Cough, nausea, labored breathing. Effects: Risk of respiratory disorders. 4. 3. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Following severe exposure the patient should be kept under medical surveillance for at least 48h. 5. Fire-Fighting Measures 5. 1. Extinguishing Media Suitable extinguishing media: Foam, carbon dioxide (CO2), water spray jet. Unsuitable extinguishing media: None known. 5. 2. Special Hazards arising from the Substance or Mixture Special hazards: Risk of bursting. In case of fire: formation of carbon and nitrogen oxides. In case of fire: formation of ammonia. 5. 3. Advice for Firefighters Protective equipment: Wear self-contained respiratory protective device. Further information: Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. 6. Accidential Release Measures 6. 1. Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Wear appropriate protective equipment. Keep spectators away. Ensure adequate ventilation. Avoid formation of dust. Avoid contact with skin and eyes. Do not ingest or inhale. 6. 2. Environmental Precautions Environmental precautions: Prevent contamination of soil, drains and surface waters. Contact local authorities if product pollutes soil or vegetation. Use water spray when very dusty. 6. 3. Methods and Material for Containment and Cleaning Up Methods and material: Clean up mechanically. Transfer liquids and solid diking material to next page: 4 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 4 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 separate suitable containers for recovery or disposal. 6. 4. Reference to other Sections Protective clothing, see Section 8. See Section 13 for information on disposal. 7. Handling and Storage 7. 1. Precautions for Safe Handling Instructions on safe handling: Provide adequate ventilation. Avoid formation and deposition of dust. Provide adequate ventilation. Hygienic measures: Avoid contact with eyes and skin. Do not inhale gas/fumes/vapours/aerosols. 7. 2. Conditions for Safe Storage, including any Incompatibilities Storage conditions: Store containers in a well ventilated location. Store in tightly sealed containers in a dry and cool room. Do not store above 30°C. Product is hygroscopic. Heat causes pressure increase and risk of bursting. Requirements for storage areas and containers: No special measures necessary. Information on fire and explosion protection: Keep breathing apparatus available. Do not store together with: strong oxidants. (Sodium nitrate, Sodium nitrite) Do not store together with alkalis. Storage class: 13; Non combustible solids (TRGS 510) Further Information: Maximum storage temperature: 30°C 7. 3. Specific End Use(s) Further information: No information available. 8. Exposure Controls/Personal Protection 8. 1. Parameters to be Controlled Parameters to be controlled (DE): Ammonia, anhydrous (CAS 7664-41-7): OEL (TRGS 900): 14 mg/m3; 20 ml/m3; 2(1), DFG, EU, Y Carbon dioxide (CAS 124-38-9); TLV (TRGS 900) 9100 mg/m3, 5000 ml/m3 Parameters to be controlled: next page: 5 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 5 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Ammonia, anhydrous (CAS 7664-41-7); IOELV (STEL): 36 mg/m3; 50 mg/m3; Longterm value: 14 mg/m3, 20 ml/m3 Kohlendioxid (CAS 124-38-9: IOELV (STEL): 9000 mg/m3, 5000 ml/m3 Derived No-Effect Level (DNEL): Ammonium bicarbonate (1066-33-7): 34.2 mg/kg bw/d (consumer, skin contact, long-term exposition - systemic effects) 57 mg/kg bw/d (worker, skin contact, long-term exposition - systemic effects) 143.91 mg/m3 (consumer, inhalation, short-term exposition - systemic effects) 13.33 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) 62.5 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) Ammonium carbamate (1111-78-8): 7.1 mg/kg bw/d (consumer, skin contact, long-term exposition - systemic effects) 14.1 mg/kg bw/d (worker, skin contact, long-term exposition - systemic effects) 12.3 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) 49.8 mg/m3 (worker, inhalation, long-term exposition - systemic effects) Predicted No-Effect Concentration (PNEC): Ammonium bicarbonate (1066-33-7): Fresh water: 0.37 mg/l Sea water: 0.037 mg/l Fresh water sediment: 0.1332 mg/l Seawater sediment: 0.01332 mg/l Sewage treatment system (STP): 1347 mg/l Soil: 74.9 mg/kg Ammonium carbamate (1111-78-8): Fresh water: 0.037 mg/l Sea water: 0.0037 mg/l Fresh water sediment: 0.167 mg/l Seawater sediment: 0.0167 mg/l Sewage treatment system (STP): 10 mg/l Soil: 0.0117 mg/l Intermittent release: 0.37 mg/l Additional Information: 8. 2. Exposure Controls Technical protective measures: Adequate ventilation. Personal Protection General protective measures: next page: 6 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 6 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Avoid contact with eyes and skin. Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Respiratory protection: In case of formation of dust/vapor. Particle filter Type P1 or FFP1 (solid particles of inert substances; EN 143, 149). Hand protection: Protective gloves (EN 374) Protective glove material: Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Polyvinyl chloride (> 480 min, 0.7 mm) Chloroprene rubber (> 480 min, 0.5 mm) Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Eye protection: Tightly fitting safety goggles (EN 166). Body protection: Protective clothing. Environmental precautions: 9. Physical and Chemical Properties 9. 1. Information on Basic Physical and Chemical Properties Form: powder Color: white Odor: ammonium-like Odor threshold: < 5 ppm pH-Value: 9 Melting temperature: not determined Boiling temperature: not determined Flash point: not applicable Evaporation rate: not applicable Flammability (solid, gas): not flammable Upper explosion limit: no information available Lower explosion limit: no information available next page: 7 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate Page 7 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Vapor pressure: 69 hPa (20°C) Vapor density: No information available. Density: 0.9 - 1.5 g/cm3 (20°C) Solubility in water: 320 g/l (20°C) Coefficient of variation (n- -2.4 - -0.47 logPOW Octanol/Water): Auto-ignition temperature: Product is not auto-ignitable.
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