It's Elemental! Sampling from the Periodic Table
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The Important Role of Dysprosium in Modern Permanent Magnets
The Important Role of Dysprosium in Modern Permanent Magnets Introduction Dysprosium is one of a group of elements called the Rare Earths. Rare earth elements consist of the Lanthanide series of 15 elements plus yttrium and scandium. Yttrium and scandium are included because of similar chemical behavior. The rare earths are divided into light and heavy based on atomic weight and the unique chemical and magnetic properties of each of these categories. Dysprosium (Figure 1) is considered a heavy rare earth element (HREE). One of the more important uses for dysprosium is in neodymium‐iron‐ boron (Neo) permanent magnets to improve the magnets’ resistance to demagnetization, and by extension, its high temperature performance. Neo magnets have become essential for a wide range of consumer, transportation, power generation, defense, aerospace, medical, industrial and other products. Along with terbium (Tb), Dysprosium (Dy) Figure 1: Dysprosium Metal(1) is also used in magnetostrictive devices, but by far the greater usage is in permanent magnets. The demand for Dy has been outstripping its supply. An effect of this continuing shortage is likely to be a slowing of the commercial rollout or a redesigning of a number of Clean Energy applications, including electric traction drives for vehicles and permanent magnet generators for wind turbines. The shortage and associated high prices are also upsetting the market for commercial and industrial motors and products made using them. Background Among the many figures of merit for permanent magnets two are of great importance regarding use of Dy. One key characteristic of a permanent magnet is its resistance to demagnetization, which is quantified by the value of Intrinsic Coercivity (HcJ or Hci). -
Treatment Outcome Following Use of the Erbium, Chromium:Yttrium
Treatment outcome following use IN BRIEF • Highlights that successful treatment RESEARCH of peri-implantitis is unpredictable and of the erbium, chromium:yttrium, usually involves the need for surgery. • Outlines a minimalistic treatment approach for peri-implantitis with promising results after six months. scandium, gallium, garnet laser • Suggests that the protocol described may be of use in a pilot study or controlled in the non-surgical management clinical trial. of peri-implantitis: a case series R. Al-Falaki,*1 M. Cronshaw2 and F. J. Hughes3 VERIFIABLE CPD PAPER Aim To date there is no consensus on the appropriate usage of lasers in the management of peri-implantitis. Our aim was to conduct a retrospective clinical analysis of a case series of implants treated using an erbium, chromium:yttrium, scandium, gallium, garnet laser. Materials and methods Twenty-eight implants with peri-implantitis in 11 patients were treated with an Er,Cr:YSGG laser (68 sites >4 mm), using a 14 mm, 500 μm diameter, 60º (85%) radial firing tip (1.5 W, 30 Hz, short (140 μs) pulse, 50 mJ/pulse, 50% water, 40% air). Probing depths were recorded at baseline after 2 months and 6 months, along with the presence of bleeding on probing. Results The age range was 27-69 years (mean 55.9); mean pocket depth at baseline was 6.64 ± SD 1.48 mm (range 5-12 mm),with a mean residual depth of 3.29 ± 1.02 mm (range 1-6 mm) after 2 months, and 2.97 ± 0.7 mm (range 1-9 mm) at 6 months. -
Evolution and Understanding of the D-Block Elements in the Periodic Table Cite This: Dalton Trans., 2019, 48, 9408 Edwin C
Dalton Transactions View Article Online PERSPECTIVE View Journal | View Issue Evolution and understanding of the d-block elements in the periodic table Cite this: Dalton Trans., 2019, 48, 9408 Edwin C. Constable Received 20th February 2019, The d-block elements have played an essential role in the development of our present understanding of Accepted 6th March 2019 chemistry and in the evolution of the periodic table. On the occasion of the sesquicentenniel of the dis- DOI: 10.1039/c9dt00765b covery of the periodic table by Mendeleev, it is appropriate to look at how these metals have influenced rsc.li/dalton our understanding of periodicity and the relationships between elements. Introduction and periodic tables concerning objects as diverse as fruit, veg- etables, beer, cartoon characters, and superheroes abound in In the year 2019 we celebrate the sesquicentennial of the publi- our connected world.7 Creative Commons Attribution-NonCommercial 3.0 Unported Licence. cation of the first modern form of the periodic table by In the commonly encountered medium or long forms of Mendeleev (alternatively transliterated as Mendelejew, the periodic table, the central portion is occupied by the Mendelejeff, Mendeléeff, and Mendeléyev from the Cyrillic d-block elements, commonly known as the transition elements ).1 The periodic table lies at the core of our under- or transition metals. These elements have played a critical rôle standing of the properties of, and the relationships between, in our understanding of modern chemistry and have proved to the 118 elements currently known (Fig. 1).2 A chemist can look be the touchstones for many theories of valence and bonding. -
