Statistical Thermodynamics - Fall 2009
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Thermodynamics Notes
Thermodynamics Notes Steven K. Krueger Department of Atmospheric Sciences, University of Utah August 2020 Contents 1 Introduction 1 1.1 What is thermodynamics? . .1 1.2 The atmosphere . .1 2 The Equation of State 1 2.1 State variables . .1 2.2 Charles' Law and absolute temperature . .2 2.3 Boyle's Law . .3 2.4 Equation of state of an ideal gas . .3 2.5 Mixtures of gases . .4 2.6 Ideal gas law: molecular viewpoint . .6 3 Conservation of Energy 8 3.1 Conservation of energy in mechanics . .8 3.2 Conservation of energy: A system of point masses . .8 3.3 Kinetic energy exchange in molecular collisions . .9 3.4 Working and Heating . .9 4 The Principles of Thermodynamics 11 4.1 Conservation of energy and the first law of thermodynamics . 11 4.1.1 Conservation of energy . 11 4.1.2 The first law of thermodynamics . 11 4.1.3 Work . 12 4.1.4 Energy transferred by heating . 13 4.2 Quantity of energy transferred by heating . 14 4.3 The first law of thermodynamics for an ideal gas . 15 4.4 Applications of the first law . 16 4.4.1 Isothermal process . 16 4.4.2 Isobaric process . 17 4.4.3 Isosteric process . 18 4.5 Adiabatic processes . 18 5 The Thermodynamics of Water Vapor and Moist Air 21 5.1 Thermal properties of water substance . 21 5.2 Equation of state of moist air . 21 5.3 Mixing ratio . 22 5.4 Moisture variables . 22 5.5 Changes of phase and latent heats . -
Equilibrium Thermodynamics
Equilibrium Thermodynamics Instructor: - Clare Yu (e-mail [email protected], phone: 824-6216) - office hours: Wed from 2:30 pm to 3:30 pm in Rowland Hall 210E Textbooks: - primary: Herbert Callen “Thermodynamics and an Introduction to Thermostatistics” - secondary: Frederick Reif “Statistical and Thermal Physics” - secondary: Kittel and Kroemer “Thermal Physics” - secondary: Enrico Fermi “Thermodynamics” Grading: - weekly homework: 25% - discussion problems: 10% - midterm exam: 30% - final exam: 35% Equilibrium Thermodynamics Material Covered: Equilibrium thermodynamics, phase transitions, critical phenomena (~ 10 first chapters of Callen’s textbook) Homework: - Homework assignments posted on course website Exams: - One midterm, 80 minutes, Tuesday, May 8 - Final, 2 hours, Tuesday, June 12, 10:30 am - 12:20 pm - All exams are in this room 210M RH Course website is at http://eiffel.ps.uci.edu/cyu/p115B/class.html The Subject of Thermodynamics Thermodynamics describes average properties of macroscopic matter in equilibrium. - Macroscopic matter: large objects that consist of many atoms and molecules. - Average properties: properties (such as volume, pressure, temperature etc) that do not depend on the detailed positions and velocities of atoms and molecules of macroscopic matter. Such quantities are called thermodynamic coordinates, variables or parameters. - Equilibrium: state of a macroscopic system in which all average properties do not change with time. (System is not driven by external driving force.) Why Study Thermodynamics ? - Thermodynamics predicts that the average macroscopic properties of a system in equilibrium are not independent from each other. Therefore, if we measure a subset of these properties, we can calculate the rest of them using thermodynamic relations. - Thermodynamics not only gives the exact description of the state of equilibrium but also provides an approximate description (to a very high degree of precision!) of relatively slow processes. -
Thermodynamics of Solar Energy Conversion in to Work
Sri Lanka Journal of Physics, Vol. 9 (2008) 47-60 Institute of Physics - Sri Lanka Research Article Thermodynamic investigation of solar energy conversion into work W.T.T. Dayanga and K.A.I.L.W. Gamalath Department of Physics, University of Colombo, Colombo 03, Sri Lanka Abstract Using a simple thermodynamic upper bound efficiency model for the conversion of solar energy into work, the best material for a converter was obtained. Modifying the existing detailed terrestrial application model of direct solar radiation to include an atmospheric transmission coefficient with cloud factors and a maximum concentration ratio, the best shape for a solar concentrator was derived. Using a Carnot engine in detailed space application model, the best shape for the mirror of a concentrator was obtained. A new conversion model was introduced for a solar chimney power plant to obtain the efficiency of the power plant and power output. 1. INTRODUCTION A system that collects and converts solar energy in to mechanical or electrical power is important from various aspects. There are two major types of solar power systems at present, one using photovoltaic cells for direct conversion of solar radiation energy in to electrical energy in combination with electrochemical storage and the other based on thermodynamic cycles. The efficiency of a solar thermal power plant is significantly higher [1] compared to the maximum efficiency of twenty percent of a solar cell. Although the initial cost of a solar thermal power plant is very high, the running cost is lower compared to the other power plants. Therefore most countries tend to build solar thermal power plants. -
