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WO 2016/049398 Al 31 March 2016 (31.03.2016) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/049398 Al 31 March 2016 (31.03.2016) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every A61K 8/35 (2006.01) CUB 9/00 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/US20 15/052094 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 25 September 2015 (25.09.201 5) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 62/055,844 26 September 2014 (26.09.2014) US (84) Designated States (unless otherwise indicated, for every 62/143,862 7 April 2015 (07.04.2015) US kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, (71) Applicant: THE PROCTER & GAMBLE COMPANY TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, [US/US]; One Procter & Gamble Plaza, Cincinnati, Ohio TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, 45202 (US). -
Iodine Oxoacids in Atmospheric Aerosol Formation – from Chamber Simulations to Field Observations
REPORT SERIES IN AEROSOL SCIENCE No. 239 (2021) IODINE OXOACIDS IN ATMOSPHERIC AEROSOL FORMATION – FROM CHAMBER SIMULATIONS TO FIELD OBSERVATIONS XU-CHENG HE （何旭成） Institute for Atmospheric and Earth System Research / Physics Faculty of Science, University of Helsinki, Helsinki, Finland Academic dissertation To be presented, with the permission of the Faculty of Science of the University of Helsinki, for public criticism in Exactum auditorium CK112, Pietari Kalmin Katu 5, on August 23rd, 2021, at 14 o'clock. Helsinki 2021 Author’s Address Institute for Atmospheric and Earth System Research / Physics P.O. box 64 FI-00140 University of Helsinki [email protected] Supervisors Academician, Professor Markku Kulmala, Ph.D. Institute for Atmospheric and Earth System Research / Physics University of Helsinki Associate Professor Mikko Sipilä, Ph.D. Institute for Atmospheric and Earth System Research / Physics University of Helsinki Assistant Professor Matti Petteri Rissanen, Ph.D. Aerosol Physics Laboratory Tampere University Lecturer Theo Kurtén, Ph.D. Department of Chemistry University of Helsinki Reviewers Research Professor Hannele Hakola, Ph.D. Air Quality Group Finnish Meteorological Institute Assistant Professor Julia Schmale, Ph.D. Extreme Environments Research Laboratory École polytechnique fédérale de Lausanne Opponent Professor Gordon McFiggans, Ph.D. Department of Earth and Environmental Sciences University of Manchester ISBN 978-952-7276-59-4 (printed version) ISSN 0784-3496 Helsinki 2021 Unigrafia Oy ISBN 978-952-7276-60-0 (pdf version) http://www.atm.helsinki.fi FAAR Helsinki 2021 Acknowledgements The work for this thesis was carried out at the Division of Atmospheric Sciences at the Department of Physics and later at the Institute for Atmospheric and Earth System Research (INAR), University of Helsinki. -
Atmospheric Chemistry of Iodine ,† ,‡ § || § Alfonso Saiz-Lopez,* John† M
REVIEW pubs.acs.org/CR Atmospheric Chemistry of Iodine ,† ,‡ § || § Alfonso Saiz-Lopez,* John† M. C. Plane,* Alex^ R. Baker, Lucy J. Carpenter,‡ Roland von Glasow, Juan C. Gomez Martín, Gordon McFiggans, and Russell W. Saunders † Laboratory for Atmospheric and Climate Science (CIAC), CSIC, Toledo, Spain ‡ School of Chemistry, University of Leeds, Leeds, LS2 9JT, United Kingdom §School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ, United Kingdom Department) of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom ^ School of Earth, Atmospheric & Environmental Sciences, University of Manchester, Manchester, M13 9PL, United Kingdom CONTENTS 5.2.2. Particle Formation in Macroalgal 1. Introduction A Incubation Experiments R 2. Sources of Iodine to the Atmosphere C 5.2.3. Iodine Oxide Particle Growth to 2.1. Atmospheric Mixing Ratios, Seasonality, and Potential Cloud Condensation Nuclei S Trends in Distributions C 5.3. Unresolved Aspects of Iodine-Mediated Particle 2.2. Emission Rates and Mechanisms E formation S 2.3. Molecular Iodine H 6. Accumulation of Iodine in Aerosol U 2.4. Summary H 6.1. Iodine Concentrations in Aerosol U 3. Measurements of Gas-Phase Reactive Iodine Species I 6.2. Iodine Speciation U 3.1. Coastal Marine Boundary Layer I 6.3. Key Uncertainties V 7. Impacts and Modeling of Reactive Iodine Species V 3.2. Remote, Open Ocean, and Tropical Marine 7.1. Impacts of Iodine Chemistry V Boundary Layer I 7.1.1. Ozone Depletion V 3.3. Polar Boundary Layer J 7.1.2. Influence on the NO and HO Balance W 3.4. Salt Lakes and Volcanoes K x x 7.1.3. -
