Implications for Energy Innovation from the Chemical Industry
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Curriculum Vitae Professor Dr. Martin Jansen
Curriculum Vitae Professor Dr. Martin Jansen Name: Martin Jansen Born: 5 November 1944 Main areas of research: preparative solid-state chemistry, crystal chemistry, materials research, structure-property relationship of solids Since 1998, he has been a member of the scientific council of the Max Planck Society and a director at the Max Planck Institute for solid-state research in StuttgartHe has developed a concept for plan- ning solid state syntheses, combining computational and experimental tools, that is pointing the way to rational and efficient discovery of new materials. Academic and Professional Career since 1998 Director at the Max Planck Institute for Solid State Research, Stuttgart and Honorary Professor at the University of Stuttgart, Germany 1987 - 1998 Professor (C4) and Director of the Institute at the University of Bonn, Germany 1981 - 1987 Professor (C4), Chair B for Inorganic Chemistry of the University of Hannover, Germany 1978 Habilitation at the University of Gießen, Germany 1973 Promotion (Ph.D.) at the University of Gießen, Germany 1966 - 1970 Study of Chemistry at the University of Gießen, Germany Honours and Awarded Memberships (Selection) 2019 Otto-Hahn-Prize 2009 Centenary Prize, Royal Society of Chemistry, UK 2009 Georg Wittig - Victor Grignard Prize, Société Chimique de France 2008 Member of acatech (National Academy of Science and Engineering) Nationale Akademie der Wissenschaften Leopoldina www.leopoldina.org 1 2007 Karl Ziegler Award, Germany 2004 Honorary Doctorate of the Ludwig Maximilians-University of -
Burton Introduces Thermal Cracking for Refining Petroleum John Alfred Heitmann University of Dayton, [email protected]
University of Dayton eCommons History Faculty Publications Department of History 1991 Burton Introduces Thermal Cracking for Refining Petroleum John Alfred Heitmann University of Dayton, [email protected] Follow this and additional works at: https://ecommons.udayton.edu/hst_fac_pub Part of the History Commons eCommons Citation Heitmann, John Alfred, "Burton Introduces Thermal Cracking for Refining Petroleum" (1991). History Faculty Publications. 92. https://ecommons.udayton.edu/hst_fac_pub/92 This Encyclopedia Entry is brought to you for free and open access by the Department of History at eCommons. It has been accepted for inclusion in History Faculty Publications by an authorized administrator of eCommons. For more information, please contact [email protected], [email protected]. 573 BURTON INTRODUCES THERMAL CRACKING FOR REFINING PETROLEUM Category of event: Chemistry Time: January, 1913 Locale: Whiting, Indiana Employing high temperatures and pressures, Burton developed a large-scale chem ical cracking process, thus pioneering a method that met the need for more fuel Principal personages: WILLIAM MERRIAM BURTON (1865-1954), a chemist who developed a commercial method to convert high boiling petroleum fractions to gas oline by "cracking" large organic molecules into more useful and marketable smaller units ROBERT E. HUMPHREYS, a chemist who collaborated with Burton WILLIAM F. RODGERS, a chemist who collaborated with Burton EUGENE HOUDRY, an industrial scientist who developed a procedure us ing catalysts to speed the conversion process, which resulted in high octane gasoline Summary of Event In January, 1913, William Merriam Burton saw the first battery of twelve stills used in the thermal cracking of petroleum products go into operation at Standard Oil of Indiana's Whiting refinery. -
Invention and Innovation in the Petroleum Refining Industry
This PDF is a selection from an out-of-print volume from the National Bureau of Economic Research Volume Title: The Rate and Direction of Inventive Activity: Economic and Social Factors Volume Author/Editor: Universities-National Bureau Committee for Economic Research, Committee on Economic Growth of the Social Science Research Council Volume Publisher: Princeton University Press Volume ISBN: 0-87014-304-2 Volume URL: http://www.nber.org/books/univ62-1 Publication Date: 1962 Chapter Title: Invention and Innovation in the Petroleum Refining Industry Chapter Author: John L. Enos Chapter URL: http://www.nber.org/chapters/c2124 Chapter pages in book: (p. 299 - 322) Invention and Innovation in the Petroleum Refining Industry JOHN L. ENOS MASSACHUSETTS INSTITUTE OF TECHNOLOGY AN INNOVATION is the combination of many different activities. Gener- ally an invention is made and recognized, capital is obtained, plant is acquired, managers and workers are hired, markets are developed, and production and distribution take place. As the innovation proceeds the original conception may be altered to make it more amenable to commercial realities. Accomplishing these activities consumes re- sources. At any point in the sequence failure may occur, delaying or even frustrating the innovation. In studying the petroleum refining industry I observed several pro- cessing innovations following one another in time and generating technological progress.' I then sought their origins in terms of the original ideas and the men who conceived them. In this paper I shall discuss the relations between the inventions and the subsequent inno- vations, focusing on the intervals between them, the returns to the inventors and innovators, and the changes in the proportions in which the factors of production in petroleum processing were combined. -
