US 2011 O150817A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2011/0150817 A1 WOO et al. (43) Pub. Date: Jun. 23, 2011

(54) FRESHENING COMPOSITIONS (22) Filed: Sep. 20, 2010 COMPRISING MALODOR BINDING POLYMERS AND MALODOR CONTROL Related U.S. Application Data COMPONENTS (60) Provisional application No. 61/287.348, filed on Dec. (76) Inventors: Ricky Ah-Man WOO, Hamilton, 17, 2009, provisional application No. 61/287,369, OH (US); Christine Marie filed on Dec. 17, 2009, provisional application No. Readnour, Fort Mitchell, KY (US); 61/287,383, filed on Dec. 17, 2009. Jason John Olchovy, West Chester, OH (US); Michael-Vincent Nario Publication Classification Malanyaon, Indian Springs, OH (51) Int. Cl. (US); Zaiyou Liu, West Chester, A6IL 9/01 (2006.01) OH (US); Rhonda Jean Jackson, Cincinnati, OH (US); Kristin (52) U.S. Cl...... 424/76.21; 424/76.1 Rhedrick Williams, West Chester, OH (US); Carla Jean Colina, (57) ABSTRACT Cincinnati, OH (US); Cahit Eylem, West Chester, OH (US); Lon Freshening compositions comprising a malodor binding Montgomery Gray, Florence, KY polymer, malodor control components, and an aqueous car (US); Shih-Chuan Liou, rier; and methods thereof are provided. In some embodi Cincinnati, OH (US); Steven ments, the freshening composition comprises a homopoly Anthony Horenziak, Fairfield, OH meric polyethylenimine having a molecular weight of about (US) 1,000 to about 2,000,000 and a mixture of volatile aldehydes. Such freshening compositions may be used to reduce mal (21) Appl. No.: 12/885,884 odor and/or microbes on inanimate Surfaces or in the air. Patent Application Publication Jun. 23, 2011 Sheet 1 of 5 US 2011/O150817 A1

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FRESHENING COMPOSITIONS BRIEF DESCRIPTION OF THE DRAWINGS COMPRISING MALODOR BINDING POLYMERS AND MALODOR CONTROL 0008 FIG. 1 is a bar graph showing the reduction of alde COMPONENTS hydic malodors evaporating off fabrics treated with freshen ing compositions according to the present invention contain CROSS REFERENCES TO RELATED ing a malodor binding polymer in comparison to a freshening APPLICATIONS composition lacking Such malodor binding polymer. 0001. This application claims the benefit of U.S. Provi sional Application No. 61/287.348, filed, Dec. 17, 2009 and 0009 FIG. 2 is a bar graph showing microbe reduction U.S. Provisional Application No. 61/287,369, filed Dec. 17, with a freshening composition according to the present inven 2009 and U.S. Provisional Application No. 61/287,383, filed tion containing a malodor binding polymer in comparison to Dec. 17, 2009 and U.S. application Ser. No. 12/562,534, filed a freshening composition lacking Such malodor binding poly Sep. 18, 2009 and U.S. application Ser. No. 12/562.553 filed C. Sep. 18, 2009. 0010 FIG. 3 is a graph showing the performance of one embodiment of a malodor control component, in accordance FIELD OF THE INVENTION with the present invention, on a Sulfur-based malodor. 0002 The present invention relates to freshening compo 0011 FIG. 4 is a graph showing the performance of one sitions comprising a malodor binding polymer, malodor con embodiment of a malodor control component, in accordance trol components, and an aqueous carrier; and methods with the present invention, on an amine-based malodor. thereof. 0012 FIG. 5 is a graph showing butanethiol reduction by BACKGROUND OF THE INVENTION thiophene carboxaldehyde in combination with various acid catalysts. 