GROUP TECHNOLOGY & RESEARCH – POSITION PAPER 2018 HYDROGEN AS AN ENERGY CARRIER An evaluation of emerging hydrogen value chains
SAFER, SMARTER, GREENER 2 Hydrogen as an energy carrier Table of contents 3
TABLE OF CONTENTS
1. EXECUTIVE SUMMARY 4
2. INTRODUCTION 6 2.1 Hydrogen value chains 7 2.2 Decarbonization context 10
3. HYDROGEN APPLICATIONS 12 3.1 Heating in buildings 12 3.2 Electricity valorization 15 3.3 Mobility 21 3.4 Industry 27
4. BUSINESS CASE FOR OFFSHORE HYDROGEN PRODUCTION 32 4.1 Concept descriptions 33 4.2 Assumptions 34 4.3 Results 38
5. UPTAKE IN 2030 AND 2050 40 Authors: Jørg Aarnes (lead author), Marcel Eijgelaar and Erik A. Hektor 5.1 2030 prognosis 40 5.2 2030—2050 scenarios 41 Contact details: [email protected] REFERENCES 48 Acknowledgements: We thank the following for contributing valuable insights: Ketil Aamnes, Sverre Alvik, Bent E. Bakken, Graham Bennett, Theo Bosma, Hendrik Brinks, Paul Gardner, Albert van den Noort, Ben Oudman, APPENDIX A: EXPLENERGY — ENERGY VALUE CHAIN EXPLORER 50 Frank Børre Pedersen, Pierre C. Sames, Bjørn-Johan Vartdal and Andrew R. Williams. APPENDIX B: 2050 SCENARIO ELEMENTS 54 In addition, we would like to thank Kathrine Ryengen and Nicola di Giulio from ZEG Power for providing data and insights. APPENDIX C: ABBREVIATIONS 58 4 Hydrogen as an energy carrier Executive summary 5
1. EXECUTIVE SUMMARY
Some 3% of global energy consumption today is used to produce hydrogen. Only 0.002% of BLUE HYDROGEN WILL IN MOST REGIONS HAVE A CHEAPER GREEN HYDROGEN AND FUELLING this hydrogen, about 1,000 tonnes per annum(i), is used as an energy carrier. Yet as this timely LOWER CARBON FOOTPRINT THAN HYDROGEN INFRASTRUCTURE WILL BOOST UPTAKE OF FROM ELECTROLYSIS FUEL-CELL ELECTRIC VEHICLES position paper from DNV GL indicates, hydrogen can become a major clean energy carrier in This assumes that the carbon footprint of the power We expect rapid decline in the cost of green(iv) a world struggling to limit global warming. for electrolysis is equal to the carbon footprint of hydrogen and continued development of refuelling the regional electricity mix(iii). However, large-scale infrastructure to trigger broader uptake of fuel-cell The company’s recently published 2018 Energy Transition Outlook(1) projects moderate uptake production of blue hydrogen, which is made from electric vehicles. The uptake of zero-emission fossil fuels with carbon capture and storage, vehicles will reduce carbon intensity per vehicle, of hydrogen in this role towards 2050, then significant growth towards 2100. Building on that, requires parallel development of large-scale CCS but the aggregated carbon emissions from road this position paper provides a more granular analysis of hydrogen as an energy carrier. infrastructure. This needs considering when transport will continue to rise to 2030 on growth designing policy measures to incentivize low-carbon in the overall vehicle stock. According to our hydrogen production. Energy Transition Outlook, most vehicles will be non-combustion models by 2050(1). We estimate that
DECARBONIZATION IS THE MAIN DRIVER FOR be adapted to hydrogen distribution and storage. WE FIND A POSITIVE BUSINESS CASE FOR more than 80% of H2 demand for mobility will then USING HYDROGEN AS AN ENERGY CARRIER This application requires substantial policy push OFFSHORE GAS REFORMING WITH CCS be for buses, trucks and other heavy vehicles. Hydrogen can be an effective decarbonization agent and public co-funding to materialize. We explore concepts for blue and green hydrogen if it is produced with a low carbon footprint. Such on an offshore platform. The variables include the HYDROGEN MAY ENABLE GREATER MARKET hydrogen can heat buildings, fuel transport, provide HYDROGEN USE FOR INDUSTRIAL FEEDSTOCK varying needs for power cables and pipelines/ PENETRATION OF RENEWABLES
