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US 20030228333A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2003/0228333 A1 Fecht et al. (43) Pub. Date: Dec. 11, 2003

(54) SUBSTITUTED HYDROCARBYL Publication Classification FUNCTIONAL SILOXANES FOR HOUSEHOLD, HEALTH, AND PERSONAL (51) Int. Cl." ...... A61K 7/16; A61K 7/42; CARE APPLICATIONS A61K 7/135; A61K 31/695; A61K 7/06 (76) Inventors: Cassandre Michelle Fecht, Sanford, (52) U.S. Cl...... 424/401; 424/59; 514/63; MI (US); Deborah Lynn Meyers, 424/62; 424/49 Midland, MI (US); Heidi Marie Van Dort, Sanford, MI (US); Isabelle Van Reeth, Incourt (BE) (57) ABSTRACT Correspondence Address: DOW CORNING CORPORATION CO1232 Cosmetic, household, and medical compositions containing 2200 W. SALZBURG ROAD certain substituted hydrocarbyl functional siloxane fluids or P.O. BOX 994 certain Substituted hydrocarbyl functional Siloxane resins MIDLAND, MI 48686-0994 (US) provide good aesthetic, Solvency, and Stability performance, and are useful as delivery vehicles for personal, health, and (21) Appl. No.: 10/157,639 household care ingredients Such as pigments, antiperspirant Salts, drugs, Sunscreens, alpha-hydroxy fatty acids, and (22) Filed: May 28, 2002 Vitamins. US 2003/0228333 A1 Dec. 11, 2003

SUBSTITUTED HYDROCARBYL FUNCTIONAL SUMMARY OF THE INVENTION SILOXANES FOR HOUSEHOLD, HEALTH, AND PERSONAL CARE APPLICATIONS 0008. This invention relates to a composition which is a guar gum free and hydroxyStearic acid derivative free mix FIELD OF THE INVENTION ture of (i) a substituted hydrocarbyl functional siloxane fluid, or a Substituted hydrocarbyl functional Siloxane resin; 0001. In the household, health and personal care areas, and (ii) a cosmetic ingredient, a household care ingredient, the need exists for Silicone raw materials that contain both or a health care ingredient, and (iii) an optional cosmetic hydrophilic and hydrophobic functionality. To date, this active, a household care active, or a health care active Such need has been addressed with polyoxyalkylene and Silanol as an antiacne agent, anticaries agent, antidandruff agent, functional Silicone materials. These structures have a num antifungal agent, antimicrobial agent, antioxidant, antiper ber of limitations including unpleasant aesthetics and acid/ Spirant agent, cosmetic biocide, deodorant agent, external base instability, respectively. analgesic, oral care agent, oral care drug, oxidizing agent, 0002 The present invention relates to cosmetic, house reducing agent, skin bleaching agent, skin protectant, Sun hold and healthcare compositions containing Substituted Screen agent, UV light absorbing agent, pigments, moistur hydrocarbyl functional Siloxane Structures for improved izers, Vitamins, enzymes, optical brighteners, fabric Soften performance and/or Stability. In an alternate embodiment, ing agents, or . certain Substituted hydrocarbyl functional organosiloxane 0009. These and other features of the invention will resins can be included in the compositions. become apparent from a consideration of the detailed description. BACKGROUND OF THE INVENTION 0.003 Polar silicone compounds have found use in a DETAILED DESCRIPTION OF THE number of different types of products ranging from cosmet INVENTION ics to car polish formulations. Most of these products have 0010. The present invention is based on the unexpected been formulated as aerosol or pump Sprays, liquids, roll-on discovery that the inclusion of a substituted hydrocarbyl liquids, creams, emulsions, gels, gel-Solids, or Solid Stick functional Siloxane, in particular, results in personal care, formulations, and Sometimes comprise an additional active medical and household care compositions with novel prop material, e.g. Vitamins, erties. For example, compositions containing Such siloxanes 0004 alpha-hydroxy-acids, Zirconium salts or combina impart the following characteristics when compared to Simi tions thereof, incorporated into a Suitable carrier. lar formulations without Such siloxanes: (a) remain stable at relatively high and low pH; (b) compatibilize both polar and 0005 These products are designed to provide a variety of non-polar Solvents; (c) offer high lubricity; (d) mitigate skin benefits, for example, moisturize dry skin, mask Surface discomfort or irritation; (e) impart a Smooth, Soft, moist imperfections, and allow effective perspiration and odor texture, (f) evenly disperse active agents and pigments, (g) control while being cosmetically acceptable during and after detackify formulation components, (h) moisturize the skin; application onto the axillary region or other areas of the skin. (i) enhance the durability of formulation components; () Polar Silicone compounds used in these applications include enhance Surface Shine; (k) impart the Sensory performance polydiorganosiloxane-polyoxyalkylene copolymers and Sil of higher molecular weight Structures; (1) protect the hair anol functional Substituted Siloxane Structures. cuticle; (m) aid curl retention, (n) Sustain fragrance release; 0006 The preparation of siloxane-oxyalkylene copoly (o) impart Softness to Solid Substrates; (p) increase water mers by hydrosilylation of an organohydrogensiloxane absorbency of fabrics; (q) mask Surface imperfections; (r) (SiH) and an olefinically