What Are the Sources of Air Pollution?
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MTBE and New Hampshire's Waters
Remediating New Hampshire’s Groundwater A Comprehensive Study of MTBE in New Hampshire and Amicus Curiae Brief for State of New Hampshire v. Hess Corporation et al. A Major Qualifying Project Submitted to the faculty of Worcester Polytechnic Institute In partial fulfillment of the requirements for the Degree of Bachelor of Arts In Environmental & Sustainability Studies Susan Brennan Project Advisor: Robert Krueger March 2, 2013 2 Abstract New Hampshire’s groundwater has been contaminated by the gasoline additive methyl tertiary butyl ether (MTBE), a chemical that has dramatic repercussions on the environment. Once in the groundwater, MTBE can be difficult and expensive to treat and remove. New Hampshire hopes to hold the oil corporations that used MTBE in their gasoline accountable for the pollution caused by the additive through the Superior Court case State of New Hampshire v. Hess Corporation et al. This project both summarizes background research on MTBE and its implications on New Hampshire’s groundwater, as well as provides an amicus curiae brief in support of the state of New Hampshire in the case against the oil corporations. 3 Table of Contents Abstract ......................................................................................................................................................... 2 Technical Report What is MTBE? .............................................................................................................................................. 5 MTBE and United States Legislation ............................................................................................................ -
Common Myths and Misconceptions About the Behavior and Impact of MTBE Released from Petroleum Products
Transactions on Ecology and the Environment vol 65, © 2003 WIT Press, www.witpress.com, ISSN 1743-3541 Common myths and misconceptions about the behavior and impact of MTBE released from petroleum products R. E. woodward' & R. L. sloan2 '~ievvaEnvironmental Services, Inc., Houston, TX 2 Lyondell Chemical Company, Channelview, TX Abstract Auto fuel regulatory-mandates, to decrease the aromatic content of fuels and to reduce exhaust emissions, have led to the expanded use of additives to oxygenate auto fuels in the European Union (EU) and United States (US). The economical ether oxygenates, methyl tertiary butyl ether (MTBE) or ethyl tertiary butyl ether (ETBE) are frequently the oxygenate of choice because they deliver oxygen without increasing the Reid Vapor Pressure (RVP) or altering the fungible characteristics of autofuel. However, transport of auto fuels by common carriers that also transport heating oil and other heavier petroleum products has lead to the discovery of trace concentrations of auto fuel in many petroleum products. Subsequent leaks and spills during storage and handling of petroleum products result in the release of Auto fuel constituents to the environment. Critical review of 12 myths and misconceptions about MTBE in auto fuels reveals the concepts were conceived to rationalize early field observations andlor incomplete data sets. Closer scrutiny, in light of recent laboratory investigations, field data, case studies and world literature, indicates the myths are unsubstantiated misconceptions and assumptions about the behavior of ether oxygenates in the environment. Commonly held myths focus on four general areas of fuel and fuel oxygenates management: storageldispensing, hydrology, remediation, and health effects. Storageldispensing misconceptions address materials stability to ethers in fuel and the environmental forensics of fuel systems failure. -
But You Said We Could Do It: Oil Companies
"But You Said We Could Do It!": Oil Companies' Liability for the Unintended Consequence of MTBE Water Contamination CarrieL. Williamson* In 1990 Clean Air Act Amendments, Congress mandated the addition of an oxygenate to gasoline in an attempt to improve air quality. However, using methyl tertiary butyl ether (MTBE), the most frequently added oxygenate, has created another environmental problem: water contamination. Private individuals and public water utilities are suing oil companies to remedy MTBE water contamination, and some oil companies have successfully raisedpreemption arguments to escape liabilityfor contamination. This comment argues that judges should not be persuaded by these preemption arguments; oil companies should be responsible for remedying MTBE contamination. CONTENTS Introdu ction .......................................................................... 3 16 I. Introduction of MTBE to Fuels and Its Potential Consequences .............................................................. 3 17 A. Legislative Introduction of MTBE ............................ 317 B. Characteristics of MTBE and Water Pollution .......... 320 C. Health Effects of MTBE ........................................... 321 D. MTBE and Air Pollution .......................................... 322 II. Restrictions on Use ....................................................... 323 III. Preemption of State Bans and State Law Claims ........... 324 A. Preemption Doctrine ............................. 326 Copyright © 2002 by the Regents of the University -
Chapter Eleven
chapter eleven Regulation of Fuels and Fuel Additives Jonathan S. Martel, Jeremy D. Peterson, Sarah Greer, and Tom Glazer Introduction This chapter focuses on vehicle fuels as the counterpart to the vehicle in deter- mining air pollutant emissions. Common conventional fuels such as gasoline and diesel fuel contain hundreds of separate organic chemical compounds. These compounds may evaporate into the air, react in the atmosphere to create other pollutants (e.g., ozone and particulate matter), and interact to affect the fuel’s combustion properties and tailpipe emissions. In addition, gasoline and diesel fuel contain additives designed to enhance performance and to improve vehicle main- tenance. These additives introduce many more chemical compounds that also are combusted and emitted. Unlike gasoline and diesel fuel, alternative fuels such as compressed natural gas (CNG), liquefied petroleum gas (LPG), methanol, and ethanol generally consist of a single compound and, if liquid, may be blended with gasoline. Even the simpler alternative fuels, however, react with constituents of the air during combustion to generate pollutants. Measuring the emissions impacts of fuels presents special challenges. The motor vehicle emission standards discussed in chapter 10 are based on emissions testing using standardized test fuels. Vehicles in use actually encounter fuels with varying compositions. The fuel composition can affect the same pollutants that are addressed in the vehicle regulations: hydrocarbons and nitrogen oxides (NOx) that are the precursors to ozone and urban smog, toxic air pollutants, carbon monoxide (CO), and particulate matter. Furthermore, changes in fuel composition can have different effects depending on the characteristics of the vehicle in which the fuel is burned. -
Biofuels - at What Cost?