Table 2.Iii.1. Fissionable Isotopes1
FISSIONABLE ISOTOPES Charles P. Blair Last revised: 2012 “While several isotopes are theoretically fissionable, RANNSAD defines fissionable isotopes as either uranium-233 or 235; plutonium 238, 239, 240, 241, or 242, or Americium-241. See, Ackerman, Asal, Bale, Blair and Rethemeyer, Anatomizing Radiological and Nuclear Non-State Adversaries: Identifying the Adversary, p. 99-101, footnote #10, TABLE 2.III.1. FISSIONABLE ISOTOPES1 Isotope Availability Possible Fission Bare Critical Weapon-types mass2 Uranium-233 MEDIUM: DOE reportedly stores Gun-type or implosion-type 15 kg more than one metric ton of U- 233.3 Uranium-235 HIGH: As of 2007, 1700 metric Gun-type or implosion-type 50 kg tons of HEU existed globally, in both civilian and military stocks.4 Plutonium- HIGH: A separated global stock of Implosion 10 kg 238 plutonium, both civilian and military, of over 500 tons.5 Implosion 10 kg Plutonium- Produced in military and civilian 239 reactor fuels. Typically, reactor Plutonium- grade plutonium (RGP) consists Implosion 40 kg 240 of roughly 60 percent plutonium- Plutonium- 239, 25 percent plutonium-240, Implosion 10-13 kg nine percent plutonium-241, five 241 percent plutonium-242 and one Plutonium- percent plutonium-2386 (these Implosion 89 -100 kg 242 percentages are influenced by how long the fuel is irradiated in the reactor).7 1 This table is drawn, in part, from Charles P. Blair, “Jihadists and Nuclear Weapons,” in Gary A. Ackerman and Jeremy Tamsett, ed., Jihadists and Weapons of Mass Destruction: A Growing Threat (New York: Taylor and Francis, 2009), pp. 196-197. See also, David Albright N 2 “Bare critical mass” refers to the absence of an initiator or a reflector. -
Promotion Effects and Mechanism of Alkali Metals and Alkaline Earth
Subscriber access provided by RES CENTER OF ECO ENVIR SCI Article Promotion Effects and Mechanism of Alkali Metals and Alkaline Earth Metals on Cobalt#Cerium Composite Oxide Catalysts for N2O Decomposition Li Xue, Hong He, Chang Liu, Changbin Zhang, and Bo Zhang Environ. Sci. Technol., 2009, 43 (3), 890-895 • DOI: 10.1021/es801867y • Publication Date (Web): 05 January 2009 Downloaded from http://pubs.acs.org on January 31, 2009 More About This Article Additional resources and features associated with this article are available within the HTML version: • Supporting Information • Access to high resolution figures • Links to articles and content related to this article • Copyright permission to reproduce figures and/or text from this article Environmental Science & Technology is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Environ. Sci. Technol. 2009, 43, 890–895 Promotion Effects and Mechanism such as Fe-ZSM-5 are more active in the selective catalytic reduction (SCR) of N2O by hydrocarbons than in the - ° of Alkali Metals and Alkaline Earth decomposition of N2O in a temperature range of 300 400 C (3). In recent years, it has been found that various mixed Metals on Cobalt-Cerium oxide catalysts, such as calcined hydrotalcite and spinel oxide, showed relatively high activities. Composite Oxide Catalysts for N2O One of the most active oxide catalysts is a mixed oxide containing cobalt spinel. Calcined hydrotalcites containing Decomposition cobalt, such as Co-Al-HT (9-12) and Co-Rh-Al-HT (9, 11), have been reported to be very efficient for the decomposition 2+ LI XUE, HONG HE,* CHANG LIU, of N2O. -
Indium, Caesium Or Cerium Compounds for Treatment of Cerebral Disorders