heat to industry, and be a medium to valorize surplus WILL KEEP GROWING storage for hydrogen and/or CO2. We find a positive Surplus electricity from renewables can be valorized power from renewables(ii). Enabling and limiting We see demand for this application rising from about business case for offshore gas reforming with CCS; by electrolytic production of hydrogen. However, we factors for these applications include learning rates 55 Mtpa today(2) to 69–114 Mtpa in 2050. The iron this concept has higher net present value than a show that the cost of such hydrogen production can for technology, e.g. electrolysers and fuel cells; and steel industry may begin to use hydrogen in the corresponding onshore concept if the platform is be reduced widely by increasing operating hours regional natural gas consumption; development direct iron reduction steelmaking process. This may more than about 300 km from shore. We find further beyond those when surplus electricity is available. of hydrogen-distribution infrastructure, such as add 4–11 Mtpa of hydrogen consumption by 2050. that a business case for making hydrogen from Green hydrogen producers may therefore secure pipelines and fuelling stations; and, uptake of offshore wind requires a high hydrogen price. continuous supply of green electricity through, for carbon capture and storage (CCS). HYDROGEN WILL NOT SEE SUBSTANTIAL-SCALE The primary cost driver is the offshore wind farm. example, green certificates. USE FOR INDUSTRIAL PROCESS HEATING BY 2030 SEVERAL COUNTRIES MAY SEE HYDROGEN- We reach this conclusion because other ELECTROLYSIS CAN COMPETE ON COST AGAINST USING HYDROGEN FOR PEAK SHAVING IN HEATED BUILDINGS AS A GOOD decarbonization options are more mature and many GAS REFORMING WITH CCS IN 2030 ELECTRICITY SYSTEMS MAY BE VIABLE IN 2050 DECARBONIZATION OPTION are simpler. However, we expect hydrogen-fuelled This finding assumes significantly reduced capital This requires large-scale storage of hydrogen and Australia, Canada, the Netherlands, South Korea, UK heating to be established in industries such as costs for electrolysers and that they operate only hydrogen power generation systems that can be and US are the most likely to adopt this at significant cement and aluminium by 2050 in portfolios of when electricity prices are ‘low’, below a given deployed on-demand. However, the application has scale. These countries predominantly use gas for decarbonization measures. threshold, typically with some 3,000–5,000 annual significant energy losses; each MWh of output power heating buildings, and have infrastructure that can load hours. In this scenario, electrolysers operate requires 3 MWh input power to the electrolyser. This intermittently in step with fluctuating power prices, implies that the number of hours during a year when and hydrogen storage is available for matching hydrogen for peak shaving is cost effective is limited. supply and demand.
(i) Hydrogen is today used as an energy carrier only for mobility. According to h2tools.org/hyarc/hydrogen-consumption, there were about
10,000 active fuel-cell vehicles at end of Q3 2018, including 180 buses. Assuming an average fuel consumption of 100 kg hydrogen per (iii) Blue hydrogen will typically have a carbon footprint between 1 and 5 kgCO2e/kgH2 produced. This corresponds to hydrogen (3) vehicle per year, which may be a conservative assumption, this translates to 1,000 tonnes of hydrogen. production from electrolysis using electricity with 20–100 kgCO2e/MWh. According to the IEA World Energy Outlook 2013 , (ii) Here valorize means ‘creating value that could otherwise be lost’ insofar as hydrogen is a commodity that can be stored and sold, the carbon footprint of electricity production in 2011 was 532 kgCO2e/MWh globally and 345 kgCO2e/MWh in Europe.
whereas one alternative to hydrogen production is to curtail electricity generation output. (iv) Produced by electrolysis using an electricity mix with a low greenhouse gas footprint; for example, less than 100 kgCO2e/MWh. 6 Hydrogen as an energy carrier Introduction 7
The paper is organized as follows. Section 2.1 is compared with two related concepts for onshore intended to provide readers with an overview of production. Finally, in Section 5 we estimate the possible hydrogen value chain constellations. demand for hydrogen as an energy carrier in 2030, Section 2.2 describes the context for decarbonization and project the possible total demand for hydrogen through hydrogen. This section draws on the 2014 (as a feedstock and as an energy carrier) in 2050. Assessment Report by the Intergovernmental Panel on Climate Change (IPCC) on climate change mitigation(5) in order to describe the scale of the 2.1 Hydrogen value chains 2. INTRODUCTION decarbonization challenge for respective economic sectors. Next, in Section 3 we describe how Figure 1 provides an overview of options for hydrogen can contribute to decarbonization for production, transport and storage of hydrogen.