BIOFUELS - AT WHAT COST? Government support for ethanol and biodiesel in the United States One of a series of reports addressing subsidies for biofuels in Australia, Brazil, Canada, the European Union, Switzerland and the United States. October 2006 Prepared by: Doug Koplow, Earth Track, Inc. Cambridge,MA Prepared for: The Global Subsidies Initiative (GSI) of the International Institute for Sustainable Development (IISD) Geneva, Switzerland Biofuels – At What Cost? Government support for ethanol and biodiesel in the United States One of a series of reports addressing subsidies for biofuels in Australia, Brazil, Canada, the European Union, Switzerland and the United States. October 2006 Prepared by: Doug Koplow, Earth Track, Inc. Cambridge, MA Prepared for: The Global Subsidies Initiative (GSI) of the International Institute for Sustainable Development (IISD) Geneva, Switzerland Biofuels – At What Cost? Government support for ethanol and biodiesel in the United States One of a series of reports addressing subsidies for biofuels in Australia, Brazil, Canada, the European Union, Switzerland and the United States. October 2006 Prepared by: Doug Koplow, Earth Track, Inc. Cambridge, MA Prepared for: The Global Subsidies Initiative (GSI) of the International Institute for Sustainable Development (IISD) Geneva, Switzerland Government Support for Ethanol and Biodiesel in the United States © 2006, International Institute for Sustainable Development Acknowledgments The International Institute for Sustainable Development contributes to sustainable development by advancing This report was written by Doug Koplow (Earth Track). The author is grateful for the dedication, assistance and policy recommendations on international trade and investment, economic policy, climate change and energy, encouragement provided by Ronald Steenblik, Director of Research for the Global Subsidies Initiative, who man- measurement and assessment, and sustainable natural resources management. -
Biofuels, Solar and Wind As Renewable Energy Systems David Pimentel Editor
Biofuels, Solar and Wind as Renewable Energy Systems David Pimentel Editor Biofuels, Solar and Wind as Renewable Energy Systems Benefits and Risks 123 Editor Dr. David Pimentel Cornell University College of Agriculture and Life Sciences 5126 Comstock Hall Ithaca, NY 15850 USA [email protected] ISBN: 978-1-4020-8653-3 e-ISBN: 978-1-4020-8654-0 Library of Congress Control Number: 2008931413 Chapter 5 c The Authors c 2008 Springer Science+Business Media B.V. No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work. Cover Images Dutch windmill (Courtesy of Schoen Photography, www.schoenphotography.com) c Schoen Photography, Colorado, USA Wind turbine c 2008 JupiterImages Corporation Printed on acid-free paper 987654321 springer.com Preface The petroleum age began about 150 years ago. Easily available energy has sup- ported major advances in agriculture, industry, transportation, and indeed many diverse activities valued by humans. Now world petroleum and natural gas sup- plies have peaked and their supplies will slowly decline over the next 40–50 years until depleted. Although small amounts of petroleum and natural gas will remain underground, it will be energetically and economically impossible to extract. In the United States, coal supplies could be available for as long as 40–50 years, depending on how rapidly coal is utilized as a replacement for petroleum and natural gas. -
Para Introducción
UNIVERSIDAD AUTÓNOMA METROPOLITANA “DEGRADACIÓN DE METIL TERT-BUTIL ÉTER (MTBE) Y OTROS OXIGENANTES DE LA GASOLINA POR HONGOS FILAMENTOSOS” T E S I S Que para obtener el grado de Doctor en Biotecnología P R E S E N T A M. en B. MIGUEL MAGAÑA REYES Director Dr. Sergio Revah Moiseev Enero/ 2007 “El aire es precioso para el piel roja, pues todos los seres comparten el mismo aliento: el animal, el árbol, el hombre..., todos respiramos el mismo aire. El hombre parece no notar el aire que respira. Como un moribundo que agoniza desde hace muchos días, es insensible a la pestilencia. Pero si nosotros os vendemos nuestras tierras no debéis olvidar que el aire es precioso, que el aire comparte su espíritu con toda la vida que mantiene. El aire dio a nuestros padres su primer aliento y recibió su última expiación. Y el aire también debe dar a nuestros hijos el espíritu de la vida. Y si nosotros os vendemos nuestras tierras, debéis apreciarlas como algo excepcional y sagrado, como el lugar donde también el hombre blanco sienta que el viento tiene el dulce aroma de las flores de las praderas. Enseñad a vuestros hijos lo que nosotros hemos enseñado a nuestros hijos: la tierra es nuestra madre. Lo que afecte a la tierra, afectará también a los hijos de la tierra. Si los hombres escupen a la tierra, se escupen a si mismos. Porque nosotros sabemos esto: la tierra no pertenece al hombre, sino el hombre a la tierra. Todo está relacionado como la sangre que une a una familia. -