10102-68-8 SDS Document Number: 000041 1.2: Recommended Uses and Restrictions Recommended Uses Manufacture of Substances Restrictions Not for Food Or Drug Use
Safety Data Sheet 1: Identification 1.1: Product Identifier Product Name: CaI2 Product Number(s): 1CAI2-0019F CAS Number: 10102-68-8 SDS Document Number: 000041 1.2: Recommended Uses and Restrictions Recommended Uses Manufacture of substances Restrictions Not for food or drug use. 1.3: Supplier Contact Information APL Engineered Materials, Inc. 2401 N. Willow Rd. Urbana, IL 61802 Phone: 217-367-1340 Fax: 217-367-9084 1.4: Emergency Phone Number United States: 800-255-3924 International: +01-813-248-0585 2: Hazards Identification 2.1: Classifications Not a hazardous substance or mixture - . 2.2: GHS Label Elements Pictograms Signal Word: Hazard Statements Not a hazardous substance. Precautionary Statements Not a hazardous substance. 2.3: Hazards Not Otherwise Classified or Not Covered by GHS Thursday, July 16, 2015 Page 1 of 9 None. 2.4: Amount(s) of substances with unknown toxicity None 3: Composition/Information on Ingredients 3.1: .Ingredient .Weight% .Formula .CAS Number .Mol Wt .EC Number CaI2 100 CaI2 10102-68-8 293.89 233-276-8 3.2: Other Hazardous components none 3.3: Trade Secret Disclaimer none 3.4: Synonyms Calcium Iodide 4: First Aid Measures 4.1: First Aid General Remove person from area of exposure and remove any contaminated clothing Consult with physician and provide this Safety Data Sheet In contact with eyes Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention if irritation develops or persists In contact with skin Wash thoroughly with soap and plenty of water. -
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Library Listing – 1,523 spectra Subset of Aldrich FT-IR Library related to organometallic, inorganic, boron and deueterium compounds. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collections of FT-IR Spectra Editions I or II, and the data has been carefully examined and processed by Thermo Fisher Scientific. Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1066 ((R)-(+)-2,2'- 1193 (1,2- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)ETHAN BINAPH)(1,5-CYCLOOCTADIENE) E)TUNGSTEN TETRACARBONYL, 1068 ((R)-(+)-2,2'- 97% BIS(DIPHENYLPHOSPHINO)-1,1'- 1062 (1,3- BINAPHTHYL)PALLADIUM(II) CH BIS(DIPHENYLPHOSPHINO)PROPA 1067 ((S)-(-)-2,2'- NE)DICHLORONICKEL(II) BIS(DIPHENYLPHOSPHINO)-1,1'- 598 (1,3-DIOXAN-2- BINAPH)(1,5-CYCLOOCTADIENE) YLETHYNYL)TRIMETHYLSILANE, 1140 (+)-(S)-1-((R)-2- 96% (DIPHENYLPHOSPHINO)FERROCE 1063 (1,4- NYL)ETHYL METHYL ETHER, 98 BIS(DIPHENYLPHOSPHINO)BUTAN 1146 (+)-(S)-N,N-DIMETHYL-1-((R)-1',2- E)(1,5- BIS(DI- CYCLOOCTADIENE)RHODIUM(I) PHENYLPHOSPHINO)FERROCENY TET L)E 951 (1,5-CYCLOOCTADIENE)(2,4- 1142 (+)-(S)-N,N-DIMETHYL-1-((R)-2- PENTANEDIONATO)RHODIUM(I), (DIPHENYLPHOSPHINO)FERROCE 99% NYL)ETHYLAMIN 1033 (1,5- 407 (+)-3',5'-O-(1,1,3,3- CYCLOOCTADIENE)BIS(METHYLD TETRAISOPROPYL-1,3- IPHENYLPHOSPHINE)IRIDIUM(I) -
Phenol Disgrace Via Periodate in Integrating by Using Supersonic Radiation