substituted polyoxyalkylene is well reduce whitening of antiperspirant salts, (s) modify formu known and reported in the literature. The hydrosilylation lation rheology, (t) improve particulate active Suspension; reaction is typically performed in a low molecular weight (u) improve ease of ironing, (v) enable the Suspension and Volatile Solvent Such as benzene, toluene, delivery of polar materials in non-polar Solvents; and (w) Xylene, or isopropanol to aid in handling the reactants, to enhance emulsion Stability. moderate an exothermic reaction or to promote the Solubility 0011 AS used herein, the terms personal care composi of the reactants. The CPA catalyzed reaction of Si-H tion, health care composition, and household care compo polymers with allyl ethers was disclosed in U.S. Pat. No. Sition are intended to mean typical materials commercially 2,823,218 (Feb. 11, 1958). Typically, although not exclu available as products or raw materials in consumer markets Sively, the Smallest oxyalkylene Substitutents disclosed in containing active and inactive ingredients. patents are EO and PO. This is because of the ready availability of the Starting materials and Synthetic ease of 0012. In the preferred embodiment, the compositions of making allyloxypolyethers with that minimum Substitution. the present invention comprise at least one Substituted hydrocarbyl functional Siloxane. These siloxanes generally 0007) While U.S. Pat. No. 5,486,566 (Jan. 23, 1996) and U.S. Pat. No. 6,060,044 (May 9, 2000) describe silicone have a formula Selected from the group consisting of: ethers containing only a single oxyalkylene unit in any RSiO(RR'SiO),SiR, chain, the compositions containing Such Silicone ethers must Rs. SiO(RSiO) (RR'SiO)SiRs, necessarily include guar gum or an hydroxyStearic acid RRSiO(RSiO)SiRR', derivative for effectiveness, whereas compositions accord ing to this invention possess the above described benefits RRSiO(RR'SiO)SiRR', without requiring the use of guar gum and hydroxyStearic R" RSiO(RSiO),(RR'SiO),SiRR', acid derivatives. R"RSiO(RSiO)SiRs, US 2003/0228333 A1 Dec. 11, 2003

RRSiO(RR'SiO)SiR, a nitro group. In addition, the hydrogen atom can be Sub R"RSiO(RSiO) (RR'SiO)SiR, and cyclic silox Stituted with a group containing a Sulfur atom to form anes of the formula -SOH. -(MeSiO) (MeR'SiO)-. 0022. The Substituted hydrocarbyl functional siloxanes of 0013 In these formulas, R is an alkyl, cycloalkyl, alk the present invention can be made by Standard processes enyl, aralkyl, or an aryl group containing 1-20 carbon atoms, Such as the hydrosilylation of organohydrogensiloxanes and R" is a group having one of the formulas (i)-(iv): olefinically substituted polyoxyalkylenes. The hydrosilyla tion reaction is typically performed in a low molecular -(CH2)(OCH2CH)OR (i) weight volatile hydrocarbon Solvent Such as benzene, tolu -(CH),(OCHCHCH)OR (ii) ene, Xylene, or isopropanol to aid in handling the reactants, -(CH),IOCHCH(CHCH.) IOR’ (iii) to moderate an exothermic reaction or to promote the Solubility of the reactants. Such processes are described, for -(R)OR (iv) example, in the 218 patent noted above, which is incorpo 0014) whereina is 3-11; b is 1-50; R is selected from the group consisting of hydrogen, an alkyl group, an aryl group, rated herein by reference. an arylalkyl group and an acyl group, X is 1-500, y is 1-40, 0023 These silicone compounds are useful in a number of different products, including hair care products Such as Z is 1-40, m is 1-6, n is 1-6, and the Sum of m+n is 3-12. hairsprays, , mousses, Styling gels and lotions, 0.015 For the sake of simplicity in nomenclature in the cream rinses/conditioners, hair tonics, hair dyes and colo Examples, these Substituted hydrocarbyl siloxanes are rants, permanent waves and bleaches. Also included are skin referred to as the CARBINOLFLUID. In preferred embodi care products Such as cleansers, moisturizers, conditioners, ments of the invention, and in the Examples, R is the methyl lipsticks, eye makeup, foundations, fingernail polish, Suntan group, R' is -(CH2),(OCH2CH)OR, products, antiperSpirant/deodorant products and depilato ries. Also included are household products Such as waxes, 0016 R is hydrogen, a is 3, X is polishes, heavy and light duty liquid cleaners, fabric Soft 0017 3-500, y and Z are 10-20, and m+n is 5. eners, ironing aids, laundry detergents, and window clean CS. 0.018. In the alternate embodiment, compositions of the 0024. Some typical ingredients used in these products are present invention can contain a Substituted hydrocarbyl Surfactants, pigments, Solvents, emollients, and carriers. For functional siloxane resin rather than a Substituted hydrocar example, the Solvents can include esters (for example, byl functional siloxane fluid. Suitable Substituted hydrocar isopropyl myristate and C2s alkyl lactate), water, Silicone byl functional siloxane resins have the formula fluids (for example, cyclomethicone, dimethicone), , (SQ), (R SiO2),(RSiO),(RSiO2){O, isopropanol, guerbet having 8-30 carbons, particu 2SiR,R), larly 12-22 carbons (for example, isolauryl alcohol, isocetyl 0019 where R is an alkyl group with 1-20 carbon atoms, alcohol, isostearyl alcohol), fatty alcohols (for example, a cycloalkyl group with 3-20 carbon atoms, an alkenyl group Stearyl