Mining-Related Contamination of Surface Water and Sediments of The
Journal of Geochemical Exploration 112 (2012) 174–188 Contents lists available at SciVerse ScienceDirect Journal of Geochemical Exploration journal homepage: www.elsevier.com/locate/jgeoexp Mining-related contamination of surface water and sediments of the Kafue River drainage system in the Copperbelt district, Zambia: An example of a high neutralization capacity system Ondra Sracek a,b,⁎, Bohdan Kříbek c, Martin Mihaljevič d, Vladimír Majer c, František Veselovský c, Zbyněk Vencelides b, Imasiku Nyambe e a Department of Geology, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic b OPV s.r.o. (Protection of Groundwater Ltd), Bělohorská 31, 169 00 Praha 6, Czech Republic c Czech Geological Survey, Klárov 3, 118 21 Praha 1, Czech Republic d Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University, Albertov 6, 128 43 Praha 2, Czech Republic e Department of Geology, School of Mines, University of Zambia, P.O. Box 32 379, Lusaka, Zambia article info abstract Article history: Contamination of the Kafue River network in the Copperbelt, northern Zambia, was investigated using sam- Received 24 January 2011 pling and analyses of solid phases and water, speciation modeling, and multivariate statistics. Total metal Accepted 23 August 2011 contents in stream sediments show that the Kafue River and especially its tributaries downstream from the Available online 3 September 2011 main contamination sources are highly enriched with respect to Cu and exceed the Canadian limit for fresh- water sediments. Results of sequential analyses of stream sediments revealed that the amounts of Cu, Co and Keywords: Mn bound to extractable/carbonate, reducible (poorly crystalline Fe- and Mn oxides and hydroxides) and ox- Zambia fi Copperbelt idizable (organic matter and sul des) fractions are higher than in the residual (Aqua Regia) fraction.
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