Journal of Medicine and Life Vol. 8, Special Issue 3, 2015, pp.233-237 Phenol disgrace via Periodate in integrating by using Supersonic Radiation Seid-Mohamadi A*, Asgari G**, Shokoohi R**, Adabi S** *Social Determinants of Health Research Center, Department of Environmental Health Engineering, School of Public Health, Hamadan University of Medical Sciences, Hamedan, Iran, **Department of Environmental Health Engineering, School of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran Correspondence to: Shervin Adabi, MSc, Department of Environmental Health Engineering, School of Public Health, Hamadan University of Medical Sciences, Shahid Fahmideh Street, Hamadan, Iran Mobile phone: +989374196112, E-mail: [email protected] Received: March 14th, 2015 – Accepted: June 18th, 2015 Abstract In this study, a successful degradation of phenol was achieved by a combination of processes, ultrasonic irradiation and periodate. The effect of pH, dosage of IO4-, dosage of initial phenol and ultrasonic irradiation time on the phenol degradation were examined. Furthermore, the impacts of ion intensity on phenol degradation were examined. The findings indicated that the disgrace ratio advanced in acidic conditions and an upper degradation was achieved in combination processes. The current new investigation examined the effect of ion intensity and the findings determined that the principal intensity of solution is an inactive variable on phenol disgrace with these systems. A comparison research among IO4-/ US system and IO4- and US separately determined the COD removal and indicated that an combined method of IO4-/ US system had the best execution. Introduction degrade phenol residuals before the discharge to water sources. Advanced Oxidation Processes (AOPs) have Industries generate a considerable amount of been studied as efficient methods in last decades [5,6]. -
IODINE Its Properties and Technical Applications
IODINE Its Properties and Technical Applications CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York IODINE Its Properties and Technical Applications ¡¡iiHiüíiüüiütitittüHiiUitítHiiiittiíU CHILEAN IODINE EDUCATIONAL BUREAU, INC. 120 Broadway, New York 5, New York 1951 Copyright, 1951, by Chilean Iodine Educational Bureau, Inc. Printed in U.S.A. Contents Page Foreword v I—Chemistry of Iodine and Its Compounds 1 A Short History of Iodine 1 The Occurrence and Production of Iodine ....... 3 The Properties of Iodine 4 Solid Iodine 4 Liquid Iodine 5 Iodine Vapor and Gas 6 Chemical Properties 6 Inorganic Compounds of Iodine 8 Compounds of Electropositive Iodine 8 Compounds with Other Halogens 8 The Polyhalides 9 Hydrogen Iodide 1,0 Inorganic Iodides 10 Physical Properties 10 Chemical Properties 12 Complex Iodides .13 The Oxides of Iodine . 14 Iodic Acid and the Iodates 15 Periodic Acid and the Periodates 15 Reactions of Iodine and Its Inorganic Compounds With Organic Compounds 17 Iodine . 17 Iodine Halides 18 Hydrogen Iodide 19 Inorganic Iodides 19 Periodic and Iodic Acids 21 The Organic Iodo Compounds 22 Organic Compounds of Polyvalent Iodine 25 The lodoso Compounds 25 The Iodoxy Compounds 26 The Iodyl Compounds 26 The Iodonium Salts 27 Heterocyclic Iodine Compounds 30 Bibliography 31 II—Applications of Iodine and Its Compounds 35 Iodine in Organic Chemistry 35 Iodine and Its Compounds at Catalysts 35 Exchange Catalysis 35 Halogenation 38 Isomerization 38 Dehydration 39 III Page Acylation 41 Carbón Monoxide (and Nitric Oxide) Additions ... 42 Reactions with Oxygen 42 Homogeneous Pyrolysis 43 Iodine as an Inhibitor 44 Other Applications 44 Iodine and Its Compounds as Process Reagents ... -
THE UNIVERSITY of EDINBURGH
THE UNIVERSITY of EDINBURGH & l N Thesis scanned from best copy available: may contain faint or blurred text, and/or cropped or missing pages. Scanned as part of the PhD Thesis Digitisation project http://librarvblogs.is.ed.ac.uk/phddigitisation THE ACTION OF YELLOYif PHOSPHORUS ON SALT SOLUTIONS OF CERTAIN HEAVY METALS by OSWALD JAMES WALKER. Thesis presented for the Degree of Ph.D. INTRODUCTION. The fact that yellow phosphorus is able to precipitate many heavy metals from solutions of their Salts has been known for a considerable period. If a stick of phosphorus is placed in a solution of silver nitrate or of copper sulphate, the phosphorus gradually becomes covered with a deposit of the metal and acids of phosphorus are found in the solution. The action may be represented as follows: P + M X + H_0 > M + H X + P acids, and continues