Europaisches Patentamt 298 644 J European Patent Office Oy Publication number: 0 A3 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 88305895.0 © intci.s A61K 31/20, A61K 31/28, A61K 33/24 @ Date of filing: 29.06.88 © Priority: 07.07.87 GB 8715914 © Applicant: EFAMOL HOLDINGS PLC Efamol House Woodbridge Meadows © Date of publication of application: Guildford Surrey GU1 1BA(GB) 11.01.89 Bulletin 89/02 @ Inventor: Horrobin, David Frederick © Designated Contracting States: c/o Efamol House Woodbridge Meadows AT BE CH DE ES FR GB GR IT LI LU NL SE Guildford Surrey GU1 1BA(GB) Inventor: Corrigan, Frank ® Date of deferred publication of the search report: c/o Argyll & Bute Hospital 14.11.90 Bulletin 90/46 Lochgilphead, Argyll PA3T 8ED Scotland(GB) © Representative: Caro, William Egerton et al J. MILLER & CO. Lincoln House 296-302 High Holborn London WC1V 7 JH(GB) © Indium, caesium or cerium compounds for treatment of cerebral disorders. © A method of treatment of schizophrenia or other chronic cerebral disorder in which cerebral atrophy is shown, is characterised in that one or more as- similable or pharmaceutically acceptable indium caesium or cerium compounds is associated with a pharmaceutically acceptable diluent or carrier. CO < CD 00 O> Xerox Copy Centre PARTIAL EUROPEAN SEARCH REPORT Application number European Patent J which under Rule 45 of the European Patent Convention Office shall be considered, for the purposes of subsequent EP 88 30 5895 proceedings, as the European search report DOCUMENTS CONSIDERED TO BE RELEVANT Citation of document with indication, where appropriate, Relevant CLASSIFICATION OF THE ategory of relevant passages to claim APPLICATION (Int. -
Historical Development of the Periodic Classification of the Chemical Elements
THE HISTORICAL DEVELOPMENT OF THE PERIODIC CLASSIFICATION OF THE CHEMICAL ELEMENTS by RONALD LEE FFISTER B. S., Kansas State University, 1962 A MASTER'S REPORT submitted in partial fulfillment of the requirements for the degree FASTER OF SCIENCE Department of Physical Science KANSAS STATE UNIVERSITY Manhattan, Kansas 196A Approved by: Major PrafeLoor ii |c/ TABLE OF CONTENTS t<y THE PROBLEM AND DEFINITION 0? TEH-IS USED 1 The Problem 1 Statement of the Problem 1 Importance of the Study 1 Definition of Terms Used 2 Atomic Number 2 Atomic Weight 2 Element 2 Periodic Classification 2 Periodic Lav • • 3 BRIEF RtiVJiM OF THE LITERATURE 3 Books .3 Other References. .A BACKGROUND HISTORY A Purpose A Early Attempts at Classification A Early "Elements" A Attempts by Aristotle 6 Other Attempts 7 DOBEREBIER'S TRIADS AND SUBSEQUENT INVESTIGATIONS. 8 The Triad Theory of Dobereiner 10 Investigations by Others. ... .10 Dumas 10 Pettehkofer 10 Odling 11 iii TEE TELLURIC EELIX OF DE CHANCOURTOIS H Development of the Telluric Helix 11 Acceptance of the Helix 12 NEWLANDS' LAW OF THE OCTAVES 12 Newlands' Chemical Background 12 The Law of the Octaves. .........' 13 Acceptance and Significance of Newlands' Work 15 THE CONTRIBUTIONS OF LOTHAR MEYER ' 16 Chemical Background of Meyer 16 Lothar Meyer's Arrangement of the Elements. 17 THE WORK OF MENDELEEV AND ITS CONSEQUENCES 19 Mendeleev's Scientific Background .19 Development of the Periodic Law . .19 Significance of Mendeleev's Table 21 Atomic Weight Corrections. 21 Prediction of Hew Elements . .22 Influence -
The Development of the Periodic Table and Its Consequences Citation: J
Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1. -
FRANCIUM Element Symbol: Fr Atomic Number: 87
FRANCIUM Element Symbol: Fr Atomic Number: 87 An initiative of IYC 2011 brought to you by the RACI KAYE GREEN www.raci.org.au FRANCIUM Element symbol: Fr Atomic number: 87 Francium (previously known as eka-cesium and actinium K) is a radioactive metal and the second rarest naturally occurring element after Astatine. It is the least stable of the first 103 elements. Very little is known of the physical and chemical properties of Francium compared to other elements. Francium was discovered by Marguerite Perey of the Curie Institute in Paris, France in 1939. However, the existence of an element of atomic number 87 was predicted in the 1870s by Dmitri Mendeleev, creator of the first version of the periodic table, who presumed it would have chemical and physical properties similar to Cesium. Several research teams attempted to isolate this missing element, and there were at least four false claims of discovery during which it was named Russium (after the home country of soviet chemist D. K. Dobroserdov), Alkalinium (by English chemists Gerald J. K. Druce and Frederick H. Loring as the heaviest alkali metal), Virginium (after Virginia, home state of chemist Fred Allison), and Moldavium (by Horia Hulubei and Yvette Cauchois after Moldavia, the Romanian province where they conducted their work). Perey finally discovered Francium after purifying radioactive Actinium-227 from Lanthanum, and detecting particles decaying at low energy levels not previously identified. The new product exhibited chemical properties of an alkali metal (such as co-precipitating with Cesium salts), which led Perey to believe that it was element 87, caused by the alpha radioactive decay of Actinium-227. -
The Periodic Table of Elements
