Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 1 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 1. Identification of the Substance/Mixture and of the Company/Undertaking 1. 1. Product Identifier Product Name: Ammonium Carbonate Article No.: 64021 1. 2. Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical for different applications Food additive Uses advised against: 1. 3. Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Kremer Pigmente GmbH & Co. KG Address: Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: www.kremer-pigmente.com EMail: [email protected] Importer: -- 1. 4. Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00) 1. 4. 2 Poison Center: 2. Hazards Identification 2. 1. Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Acute toxicity (oral), hazard category 4 Eye irritation, hazard category 2 H302 Harmful if swallowed. Cat.: 4 H319 Causes serious eye irritation. Cat.: 2 Possible Environmental Effects: 2. 2. Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation:
GHS07-1
Signal word: Warning Hazard designation: next page: 2 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 2 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 H302 Harmful if swallowed. H319 Causes serious eye irritation. Safety designation: P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ clothing/ eye/ face protection. P301+P330+P331 If swallowed: Rinse mouth. Do not induce vomiting. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. P337+P313 If eye irritation persists: Get medical advice/ attention. Hazardous components for labelling: Ammonium carbamate Ammonium bicarbonate 2. 3. Other Hazards 3. Composition/Information on Ingredients 3. 1. Substance 3. 2. Mixture Chemical Characterization: CAS No. 10361-29-2; EINECS 233-786-0 Mixture of the following substances. Information on Components / Hazardous Ingredients: Ammonium carbamate (Acute Tox. 4, H302- Eye 50 % CAS-Nr: 1111-78-0 Dam. 1, H315); REACH 01-2119493982-22 EINECS-Nr: 214-185-2 EC-Nr:
Ammonium bicarbonate (Acute Tox. 4, H302); 50 % CAS-Nr: 1066-33-7 REACH 01-2119486970-26 EINECS-Nr: 213-911-5 EC-Nr:
Additional information: 4. First Aid Measures 4. 1. Description of the First Aid Measures General information: Remove contaminated clothes. Take person away from hazardous area. After inhalation: Supply fresh air. Consult physician if symptoms persist. After skin contact: Wash with soap and rinse with plenty of water. If symptoms persist, consult a physician. After eye contact: Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. After ingestion: Rinse mouth with water and drink plenty of water. next page: 3 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 3 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Immediately get medical help. 4. 2. Most important Symptoms and Effects, both Acute and Delayed Symptoms: Cough, nausea, labored breathing. Effects: Risk of respiratory disorders. 4. 3. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Following severe exposure the patient should be kept under medical surveillance for at least 48h. 5. Fire-Fighting Measures 5. 1. Extinguishing Media Suitable extinguishing media: Foam, carbon dioxide (CO2), water spray jet. Unsuitable extinguishing media: None known. 5. 2. Special Hazards arising from the Substance or Mixture Special hazards: Risk of bursting. In case of fire: formation of carbon and nitrogen oxides. In case of fire: formation of ammonia. 5. 3. Advice for Firefighters Protective equipment: Wear self-contained respiratory protective device. Further information: Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. 6. Accidential Release Measures 6. 1. Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Wear appropriate protective equipment. Keep spectators away. Ensure adequate ventilation. Avoid formation of dust. Avoid contact with skin and eyes. Do not ingest or inhale. 6. 2. Environmental Precautions Environmental precautions: Prevent contamination of soil, drains and surface waters. Contact local authorities if product pollutes soil or vegetation. Use water spray when very dusty. 6. 3. Methods and Material for Containment and Cleaning Up Methods and material: Clean up mechanically. Transfer liquids and solid diking material to next page: 4 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 4 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 separate suitable containers for recovery or disposal. 6. 4. Reference to other Sections Protective clothing, see Section 8. See Section 13 for information on disposal. 7. Handling and Storage 7. 1. Precautions for Safe Handling Instructions on safe handling: Provide adequate ventilation. Avoid formation and deposition of dust. Provide adequate ventilation. Hygienic measures: Avoid contact with eyes and skin. Do not inhale gas/fumes/vapours/aerosols. 7. 