alcohol, myristyl alcohol, oleyl alcohol), and ethoxy with 2-20 carbon atoms, an aralkyl group, or an aryl group; lated and propoxylated alcohols (for example, the polyeth R" is the same as R above, i.e., one of the formulas (i) to ylene glycol ether of lauryl alcohol that conforms to the (iv); and g is 1-15,000. In Such resins, c, d, e, and frepresent formula CH3(CH2)CH(OCH2CH), OH where r has an mole percents, such that c-100, c--dd-0, and c+d+e+f is 100. average value of 4 (Laureth-4); PPG-14 butyl ether, where Organosiloxane resins of this type typically contain about the “PPG-14' portion is the polymer of propylene oxide that 0.01-15 weight percent of silanol. conforms generally to the formula H(OCHC(CH)H),OH, where S has an average value of 14, or PPG-3 myristyl ether 0020. As used herein, the term hydrocarbyl is defined as which is the polypropylene glycol ether of myristyl alcohol any group consisting exclusively of carbon and hydrogen. that conforms tO the formula The hydrocarbyl group can be branched or unbranched, CH(CH)2CH(OCH(CH)CH), OH where t has an aver Saturated or unsaturated, and can contain one or more rings. age value of 3, or a hydrocarbon fluid. Some Suitable hydrocarbyl groups include alkyl, alkenyl, alkynyl, and aryl groups. Also included are alkyl, alkenyl, 0025 Hydrocarbon fluids are exemplified by organic alkynyl, and aryl groups which are Substituted with other hydrocarbon fluids Such as halogenated hydrocarbon fluids, aliphatic or cyclic hydrocarbyl groupS. Such as alkaryl, aliphatic hydrocarbon fluids, aromatic hydrocarbon fluids, alkenaryl, and alkynaryl. and mixtures of aromatic and aliphatic hydrocarbon fluids. The hydrocarbon fluids usually contain about 6 to about 12 0021. The term Substituted hydrocarbyl is therefore carbon atoms. Examples of suitable hydrocarbon fluids intended to mean any Such hydrocarbyl group wherein at include perchloroethylene, benzene, Xylene, toluene, min least one hydrogen atom has been Substituted with an atom eral oil fractions, kerosenes, naphthas, and petroleum frac other than hydrogen, or with a group of atoms containing at tions. Particularly preferred are isoparaffinic hydrocarbon least one atom other than hydrogen. For example, the fluids exemplified by isoparaffin fluids available from Exxon hydrogen atom can be Substituted with a halogen atom Such Mobil Chemical Company, Houston, Tex. U.S.A, sold as as a chlorine or fluorine atom. The hydrogen atom alterna IsoparE M Fluid (a C-C Isoparaffin), Isopar(R) C Fluid (a tively can be Substituted with an atom, or with a C7-C. Isoparaffin), IsoparE E Fluid (a C-C Isoparaffin), group containing an OXygen atom to form a hydroxy group, IsoparE G Fluid (a Co. Isoparaffin), Isopar?& L. Fluid (a an ether, an ester, an anhydride, an aldehyde, a ketone, or a C-C, Isoparaffin), Isopar?R H Fluid (a C1-C1, Isoparaffin), carboxylic acid. The hydrogen atom also can be replaced and combinations thereof. Mixtures of Solvents can also be with a group containing a nitrogen atom to form an amide or used. US 2003/0228333 A1 Dec. 11, 2003

0026. Another ingredient which can be used is an emol Ascorbyl Dipalmitate, Ascorbyl Methylsilanol Pectinate, lient, including compositions Such as guerbet alcohols (Such Ascorbyl Palmitate, Ascorbyl Stearate, BHA, p-Hydroxya as isocetyl alcohol or isoStearyl alcohol); esters (Such as nisole, BHT, t-Butyl Hydroquinone, Caffeic Acid, Camellia isopropyl palmitate, isopropyl isoStearate, octyl Stearate, Sinensis Oil, Chitosan Ascorbate, Chitosan Glycolate, Chi hexyl laurate and isostearyl lactate); a liquid mixture of tosan Salicylate, Chlorogenic Acids, Cysteine, Cysteine which are liquids at ambient temperatures HCI, Decyl Mercaptomethylimidazole, Erythorbic Acid, (Such as petroleum distillates and light mineral oils); etha Diamylhydroquinone, Di-t-Butylhydroquinone, Dicetyl nol, Volatile and non-volatile Silicone oils, highly branched Thiodipropionate, Dicyclopentadiene/t-Butylcresol Copoly hydrocarbons, and non-polar carboxylic acids. The emol mer, Digalloyl Trioleate, Dilauryl Thiodipropionate, lients can be included in the compositions of the present Dimyristyl Thiodipropionate, Dioleyl Tocopheryl Methylsi invention in amounts within the range of 0.01-70%, prefer lanol, Isoquercitrin, Diosmine, Disodium AScorbyl Sulfate, ably 0.1-25%, by weight, of the total weight of the compo Disodium Rutinyl Disulfate, Distearyl Thiodipropionate, Sition. Ditridecyl Thiodipropionate, Dodecyl Gallate, Ethyl Feru 0027. The carrier can include a wide variety of condi late, Ferulic Acid, Hydroquinone, Hydroxylamine HCI, tioning materials, Such as hydrocarbons, Silicone fluids, and Hydroxylamine Sulfate, Isooctyl Thioglycolate, Kojic Acid, cationic materials. The carrier can include Surfactants, Sus Madecassicoside, AScorbate, Magnesium pending agents, thickeners etc. Various additional compo Ascorbyl Phosphate, Melatonin, Methoxy-PEG-7 Rutinyl nents useful in these compositions are described in U.S. Pat. Succinate, Methylene Di-t-Butylcresol, Methylsilanol No. 4,387,090 (Jun. 7, 1983). Ascorbate, Nordihydroguaiaretic Acid, Octyl Gallate, Phe 0028 Topical cosmetic, and pharmaceutical composi nylthioglycolic Acid, Phloroglucinol, Potassium Ascorbyl tions according to the invention can contain a