The Periodic Table of Elements 1 2 6 Atomic Number = Number of Protons = Number of Electrons HYDROGENH HELIUMHe 1 Chemical Symbol NON-METALS 4 3 4 C 5 6 7 8 9 10 Li Be CARBON Chemical Name B C N O F Ne LITHIUM BERYLLIUM = Number of Protons + Number of Neutrons* BORON CARBON NITROGEN OXYGEN FLUORINE NEON 7 9 12 Atomic Weight 11 12 14 16 19 20 11 12 13 14 15 16 17 18 SODIUMNa MAGNESIUMMg ALUMINUMAl SILICONSi PHOSPHORUSP SULFURS CHLORINECl ARGONAr 23 24 METALS 27 28 31 32 35 40 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 POTASSIUMK CALCIUMCa SCANDIUMSc TITANIUMTi VANADIUMV CHROMIUMCr MANGANESEMn FeIRON COBALTCo NICKELNi CuCOPPER ZnZINC GALLIUMGa GERMANIUMGe ARSENICAs SELENIUMSe BROMINEBr KRYPTONKr 39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 RUBIDIUMRb STRONTIUMSr YTTRIUMY ZIRCONIUMZr NIOBIUMNb MOLYBDENUMMo TECHNETIUMTc RUTHENIUMRu RHODIUMRh PALLADIUMPd AgSILVER CADMIUMCd INDIUMIn SnTIN ANTIMONYSb TELLURIUMTe IODINEI XeXENON 85 88 89 91 93 96 98 101 103 106 108 112 115 119 122 128 127 131 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 CESIUMCs BARIUMBa HAFNIUMHf TANTALUMTa TUNGSTENW RHENIUMRe OSMIUMOs IRIDIUMIr PLATINUMPt AuGOLD MERCURYHg THALLIUMTl PbLEAD BISMUTHBi POLONIUMPo ASTATINEAt RnRADON 133 137 178 181 184 186 190 192 195 197 201 204 207 209 209 210 222 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 FRANCIUMFr RADIUMRa RUTHERFORDIUMRf DUBNIUMDb SEABORGIUMSg BOHRIUMBh HASSIUMHs MEITNERIUMMt DARMSTADTIUMDs ROENTGENIUMRg COPERNICIUMCn NIHONIUMNh -
Microdosimetry of Astatine-211 and Xa0102708 Comparison with That of Iodine-125
MICRODOSIMETRY OF ASTATINE-211 AND XA0102708 COMPARISON WITH THAT OF IODINE-125 T. UNAK Ege University, Bomova, Izmir, Turkey Abstract.' 21lAt is an alpha and Auger emitter radionuclide and has been frequently used for labeling of different kind of chemical agents. 125I is also known as an effective Auger emitter. The radionuclides which emit short range and high LET radiations such as alpha particles and Auger electrons have high radiotoxic effectiveness on the living systems. The microdosimetric data are suitable to clarify the real radiotoxic effectiveness and to get the detail of diagnostic and therapeutic application principles of these radionuclides. In this study, the energy and dose absorptions by cell nucleus from alpha particles and Auger electrons emitted by 211At have been calculated using a Monte Carlo calculation program (code: UNMOC). For these calculations two different model corresponding to the cell nucleus have been used and the data obtained were compared with the data earlier obtained for I25I. As a result, the radiotoxicity of 21lAt is in the competition with 125I. In the case of a specific agent labelled with 2I1At or 125I is incorporated into the cell or cell nucleus, but non-bound to DNA or not found very close to it, 2llAt should considerably be much more radiotoxic than i25I, but in the case of the labelled agent is bound to DNA or take a place very close to it, the radiotoxicity of i25I should considerably be higher than 21'At. 1. INTRODUCTION 21'At as an alpha and Auger emitter radionuclide has an extremely high potential application in cancer therapy; particularly, in molecular radiotherapy. -
Of the Periodic Table
of the Periodic Table teacher notes Give your students a visual introduction to the families of the periodic table! This product includes eight mini- posters, one for each of the element families on the main group of the periodic table: Alkali Metals, Alkaline Earth Metals, Boron/Aluminum Group (Icosagens), Carbon Group (Crystallogens), Nitrogen Group (Pnictogens), Oxygen Group (Chalcogens), Halogens, and Noble Gases. The mini-posters give overview information about the family as well as a visual of where on the periodic table the family is located and a diagram of an atom of that family highlighting the number of valence electrons. Also included is the student packet, which is broken into the eight families and asks for specific information that students will find on the mini-posters. The students are also directed to color each family with a specific color on the blank graphic organizer at the end of their packet and they go to the fantastic interactive table at www.periodictable.com to learn even more about the elements in each family. Furthermore, there is a section for students to conduct their own research on the element of hydrogen, which does not belong to a family. When I use this activity, I print two of each mini-poster in color (pages 8 through 15 of this file), laminate them, and lay them on a big table. I have students work in partners to read about each family, one at a time, and complete that section of the student packet (pages 16 through 21 of this file). When they finish, they bring the mini-poster back to the table for another group to use.