475528 1 En Bookfrontmatter 1..21
Primed for Success: The Story of Scientific Design Company “More than a company history, Primed for Success is the story of the chemical industry in the United States. It is comprehensive in scope and detailed in its treatment—an essential read for anyone who studies the chemical industry or has been part of it.” —Thomas M. Connelly, Chief Executive Officer, ACS “Peter Spitz’ detailed and engrossing account of the rise of the petrochemical industry—which set in motion the building blocks of the modern industrial economy—captures how transformative the industry has been to not just economic development, but to so many aspects of modern life.” —Andrew N. Liveris, Former Chairman and CEO, Dow Chemical “Peter Spitz is opening up a new chapter in the history of the petrochemical industry that provides a lasting platform and remembrance of the great entrepreneurs of the industry. The new book should be very valuable for the new generation of chemical engineers as they recognize the vision and creativity of many courageous scientists and engineers.” —Werner Praetorius, President Petrochemicals (ret.), BASF Group “Peter Spitz delivers an essential history with Primed for Success. He details the inside story of a disruptive startup that invented the breakthrough technologies that would help usher in the petrochemical age. The book’s insights on entrepreneurship, successful innovation and the risks of overreach and hubris offer enduring lessons for today’s engineers and professionals as well.” —Robert Westervelt, Editor-in-Chief, Chemical Week “Ralph Landau was one of the giants of the chemical engineering profession. Both experienced and early-stage chemical engineers can appreciate how Ralph created a new business model as well as learn many lessons from his technical and business leadership.” —June C. -
A Case Study in Fluid Catalytic Cracking
THERMAL DENOX OPTIMIZATION: A CASE STUDY IN FLUID CATALYTIC CRACKING by: David E. Rozier III A thesis submitted to the faculty of the University of Mississippi in partial fulfillment of the requirements of the Sally McDonnell Barksdale Honors College Oxford May 2017 Approved by: ______________________________ Advisor: Dr. Adam Smith ______________________________ Reader: Dr. John O’Haver ______________________________ Reader: Dr. Wei-Yin Chen i © 2017 David E. Rozier III ALL RIGHTS RESERVED ii This thesis is dedicated to my late grandfather, David E. Rozier, Sr., who was fond of saying, “A job worth doing is a job worth doing well.” iii Acknowledgments First and foremost, my completion of this thesis would not have been possible without the love and support of my family and friends, especially my parents, Dave and Jackie Rozier. I would like to thank Dr. Adam Smith, Dr. John O’Haver, Dr. Wei-Yin Chen, and Mr. David Carroll for their feedback and encouragement. I would also like to thank ExxonMobil for affording me the opportunity as an intern to conduct this project work and granting me permission to publish technical details. Finally, I must thank all of my coworkers in Operations Support at the Baton Rouge Refinery for their assistance with the project discussed here. iv Abstract This thesis will first provide background information on fluid catalytic cracking (FCC), a highly important unit operation to the process of petroleum refining, and a description of Thermal DeNOx, an environmental treatment system common to FCC units and other process units where high temperature furnaces are used. Next, this thesis will detail a project which I had the chance to lead as a process engineering intern at ExxonMobil’s Baton Rouge Refinery in the fall of 2016. -
AWARDS, HONORS, DISTINGUISHED LECTURESHIPS Prof. Dr. Dieter Seebach
AWARDS, HONORS, DISTINGUISHED LECTURESHIPS Prof. Dr. Dieter Seebach 1964 <> Wolf-Preis for the Ph.D. thesis, Universität Karlsruhe, Germany 1969 <> Dozentenpreis Fonds der Chemischen Industrie, Germany 1969/1970 – Visiting Professorship, University of Wisconsin, Madison, USA 1972 – "DuPont Travel Grantee", USA (lectures at 15 universities and companies) 1974 – Visiting Professorship, California Institute of Technology, Pasadena, USA 1977 – Visiting Professorship, Rand Afrikaans University, Johannesburg, South Africa – "Pacific Coast Lectureship“, USA/Canada (9 lectures at universities and companies along theUSA west coast) 1978 – Visiting Professorship, Polish Academy of Sciences (lectures in Warsaw and Lodz) 1980 – Visiting Professorship, Australian National University, Canberra, Australia – Visiting Professorship, Imperial College, London, U.K. 1981 – Visiting Professorship at the Weizmann Institute of Science, Rehovot, Israel –"Kolthoff Lectureship", University of Minnesota, Minneapolis, USA 1981 – „Carl Ziegler Visiting Professorship“, Max-Planck-Institut für Kohlenforschung, Mülheim a.d.Ruhr, Germany 1982 – "Vorhees Memorial Lectureship", University of Illinois, Urbana-Champaign, USA – "First Atlantic Coast Lectureship", (6 lectures at universities of the South-East of USA) – "Organic Syntheses Lectureship", Princeton University, Princeton, USA 1984 <> FRSC (Fellow of the Royal Society of Chemistry, U.K.) <> Elected member of the Deutsche Akademie der Naturforscher Leopoldina, D-Halle – "Greater Manchester Lectureship", University -