Hydrogen (H2) is, by any standard, a truly unique Hydrogen is already extensively used as a chemical the main application areas listed on page 6. Section The preferred option will depend on the application element. It is the lightest atomic element, was the feedstock in making products, principally for 4 contains a business case assessment for offshore (e.g. for mobility or as fuel for heating) and on first to be created after the Big Bang, represents an producing fertilizers and petrochemicals. According hydrogen production, where two concepts for regional circumstances such as existing infrastructure, estimated 75% of all mass in the universe, and has to the Hydrogen Council, the world currently producing hydrogen on an offshore platform are regional energy mix and national policy. the highest chemical energy content by mass consumes more than 55 Mtpa(2), of which some 95% (4) (4) of all gaseous and liquid fuels . It is therefore stem from fossil fuels . The bulk of this H2 is used for
unsurprising that H2 has been envisioned as having ammonia production (55%), in petroleum refining MAIN OPTIONS FOR PRODUCTION, TRANSPORT AND STORAGE OF HYDROGEN a prominent role in a future energy system. As far (25%), and for methanol production (10%). The
back as 1874, the author Jules Verne had a character energy required to produce 55 Mtpa H2 represents in his novel The Mysterious Island declare: “I believe about 3% of the global energy demand. Hydrogen HYDROGEN PRODUCTION OPTIONS that water will one day be employed as fuel, that production is therefore a large and thriving industry. hydrogen and oxygen which constitute it, used SOURCE o er a er a ra gas oa io ass singly or together, will furnish an inexhaustible Hydrogen as an energy carrier source of heat and light, of an intensity of which Today, we are witnessing a revival of interest around coal is not capable.” prospective uses of hydrogen as an energy carrier, in HYDROGEN Gasification or which it is used as a fuel rather than as a feedstock. ec ro ysis e or ing Gasification PRODUCTION iogas re or ing This may be attributed mainly to the potential role HYDROGEN: THE CRUX OF THE DEBATE of hydrogen in global efforts to decarbonize. The main question addressed in this position paper is for DECARBONIZATION o car on ar on ca re ar on ca re one ne ra On Earth, hydrogen is found only as part of a which applications, and under what circumstances, MEASURE e ec rici y and s orage and s orage nega i e compound, most commonly in the form of water can hydrogen emerge as a major energy carrier? To but also in, for instance, hydrocarbons such as answer this, we focus on the cost effectiveness of TRANSPORTATION STATE OF TRANSPORT STORAGE methane, gasoline and coal. decarbonization through using H2 as a fuel; i.e. we OPTIONS AND STORAGE OPTIONS ask when a fuel switch to H2 can be competitive To enable water to be part of Jules Verne’s energy with alternative decarbonization options. The main s r ace gas i e ine utopia, hydrogen must temporarily be released applications considered are: s orage from its bond with oxygen. Similarly, it can be extracted from hydrocarbons through its separation ■■Hydrogen as fuel for mobility; o ressed o ressed from carbon, e.g. in the form of coal or natural gas. ■■Hydrogen for heating in buildings; r c ■■Hydrogen for decarbonization of ydrogen ydrogen an s This separation process requires energy, and the industrial processes; and, energy content of the output hydrogen is always ■■Hydrogen for valorization of excess electricity i e ine i less than the energy content of the input fuel, plus from variable renewable power. in ras r c re the energy required for the hydrogen separation. This paper aims to raise understanding of the
Furthermore, hydrogen is generally more energy benefits and disadvantages of 2H for these ryogenic i id i id ydrogen intensive to store and transport than other applications, describe the circumstances required ydrogen an s conventional fuels. This implies that the value of for them to materialize, and to provide a basis for hydrogen in pure form to users or to society at analysing the scale of uptake. Accordingly, we have large must be sufficient to justify the energy losses also developed ExplEnergy, a web application for ai arge onia onia an s in its production, distribution and use. economic assessment of energy value chains.