0003 Freshening products for reducing or masking mal odors on fabrics and in air are currently available and are described in the patent literature. The Procter & Gamble DETAILED DESCRIPTION OF THE INVENTION Company sells fabric and air freshening products under the FEBREZER) brand name. These products typically contain 0013 The freshening composition of the present invention perfume, solubilizer, cyclodextrin, and an aqueous carrier. is designed to deliver genuine malodor reduction and not S.C. Johnson sells products such as Glade(R) Fabric and Air function merely by using perfume to cover up or mask odors. Odor Eliminator and Oust(R) Surface Disinfectant and Air The freshening composition reduces malodor in the air or on Sanitizer. Reckitt-Benckiser sells products such as Lysol R. inanimate surfaces, for example, fabrics that are contami Disinfectant Spray. nated with environmental odors such as food and tobacco 0004 Certain freshening compositions do not effectively odors, or wetted with perspiration. The freshening composi neutralize a broad range of malodors on fabrics and in the air. tion may also reduce microbes on inanimate Surfaces or in air. Further, the time required for a composition to noticeably The freshening composition may also act as a barrier to pre combat malodors may create consumer doubt as to a prod vent malodors from adhering to or penetrating an inanimate uct’s efficacy on malodors. For example, the consumer may Surface. leave the treated space before the product begins to noticeably 0014. A genuine malodor reduction provides a sensory reduce the malodor. and analytically measurable (e.g. gas chromatograph) mal 0005. There remains a need for improved freshening com odor reduction. Thus, if the freshening composition delivers a positions that neutralize a broad range of malodors, including genuine malodor reduction, the freshening composition will amine-base and Sulfur-based malodors and malodors caused neutralize malodors in the air and/or on fabrics. “Neutralize” by microbes, while not overpowering malodors with over or “neutralization” as used herein means chemically reacting whelming perfume. with malodor components (e.g. the reaction of primary amines with aldehydes to formimines, reductive alkylation of SUMMARY OF THE INVENTION amines, protonation and deprotonation of amines, polymer 0006. The present invention relates to a freshening com ization or de-polymerization); or Suppressing the Volatility of position for reducing malodor. In one embodiment, the fresh malodorous components such that other parts of the compo ening composition for reducing malodor comprises an effec sition may react (e.g. acid-base neutralization); or physically tive amount of a malodor binding polymer; a malodor control entrapping odorous molecules such that they are not re-re component; an aqueous carrier. In another embodiment, the leased into the air (e.g. cyclodextrin inclusion complexes as freshening composition comprises a homopolymeric poly described herein). Odor neutralization may be distinguished ethyleneimine having a molecular weight of 1,000 to 2,000, from odor masking or odor blocking by a change in the 000; at least one aliphatic aldehyde; a glycol; a dicarboxylic malodorous compound, as opposed to a change in the ability acid to provide a pH of about 3 to about 8; about 90% to about to perceive the malodor without any corresponding change in 99.5% of an aqueous carrier; wherein said composition is the condition of the malodorous compound. essentially free of any material that would soil or stain fabric. 0007. The present invention also relates to methods of I. Freshening Composition reducing malodor comprising the steps of providing a fresh ening composition comprising an effective amount of a mal 0015 The freshening composition for reducing malodor odor binding polymer, a malodor counteractant comprising at comprises a malodor binding polymer, a malodor counterac least one aliphatic aldehyde, an aqueous carrier, wherein said tant comprising at least one aliphatic aldehyde, and an aque composition is essentially free of any material that would soil ous carrier, wherein said composition is essentially free of or stain fabric; and dispersing an effective amount of said materials that soil or stain fabric. The total amount of surfac freshening composition on an inanimate Surface or in the air. tants (e.g. solubilizer, wetting agent) in the freshening com US 2011/O 150817 A1 Jun. 23, 2011