Department of Chemical Engineering, Report to the President 2014-2015
Department of Chemical Engineering Overview The Department of Chemical Engineering (ChemE) continues to be ranked as the world’s number-one chemical engineering program, a position it has held for the past 26 years. Many of our faculty received major honors and awards this year. Despite this continuity, there have been some significant changes in the physical space that the department has occupied for almost 40 years and a recent change in leadership. Research volume in the department continues to be strong, increasing by 7% this year to $57.6 million. Of these funds, $23.6 million were handled directly through the department, and the rest was handled by different cost centers at MIT, including the Koch Institute for Integrative Cancer Research, the MIT Energy Initiative, the Institute for Soldier Nanotechnologies, and the Ragon Institute. The strong engagement with these interdisciplinary centers continues to provide a robust basis for innovation, and provides our students with experience solving important and difficult real-world problems. Professor Klavs F. Jensen stepped down as department head in July 2015, after leading the department for eight years. Among his many accomplishments are significant space renovations, including the modernization of Building 66 and new faculty laboratories in buildings E17 and E18; successful recruiting 10 new faculty members; and exemplary leadership. His many years of service are greatly appreciated by the faculty and staff of the Department of Chemical Engineering. Paula T. Hammond, the David H. Koch professor in engineering, became the new head of the Department of Chemical Engineering, effective July 13, 2015. Professor Hammond is an accomplished researcher with a strong record of service to MIT and the department. -
Philip D. Lane Ziegler-Natta Catalysis: the Nature of the Active Site Literature Seminar April 3, 1992 Karl Ziegler, While Study
47 Ziegler-Natta Catalysis: The Nature of the Active Site Philip D. Lane Literature Seminar April 3, 1992 Karl Ziegler, while studying ethylene insertion into aluminum-alkyl bonds, serendipi tously discovered the effect transition metals had on ethylene polymerization. He and Guilio Natta made significant contributions to the catalytic polymerization of olefins using a transition metal from groups 4-8 and an organometallic from groups 1, 2, or 13, the most famous com bination being TiC4 + Al(C2H5)3 for the polymerization of polyethylene. The Nobel Prize in Chemistry was awarded to them in 1963 for their contributions in this area [l,2]. The impor tance of this catalytic process can be seen by the amount of polyethylene produced in the U.S. In 1990, 8.3 billion lbs. of high-density polyethylene were produced [3]. The heterogeneous nature of Ziegler-Natta catalysts make them difficult to study [l,4,5]. Despite improved techniques for studying surfaces, information on an atomic level about the active sites remains elusive. For example, the surface reaction of [Zr(allyl)4] with SiQi leads to different surface species [5]. It is not clear which of the resulting surface species is responsible for the polymerization process. Various mechanisms [6,7] have been proposed for Ziegler-Natta catalysis, with the most widely accepted proposal from Cossee and Adman (Figure 1). The aluminum-alkyl is suggested to be responsible for alkylating the transition metal which is in an octahedral environment with one site vacant. Ethylene is thought to coordinate, followed by direct insertion into the metal-alkyl bond of the transition metal. -
JUN 2 41996 Science
POLYMER-BASED SOLVENTS FOR MINIMIZING POLLUTION DURING THE SYNTHESIS OF FINE CHEMICALS by Linda K. Molnar B.S., Chemistry University of Pittsburgh, 1991 Submitted to the Department of Materials Science and Engineering Program in Polymer Science and Technology in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy at the Massachusetts Institute of Technology June 1996 © 1996 Massachusetts Institute of Technology All rights reserved Signature of A uthor ....................... ............ Department of Materials Science anidEngineering Program in Polymer Science and Technology May 3, 1996 Certified by ........................................................... .............. T. Alan Hatton Ralph Landau Professor of Chemical Engineering Practice Thesis Supervisor Certified by.... ......................... Stephen L. Buchwald Professor of Chemistry T~esis Supervisor Accepted by ............. Michael F. Rubner TDK Professor of Materials Science and Engineering Chair, Departmental Committee of Graduate Students SOF TECHNOLOGY OF TECýNNLOC~ JUN 2 41996 Science UBRARiES Polymer-Based Solvents for Minimizing Pollution During the Synthesis of Fine Chemicals by Linda K. Molnar Submitted to the Department of MaterialsScience and Engineering Program in Polymer Science and Technology on May 3, 1996 in PartialFulfillment of the Requirementsfor the Degree of Doctorof Philosophy ABSTRACT Most processes used in the pharmaceutical industry are, by necessity, carried out in organic solvents. In many cases these solvents are volatile and sufficiently water-soluble to contaminate air emission and aqueous discharge streams, adding to the environmental burden and the cost of downstream processing and recovery operations. One example is the use of tetrahydrofuran (THF) as the solvent for Grignard reactions which must be carried out under anhydrous conditions. The desired product is often obtained by aqueous precipitation. -