carrier, but the Tocopheryl Phosphate, Thiodiglycolamide, Potassium carrier should be cosmetically and/or pharmaceutically Sulfite, Propyl Gallate, Rosmarinic Acid, Rutin, acceptable, i.e., that it is Suitable for topical application to Ascorbate, Sodium Ascorbyl/Cholesteryl Phosphate, the skin, has good aesthetic properties, is compatible with Sodium Bisulfite, Sodium Erythorbate, Sodium Metabisul the Siloxane copolymers of the present invention, and will fide, Sodium Sulfite, Sodium Thioglycolate, Sorbityl Fur not cause any Safety or toxicity concerns. It can be formu fural, Tea Tree (Melaleuca Aftemifolia) Oil, Tocopheryl lated to include an emulsion as the carrier Such as an Acetate, Tetrahexyldecyl Ascorbate, Tetrahydrodiferuloyl oil-in-water emulsion, water-in-oil emulsion, water-in-oil methane, Tocopheryl Linoleate/Oleate, Thiodiglycol, Toco in-water emulsion, or oil-in-water-in-Silicone oil emulsion. pheryl Succinate, Thiodiglycolic Acid, Thioglycolic Acid, 0029. Some other suitable topical carriers include anhy Thiolactic Acid, Thiosalicylic Acid, Thiotaurine, Retinol, drous liquid Solvents Such as oils, alcohols, and Silicones Tocophereth-5, Tocophereth-10, Tocophereth-12, Toco (e.g., mineral oil, ethanol, isopropanol, dimethicone, phereth-18, Tocophereth-50, Tocopherol, Tocophersolan, cyclomethicone, and the like), aqueous-based single phase Tocopheryl Linoleate, Tocopheryl Nicotinate, Tocoquinone, Solvents (e.g., where the Viscosity of the Solvent has been o-Tolyl , Tris(Nonylphenyl)Phosphite, increased to form a solid or semi-solid by the addition of Ubiquinone, and Zinc Dibutyldithiocarbamate. appropriate gums, resins, Waxes, polymers, Salts, and the like). However, the preferred cosmetically and/or pharma 0033 Some examples of antiperspirant agents and ceutically acceptable topical carrier is a hydroalcoholic deodorant agents are Aluminum Chloride, Aluminum Zir System or an oil-in-water emulsion. When the carrier is an conium Tetrachlorohydrex GLY, Dichloro-m-Xylenol, Alu oil-in-water emulsion, it will include common ingredients minum Chlorohydrate, Aluminum Zirconium Tetrachloro generally used for preparing emulsions. hydrex PEG, Aluminum Chlorohydrex, Aluminum 0030) Some of the typical active ingredients used in Zirconium Tetrachlorohydrex PG, Aluminum Chlorohydrex products Such as these are antiacne agents, anticaries agents, PEG, Aluminum Zirconium Trichlorohydrate, Domiphen antidandruff agents, antifungal agents, antimicrobial agents, Bromide, Aluminum Chlorohydrex PG, Aluminum Zirco antioxidants, antiperspirant agents and deodorant agents, nium Trichlorohydrex GLY, , Aluminum cosmetic biocides, external analgesics, oral care agents, oral Dichlorohydrate, Ammonium Phenolsulfonate, Ketoglutaric care drugs, oxidizing agents, reducing agents, skin bleaching Acid, Aluminum Dichlorohydrex PEG, Benzalkonium Bro agents, Skin protectants, Sunscreen agents, UV light absorb mide, Lauryl Isoquinolinium Bromide, Aluminum Dichlo ing agents, enzymes, optical brighteners, fabric Softening rohydrex PG, Benzalkonium Cetyl Phosphate, Laurylpyri dinium Chloride, Aluminum Lactate, Benzalkonium agents, and Surfactants Chloride, Methylbenzethonium Chloride, Aluminum Phe 0.031) Some examples of antiacne agents are Salicylic nolsulfonate, BenZalkonium Saccharinate, , Alumi acid and Sulfur. Some examples of anticaries agents are num Sesquichlorohydrate, , Sodium Sodium , Sodium Monofluorophosphate, and Stan Bicarbonate, Aluminum Sesquichlorohydrex PEG, Bromo nous Fluoride. Some examples of antidandruff agents are chlorophene, Sodium Phenolsulfonate, Aluminum Ses Coal tar, Salicylic acid, Selenium Sulfide, Sulfur, and Zinc quichlorohydrex PG, , Tricloban, Pyrithione. Some examples of antifungal agents are Aluminum Sulfate, Chlorophyllin-Copper Complex, Tri Undecylenate, Undecylenic Acid, Zinc Undecylenate, and closan, Aluminum Zirconium Octachlorohydrate, Chlo PoVidone-. Some examples of antimicrobial agents rothymol, Zeolite, Aluminum Zirconium Octachlorohydrex are Alcohol, , Benzethonium Chlo GLY, Zinc Lactate, Aluminum Zirconium Pentachlorohy ride, Hydrogen , Methylbenzethonium Chloride, drate, Cloflucarban, Zinc Phenolsulfonate, Aluminum Zir Phenol, Poloxamer 188, and Povidone-Iodine. conium Pentachlorohydrex GLY, Chloride, 0.032 Some examples of antioxidants are Acetyl Cys Zinc Ricinoleate, Aluminum Zirconium Tetrachlorohydrate, teine, Arbutin, AScorbic Acid, AScorbic Acid Polypeptide, and Dichlorophene. US 2003/0228333 A1 Dec. 11, 2003

0034 Some examples of cosmetic biocides are Alumi phate, , Ammonium Monofluorophosphate, num Phenolsulfonate, Ammonium Phenolsulfonate, Baku Glycerin, Sodium Fluorosilicate, Ammonium Phosphate, chiol, Benzalkonium Bromide, Benzalkonium Cetyl Phos , Sodium Glycerophosphate, , phate, Benzalkonium Chloride, Benzalkonium Saccharinate, Hydrated Silica, Sodium Metaphosphate, , Benzethonium Chloride, Potassium Phenoxide, Benzox Hydrogenated Starch Hydrolysate, Sodium Monofluoro iquine, , Bispyrithione, Boric Acid, phosphate, Calcium Glycerophosphate, , Bromochlorophene, Camphor Benzalkonium Methosulfate, Sodium Phytate, Calcium Monofluorophosphate, Hydroxya Captan, Cetalkonium Chloride, Cetearalkonium Bromide, patite, Sodium Styrene/Acrylates/Divinylbenzene, Calcium Cetethyldimonium