SELECTED BIBLIOGRAPHY of the FUEL OXYGENATE METHYL Te/F-BUTYL ETHER (MTBE) with EMPHASIS on WATER QUALITY
SELECTED BIBLIOGRAPHY OF THE FUEL OXYGENATE METHYL te/f-BUTYL ETHER (MTBE) WITH EMPHASIS ON WATER QUALITY U.S. GEOLOGICAL SURVEY Open-File Report 97-564 National Water-Quality Assessment Study Unit NATIONAL WATER-QUALITY ASSESSMENT PROGRAM SELECTED BIBLIOGRAPHY OF THE FUEL OXYGENATE METHYL terf-BUTYL ETHER (MTBE) WITH EMPHASIS ON WATER QUALITY By Ellse V. Brachtl, Curtis V. Price, and Rick M. Clawges U.S. GEOLOGICAL SURVEY Open-File Report 97-564 Rapid City, South Dakota 1997 U.S. DEPARTMENT OF THE INTERIOR BRUCE BABBITT, Secretary U.S. GEOLOGICAL SURVEY Gordon P. Eaton, Director For additional information write to: Copies of this report can be purchased from: District Chief U.S. Geological Survey U.S. Geological Survey Information Services 1608 Mt. View Road Box 25286 Rapid City, SD 57702 Federal Center Denver, CO 80225 FOREWORD The mission of the U.S. Geological Survey Describe how water quality is changing over (USGS) is to assess the quantity and quality of the time. earth resources of the Nation and to provide informa Improve understanding of the primary natural tion that will assist resource managers and policy- and human factors that affect water-quality conditions. makers at Federal, State, and local levels in making This information will help support the develop sound decisions. Assessment of water-quality condi ment and evaluation of management, regulatory, and tions and trends is an important part of this overall monitoring decisions by other Federal, State, and local mission. agencies to protect, use, and enhance water resources. One of the greatest challenges faced by water- The goals of the NAWQA Program are being resources scientists is acquiring reliable information achieved through ongoing and proposed investigations that will guide the use and protection of the Nation's of 59 of the Nation's most important river basins and water resources. -
Read Book « Fuel Additives ~ GYNZNZIFNQ7W
O31GXDQTOYLH # PDF « Fuel additives Fuel additives Filesize: 4.98 MB Reviews This publication is definitely worth purchasing. Yes, it is actually engage in, nevertheless an amazing and interesting literature. You can expect to like just how the author write this publication. (Odie Dicki) DISCLAIMER | DMCA P9UP2LTEETJ2 / eBook » Fuel additives FUEL ADDITIVES To read Fuel additives PDF, you should follow the link under and download the file or have access to additional information that are relevant to FUEL ADDITIVES book. Reference Series Books LLC Jan 2012, 2012. Taschenbuch. Book Condition: Neu. 252x192x10 mm. This item is printed on demand - Print on Demand Neuware - Source: Wikipedia. Pages: 48. Chapters: Antiknock agents, Fuel antioxidants, Fuel dyes, Oxygenates, Ethanol, Methanol, Toluene, Ferrocene, Butylated hydroxytoluene, Tetraethyllead, Methyl tert-butyl ether, Acetone, Coumarin, Isopropyl alcohol, Nitromethane, Iron pentacarbonyl, Ethylenediamine, 1,2-Dichloroethane, MTBE controversy, Methylcyclopentadienyl manganese tricarbonyl, Tetranitromethane, Butyl rubber, Fuel Freedom International, 1,2-Dibromoethane, 2,2,4- Trimethylpentane, Tert-Butanol, Tricresyl phosphate, Sudan IV, Gasoline additive, 2,6-Di-tert-butylphenol, Solvent Yellow 124, Triacetin, Dimethyl methylphosphonate, Tert-Amyl methyl ether, Biobor, Dinonylnaphthylsulfonic acid, Diisopropyl ether, 2,4-Dimethyl-6-tert-butylphenol, Sudan Red 7B, Ecalene, Dry gas, Metal deactivator, Solvent Red 26, Solvent Red 164, Oil Blue 35. Excerpt: Ethanol, also called ethyl alcohol, pure alcohol, grain alcohol, or drinking alcohol, is a volatile, flammable, colorless liquid. It is a powerful psychoactive drug and one of the oldest recreational drugs. Best known as the type of alcohol found in alcoholic beverages, it is also used in thermometers, as a solvent, and as a fuel. -
Assessment of the Relationship Between the Spilled LNAPL Volume and Its Thickness in Monitoring Wells Considering the Water Table Fluctuation History