position is from 0% to 3% or no more than 3%, alternatively a functional group that enhances deposition of the monoam from 0% to 1% or no more than 1%, alternatively from 0% to ine compared to monoamines that lack that functional group, 0.9% or no more than 0.9%, alternatively from 0% to 0.7 or no especially when the monoamine is interacting with the benefit more than 0.7%, alternatively from 0% to 0.5% or no more agent. Primary monoamines may also be used herein in com than 0.5%, alternatively from 0% to 0.3% or no more than bination with secondary monoamines. However, Sufficient 0.3%, by weight of the composition. Compositions with levels of the primary monoamine must be used to provide at higher concentrations can make fabrics Susceptible to Soiling least 10% of the total amine groups within such combinations and/or leave unacceptable visible stains on fabrics as the as primary amine groups. Solution evaporates. 0026 b. Aminoaryl Derivatives 0016 A. Malodor Binding Polymer 0027 Exemplary aminoaryl derivatives are the amino 0017. The freshening composition of the present invention benzene derivatives including the alkyl esters of 4-amino includes a malodor binding polymer. A malodor binding benzoate compounds, ethyl-4-amino benzoate, phenylethyl polymer is polymer having an available functional group (e.g. 4-aminobenzoate, phenyl-4-aminobenzoate, 4-amino-N'-(3- amine) that has the affinity to neutralize malodor compo aminopropyl)-benzamide, or mixtures thereof. nents. Monomers having an available function group with an affinity to neutralize malodor components are also contem (0028 c. Polyamines plated. In the case of amine based compounds, the amine will 0029. Examples of suitable amino functional polymers have an affinity for aldehyde malodors. The amine may react containing at least one primary amine group for the purposes with aldehyde malodors and form a new compound. Such as of the present invention are: an aminol, imine, or enamine which is not odorous. 0030 Polyvinylamine with a MW of 300-2.10E6 Daltons 0018. A malodor binding polymer may include amine (e.g. Lupamine series 1500, 4500, 5000, 9000 available from based compounds, Such as monoamines, amino acids, poly BASF); ethyleneimine polymers (PEIs), modified PEIs, substituted 0031 Polyvinylamine alkoxylated with a MW of 2600 PEIs; acrylic acid polymers. Such as polyacrylate co-polymer Daltons and a degree of ethoxylation of at least 0.5; (e.g. AcumerTM 9000 from Rohm & Haas), polyacrylic acid 0032 Polyvinylamine vinylalcohol molar ratio 2:1, polymers (e.g. AcusolTM from Rohm & Haas), and modified polyvinylaminevinylformamide—molar ratio 1:2 and poly acrylate copolymers (e.g. AculynTM from Rohm & Haas); and vinylamine vinylformamide-molar ratio 2:1; modified methacrylate copolymers (e.g. HydroSalTM from 0033 Triethylenetetramine, diethylenetriamine, tetraeth Salvona Technologies); or mixtures thereof. ylenepentamine; 0019 1. Amine Based Compounds 0020. In some embodiments, the malodor binding poly 0034 Bis-aminopropylpiperazine; mer is an amine based compound with a molecular weight 0035 amino substituted polyvinylalcohol with a MW greater than 100 Daltons and at least 10% of its amine groups ranging from 400-300,000 Daltons; are primary amines. In one embodiment, the amine-based 0036 polyoxyethylene bisamine available from e.g. compound will be a polyamine with a molecular weight Sigma; greater than 150 Daltons and 15% to 80% of its amine groups 0037 polyoxyethylene bis(5-aminohexyl available from are primary amines. In another embodiment, the malodor e.g. Sigma; binding polymer is an amine-based compound with a molecu 0038 N,N'-bis-(3-aminopropyl)-1,3-propanediamine lin lar weight greater than 1000 Daltons and from 0% to about 10% or less than 10% of its amine groups are primary amines. ear or branched (TPTA); 0021. A general structure for a primary amine compound 0039 N,N'-bis-(3-aminopropyl)ethylenediamine; useful in this invention is as follows: 0040 bis(amino alkyl)alkyl diamine, linear or branched; and 0041 14-bis-(3-aminopropyl)piperazine (BNPP). wherein B is a carrier