2. Conditions for Safe Storage, including any Incompatibilities Storage conditions: Store containers in a well ventilated location. Store in tightly sealed containers in a dry and cool room. Do not store above 30°C. Product is hygroscopic. Heat causes pressure increase and risk of bursting. Requirements for storage areas and containers: No special measures necessary. Information on fire and explosion protection: Keep breathing apparatus available. Do not store together with: strong oxidants. (Sodium nitrate, Sodium nitrite) Do not store together with alkalis. Storage class: 13; Non combustible solids (TRGS 510) Further Information: Maximum storage temperature: 30°C 7. 3. Specific End Use(s) Further information: No information available. 8. Exposure Controls/Personal Protection 8. 1. Parameters to be Controlled Parameters to be controlled (DE): Ammonia, anhydrous (CAS 7664-41-7): OEL (TRGS 900): 14 mg/m3; 20 ml/m3; 2(1), DFG, EU, Y Carbon dioxide (CAS 124-38-9); TLV (TRGS 900) 9100 mg/m3, 5000 ml/m3 Parameters to be controlled: next page: 5 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 5 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Ammonia, anhydrous (CAS 7664-41-7); IOELV (STEL): 36 mg/m3; 50 mg/m3; Longterm value: 14 mg/m3, 20 ml/m3 Kohlendioxid (CAS 124-38-9: IOELV (STEL): 9000 mg/m3, 5000 ml/m3 Derived No-Effect Level (DNEL): Ammonium bicarbonate (1066-33-7): 34.2 mg/kg bw/d (consumer, skin contact, long-term exposition - systemic effects) 57 mg/kg bw/d (worker, skin contact, long-term exposition - systemic effects) 143.91 mg/m3 (consumer, inhalation, short-term exposition - systemic effects) 13.33 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) 62.5 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) Ammonium carbamate (1111-78-8): 7.1 mg/kg bw/d (consumer, skin contact, long-term exposition - systemic effects) 14.1 mg/kg bw/d (worker, skin contact, long-term exposition - systemic effects) 12.3 mg/m3 (consumer, inhalation, long-term exposition - systemic effects) 49.8 mg/m3 (worker, inhalation, long-term exposition - systemic effects) Predicted No-Effect Concentration (PNEC): Ammonium bicarbonate (1066-33-7): Fresh water: 0.37 mg/l Sea water: 0.037 mg/l Fresh water sediment: 0.1332 mg/l Seawater sediment: 0.01332 mg/l Sewage treatment system (STP): 1347 mg/l Soil: 74.9 mg/kg Ammonium carbamate (1111-78-8): Fresh water: 0.037 mg/l Sea water: 0.0037 mg/l Fresh water sediment: 0.167 mg/l Seawater sediment: 0.0167 mg/l Sewage treatment system (STP): 10 mg/l Soil: 0.0117 mg/l Intermittent release: 0.37 mg/l Additional Information: 8. 2. Exposure Controls Technical protective measures: Adequate ventilation. Personal Protection General protective measures: next page: 6 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 6 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Avoid contact with eyes and skin. Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Respiratory protection: In case of formation of dust/vapor. Particle filter Type P1 or FFP1 (solid particles of inert substances; EN 143, 149). Hand protection: Protective gloves (EN 374) Protective glove material: Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Polyvinyl chloride (> 480 min, 0.7 mm) Chloroprene rubber (> 480 min, 0.5 mm) Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Eye protection: Tightly fitting safety goggles (EN 166). Body protection: Protective clothing. Environmental precautions: 9. Physical and Chemical Properties 9. 1. Information on Basic Physical and Chemical Properties Form: powder Color: white Odor: ammonium-like Odor threshold: < 5 ppm pH-Value: 9 Melting temperature: not determined Boiling temperature: not determined Flash point: not applicable Evaporation rate: not applicable Flammability (solid, gas): not flammable Upper explosion limit: no information available Lower explosion limit: no information available next page: 7 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 7 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Vapor pressure: 69 hPa (20°C) Vapor density: No information available. Density: 0.9 - 1.5 g/cm3 (20°C) Solubility in water: 320 g/l (20°C) Coefficient of variation (n- -2.4 - -0.47 logPOW Octanol/Water): Auto-ignition temperature: Product is not auto-ignitable. Decomposition temperature: > 59°C Viscosity, dynamic: not applicable Explosive properties: Product does not present an explosion hazard. Oxidizing properties: no information available Bulk density: 780 - 830 kg/m3 9. 2. Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: No data available. Other information: 10. Stability and Reactivity 10.1. Reactivity No decomposition if used according to specifications. 10.2. Chemical Stability Stable if used according to specifications. 10.3. Possibility of Hazardous Reactions Risk of bursting. Reacts with nitrites. Exothermic reaction. Development of ammonia after contact with alkalis. Vigorous reactions with nitrates. 