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Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries
Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries. Peter Jentsch Extension Associate Department of Entomology Cornell University's Hudson Valley Lab 3357 Rt. 9W; PO box 727 Highland, NY 12528 email: [email protected] Phone 845-691-7151 Mobile: 845-417-7465 http://www.nysaes.cornell.edu/ent/faculty/jentsch/ 2 Historical Perspectives on Fruit Production: Fruit Tree Pest Management, Regulation and New Chemistries. by Peter Jentsch I. Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 Synthetic Pesticide Development and Use II. Influences Changing the Pest Management Profile in Apple Production Chemical Residues in Early Insect Management Historical Chemical Regulation Recent Regulation Developments Changing Pest Management Food Quality Protection Act of 1996 The Science Behind The Methodology Pesticide Revisions – Requirements For New Registrations III. Resistance of Insect Pests to Insecticides Resistance Pest Management Strategies IV. Reduced Risk Chemistries: New Modes of Action and the Insecticide Treadmill Fermentation Microbial Products Bt’s, Abamectins, Spinosads Juvenile Hormone Analogs Formamidines, Juvenile Hormone Analogs And Mimics Insect Growth Regulators Azadirachtin, Thiadiazine Neonicotinyls Major Reduced Risk Materials: Carboxamides, Carboxylic Acid Esters, Granulosis Viruses, Diphenyloxazolines, Insecticidal Soaps, Benzoyl Urea Growth Regulators, Tetronic Acids, Oxadiazenes , Particle Films, Phenoxypyrazoles, Pyridazinones, Spinosads, Tetrazines , Organotins, Quinolines. 3 I Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 The apple has a rather ominous origin. Its inception is framed in the biblical text regarding the genesis of mankind. The backdrop appears to be the turbulent setting of what many scholars believe to be present day Iraq. -
Multi-Residue Method I for Agricultural Chemicals by LC-MS (Agricultural Products)
Multi-residue Method I for Agricultural Chemicals by LC-MS (Agricultural Products) 1. Analytes See Table 2 or 3. 2. Instruments Liquid chromatograph-mass spectrometer (LC-MS) Liquid chromatograph-tandem mass spectrometer (LC-MS/MS) 3. Reagents Use the reagents listed in Section 3 of the General Rules except for the following. 0.5 mol/L Phosphate buffer (pH 7.0): Weigh 52.7 g of dipotassium hydrogenphosphate (K2HPO4) and 30.2 g of potassium dihydrogenphosphate (KH2PO4), dissolve in about 500 mL of water, adjust the pH to 7.0 with 1 mol/L sodium hydroxide or 1 mol/L hydrochloric acid, and add water to make a 1 L solution. Reference standards of agricultural chemicals: Reference standards of known purities for each agricultural chemical. 4. Procedure 1) Extraction i) Grains, beans, nuts and seeds Add 20 mL of water to 10.0 g of sample and let stand for 15 minutes. Add 50 mL of acetonitrile, homogenize, and filter with suction. Add 20 mL of acetonitrile to the residue on the filter paper, homogenize, and filter with suction. Combine the resulting filtrates, and add acetonitrile to make exactly 100 mL. Take a 20 mL aliquot of the extract, add 10 g of sodium chloride and 20 mL of 0.5 mol/L phosphate buffer (pH 7.0), and shake for 10 minutes. Let stand, and discard the separated aqueous layer. Add 10 mL of acetonitrile to an octadecylsilanized silica gel cartridge (1,000 mg) and discard the effluent. Transfer the acetonitrile layer to the cartridge, elute with 2 mL of acetonitrile, collect the total eluates, dehydrate with anhydrous sodium sulfate, and filter out the anhydrous sodium sulfate. -
Genetically Modified Baculoviruses for Pest
INSECT CONTROL BIOLOGICAL AND SYNTHETIC AGENTS This page intentionally left blank INSECT CONTROL BIOLOGICAL AND SYNTHETIC AGENTS EDITED BY LAWRENCE I. GILBERT SARJEET S. GILL Amsterdam • Boston • Heidelberg • London • New York • Oxford Paris • San Diego • San Francisco • Singapore • Sydney • Tokyo Academic Press is an imprint of Elsevier Academic Press, 32 Jamestown Road, London, NW1 7BU, UK 30 Corporate Drive, Suite 400, Burlington, MA 01803, USA 525 B Street, Suite 1800, San Diego, CA 92101-4495, USA ª 2010 Elsevier B.V. All rights reserved The chapters first appeared in Comprehensive Molecular Insect Science, edited by Lawrence I. Gilbert, Kostas