Solar Thermal Energy
22 Solar Thermal Energy Solar thermal energy is an application of solar energy that is very different from photovol- taics. In contrast to photovoltaics, where we used electrodynamics and solid state physics for explaining the underlying principles, solar thermal energy is mainly based on the laws of thermodynamics. In this chapter we give a brief introduction to that field. After intro- ducing some basics in Section 22.1, we will discuss Solar Thermal Heating in Section 22.2 and Concentrated Solar (electric) Power (CSP) in Section 22.3. 22.1 Solar thermal basics We start this section with the definition of heat, which sometimes also is called thermal energy . The molecules of a body with a temperature different from 0 K exhibit a disordered movement. The kinetic energy of this movement is called heat. The average of this kinetic energy is related linearly to the temperature of the body. 1 Usually, we denote heat with the symbol Q. As it is a form of energy, its unit is Joule (J). If two bodies with different temperatures are brought together, heat will flow from the hotter to the cooler body and as a result the cooler body will be heated. Dependent on its physical properties and temperature, this heat can be absorbed in the cooler body in two forms, sensible heat and latent heat. Sensible heat is that form of heat that results in changes in temperature. It is given as − Q = mC p(T2 T1), (22.1) where Q is the amount of heat that is absorbed by the body, m is its mass, Cp is its heat − capacity and (T2 T1) is the temperature difference. -
Empirical Modelling of Einstein Absorption Refrigeration System
Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 75, Issue 3 (2020) 54-62 Journal of Advanced Research in Fluid Mechanics and Thermal Sciences Journal homepage: www.akademiabaru.com/arfmts.html ISSN: 2289-7879 Empirical Modelling of Einstein Absorption Refrigeration Open Access System Keng Wai Chan1,*, Yi Leang Lim1 1 School of Mechanical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia ARTICLE INFO ABSTRACT Article history: A single pressure absorption refrigeration system was invented by Albert Einstein and Received 4 April 2020 Leo Szilard nearly ninety-year-old. The system is attractive as it has no mechanical Received in revised form 27 July 2020 moving parts and can be driven by heat alone. However, the related literature and Accepted 5 August 2020 work done on this refrigeration system is scarce. Previous researchers analysed the Available online 20 September 2020 refrigeration system theoretically, both the system pressure and component temperatures were fixed merely by assumption of ideal condition. These values somehow have never been verified by experimental result. In this paper, empirical models were proposed and developed to estimate the system pressure, the generator temperature and the partial pressure of butane in the evaporator. These values are important to predict the system operation and the evaporator temperature. The empirical models were verified by experimental results of five experimental settings where the power input to generator and bubble pump were varied. The error for the estimation of the system pressure, generator temperature and partial pressure of butane in evaporator are ranged 0.89-6.76%, 0.23-2.68% and 0.28-2.30%, respectively. -
Thermodynamics
ME346A Introduction to Statistical Mechanics { Wei Cai { Stanford University { Win 2011 Handout 6. Thermodynamics January 26, 2011 Contents 1 Laws of thermodynamics 2 1.1 The zeroth law . .3 1.2 The first law . .4 1.3 The second law . .5 1.3.1 Efficiency of Carnot engine . .5 1.3.2 Alternative statements of the second law . .7 1.4 The third law . .8 2 Mathematics of thermodynamics 9 2.1 Equation of state . .9 2.2 Gibbs-Duhem relation . 11 2.2.1 Homogeneous function . 11 2.2.2 Virial theorem / Euler theorem . 12 2.3 Maxwell relations . 13 2.4 Legendre transform . 15 2.5 Thermodynamic potentials . 16 3 Worked examples 21 3.1 Thermodynamic potentials and Maxwell's relation . 21 3.2 Properties of ideal gas . 24 3.3 Gas expansion . 28 4 Irreversible processes 32 4.1 Entropy and irreversibility . 32 4.2 Variational statement of second law . 32 1 In the 1st lecture, we will discuss the concepts of thermodynamics, namely its 4 laws. The most important concepts are the second law and the notion of Entropy. (reading assignment: Reif x 3.10, 3.11) In the 2nd lecture, We will discuss the mathematics of thermodynamics, i.e. the machinery to make quantitative predictions. We will deal with partial derivatives and Legendre transforms. (reading assignment: Reif x 4.1-4.7, 5.1-5.12) 1 Laws of thermodynamics Thermodynamics is a branch of science connected with the nature of heat and its conver- sion to mechanical, electrical and chemical energy. (The Webster pocket dictionary defines, Thermodynamics: physics of heat.) Historically, it grew out of efforts to construct more efficient heat engines | devices for ex- tracting useful work from expanding hot gases (http://www.answers.com/thermodynamics). -
Teaching Psychrometry to Undergraduates