Bromide, Bromide, Cetri Phosphate, Magnesium Fluoride, Calcium Pyrophosphate, monium Chloride, Cetrimonium Methosulfate, Cetrimo Magnesium Fluorosilicate, Stannous Fluoride, Cetylamine nium Saccharinate, Cetrimonium Tosylate, Cetylpyridinium Hydrofluoride, Magnesium Glycerophosphate, Stannous Chloride, Chloramine T, , Chlorhexidine Pyropbosphate, Cetylpyridinium Chloride, Manganese Diacetate, Chlorhexidine Digluconate, Chlorhexidine Dihy Glycerophosphate, Strontium Acetate, Chlorohexidine, drochloride, p-Chloro-m-Cresol, Chlorophene, p-Chlo , Strontium Chloride, Chlorohexidine Diacetate, rophenol, Chlorothymol, , Chlorphenesin, Phytic Acid, Tetrapotassium Pyrophosphate, Chlorohexidine Ciclopirox Olamine, Climbazole, Cloflucarban, Clotrima Digluconate, Polyethylene, Tetrasodium Pyrophosphate, zole, Coal Tar, Colloidal Sulfur, o-Cymen-5-ol, Dequal Chlorohexidine Dihydrochloride, Potassium Fluoride, Tri inium Acetate, Dequalinium Chloride, Dibromopropami calcium Phosphate, Chlorothymol, Potassium Fluorosili dine Disethionate, Dichlorobenzyl Alcohol, Dichlorophene, cate, Zinc Chloride, Dequalinium Chloride, Potassium Glyc Dichlorophenyl Imidazoldioxolan, Dichloro-m-Xylenol, erophosphate, Zinc Citrate, Diammonium Phosphate, Diiodomethyltolylsulfone, Dimethylol Ethylene Thiourea, Potassium Monofluorophosphate, Zinc Sulfate, and Dical Diphenylmethyl Piperazinylbenzimidazole, Domiphen Bro cium Phosphate. mide, 7-Ethylbicyclooxazolidine, Fluorosalan, Formalde hyde, Glutaral, Hexachlorophene, , Hexamidine 0037 Some examples of oral care drugs are Ammonium Diisethionate, Hexamidine Diparaben, Hexamidine Para Alum, Potassium Alum, Benzyl Alcohol, Carbamide Perox ben, Hexetidine, Hydrogen Peroxide, Hydroxymethyl ide, Elm Bark Extract, Gelatin, Glycerin, Hydrogen Perox DioxoaZabicyclooctane, Ichthammol, Isopropyl CreSol, ide, Menthol, Pectin, Phenol, , Sodium Lapyrium Chloride, Lauralkonium Bromide, Lauralkonium Perborate, and Zinc Chloride. Chloride, Laurtrimonium Bromide, Laurtrimonium Chlo 0038. Some examples of oxidizing agents are Ammo ride, Laurtrimonium Trichlorophenoxide, Lauryl Isoquino nium Persulfate, , Hydrogen Peroxide, linium Bromide, Lauryl Isoquinolinium Saccharinate, Lau Magnesium Peroxide, Melamine Peroxide, Potassium Bro rylpyridinium Chloride, Mercuric Oxide, Methenamine, mate, Potassium Caroate, Potassium Chlorate, Potassium Methenammonium Chloride, Methylbenzethonium Chlo Persulfate, Sodium Bromate, Sodium Carbonate Peroxide, ride, Myristalkonium Chloride, Myristalkonium Sacchari Sodium Chlorate, Sodium Iodate, , nate, Myrtrimonium Bromide, Nonoxynol-9 Iodine, Nonox Sodium Persulfate, Strontium Dioxide, Strontium Peroxide, ynol-12 Iodine, Olealkonium Chloride, Oxyquinoline, Urea Peroxide, and Zinc Peroxide. Oxyquinoline Benzoate, Oxyquinoline Sulfate, PEG-2 Coco-Benzonium Chloride, PEG-10 Coco-Benzonium 0039. Some examples of reducing agents are Ammonium Chloride, PEG-6 Undecylenate, PEG-8 Undecylenate, Phe Bisulfite, Ammonium Sulfite, Ammonium Thioglycolate, nol, o-Phenylphenol, Phenyl Salicylate, Piroctone Olamine, Ammonium Thiolactate, Cystemaine HCl, Cystein, Cys SulfoSuccinylundecylenate, Potassium o-Phenylphenate, teine HCl, Ethanolamine Thioglycolate, Glutathione, Glyc Potassium Salicylate, Potassium Troclosene, Propionic eryl Thioglycolate, Glyceryl Thioproprionate, Hydro Acid, PVP-Iodine, Quaternium-8, Quaternium-14, Quater quinone, p-Hydroxyanisole, Isooctyl Thioglycolate, nium-24, Sodium Phenolsulfonate, Sodium Phenoxide, Magnesium Thioglycolate, Mercaptopropionic Acid, Potas Sodium o-Phenylphenate, Sodium Shale Oil Sulfonate, sium Metabisulfite, Potassium Sulfite, Potassium Thiogly Sodium Usnate, Thiabendazole, 2,2'-Thiobis(4-Chlorophe colate, Sodium Bisulfite, Sodium Hydrosulfite, Sodium nol), Thiram, Triacetin, , , Trioctyl Hydroxymethane Sulfonate, Sodium Metabisulfite, Sodium dodecyl Borate, Undecylenamidopropylamine Oxide, Unde Sulfite, Sodium Thioglycolate, Strontium Thioglycolate, cyleneth-6, Undecylenic Acid, Zinc Acetate, Zinc Aspartate, Superoxide Dismutase, Thioglycerin, Thioglycolic Acid, Zinc Borate, Zinc Chloride, Zinc Citrate, Zinc Cysteinate, Thiolactic Acid, Thiosalicylic Acid, and Zinc Formaldehyde Zinc Dibutyldithiocarbamate, Zinc Gluconate, Zinc Sulfoxylate. Glutamate, Zinc Lactate, Zinc Phenolsulfonate, Zinc 0040. An example of a skin bleaching agent is Hydro Pyrithione, Zinc Sulfate, and Zinc Undecylenate. quinone. 0035) Some examples of external analgesics are Benzyl Alcohol, Capsicum Oleoresin (Capsicum Frutescens Oleo 0041. Some examples of skin protectants are Allantoin, resin), Methyl Salicylate, Camphor, Phenol, Capsaicin, Juni Aluminum Acetate, Aluminum Hydroxide, Aluminum Sul per Tar (Juniperus Oxycedrus Tar), Phenolate Sodium fate, Calamine, Cocoa Butter, Cod Liver Oil, Colloidal (Sodium Phenoxide), Capsicum (Capsicum Frutescens), Oatmeal, Dimethicone, Glycerin, Kaolin, Lanolin, Mineral Menthol, Resorcinol, Methyl Nicotinate, and Turpentine Oil Oil, Petrolatum, Shark Liver Oil, Sodium Bicarbonate, , (Turpentine). Witch Hazel, Zinc Acetate, Zinc Carbonate, and Zinc Oxide. 