Assessment of the relationship between the spilled LNAPL volume and its thickness in monitoring wells considering the water table fluctuation history Muhammad Saleem Civil Engineering March 2005 Abstract The quantification of spilled hydrocarbon is of vital importance and is a first step in the remediation hierarchy. In most cases, watertable elevation and hydrocarbon thickness are the primary field data available to enable the evaluation of the extent of hydrocarbon contamination. However, because of the unavailability of relationship between the spilled hydrocarbon and its thickness in the monitoring wells under dynamic water table conditions, there is a marked paucity of research considering fluctuating water table conditions. A mathematical model was developed to predict the extent of hydrocarbon contamination. Developed model incorporates the water table fluctuation history, hysteresis, and entrapment. An experimental setup was utilized to obtain data on hydrocarbon thickness with the fluctuated water table conditions. The data obtained from the study were used to validate the mathematical model. In the experimental program four runs were performed: Uniform sand and well- graded sand were used with diesel and kerosene. Simulation results using the developed model were compared with experimental as well as results reported in the literature. Critical spilled volumes noted for all four runs were 4.8, 4.3, 4.15, and 3.9 cm³/cm², respectively. Comparison of experimental results based on hydrostatic conditions with the results predicted by different models reported in the literature were also performed. Comparison on the basis of percentage error shows that the developed mathematical model is the best predictor in all four cases (with percentage error of 5.8 to 10.7%, 3.7 to 19.7%, 0.6 to 6.1% and 1.6 to 10.0% respectively). -
February 2010 Teacher's Guide Table of Contents
February 2010 Teacher's Guide Table of Contents About the Guide ............................................................................................................ 3 Student Questions ........................................................................................................ 4 Answers to Student Questions .................................................................................... 6 ChemMatters Puzzle: Chemical Ronion .................................................................... 11 Answers to the ChemMatters Puzzle......................................................................... 12 NSES Correlation ........................................................................................................ 13 Anticipation Guides .................................................................................................... 14 The Many Colors of Blood....................................................................................................................... 15 Anesthesia: Chemistry in the Operating Room ....................................................................................... 16 Battling Wildfires: When Water Won’t Cut It............................................................................................ 17 Green Gasoline: Fuel from Plants ........................................................................................................... 18 The Makeup of Mineral Makeup............................................................................................................. -
Subsidies to Ethanol in the United States
Chapter 4 Subsidies to Ethanol in the United States Doug Koplow and Ronald Steenblik Abstract Ethanol, or ethyl alcohol used for motor fuel, has long been used as a transport fuel. In recent years, however, it has been promoted as a means to pursue a multitude of public policy goals: reduce petroleum imports; improve vehicle emis- sions and reduce emissions of greenhouse gases; and stimulate rural development. Annual production of ethanol for fuel in the United States has trebled since 1999 and is expected to reach almost 7 billion gallons in 2007. This growth in production has been accompanied by billions of dollars of investment in transport and distribution infrastructure. Market factors, such as rising prices for petroleum products and state bans on methyl tertiary butyl ether (MTBE), a blending agent for which ethanol is one of the few readily available substitutes, drove some of this increase. But the main driving factor has been government support, provided at every point in the supply chain and from the federal to the local level. This chapter reviews the major policy developments affecting the fuel-ethanol industry of the United States since the late 1970s, quantifies their value to the industry, and evaluates the efficacy of ethanol subsidization in achieving greenhouse gas reduction goals. We conclude that not only is total support for ethanol already substantial — $5.8–7.0 billion in 2006 — and set to rise quickly, even under existing policy settings, but its cost effectiveness is low, especially as a means to reduce greenhouse gas emissions. Keywords Agriculture · biofuel · corn · energy · ethanol · policy · renewable energy · subsidies · support · United States D.