AC 2007-195: TEACHING PSYCHROMETRY TO UNDERGRADUATES Michael Maixner, U.S. Air Force Academy James Baughn, University of California-Davis Michael Rex Maixner graduated with distinction from the U. S. Naval Academy, and served as a commissioned officer in the USN for 25 years; his first 12 years were spent as a shipboard officer, while his remaining service was spent strictly in engineering assignments. He received his Ocean Engineer and SMME degrees from MIT, and his Ph.D. in mechanical engineering from the Naval Postgraduate School. He served as an Instructor at the Naval Postgraduate School and as a Professor of Engineering at Maine Maritime Academy; he is currently a member of the Department of Engineering Mechanics at the U.S. Air Force Academy. James W. Baughn is a graduate of the University of California, Berkeley (B.S.) and of Stanford University (M.S. and PhD) in Mechanical Engineering. He spent eight years in the Aerospace Industry and served as a faculty member at the University of California, Davis from 1973 until his retirement in 2006. He is a Fellow of the American Society of Mechanical Engineering, a recipient of the UCDavis Academic Senate Distinguished Teaching Award and the author of numerous publications. He recently completed an assignment to the USAF Academy in Colorado Springs as the Distinguished Visiting Professor of Aeronautics for the 2004-2005 and 2005-2006 academic years. Page 12.1369.1 Page © American Society for Engineering Education, 2007 Teaching Psychrometry to Undergraduates by Michael R. Maixner United States Air Force Academy and James W. Baughn University of California at Davis Abstract A mutli-faceted approach (lecture, spreadsheet and laboratory) used to teach introductory psychrometric concepts and processes is reviewed. -
Thermodynamics of Interacting Magnetic Nanoparticles
This is a repository copy of Thermodynamics of interacting magnetic nanoparticles. White Rose Research Online URL for this paper: https://eprints.whiterose.ac.uk/168248/ Version: Accepted Version Article: Torche, P., Munoz-Menendez, C., Serantes, D. et al. (6 more authors) (2020) Thermodynamics of interacting magnetic nanoparticles. Physical Review B. 224429. ISSN 2469-9969 https://doi.org/10.1103/PhysRevB.101.224429 Reuse Items deposited in White Rose Research Online are protected by copyright, with all rights reserved unless indicated otherwise. They may be downloaded and/or printed for private study, or other acts as permitted by national copyright laws. The publisher or other rights holders may allow further reproduction and re-use of the full text version. This is indicated by the licence information on the White Rose Research Online record for the item. Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing [email protected] including the URL of the record and the reason for the withdrawal request. [email protected] https://eprints.whiterose.ac.uk/ Thermodynamics of interacting magnetic nanoparticles P. Torche1, C. Munoz-Menendez2, D. Serantes2, D. Baldomir2, K. L. Livesey3, O. Chubykalo-Fesenko4, S. Ruta5, R. Chantrell5, and O. Hovorka1∗ 1School of Engineering and Physical Sciences, University of Southampton, Southampton SO16 7QF, UK 2Instituto de Investigaci´ons Tecnol´oxicas and Departamento de F´ısica Aplicada, Universidade de Santiago de Compostela, -
Understanding Psychrometrics, Third Edition It’S Really a Mine of Information
Gatley The Comprehensive Guide to Psychrometrics Understanding Psychrometrics serves as a lifetime reference manual and basic refresher course for those who use psychrometrics on a recurring basis and provides a four- to six-hour psychrometrics learning module to students; air- conditioning designers; agricultural, food process, and industrial process engineers; Understanding Psychrometrics meteorologists and others. Understanding Psychrometrics Third Edition New in the Third Edition • Revised chapters for wet-bulb temperature and relative humidity and a revised Appendix V that includes a summary of ASHRAE Research Project RP-1485. • New constants for the universal gas constant based on CODATA and a revised molar mass of dry air to account for the increase of CO2 in Earth’s atmosphere. • New IAPWS models for the calculation of water properties above and below freezing. • New tables based on the ASHRAE RP-1485 real moist-air numerical model using the ASHRAE LibHuAirProp add-ins for Excel®, MATLAB®, Mathcad®, and EES®. Includes Access to Bonus Materials and Sample Software • PDF files of 13 ultra-high-pressure and 12 existing ASHRAE psychrometric charts plus three new 0ºC to 400ºC charts. • A limited demonstration version of the ASHRAE LibHuAirProp add-in that allows users to duplicate portions of the real moist-air psychrometric tables in the ASHRAE Handbook—Fundamentals for both standard sea level atmospheric pressure and pressures from 5 to 10,000 kPa. • The hw.exe program from the second edition, included to enable users to compare the 2009 ASHRAE numerical model real moist-air psychrometric properties with the 1983 ASHRAE-Hyland-Wexler properties. Praise for Understanding Psychrometrics, Third Edition It’s really a mine of information. -
Chapter03 Introduction to Thermodynamic Systems