Iatrou, and Sarjeet S. Gill (Elsevier, B.V. 2005). All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publishers. Permissions may be sought directly from Elsevier’s Rights Department in Oxford, UK: phone (þ44) 1865 843830, fax (þ44) 1865 853333, e-mail [email protected]. Requests may also be completed on-line via the homepage (http://www.elsevier.com/locate/permissions). Library of Congress Cataloging-in-Publication Data Insect control : biological and synthetic agents / editors-in-chief: Lawrence I. Gilbert, Sarjeet S. Gill. – 1st ed. p. cm. Includes bibliographical references and index. ISBN 978-0-12-381449-4 (alk. paper) 1. Insect pests–Control. 2. Insecticides. I. Gilbert, Lawrence I. (Lawrence Irwin), 1929- II. Gill, Sarjeet S. SB931.I42 2010 632’.7–dc22 2010010547 A catalogue record for this book is available from the British Library ISBN 978-0-12-381449-4 Cover Images: (Top Left) Important pest insect targeted by neonicotinoid insecticides: Sweet-potato whitefly, Bemisia tabaci; (Top Right) Control (bottom) and tebufenozide intoxicated by ingestion (top) larvae of the white tussock moth, from Chapter 4; (Bottom) Mode of action of Cry1A toxins, from Addendum A7. -
Pesticide Action Networknews
30th Anniversary Edition Pesticide Action Network NEWS Advancing alternatives to pesticides worldwide • www.panna.org Year-end 2012 Cultivating the roots of health and justice Pesticide Action Network: The First 30 Years By 1982, the luster of industrial agriculture—the so-called “Green Revolution”—had faded in developing countries. The promised dramatic increases in yields from “miracle” hybrid grains that required high inputs of water, chemical fertilizers and pesticides failed to deliver and were revealed as campaigns to sell technology to people who couldn’t afford it. Local communities were losing control over their own food systems, and women and children shouldered more of the fieldwork—and bore the brunt of pesticide exposure. The global pesticide trade was, however, yielding dramatic profits for chemical companies as more and more farmers were trapped on a pesticide treadmill. That was the world when PAN was founded. In the years since, the world community has reassessed. When rice farming was collapsing in the 1980s due to pest resurgence from resistance to pesticides, Indonesia needed alternatives. A com- ifty years after Silent Spring and 30 years bination of community-scale peer-learning projects recaptured Fafter PAN’s founding, our struggle for health Indigenous farming knowledge and wove it into new ecological pest management. “Farmer Field Schools”—today adapted to and justice remains vital and more urgent than local needs in many countries—returned bountiful crops of rice ever. Challenging the global proliferation of while expenditures on agrichemicals were slashed. By 2002, more pesticides is about challenging corporate control, than a million Indonesian farmers had participated in field schools that became models for localized sustainable agriculture in other ensuring scientific integrity and defending basic countries. -
Complaint for Declaratory and Injunctive Relief 1 1 2 3 4 5 6 7 8 9
1 Justin Augustine (CA Bar No. 235561) Jaclyn Lopez (CA Bar No. 258589) 2 Center for Biological Diversity 351 California Street, Suite 600 3 San Francisco, CA 94104 Tel: (415) 436-9682 4 Fax: (415) 436-9683 [email protected] 5 [email protected] 6 Collette L. Adkins Giese (MN Bar No. 035059X)* Center for Biological Diversity 8640 Coral Sea Street Northeast 7 Minneapolis, MN 55449-5600 Tel: (651) 955-3821 8 Fax: (415) 436-9683 [email protected] 9 Michael W. Graf (CA Bar No. 136172) 10 Law Offices 227 Behrens Street 11 El Cerrito, CA 94530 Tel: (510) 525-7222 12 Fax: (510) 525-1208 [email protected] 13 Attorneys for Plaintiffs Center for Biological Diversity and 14 Pesticide Action Network North America *Seeking admission pro hac vice 15 16 IN THE UNITED STATES DISTRICT COURT 17 FOR THE NORTHERN DISTRICT OF CALIFORNIA 18 SAN FRANCISCO DIVISION 19 20 CENTER FOR BIOLOGICAL ) 21 DIVERSITY, a non-profit organization; and ) Case No.__________________ PESTICIDE ACTION NETWORK ) 22 NORTH AMERICA, a non-profit ) organization; ) 23 ) Plaintiffs, ) COMPLAINT FOR DECLARATORY 24 ) AND INJUNCTIVE RELIEF v. ) 25 ) ENVIRONMENTAL PROTECTION ) 26 AGENCY; and LISA JACKSON, ) Administrator, U.S. EPA; ) 27 ) Defendants. ) 28 _____________________________________ ) Complaint for Declaratory and Injunctive Relief 1 1 INTRODUCTION 2 1. This action challenges the failure of Defendants Environmental Protection Agency and 3 Lisa Jackson, Environmental Protection Agency Administrator, (collectively “EPA”) to consult with the 4 United States Fish and Wildlife Service (“FWS”) and National Marine Fisheries Service (“NMFS”) 5 (collectively “Service”) pursuant to Section 7(a)(2) of the Endangered Species Act (“ESA”), 16 U.S.C. -