as long as any free phosphorus remains. The apparent similarity between this action and the displacement of a metal from solutions of its salts by another metal is very marked and has been commented on by more than one investigator. It has even been suggested that phosphorus, which is usually regarded as a typical non-metallic element, does in this case act in the same way as a real metal. There are, ■ indeed, other reactions of phosphorus which point to it being an element of an 'amphoteric1 nature, capable of furnishing both negative and positive ions. It was noticed, however, that in many cases, the action between phosphorus and the metallic Salt solution/ solution was more complicated,and other products such as phosphides of the metal were found. -
Passivated Iodine Pentoxide Oxidizer for Potential Biocidal Nanoenergetic Applications Jingyu Feng, Guoqiang Jian, Qing Liu, and Michael R
Research Article www.acsami.org Passivated Iodine Pentoxide Oxidizer for Potential Biocidal Nanoenergetic Applications Jingyu Feng, Guoqiang Jian, Qing Liu, and Michael R. Zachariah* Department of Chemistry and Biochemistry, and Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States *S Supporting Information ABSTRACT: Iodine pentoxide (I2O5), also known as diiodine pentoxide, is a strong oxidizer which has been recently proposed as an iodine-rich oxidizer in nanoenergetic formulations, whose combustion products lead to molecular iodine as a biocidal agent. However, its highly hygroscopic nature hinders its performance as a strong oxidizer and an iodine releasing agent and prevents its implementation. In this work, we developed a gas phase assisted aerosol spray pyrolysis which enables creation of iron oxide passivated I2O5. Transmission electron microscopy elemental imaging as well as temperature-jump mass spectrometry confirmed the core shell fi nature of the material and the fact that I2O5 could be encapsulated in pure unhydrated form. Combustion performance nds an optimal coating thickness that enables combustion performance similar to a high performing CuO based thermite. KEYWORDS: passivated, aerosol spray pyrolysis, nanothermite, energetic materials, nanocomposite, biocide 1. INTRODUCTION spores, presumably because of the release of elemental iodine as a combustion product when reacted with aluminum:16 10Al + Nanoenergetic materials, including metal based fuels and metal → 3I2O5 5Al2O3 +3I2. However, I2O5 is sensitive to humid oxide oxidizers with typically nanosized dimensions, have been 20,21 shown to have reactive properties superior to traditional environments and reacts with water in the ambient air. This 1−4 not only increases the particle size which degrades combustion energetic materials. -
Recommended Methods for the Identification and Analysis Of
Vienna International Centre, P.O. Box 500, 1400 Vienna, Austria Tel: (+43-1) 26060-0, Fax: (+43-1) 26060-5866, www.unodc.org RECOMMENDED METHODS FOR THE IDENTIFICATION AND ANALYSIS OF AMPHETAMINE, METHAMPHETAMINE AND THEIR RING-SUBSTITUTED ANALOGUES IN SEIZED MATERIALS (revised and updated) MANUAL FOR USE BY NATIONAL DRUG TESTING LABORATORIES Laboratory and Scientific Section United Nations Office on Drugs and Crime Vienna RECOMMENDED METHODS FOR THE IDENTIFICATION AND ANALYSIS OF AMPHETAMINE, METHAMPHETAMINE AND THEIR RING-SUBSTITUTED ANALOGUES IN SEIZED MATERIALS (revised and updated) MANUAL FOR USE BY NATIONAL DRUG TESTING LABORATORIES UNITED NATIONS New York, 2006 Note Mention of company names and commercial products does not imply the endorse- ment of the United Nations. This publication has not been formally edited. ST/NAR/34 UNITED NATIONS PUBLICATION Sales No. E.06.XI.1 ISBN 92-1-148208-9 Acknowledgements UNODC’s Laboratory and Scientific Section wishes to express its thanks to the experts who participated in the Consultative Meeting on “The Review of Methods for the Identification and Analysis of Amphetamine-type Stimulants (ATS) and Their Ring-substituted Analogues in Seized Material” for their