0.036 Some examples of oral care agents are Aluminum 0042 Some examples of sunscreen agents are Aminoben Fluoride, Dicalcium Phosphate Dihydrate, Sodium Bicar Zoic Acid, Cinoxate, Diethanolamine Methoxycinnamate, bonate, Ammonium Fluoride, , Sodium Digalloyl Trioleate, Dioxybenzone, Ethyl 4-bis(Hydrox Chloride, Ammonium Fluorosilicate, Ferric Glycerophos ypropyl) Aminobenzoate, Glyceryl Aminobenzoate, Homo US 2003/0228333 A1 Dec. 11, 2003 salate, Lawsone with Dihydroxyacetone, Menthyl Anthra nilate, Octocrylene, Octyl Methoxycinnamate, Octyl Salicylate, Oxybenzone, Padimate O, Phenylbenzimidazole Sulfonic Acid, Red Petrolatum, Sulisobenzone, Titanium Ingredient Weight Percent Dioxide, and Trolamine Salicylate. Decamethylcyclopentasiloxane (D5) 38 Carbinol Fluid 15 0043. Some examples of UV light absorbing agents are Aluminum Zirconium Acetaminosalol, Allatoin PABA, Benzalphthalide, Ben Tetrachlorohydrex-Gly 25 Zophenone, BenZophenone 1-12, 3-Benzylidene Camphor, (AZG-370, Summit Research Labs, Benzylidenecamphor Hydrolyzed Collagen Sulfonamide, Flemington, New Jersey) Benzylidene Camphor Sulfonic Acid, Benzyl Salicylate, Hydrogenated 5 Bornelone, Bumetriozole, Butyl Methoxydibenzoyl Talc 1. methane, Butyl PABA, Ceria/Silica, Ceria/Silica Talc, Cino Stearyl Alcohol 16 Xate, DEA-Methoxycinnamate, Dibenzoxazol Naphthalene, Di-t-Butyl Hydroxybenzylidene Camphor, Digalloyl Tri oleate, Diisopropyl Methyl Cinnamate, Dimethyl PABA Example 2 Ethyl Cetearyldimonium Tosylate, Dioctyl Butamido Tria Zone, Diphenyl Carbomethoxy Acetoxy Naphthopyran, Cosmetic Foundation Disodium Bisethylphenyl Tiamminotriazine Stilbenedisul fonate, Disodium Distyrylbiphenyl Triaminotriazine Stil 0046) A pigment premix was made by mixing the fol benedisulfonate, Disodium Distyrylbiphenyl Disulfonate, lowing amounts of the following ingredients: Drometrizole, Drometrizole Trisiloxane, Ethyl Dihydrox ypropyl PABA, Ethyl Diisopropylcinnamate, Ethyl Meth oxycinnamate, Ethyl PABA, Ethyl Urocanate, Etrocrylene Ferulic Acid, Glyceryl Octanoate Dimethoxycinnamate, Pigment Premix Weight Percent Glyceryl PABA, Glycol Salicylate, Homosalate, Isoamyl D5 SO.O p-Methoxycinnamate, Isopropylbenzyl Salicylate, Isopropyl Caprylyl Silane treated Titanium Dioxide 13.2 Dibenzolylmethane, Isopropyl Methoxycinnamate, Menthyl Caprylyl Silane treated Red Iron Oxide 11.4 Anthranilate, Menthyl Salicylate, 4-Methylbenzylidene, Caprylyl Silane treated Yellow Iron Oxide 18.3 Camphor, Octocrylene, Octrizole, Octyl Dimethyl PABA, Caprylyl Silane treated Black Iron Oxide 7.1 Octyl Methoxycinnamate, Octyl Salicylate, Octyl Triazone, PABA, PEG-25 PABA, Pentyl Dimethyl PABA, Phenylben Zimidazole Sulfonic Acid, Polyacrylamidomethyl Ben 0047 Phase A was them made by mixing the following Zylidene Camphor, Potassium Methoxycinnamate, Potas amounts of the following ingredients at 400 rpm using a dual sium Phenylbenzimidazole Sulfonate, Red Petrolatum, blade emulsion mixing Setup. D5 in the Silicone polyether Sodium Phenylbenzimidazole Sulfonate, Sodium Urocan used in Phase A is decamethylcyclopentasiloxane. ate, TEA-Phenylbenzimidazole Sulfonate, TEA-Salicylate, Terephthalylidene Dicamphor Sulfonic Acid, Titanium Dioxide, TriPABA Panthenol, Urocanic Acid, and VA/Cro tonates/Methacryloxybenzophenone-1 Copolymer. Phase A Weight Percent Pigment Premix 28.5 0044) Compositions according to the invention can be Silicone Polyether in D5 7.5 formed by combining Such components in the following Carbinol Fluid 8.0 ranges expressed as weight percent, i.e., (i) 0.1-99.9 percent of the substituted hydrocarbyl functional siloxane fluid or the substituted hydrocarbyl functional siloxane resin; (ii) 0.1 0048 Phase B was them made by mixing the following to 99.9 percent of the cosmetic ingredient, household care amounts of the following ingredients with a magnetic stir ingredient, or health care ingredient; (iii) 0.1-40 percent of bar. a cosmetic active, household care active, or health care active; and (iv) the balance to 100 percent being water, an organic Solvent, a Silicone Solvent, or one or more optional ingredients, depending upon the particular type of compo Phase B Weight Percent Sition being prepared, and its intended end use or applica Water 54.8 tion. Generally, Such compositions can generally be pre Sodium Chloride 1.O pared at room temperature, using simple propeller mixers, Polyoxyethylene (20) Sorbitan O.2 Brookfield counter-rotating mixers, or homogenizing mix Monolaurate (Tween 20) erS. No special equipment or processing conditions are typically required. 0049 Phase B was then slowly added to phase Ausing an EXAMPLES addition funnel. The mixture was then mixed an additional Example 1 10 minutes at 1376 rpm. AntiperSpirant Stick Example 3 0.045 An antiperspirant stick was made by simulta neously mixing the following amounts of the following Fabric Softener ingredients using a propellerblade at 1200 rpm. The mixture 0050. A fabric softener was made by simultaneously was heated to 80 C. until fully melted, then cooled to 60 mixing the following amounts of the following ingredients C. with Stirring, and poured into AP Stick containers. using a magnetic Stir bar until thoroughly blended. US 2003/0228333 A1 Dec. 11, 2003