Chapter03 Introduction to Thermodynamic Systems February 13, 2019 This chapter introduces the concept of thermo- Remark 1.1. In general, we will consider three kinds dynamic systems and digresses on the issue: How of exchange between S and Se through a (possibly ab- complex systems are related to Statistical Thermo- stract) membrane: dynamics. To do so, let us review the concepts of (1) Diathermal (Contrary: Adiabatic) membrane Equilibrium Thermodynamics from the conventional that allows exchange of thermal energy. viewpoint. Let U be the universe. Let a collection of objects (2) Deformable (Contrary: Rigid) membrane that S ⊆ U be defined as the system under certain restric- allows exchange of work done by volume forces tive conditions. The complement of S in U is called or surface forces. the exterior of S and is denoted as Se. (3) Permeable (Contrary: Impermeable) membrane that allows exchange of matter (e.g., in the form 1 Basic Definitions of molecules of chemical species). Definition 1.1. A system S is an idealized body that can be isolated from Se in the sense that changes in Se Definition 1.4. A thermodynamic state variable is a do not have any effects on S. macroscopic entity that is a characteristic of a system S. A thermodynamic state variable can be a scalar, Definition 1.2. A system S is called a thermody- a finite-dimensional vector, or a tensor. Examples: namic system if any possible exchange between S and temperature, or a strain tensor. Se is restricted to one or more of the following: (1) Any form of energy (e.g., thermal, electric, and magnetic) Definition 1.5. -
Applied Physics
Physics 1. What is Physics 2. Nature Science 3. Science 4. Scientific Method 5. Branches of Science 6. Branches of Physics Einstein Newton 7. Branches of Applied Physics Bardeen Feynmann 2016-03-05 What is Physics • Meaning of Physics (from Ancient Greek: φυσική (phusikḗ )) is knowledge of nature (from φύσις phúsis "nature"). • Physics is the natural science that involves the study of matter and its motion through space and time, along with related concepts such as energy and force. More broadly, it is the general analysis of nature, conducted in order to understand how the universe behaves. • Physics is one of the oldest academic disciplines, perhaps the oldest through its inclusion of astronomy. Over the last two millennia, physics was a part of natural philosophy along with chemistry, certain branches of mathematics, and biology, but during the scientific revolution in the 17th century, the natural sciences emerged as unique research programs in their own right. Physics intersects with many interdisciplinary areas of research, such as biophysics and quantum chemistry, and the boundaries of physics are not rigidly defined. • New ideas in physics often explain the fundamental mechanisms of other sciences, while opening new avenues of research in areas such as mathematics and philosophy. 2016-03-05 What is Physics • Physics also makes significant contributions through advances in new technologies that arise from theoretical breakthroughs. • For example, advances in the understanding of electromagnetism or nuclear physics led directly to the development of new products that have dramatically transformed modern-day society, such as television, computers, domestic appliances, and nuclear weapons; advances in thermodynamics led to the development of industrialization, and advances in mechanics inspired the development of calculus. -
Relativity in Classical Physics
PHYSICS IV COURSE TOPICS 1 - The Birth of Modern Physics 2 - Special Theory of Relativity 3 - The Experimental Basis of Quantum Physics 4 - Structure of the Atom 5 - Wave Properties of Matter 6 - Quantum Mechanics The Birth of Modern Physics Lecture 1 • The word physics is derived from the Latin word physica, which means «natural thing». • Physics is a branch of science that deals with the properties of matter and energy and the relationship between them. • The scope of physics is very wide and vast. It deals with not only the tinniest particles of atoms, but also natural phenomenon like the galaxy, the milky way, solar and lunar eclipses, and more. Branches of Physics • Classical physics • Modern physics • Nuclear physics This branch is mainly • Atomic physics • Geophysics concerned with the • Biophysics theory of relativity • Mechanics and • Acoustics quantum mechanics. • Optics • Thermodynamics • Astrophysics • The term modern physics generally refers to the study of those facts and theories developed in this century starting around 1900, that concern the ultimate structure and interactions of matter, space and time. • The three main branches of classical physics such as mechanics, heat and electromagnetism – were developed over a period of approximately two centuries prior to 1900. • Newton’s mechanics dealt succesfully with the motions of bodies of macroscopic size moving with low speeds. • This provided a foundation for many of the engineering accomplishments of the 18th and 19th centuries. • Between 1837 – 1901, there were many remarkable achievements occured in physics. • For example, the description and predictions of electromagnetism by Maxwell. Partly responsible for the rapid telecommunications of today.