material, and n is an index of value of at 0042 d. Polyamino Acids least 1. Suitable B carriers include both inorganic and organic 0043 Suitable amine based compounds include carrier moieties. By “inorganic carrier, it is meant a carrier polyamino acids. Polyamino acids are made up of amino which is comprised of non- or Substantially non-carbon based acids or chemically modified amino acids. The amino acids backbones. may be selected from cysteine, histidine, isoleucine, tyrosine, 0022 Compounds containing a secondary amine group tryptophane, leucine, lysine, glutamic acid, glutamine, gly have a structure similar to the above with the exception that cine, alanine, aspartic acid, arginine, asparagine, phenylala the compound comprises one or more —NH-groups as well nine, proline, serine, histidine, threonine, methionine, Valine, as —NH2 groups. The amine compounds of this general type and mixtures thereof. Amino acid derivatives may be tyrosine may be relatively viscous materials. ethylate, glycine methylate, tryptophane ethylate, or mixtures 0023 Exemplary amine based compounds are those thereof, homopolymers of amino acids; hydroxyamines; selected from monoamines, aminoaryl derivatives, polyamino acids; or mixtures thereof. polyamines and derivatives thereof, polyamino acids and 0044. In chemically modified amino acids, the amine or copolymers thereof, glucamines, dendrimers, PEIS, Substi acidic function of the amino acid has reacted with a chemical tuted amines and amides monoamines, or mixtures thereof. reagent. This is often done to protect these chemical amine 0024 a. Monoamines and acid functions of the amino acid in a Subsequent reaction 0025 Monoamines may be utilized in the present inven or to give special properties to the amino acids, like improved tion. Nonlimiting examples of suitable monoamines for use in solubility. Examples of such chemical modifications are ben the present invention include, but are not limited to, primary Zyloxycarbonyl, aminobutyric acid, butyl ester, and pyro amines that also contain hydroxy and/or alkoxy functional glutamic acid. More examples of common modifications of groups, such as the 2-hydroxyamines and/or 3-hy amino acids and Small amino acid fragments can be found in droxyamines; primary or secondary amines that also contain the Bachem, 1996, Peptides and Biochemicals Catalog. US 2011/O 150817 A1 Jun. 23, 2011

0045 One polyamino acid is polylysine, alternatively 0053. The freshening composition may comprise a polylysines or polyamino acids where more than 50% of the homopolymeric polyethylenimine having a molecular weight amino acids are lysine, since the primary amine function in of about 800 to about 2,000,000, alternatively about 1,000 to the side chain of the lysine is the most reactive amine of all about 2,000,000, alternatively about 1,200 to about 25,000, amino acids. One polyamino acid has a molecular weight of alternatively about 1,300 to about 25,000, alternatively about 500 to 10,000,000, alternatively between 2000 and 25,000. 2,000 to about 25,000, alternatively about 10,000 to about 0046. The polyamino acid can be cross linked. The cross 2,000,000, alternatively about 25,000 to about 2,000,000, linking can be obtained for example by condensation of the alternatively about 25,000. Exemplary homopolymeric PEIs amine group in the side chain of the amino acid like lysine with the carboxyl function on the amino acid or with protein include those that are commercially available under the trade cross linkers like PEG derivatives. The cross linked name Lupasol(R) from BASF. Lupasol products are usually polyamino acids still need to have free primary and/or sec obtained through polymerization of the ethylenimine mono ondary amino groups left for neutralization. Cross linked mer. The ethylenimine monomer has totally reacted in the polyamino acid has a molecular weight of 20,000 to 10,000, polymer matrix. Suitable Lupasol products include Lupasol 000; alternatively between 200,000 and 2,000,000. FG (MW 