New Applications of Silafluofen to Termite Control
IRG/WP 01-30274 THE INTERNATIONAL RESEARCH GROUP ON WOOD PRESERVATION Section 3 Wood Protecting Chemicals NEW APPLICATIONS OF SILAFLUOFEN TO TERMITE CONTROL Koji Nakayama, Yoshihiro Minamite, Shinobu Koike and Yoshio Katsuda Dainihon Jochugiku Co., Ltd., 1-11, 1-Chome Daikoku-cho, Toyonaka, Osaka 561-0827, Japan Koichi Nishimoto, Professor em., Kyoto University Japan Wood Preserving Association, 2-5, 4-Chome Toranomon, Minato-ku, Tokyo 105-0001, Japan Paper prepared for the 32nd Annual Meeting Nara, Japan May 20-25th, 2001 IRG Secretariat c/o KTH SE-100 44 Stockholm Sweden NEW APPLICATIONS OF SILAFLUOFEN TO TERMITE CONTROL Koji Nakayama, Yoshihiro Minamite, Shinobu Koike, Yoshio Katsuda, K Nishimoto ABSTRACT Silafluofen-based termiticides are widely used for soil and timber treatments in Japan, as silafluofen possesses advantageous properties of low fish toxicity and high chemical stability (to light, in soil, in alkaline environments, etc) in addition to high termiticidal activity and low mammalian toxicity. As new applications of silafluofen to termite control, we have developed another type of products in the forms of practical anti-termitic plastic sheets and anti-termitic plastic heat insulators which are free from the exposure risk of termite control operators and inhabitants to the sprayed chemical. Anti-termitic plastic sheets containing silafluofen in ethylene vinylacetate copolymer film have already been put into practical use, showing a high anti-termitic effect. Plastic heat insulators made of such materials as polystylene and polyurethane have the problem of the decrease in their insulating effect due to termite damage, although they have been widely used as building materials. To solve this problem, we prepared anti-termitic plastic heat insulators by impregnating silafluofen at concentrations of 0.1 ~0.3 % into plastic foam. -
Sound Management of Pesticides and Diagnosis and Treatment Of
* Revision of the“IPCS - Multilevel Course on the Safe Use of Pesticides and on the Diagnosis and Treatment of Presticide Poisoning, 1994” © World Health Organization 2006 All rights reserved. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. Dotted lines on maps represent approximate border lines for which there may not yet be full agreement. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. All reasonable precautions have been taken by the World Health Organization to verify the information contained in this publication. However, the published material is being distributed without warranty of any kind, either expressed or implied. The responsibility for the interpretation and use of the material lies with the reader. In no event shall the World Health Organization be liable for damages arising from its use. CONTENTS Preface Acknowledgement Part I. Overview 1. Introduction 1.1 Background 1.2 Objectives 2. Overview of the resource tool 2.1 Moduledescription 2.2 Training levels 2.3 Visual aids 2.4 Informationsources 3. Using the resource tool 3.1 Introduction 3.2 Training trainers 3.2.1 Organizational aspects 3.2.2 Coordinator’s preparation 3.2.3 Selection of participants 3.2.4 Before training trainers 3.2.5 Specimen module 3.3 Trainers 3.3.1 Trainer preparation 3.3.2 Selection of participants 3.3.3 Organizational aspects 3.3.4 Before a course 4. -
Determination of Selected Priority Pesticides in High Water Fruits and Vegetables by Modified Quechers and GC-ECD with GC-MS/MS Confirmation