This App can estimate the cost of various H2 This is the crux of the debate over hydrogen. production paths and associated transport and i id organic i id ydrocar on storage options. Appendix A provides a brief ydrogen carrier an s introduction to ExplEnergy. Figure 1: Overview of main options for production, transport and storage of hydrogen. Source: DNV GL 8 Hydrogen as an energy carrier Introduction 9
2.1.1 Production 2.1.2 Transport and storage Ammonia and liquid organic hydrogen carrier (LOHC) Ammonia has a higher energy density per volume Hydrogen can be produced in several ways, as shown in Figure 1. However, the primary driver for uptake of Hydrogen can be transported and stored in pure than liquid hydrogen, and can be stored and hydrogen as an energy carrier is decarbonization. This implies that emphasis will be placed on producing form or as an intermediate energy carrier that can transported as a liquid at low pressures or in
hydrogen in ways that allow hydrogen value chains to have a lower carbon footprint than alternative be charged and de-charged with H2, processes cryogenic tanks at around -33°C at 1 bar. This implies competing energy value chains, including alternative hydrogen value chains. referred to as hydrogenation and dehydrogenation that ammonia can be transported at low cost by respectively. Figure 1 on page 7 displays four pipelines, ships, trucks and other bulk modes. Hydrogen produced by gas reforming without carbon capture and storage (CCS), the most common method alternative states: The caveat is that the ammonia synthesis and its
today, has a carbon footprint of about 10–12 kgCO2e per kg hydrogen. Hydrogen can be produced from subsequent dehydrogenation to release hydrogen
electrolysis with a lower carbon footprint if the electricity used has a carbon footprint less than 250 kgCO2e/ ■■Liquid (cryogenic) hydrogen require significant energy. Hydrogenation and MWh, roughly 55% of the emission intensity of a modern combined cycle natural gas-fired power plant(6). ■■Ammonia dehydrogenation of a LOHC, such as toluene, ■■Hydrogenated liquid organic hydrogen carrier requires less energy, but the gravimetric density ■■Compressed gaseous hydrogen. of the hydrogen that can be extracted from the hydrogenated liquid (methylcyclohexane for the GREEN AND BLUE HYDROGEN The preferred or lowest-cost option for transport LOHC toluene) is 50%–70% lower than the and storage will depend on the state. gravimetric hydrogen density of ammonia.
Hydrogen produced by electrolysis or from biomass with emissions less than 8 kgCO2e /kgH2, based on a lifecycle analysis, will henceforth be called green hydrogen(i) in this paper. This can be explored by using the ExplEnergy web Pipeline hydrogen gas application described in Appendix A, which also sets Pipeline transport of compressed gaseous hydrogen We use blue hydrogen to refer to that produced from fossil fuels with CCS. Hydrogen produced from out some example comparisons. is in general the most cost-effective way of transporting
fossil fuels with CO2 capture, where the CO2 is used for enhancing oil recovery, does not qualify large volumes of it over long distances. This can as blue hydrogen. Liquid hydrogen be done in pure form, or blended into natural gas For instance, while liquid hydrogen has a higher in gas pipelines, up to limits prescribed by the Production of blue hydrogen is less modular than for green hydrogen, represents a major investment, energy density than compressed hydrogen, more relevant regulations or imposed by contract or other and has longer lead times than green hydrogen production. In addition to building the hydrogen energy is required to liquefy hydrogen than for restrictions. Small volumes, such as those required
production and CO2-capture facility, blue hydrogen production requires a permit for injection and compressing it to relevant pressures. today at hydrogen fuelling stations, would generally
storage of CO2 into a qualified site for geological storage of CO2. Getting this permit can take 3–10 years, be most cost-effectively transported in bulk by truck. depending on site characteristics. It is therefore likely that investments into large-scale blue hydrogen Furthermore, liquid hydrogen has different safety production towards 2030 will be made only as part of government-supported initiatives. characteristics than compressed gaseous hydrogen. These considerations, along with those regarding For example, a leak into open air from compressed selection of production method, show that the hydrogen tanks will rise due to buoyancy, and will lowest cost or preferred value chain depends on the generally dissipate