800), G20 wifv (MW 1300), PR8515 (MW 2000), 0047. The polyamino acid or the amino acid can be co WF (MW 25,000), FC (MW 800), G20 (MW 1300), G35 polymerized with other reagents like for instance with acids, (MW 1200), G100 (MW 2000), HF (MW 25,000), P (MW amides, acyl chlorides, aminocaproic acid, adipic acid, eth 750,000), PS (MW 750,000), SK (MW 2,000,000), SNA ylhexanoic acid, caprolactam, or mixtures thereof. The molar (MW 1,000,000). ratio used in these copolymers ranges from 1:1 (reagent/ 0054. In some embodiments, the freshening composition amino acid (lysine)) to 1:20, alternatively from 1:1 to 1:10. comprises Lupasol HF or WF (MW 25,000), P (MW 750, The polyamino acid like polylysine can be unethoxylated or 000), PS (MW 750,000), SK(MW 2,000,000), 620 wifv (MW partially ethoxylated so long as the requisite amount of pri 1300) or PR 1815 (MW 2000), or Epomin SP-103, Epomin mary amine remains in the polymer. SP-110, Epomin SP-003, Epomin SP-006, Epomin SP-012, 0048 e. Dendrimers Epomin SP-018, Epomin SP-200, or partially alkoxylated 0049. Also useful amine based compounds are polypropy polyethyleneimine, like polyethyleneimine 80% ethoxylated lenimine dendrimers and the commercially available Star from Aldrich. In one embodiment, the freshening composi burst(R) polyamidoamines (PAMAM) dendrimers, generation tion contains Lupasol WF (MW 25,000). G0-G10 from Dendritech and the dendrimers Astromols(R), generation 1-5 from DSM being DiAminoButane Poly Amine 0055 Also suitable amine based compounds for use in the DAB (PA)x dendrimers with X=2"x4 and n being generally freshening composition are modified PEIs, partially alkylated comprised between 0 and 4. polyethylene polymers, PEIs with hydroxyl groups, 1,5-pen 0050 f. PEIs tanediamine, 1.6-hexanediamine, 1.3 pentanediamine, 0051. In one embodiment, the malodor binding polymer is 3-dimethylpropanediamine, 1.2-cyclohexanediamine, 1.3- a PEI. It has been surprisingly discovered that amine based bis(aminomethyl)cyclohexane, tripropylenetetraamine, bis polymers at a pH of about 4 to about 8, alternatively above 5 (3-aminopropyl)piperazine, dipropylenetriamine, tris(2-ami to about 8, alternatively 7 can neutralize amine based odors. noethylamine), tetraethylenepentamine, PEIs have the following general formula: bishexamethylenetriamine, bis(3-aminopropyl) 1..6-hexam ethylenediamine, 3,3'-diamino-N-methyldipropylamine, 2-methyl-1,5-pentanediamine, N.N.N',N'-tetra(2-aminoet 0052 Homopolymeric PEIs are branched, spherical hyl)ethylenediamine, N.N.N',N'-tetra(3-aminopropyl)-1,4- polyamines with a well defined ratio of primary, secondary butanediamine, pentaethylhexamine, 1,3-diamino-2-propyl and tertiary amine functions. They are best described in the tert-butylether, isophorondiamine, 4,4'- following partial structural formula: diaminodicyclohylmethane, N-methyl-N-(3-aminopropyl) ethanolamine, spermine, spermidine, 1-piperazineethaneamine, 2-(bis(2-aminoethyl)amino)etha H nol, ethoxylated N-(tallowalkyl)trimethylene diamines, poly l oxy(methyl-1,2-ethanediyl). C.-(2-aminomethyl-ethoxy)- (=C.A.S No. 9046-10-0); polyoxy(methyl-1,2-ethanediyl). O-hydro-)-()-(2-aminomethylethoxy)-, ether with 2-ethyl-2- ul (hydroxymethyl)-1,3-propanediol (C.A.S. No. 39423-51 YN 1N-N-1N1 3); commercially available under the tradename Jeffamines T403, D-230, D-400, D-2000: 2,2'2"-triaminotriethy lamine; 2,2'-diamino-diethylamine; 3,3'-diamino-dipropy lamine, 1.3 bis aminoethyl-cyclohexane commercially avail HN able from Mitsubishi, and the C12 Sternamines commercially available from Clariant like the C12 Sternamin (propylena 1\-N-1 ns mine), with n=3/4. 0056. In one embodiment, the malodor binding polymer H may be used in an effective amount to provide a reduction of microbes on fabric and/or in the air. When using a malodor binding polymer, an effective amount reduces microbes by at least 1 log difference as compared to a composition lacking the malodor binding polymer. This difference is then attrib The chemical structure of homopolymeric PEIs follows a uted to the use of the malodor binding polymer and not the simple principle: one amine function-two carbons. inherent variability in the microbial species. US 2011/O 150817 A1 Jun. 23, 2011