Example 6 Hair Conditioner Ingredient Weight Percent 0054) A hair conditioner was made by the following Tetranyl L1/90 17.8 process. The water in Phase A was heated to about 5 C. and Magnesium Chloride O.1 Preservative (Formol) O.1 then the hydroxyethyl cellulose and Carbinol Fluid 2.O was added. Water 8O.O 0055. The mixture was mixed until uniform. The ingre dients of phase B were mixed together and heated to 60-70 C. using a water bath. Phase C was heated to 80° C. and 0051) Tetranyl L1/90 is Dihydrogenated Tallowoylethyl added to phase B while stirring at 800 RPM. The mixture Hydroxyethylmonium Methosulfate, a fabric soft was stirred for an additional 10 minutes then added to Phase ener manufactured by Kao Corporation. A with gentle mixing and continued until uniform. The mixture was then cooled to room temperature with gentle Example 4 mixing, then Phase D was added and mixed for an additional 10 minutes. Hair Gel 0.052 A hair gel was made by the following process. The ingredients in Phase A were mixed together at 500 RPM, Weight Percent using a dual blade Set up. The mixing Speed was increased to 800 RPM and Phase B was added incrementally to Phase Phase A A, and then stirred until uniform Phase C was added. The Deionized Water SO.O mixing speed was increased to 1376 RPM and continued for Hydroxyethyl Cellulose 1.5 an additional 10 minutes. (Natrosol 250 HHR, Hercules Inc., Wilmington, Delaware) Cetrimonium Chloride O.3 (Arquad 16-29, Akzo Nobel Chemicals, Inc., Chicago, Illinois) Weight Percent Phase B Phase A Cetearyl Alcohol 1.O Polyacrylamide (and) Isoparaffin (and) Laureth-7 1.5 Glyceryl stearate (and) PEG 100 stearate 1.O (Sepigel 305, Seppic, Paris, France) (Arlacel 165, Uniqema (ICI Surfactants), Silicone Polyether in D5 2.O Wilmington, Delaware) Glycerin 40.O Carbinol Fluid 2.O Phase B Phase C

Deionized water 46.5 Deionized Water 44.2 Phase C Phase D Preservative, DMDM Hydantoin O.2 Carbinol Fluid 5.0 (Glydant, Lonza Inc., Fair Lawn, New Jersey)

Example 5 Example 7 Anhydrous Roll-On Antiperspirant Water-In-Oil Moisturizer 0.053 An anhydrous roll-on antiperspirant was made by 0056. A water-in-oil moisturizer was made using the the following process. The ingredients in Phase A were following procedure. Phase A was mixed at 300 RPM and mixed together at 800 RPM until homogeneous. Phase B heated to 40 C. to solubilize the petrolatum and lanolin. was then slowly added to Phase A, and then mixed for an Phase B was made by dissolving the Sodium chloride in the additional 15 minutes. water and then adding glycerin and mixing until uniform. Using an addition funnel, Phase B was slowly added to Phase A while mixing at 1376 RPM. After the addition was complete, preservative was added and mixing continued for Weight Percent 10 minutes. The resultant cream was passed through a Phase A Gifford-Wood homogenizer for 3 minutes.

D5 7O.O Carbinol Fluid 5.0 Cyclomethicone (and) Quaternium 18 Hectorite 3.0 Weight Percent (and) SDA 40 (Bentone Gel VS-5, Rheox Inc., Highstown, New Jersey) Phase A 200 Proof Ethanol 2.O Phase B Crosslinked Silicone Polyether 2.O (Laurylmethicone Copolyol) Aluminum Zirconium Tetrachlorohydrex-Gly 2O.O Mineral Oil 1O.O Petrolatum 2.O US 2003/0228333 A1 Dec. 11, 2003

RRSiO(RSiO) (RR'SiO)SiRR', -continued R"RSiO(RSiO)SiR, Weight Percent RRSiO(RR'SiO),SiR, R"RSiO(RSiO) (RR'SiO)SiR, and cyclic silox Lanolin 1.O anes of the formula Isopropyl Myristate, (Emerest 2314, 2.O Henkel Corp./Emery Group, (MeSiO) (MeR'SiO)- Ambler, Pennsylvania) Carbinol Fluid 1.O where R is an alkyl, cycloalkyl, alkenyl, aralkyl, or an aryl D5 5.0 group containing 1-20 carbon atoms; R is a group Phase B having one of the formulas (i)-(iv): Glycerin 5.0 -(CH),(OCHCH)OR’ (i) Sodium Chloride 2.O Deionized Water 69.8 -(CH),(OCHCHCH)OR’ (ii) Preservative, Diazolidinyl urea & parabens, O.2 -(CH),IOCHCH(CHCH.) IOR’ (iii) Germaben II, International Specialty Product/ISP, Wayne, New Jersey) -(R)OR’ (iv) in which a is 3-11; b is 1-50; R is selected from the group consisting of hydrogen, an alkyl group, an aryl group, 0057 Compositions prepared according to the invention an arylalkyl group and an acyl group; X is 1-500, y is can be used in various over-the-counter (OTC) personal care 1-40, Z is 1-40, m is 1-6, n is 1-6, and the Sum of m+n compositions, health care compositions, and household care is 3-12. compositions, but especially in the personal care arena. 4. A method of providing a cosmetic property, a house Thus, they can be used in antiperspirants, deodorants, skin hold care property, or a health care property to a Substrate creams, skin care lotions, moisturizers, facial treatments comprising applying to the Substrate a composition accord Such as acne or wrinkle removers, personal and facial cleansers, bath oils, perfumes, colognes, Sachets, Sun ing to claim 1. Screens, pre-shave and after-shave lotions, liquid Soaps, 5. A product containing the composition of claim 1 Shaving Soaps, Shaving lathers, hair Shampoos, hair condi Selected from the group consisting of hairsprays, Shampoos, tioners, hair sprays, mousses, permanents, depilatories, hair mousses, Styling gels, Styling lotions, cream rinses, condi cuticle coats, make-ups, color cosmetics, foundations, tioners, hair tonics, hair dyes, hair colorants, permanent blushes, lipsticks, lip balms, eyeliners, mascaras, oil remov waves, bleaches, hair cuticle coats, skin cleansers, moistur ers, color cosmetic removers, nail polishes, and powders. izers, lipsticks, eye makeup, fingernail polish, Suntan prod ucts, antiperSpirants, deodorants, depilatories, household 