quickly. In contrast, a leak of application and context. No single solution would Hydrogen production method will depend In contrast, we expect that hydrogen used for liquid hydrogen into open air will freeze the be equally applicable in all circumstances. This is the on application transport before 2030 will predominantly be green surrounding air, become a heavy gas, and may rationale for developing the ExplEnergy web We argue further that the preferred production hydrogen. This is due to several factors, including accumulate on the ground for some time. This is application, which allows users to configure and method for a given application will depend greater consumer pressure for a non-fossil hydrogen relevant when, for instance, transporting hydrogen compare alternative energy value chains under
on context. source and the capability to develop on-site H2 either by ship or truck, or when storing it in tanks. circumstances relevant to the case being considered. production by electrolysis, thereby avoiding the For instance, we argue that hydrogen used for need for its transport. heating in buildings will predominantly be blue hydrogen for two reasons: Fuelling stations will seek to secure certified green hydrogen. This will, in turn, make producers certify
■■The main driver for this application is that the H2 is produced from renewables. This can be decarbonization of gas-based heating. achieved through power purchase agreements or the A gas infrastructure that can be repurposed or purchase of green electricity certificates, for example. upgraded for hydrogen will therefore often exist where this application is relevant. ■■Electric heating is much more efficient than the power-to-hydrogen-to-heat value chain, particularly if heat pumps are used. This implies that it would generally be much cheaper to use electric heating rather than hydrogen produced from electricity.
(i) This is in accordance with TÜV SÜD Standard CMS 70 (Version 12/2011) — Generation of green hydrogen, which states that “A certificate for green hydrogen can be issued if the greenhouse gas reduction potential is at least 35% compared to fossil fuels or conventionally produced hydrogen”. 10 Hydrogen as an energy carrier Introduction 11
2.2 Decarbonization context renewable energy sources, nuclear, or gas- or When used as an energy carrier, hydrogen can ■■Power generation: coal-fired power with CCS. support decarbonization of buildings, transport, - Decarbonize electricity generation source, e.g. Figure 2 shows carbon emissions for 2010 by industry and power generation, provided that the by replacing a fossil fuel-fired plant with turbines (i) economic sector . The current production of It can be noted that CCS on industrial-scale production, storage and distribution of hydrogen fired by 2H , or by H2 fuel-cell systems. hydrogen represents approximately 0.5 Gt of direct hydrogen production has been demonstrated. Two comes with a low carbon footprint. The principal - Pave the way for greater penetration of carbon emissions (not including indirect emissions large-scale projects — Air Products’ steam methane means to achieve this are: renewables by providing an effective way of from electricity consumption, or upstream emissions reforming (SMR) plants at Port Arthur, Texas, US, valorizing (and storing) surplus power from from production of fossil fuels). This represents about and Shell’s oilsands upgrader in Scotford, Alberta, ■■Buildings: Replace natural gas used for heating variable renewables, i.e. excess electricity during 5% of total direct industry carbon emissions. Canada — and one demonstration project in Japan (boilers, gas fires and cookers) with hydrogen. periods when production output from variable are currently in operation. ■■Transport: Replace internal combustion engines renewables alone exceeds demand. These emissions can be reduced by capturing with fuel cells and electric drivetrains(ii).
and storing the direct emissions from the hydrogen The scale and cost advantage of H2 production from ■■Industry: Replace fossil fuel for medium and high Section 3 will discuss and analyse the circumstances production unit, or through fuel switching, i.e. by fossil fuels today suggest that a major fraction of heat production (by combustion) with hydrogen. required for each of these applications to scale. replacing the fossil feedstock with biomass, or by hydrogen production will continue to be produced producing hydrogen from water and electricity (by from fossil fuels in the near term, requiring CCS to electrolysis), where the electricity comes from achieve decarbonization.
GREENHOUSE GAS EMISSIONS IN 2010 BY ECONOMIC SECTOR