molecules Article Determination of Selected Priority Pesticides in High Water Fruits and Vegetables by Modified QuEChERS and GC-ECD with GC-MS/MS Confirmation Maciej Tankiewicz Department of Environmental Toxicology, Faculty of Health Sciences with Subfaculty of Nursing and Institute of Maritime and Tropical Medicine, Medical University of Gda´nsk,D˛ebowaStr. 23A, 80-204 Gda´nsk,Poland; [email protected]; Tel.: +48-58-349-1937 Received: 21 December 2018; Accepted: 23 January 2019; Published: 24 January 2019 Abstract: A modified quick, easy, cheap, efficient, rugged and safe (QuEChERS) method coupled to gas chromatography with electron capture detector (GC-ECD) was developed for simultaneous determination of selected electronegative pesticides in fruits and vegetables with high water content. The chosen compounds are commonly detected in fruit and vegetable crops, and some of their metabolites have even been found in human urine. In addition, some of them are known or suspected carcinogens according to the International Agency for Research of Cancer. Extraction and clean up parameters were optimized, thus the original QuEChERS method was modified to decrease solvent usage, in accordance with ‘green chemistry’ principles. The proposed methodology was validated in terms of selectivity, specificity, linearity, precision and accuracy. The obtained limits of detection (LODs) for all investigated pesticides ranged from 5.6 µg·kg−1 to 15 µg·kg−1 and limits of quantification (LOQs) from 17 µg·kg−1 to 45 µg·kg−1. The obtained data demonstrated the good reproducibility and stability of the procedure in the tested concentration range up to 10 mg·kg−1, with relative standard deviations (RSDs) lower than 10%. -
Laboratory Test Report
Aromatic Plant Research Center 230 N 1200 E STE 100 Lehi, UT 84043 www.aromaticplant.org Laboratory Test Report SAMPLE NAME : Cypress CLIENT NAME : ACHS CLIENT LOT # : 36186C Column: ZB5 (60 m length × 0.25 mm inner diameter × 0.25 μm film thickness) Instrument: Shimadzu GCMS-QP2010 Ultra Carrier gas: Helium 80 psi Temperature ramp: 2 degrees Celsius per minute up to 260-degree Celsius Split ratio: 30:1 Sample preparation: 5% w/v solution with Dichloromethane Interpretation on sample: This analysis of Cypress essential oil meets the standard chemical profile of Cupressus sempervirens essential oil. Analyzed by: Dr. Prabodh Satyal Reviewed by: Ambika Poudel Issued Date: 9/25/2020 Copyright © 2020 by Aromatic Plant Research Center (APRC). All rights reserved. The information contained in this document may not be used, published or redistributed, including online, without the prior written consent of APRC. 1 / 4 24,426,457 Chromatogram Injection Volume Lot# Client Name Sample Name Sample Type Analyzed Analyzed by Sample Information www.aromaticplant.org UT Lehi, 84043 100 STE 230N E 1200 Center Aromatic Plant Research 10.856 Copyright © 2020 by Aromatic Plant Research Center (APRC). All rights reserved. Copyright information The All (APRC). rights reserved. this document contained in Center may © 2020by Aromatic Plantnot be used, published Research or 11.74611.898 13.37013.18113.088 12.429 14.335 14.41714.716 15.343 16.015 16.405 16.628 17.032 17.18317.501 18.00417.910 17.812 20.0 18.866 19.30119.646 21.153 21.744 21.445 22.392 : : : 0.30 : : : : ACHS Cy Esse 9/25/2020 7:12:23 AM AM 7:12:23 9/25/2020 Dr. -
Development of Silafluofen-Based Termiticides in Japan and Thailand
Insects 2011, 2, 532-539; doi:10.3390/insects2040532 OPEN ACCESS insects ISSN 2075-4450 www.mdpi.com/journal/insects/ Review Development of Silafluofen-Based Termiticides in Japan and Thailand Yoshio Katsuda 1, Yoshihiro Minamite 1,* and Charunee Vongkaluang 2 1 Dainihon Jochugiku Co., Ltd., 1-11, 1-Chome, Daikoku-cho, Toyonaka, Osaka 561-0827, Japan; E-Mail: [email protected] 2 Royal Forest Department, Bangkok 10900, Thailand; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +81-6-6334-0001; Fax: +81-6-6334-0004. Received: 3 October 2011; in revised form: 29 October 2011 / Accepted: 30 November 2011 / Published: 8 December 2011 Abstract: With the advancement from natural pyrethrins to synthetic pyrethroids, their applications have expanded from household insecticides for indoor use against sanitary pests to outdoor use for agriculture, forestry, animal health, termite control, and many other pest situations. However, high fish toxicity and development of pyrethroid resistance in some pests have been cited as common shortcomings of pyrethroids. To overcome these pyrethroid problems such as high fish toxicity, Katsuda and fellow scientists invented silafluofen by introducing a silicone atom into the pyrethroidal chemical structure in 1984. In addition to the high insecticidal activity and low mammalian toxicity, this compound features low fish toxicity, chemical stability under sunlight, in the soil and under alkaline environments. These features make silafluofen unique among pyrethroids. In Japan, silafluofen has been used as an agricultural insecticide for 15 years since 1995 for various plants, especially useful for paddy rice protection because of its low fish toxicity. -