The Catalytic Development of High Octane Gasoline Lead
Volume 16 Number 041 Giving Gas a Boost: The Catalytic Development of High Octane Gasoline Lead: In the 1930s, oil companies were struggling to boost the octane of gasoline. Eugène Houdry’s catalytic cracking process made it possible and may have helped win World War II. Intro.: A Moment in Time with Dan Roberts. Content: When it comes from the ground, crude oil is almost useless, a mixture of thousands of different types of hydrocarbons: asphalt to gasoline to natural gas. Each has a different molecular weight, therefore, crude oil must be refined to pull out the impurities such as sulfur compounds and separate different components such as kerosene, gasoline, fuel oil, and so forth. In the 19th century kerosene was the most valuable product because it was used in lamps and for heating. Because it was so unstable, gasoline was often just dumped on the ground or in a nearby stream and natural gas, considered completely useless, was just burned off at the well. By the early 20th century things had changed. Because of the automobile, the most valuable product of crude oil had become gasoline. It, however, was becoming more and more rare as automobiles grew in number and power. The problem was that not all gasoline was the same. Different grades of gas are determined by the level of octane they contain. The scale is 0 to 100. The higher the number the greater the power and the less knocking. In an internal combustion engine, gasoline is combined with air inside a cylinder, it is then fired off by a spark plug, and the resulting explosion creates compression which pushes the cylinder and turns the engine. -
The Department of Chemical Engineering at MIT Maintained Its Usual High Productivity and Visibility in Teaching and Research
Department of Chemical Engineering In academic year 2004, the Department of Chemical Engineering at MIT maintained its usual high productivity and visibility in teaching and research. For the 15th consecutive year, both our graduate and undergraduate programs garnered the number‐one ranking among the nation’s chemical engineering departments by US News and World Report. The department also had a tremendous year fiscally, with research expenditures of $23.3 million. During the academic year, 28 doctoral degrees (PhD and ScD) were awarded, along with 36 SM and/or master’s‐level degrees, yielding a total of 64 advanced degrees conferred. Forty‐one SB degrees were conferred as of June 2004, with 70 percent awarded to women. The department’s undergraduate enrollment stands at 140 students. The graduate student enrollment is stable at 258 students, with 232 in the doctoral program and 26 master’s‐level degree candidates. The graduate programs include 91 foreign, 75 female, 28 Asian American, and 10 self‐identified minority students. This year, we received 335 applications for our doctoral program and offered admissions to 75 individuals, of which 53 accepted our admissions. Among the incoming class for 2004, 14 are female and 8 are minority or Asian American graduate students. Renovation of the Edwin R. Gilliland Auditorium, on the first floor of the Ralph Landau Building, has added updated audiovisual, networking, and digital media technology to the lecture hall. This has substantially improved both the teaching environment for several key departmental undergraduate and graduate courses and the functionality of the space for various lectures events. Modernized lighting and finishes in the first floor corridor effectively link the renovated auditorium to an Edwin R. -
The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals
University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange Masters Theses Graduate School 8-2013 The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals Zachary Reynolds Sprigler [email protected] Follow this and additional works at: https://trace.tennessee.edu/utk_gradthes Recommended Citation Sprigler, Zachary Reynolds, "The Design of Redox-Active, Olefin Polymerization Catalysts Using Late- Transition Metals. " Master's Thesis, University of Tennessee, 2013. https://trace.tennessee.edu/utk_gradthes/2458 This Thesis is brought to you for free and open access by the Graduate School at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Masters Theses by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. To the Graduate Council: I am submitting herewith a thesis written by Zachary Reynolds Sprigler entitled "The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals." I have examined the final electronic copy of this thesis for form and content and recommend that it be accepted in partial fulfillment of the equirr ements for the degree of Master of Science, with a major in Chemistry. Brian K. Long, Major Professor We have read this thesis and recommend its acceptance: Jimmy Mays, David Jenkens Accepted for the Council: Carolyn R. Hodges Vice Provost and Dean of the Graduate School (Original signatures are on file with official studentecor r ds.) The Design of Redox-Active, Olefin Polymerization Catalysts Using Late-Transition Metals A Thesis Presented for the Masters of Science Degree The University of Tennessee, Knoxville Zachary Reynolds Sprigler August 2013 Copyright © 2013 by Zachary R.