0057 Suitable levels of malodor binding polymer are from database. The “calculated logP' (ClogP) is determined by the about 0.01% to about 2%, alternatively from about 0.01% to fragment approach of Hansch and Leo (cf., A. Leo, in Com about 1%, alternatively about 0.01% to about 0.8%, alterna prehensive Medicinal Chemistry, Vol. 4, C. Hansch, P. G. tively about 0.01% to about 0.6%, alternatively about 0.01% Sammens, J. B. Taylor and C. A. Ramsden, Eds., p. 295, to about 0.1%, alternatively about 0.01% to about 0.07%, Pergamon Press, 1990). The fragment approach is based on alternatively about 0.07%, by weight of the freshening com the chemical structure of each volatile aldehyde, and takes position. Compositions with higher amount of malodor bind into account the numbers and types of atoms, the atom con ing polymer may make fabrics susceptible to Soiling and/or nectivity, and chemical bonding. The ClogP values, which are leave unacceptable visible stains on fabrics as the solution the most reliable and widely used estimates for this physico evaporates off of the fabric. chemical property, are preferably used instead of the experi 0058 B. Malodor Control Components mental logP values in the selection of volatile aldehydes for 0059. The freshening composition may include malodor the malodor control component. control components. The malodor control component 0065. The ClogP values may be defined by four groups includes a mixture of Volatile aldehydes and is designed to and the volatile aldehydes may be selected from one or more deliver genuine malodor neutralization and not function of these groups. The first group comprises Volatile aldehydes merely by covering up or masking odors. A genuine malodor that have a B.P. of about 250° C. or less and ClogP of about 3 neutralization provides a sensory and analytically measurable or less. The second group comprises Volatile aldehydes that (e.g. gas chromatograph) malodor reduction. Thus, if the have a B.P. of 250° C. or less and ClogP of 3.0 or more. The malodor control component delivers a genuine malodor neu third group comprises volatile aldehydes that have a B.P. of tralization, the composition will reduce malodors in the vapor 250° C. or more and ClogP of 3.0 or less. The fourth group and/or liquid phase. When used in combination with the mal comprises volatile aldehydes that have a B.P. of 250° C. or odor binding polymer, the freshening composition may neu more and ClogP of 3.0 or more. The malodor control compo tralize abroader range of malodor causing materials which, in nent may comprise any combination of volatile aldehydes turn, further reduces malodors in the air or on inanimate from one or more of the ClogP groups. Surfaces. 0066. In some embodiments, the malodor control compo 0060) 1. Volatile Aldehydes nent of the present invention may comprise, by total weight of 0061 The malodor control component includes a mixture the malodor control component, from about 0% to about 30% of volatile aldehydes that neutralize malodors in vapor and/or of volatile aldehydes from group 1, alternatively about 25%; liquid phase via chemical reactions. Aldehydes that are par and/or about 0% to about 10% of volatile aldehydes from tially volatile may be considered a volatile aldehyde as used group 2, alternatively about 10%; and/or from about 10% to herein. Volatile aldehydes may react with amine-based odors, about 30% of volatile aldehydes from group 3, alternatively following the path of Schiff-base formation. Volatiles alde about 30%; and/or from about 35% to about 60% of volatile hydes may also react with Sulfur-based odors, forming thiol aldehydes from group 4, alternatively about 35%. acetals, hemi thiolacetals, and thiol esters in vapor and/or 0067 Exemplary volatile aldehydes which may be used in