10.4. Conditions to Avoid Conditions to avoid: Do not overheat. next page: 8 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 8 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Thermal decomposition: Avoid temperatures above 55°C. 10.5. Imcompatible Materials Strong oxidizing agents. Acids, alkalies, nitrites, nitrates. 10.6. Hazardous Decomposition Products Carbon monoxide, cabon dioxide and nitrogen oxide. Ammonia. 10.7. Further Information 11. Toxicological Information 11. 1. Information on Toxicological Effects Acute Toxicity LD50, oral: 1800 - 2150 mg/kg (rat) Ammonium bicarbonate (1066-37-7): 1576 mg/kg (rat) Ammonium carbamate (1111-78-0): 681-1470 mg/kg (rat; BASF- Test) LD50, dermal: > 2000 mg/kg (rat) Ammonium carbamate (1111-78-0): > 2000 mg/kg (rat) LC50, inhalation: Ammonium carbamate (1111-78-0): 6.6 mg/kg (4h, rat; OECD 403) Primary effects Irritant effect on skin: Irritating to skin (OECD 439) Irritant effect on eyes: Causes serious eye irritation (OECD 405) Inhalation: Can cause irritation of the respiratory system. Ingestion: No information available Sensitization: No sensitizing effects known. Mutagenicity: No relevant data found. Reproductive toxicity: No relevant data found. Carcinogenicity: No relevant data found. Teratogenicity: No information available. Specific target organ toxicity (STOT): No relevant data found. next page: 9 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 9 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 Additional toxicological information: Harmful 12. Ecological Information 12. 1. Aquatic Toxicity Fish toxicity: LC50: 37 mg/l (96h, Pimephales promelas); 61 mg/l (96h, Oncorhynchus mykiss) Ammonium bicarbonate: LC50: 63.4 mg/l (96h, Oncorhynchus mykiss); EC10: 6.3 mg/l (21d, Lepomis macrochirus) Ammonium carbamate: LC50: 37.0 mg/l (96h, Pimephales promelas) Daphnia toxicity: LC50: 63.4 mg/l (96h, Daphnia magna; OECD 202) Ammonium bicarbonate: EC50: 145.6 mg/l (48h, Daphnia magna) Ammonium carbamate: EC50: 63.7 mg/l (48h, Daphnia magna; OECD 202) Bacteria toxicity: Ammonium bicarbonate: EC10: 1347 mg/l (16h; Pseudomonas putida) Ammonium carbamate: EC50: 1180 mg/l (17h; Pseudomonas putida) Algae toxicity: EC50: > 75.9 mg/l (72h, Desmodesmus subspicatus) Ammonium bicarbonate: EC50: 3231 mg/l (18d, Chlorella vulgaris); 1900 mg/l (6d; Chlorella vulgaris) Ammonium carbamate: EC50: 129.13 mg/l (72h, Scenedesmus subspicatus) 12. 2. Persistency and Degradability Methods for the evaluation of the biological degradability are not applicable for inorganic substances. 12. 3. Bioaccumulation No bioaccumulation expected (log P(o/w) < 1). 12. 4. Mobility No information available. 12. 5. Results of PBT- und vPvP Assessment Not applicable. 12. 6. Other Adverse Effects Water hazard class: 1, slightly hazardous (German Regulation; Self-assessment). Do not allow undiluted product or large quantities of it to reach ground water, waterways or sewage system. Behaviour in sewage systems: Further ecological effects: When used properly, no ecological problems expected. AOX Value: next page: 10 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 10 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 13. Disposal Considerations 13. 1. Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): The waste code is determined according to the kind of waste and industry stated in the European Waste Catalogue. Uncleaned packaging: Dispose of according to official local regulations. Waste Code No.: 14. Transport Information 14. 1. UN Number ADR, IMDG, IATA 14. 2. UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG. 14. 3. Transport Hazard Classes ADR Class: not applicable Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: 14. 4. Packaging Group ADR/RID: not applicable IMDG: IATA: 14. 5. Environmental Hazards None 14. 6. Special Precautions for User none known next page: 11 Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH) 64021 Ammonium Carbonate
Page 11 Revised edition: 26.09.2016 Version: 11 Printed: 03.07.2019 14. 7. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable 14. 8. Further Information Not classified as a dangerous good under transport regulations. 15. Regulatory Information 15. 1. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation, self- assessment) Local regulations on chemical accidents: Not listed. Employment restrictions: The employment restrictions for young workers in accordance with the Youth Employment Protection Law (§ 22 JArbSchG) are to be observed. Restriction and prohibition of application: Technical instructions on air quality: 15. 2. Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. 15. 3. Further Information 16. Other Information This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties. Changes: The following sections were changed: 1-16 Sources: The specifications are based on the information of upstream suppliers.