Pesticide Action Network Europe
PESTICIDE ACTION NETWORK EUROPE PESTICIDE TAXATION IPM CAMPAIGN VOICES OF PESTICIDES BEES PESTICIDE FREE TOWNS SUPD GLYPHOSATE DEVELOP- MENTS COURT CASES ENDOCRINE DISRUPTORS AGRI- HUMAN CULTURE HEALTH POLICY NATURE VOICES 2015PAN TOWNS EUROPE ACTIVITY REPORT WHO WE ARE 3 WHAT WE DO 5 PAN EUROPE & THE SUSTAINABLE USE DIRECTIVE 9 INTEGRATED PEST MANAGEMENT 11 PESTICIDE FREE TOWNs 13 BEEs 15 ENDOCRINE DISRUPTING CHEMICALs 17 FURTHER THREATS (GLYPHOSATE, ETC.) 19 COURT CASEs 21 VAT & PESTICIDE TAXATION 23 PESTICIDE SALE 2011-2013 – BASELINE YEAR 2011=100 TONS OF PESTICIDES SOLD IN 2011–2013 WHO WE ARE Pesticide Action Network (PAN) was founded in 1982 and is a network of over 600 non- governmental organisations, institutions and individuals in over 60 countries worldwide working to minimise the negative effects and replace the use of harmful pesticides with eco- logically sound alternatives. Its projects and campaigns are coordinated by five autonomous Regional Centres. PAN Europe is the regional centre in Europe. Located in Brussels, it was founded in 1987 and brings together 34 consumer, public health, and environmental organisations, trades unions, women’s groups and farmer associations from across 21 European countries. PAN Europe’s vision is of a world in which high agricultural productivity is achieved by truly sustainable agricultural production systems in which agrochemical inputs and environmental damage are minimised, and where local people control local production using local varieties. WHY THE FIGHT ON PESTICIDES IS IMPORTANT All of us are exposed directly or indirectly to pesticides and other agrochemicals- farm workers and their families most of all, but every consumer will be exposed to dozens of different pesti- cides every day through food and the environment. -
Acknowledgements
Acknowledgements We would like to thank those involved in creating Planning a Drift Catcher Project and Organizing a Drift Campaign, including: Jeff Conant from the Hesperian Foundation; Mateo Rutherford and Roy Rojas of BITTS for translation; Brenda J. Willoughby (Pesticide Action Network North America) for layout; and contributors Andrea Wilson and Tracey Brieger (Californians for Pesticide Reform) and Katherine Mills, Susan Kegley, Tanya Brown, Kelly Campbell and Christine Riordan (Pesticide Action Network North America). Major funding for this guide and development of the Drift Catcher was provided by the Cedar Tree Foundation. Additional support was provided by grants to Pesticide Action Network North America and/or Californians for Pesticide Reform by the Beldon Fund, The California Endowment, The California Wellness Foundation, Columbia Foundation, Nathan Cummings Foundation, David B. Gold Foundation, Richard and Rhoda Goldman Foundation, Clarence E. Heller Charitable Foundation, David H. Klein, Jr. Foundation and John Merck Fund. The authors bear responsibility for any factual errors. Recommendations and views expressed are those of Pesticide Action Network North America, and do not necessarily represent the views of our funders and supporters. © 2012 by Pesticide Action Network North America. Permission is granted to reproduce portions of this report, provided the title and publishing organizations—Pesticide Action Network and Californians for Pesticide Reform—are acknowledged. Our sincerest thanks to the Hesperian Foundation for providing many of the images used in these materials. Copyright © 2003 by the Hesperian Foundation. The Hesperian Foundation encourages others to copy, reproduce, or adapt to meet local needs any or all of this pamphlet provided that what is reproduced is distributed free or at cost—not for profit.