liquid phase. It may be desirable for these vapor and/or liquid a malodor control component include, but are not limited to, phase Volatile aldehydes to have virtually no negative impact Adoxal (2,6,10-Trimethyl-9-undecenal), Bourgeonal (4-t- on the desired perfume character of a product. butylbenzenepropionaldehyde), Lilestralis 33 (2-methyl-4-t- 0062 Suitable volatile aldehydes may have a vapor pres butylphenyl)propanal), Cinnamic aldehyde, cinnamaldehyde sure (VP) in the range of about 0.0001 torr to 100 torr, alter (phenyl propenal, 3-phenyl-2-propenal), Citral, Geranial, natively about 0.0001 torr to about 10 torr, alternatively about Neral (dimethyloctadienal, 3,7-dimethyl-2,6-octadien-1-al), 0.001 torr to about 50 torr, alternatively about 0.001 torr to Cyclal C (2,4-dimethyl-3-cyclohexen-1-carbaldehyde), Flo about 20 torr, alternatively about 0.001 torr to about 0.100 rhydral (3-(3-Isopropyl-phenyl)-butyraldehyde), Citronellal torr, alternatively about 0.001 torr to 0.06 torr, alternatively (3,7-dimethyl 6-octenal), Cymal, cyclamen aldehyde, about 0.001 torr to 0.03 torr, alternatively about 0.005 torr to Cyclosal, Lime aldehyde (Alpha-methyl-p-isopropyl phenyl about 20 torr, alternatively about 0.01 torr to about 20 torr, propyl aldehyde), Methyl Nonyl Acetaldehyde, aldehyde alternatively about 0.01 torr to about 15 torr, alternatively C12 MNA (2-methyl-1-undecanal), Hydroxycitronellal, cit about 0.01 torr to about 10 torr, alternatively about 0.05 torr to ronellal hydrate (7-hydroxy-3,7-dimethyl octan-1-al), about 10 torr, measured at 25°C. Helional (alpha-methyl-3,4-(methylenedioxy)-hydrocinna 0063. The volatile aldehydes may also have a certain boil maldehyde, hydrocinnamaldehyde (3-phenylpropanal, ing point (B.P.) and octanol/water partition coefficient (P). 3-phenylpropionaldehyde), Intreleven aldehyde (undec-10 The boiling point referred to herein is measured under normal en-1-al), Ligustral, Trivertal (2,4-dimethyl-3-cyclohexene-1- standard pressure of 760 mmHg. The boiling points of many carboxaldehyde), Jasmorange, satinaldehyde (2-methyl-3- volatile aldehydes, at standard 760 mm Hg are given in, for tolylproionaldehyde, 4-dimethylbenzenepropanal), Lyral (4- example, “Perfume and Flavor Chemicals (Aroma Chemi (4-hydroxy-4-methyl pentyl)-3-cyclohexene-1- cals), written and published by Steffen Arctander, 1969. carboxaldehyde), Melonal (2,6-Dimethyl-5-Heptenal), 0064. The octanol/water partition coefficient of a volatile Methoxy Melonal (6-methoxy-2,6-dimethylheptanal), meth aldehyde is the ratio between its equilibrium concentrations oxycinnamaldehyde (trans-4-methoxycinnamaldehyde), in octanol and in water. The partition coefficients of the vola Myrac aldehyde isohexenyl cyclohexenyl-carboxaldehyde, tile aldehydes used in the malodor control component may be trifernal ((3-methyl-4-phenyl propanal, 3-phenyl butanal), more conveniently given in the form of their logarithm to the lilial, P.T. Bucinal, lysmeral, benzenepropanal (4-tert-butyl base 10, logP. The logP values of many volatile aldehydes alpha-methyl-hydrocinnamaldehyde), Dupical, tricyclode have been reported. See, e.g., the Pomona')2 database, avail cylidenebutanal (4-Tricyclo521.0-2.6decylidene-8butanal), able from Daylight Chemical Information Systems, Inc. Melafleur (1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naph (Daylight CIS), Irvine, Calif. However, the logP values are thaldehyde), Methyl Octyl Acetaldehyde, aldehyde C-11 most conveniently calculated by the "CLOGP program, also MOA (2-methyl deca-1-al), Onicidal (2,6,10-trimethyl-5.9- available from Daylight CIS. This program also lists experi undecadien-1-al), Citronellyl oxyacetaldehyde, Muguet mental logP values when they are available in the Pomona'92 aldehyde 50 (3,7-dimethyl-6-octenyl)oxyacetaldehyde), US 2011/O 150817 A1 Jun. 23, 2011