0.058 Other variations may be made in compounds, com waxes, polishes, heavy duty liquid cleaners, light duty liquid positions, and methods described herein without departing from the essential features of the invention. The embodi cleaners, fabric Softeners, laundry detergents, ironing aids, ments of the invention specifically illustrated herein are and window cleaners. exemplary only and not intended as limitations on their 6. A composition comprising a guar gum free and hydrox Scope except as defined in the appended claims. yStearic acid derivative free mixture of (i) a Substituted hydrocarbyl functional siloxane resin 1. A composition comprising a guar gum free and hydrox having the formula yStearic acid derivative free mixture of (i) at least one Substituted hydrocarbyl functional siloxane fluid containing Sigi SiO2),(R'SiO.R.S.O.) to, only a single oxyalkylene unit in any chain; and (ii) at least where R is an alkyl group with 1-20 carbon atoms, a one cosmetic ingredient, household care ingredient, or cycloalkyl group with 3-20 carbon atoms, an alkenyl health care ingredient, other than an active cosmetic, house group with 2-20 carbon atoms, an aralkyl group, or an hold care, or health care ingredient. aryl group; 2. A composition according to claim 1 further comprising (iii) at least one cosmetic, household care, or health care R" is a group having one of the formulas (i)-(iv): active ingredient Selected from the group consisting of antiacne agents, anticaries agents, antidandruff agents, anti -(CH),(OCHCH)OR’ (i) fungal agents, antimicrobial agents, antioxidants, antiperSpi -(CH),(OCHCHCH)OR’ (ii) rant agents, cosmetic biocides, deodorant agents, external -(CH),IOCHCH(CHCH.) IOR’ (iii) analgesics, oral care agents, oral care drugs, oxidizing agents, reducing agents, skin bleaching agents, Skin pro -(R)OR’ (iv) tectants, Sunscreen agents, UV light absorbing agents, pig in which a is 3-11; b is 1-50; R is selected from the group ments, moisturizers, Vitamins, enzymes, optical brighteners, consisting of hydrogen, an alkyl group, an aryl group, fabric Softening agents, and Surfactants. an arylalkyl group and an acyl group; X is 1-500, y is 3. A composition according to claim 1 in which the 1-40, Z is 1-40, m is 1-6, n is 1-6, and the Sum of m+n substituted hydrocarbyl functional siloxane fluid has a for is 3-12; g is 1-15,000; c, d, e, and fare mole percents mula Selected from the group consisting of: Such that c is less than 100, c+d is more than 0, and c+d+e+f is 100; and RSiO(RR'SiO),SiR, (ii) at least one cosmetic ingredient, household care Rs. SiO(RSiO) (RR'SiO)SiRs, ingredient, or health care ingredient, other than an RRSiO(RSiO)SiRR', active cosmetic, household care, or health care ingre RRSiO(RR'SiOSiRR', dient. US 2003/0228333 A1 Dec. 11, 2003

7. A composition according to claim 6 further comprising 10. A composition comprising a guar gum free and (iii) at least one cosmetic, household care, or health care hydroxyStearic acid derivative free mixture of (i) at least one active ingredient Selected from the group consisting of antiacne agents, anticaries agents, antidandruff agents, anti substituted hydrocarbyl functional siloxane fluid; and (ii) at fungal agents, antimicrobial agents, antioxidants, antiperSpi least one cosmetic ingredient, household care ingredient, or rant agents, cosmetic biocides, deodorant agents, external health care ingredient, other than an active cosmetic, house analgesics, oral care agents, oral care drugs, oxidizing hold care, or health care ingredient. agents, reducing agents, skin bleaching agents, Skin pro tectants, Sunscreen agents, UV light absorbing agents, pig 11. A composition according to claim 10 wherein the ments, moisturizers, Vitamins. enzymes, optical brighteners, substituted hydrocarbyl functional siloxane fluid is a fabric Softening agents, and Surfactants. monoallylether modified Siloxane. 8. A method of providing a cosmetic property, a house 12. A composition according to claim 11 further compris hold care property, or a health care property to a Substrate ing (iii) at least one cosmetic, household care, or health care comprising applying to the Substrate a composition accord active ingredient Selected from the group consisting of ing to claim 6. antiacne agents, anticaries agents, antidandruff agents, anti 9. A product containing the composition of claim 6 fungal agents, antimicrobial agents, antioxidants, antiperSpi Selected from the group consisting of hairsprays, Shampoos, mousses, Styling gels, Styling lotions, cream rinses, condi rant agents, cosmetic biocides, deodorant agents, external tioners, hair tonics, hair dyes, hair colorants, permanent analgesics, oral care agents, oral care drugs, oxidizing waves, bleaches, hair cuticle coats, skin cleansers, moistur agents, reducing agents, skin bleaching agents, Skin pro izers, lipsticks, eye makeup, fingernail polish, Suntan prod tectants, Sunscreen agents, UV light absorbing agents, pig ucts, antiperSpirants, deodorants, depilatories, household ments, moisturizers, Vitamins, enzymes, optical brighteners, waxes, polishes, heavy duty liquid cleaners, light duty liquid fabric Softening agents, and Surfactants. cleaners, fabric Softeners, laundry detergents, ironing aids, and window cleaners.