contribution to the contents of this manual. Ms. Rosa Alis Rodríguez, Laboratorio de Drogas y Sanidad de Baleares, Palma de Mallorca, Spain Dr. Hans Bergkvist, SKL—National Laboratory of Forensic Science, Linköping, Sweden Ms. Warank Boonchuay, Division of Narcotics Analysis, Department of Medical Sciences, Ministry of Public Health, Nonthaburi, Thailand Dr. Rainer Dahlenburg, Bundeskriminalamt/KT34, Wiesbaden, Germany Mr. Adrian V. Kemmenoe, The Forensic Science Service, Birmingham Laboratory, Birmingham, United Kingdom Dr. Tohru Kishi, National Research Institute of Police Science, Chiba, Japan Dr. -
The Replacement of Calcium Carbonate with Calcium Chloride and Calcium Fluoride in a Whiteware Body
Scholars' Mine Bachelors Theses Student Theses and Dissertations 1933 The replacement of calcium carbonate with calcium chloride and calcium fluoride in a whiteware body Charles Richard Rosenbaum Follow this and additional works at: https://scholarsmine.mst.edu/bachelors_theses Part of the Ceramic Materials Commons Department: Materials Science and Engineering Recommended Citation Rosenbaum, Charles Richard, "The replacement of calcium carbonate with calcium chloride and calcium fluoride in a whiteware body" (1933). Bachelors Theses. 58. https://scholarsmine.mst.edu/bachelors_theses/58 This Thesis - Open Access is brought to you for free and open access by Scholars' Mine. It has been accepted for inclusion in Bachelors Theses by an authorized administrator of Scholars' Mine. This work is protected by U. S. Copyright Law. Unauthorized use including reproduction for redistribution requires the permission of the copyright holder. For more information, please contact [email protected]. THE ~PLACEMENT OF CALCIUM CARBO ATE WITH CALCIUM CHLORIDE ~~ . AND CALCIUM FLUORIDE IN A WHITEWARE BODY BY CHARLES RICHARD ROSENBAUM 1\/ A ~HESIS ·submitted _to the faculty of. the SCHOOL OF MINES AND METALLURGY OF THE UNIVERSITY OF MISSOURI in partial-fulfillment rof.the ·work-requlred·for the Degree .. Of BACHELOR- OF.- SCIENCE IN· eERAMIC .. ENGINEERING Rolla, . Mo. 1933. Approved by a222. a<9zmt:d? ~ Professor of Ceramic Eng1neer~ng. '\ THE REPLACE1mNT OF CALCIUM CARBONATE WITH CALCIUM. CHLORIDE AND CALCIUM FLUORIDE IN A WHITEWARE BODY BY CHARLES RICHARD ROSENBAUM IY' A THESI.S submitted to the faculty of the SCHOOL OF MINES AND METALLURGY OF THE UNIVERSITY OF MISSOURI in partial fulfillment of the work required for the Degree Of BACHELOR OF SCIENCE IN CERAMIC ENGINEERING Rolla, Mo. -
Nature [December 22, 1904
180 NATURE [DECEMBER 22, 1904 As an example of the successful accomplishment this spherical globule when solidified forms the ruby. of a difficult task, we reproduce (Fig. I) the photo The cooling has to be very gradual, so that the crystal graph of kittiwake gulls nesting on the precipitous line particles have time to become regularly arranged, face of a cliff, approach to which was effected by climb or an opaque product is obtained. If the ovoid mass ing down a narrow gulley and then scrambling over is carefully detached when cold, it splits up into two seaweed-clad boulders, to the imminent peril of the nearly equal portions, but not along a cleavage-plane. camera. The product so obtained is !in individual crystal, and As a specimen of really excellent bird-photography, the direction of its principal optic axis is never very we present to our readers the picture of a group of different from that of the major axis of the ovoid. young ringed plovers (Fig. 2), the mottled down of The product when cut cannot be distinguished by which harmonises so admirably at a short distance with its chemical, physical, or optical properties from a their surroundings. stone cut from a natural ruby. The operation may If it be said that this notice is purely commendatory, be considered successful when the clear product weighs and contains nothing in the way of criticism, the reply 12 to IS carats, and has a real diameter of 5 or 6 is that we have found nothing to criticise or to con- millimetres.