phenylacetaldehyde, Mefranal (3-methyl-5-phenyl penta 0070. In some embodiments, the malodor control compo nal), Triplal, Vertocitral dimethyl tetrahydrobenzene alde nent includes fast reacting Volatile aldehydes. "Fast reacting hyde (2,4-dimethyl-3-cyclohexene-1-carboxaldehyde), volatile aldehydes' refers to volatile aldehydes that either (1) 2-phenylproprionaldehyde, Hydrotropaldehyde, Canthoxal, reduce amine odors by 20% or more in less than 40 seconds; anisylpropanal 4-methoxy-alpha-methyl benzenepropanal or (2) reduce thiol odors by 20% or more in less than 30 (2-anisylidene propanal), Cylcemone A (1,2,3,4,5,6,7,8-oc minutes. tahydro-8,8-dimethyl-2-naphthaldehyde), and Precylcemone 0071. In one embodiment, the malodor control component B (1-cyclohexene-1-carboxaldehyde). includes a mixture of the volatile aldehydes listed in Table 1 0068. Still other exemplary aldehydes include, but are not and referred to herein as Accord A. limited to, acetaldehyde (ethanal), pentanal, Valeraldehyde, amylaldehyde, Scentenal (octahydro-5-methoxy-4,7- TABLE 1 Methano-1H-indene-2-carboxaldehyde), propionaldehyde (propanal), Cyclocitral, beta-cyclocitral. (2,6,6-trimethyl-1- ClogP VP (torr) cyclohexene-1-acetaldehyde), Iso Cyclocitral (2,4,6-trim Material Wt.% CAS Number Group (a)25° C. ethyl-3-cyclohexene-1-carboxaldehyde), isobutyraldehyde, Intreleven Aldehyde S.OOO 112-45-8 3 O.O60 butyraldehyde, isovaleraldehyde (3-methylbutyraldehyde), Florhydral 1O.OOO 12S109-85-S 4 O.OO8 methylbutyraldehyde (2-methyl butyraldehyde, 2-methyl Floral Super 2S.OOO 71077-31-1 3 O.O3O butanal), Dihydrocitronellal (3,7-dimethyl octan-1-al), Scentenal 1O.OOO 868O3-90-9 2 O.O10 2-Ethylbutyraldehyde, 3-Methyl-2-butenal, 2-Methylpenta Cymal 2S.OOO 103-95-7 4 O.OO7 nal, 2-Methyl Valeraldehyde, Hexenal (2-hexenal, trans-2- o-anisaldehyde 2S.OOO 135-02-4 1 O.O32 hexenal), Heptanal, Octanal. Nonanal, Decanal, Lauric alde hyde, Tridecanal, 2-Dodecanal, Methylthiobutanal, 0072. In another embodiment, the malodor control com Glutaraldehyde, Pentanedial, Glutaric aldehyde, Heptenal, ponent includes a mixture of the volatile aldehydes listed in cis or trans-Heptenal. Undecenal (2-, 10-), 2.4-octadienal, Table 2 and referred to herein as Accord B. Nonenal (2-, 6-), Decenal (2-, 4-), 2.4-hexadienal, 2,4-Deca dienal, 2,6-Nonadienal, Octenal, 2,6-dimethyl 5-heptenal, 2-isopropyl-5-methyl-2-hexenal, Trifemal, beta methyl Ben TABLE 2 Zenepropanal. 2.6.6-Trimethyl-1-cyclohexene-1-acetalde ClogP VP (torr) hyde, phenyl Butenal (2-phenyl 2-butenal). 2. Methyl-3(p- Material Wt.% CAS Number Group (a)25° C. isopropylphenyl)-propionaldehyde, 3-(p-isopropylphenyl)- Intreleven Aldehyde 2.OOO 112-4S-8 3 0.060 propionaldehyde, p-Tolylacetaldehyde Florhydral 2O.OOO 12S109-85-S 4 O.OO8 (4-methylphenylacetaldehyde), Anisaldehyde (p-methoxy Floral Super 1O.OOO 71077-31-1 3 O.O3O benzene aldehyde), Benzaldehyde, Vernaldehyde (1-Methyl Scentenal S.OOO 868O3-90-9 2 O.O10 4-(4-methylpentyl)-3-cyclohexenecarbaldehyde), Heliotro Cymal 2S.OOO 103-95-7 4 O.OO7 Floralozone 1O.OOO 67634-14-4 4 O.OOS pin (piperonal) 3.4-Methylene dioxy benzaldehyde, alpha Adoxal 1.OOO 141-13-9 4 O.OO7 Amylcinnamic aldehyde, 2-pentyl-3-phenylpropenoic Methyl Nonyl 1.OOO 110-41-8 3 O.O3O aldehyde, Vanillin (4-methoxy 3-hydroxy benzaldehyde), Acetaldehyde Ethyl vanillin (3-ethoxy 4-hydroxybenzaldehyde), Hexyl Melonal 1.OOO 106-72-9 3 O.670 Cinnamic aldehyde, Jasmonal H (alpha-n-hexyl-cinnamalde o-anisaldehyde 2S.OOO 135-02-4 1 O.O32 hyde), FloraloZone, (para-ethyl-alpha,alpha-dimethyl Hydrocinnamaldehyde), Acalea (p-methyl-alpha-pentylcin namaldehyde), methylcinnamaldehyde, alpha-Methylcinna 0073. In another embodiment, the malodor control com maldehyde (2-methyl 3-pheny propenal), alpha-hexylcinna ponent includes a mixture of about 71.2% volatile aldehydes, maldehyde (2-hexyl 3-phenyl propenal), Salicylaldehyde the remainder being other an ester and an alcohol perfume (2-hydroxybenzaldehyde), 4-ethylbenzaldehyde, Cuminal raw material. This mixture is listed in Table 3 and referred to dehyde (4-isopropyl benzaldehyde), Ethoxybenzaldehyde, herein as Accord C. 2,4-dimethylbenzaldehyde, Veratraldehyde (3,4-dimethoxy b